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  • 1985-1989  (691)
  • 1970-1974
  • 1915-1919
  • 1988  (691)
  • Chemical Engineering  (691)
  • 101
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 239-252 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The equations governing consolidation in a continuous-flow gravity thickener are developed based on the assumption that a flocculated suspension possesses a compressive yield stress Py(φ) that is a function of local volume fraction only. These equations are used to model the steady state operation of a thickener. The bed height required to achieve a given underflow concentration is found to be a relatively sensitive function of the details of the Py(φ) function, particle flux through the thickener, and variations in the cross-sectional area of the thickener. The limiting values of the underflow concentration φu for a given flux or the limiting values of flux for a desired φu are studied and shown to exist only for cylindrical and converging thickeners.
    Additional Material: 8 Ill.
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  • 102
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 283-292 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The hydrodynamics of a pilot plant multistage mixer column extractor was studied for the toluene/water physically equilibrated system. The effects of rotational speed, and continuous and dispersed phase flow rates were investigated under a variety of operating conditions. Dispersed phase axial holdup profiles, determined by a noninvasive ultrasonic method, showed a strong nonuniformity. Depending on the operating conditons, holdup profiles can change from a concave shape to a sigmoidal form with a maximum in the bottom of the column. Sauter mean diameter and drop size distribution profiles are strongly affected by rotational speed. Significant, but weaker, are the effects of continuous and dispersed phase flow rates. Continuous monitoring of the holdup profile in the proximity of flooding leads to the formulation of proper criteria for the prediction of flooding. These criteria are appropriate for models allowing for axial variation of the holdup along the contactor.
    Additional Material: 11 Ill.
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  • 103
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 253-262 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Aerosol deposition in model filters composed of layers of parallel fibers with the orientation of the fiber of each layer kept arbitrary was simulated stochastically. Particle positions at the inlet of the filter were assumed to be randomly distributed over the inlet plane with the trajectory assumed to be rectilinear because of the particles' high inertia. In the simulation, the track of each particle through the filter was monitored and the possible bounce-off from collision surfaces was allowed for. Deposition behavior and the structure of deposits were studied with various aerosol flow conditions and filter characteristics.
    Additional Material: 19 Ill.
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  • 104
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 263-271 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two models are presented that can simulate two peaks in a temperature-programmed desorption (TPD) spectrum from a high surface area catalyst at atmospheric pressure: a multisite model and a subsurface diffusion model. The multisite model assumes that the two peaks arise from two distinct adsorption sites on the catalyst surface with different activation energies for desorption. The subsurface diffusion model assumes that the high-temperature peak is produced by adsorbate that diffuses into the subsurface region of the catalyst during heating, and then back to the surface when it becomes depleted by the desorption process. It is shown that one can distinguish between the two models experimentally by measuring the effect of carrier gas flow rate and heating rate on the TPD spectrum.
    Additional Material: 10 Ill.
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  • 105
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 272-282 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The transient behavior of polymer properties following a step change in feed conditions during copolymerization in a continuous-flow stirred-tank reactor has been investigated by both modeling and experiment. For kinetics appropriate to Ziegler catalyzed olefin polymerization, the dynamic response of polymer molecular weight and composition is predicted to be relatively slow; four to six reactor turnovers could be required to reach steady state. In addition, response time depends on the direction and magnitude of change and is generally shorter when a property value is decreased. These model predictions were confirmed by measurement of the transient response of copolymer composition and molecular weight for ethylene-propylene-ethylidene norbornene terpolymerization.The model equations also were used to simulate reactor startups, and it was found that steady state following a startup can be reached in about three reactor turnovers. The initial absence of polymer in the reactor causes the dynamic response to be faster for a startup than for reactor control.
    Additional Material: 14 Ill.
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  • 106
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 353-365 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Spontaneous combustion may occur in a coal stockpile when the heat generated within the pile cannot be dissipated at near ambient temperature. Under practical conditions, natural convection enhances the rate of heat removal from the bed and shifts the ignition to lower particle sizes (higher reactivities). Analysis of three limiting cases of a one-dimensional model yields criteria predicting the conditions under which ignition occurs as well as those for which a low-temperature (extinguished) state exists for all particle sizes. A simple asymptotic relation predicts the ignition point at large Rayleigh numbers.
    Additional Material: 14 Ill.
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  • 107
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 366-382 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A three-dimensional radiation model coupled with two-dimensional mass balances for the intervening chemical species is solved for the photochemical chlorination of ethane. The analysis was carried out using the full mechanistic kinetic sequence and employing polychromatic radiation for a process conducted in a tubular reactor placed inside an elliptical reflector.Theoretical predictions were compared with bench-scale experiments and showed excellent agreement. Using the validated model, computational experiments were conducted to explore the influence of reactor design and operational parameters upon the degree of chlorination. Dichlorination reactions were also added to the kinetic model to analyze reactor behavior from the viewpoint of selectivity. The a priori design method described can be applied from first principles and requires no experimentally adjustable parameters.
    Additional Material: 15 Ill.
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  • 108
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 383-388 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bifurcation problems with slowly varying control parameters are of interest in several research areas, including catalyst deactivation, combustion, and lasers and other nonlinear optical devices. Significant theoretical work has been devoted to the study of these dynamic phenomena, but very little directly relevant experimental information is currently available. Results are presented here from an experimental study of the dynamic behavior of a catalytic reaction system due to a deliberately slowly varied control parameter. Attention is focused on the dynamics due to slow passage through simple limit and Hopf points.
    Additional Material: 10 Ill.
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  • 109
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 435-446 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A detailed mathematical model is used to predict local and effluent properties within an axisymmetric, entrained-flow gasifier. Laboratory experiments were conducted to provide local properties for four coal types from a gasifier operating at near-atmospheric pressure. Effects of selected model parameters and test variables were examined and compared with measurements in most cases. The comparison of predictions and measurements provides the first evaluation of capabilities and limitations of a comprehensive model for entrained-flow gasifiers.
    Additional Material: 20 Ill.
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  • 110
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 456-464 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When thin films of liquid are produced by roll coaters it is commonly observed that the liquid film is not uniform but shows either regular or irregular patterns resulting from hydrodynamic origins. The appearance of the liquid film has been considered to be governed by the flow geometry and dynamics in a nip region between two adjacent solid planes.Experimental work was done to observe the flow geometries in the nip region and patterns of liquid film by using a roll-stationary, transparent flat plate system. Two fundamental mechanisms for rib disappearance in practical high-speed coatings were recognized. It was also found that the constant rib interval for infinite capillary number depends not only upon the minimum gap size but also upon the physical properties of the liquid. Experimental data are presented in dimensionless form for meniscus position, rib interval, constant rib interval, and for the critical or transient conditions of rib formation, rib disappearance, unstead ribbing, and centrifugal splash.Comparison of present results for the speed ratio U2/U1 = 0 with previous results for U2/U1 = 1 shows the significance of the speed ratio to the meniscus position and the rib interval.
    Additional Material: 15 Ill.
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  • 111
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 493-498 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analytical, theoretical investigation of mass transfer in a Newtonian, isothermal falling film displaying periodic, finite-amplitude waves is presented. The solution derived provides full information on the mass transfer rate as expressed exclusively in terms of physical properties of the liquid and the completely determined flow.
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  • 112
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 499-501 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 113
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 502-505 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 114
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 506-509 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 115
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 514-518 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 116
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 510-513 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 117
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 519-523 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 118
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 524-524 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 119
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 524-525 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 120
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 525-525 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 121
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 551-557 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Design equations are derived for calculating the properties of an aerosol generated in a tubular flow reactor operated at a constant rate of formation of condensable monomer. These equations lead to a set of characteristic dimensionless groups. Independently, it is shown that nearly monodisperse aerosols can be generated by: (1) separating particle formation and growth processes, (2) operating with a narrow residence time distribution, and (3) minimizing monomer concentration gradients. These criteria can be used in solving the design equations over ranges of the dimensionless groups suitable for monodisperse aerosol production. In general, high rates of monomer formation are desirable, subject to the desired particle size and concentration, but an upper bound may result from coagulation.
    Additional Material: 3 Ill.
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  • 122
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 567-573 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study was carried out of the momentum and the heat transfer to fine alumina particles injected into a DC plasma jet. Measurements are reported of particle number flux distribution, particle velocity, and inflight particle surface temperature under different operating conditions. The results show that the particle trajectories and associated particle flux distribution depends to a large extent on the particle injection velocity. The maximum particle velocity and surface temperature are noted, however, to remain close to the centerline of the jet, independent of the particle injection conditions. The maximum surface temperature reached by the particles increases with increasing plasma power and the use of an Ar/H2 plasma gas (17 vol. % H2) compared to that for a pure argon plasma.The particle velocity data are in good agreement with the predictions of a two-dimensional mathermatical model used for the calculation of the particle trajectories and temperature history. The model predictions, however, agreed only in trend with the measured particle surface temperatures. Deviations between the two could still be observed at large distances from the point of injection of the powder. The computed particle number flux distributions were narrower than the measured profiles, which can be attributed to the fact that the model did not include, at this stage, turbulent particle diffusion effects.
    Additional Material: 17 Ill.
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  • 123
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 574-582 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fossil fuel process oils consist of such a large number of components that their only proper description is in terms of continuous distribution functions of a suitable characteristic variable. A methodology is presented to describe the oils in terms of a generalized distribution function. The characteristic variable is determined from measurements of the equilibrium ratios of two test oils, at ambient pressure. Application of the proposed methodology to a sequence of operations shows that, unlike the pseudocomponents technique, the level of accuracy can be maintained.
    Additional Material: 10 Ill.
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  • 124
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 583-601 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: All process designs are subject to uncertainties which make it impossible to state with complete certainty that a design will work. This study presents a measure of design confidence which considers the nature of the uncertainty and the operability of the process as a whole. This measure, called design reliability, quantifies the likelihood that a design will work. Detailed analyses are presented for three special cases: designs subject to random uncertainties, designs subject to fuzzy uncertainties, and designs subject to both random and fuzzy uncertainties. Practical procedures for estimating design reliability in these special cases are also presented.
    Additional Material: 18 Ill.
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  • 125
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 602-609 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Drops are stabilized in agitated liquid-liquid systems by both surface and internal viscous forces. The dispersion of an inviscid liquid into a turbulent continuous phase in static mixers has been studied but the effect of dispersed phase viscosity is not well understood. Systematic experiments have been conducted in a Kenics mixer by photographically examining dilute suspensions of viscous oils in water to determine how viscosity and conditions of agitation affect equilibrium mean drop size and size distribution. A semiempirical theory is developed which correlates the mean size data and collapses to the well-known Weber number result in the inviscid limit. A correlation for drop size distribution in terms of cumulative volume frequency is developed by normalization with the Sauter mean diameter D32. Measurements at the mixer entrance indicate that the method of introduction of the dispersed phase should be considered when evaluating mixer performance.
    Additional Material: 8 Ill.
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  • 126
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 633-644 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Nonlinear inferential control (NLIC) has been developed as a method for improving control of nonlinear systems. The controller is modelbased, and allows for direct use of available measurements. This paper presents the structure of NLIC and the manner in which it is applied to processes when the controlled variables are measured. Also described is the improvement in the process control using NLIC. Two illustrative examples are presented, a laboratory heat exchanger process and a simulated neutralization process. The results indicate that a substantial improvement in control is possible using NLIC.
    Additional Material: 11 Ill.
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  • 127
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 618-625 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study of the efficiencies of two plate distillation columns is reported. One column had three rectangular trays with a flow path length of about 1 m, the other was a modified glass Oldershaw column with one tray of 38 mm dia. Tray efficiencies were measured in both columns and point efficiencies were deduced for the rectangular column.The systems studied were ternary and quaternary mixtures of alcohols and water. The results showed that for thermodynamically nonideal systems significant differences existed among the individual component point efficiencies. In the case of an ideal system the component point efficiencies were effectively equal, but tray efficiencies were different due to differing volatilities and composition profiles across the large trays.This study illustrates the need to allow for the above effects in large-column designs for multicomponent systems. The possibility of using laboratory-scale point efficiencies in these designs is explored.
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  • 128
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 610-617 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental study was made of tracer dispersion in bidisperse sintered glass materials prepared from mixtures of two sizes of beads with mean diameters of 325 and 95 μm. The equivalent dispersion coefficient increases by a factor of 30 when the porosity decreases from 30 to 12%; this variation is similar to that measured in monodisperse samples. The variation of dispersion can be characterized by the ratio R = ℓd/L1 where ℓd is a length scale deduced from the equivalent dispersion coefficient and L1 is obtained from conductivity and permeability measurements. It is shown that the increase of ℓd/L1 correlates with the loss of porosity during the sintering process. Lightly sintered samples with a percentage of small beads around the minimum of porosity display a nearly Gaussian behavior, with a dispersion coefficient close to that obtained in homogeneous equivalent mixtures. This result is in contrast with very large anomalies observed by other authors. These results imply that dispersion in consolidated samples is sensitive to large-scale inhomogeneities of the materials rather than to their detailed structure.
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  • 129
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 669-671 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 130
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    AIChE Journal 34 (1988), S. 672-675 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 131
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    AIChE Journal 34 (1988), S. 658-668 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is presented for the supercritical reaction-extraction of a solid component from a bed of porous particles through which the solvent flows. Accounted for are reaction at an intraparticle position, pore diffusion, interphase mass and heat transfer, and flow in a differential reactor. The behavior of the bed is dynamic since both temperature and concentration of extractable solid vary with time.The model is compared with experimental data for the extraction with toluene of kerogen from a bed of Colorado shale particles. Curves of effluent bitumen concentration vs. time were measured and fitted with predicted curves to evaluate three parameters: preexponential factor and activation energy for the conversion of insoluble kerogen to soluble bitumen, and the diffusivity of toluene at the critical point. The predicted curves agreed well with the experimental results and gave reasonable values for the parameters. Rates of reaction-extraction as well as extraction curves exhibited a sharp dip as the reactor was heated through the critical temperature.
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  • 132
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    AIChE Journal 34 (1988), S. 676-678 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 133
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 645-657 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The behavior of solute partial molar enthalpies in dilute supercritical mixtures gives rise to the well-known phenomenon of retrograde solubility (equilibrium solubility decreasing with increasing temperature at constant pressure). A mechanistic interpretation of this phenomenon in terms of the formation of large clusters of solvent molecules around solute molecules is consistent with experimentally observed retrograde behavior. Cluster formation occurs as a consequence of the unbounded increase in the solvent's compressibility arbitrarily close to the latter's critical point. At infinite dilution, the solute's partial molar volume and enthalpy grow linearly with cluster size. This means that the negative divergence of these quantities is simply a macroscopic manifestation of a “condensation” in which an increasing number of solvent molecules cluster around solute molecules. Arbitrarily close to the solvent's critical point, scaling relationships show that the decay of both solvent-solvent and solute-solvent correlation functions exhibits the same radial dependence. This functionality is thus solute-independent, and is determined exclusively by the proximity to the solvent's critical point. The locus along which thermal effects associated with cluster formation are maximized is arbitrarliy close to the solvent's critical isochore as the latter's critical point is approached.
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  • 134
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    AIChE Journal 34 (1988), S. 679-683 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 135
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    AIChE Journal 34 (1988), S. 684-687 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 136
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    AIChE Journal 34 (1988), S. 688-691 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 137
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    AIChE Journal 34 (1988), S. 692-693 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 138
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    AIChE Journal 34 (1988), S. 1550-1558 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The optimal control policy for the maximization of the secreted heterologous protein in a fed-batch bioreactor was obtained using SEY2102 as a model host yeast and SUC2-s2 as a model secretory protein. A dynamic model for host cell growth, gene expression, and the secretion of expressed polypeptides was formulated. The optimal system trajectory contains multiple singular arcs that are distinct from one another. Optimal control requires transitions between these singular arcs. Optimal transitions between multiple singular arcs with bounded controls are uniquely located in observance with the Minimum Principle of Pontryagin. An iterative numerical search strategy for determining the optimal control showed successful convergence properties.
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  • 139
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    AIChE Journal 34 (1988), S. 1573-1576 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 140
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    AIChE Journal 34 (1988), S. 1577-1580 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 141
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    AIChE Journal 34 (1988), S. 1568-1572 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
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  • 142
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    AIChE Journal 34 (1988) 
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  • 143
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    AIChE Journal 34 (1988), S. 1581-1583 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 144
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    AIChE Journal 34 (1988), S. 814-824 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mixtures of water, oil, and surfactant often form microemulsions where tiny drops of oil (or water) are dispersed in a matrix of water (or oil). A microemulsion is a partially-ordered fluid in which the surfactant molecules exist in an oriented layer at the boundary between the continuous phase and the discontinuous phase. This work proposes a molecular-thermodynamic model that is useful for calculating a variety of phase diagrams observed in microemulsion-forming systems.The model is based on a revised form of Widom's abstract representation of a microemulsion; that representation provides a procedure for calculating essential contributions to the configurational entropy. In Widom's representation, all molecules are difunctional dumbbells such that all the hydrophilic ends are situated together in some lattice sites and all the lipophilic ends are situated together in other sites. A form of Guggenheim's quasichemical theory is used to evaluate the combinatorial contributions that correspond to Widom's picture. Chemical association of surfactant molecules and physical interactions are also taken into account. Minimization of the Gibbs energy yields a distribution function for representing micelle sizes.Calculated ternary phase diagrams are in good agreement with experimental results. Different types of diagrams can be obtained upon changing physically significant model parameters. A study of how these parameters affect phase behavior provides insight on microemulsion stability.
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  • 145
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    AIChE Journal 34 (1988), S. 840-848 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The continuous stirred tank emulsion polymerization of vinyl acetate has shown oscillatory behavior in conversion, particle size, molecular weight, and polydispersity during polymerization. The kinetics in vinyl acetate emulsion polymerization are especially complex because of chain transfer to polymer and monomer and the terminal double bond reaction. A nonsteady-state model to predict the average molecular weights is developed for this polymerization system. Improved results are achieved by inclusion of the effects of polymer chain initiation and termination by absorbed radicals. It is found that the observed oscillations are closely related to the radical diffusion and desorption rates that are involved in a heterogeneous initiation mechanism. The molecular weights and polydispersities are successfully predicted by the model. The nature of the oscillations in these properties is examined.
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  • 146
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    AIChE Journal 34 (1988), S. 849-852 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 147
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    AIChE Journal 34 (1988), S. 859-861 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 148
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    AIChE Journal 34 (1988), S. 853-858 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 149
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    AIChE Journal 34 (1988), S. 862-864 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 150
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    AIChE Journal 34 (1988), S. 865-869 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 151
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    AIChE Journal 34 (1988), S. 870-872 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 152
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    AIChE Journal 34 (1988), S. 877-878 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 153
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    AIChE Journal 34 (1988), S. 873-876 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 154
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    AIChE Journal 34 (1988) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 155
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    AIChE Journal 34 (1988), S. 881-911 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The quality of large semiconductor crystals grown from the melt for use in electronic and optoelectronic devices is strongly influenced by the intricate coupling of heat and mass transfer and melt flow in growth systems. This paper reviews the present state of understanding of these processes starting from the simplest descriptions of solidification processes to detailed numerical calculations needed for quantitative modeling of processing with solidification. Descriptions of models for the vertical Bridgman-Stockbarger and Czochralski crystal growth techniques are included as examples of the level of understanding of industrially important methods.
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  • 156
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    AIChE Journal 34 (1988), S. 1321-1331 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gross error identification in dynamic processes is important in ensuring proper process control. This paper describes the application of a generalized likelihood ratio (GLR) method for identifying gross errors caused by biases in measuring instruments and controllers, process leaks, and failure of controllers. As shown in the application to steady state processes (Narasimhan and Mah, 1987), this method provides a general framework for identifying different types of gross errors whose effect on the process can be modeled. An important feature of the work is the treatment of closed-loop dynamic processes. The formulation of the hypotheses of the GLR method proposed by Willsky and Jones (1974) is extended for this purpose. For estimating the time of occurrence of the gross error, a simple chi-square test on the innovations (measurement residuals) is used, which is computationally more efficient than the method used by Willsky and Jones. Through simulation studies of a level control process the appropriate selection of parameters of the GLR method is investigated.
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  • 157
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    AIChE Journal 34 (1988), S. 1332-1340 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Critical impeller speed for the suspension of solid particles, Ncs, has been measured in 0.3, 0.4, 0.57, 1.0, and 1.5 m ID mechanically agitated contactors. Tap water and quartz particles (100, 340, 700, 850, 2,000 μm) were used as liquid and solid phase, respectively. The impeller speed was varied from 3.5 to 13.3 r/s and solid loading from 0 to 50 wt. %. Three types of impellers were employed: disk turbine, pitched turbine downflow, and pitched turbine upflow. The impeller diameter to vessel diameter ratio was varied in the range 0.175 to 0.58 and the impeller blade width to impeller diameter ratio was varied in the range 0.25 to 0.4. The impeller clearance from the tank bottom was varied from 0.5 to 0.167 of tank diameter. The effect of impeller blade thickness was also studied.The pitched-blade impellers were found to be more efficient than a conventional disk turbine, and the pitched turbine downflow type was found to be more efficient than a pitched turbine upflow impeller. An attempt has been made to explain the mechanism of suspension on a rational basis and a correlation has been proposed for the estimation of Ncs that is expected to be useful in design.
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  • 158
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    AIChE Journal 34 (1988), S. 1361-1366 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
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  • 159
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    AIChE Journal 34 (1988), S. 1367-1372 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 160
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    AIChE Journal 34 (1988), S. 1354-1360 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Supercritical carbon dioxide was studied as a solvent for the enzymatic oxidation of cholesterol with molecular oxygen. Enzymes isolated from Streptomyces sp., Norcardia sp., Pseudomonas sp., and Gloeocysticum chrysocreas are active in supercritical carbon dioxide.For the oxidation of cholesterol to cholest-4-ene-3-one (via cholesterol oxidase) from Gloeocysticum chrysocreas, turnovers are almost two orders of magnitude higher than those found in aqueous solutions; initial rates of the reaction catalyzed by Streptomyces sp. in supercritical carbon dioxide are comparable to or greater than those found in aqueous solutions. Cholesterol oxidase from Gloeocysticum chrysocreas is stable in supercritical carbon dioxide at 100 bar and 35°C, while the enzyme from Streptomyces sp. is not. A trace amount of water is necessary for catalysis in carbon dioxide.The rate of oxidation is increased markedly by addition of small amounts of tert-butanol and iso-butanol, moderately by ethanol, slightly by acetone and n-butanol, and not at all by addition of methanol. Solubility data cannot explain these observations.EPR spectroscopy reveals no large conformational changes in the enzyme from Gloeocysticum chrysocreas as a function of carbon dioxide pressure or cosolvent addition. However, EPR spectroscopy indicates that aggregation of cholesterol molecules in supercritical carbon dioxide is strongly affected by changes in pressure or cosolvent content. The degree of cholesterol aggregation correlates well with observed rate enhancements.
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  • 161
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    AIChE Journal 34 (1988), S. 1006-1019 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Scaling rules for both linear and nonlinear elution chromatography with independent solutes are discussed. The scaling method utilizes smaller diameter particles with high mass transfer rates. The column length, diameter, and cycle time are then scaled so that pressure drop, separation, and throughput are the same or better than in the old design. The new design uses much less packing and cycles more rapidly than the old design. Mathematical derivation shows that the scaling rules for systems with linear and nonlinear isotherms are the same in certain circumstances. Gaussian solutions are used for studying linear systems. Mass transfer zone and diffusive wave analyses are used for constant and proportional patterns, respectively, to describe elution when plateaus form at the feed concentration. Numerical examination of the constant-pattern elution curve using the Thomas solution shows that the scaling rules are applicable to short columns, which means that there is a negligible entrance effect on the scaling rules. The Thomas solution also shows that the mass transfer resistance has little effect on the scaling rules for the proportional-pattern wave of a nonlinear solute. Shock and diffusive wave analyses based on the local equilibrium model are employed to describe the separation when the elution curves do not have plateaus. The calculated results show that the scaling rules are followed exactly when pore diffusion controls. Separation of two noninteracting nonlinear components and of a linear and a nonlinear component remains constant when these scaling rules are followed. Several example calculations are used to demonstrate the method.
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  • 162
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    AIChE Journal 34 (1988), S. 980-995 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this study the impact of the transport processes and the degree of wetting on the overall selectivity of a single catalytic pellet is examined for the commercially important consecutive-parallel network A(g) + vBB(l) → vR1R(l), A(g) + vR2R(l) → P(l). The one-dimensional formulation applies to catalysts in which the active component is concentrated in a thin porous surface shell coating an impermeable support. Model modifications provide an approximate description of uniformly active catalysts. The kinetics are assumed to be first and zero order with respect to the volatile (A) and nonvolatile (B, R) components, respectively, as encountered in many olefin hydrogenations. The common literature assumption of volatile reactant limiting reactions is relaxed by accounting for nonvolatile reactant depletion. The depletion can significantly reduce the desired product (R) selectivity below its intrinsic value attained under fully wetted, no-depletion conditions. A model employing the single limiting reactant assumption cannot predict such selectivity variations. The selectivity is shown to be a complex function of the wetting efficiency, the stoichiometry, and the interacting reactions and mass transport processes. In many cases the intrinsic selectivity is attained for wetting efficiencies exceeding a critical value. Increases in the wetting above this value can reduce significantly the production rate of R because of resistance to A supply through the liquid film. Thus, an optimal range of wetting efficiencies exists for which the selectivity is equal to its intrinsic value and overall rates are high. The significance of the main findings with regard to trickle-bed reactor performance are discussed.
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  • 163
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    AIChE Journal 34 (1988), S. 1027-1030 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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    AIChE Journal 34 (1988), S. 1030-1030 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 34 (1988), S. 1020-1026 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ion exchange accompanied by a neutralization reaction has been analyzed for the general cases where the bulk solution contains a neutral salt and an acid or a base, e.g., [R · H] + (NaCl + NaOH). Both intraparticle and liquid film diffusion are considered. The Nernst-Planck equation was applied for the fluxes of the ionic species in the liquid film and the resin phase with a mobile reaction plane in the liquid film. When the solution contains acid or base more than 50%, the exchange rate is approximated by the case for pure acid or base solution: the reaction plane is located at the solid/liquid interface. When the solution contains acid or base less than 50% (this situation is generally encountered in the case where a neutral salt flows through a mixed bed of OH-form and H-form resins), the mobile reaction plane should be considered. When the ratio of intraparticle diffusion resistance to liquid diffusion resistance defined in the text is larger than 2, the exchange rate can be approximated by intraparticle diffusion control. The larger the ratio, the faster the reaction plane moves to the resin particle surface. Experimental uptake curves for the ion exchange systems [R · H] + (NaCl + NaOH) and [R · OH] + (NaCl + HCl) confirm the above conclusions.
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    AIChE Journal 34 (1988), S. 1043-1047 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 34 (1988), S. 1034-1038 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 168
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  • 169
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    AIChE Journal 34 (1988), S. 1053-1054 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 34 (1988), S. 1057-1064 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Interfacial activity between liquid reaction injection molding (RIM) reactants was observed using light microscopy. Diisocyanates were brought into contact with various diols and diamines in a thin (250 μm) gap. A dynamic phenomenon, rapidly producing a well-mixed, intermaterial phase, was discovered. It was revealed that the rate of growth of this newly formed region was dependent on both the rate of reaction and the physical properties of the initially formed product species at the reaction interface. Spontaneous interfacial mixing also occurred without chemical reaction when a reaction product was dissolved in “capped” contacting reactant liquids. It is believed that strong interfacial intermolecular forces, inducing flow through the polymerization product layer formed immediately upon reactant contact, are responsible for the initial explosiveness of this microscopic process. The range of eventual thicknesses of the mixed, interfacial region (100-800 μm) for various typical RIM systems indicates that this microscopic subprocess may be significant to the fate of the overall process.
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    AIChE Journal 34 (1988), S. 1086-1093 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Reaction mechanism and rates were determined from 803 to 1,073 K for the carbochlorination of Al2O3 and of Al, Si and Fe-mixed oxides using Cl2 and C slurried in a stirred melt of NaCl - AlCl3. Alumina chlorination rates of 0.33-2.0 × 10-8 kmol/s were obtained using C:melt weight ratios between 1:21 and 1:42. The reaction rate was proportional to C loading at temperatures below 923 K, while gas-liquid mass transfer was rate-controlling at higher temperatures. Carbochlorination of the combined oxides in coal fly ash at 923 K and oxide conversions less than about 50% was also gas-liquid mass-transfer-controlled. At higher conversions, dissolution became the rate-controlling factor. A 40% (molar) AlCl3 melt was more effective than a 48% AlCl3 melt for the selective chlorination of Al2O3 over SiO2.
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    AIChE Journal 34 (1988), S. 1128-1134 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rate of dissolution of sphalerite is shown to be directly proportional to the concentration of substitutional iron impurity in the solid. This is attributed to the formation of a narrow impurity band within the forbidden band gap of the sphalerite. The impurity band is of iron d-orbital origin. The transfer of electrons between this d-orbital band and the oxidant is energetically more favorable than the transfer of electrons between the valence band and the oxidant. A fundamental model combining the electronic structure of sphalerite and semiconductor electrochemistry is presented. An equation is derived that describes the rate of dissolution as being first order for the concentration of iron in the solid and half-order for the concentration of the oxidant. This is in agreement with the experimental evidence.
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  • 173
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    AIChE Journal 34 (1988), S. 1135-1145 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new liquid membrane separation technique for gas mixtures has been developed: feed and sweep gases flow through the lumen of two different sets of hydrophobic microporous hollow fibers while a liquid on the shell side acts as the membrane. This membrane is identified as the contained liquid membrane (CLM). Major shortcomings of immobilized liquid membrane techniques are eliminated. The novel separation device is identified as the hollow fiber contained liquid membrane (HFCLM) permeator. Experimental studies are made with different CO2-N2 feed mixtures and a pure helium sweep stream, with special emphasis on model landfill gas purification. Either pure water or an aqueous solution of K2CO3 is used as membrane. The effects of several variables on the performance of the HFCLM permeator have been studied. A three-component permeation model, incorporating axial pressure drop, is developed for binary mixture separation in a HFCLM permeator having a sweep gas stream. The experimental data show good agreement with the theoretical predictions.
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  • 174
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    AIChE Journal 34 (1988), S. 1164-1184 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A continuum model for multicomponent distillation in the minimum reflux limit, first proposed by Nandakumar and Andres, is refined for the special case of constant relative volatility (CRV) and constant molar overflow (CMO) and is extended to columns with multiple feeds and multiple products. A relaxation algorithm for calculating steady-state conditins in any minimum reflux CRV, CMO column is established. This generalization of Underwood's classic treatment of single-feed columns is used to explore the characteristics of several single-feed and multiple-feed distillation systems. Critical operating points at which the steady-state composition profile in a minimum reflux column is indeterminate are identified and analytical expressions predicting the location of these points are established.
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  • 175
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    AIChE Journal 34 (1988), S. 1207-1210 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Tab.
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  • 176
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    AIChE Journal 34 (1988), S. 1752-1756 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 177
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    AIChE Journal 34 (1988), S. 1743-1746 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 178
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    AIChE Journal 34 (1988) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 179
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    AIChE Journal 34 (1988), S. 1887-1893 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Multicomponent adsorption equilibria are predicted from theories based on experimental data for single-gas adsorption isotherms. Theories of multicomponent adsorption differ in the details of their results but should agree in special cases such as low surface coverage and ideal solution behavior. This paper is a summary of rules, limits, and consistency requirements that apply to adsorption of single gases and their mixtures. These rules and limits provide a basis for comparing theories with each other and with experimental data.
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  • 180
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    AIChE Journal 34 (1988), S. 1910-1912 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 181
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    AIChE Journal 34 (1988), S. 2005-2010 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When a porous solid is placed in acid, the solid dissolves at its surface. However, the same solid can precipitate or dissolve in pores inside the solid. The internal precipitation is a consequence of a nonlinear solubility product amplified by fast chemical kinetics. The internal dissolution can be enhanced by unequal diffusion coefficients. Both precipitation and dissolution can occur simultaneously but in different regions, mimicking the patterns of mineral found in teeth.
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  • 182
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    AIChE Journal 34 (1988), S. 2063-2068 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
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  • 183
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    AIChE Journal 34 (1988), S. 2069-2072 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 184
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    AIChE Journal 34 (1988), S. 2077-2079 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 185
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    AIChE Journal 34 (1988), S. 2088-2094 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 11 Ill.
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  • 186
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    AIChE Journal 34 (1988), S. 2083-2087 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 187
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    AIChE Journal 34 (1988), S. 94-106 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Viscoelasticity, nonisothermality, and fountain flow influence the microstructure development during injection mold filling of polymer melts and, therefore, the ultimate properties of a molded article. A comprehensive two-dimensional mathematical model is developed to evaluate the effects of these factors on the structure of the flow field. Special consideration is given to the shape of the flow front, which is crucial in determining the structure of flow in the fountain region. The effects of slip and crystallization are also considered and their influence on model predictions are analyzed. Simulations using the no-slip and slip boundary conditions show that a slip boundary condition is necessary to alleviate the singularities in the flow structure. The results also indicate that the predicted stress profiles are significantly influenced by the viscoelasticity of the polymer melt. Furthermore, the nonisothermality and subsequent deposition of a solid layer next to the mold walls considerably alter the moldability parameters and the flow field.
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  • 188
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    AIChE Journal 34 (1988), S. 107-115 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental investigation has been made to evaluate the friction, acceleration, and hydrostatic pressure drops in two-phase vertical crossflow across a horizontal tube bundle through the measurement of the void fraction and determination of the two-phase friction multiplier. The void fractions were found to increase with increasing mass velocity for a fixed quality level. The two-phase friction multiplier increased with increasing mass velocity for a fixed value of the Martinelli parameter in both slug and spray flow and decreased with increasing mass velocity in bubbly flows. The void fraction and two-phase friction multiplier data were correlated and used to predict with very good results the total pressure drop occurring in simulated diabatic flow tests and in actual diabatic tests using R-113.
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  • 189
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    AIChE Journal 34 (1988), S. 116-122 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The oxygen bleaching of wood pulp takes place in a heterogeneous system involving oxygen (gas), water (liquid), and fiber (solid). Inconsistent effects of process variables (reaction temperature, alkali concentration, and oxygen pressure) on the overall oxygen delignification rate of wood pulp in various reacting systems have been reported in the literature.An apparent intrinsic reaction rate model, excluding the interphase mass transfer effects, has been developed based on oxygen bleaching experiments in an agitated and ultralow-consistency (solids content) reactor. The apparent intrinsic reaction rate model shows a faster delignification rate than those reported in the literature. The degree of inadequate delignification observed in the literature data is likely to be caused by insufficient mass transfer of bleaching chemicals to fibers.
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  • 190
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    AIChE Journal 34 (1988), S. 123-129 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A light-extinction principle was used to measure the fall speeds of the interfaces that develop during gravity sedimentation of monodisperse, bidisperse, and tridisperse suspensions of noncolloidal particles with small particle Reynolds numbers in the semidilute total particle volume fraction range 0.0003 ≤ c0 ≤ 0.15. For monodisperse suspensions, the hindered settling velocity of the interface at the top of the suspension was found to be well represented by the correlation of Richardson and Zaki, provided that the isolated particle fall speed was chosen by linear extrapolation of the data to c0 = 0, with 90% confidence intervals on the exponent of n = 5.0 ± 0.1. For dilute monodisperse, bidisperse, and tridisperse suspensions, the hindered settling velocities of the interfaces showed agreement within experimental uncertainty with the theory of Batchelor, which predicts that the settling velocity decreases linearly with increasing particle concentration and which is based upon pairwise particle interactions.
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  • 191
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    AIChE Journal 34 (1988), S. 81-93 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In an industrial gas-liquid reactor both mass transfer and kinetics have, in principle, a role to play. This paper describes studies on the oxidation of cyclohexane in two-phase, gas-liquid reactors. Regimes of absorption have been clarified by measurements of dissolved oxygen concentrations. The behavior is found to be complex, arising from the fact that the reaction is autocatalytic, and zero order in oxygen over almost the entire absorption range. As reaction velocity increases, due to the autocatalytic kinetics, enhanced physical mass transfer rates arise. Bubble swarms have properties that prevent the simple application of mass transfer and enhancement from flat-surface systems. A theory is developed here that accounts qualitatively for the enhancement found in bubble swarms in the present case. The theory is also shown to predict quantitatively the appropriate physical mass transfer coefficients.
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  • 192
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    AIChE Journal 34 (1988), S. 130-136 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Differential protein extractions were measured with two types of extractants: inverted micelles and two-phase aqueous systems. The results show that hollow-fiber extractions are substantially faster than those possible in conventional equipment. The extractions are not compromised by loading or flooding because the flows of extractant and raffinate are almost completely independent. Mass transfer coefficients inferred from the measurements both support and extend design equations for these contactors.
    Additional Material: 5 Ill.
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    AIChE Journal 34 (1988), S. 140-143 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 194
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    AIChE Journal 34 (1988), S. 137-139 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 195
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    AIChE Journal 34 (1988), S. 173-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 196
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    AIChE Journal 34 (1988) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 197
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    AIChE Journal 34 (1988), S. 175-175 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 198
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    AIChE Journal 34 (1988), S. 189-194 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Micellar-enhanced ultrafiltration can be used to remove multivalent anions or cations from aqueous streams. In the removal of chromate ions (CrO42-), the cationic surfactant hexadecylpyridinium chloride is added to the solution, and the chromate ions preferentially adsorb at the surface of the highly charged surfactant micelles. The solution is processed by ultrafiltration, using a membrane with pore sizes small enough to block the passage of the micelles and adsorbed ions. The permeate solution has a chromate concentration less than 0.1% that in the original stream. A new equilibrium model, combining the simple two-phase polyelectrolyte theory of Oosawa with thermodynamic activity, material-balance, and charge-balance equations, successfully correlates ultrafiltration and equilibrium dialysis results for chromate solutions.
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  • 199
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    AIChE Journal 34 (1988), S. 177-188 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Extensive studies on dispersion-free solvent extraction have been carried out using modules made with either hydrophobic or hydrophilic microporous hollow-fiber membranes. Membrane and boundary layer resistances have been characterized for both kinds of hollow fiber using solvent extraction systems with a wide variation of distribution coefficients and interfacial tensions. It has been found that the Graetz solution for a constant wall concentration describes satisfactorily mass transfer on the lumen side of a hollow-fiber device. A correlation of the form NSh = [Dh(1 - φ)/L]NRe0.6NSc0.33 appears to provide a close fit to the shell-side mass transfer coefficient data. The perforamnce characteristics of dispersion-free extraction in hollow-fiber modules have been considered against those of commercial packed-bed extractors. A perspective has been provided on comparative utilities of hydrophobic or hydrophilic hollow fibers for a given solvent extraction problem.
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    AIChE Journal 34 (1988), S. 321-325 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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