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  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 23 (1996), S. 459-464 
    ISSN: 1432-0789
    Keywords: Key words Crop residues ; Hordeum vulgare L. ; Pisum sativum L. ; Mineralization-immobilization ; turnover of N ; Symbiotic N2 fixation-labelled N
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Nitrogen acquisition by field pea (Pisum sativum L.) and spring barley (Hordeum vulgare L.) grown on a sandy loam soil and availability of N in three subsequent sequences of a cropping system were studied in an outdoor pot experiment. The effect of crop residues on the N availability was evaluated using 15N-labelled residues. Field pea fixed 75% of its N requirement and the N2 fixation almost balanced the N removed with the seeds. The barley crop recovered 80% of the 15N-labelled fertilizer N supplied and the N in the barley grain corresponded to 80% of the fertilizer N taken up by the crop. The uptake of soil-derived N by a test crop (N catch crop) of white mustard (Sinapis alba L.) grown in the autumn was higher after pea than after barley. The N uptake in the test crop was reduced by 27% and 34% after pea and barley residue incorporation, respectively, probably due to N immobilization. The dry matter production and total N uptake of a spring barley crop following pea or barley, with a period of unplanted soil in the autumn/winter, were significantly higher after pea than after barley. The barley crop following pea and barley recovered 11% of the pea and 8% of the barley residue N. The pea and barley residue N recovered constituted only 2.5% and 〈1%, respectively, of total N in the N-fertilized barley. The total N uptake in a test crop of mustard grown in the second autumn following pea and barley cultivation was not significantly influenced by pre-precrop and residue treatment. In the short term, the incorporation of crop residues was not important in terms of contributing N to the subsequent crop compared to soil and fertilizer N sources, but residues improved the conservation of soil N in the autumn. In the long-term, crop residues are an important factor in maintaining soil fertility and supplying plant-available N via mineralization.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 3958-3969 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report the polarized emission spectra from photodissociating nitromethane excited at 200 and 218 nm. At both excitation wavelengths, the emission spectra show a strong progression in the NO2 symmetric stretch; at 200 nm a weak progression in the NO2 symmetric stretch in combination with one quantum in the C–N stretch also contributes to the spectra. We measure the angular distribution of emitted photons in the strong emission features from the relative intensity ratio between photons detected perpendicular to versus along the direction of the electric vector of the excitation laser. We find the anisotropy is substantially reduced from the 2:1 ratio expected for the pure CH3NO2 X(1A1)→1B2(ππ*)→X(1A1) transition with no rotation of the molecular frame. The intensity ratios for the features in the NO2 symmetric stretching progression lie near 1.5 to 1.6 for 200 nm excitation and 1.7 for 218 nm excitation. The analysis of the photon angular distribution measurements and consideration of the absorption spectrum indicate that the timescale of the dissociation is too fast for molecular rotation to contribute significantly to the observed reduction in anisotropy. The detailed analysis of our results in conjunction with electron correlation arguments and previous work on the absorption spectroscopy and final products' velocities results in a model which includes two dissociation pathways for nitromethane, an electronic predissociation pathway and a vibrational predissociation pathway along the 1B2(ππ*) surface. Our analysis suggests a reassignment of the minor dissociation channel, first evidenced in photofragment velocity analysis experiments which detected a pathway producing slow CH3 fragments, to the near threshold dissociation channel CH3 + NO2(2 2B2).
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 113 (2000), S. 6882-6887 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Using supersonic molecular beam techniques we have investigated the dissociative adsorption of NH3 on a Ru(0001) surface. At high incident energies, the dissociation increases substantially due to a direct breaking of the N–H bond on impact with the surface. For low incident translational energies, the dissociation depends on surface temperature Ts in an unusual manner, peaking sharply around 400 K. Increasing the surface defect density by low-fluence Ar+ sputtering strongly enhances the dissociation probability while preserving the overall Ts-dependence. We interpret the low incident energy behavior as due to a mechanism in which a molecular precursor must undergo diffusion to defects before dissociating. At the lowest surface temperatures, dissociation is limited by the diffusion of the reaction products away from the defects in order to reactivate them. A kinetic model based on this mechanism is developed which is in good agreement with all experimental observations. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 115 (2001), S. 9028-9035 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: New molecular beam experiments on the dissociation probability S0 for N2 on Ru(0001) are presented. These are in general agreement with prior measurements and exhibit very unusual behavior; a very slow increase of S0 with incident kinetic energy E and the fact that S0 is still only ∼10−3 at incident energies considerably above the barrier. A simple dynamical model is developed to describe this unusual sticking behavior. The key aspect is that there is considerable energy loss Δ from E upon initial impact with the surface (principally to the lattice) and only E−Δ is then available to surmount the activation barrier in the exit channel. Using experimentally measured values of Δ from scattering experiments gives good qualitative agreement of this model with the measured S0. One implication of the strong energy loss is that there is an apparent violation of detailed balance when comparing only the reactive fluxes of activated adsorption and associative desorption. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 5919-5931 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The photochemistry of methyl iodide adsorbed on Cu(110) surfaces has been studied using time-of-flight mass spectrometry, temperature programmed desorption, and retarding potential spectroscopy. The λ=337 nm photodissociation of CH3I adsorbed on clean and iodided Cu(110) is found to have an increased cross section (by ∼2 orders of magnitude) and altered dynamics from that of the gas phase at the same wavelength. On the clean Cu(110) surface both enhanced neutral photodissociation and charge-transfer photodissociation processes are observed, the latter being ascribed to hot photoelectrons generated in the substrate. On the Cu(110)–I surface, only enhanced neutral photodissociation is observed and the CH3I molecules are found to be orientationally ordered with a 20° tilt in the [11¯0] azimuth. Further evidence of altered neutral photodissociation dynamics is found in the observed I/I* branching ratio. In contrast to earlier studies of adsorbed CH3I, the branching ratio is found to favor the higher energy I* dissociation pathway as compared to the gas phase. The altered neutral photodissociation dynamics are ascribed to changes in the CH3I excited state potential energy surfaces, caused by interactions with the copper–iodine interface. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 87 (1960), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochemical and Biophysical Research Communications 99 (1981), S. 1303-1310 
    ISSN: 0006-291X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 18
    ISSN: 0550-3213
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 19
    ISSN: 0550-3213
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 20
    ISSN: 0550-3213
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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