Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 1595-1608 
    ISSN: 0887-6266
    Keywords: PVC blends ; thermally stimulated current depolarization ; dynamic mechanical analysis ; physical quantities of relaxation transitions ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A number of blends based on suspension poly(vinyl chloride) and stabilizers with poly(ethylene) chlorinated in a fluidized-bed reactor containing 21.8% chlorine, hydroxyl-terminated poly(butadiene), and ethylene-propylene-diene terpolymer have been studied using such methods as thermally stimulated current depolarization and dynamic mechanical analysis. Some dielectric and thermodynamic parameters (τmax, τo, Ea, ΔH*, ΔSE*, ΔG*, μeff) have been determined. Blends containing randomly chlorinated poly(ethylene) exhibited dipole-dipole interactions between the macromolecules of poly(vinyl chloride) which decreased at the expense of the long sequences of nonchlorinated methylene groups. Simultaneously, an increased physical interaction between poly(vinyl chloride) and the additives was observed in blends containing chlorinated poly(ethylene) and/or hydroxyl-terminated poly(butadiene), and ethylene-propylene-diene terpolymer. On the basis of the data of dynamic mechanical analysis obtained a heterogeneous structure of the blends is suggested. The development of a boundary interfacial layer with a proper region of relaxation proves the formation of compatible structures between the components. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 1595-1608, 1998
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 30 (1979), S. 694-699 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: With a series of CPE samples chlorinated in the solid state the composition, degree of chlorination and sequential chlorine distribution have been investigated by 13C-NMR microstructure analysis. The measuring conditions were chosen thus as to avoid the effect of incompatibility caused by chemical inhomogeneity of the degree of chlorination on the results. The samples were separated spectroscopically (without prior fractionation) into two fractions. This evaluation provides two quantitative informations on the maximum PE-like fraction γ as well as on the maximum degree of chlorination of the CPE fraction αCPE and thus on the inhomogeneity of the degree of chlorination.
    Notes: An einer feststoffchlorierten CPE-Probenserie wird eine 13C-NMR-Mikrostrukturanalyse, die die Bestimmung der Konstitution, des Chlorierungsgrades \documentclass{article}\pagestyle{empty}\begin{document}$\bar \alpha $\end{document} sowie der sequentiellen Chlorverteilung umfaßt, durchgeführt. Die Meßbedingungen wurden dabei so gewählt, daß die mit der chemischen Uneinheitlichkeit des Chlorierungsgrades \documentclass{article}\pagestyle{empty}\begin{document}$\bar \alpha $\end{document} verbundenen Unverträglichkeitserscheinungen keinen Einfluß auf die erhaltenen Meßwerte haben. An den Proben wird näherungsweise (ohne vorherige Fraktionierung) eine spektroskopische Zweikomponenten-Zerlegung vorgenommen. Mit dieser Abschätzung können quantitative Aussagen über den maximalen PE-artigen Anteil γ sowie über den maximalen Chlorierungsgrad αCPE des CPE-Anteils und damit über die Chlorierungsgrad-Uneinheitlichkeit ge wonnen werden.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 119-127 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The influence of natural, activated, and modified microzeolite with the general formula Me2/m · Al2O3 · nSiO2 · pH2O (where Me = Fe3+, Ca2+, Mg2+, Zn2+, K+, Na+) and an organic additive, such as ammonium sulfamate combined with ammonium sulfate on smoke formation and flammability of suspension poly(vinyl chloride) has been studied in the present work. Microzeolite in native (i.e., natural), activated, and modified forms has been found to possess both fire-retardant and smoke-suppressant effects in solid poly(vinyl chloride) compositions. Such effects have been best revealed by modified microzeolite containing 3,5-4% zinc. On the other hand, the ammonium sulfamate combined with ammonium sulfate is believed to act as a strong smoke-suppressant additive. Thermogravimetric examinations and limited oxygen index measurements show that microzeolite acts as a fireresistant and smoke-suppressant additive predominantly in the condensed phase. The ammonium sulfamate in combination with ammonium sulfate gives evidence of the same effects, mostly in the gaseous phase.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 47 (1993), S. 1859-1865 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Natural, activated, and modified microzeolites were studied individually and in combination with ammonium sulfamate as high-melting dispersed additives. The strength - deformation properties of poly(vinyl chloride) were improved within the interval of 3-8 wt % additive. The strengthening effect due to the considered dispersed additives can be ascribed to the optimal adhesive interaction of the phase-boundary surface and to the formation of a partially ordered dispersed phase. The tetrahedral configuration of the modified microzeolite that contains 3.5-4% zinc in its crystal lattice remains unchanged, but exhibits a reduced birefringence. These relationships are of exceptional importance for the use of poly(vinyl chloride). The introduction of certain amounts of the additives improves the melt flow of the polymer and facilitates the processibility of the compositions. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...