ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
From GILBERT & GARETT'S (2) data on the solubility of α-Be(OH)2 in diluted acids, the following equilibrium constants have been calculated (25°, ionic strength zero): \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{*{20}c} {\alpha - {\rm Be(OH)}_{\rm 2} + 2{\rm H}^{\rm + } = {\rm Be}^{{\rm 2 + }} + 2{\rm H}_{\rm 2} {\rm O; log }*\,Kso{\rm = - 6,86} \pm {\rm 0,05}} \\ {3\,\alpha - {\rm Be}({\rm OH})_2 + 3{\rm H}^ + = {\rm Be}_3 ({\rm OH})_3^{3 + } + 3{\rm H}_{\rm 2} {\rm O};\,\,\log \,*\,Ks33 = - 11,67 \pm 0,05} \\ {3\,{\rm Be}^{{\rm 2 + }} + 3{\rm H}_{\rm 2} {\rm O}\,{\rm = }\,{\rm Be}_{\rm 3} ({\rm OH})_3^{3 + } + 3{\rm H;}\,{\rm log}\,{\rm *}\beta {\rm 33}\,{\rm = }\,{\rm - 8,9} \pm {\rm 0,1}} \\ \end{array} $$\end{document}.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19600430740
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