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  • 1
    Electronic Resource
    Electronic Resource
    In-vitro apatite formation on phosphorylated bamboo (1997)
    Springer
    Journal of materials science 8 (1997), S. 543-549 
    Details
    ISSN: 1573-4838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Technology
    Notes: Abstract Natural self-reinforced composite, bamboo, was surface modified by phosphorylation with urea–H3PO4 and NaOH–H3PO4 methods; then precalcification was performed by immersing samples in saturated Ca(OH)2 solution. After that, calcium phosphate can be formed on the surface of bamboo samples in calcification media: simulated body fluid (1.5 SBF) and accelerated calcification solution (ACS). Experimental results reveal that pre-calcification is an inevitable step for the formation of calcium phosphate. The calcium phosphate formed in 1.5 SBF was identified by thin-film X-ray diffraction as apatite which was not well crystallized. Compared with the urea–H3PO4 method, the NaOH–H3PO4 method has the advantages of quicker and continuous apatite formation and stronger adhesive between apatite and bamboo.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1018546730925
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  • 2
    Electronic Resource
    Electronic Resource
    The role of hydrated silica, titania, and alumina in inducing apatite on implants (1994)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 28 (1994), S. 7-15 
    Details
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Pure soluble silica prepared by a sol-gel method induced bone-like hydroxyapatite formation onto its surface when the silica was immersed in a simulated body fluid (SBF), whereas silica glass and quartz did not. This finding directly supports the hypothesis that hydrated silica plays an important role in biologically active hydroxyapatite formation on the surfaces of bioactive glasses and glass-ceramics, which leads to bone-bonding. Gel-derived titania is also a hydroxyapatite inducer because of its abundant TiOH groups. These results provide further insight into the unique osseointegration of titanium and its alloys. It is suspected that gel-derived titania develops an apatite layer by taking calcium and phosphate from the body fluid, thus producing bonebonding. Although sufficient AlOH groups may remain in the alumina gel, they do not serve to initiate apatite generation when immersed in SBF. This phenomenon explains the fact that an intermediate fibrous tissue is usually found to separate the alumina implant from bone. One may infer that both abundant OH groups and negatively charged surfaces of gel-derived silica and titania are important for hydroxyapatite induction. Material which possesses and / or develops both a negatively charged surface and abundant OH groups in a physiologically-related fluid is most likely to be an efficient apatite inducer. Such materials are suitable candidates to serve as bone-bonding biomaterials. © 1994 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jbm.820280103
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Collagen/apatite coating on 3-dimensional carbon/carbon composite (1998)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 40 (1998), S. 520-529 
    Details
    ISSN: 0021-9304
    Keywords: 3D carbon/carbon composite ; collagen/apatite composite ; coating ; grafting ; phosphorylation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: A three-dimensional carbon/carbon composite (3D C/C) was studied as potential bone-repairing material; its major mechanical properties were found to be closer to those of human bone than other common bone-repairing materials available. In vitro calcification tests revealed that as-received 3D C/C is almost bioinert in simulated body fluid (SBF) over an immersion period of 4 weeks. To improve the bioactivity of 3D C/C, surface modification was accomplished through two practical routes: (1) grafting with polyethylene glycol (PEG) and (2) phosphorylation and precalcification. After grafting with α, ω di(aminopropyl) polyethylene glycol 800 (NH2-PEG-NH2), a continuous layer of calcium phosphate was formed on the surface of 3D C/C in SBF after 4 weeks. Phosphorylated 3D C/C samples have the ability to induce apatite precipitation after precalcification in a saturated Ca(OH)2 solution for 1 week. To speed up the coating process, a calcification solution with collagen was developed in which a collagen/apatite coating layer can be formed on 3D C/C in 9 h in ambient conditions. © 1998 John Wiley & Sons, Inc. J Biomed Mater Res, 40, 520-529, 1998.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Tensile tests of interface between bone and plasma-sprayed HA coating-titanium implant (1998)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 43 (1998), S. 113-122 
    Details
    ISSN: 0021-9304
    Keywords: plasma-sprayed HA coating ; HA coating-metal substrate ; tensile strength ; degradation ; bone bonding ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Tensile strength testing of the interface between bone and a plasma-sprayed hydroxyapatite (HA) coating-Ti-6Al-4V (implant I) and an HA coating-Ti (implant II) was performed. The bone-implant interface and tensile failure mode were evaluated by light microscopy (LM), SEM-energy dispersive X-ray analysis, and backscattered electron imaging. The crystallinity of the HA coating of implant I and implant II was 62 and 40%, respectively. Eleven semidisk implants of each type were inserted in the left tibia of 22 rabbits in each period. After 2, 4, 8, and 16 weeks, the tensile strength of the bone-implant I was 0.86, 1.32, 1.10, and 0.92 MPa, respectively; the value of the bone-implant II was 0.66, 0.92, 0.84, and 1.12 MPa, respectively. No significant difference was found in tensile strength between implant I and implant II, and between the data of different periods. LM and SEM revealed that the two types of coatings behave the same in bone. Failure after the tensile test mainly occurred at the bony tissue at 2 and 4 weeks, inside the HA coating layer at 8 weeks, and at the HA coating-metal substrate interface at 16 weeks. Degradation and delamination of the HA coating continued with time, resulting in the interfacial tensile strength not increasing with time. Thus, we concluded that differences between the two implants, mainly the difference in crystallinity of the HA coating (62 vs. 40%), have no significant influence on bone bonding ability, bone bonding strength, tensile failure mode, and degradation of the coating. © 1998 John Wiley & Sons, Inc. J Biomed Mater Res (Appl Biomater) 43: 113-122, 1998
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Synthesis and viscosity behavior of poly(γ-p-biphenylmethyl-L-glutamate) in benzene/dichloroacetic acid mixtures, a comparison with poly(γ-benzyl-L-glutamate) (1974)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 175 (1974), S. 3193-3206 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Darstellung von Poly(γ-p-biphenylmethyl-L-Glutamat), PBPLG, (Poly{L-imino-1-[2-(4-biphenylmethoxycarbonyl)äthyl]-2-oxoäthylen}), (1d) wird beschrieben. Das Viskositätsverhalten dieses Polymers in Mischungen aus Benzol und Dichloressigsäure (c=0,2.10 - 3 - 1,4.10 - 3g/cm3) bei 25°CC wird untersucht. Die Ergebnisse werden verglichen mit Messungen unter den gleichen Bedingungen an Poly(γ-benzyl-L-Glutamat),PBLG, (Poly[ L-imino-l-(2-benzyloxycarbonylathyl)-2-oxoathylen]), (lc). In beiden Fallenfindet ein zweistufiger Ubergang von einer starren, von Wasserstoffbrucken stabilisiertenHelix in ein statistisches, solvatisiertes Knduel statt : PBPLG (erste Stufe CrSSX,, zweite Stufe 55-100%, Dichloressigsaure und PBLG (erste Stufe 0-70%, zweite Stufe 70-100%,Dichloressigsaure)).Die Einfiihrung eines p-Phenylsubstituenten in PBLG fuhrt deshalb in Mischungen aus Benzol- und Dichloressigsaure zu einer weniger stabilisierten Helix.Die Stabilitat und das Viskositatsverhalten von PBLG in Mischungen aus Benzol und Dichloressigsaure (c=0,2.10-3 -14.10-3g/cm3) sind denjenigen von PBLG in Mi-schungen aus m-Kresol und Dichloressigslure ( c = 1,0.10-3-4,0. 10-3g/cm3) ähnlich.
    Notes: The synthesis of poly(γ-p-biphenylmethyl-L-glutamate), PBPLG, (poly{L-imino-1-[2-(4-biphenylylmethoxycarbonyl)ethyl]-2-oxoethylene}), (1d) is described. The viscosity behavior of this polymer in benzene/dichloroacetic acid mixtures (c=0,2.10 - 3 - 1,4.10 - 3 g/cm3) at 25°CC is investigated. The results are compared with measurements on poly(γ-benzyl-L-glutamate), PBLG, (poly[L-imino-1-(2-benzyloxycarbonylethyl)-2-oxoethylene]), (1c) under the same conditions. A transition from a rigid hydrogen bonded helix to a random solvated coil occurs in two stages for both: PBPLG (first stage 0 - 55%, second stage 55 - 100% dichloroacetic acid) and PBLG (first stage 0 - 70%, second stage 70 - 100% dichloroacetic acid).Therefore, the introduction of a p-phenyl substituent in PBLG leads to a less stable helix in benzene/dichloroacetic acid mixtures.The stability and viscosity behavior of PBLG in benzene/dichloroacetic acid mixtures (c=0,2.10 - 3 - 1,4.10 - 3g/cm3) is quite similar to the behavior of PBLG in m-cresol/dichloroacetic acid mixtures (c=1,0.10 - 3 - 4,0.10 - 3 g/cm3).
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1974.021751113
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  • 6
    Electronic Resource
    Electronic Resource
    Integrity and thermal decomposition of apatite in coatings influenced by underlying titanium during plasma spraying and post-heat-treatment (1996)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 30 (1996), S. 5-11 
    Details
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The integrity and thermal decomposition of calcium apatite are influenced by the underlying titanium during plasma-spraying deposition, especially at the apatite/titanium interface. The destruction of apatite at the interface is governed by substrate temperature, titanium catalysis, and its reaction with titanium dioxide produced from oxidation of titanium in the plasma gas. The apatite in the outer layer of coatings is affected mainly by the substrate temperature and can keep its integrity with a suitable plasma-spraying procedure to minimize the increase of substrate temperature. The heat treatment of the coatings in vacuum results in the decomposition of apatite to α-tricalcium phosphate (α-TCP) and tetracalcium phosphate monoxide (TCPM) with the increase of intensity approaching the interface, which roughens the surface of the coatings. In the air-heat treatment, oxidation of titanium produces a thickened, dense rutile layer at the interface which prevents titanium atoms from diffusing into the coatings and inhibits the titanium-catalyzed decomposition of apatite. The apatite adjacent to the rutile layer reacts moderately with rutile to produce calcium titanate (CaTiO3), α- and β-TCP, while the apatite in the outer layer, separated from the rutile layer, maintains its integrity without decomposition even in a prolonged air-heat treatment. The retention of apatite integrity leads to a decreased surface roughness of the coating. © 1996 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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