ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Emulsion and miniemulsion copolymerizations were carried out with acrylic monomers (methyl methacrylate, butyl acrylate, and acrylic acid) in the presence of an alkyd resin. Poly(methyl methacrylate) was used as a hydrophobe or cosurfactant in the miniemulsion reactions. The results demonstrate that miniemulsion polymerization is the preferred process, probably because of mass transport limitations of the alkyd in the conventional emulsion polymerization reactions. The monomer emulsions prepared for the miniemulsion reactions were much more stable and the polymerizations were free of coagulum. Reaction rates, particle size characteristics, grafting efficiencies, and some film properties were measured. © 1996 John Wiley & Sons, Inc.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
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