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  • 1
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 10607-10615 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A theoretical study of a variety of tricyclic polymers [–(C8H2X2Y)n–] with two different types of bridging groups was performed, X(Double Bond)S and Y(Double Bond)CH2, SiH2, C(Double Bond)O, C(Double Bond)S, or C(Double Bond)CH2 for the fused bithiophene system and vice versa for the thieno-bicyclic system. These two types of the bridging groups are different from each other in that S favors the aromatic form of a cyclic polymer and the other groups prefer the quinonoid form. Geometrical structures of the polymers were obtained from semiempirical self-consistent-field (SCF) band calculations and the electronic properties from the modified extended Hückel band calculations. It is found that the ground-state geometrical structures of the tricyclic polymers are determined by the bridging groups in the outer rings. That is, the fused bithiophene system is aromatic in the ground state and the thieno-bicyclic system is quinonoid. The ground-state band gaps (which correspond to the absorption peaks of π–π* band transition) of the polymers were estimated to be in the range of 0.7–2.0 eV. The band gaps were analyzed in terms of the bond-length alternation along the conjugated carbon backbone, the C1–C4 interactions, and the electronic effect of the bridging groups. We also investigated the geometrical and electronic structures of polydicyanomethylene-cyclopenta-dicyclopentadiene (PDICNCY). Unlike the theoretical predictions of Toussaint and Bredas [Synth. Met. 69, 637 (1995)], PDICNCY in the ground state was estimated to be of the quinonoid form and to possess a large band gap (2.55 eV) comparable with the gap of polythiophene. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 25 (1986), S. 6372-6378 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 5089-5092 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electronic property variations of a two-dimensional electron gas (2DEG) in modulation-doped step quantum wells due to an embedded potential barrier were studied by performing Shubnikov–de Haas (SdH), Van der Pauw–Hall-effect, and cyclotron resonance measurements on two kinds of InxGa1−xAs/InyAl1−yAs step quantum wells which were one without and the other with an embedded barrier. The fast Fourier transformation results for the SdH data at 1.5 K indicated the electron occupation of two subbands in both step quantum wells. The total electron carrier density and the mobility of the 2DEG in the step quantum well with an embedded barrier were smaller than those in the quantum well without an embedded barrier. The electron effective masses were determined from the slopes of the main peak absorption energies as functions of the magnetic field, and satisfied qualitatively the nonparabolicity effects in both quantum wells. The electronic subband energies, the wave functions, and the Fermi energies were calculated by using a self-consistent method taking into account exchange-correlation effects together with strain and nonparabolicity effects. These present results indicate that the electronic parameters in modulation-doped InxGa1−xAs/InyAl1−yAs step quantum wells are significantly affected by an embedded barrier. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 175-180 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: SnO2 thin films were grown on p-InSb (111) substrates by radio-frequency magnetron sputtering at low temperature. Atomic force microscopy images showed that the root mean square of the average surface roughness of the SnO2 films grown on the InSb (111) substrates with an Ar/O2 flow rate of 0.667 and at a temperature of 200 °C had a minimum value of 2.71 nm, and x-ray diffraction and transmission electron microscopy (TEM) measurements showed that these SnO2 thin films were polycrystalline. Auger electron spectroscopy and bright-field TEM measurements showed that the SnO2/p-InSb(111) heterointerface was relatively abrupt. High-resolution TEM measurements revealed that the SnO2 films were nanocrystalline and that the grain sizes of the nanocystalline films were below 6.8 nm. The capacitance–voltage measurements at room temperature showed that the type and the carrier concentration of the nominally undoped SnO2 film were n type and approximately 1.67×1016 cm−3, respectively, and the current–voltage curve indicated that the Au/n-SnO2/p-InSb diode showed tunneling breakdown. Photoluminescence spectra showed that peaks corresponding to the donor acceptor pair transitions were dominant and that the peak positions did not change significantly as a function of the measured temperature. These results indicate that the SnO2 nanocrystalline thin films grown on p-InSb (111) substrates at low temperature hold promise for new kinds of potential optoelectronic devices based on InSb substrates, such as superior gas sensors and high-efficiency solar cells. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 7631-7633 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The electrical resistivity ρ, Hall coefficient RH, thermoelectric power S, and thermal conductivity κ have been measured on an antiferromagnet CeBiPt (TN=1 K) and the nonmagnetic analogue LaBiPt, which crystallize in the cubic MgAgAs-type structure. The large values |RH|∼1 cm3/C and ρ∼1.2 mΩ cm at 300 K indicate that both compounds are low-carrier concentration semimetals. The strong temperature dependences of ρ, S, and RH for CeBiPt contrast with the weak temperature dependences for LaBiPt. For CeBiPt, S(T) has a positive maximum of 120 μV/K at 100 K. However, the sign of RH(T) changes from positive to negative with increasing temperature at 170 K, above which S(T) of CeBiPt becomes smaller than LaBiPt. These observations suggest strong dependence of mobility for hole and electron carriers in CeBiPt. In this system, κ(T) is dominated by the phonon contribution, which is consistent with a small carrier concentration. Furthermore, the combination of S, ρ, and κ allows us to estimate the figure of merit for thermoelectric application, Z=1.7×10−4 K−1 at 75 K for CeBiPt. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 7186-7188 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: UIrGe crystallizes in the orthorhombic TiNiSi structure and exhibits a large magnetic anisotropy. Here, we present the results of magnetoresistance and specific-heat studies of single-crystalline UIrGe in magnetic fields up to 18 T applied along the principal axes. The phase boundaries of the zero-field antiferromagnetic phase (TN(approximate)14.1 K) are established, and we find evidence of a field-induced phase above 12.5 T at 2.1 K and 14 T at 2.5 K for magnetic fields applied along the b and c axis, respectively. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 2649-2652 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The Shubnikov–de Haas (S–dH) measurements at 1.5 K clearly demonstrated the existence of a two-dimensional electron gas (2DEG) in the modulation-doped Al0.25Ga0.75As/InyGa1−yAs/GaAs single and step quantum wells, and the fast Fourier transformation results for the S–dH data clearly indicated the electron occupation of one subband in the asymmetric single and step quantum wells. While the electron carrier density of the 2DEG in the step quantum well was larger than that in the single quantum well due to the larger conduction-band discontinuities, the mobility of the 2DEG in the step quantum well was smaller than that in the single quantum well because of the interface scattering resulting from the embedded step well. The electron effective mass in the step quantum well was smaller than that in the single quantum well, which was consistent with a smaller mass of the embedded deep step layer. The electronic subband energy, the energy wave function, and the Fermi energy in the InyGa1−yAs step quantum wells were calculated by using a self-consistent method taking into account exchange-correlation effects together with strain and nonparabolicity effects. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 1049-1051 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The growth of high quality CdTe epitaxial films on p-InSb(111) by a simple method of temperature gradient vapor transport deposition was carried out to investigate the possibility of the existence of a two-dimensional electron gas with high mobility at CdTe/InSb heterointerfaces. From the x-ray diffraction analysis, the grown layer was found to be a CdTe epitaxial film. Photoluminescence measurements at 15 K showed that a CdTe film grown on InSb(111) in the temperature range between 180 and 280 °C appeared to have an optimum crystal perfection at a substrate temperature of about 245 °C. These results also indicated that the CdTe films grown above 245 °C contained a significant problem due to interdiffusion from the InSb substrates during the growth.
    Type of Medium: Electronic Resource
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