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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: There are different models which to try to explain the transport properties of the manganese oxides in terms of magnetic polarons, Zener double exchange and Jahn-Teller distortions of the lattice which is temperature dependent. Using Rutherford backscattering techniques (2–3 MeV He ions) we are measuring the presence of lattice distortions by studying the angular scans in the channeling mode. The angular widths (FWHM) can be used to extract both dynamic and static displacements of the atoms from their equilibrium sites. The technique is extremely powerful in the sense that local uncorrected displacements as small as 0.01 A(ring) from the equilibrium position can be detected. The extraction of the physics from the data is relatively straight forward compared to other techniques such as XRD or neturon scattering. Using a variable temperature backscattering system at our center (one of three or four systems around the world) the angular width (FWHM) is found to exhibit a dramatic change with temperature increasing with decreasing temperature showing a possible correlation with both the transport and magnetic properties. The results suggest a decrease in the lattice disorder with reduced temperature far in excess of what one would predict on the basis of a simple Debye behavior. The reduction in the lattice disorder correlates very well with the resistance vs temperature dependence. A variety of manganese oxide epitaxial thin films grown by pulsed laser deposition have been studied and the data suggests a role for structural distortions in any mechanism to explain the transport properties of these materials. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 5204-5205 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have found evidence through optical spectroscopy that AgO is indeed generated in the laser plume during pulsed laser deposition of YBa2Cu3O7−δ (YBCO) thin films using Ag-doped YBCO targets. This supports our earlier conjecture that formation of AgO in the plume and its subsequent dissociation at the elevated substrate temperature (since AgO is unstable above 350 °C) provides active oxygen to the YBCO lattice, thereby increasing oxygen incorporation during growth of YBCO thin films. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 2228-2233 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Thin Fe2O3 layers (44 and 55 nm) were deposited by pulsed excimer laser ablation on single-crystal alumina (α-Al2O3) substrates heated at 675 °C. The ion beam mixing of these α-Fe2O3/α-Al2O3 couples was carried out using 300 keV Kr3+ ions at a fluence of 2×1016 ions/cm2. The mixing effect was followed by Rutherford backscattering spectrometry (RBS), conversion electron Mössbauer spectroscopy, and grazing incidence x-ray diffraction method. RBS spectra do not show any evidence of mixing at the interface, whereas the data obtained with the two other techniques display phases like oxygen deficient Fe3O4, Fe3−yAlyO4, and Fe1+xAl2−xO4. For this last phase, x is determined as being equal to about 0.5. It is shown that ion beam mixing is more efficient for the thinner Fe2O3 layer, in accordance with the projected range of the Kr3+ ions. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Thermally induced chemical transformations at the interface between a 100 nm α–Fe2O3 and a polycrystalline α–Al2O3 substrate are studied and compared for the cases of the as-formed and ion bombarded interfaces. The thermal annealings are carried out under vacuum at 450 °C for different time durations and the transformations are examined by conversion electron Mössbauer spectroscopy. It is shown that in the sample prebombarded with 110 keV Ar+ ions, the formation of Fe3−xAlxO4, FeAl2O4, and FeO phases is favored at variance with a nonbombarded sample in which primarily a defective Fe3O4-y phase is produced with some amount of FeO. This difference is explained in terms of the annealing process of the oxygen vacancies produced during Ar implantation near the interfacial region. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effect of an electric field on GMR oxide films was studied in a MOSFET configuration where the gate dielectric was a layer of SrTiO3 epitaxially grown on an underlying layer of the manganate which served as the source/drain. The response of the manganate channel was studied for different gate voltages. The following significant features were observed. The peak resistance temperature shifted to lower temperature for both polarities of the field. The resistance change varied quadratically with the field indicating the dominance of strain or polarization effects. In dynamical studies of the system using the gate voltage as an excitation the system showed anomalous slowing down near the peak of the resistivity. These results are understood on the basis of a stress effect on the film due to electro-elastic effects in the SrTiO3 layer, which introduces a tensile stress in the manganate layer upon the application of a gate voltage. The anomalous slowing down of the system near the ferromagnetic phase transition suggests a strong coupling between the spins, transport and structural distortions in the system. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetoresistivity values of the order of 106% (and in some cases even higher) have been obtained in epitaxial AxB1−xMnO3−y (A=La,Nd; B=Ca,Sr,Ba) thin films grown by pulsed laser deposition. Ferromagnetic resonance experiments suggest a granular-type behavior with conducting ferromagnetic regions (Rcond〈10 mΩ cm) in a less conducting matrix (Rinsulazting(approximately-greater-than)100.Rcond). Ion channeling experiments over a range of temperatures clearly reveal the existence of structural distortion at the peak resistivity temperature TP. Systematic studies of samples prepared under a variety of oxygenation conditions show that the resistivity above TP can be modeled with a single functional form: Rcond≈eΔ/kT, where Δ, the activation energy, is of the order of 50–200 meV. This suggests that these different samples represent the same basic material in a semiconducting matrix, with differing volume fractions of the two components which depends on the processing conditions. These "colossal'' values of MR have been obtained at temperatures lower than room temperature and at fields of the order of a few Teslas, both of which are impediments to the development of viable MR sensor and nonvolatile storage technologies.We are therefore addressing the critical scientific and technological issues through a variety of materials integration approaches. Using structural chemistry and lattice matching as fundamental guiding principles, we are growing epitaxial heterostructure superlattices consisting of the CMR oxides interleaved with magnetic perovskites such as La–Sr–Co–O (metallic ferromagnet), rare earth–Fe–O (ferromagnetic insulator). We are also exploring the possibility of using the semiconducting properties of these materials in an all-perovskite field effect transistor device. In this presentation, we will describe our progress to date on these studies to enhance the field and temperature dependence of the MR properties and explore new device architectures that utilize the inherently novel properties of these materials. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 5647-5649 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Iron oxide and ferrite films were prepared by pulsed ruby laser evaporation from the respective bulk materials on alumina substrates. The variation in the film properties as a function of the substrate temperature and oxygen partial pressure during deposition was studied. Conversion electron Mössbauser spectroscopic analysis showed that the stoichiometry and microstructure of such films depend on these deposition conditions, especially the oxygen partial pressure in the system. Typically it was observed that when laser deposition is performed by vaporizing α-Fe2O3 in the oxygen partial pressure of 10−4 Torr, Fe3O4 thin films were formed while deposition at a background pressure of 10−6 Torr led to formation of FeO films. Similar experiments were also performed on zinc ferrite and it was observed that the nanosecond pulsed evaporation process transports the stoichiometry of metal constituents from the bulk to the film with a small degree of zinc enrichment. In addition to Mössbauer spectroscopy, other techniques such as scanning electron microscopy and x-ray diffraction were also used to characterize the laser-deposited films.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 59 (1986), S. 388-394 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Ion beam induced atomic mixing at Fe-Mo interface has been studied by using the technique of conversion electron Mössbauer spectroscopy (CEMS). Use has been made of a thin (∼50 A(ring)) layer of Fe57 isotope (enriched to 95.4%) at the interface to obtain the Mössbauer information selectively from this region. A noninterface sensitive measurement has also been performed to reveal the magnetic hyperfine interactions in the entire region of the iron overlayer. It is shown that a deposition induced reaction between the molybdenum substrate (having a thin coating of native oxide) and the Fe57 layer renders a graded nature to the interface, which is transformed upon ion bombardment (100-keV Kr+, dose ∼1016 ions/cm2) into a disordered alloy. The dominant nonmagnetic component corresponding to the interface of the ion beam mixed sample happens to be a quadrupole doublet, which represents the presence of Fe57 atoms in Fe2+ charge state. The appearance of this contribution is attributed to formation of an oxygen coordinated ternary compound in the interface layer during ion bombardment. On the basis of the comparison of the results of the interface-sensitive and non-interface-sensitive studies it is established that the inclusion of oxygen in the ion mixed sample is mainly confined to the near interface region and that the region of the overlayer contains a metastable alloy of the binary Fe-Mo system. The influence of thermal annealing at various temperatures between 200 °C and 500 °C on the ion beam mixed state has also been studied by monitoring the changes in the hyperfine interaction parameters. It is shown that the oxygen-incorporated regions of the disordered alloy retain the nonmagnetic Fe2+ charge state subsequent to annealing at 500 °C, while other regions lead to precipitation of α-Fe and Fe2Mo phases.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 1367-1369 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Zinc ferrite (ZnxFe3−xO4) films have been deposited on a single-crystal Al2O3 substrate by pulsed ruby laser-induced vaporization from a sintered ZnFe2O4 pellet. The film structure has been determined by small-angle x-ray diffraction measurements, and the film morphology by scanning electron microscopy. The microstructural features have been brought out by conversion electron Mössbauer spectroscopy. The dependence of the film properties on the oxygen partial pressure and substrate temperature during deposition is studied to explore optimized conditions for deposition of near single-phase stoichiometric films.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 677-682 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Ion-beam mixing at an Fe:metallic glass (Fe67Co18B14Si1) interface is studied by employing the technique of conversion electron Mössbauer spectroscopy (CEMS). A 230-A(ring)-thick overlayer of iron (enriched to 33% in the concentration of 57Fe Mössbauer isotope) was deposited on the shiny surface of metallic glass and such composites were bombarded with 100-keV Kr+ ions at dose values in the range between 1×1015 and 2×1016 ions/cm2. The transformations in the local atomic arrangements across the interface were investigated by monitoring the changes in the hyperfine-interaction parameters. It is shown that mixing leads to significant changes in the composition, in the vicinity of the interface as a function of the ion dose. At low dose (1×1015 ions/cm2) the local atomic coordination is found to be rich in the transition-metal concentration, while at a higher dose (2×1016 ions/cm2) it is observed to be rich in the boron concentration. Interestingly, at an intermediate dose 1×1016 ions/cm2 the composite near the interface region partially crystallizes and this structural state is found to revert back to the amorphous state upon thermal annealing at 300 °C. The observations made on the basis of CEMS are well supported by x-ray diffraction measurements.
    Type of Medium: Electronic Resource
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