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  • 11
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 87 (1987), S. 742-749 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Periodic modulations of oxygen pressure or temperature were applied in the catalytic oxidation of CO on a Pt(100) surface under isothermal, low pressure conditions. Transitions from aperiodic autonomous oscillations to regular phase-locked behavior could be observed. Computer simulations using a stochastic cellular automaton model yielded qualitatively similar results. The spatial distribution in both experiment and simulation varies essentially in phase over the whole surface area under the influence of the periodic perturbation, while wave propagation in the autonomous system causes more irregular overall behavior.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 5328-5336 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The previously observed phenomena of temporal and spatial self-organization during the catalytic oxidation of CO on a Pt(100) surface were computer simulated by use of the cellular automaton technique. The underlying model is footed on the knowledge about the individual reaction steps (adsorption, desorption, surface structural transformation, etc.), which in turn formed the basis of a previous theoretical treatment in terms of the formulation and solution of a set of coupled differential equations. The present result nicely show the formation and propagation of two-dimensional patterns, and they reproduce qualitatively well all the experimental observations. The development of macroscopic patterns even with an a priori perfectly homogeneous surface is a particularly interesting effect.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 510-521 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The rate of catalytic CO oxidation on Pt(100) and (110) surfaces at low pressures (≤10−4 Torr) and under isothermal conditions may exhibit sustained temporal oscillations which are coupled with periodic transformations of the surface structures between reconstructed and nonreconstructed phases, the latter exhibiting higher oxygen sticking coefficients and hence higher reactivity. With Pt(100) the two surface phases exhibit a much larger difference in reactivity (=oxygen sticking coefficient) than with Pt(110), which effect accounts for the qualitative differences in the oscillatory behavior: if two of the control parameters (say pO2, T) are kept fixed, the third (pCO) may be varied with Pt(100) over a fairly wide range without leaving the oscillatory region. Minor (〈1%) fluctuations of the partial pressures associated with the varying reaction rate are hence without any noticeable effect. Coupling between surface reaction and diffusion causes wave propagation of the surface phase transformations and therefore spatial self-organization, as demonstrated by scanning LEED experiments. With Pt(110), on the other hand, the oscillatory region is very narrow. In this case mass transport through the gas phase as caused by the small pressure variations associated with the reaction lead to synchronization between different parts of the surface. Computer simulations with the cellular automaton technique confirm qualitatively the experimental findings and support the conclusions reached.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 42 (1977), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bovine muscle samples were fractionated and assayed to assess the effects of high postmortem temperatures on lysosomal enzymes and muscle fragmentation values. Samples of the longissimus dorsi muscle were excised from both sides of six animals. One muscle was held at 37°C (HT) and the other was maintained at 2°C as control (C). The pH of the muscles was determined at 1, 4, and 12 hr postmortem. After 12 hr the muscles were homogenized and centrifuged to separate sedimen-table and unsedimentable fractions which were assayed for β-glucuronidase and cathepsin C activities. A fragmentation value was also determined for each sample. The pH of the HT samples dropped more rapidly and was significantly lower at both 4 and 12 hr. No detectable difference in total β-glucuronidase activity was observed between HT and C samples but the distribution was markedly altered as shown by significant differences in the percent of total activity that was unsedimentable (HT 〉 C, P 〈 0.025) and specific activities of the sedimen-table (HT 〉 C, P 〈 0.025) and unsedimentable (HT 〉 C, P 〈 0.025) fractions. For cathepsin C there was a significant drop in total enzyme activity (HT 〉 C, P 〈 0.005) resulting from an apparent degradation of the unsedimentable enzyme which had been released by the HT treatment. The fragmentation values were significantly different showing that the HT samples had probably undergone limited proteolysis resulting in a reduction of muscle fragment size after homogenization. These results add support for the role of lysosomal enzymes in postmortem tenderization.
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of management studies 22 (1985), S. 0 
    ISSN: 1467-6486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 409 (2001), S. 785-790 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Nuclei undergoing fission can be described by a multi-dimensional potential-energy surface that guides the nuclear shape evolution—from the ground state, through intermediate saddle points and finally to the configurations of separated fission fragments. Until now, calculations have lacked ...
    Type of Medium: Electronic Resource
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  • 17
    ISSN: 1365-2559
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Four monoclonal antibodies against antigens expressed differentially by the normal thymus epithelium, which define the cortical, medullary and subcapsular compartments, were used for immunohistological characterization of the epithelial cells in 14 thymomas. Furthermore, thymoma-associated lymphocytes were studied with monoclonal antibodies directed against T-lymphocyte differentiation antigens (CD1a, CD3, T-cell antigen receptor). Only four of the 14 thymomas could be classified into either medullary or cortical type thymoma based on the immunophenotype of epithelial cells. Ten cases escaped immunophenotypical classification due to co-expression of medullary and cortical antigens by the tumour cells. This aberration from the normal phenotype might indicate the failure of differentiation of such tumours. The immunophenotype of the associated lymphocytes, on the other hand, made it possible to classify the tumours as cortical (5 cases), mixed (2) and medullary (3) thymomas. Four thymomas escaped this classification scheme due to the absence of lymphocytes (2) or to a hybrid immunophenotype (2). Nevertheless, thymocytes of cortical type clearly predominated and were seen in all thymomas with associated lymphocytes. This feature may constitute a good diagnostic tool in differential diagnosis since, in 28 mediastinal or extramediastinal metastasis of tumours not derived from thymic epithelium and associated with various numbers of lymphocytes, none of them were found to contain CD1a positive lymphocytes.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Scandinavian journal of immunology 32 (1990), S. 0 
    ISSN: 1365-3083
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Immunoprecipitation of radioiodinated hairy cell leukaemia (HCL) cell lysates with monoclonal antibody (MoAb) HML-1. originally reported to recognize intraepithelial T cells, and with MoAb B-ly7, originally reported to react with HCL. led to identical biochemical characteristics. In SDS PAGE under reducing conditions, a major band of 143 kDa. a broad band ranging from 112 to 122 kDa. and two additional faint bands of 175 and 100 kDa could be determined. Deglycosylation of N-linked sugar moieties by treatment of immunoprecipitates with endoglycosidases indicated that the two main protein cores of the antigen are predominantly if not exclusively glycosylated by complex and hybrid types of oligosaccharide chains. Competitive binding inhibition demonstrated that both MoAb are directed against different epitopes. Immunohistochemically. the staining patterns obtained with both MoAb in normal tissues, in T-and B-cell lymphomas, and in HCL were identical except for a single case of HCL which was HML-1−/B-ly-7+, We conclude that MoAb HML-1 and B-1y7 recognize the same antigen.
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 39 (1974), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 20
    Electronic Resource
    Electronic Resource
    Springer
    Mineralogy and petrology 45 (1992), S. 231-246 
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung Normierte Lanthaniden-Verteilungsmuster wässeriger Lösungen und deren Präzipitate enthalten Informationen über die verschiedenen physiko-chemischen Bedingungen, denen die Fluidphase während der Mobilisierung der Lanthaniden, der Migration und der Minerogenese ausgesetzt war. Positive Eu- und Yb-Anomalien weisen auf eine Mobilisierung der Lanthaniden bei erhöhten Temperaturen durch eine F−-, OH−-und CO3 2−-arme Lösung. Die positiven Anomalien der Lösung werden jedoch nur dann auf ein Mineral übertragen, wenn dessen Präzipitation in einem niedrigen Temperaturbereich erfolgt. Negative Ce-Anomalien sind Indikatoren oxischer Bedingungen, weshalb ihre Entwicklung im Verlauf einer Siderit-Präzipitation weitgehend ausgeschlossen werden kann. Die Fraktionierung von leichten und schweren Lanthaniden wird von der chemischen Zusammensetzung der Fluidphase und der “mineralogischen Kontrolle” bestimmt. Die Lanthaniden-Verteilungsmuster von Ca-Mineralen erlauben es, deren Mutter-Lösungen in “normal” (Ca/Liganil ≫1) und “Liganden-reich” (Ca/Liganil ≈ 1) zu untergliedern, wobei letztere für Remobilisierungsprozesse typisch sind. Verschiedene minerogenetische Modelle für Spatmagnesite aus der Lagerstätte Radenthein und Siderite aus der Lagerstätte Hüttenberg, beide Kärnten, Österreich, werden vor dem Hintergrund deren Lanthaniden-Verteilung diskutiert. Es wird gezeigt, daß sowohl für die Radenthein-Magnesite als auch für die Hüttenberg-Siderite nur ein nicht-sedimentäres, nicht-metamorphes, wohl aber metamorphogen-metasomatisches minerogenetisches Modell mit der Lanthaniden-Verteilung kompatibel ist.
    Notes: Summary Normalized REE patterns of aqueous solutions and their precipitates bear information on the physico-chemical environments a fluid experienced during REE mobilization, fluid migration and minerogenesis. Positive Eu and Yb anomalies indicate REE mobilization by a F−-, OH−- and CO3 2−-poor fluid in a high-temperature regime, but are only retained by a precipitating mineral if precipitation occurs in a low-temperature environment. Negative Ce anomalies are typical of oxidizing conditions and are unlikely to develop during siderite precipitation. LREE/HREE fractionation is controlled by fluid composition and “mineralogical control”. REE patterns of Ca minerals allow to class the reacting fluids in “normal” (Ca/ligand ≫ 1) and “ligand-enriched” (Ca/ligand ≈ 1), the latter being characteristic for remobilization processes. The Radenthein magnesite and Hüttenberg siderite deposits, both Carinthia, Austria, are discussed and shown to be of non-sedimentary, non-metamorphic, but metamorphogenic metasomatic origin.
    Type of Medium: Electronic Resource
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