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Notes: The equilibria and kinetics of adsorption of lysozyme and bovine serum albumin on the Fractogel-EMD tentacle-type cation exchanger and the Fractogel-TSK conventional cation exchanger have been studied experimentally by batch stirred-tank method. Adsorption equilibrium data corresponded well to the Langmuir isotherm. For both proteins, the tentacle-type exchanger exhibited a higher binding capacity than the conventional exchanger. This is attributed to the flexibility of the functional groups in the tentacle-type exchanger which enhance optimal electrostatic interactions. The dynamic data were analyzed by a simplified data model which lumped mass transfer resistances and intrinsic adsorption kinetics into a single rate constant. For both proteins, it was found that the tentacle-type exchanger showed a smaller lumped rate coefficient than the conventional exchanger. The difference in the values of the lumped rate coefficients was shown to be due to the influence of nonlinear equilibrium constants rather than due to any difference in rate of adsorption.

Notes: The paper briefly reviews the historical development of exergoeconomics, the existing methodologies, and their application. Particular emphasis is placed on the optimization of the design of new energy-conversion systems.

Notes: A critical comparison of the strength and weakness of two optimization strategies for thermochemical process is made, i.e. pinch analysis and exergy analysis. Although both methods have a unique root, i.e. the minimization of the exergy losses, pinch analysis has evolved to become an instrument of direct and optimal design of a heat exchanger network while exergy analysis as such does not give an indication about process optimization. In combination with an adequate simulation code of a process, however, it can help to find the optimum process structure.

Notes: The growth of a thin liquid film surrounded by gas pocket(s), undergoing absorption with a zero-order chemical reaction, has been simulated by an apt mathematical model in order to study the influence of various parameters involved. The solution has been obtained semi analytically using Goodman's integral method and solving the resulting differential equation by a fourth-order Runge-Kutta numerical integration algorithm. The computations reveal the strong dependence of film growth on reaction rate, diffusivity, and molar volume whereas the effect of gas-pocket volume and initial film thickness are moderate.

Notes: The optimal layout of a chemical plant is determined by both economic and environmental aspects. The mathematical approach to this problem is given by representing the process through a superstructure, including any foreseeable process topology. It is described by integer variables, whereas real variables arise from the unit models and the thermodynamic calculations. By including process constraints and an objective function, a Mixed Integer Nonlinear Programming (MINLP) optimization problem is postulated. In this paper MINLP algorithms are combined with a technique for the exergy analysis of chemical processes for the preliminary screening of process alternatives. The exergy analysis as a screening technique is advantageous due to a significantly smaller amount of required data and computing time, compared with true optimization, including cost estimation at an earlier stage of process synthesis and analysis. Thus, a broader solution space can be examined. The subsequent cost analysis has then only to be focused on a reduced set of parameters.

Notes: Heat transfer from a buried pipe carrying a flowing liquid is analysed using a 3-dimensional geometry, transient modeling and numerical methods. The pipe is buried horizontally in soil whose initial surface temperature is assumed to be below that of the bulk soil and the pipe, and also below the freezing temperature of the liquid. The problem is solved using string-intersected-boundaries and a three-level alternating-direction-implicit finite-difference method. It is possible to predict the time taken for the fluid anywhere in the pipe to fall to its freezing point. The minimum burial depth needed so that the pipe does not freeze is also predicted. The simulation was run on an ordinary mainframe computer with very small computation times. The package developed can be used by designers such as pipeline, plant and water distribution engineers.

Notes: A chain growth model for heterogeneous secondary reactions is developed for the pyrolysis of large wood particles and the parameters determined by nonlinear optimization. The model takes both the volatile retention time and cracking and repolymerization reactions of the vapours with the decomposing solid as well as sutocatalysis into consideration. The extent of the secondary reactions is strongly influenced by the time and the ratio of the autocatalytic (propagation) reaction rate to noncatalytic (initiation) reaction rate. The wood which has a higher value of the autocatalytic/noncatalytic ratio also has a higher exothermic heat of reaction and yields a higher amount of final char residue. This fact confirms the heterogeneous secondary reactions lead to carbon enrichment of the final residue and are accompanied with an exothermic heat of reaction. The lower activation energies of the initiation and propagation reactions as compared to primary reactions (competitive reaction model consisting of weight loss and char forming reactions) confirm autocatalysis in large particles. The sealed reactor studies of small quantities of fine wood samples show that heterogeneous secondary reactions and not lower heating rates in large particles are the main source of char formed during the thermal decomposition of large wood particles. The model predictions are in agreement with the weight loss and temperature versus time curves over a wide range of particle size and furnace temperatures.

Notes: Intermig impellers have been postulated as very efficient for mixing highly viscous non-Newtonian fluids (such as xanthan and mycelial broths). However, no formal characterisation has been published and no fair comparisons have been made, based on accurate power drawn measurements and using equal number of impeller stages and equal diameter, if compared (for example) with the performance of Rushton turbines. Characterisation of the shape, size, and evolution of the well-mixed zones or “caverns” were correlated with power drawn, for single and dual Rushton turbines and for one- as well as two-stage Intermig unslotted impellers. Cavern evolution studies were carried out in a mixing tank (diameter=0.205 m, H/T=1.6) equipped with an accurate air bearing dynamometer. Carbopol 940 (0.25 wt.-%) was used as a model, transparent fluid. Impeller to tank diameter ratio was 0.53 for both impellers. Caverns were visualised by injecting methylene blue in the well-mixed zones. A single Rushton turbine developed larger caverns if compared with one-stage Intermig of the same diameter under power drawn below 1.5 kW m-3. At higher power drawn, both impellers behaved very similarly, reaching a limit in cavern volume of about 40% of the total liquid volume, even at very high (20 kW m03) power drawn. A similar trend characterised dual combinations: below 3 kW m-3, dual Rushtons gave larger cavern volume if compared with the performance of two-stage Intermigs. In either case, power drawn higher than 3 kW m03 was sufficient to mix more than 90% of the liquid volume. The presence or absence of the slot in the Intermig did not influence cavern development. Experiments with a smaller if compared with those obtained with the larger Intermig (D/T = 0.53).

Notes: Heat exchanger network synthesis (HENS) is a frequently encountered class of chemical engineering optimization targets. Besides its immediate relevance to practical, industrial applications, the HENS problem presents an adequate complexity class to test new technique of numerical optimization and benchmark them.This paper first sketches two established approaches to HEN optimization. The fist one is based on thermodynamic insight, while the second one uses MINLP techniques for rigid optimization. Afterwards an alternative approach based on the paradigm of evolutionary optimization is introduced. The newly developed optimizer module is coupled to the well known ASPEN PLUS simulator. The program package allows the optimization of parameters as well as network structure.

Notes: Interfacial properties exert a fundamental influence on fluid/liquid separation processes, with the interfacial tension being an important quantity associated with mass transfer and mutual solubility of participating compounds. A better understanding of transport phenomena is achieved by obtaining interfacial tension data under different conditions of pressure and temperature and as a function of time. Generally, interfacial tension decreases with increasing pressure due to increased adsorption of the compressed fluid at the interface. In the case of considerable mutual solubility, interfacial tension further decreases with time as mass transfer into the bulk phase proceeds. Prediction of colloidal behaviour in a separation process requires acquisition of additional information on the presence of surfactants.

Notes: A mathematical model has been developed to simulate the operation of an absorption-driven multiple-effect evaporator. The model is based on mass and enthalpy balances and heat transfer rate equations of the various components of the system. The model has been validated by comparing model predictions to experimental results from the operation of a four effect absorption-driven falling film evaporator coupled with a two-effect regenerator which operated using solutions of sodium hydroxide as an absorptive medium. The model predictions are in satisfactory agreement with the experimental results.

Notes: Knowledge of the compression factor is essential for the transport, storage and utilization of natural gas. The normal way to determine this property is by using an equation of state (EOS) which utilizes the gas temperature, pressure, volume, and composition. In many industrial situations, the composition of the natural gas is not available, yet it is still necessary to calculate the compression factor. In this paper, we present an EOS which uses relative density, heating value, and diluent compositions to determine the compression factor. The applicable ranges of conditions are 220 to 500 K up to 70 MPa (-60-450°F up to 10,000 psia). The calculations agree with data within 0.1% average absolute deviatation up to 10 MPa with a maximum deviation of 1.9% near pure component critical points or mixture cricondentherms. The equation also extrapolates through data up to 70 MPa within 1.9% We present comparisons to data of AGA Report No. 8 and to data in the paper.

Notes: Complex configurations of distillation columns have been shown to consume less energy than simple configurations. These complex configurations mainly results from two considerations: either a feed split, where the condensing vapor from the top of the high pressure column is used to heat the reboiler of the low pressure column, or the overheads from a high pressure column in a distillation train used to reboil a column under lower pressure. Industrial experience shows that very often in these configurations there is still incentive for more energy reduction simply because of inefficient control. The energy integration increases the control loop coupling the system, so that the operating strategy for the columns is no longer apparent. Therefore, the dynamic behaviour and the operational constraints of such systems become very important. The use of rigorous dynamic model of the processes is an essential instruments to pursue the goal of good and reliable process control Such models allow the engineer to realistically simulate the process with the desired control system in place and to analyze the effects of equipment sizing, hest integration, and disturbances. Variable pairing proved is used to illustrate that effective control of energy-integrated distillation columns can be achieved by proper selection of manipulated variables and pairing them correctly with control variables. Hints will also be given, when multivariable predictive control schemes should be used.

Notes: Many rectification processes are used to separate corrosive substances with high boiling points. This reports deals with a new type of structured column pacing mode of corrosion-resistant carbon fiber material. These column internals allows for low pressure drop at high throughput rated with reasonable column efficiency. Experiments in columns of 50 and 100 mm diameter have been carried out to investigated separation efficiency, pressure drop and liquid holdup of the packing even at low operation pressures. In the respective columns twp geometrical different types of packing have been tested using binary mixtures of chlorobenzene/ethylbenzene with a packing geometry similar to the Sulzer EX packing, the 100 mm diameter column was filled with elements of rougher structure and smaller specific surface. Basing on the experimental results, model equations are presented, which allow the calculation of the investigated performance characteristics.

Notes: The wetting characteristics of fine powders play an important role in a variety of processes. The most important way of characterising the wettability of a fluid/fluid/solid system is to measure the contact angle. This paper describes a relatively simple method for the determination of the contact angle on powdery materials. The technique involves the measurement of the dynamic contact angle which is formed when a liquid drop is placed on a horizontal porous surface. On the basis of the measured dynamic contact angle as a function of time an “apparent” static contact angle has been defined, which gives a measure of the wettability of porous solid systems by analogy with the wetting of non-porous solids. Determinations with glass beads and NaCl-powders as the test materials indicate that the measured value depends on the particle size of the powder, the porosity and the temperature. It was concluded that the capillary penetration of the liquid droplet into the porous media itself influences the wetting characteristics.

Notes: A new reactive distillation device, the multistage gas/liquid/solid three-phase fluidized bed, has been developed. The flow regimes of the multistage three-phase fluidized bed have been studied and the regimes can be divided into the liquid leakage regime, the dispersed bubble regime, and the coalesced bubble regime. Liquid velocity has a much smaller effect on phase holdups in this device than in conventional three-phase fluidized beds. The three phase fluidized bed is used as a reactive distillation device for the hydrolysis of methyl acetate. Much higher reaction conversion than the equilibrium value and high catalyst-contacting efficiency are obtained. Different methods of feeding the water into the reactive distillation section are studied.

Notes: Chemical engineering analysis using entropy production has been proven to be an essential tool to identify areas in chemical plants, where degradation of energy occurs. Though, applied very extensively in the area of heat exchanger networks in the form of “pinch technology”, the method is rarely used with respect to processes with mass energy. Entropy productions in destillation columns have been evaluated and discussed with respect to feed introduction, sequences of columns and other technically important features.

Notes: Exergy analysis is an excellent tool for locating weak spots in a process. Purposefully applied, it improve our insight and allow us to design processes systematically. Yet for many engineers exergy remains a difficult subjects. To make analysis easier and the results easier to interpret, therefore, we need the best possible exergy analysis tools. The commercial performance of both plant suppliers and operating companies depends heavily on optimization to reduce plant costs (in the widest sense) to a minimum. As an optimization tool in plant design, exergy analysis has to compete with parametric studied and, increasingly, with equation-based optimization programs.

Notes: This paper presents results of temperature-programmed desorption (TDP) as a method for studying the acid and shape-selective properties of small- and intermediate-pore zeolites.A combination of an in situ infrared spectrometer and a downstream gas chromatograph for analyzing the desorption products is used to detect the desorption process. This is followed by a separate, newly installed microbalance facility.The studies shows that a part of the amines, esp. dimethylamine (DMA) and trimethylamine (TMA), adsorbed on the zeolites undergo decomposition, disproportionation and carbonization reaction during the TDP measurements at elevated temperatures. Comparison of the microbalance measurements and the gas chromatographic results give a good picture of the extent of these reaction.

Notes: Experimental investigations were carried out with mainly a Mogensen-Sizer, compared with test screening and additionally laser diffraction and light extinction, in order to check the qualification for on-line determination of particle size distribution under the specific conditions of feed milling. The different components of compound feed, the degree of milling, the difference in measured particle characteristics and the possibility of sample dispersion affect the comparability of the results. The results show that laser diffraction is a manysided method with accurate recording of the distribution. The modified Mogensen-Sizer can be a robust low-price alternative if the control of selected distribution parameters is sufficient.

Notes: Laser diffraction (LD), with reference to the analysis time, is highly advantageous for the automation of particle size analysis. The high measuring frequencies alloy quasi-continous measuring operation. The fineness values obtained form the particle size distribution (PSD) can be transformed into electrical signals for automatic process control.For industrial purposes, an encapsulated measuring cell was developed where the laser beam penetrates the dispersed fines stream via two optical windows. Thus, hazardous materials can also be measured, specifically pharmaceutical or chemical products, or applications requiring explosion-proof plant design are possible. Great efforts had to be made to keep the inner side of the windows clean form product dust. Ultimately, batches running for more than 8 h could be analysed continuously without any contamination of the windows. For the PSD measurements, a standard LD instrument was used with a measuring range of 0.5/0.9-175 μm.As product fineness is monitored continuously in-stream, and virtually without delay, any changes in the fineness during classifier operation can be detected immediately. On the one hand, this opens up a new field for studies of classifier performance. On the other, immediate quality control of even very small batches is possible during the micronization process. The results demonstrate very clearly, for example, the importance of controlling the feed rate to the classifier. Therefore, fineness control by means of this in-line technique gives superior advantages for direct adjustment of the classifier speed.

Notes: The precipitation of barium sulfate was investigated by photon correlation spectroscopic (PCS) measurements of the growing crystals combined with electrical conductivity measurements of the mother solution. Small silica seeds (36nm) were added to the solution. Therefore, heterogeneous nucleation did not take place on the walls and on the stirrer, which is usually the case, but on the seeds. Hence the growth of the crystals which had nucleated on the seeds could be studied by PCS. In order to avoid the ill-conditioned inversion of the measured raw data, the autocorrelation functions, a population balance model was used to calculate these functions with the help of a kinetic model taken from the literature. The measured an the calculated autocorrelation functions could coincide and adjustable parameters were found from a least-squares fit. The measurements revealed that nucleation is strongly enhanced by PMA-PVS (polymaleic acid-polyvinylsulfonic acid). However, a simple model which assumes langmuir adsorption of PMA-PVS on the crystal surface did not describe the kinetics very well. The nucleation rate in the absence of the additive was found to be J=1.3·1010 exp(-27/In2S) [m-3s-1], while the growth rate was G=2.6·10-8(S-1)2/3 S1/3 exp(-29/3 In S) [ms-1]. These results match results taken from the literature fairly well.

Notes: During the spherical agglomeration process, a suspended solid is agglomerated by adding a binding liquid. First, mircoagglomerates or flocs are produced, which are compacted in the course of the process. Agglomerate size was evaluated by laser diffraction spectrometry, image analysis was used to determine the size and some adequately defined shape parameters calculated by Fourier analysis of the particle contour.The shape analysis confirms the visual observations; the compaction of the flocs is expressed by the corresponding change of the shape parameters. The influence of several process parameters on changes in agglomerate shape can be described quantitatively and help to gain an insight into agglomeration mechanisms. The particle size distributions determined by image analysis and laser diffraction spectrometry hardly differ for fairly spherical flocs or agglomerates. Concerning the size distribution of the irregular flocs, laser diffraction spectrometry measures larger particles than image analysis.

Notes: Response of a phase Doppler system to irregularly shaped particles is examined and shown to deviate qualitatively as well as quantitatively from the spherical particles. Nevertheless, the measured phase distributions based on an ensemble of particles exhibit a high degree of order and simplicity. The experimental data and the stochastic modeling of the process have shown that the phase Doppler technique can be used successfully for in-situ sizing and velocimetry of irregular particles. In the case of irregular crystalline particles, mean size and standard deviation can be deduced without requiring any assumptions regarding the functional form of the size distribution. As opposed to other optical techniques, phase Doppler can be used, in principle, near the backscattering location, so that a single optical window would be employed for transmission of laser light and collection of the scattered signals. Furthermore, size measurements can be velocity-resolved, i.e. a size distribution can be associated with each bin of the velocity histogram.

Notes: The particle size distribution of crystalline solids has progressively become a key parameter in manufacturing processes, as important as chemical purity. Among the particle size determination and counting systems available on the market, very few offer the possibility of continuous in situ monitoring of the particle size evolution during crystallization. For this reason, much interest has been aroused by the appearance of the Par Tec 100, patented by Laser Sensor Technology [1, 2]. A study has been carried out in a stirred vessel to verify the precision and reproducibility of particle size measurement and elucidate the influence of experimental parameters on data accessible with this instrument. Optimum reproducibility has logically been achieved by fixing the highest possible cycle time and taking the mean of several cycles. Determinations with the Par Tec 100 are influenced variously, according to whether they relate to the total number of particles counted or to the mean size. Thus, the number of counts measured by a particle size probe largely depends on the operating conditions and more particularly on the hydrodynamic conditions, solvent, temperature and focal point position. Its dependence relative to the concentration of the solid in suspension is normal and linear for a solid and for a given monodisperse sample. To establish the relationship between the number of counts and the population density would therefore necessitate delicate calibration on a case-by-case basis. The mean size determined does not depend on suspension homogeneity, provided that the stirring speed is sufficient for a statistically significant total count. On the other hand, for a given sample, a displacement of the focal point can lead to considerable variations in the size determined. The optimal focal point position for small sizes is in fact highly sensitive. Lastly, the optimal position of the focal point is considerably dependent on the true size of the particles, which means that this counter is unsuitable for the precise analysis of a dispersed sample since each particle size class would require a different setting of the focal point. In addition, the sizes determined, irrespective of the products studied, appear to be underestimated for large particles and over estimated for small particles.

Notes: Electrically active fibrous filters, that is fibrous filters whose fibres carry a permanent electric charge, are an increasingly popular alternative to conventional fibrous filters in applications where low pressure drop and high collection efficiencies are critical. The advantage of these materials is the additional collection efficiency, due to electrostatic mechanisms, that can be achieved without pressure drop increase. The efficiency of these materials can fall as they are loaded with aerosol particles, so it is necessary that proper account be taken of this process during use. A complete understanding of the mechanisms responsible for this reduction in efficiency has not yet been reached. An experimental study has been undertaken at Loughborough University of Technology investigating the loading behaviour of a mixed fibre type electrically active material. The experimental techniques used in this work and experimental findings with a range of aerosol particle sizes are reported here.

Notes: The production of liquid sprays represents a key technology for a wide range of industrial proceses. Most applications currently use pressure or air-assisted atomization, resulting in the production of polydisperese sprays. Recent advances in experimental and numerical techniques for investigating liquid spraying processes, however, have enabled a closer examination of parameter optimization, leading to the conclusion that in may cases, a much narrower size distribution, or even a monodisperse spray, may exhibit many advantages. Currently monodisperse droplet generators, or drop-on-demand generators, do not meet this challenge of producing monodisperse sprays, primarily owing to the very low volume flow rate of liquid which is atomized. In the present work, a monodisperse sprya generator is introduced, which overcomes this difficulty for many applications.

Notes: Measurements of droplet deformation during wall impingement were performed for ethanol droplets and water droplets with diameters ranging from 100 to 200 μm. The wall temperature is well above the Leidenfrost temperature of the droplet liquid. With monodisperse droplet streams and a special illumination technique, slow motion images of the phenomena can be obtained. Measurements with high temporal resolution below 1 μs are possible using a standard video camera. The experimental results are compared with numerical results, which were obtained by solving the three-dimensional Navier-Stokes equations for incompressible fluids including surface tension effects. The fluids are treated with the volume-of-fluid method and the free surface is modeled according to the continuum-surface-force model. Numerical and experimental results show good agreement.

Notes: The aim of this work is a fluid dynamics study of the structured packing Sulzer BX gauze. A new model is proposed which, on the basis of a knowledge of the dynamic component of the liquid holdup, permits calculation of the fraction of the geometric area of the packing that effectively participates in the mass transfer. Both the metal and plastic versions of the packing are studied. Experimental data are supplied on the absorption of pollutants such as HCl and SO2 by aqueous solutions of NaOH in columns in cocurrent operation. The results obtained by the proposed model are in good agreement with experimental data obtained by the present authors as well as with experimental data published in the literature.

Notes: A new Paradigm has been developed fro the prediction of maximum stable diameter of viscous drops in turbulent dispersions using the Voigt model. The model assumes that a drop would break if its deformation reaches unity. The prediction from the model compares quite well with the available experimental results.

Notes: In the field of fine chemicals batch process the implementation of synthesis paths results most often in the determination of the optimal operating conditions on a bench scale apparatus; successive scale-ups are then handled in an empirical way.For multi-phase reactions, this approach can be limited due to the coupling between the chemical kinetics and the physical kinetics of the mass transfer. This work proposes a more rational approach for the overall synthesis of Amiodarone, a widely used anti-arrhythmic drug produced by a liquid/liquid/solid reaction. After analysing the reaction scheme and identifying the limiting steps of the process, a simplified model is proposed to describe the overall process kinetics. The latter is used to model a continuous pilot loop-reactor packed with static mixers.

Notes: The dynamic behavior of a Pt-Rh/CeO2-Al2O3 three-way catalyst (TWC) under pulsed flow operation conditions (intermittent mode), such as occur in a newly developed hybrid drive system, has been studied experimentally in a laboratory apparatus with simulated exhaust gas. The parallel hybrid system is based on the combination of an Otto-cycle engine with an electric motor and a flywheel providing a short-term energy storage. This configuration permits intermittent charging of the flywheel by the combustion engine which runs only during about 10% of the driving time. Each exhaust gas pulse (duration typically ca. 3 s) is proceeded by an air pulse, which results from the filling of the engine cylinders with air at start up and shut off. Experimental studies indicated that the air pulses have a negative impact on the performance of the catalytic converter, reducing the inherent benefits resulting from the intermittent operation mode of the combustion engine.Forced asymmetric λ-cycling during exhaust pulse was found to be most beneficial for improving catalyst performance. A simple reduced kinetic model derived from a Langmuir-Hinshelwood model for CO oxidation, which was extended by introducing CO and O2 equivalents to mimic the complex exhaust gas, was used to describe the dynamic behavior of the TWC. The model proved to be useful for finding the optimal λ-cycling conditions. Experiments with the real Otto-cycle engine exhaust proved that the reduced kinetic model is suitable for use in a closed loop λ-control.

Notes: When appropriate membrane was used for the assistance of chemical and biochemical equilibrium reactions, it is possible to enhance the yield and the purity of the reaction product by selectively adding educts or selectively removing products and to a lower the energy input and the reaction time compared to conventional process.In this paper a review on membrane reactors with special emphasis on membrane-assistance of esterification reactions and a continuous tube membrane reactor for the pervaporation-assistance of the esterification are presented. The heterogeneously catalyzed esterification of ethanol and acetic acid to ethyl acetate and water was investigated as a typical chemical equilibrium reaction.The selective and simultaneous water separation from the reaction mixture of the esterification with polyvinyl alcohol pervaporation membranes is considered to be an interesting process alternative to the conventional distillation process. Compared to the distillation process, for the pervaporation-assisted process a decrease of the energy input of over 75% and of the investment and operating coasts of over 50% each was calculated.

Notes: Existing design codes propose different methods for the analysis for the junction region of conical and toriconical shells (limit analysis, shake down analysis, Kellog design approach, area replacement method) submitted to internal pressure load. However, now it is possible to develop generally valid an very precise guidelines based on linear and nonlinear Finite Elements-Analyses. A clear difference is made between design with respect to fatigue strength and design according to load carrying capacity criteria. A. Major advantage of the Finite-Elements-Method(FEM) is the opportunity of its adaptation to given design criteria such as a strain limit or a plastification limit. It shown how design curves can be directly derived from the FE-analysis with respect to fatigue strength (stress concentration factors) and load carrying capacity (design factors for the calculation of a required wall thickness). The materials behavior in the plastic region is considered with an without strain hardening. Large deformation effects as geometric nonlinearities can be involved in the analysis. The method can easily be applied for the analysis of other pressure vessel components.

Notes: We developed the oxidation reaction of Cu(I) ion in aqueous hydrochloric solution by oxygen in a gas-lift capillary bubble column. The method of gas-liquid absorption with chemical reaction was used. Test data confirmed that the rate constant of the reaction is strongly affected by solution compositions, and that chloride ions induce an inhibition effect. The kinetical orders found are equal to 1 and 2 for oxygen and Cu(I) respectively. The influence of temperature on reaction rate constant showed the existence of a maximum value between 303 and 313K. The effect of gas-liquid of gas-liquid system on the liquid-side mass transfer coefficient kL was also investigated.

Notes: Comparative calculations of several methods of characterization for three multicomponent mixtures that include paraffin, naphthene, and aromatic fractions are shown. Each method requires different experimental information about the mixtures but all use the numerical Gauss-Legendre quadrature. The results show that characterization making direct use of the TPB distillation curve is the most suitable approach for characterizing complex multicomponent mixtures.

Notes: Whole mean gas hold-up εg, liquid recirculation velocity U1d and mixing time tm were measured in a 0.12 m3 airlift reactor, with an external recirculation loop (ALR-EL), which was used for the production of the exopolysaccharide, Scleroglucan, by cultivation of the filamentous fungus, Scleroticum glucanicum. Under identical fermentation conditions, the effects of air flowrate and the viscosity of the culture fluid on εg, U1d, and tm were investigated. In the range studied, empirical correlation for εg, U1d and tm with both superficial velocity Ugr and consistency coefficient K were obtained and expressed separately.

Notes: Affinity separation can be achieved by batch and fixed bed modes. Mathematical models including film mass transfer, intraparticle diffusion, and reversible reaction are formulated for both fixed bed and batch adsorption processes. Orthogonal collocation method is used to numerically evaluate the performance of batch and fixed bed adsorption. The efficiencies are evaluated in terms of both the solute recovery and adsorbent utilization. The effect of the following parameters is simulated for the comparison purpose: solute concentration, reaction kinetics, ligand content, and particle size. Fixed bed mode is found to be efficient.

Notes: A mathematical model of the absorption of HCI gas in a spray dry tower has been proposed. The proposed model describes the mechanism of HCI removal talking into account atomized droplet size distribution and the change in the droplet state from “slurry droplet” to “dry particle”. It is found that the removal efficiency can be simulated by using the model with the constant mean diameter of droplet from the simulation results. Simulation results of the removal of HCI gas are in good agreement with the experimental data in a spray dry tower.

Notes: Ultrasonic standing wave atomization (USWA) is a new process capable of atomizing both high surface energy liquids and highly viscous liquids. Atomization is achieved through acoustic forces acting upon a liquid jet which is guided into the central pressure node of a standing wave field. Spherical metal powders with minimum mass median diameters of less than 15 μm have been produced from metal melts with surface tensions of about 0.5 N/m. Organic liquids with viscosities between 1 and 10 Pas have been atomized, yielding mass median diameters from 20 to 330 μm. The influence of different operating parameters on the mass median diameter of metal melts and highly viscous liquids was evaluated. Parameters which were varied were ambient gas pressure, vibration amplitude of the transducers, mass flow rate, density of liquid, viscosity of the liquid, surface tension and the outlet diameter. The powders and sprays were analyzed with laser diffraction particle sizers. The physical background of the atomization process is discussed and an equation for the prediction of the mass median diameter is derived.

Notes: This paper describes the evaluation of the transfer function for the TSI-short differential mobility analyzer (DMA) in the nanometer particle size rang. The TSI-short DMA is identical with the TSI-long DMA (Model 3071) but has shortened inner and outer electrodes and the insulator material Teflon was replaced by black Delin. The DMA transfer function was determined by operating two identical DMAs in series. The DMA was investigated at a sheath to aerosol flow rate ratio of between 10 and 1. Usually for particles above 50 nm the parameters of the assumed triangular transfer function, i.e. height and half-width, approach the ideal values, which depend only on the flow ratio. For particle size below 50 nm the height decreases from 0.9 at 50 nm to 0.18 at 5 nm. The half-width increase from the ideal value 0.1 to about 0.17. The observed changes of the transfer function are due to diffusional effects resulting in losses mainly in the inlet and outlet and also broadening of the aerosol stream inside the DMA. The determined transfer functions were also compared with transfer functions calculated using a theoretical model. The agreement proved to be satisfactory. The half-widths and the transmission efficiencies of the conventional TSI-DMA (Model 3071), TSI-short with Teflon and also black Delin insulator as a function of particle size are compared to demonstrate the improvements in performance.

Notes: The influence of the measurement volume can be investigated by using extended geometrical optics, which is based on geometrical optics by including the amplitude and phase distribution in the laser beam. The dynamics in phase Doppler anemometry can be analysed, in addition to effects of the particle size-dependent detection volume. Extended geometrical optics has been developed as a powerful tool to investigate these influences for each order of light scattering separately. Phase errors caused by Gaussian-beam intensity distribution and the curvature of the wave fronts beyond the beam waist can easily be calculated. According to Part 1 (Reflective Mode Operation), the influence of the particle trajectories on measured phase and mass concentration is simulated for refractive mode operation.

Notes: The particle size distribution of an aerosol generated from an aqueous system is difficult to analyse because of the shrinkage of the droplets due to solvent evaporation. These problems are very important for the characterization of medical nebulizers, since most of the drugs delivered via inhalation are water soluble. In situ methods for droplet size analysis, such as laser diffraction, phase Doppler anemometry and light scattering, do not determine either the initial or the equilibrium size distribution. With the residual technique, which means evaporating the droplets and measuring the size and concentration of the residuals, the instability of the aqueous droplets plays no role and the necessary radioactive labelling of the sprayed material allows a direct determination of the mass flow rate at the mouthpiece of the nebulizer. In this way it is possible to discriminate between the delivered drug solution and the water necessary to humidify the incoming air. The output of nebulizers of different designs is given for various operating conditions, filling volumes and solution concentrations. The measured droplet size distribution of a nebulizer is found to be fixed mainly by its internal impaction system.

Notes: An account is given of the patented technique of the rotational particle separator for separating solid and liquid particles of diameter 0.1 μm and larger from gases. Attention is focused on the working principle, fluid mechanical constraints, particle design, separation performance, power consumption, dimensions, filter cleaning and costs. Furthermore, an overview is given of current developments to introduce this technique in industrial dust removal, in electricity generation and in the consumer goods market. The article concludes with a summary of the feature which distinguish this technique from existing filtering methods.

Notes: Three-Phase fluidized bed bioreactors have advantages over conventional chemical reaction systems. There is a lack of agreement over most major operational conditions, and a wide range of design variables are open to question. A large body of recent work in the field has been reviewed, with a degree of historical comparison and discussion.It has been found that aspects of fluidized bed biofilm reactors of vital importance include: choice of solid media, gas and liquid loadings, bacterial type and reactor mechanical design. A large proportion of the work in the field of three-phase fluidization is non-biologically specific, or not tested on a bacterially inoculated system.The majority of three-phase fluidized bed bioreactor work is in the field of water treatment. Although this work has highlighted the potential for use of bio-fluidized beds for this application, there are still specific problems hindering the large scale industrial acceptance of three-phase fluidized bed bioreactors.

Notes: The process of recrystallization of apatite phosphogypsum (PHG) in a solution ammonium sulphate (AS) with the subsequent decomposition of the binary salt was investigated and the resulting highly dispersed products with a low P2O5 content have been discussed. The following effects were examined: (NH4)2SO4 concentration, the quantity of ammonium sulphate, the reaction temperature of phosphogypsum with (NH4)2SO4 solution, the time of treatment of phosphogypsum with (NH4)2SO4 solution and the decomposition of the binary salt, as well as the liquid/solid ratio for the binary salts, Based on the results of the chemical and X-ray analysis, it was established that, depending on the technological conditions of the process of recrystallization, binary salts of (NH4)2SO4·CaSO4·H2O and of (NH4)2SO4·CaSO4·H2O and of (NH4)2SO4·5 CaSO4·H2O were formed. As a result of the investigations carried out, a product with a low P2O5 content, suitable for direct processing to secondary products has been prepared.

Notes: A three-step catalytic reaction (TSCR) mechanism is considered. It involves the steps of adsorption of two different reactants and the bimolecular reaction between adsorbed species. For this mechanism the rates of elementary reactions were assumed to be dependent on the surface coverages of two adspecies due to the repulsive mutual interactions between adsorbed species. The surface electronic gas model was chosen for the description of surface inhomogeneity. It is demonstrated that for such a TSCR mechanism sustained oscillations cannot exit. The application of the model to evaluation of kinetic data is discussed.

Notes: A method for the prediction of velocity and path length components for two-dimensional particle motion is developed for stagnant and slowly moving gas. The numerical algorithm appears much more straightforward and more efficient than those previously developed on the basis of simplified analytical methods. In the case of particle motion in a flowing gas, several limitations of the method occur. The method of limit estimation is briefly described.

Notes: The hybrid knowledge-based system proposed in this paper consists of a “stiff” segment, viz. the expert system based on the object-oriented approach, and a flexible part, viz. the neural network. Some of the input parameters of the problem and output parameters of the “stiff” system are presented as the fuzzy numbers. Detailed information is also presented about the development of the neural network. The most evident advantages of the proposed introduction of a hybrid architecture of the knowledge-based system are a faster evaluation and generation of design alternatives and support of systematic searches and storage of experience. In addition, the resulting ability to extrapolate results would be unattainable with separately acting stiff and flexible systems. A system for the estimation of the parameters of a mixing system for wastewater treatment is presented as an example to illustrate the principles of the hybrid system.

Notes: Numerical results are presented for a contraction flow of a non-Newtonian fluid. In this work a new finite-volume algorithm was used and various non-Newtonian fluid models (with and without elasticity) were studied. The results are discussed and compared to experimental results obtained with a dilute polymer solution.

Notes: Local mass transfer studies have been carried out in an external loop airlift reactor and indicated the existence of significant non-uniformities in aeration capacity in the various sections of the reactor. The traditional assumption of a single well mixed unit with a single kL a value for external loop airlift reactors was found to be poor and cannot represent adequately the reactor as a whole. The liquid head in the gas/liquid separator was found to have a significant negative negative effect on the local mass transfer coefficient kL a. Visualization of flow patterns showed the existence of strong vortices in the riser and downcomer which contributed to a reduction in local aeration capacity. Mass transfer experiments in an aerated tank showed that the aeration capacity can be reduced by half in viscous media but improved significantly in the presence of salts.

Notes: The generalised thermal parametric sensitivity criterion is applied to the thermal behaviour of the esterification of 2-butanol with propionic anhydride in a batch reactor under isoperibolic conditions. The reaction is catalysed by sulphuric acid, and the study covered the effects of both catalyst concentration and, in the absence of catalyst, jacket temperature. The experimental location of regions of parametric sensitivity agreed well with theoretical predictions. However, the process conditions that meet conventional standards for safe process design fall into the supercritical sensitivity region of the parametric model. This apparently contradictory result is discussed. The usefulness of the parametric sensitivity approach is illustrated by practical examples of scale-up and heat transfer in reactions prone to thermal runaway.

Notes: A general procedure for the determination of empirical rates and kinetic parameters of irreversible, constant volume reactions is presented which is clearly superior to the conventional methods of kinetic analysis. By nonlinear regression of the integrated potential rate equation for stoichiometrically independent reactions of n the order, the empirical pre-exponential factor, activation energy, and reaction order are obtained. The regression equation relates explicitly the final concentration of the reference component not only to the time parameter of the reaction but also to the initial concentration. This includes an integral method for the determination of reaction orders in concentration. Two limiting cases are treated - the stoichiometric mixture of reactants and a mixture with one reactant in large excess. By analysis of standard Hougen-Watson rate models the dependence of empirical reaction orders on experimental conditions and simulated rate parameters is evaluated. By grouping the data into ranges of monotonous concentration change, conversion rates and rate parameters of reactions with changing volumes are calculated in a less rigorous deduction. The simplified interpretation of published experimental data is demonstated for the total oxidation of methane on Pd-catalysts and the dehydrogenation of cyclohexanol on ZnO.

Notes: A random packing hydrodynamic simulator is designed specially to carry out experiments under reduced pressures with a counter-current flow air/water system. The simulator results (air/water system) compared to those obtained in a real packed distillation column (benzylchloride/ ethylbenzene system) show a good agreement between hydrodynamic parameters like pressure drop, flooding flow rate, and total liquid hold-up. Empirical relationships derived from the simulator experimental results are proposed allowing the calculation of the pressure drop in a packed distillation column, operating in the pressure range between 10 kPa and atmospheric pressure. The influence of reduced pressure on the HETP in the distillation column and interfacial area in the simulator was also investigated.

Notes: This paper deals with the modeling of toluene adsorption in a technical column of activated carbon in a low concentration range (2.6 to 3.4·10-3 kg/m3), which is usual for environmental applications. It is also concerned with methods of numerical solutions of the nonlinear partial differential equations (PDE), a modified control volume method was used to determine the PDE. Three nonequilibrium isotherm models are developed to describe mass transfer in a fixed bed of activated carbon (Degussa WS-4). The important parts of this paper are the simulation of the maldistribution of concentration and loading of the pollutant in the technical column, as a result of the flow velocity maldistribution and the study of the mass transfer mechanisms in a technical fixed bed. It is found that in a low concentration range, toluene adsorption in a fixed bed of activated carbon (Degussa WS-4) is an external rate-controlled process, thus surface diffusion cannot be neglected. The calculated results are in good agreement with the experimental ones. The measured effect of an earlier breakthrough near the wall-near zone has been calculated using the model.

Notes: Experiments on thermal decomposition of calcium carbonate were carried out in a thermogravimetric analyser under non-isothermal conditions of different heating rates (10 to 100°C/ min). A new technique for determining the kinetic parameters from non- isothermal thermogravimetric data was described. The activation energy and frequency factors were determined from the proposed method and also by the widely used Coats and Redfern method. The kinetic compensation effect between the activation energy and frequency factors obtained from both the methods were found to be very consistent and are in very good agreement with the literature values. The activation energy and frequency factors were also determined from isothermal experiments in the temperature range from 680 to 875°C. The activation energy and frequency factors determined from isothermal data using initial rate method were also found to be in very good agreement with the above results. It is also found that the kinetic parameters determined by isothermal analysis were consistent with the values determined by non-isothermal analysis.

Notes: Affinity separations rely on the highly specific binding between a protein in solution and an immobilized ligand to achieve a high degree of protein purification. A mathematical model including convection, diffusion, and rate kinetics is formulated to analyze the design and operation of affinity membrane bioseparation. The model equations are solved by orthogonal collocation method. Danckwerts' boundary conditions are used. The results obtained from model simulation show that the breakthrough of the protein is significantly influenced by Péclet number, feed protein concentration, Ligand number, Damköhler number, membrane thickness, and flow rate. Breakthrough profiles are quantitatively discussed in terms of protein recovery efficiency, ligand utilization efficiency, thickness of unused membrane, and width of the mass transfer zone.

Notes: In this paper the simulation of hybrid processes containing membrane units will be discussed. For this purpose a user-defined module for simulation and design of membrane processes was implemented into the simulation program AspenPlus.The advantages can be summarized as follows:-any combination of membrane processes with all other units already implemented in AspenPlus is possible, including internal recycle streams-utilization of the physical property models and data bases of AspenPlus is possible- cost and sensitivity analysis can be performed.These benefits are demonstrated in detail for a membrane vapor recovery unit for the treatment of tank farm off -gas, for a two-stage reverse osmosis plant for organic/-organic separations and for a combination of distillation and pervaporation for the separation of a dimethylcarbonate/methanol mixture.

Notes: Cross-flow filtration is a filtration process for separation of a disperse phase from liquids. Suspension flows tangentially to a membrane and the filtrate is drawn off perpendicular to the direction of flow. Formation of a filter cake on the membrane is thus prevented, reduced, or its composition, modified. The principle of the separation is based on tow opposing effects: on the one hand, the particles are transported by the filtration flux to the membrane where they cause and increase in concentration; on the other hand, concentration differences are again reduced by the turbulence of the cross-flow and by Brownian motion of the particles. The two mechanisms compete with each other and depend upon particle size in different ways. An energetic comparison of the two effects yields the separation law of cross-flow filtration as a steady state solution of the Fokker-Planck equation. The separation law has an exponential form and assigns each particle size a separation probability with which it reaches the membrane. Once on the membrane the particles may form a filter cake, flow through the pores or return to the bulk flow. If the particles remain on the membrane the ranges of layer-free and cake-forming filtration can be calculated from the hydro-dynamic and geometric conditions of the cross-flow filter. Conventional cake filtration is regarded as limiting case. In continuous cross-flow filtration process a low separation probability through the filtration pressure on selection of the filter medium resistance.

Notes: The performance of a packed-bed biological reactor has been analysed under sinusoidal variations of substrate concentration and temperature for zero-order, first-order and Michaelis-Menten kinetics. The model equations were solved by the method of orthogonal collocation. The results show that the cyclic steady-state conversion is not affected by cyclic variations in the feed concentration. However, cyclic temperature variations with an amplitude of 20°C significantly decrease the mean exit concentration for zero-order and Michaelis-Menten kinetics compared to the constant-temperature case. The approach to cyclic steady-state conditions is estimated to be somewhat flower for zero-order kinetics than for the other kinetics models investigated. We conclude that temperature variations during the day or changes in the performance of upstream plant will not adversely affect the performance of a packed-bed biological reactor.

Notes: The scale-up of benzoyl peroxide initiated copolymerisation of styrene and butyl methacrylate is studied here. The reaction is carried out in reactors of 3, 10 and 100 1 volume. Increasing the reactor size increase the weight average molecular weight and broadens the molecular weight distribution. Reducing the agitator diameter broadens the molecular weight distribution.

Notes: In this paper a novel process for biotechnological abatement of hydrogen sulphide is presented which details the fundamentals of chemical and biological phenomena involved. The process is based on the combination of two steps to form a closed cycle which has special enviornmental advantages. The chemical step corresponds to the abatement reaction itself with absorption of the gas in a ferric solution. The biological step is related to the regeneration of the absorbing solution by means of specific bacterial strains. Particular interest is devoted to the biological kinetics of the regeneration stage, where several inhibition phenomena appear, and are also related to parameters such as temperature and pH. Results of experimental runs of gas absorption in a laboratory scale plant are also described.

Notes: Suspension polymerization of styrene was performed in the loop reactor. In order to allow wide change to the polymer particle size, a sub impeller was included within the main impeller. The sub impeller served to increase the fluid velocity and to uniformly disperse the polymer droplets during polymerization.It was investigated how the double agitation method by the main and the sub impellers affected the transient droplet diameter distribution and the final particle size distribution. The particle size could be changed widely by the double agitation method without the decrease in degree of the uniformity of the particle size.

Notes: Vanillin can be produced by oxidation of kraft lignin, with air, in alkaline medium. The optimal conditions for vanillin production strongly depend on pH and temperature. This paper addresses the effect of temperature and pH on vanillin degradation by oxidation. Experiments were carried out in a wide range of vanillin concentration, oxygen partial pressure, temperature and pH. Simple models are proposed to explain the observed rate of vanillin consumption under conditions of high alkalinity (pH〉12) and lower alkalinity (pH〈12). At pH〉12,the reaction rate of vanillin oxidation is first order in dissolved oxygen concentration [O2] and in vanillin concentration [C], i.e., (-rC) ∝[O2][C]; at pH〈12, the rate is zero order in oxygen concentration and second order in vanillin concentration, i.e., (-rC)∝f(pH)[C]2.

Notes: Process energy integration and continuous improvement of process technology are everlasting issues to ensure profitability of chemical productions. And both objectives become increasingly important due to long-term environmental effects of energy degradation, such as resource depletion, emissions and the release of “waste” heat. The key success factor for process improvement lies in combining up-to-date expertise from different areas in an overall approach. One such approach is the systems engineering concept. It helps to structure and to organize problem-solving process. We strongly believe that the increasing complexity of large and interlinked chemical production system and the tightening of global economic pressure force us to use more than ever systematic analysis and design methods to guarantee optimality throughout the entire product life. First we present a brief introduction to systems engineering in general. Then, in the main part of the paper, we give examples for optimizing the use of energy in chemical plants in order to illustrate advantages of the systems engineering concept. The examples range from improving the performance of individual pieces of equipment over changes in the process structure up to optimizing process clusters.

Notes: This paper represents an attempt to explicitly map the conceptual activities which constitute a process design task into a series of well-posed, complete and general numerical procedures. In spite of the fact that there is substantial number of design manuals and design procedures which process engineers can consult to choose the most proper approach to a particular problem, there is a remarkable lack of generality on the one side (procedures which apply to the design of a wastewater treatment process cannot be used even in principle to design a fluidized bed system), and an obvious receptivity on the other side (all procedures involve mass and energy balances at some point). With the advance of numerical techniques, virtually every procedure has been computerized, so that engineers can avail themselves of a multitude of computer tools in the majority of their process design activities: as a result of the lack of coordination among different producers though, the situation for what codes are concerned is very confusing: there are many codes which perform nominally the same task, giving (sometimes substantially!) different results when applied to the very same problem; each code sue its won set of property tables, its own I/O format, etc. Finally, with very few exceptions, these codes are not mutually compatible, i.e. the output from any of them cannot be used as the input to any of the other, not only because of the respective formats, but rather because the quantities taken to represent a certain physical process are not the same in different codes.This is a very unsatisfactory state of affairs, both for the final user and for the software producer. Unfortunately, this seems to be a problem for which commercial, technical and historical reasons make it very difficult to find a solution in the short term. The author is convinced that an early exposure to this problem and to a new approach to its solution can only benefit our engineering students, and has therefore endeavored, together with his coworkers, to devise a “modular approach” to the solution of process simulation problems. The material presented here has been originated by a series of lectures and seminars developed in the last three years for master and doctoral level students in Mechanical Engineering. The result of this “distillation” process maybe yet unripe, as they are definitely not complete: but the implications, also in terms of practical application, are very promising, and the approach deserves more attention in the future.The order of presentation of the material is historical/logical: it beings with the old fashioned slide-rule calculations and proceeds towards the most recent developments of AI base methods. The path is made clear from the very beginning: we are trying to extract from the various engineering activities all the essential knowledge which pertains to the engineer himself, with the final goal of transferring this body of knowledge - in some form suitable to machine communication - to a “universal-process simulator”, which can then be applied with a high degree of confidence to variety of particular process simulations.

Notes: The Pumping characteristic of an agitator in a tube is necessary of the calculation of its pumping capacity in configuration in the vessel with a draught tube. The general dimensionless equation of the pumping characteristic suitable for the higher Reynolds number region was derived by inspection analysis of basic equations. The new dynamic experimental method for determination of pumping characteristics is put forward. The application of this method is illustrated on a special three-blade axial-flow impeller.

Notes: A nonlinear unsteady state optimal control problem for a classical, constant diameter ethane thermal cracking reactor is formulated and solved. The process is represented by a pseudo steady state mathematical model, consisting of mass and heat balance, pressure drop, and coking equations. The performance index is of an economical nature, representing the global benefit of reactor operation over a constant operating time. As control variables, the space and time dependent skin tube temperature, the time dependent steam to hydrocarbon ratio, and the time dependent feed flow rate were considered. The results are in agreement with the process physicochemical and technological fundamentals.

Notes: The results of simulations of direct concentration control of a distillation column in industrial scale are presented. Both controlled variables, the two product concentrations, are determined by on-line gas chromatographs and are characterised by high dead times of about 30 min. For the resulting scanning control of the product concentrations corresponding decentralised PI controllers were developed and applied. The control of the product concentrations developed presents a conventional DV structure and was exemplarily tested for disturbances in feed flow and feed concentrations. The calculations carried out exhibit a good time behaviour of the whole system. On this occasion it can be stated that the control quality could be clearly improved if a steady-state decoupling by output transformation was employed. In this case the results achieved are totally comparable to those of internal model control (IMC), which was in use at the production plant for over two years.

Notes: This article presents gas kinetic calculation methods for the energy transport in hydrogen/ air and methane/ air mixture. The total molecular heat conductivity as well as its various shares are calculated and discussed for a temperature range of 400 to 3500 K and for a pressure of 105 Pa. The variation of the air/ fuel ratio under the conditions of chemical equilibrium is also investigated. As opposed to our previous article, an extension of the Chapman-Knskog method which goes beyond the classical 1st approximation for elastic collisions is applied for the evaluation of suitable calculation methods. This is carried out following the method for strong relaxing thermal nonequilibrium according to Brun. The equations applied in this work are simplified formulations for the proximity to equilibrium. The method for the evaluation of the parameters of the inelastic collision and some chosen results are presented. A discussion of the various shares of the molecular heat conductivity emphasizes the considerable influence of the diffusion and the thermal diffusion processes in fuel/ air mixtures compared to the Fourier heat conductivity.

Notes: The present paper deals with a novel hydrogen sulphide abatement process applying a combined chemical-biological process. The authors already dealt with this subject in the paper “Biotechnological H2S gas treatment with Thiobacillus ferrooxidans” [1], previously published in Chemical Engineering and Technology. This study, in particular, deals with over all process test runs in a laboratory scale plant with a single-stage immobilised biomass reactor.

Notes: A dynamic model incorporating biomass growth and liquid hold-up evolution is developed to describe a fixed bed bioreactor operation with cocurrent upflow of water and air flows. The model permits to predict cycle time and optimal operation conditions for high substrate removal and long cycle times. Simulation results are compared with published experimental results and show good model accuracy.

Notes: A new continuous-flow recycle microwave reactor suitable for organic synthesis has been developed to handle 0.51 quantities of reagents. The apparatus, which is designed for laboratory use, operates at atmospheric pressure in open- or closed-loop mode. It is fitted with a temperature control system. We describe this novel reactor and illustrate its efficiency with examples of organic syntheses carried out using both homogeneous and heterogeneous reactions.

Notes: A novel expert-system-based method for selection of sensors for process variables is presented. EXSENSEL (expert system based sensor selection) deals with 12 process variables and currently has 94 rules in its knowledge base. Despite its large knowledge base, users have to answer a set of only a few questions regarding a particular process variable, which is selected from a menu of 12 variables. A general description of the chosen process variable can be viewed before invoking the rules. Once a sensor has been selected, a brief write up on that particular sensor is also available on user's request. EXSENSEL is the successor to TRANSELEX, which is a single expert system for selection of transducers in the area of temperature, pressure, and flow measurement.

Notes: The interfacial tension of the binary system α-tocopherol/carbon dioxide was measured using the pendant drop method in the pressure range between 10 and 37 MPa at nine different temperatures: 313, 333, 343, 353, 363, 373, 383, 393, and 402 K. At every interfacial tension measurement, densities of both the liquid and the supercritical gas phase were also determined as the knowledge of these values is essential for calculating interfacial tension from the shape and size of drops. The interfacial tension decrease with rising pressure at a constant temperature and increases with increasing temperature at a constant pressure. The interfacial tension was found to be mainly a function of the mutual solubility of the two system components and of the density of pure carbon dioxide.

Notes: Distillation is a unit operation in which two main processes are involved: heat transfer for vaporizing and condensing and mass transfer for the separation of the mixture. A distillation unit can be described as an exergy converter: that is a unit which converts thermal exergy into chemical exergy. To obtain a complete graphical representation of mass, enthalpy and exergy balances in a fractional distillation, we propose the use of a diagram: the specific enthalpy (in KJ/ Kg of mixture) is plotted against the Carnot factor θ to show the heat and mass transfer effects simultaneously. The application of the methodology to the distillation of an ammonia-water mixture is presented. Conventional fractional distillation consumes a lot of exergy. We propose a new type of distillation in which the reboiler and the condenser normally located at the bottom and at the top of distillation column, are replaced by two heat exchangers integrated in the column itself. The exchanger integrated in the bottom of the column inputs heat to the column, and the other exchanger located in the upper part of the column removes heat. This arrangement minimizes the creation of entropy in the column and therefore maximizes the exegetic effectiveness. This new process, called:“diabatic” or “quasi-reversible” distillation should bring important improvement to conventional distillation, not only from the point of view of energy use (large reduction in the consumption of heat carriers fluids for heating and cooling), but also in terms of capital investment as the cost of fitting a heat exchanger in the destillation column will probably be less than the cost of reboiler or condenser and reflux head.

Notes: In the Chemical and Process Industry, liquid streams having a variable concentration solids are not uncommon. The hydrocyclone has been found to be a useful unit for the removal of particulate matter from these streams. The function of a hydrocyclone gets disturbed by an increase in the solid load concentration beyond a specified limit, and it may even overload the underflow opening. A variation of the solid load calls for a change in the split ratio of the hydrocyclone, which in turn requires an adjustment to the diameter of the underflow opening. A new technique has been developed which can automatically adjust to the change in the solid load without changing the underflow opening diameter. The split ration of a hydrocyclone can be changed by varying the pneumatic injection rate at the hydrocyclone's axis. Experiments were conducted using three geometrically similar hydrocyclones, and equations have been evolved to size the underflow opening.

Notes: In order to influence the habit of barite (BaSO4) single crystals obtained by precipitation, the tailor-made additives 2-aminomethanol, 3-aminoproponal, 5-aminopentanol, 4-aminobutane sulfonic acid, and several other growth inhibitors have been tested. The crystallization experiments have been carried out in a fully automated crystallizer with reproducible educt feed rates. The kinetics of the reaction has been measured by means of the conductivity. Scanning electron microscopic analysis of the obtained crystal habits led to the raesult that most of the additives tested did not influence the growth form of the crystals, but the predicted, tailor-made additives resulted in a more isometric crystal form.

Notes: Coherent transmission and reflection of a plane wave through a monolayer of discrete particles are considered on the basis of simple and physically transparent formulae for the single scattering approximation (SSA) corrected by introducing a multiple scattering permittivity factor. This factor allows for multiple scattering of Waves between monolayer particles, opposite to the SSA. The multiple scattering permittivity factor is considered on the basis of the quasi-crystalline approximation (QCA) via Ť matrix formalism. The multiple scattering permittivity factor and parameters for obtaining coherent transmission and reflection coefficients (the effective extinction coefficient and the transmission and reflection coefficients due to rescattering) are calculated within the scope of QCA and plotted for comparison with SSA results. The expressions for these values are simplified for small Rayleigh particles to simple analytical formulae.

Notes: The light scattering technique is now widely used in particle sizing, and includes the turbidimetric spectrum method. Although it has been reported that the light scattering technique, especially the turbidimetric method, is sensitive to refractive index, quantitative studies are rare. In this work, the effects of refractive index on the turbidimetric spectrum method were comprehensively investigated and detailed results are presented.

Notes: This paper describes a study to determine the most appropriate particle size parameter for polydisperse powders dispersed as aerosol and detected by light scattering. It is relevant to many areas of engineering research. By means of calculations of the intensity of light scattered from particles of different sizes, it has been shown that the surface median aerodynamic diameter (SMAD) is an appropriate measure for polydisperse aerosolised powders. The microscope-based procedure for obtaining the SMAD is described, as well as its implementation for narrowly-graded polydisperse powders of fused alumina of type which have been widely used in studies of particle transport in wind tunnels. It was shown that for the fused alumina powders examined, SMAD = 1.25 x (PASMAD), where PASMAD is the projected area surface median aerodynamic diameter.

Notes: Computer simulations of diffusion-limited aggregation (DLA) for monomers to investigate the effects of size and of lognormal distribution on the fractal dimensionality of the aggregates were conducted on a two-dimensional lattice. The results show the DLA clusters posses multifractal characteristics. For clusters consisting of monodisperse monomers, the bifurcation point on the graph of the pair correlation function (PCF) for each cluster is located right at the monomers size under investigation The textural dimension (Df1) has a stable value of about 1.65, whereas the structural dimension (Df2) decreased with increase in monomer size. For the cases with monomers in log-normal distributions, the textural dimension is around 1.67; however, the structural dimension decreases with increasing polydispersity of monomer size.

Notes: A series of industrial powders, most of them organic, were characterized in terms of volumetric mean size, size distribution, density, particle shape, water rentention characteristics (under a series of controlled ambient relative humidities) and loosely packed and densely packed voidages (giving the compressibility). The behaviour of the powders in powder handling apparatus (a precision powder filler) was also determined. The minimum and maximum bulk densities of the powders were related to the properties of the individual particles by means of a semi-empirical equation. The filling capacity of the powder handling apparatus was found to be related to the maximum bulk density of the powder while the filling accuracy turned out to be related to the compressibility of the powder. Knowing these interrelations made it possible to predict the powder behaviour in the handling apparatus directly on basis of the particle properties.

Notes: Fiber optic dynamic light scattering (FODLS) was used to study the kinetics of aging processes in emulsions of n-alkanes stabilized by a surfactant. The method is particularly useful for this purpose because it permits measurements in concentrated emulsions. Complications that may occur in traditional DLS due to the extreme dilution, such as solubilization of the particles in the medium, can be easily avoided in this way. The experimental results show that the main aging process is Ostwald ripening. The results are in agreement with theoretical predictions based on the Lifshitz-Slyozov-Wagner (LSW) theory as far as it concerns the relation between the molecular solubility of the n-alkanes (in the aqueous phase) and the Ostwald ripening rate. This illustrates that the main rate-determining factor is the molecular diffusion of the alkane molecules through the continuous (aqueous) phase. The Ostwald ripening rate is affected by the concentration of surfactant but in all situations is higher than expected from LSW theory.

Notes: Designing modern devices for bulk solids storage and handling requires an increasingly complex understanding of the handled bulk solids' mechanical behaviour. Models able to describe the behaviour of bulk solids can neither be formulated nor their parameters determined from common shear tests, since these do not contain sufficient information especially about the materials' stiffness characteristics. The paper describes the response envelope as a measure of the deformation resistance and its experimental determination from biaxial tests. It is shown that for fine limestone powder the stiffness in compression is only about 1/70 of the stiffness in expansion. The shape of the response envelope depends only on the ratio between the principal stresses at the stress state considered, whereas the size of the response envelope also depends on the stress magnitude.

Notes: This paper reports an experimental study on the stability, coagulation and diffusion of molecular clusters and ultrafine particles generated from organic vapors by corona ionizers. Upon leaving the ionizer, particles are made to flow within several types of vessels: depending on the specific geometry of the flow system, clusters either coagulate into large particles or are deposited on the walls. Particles larger than 4nm and molecular clusters penetrate through a wire-screen type diffusion battery, but particles in the size range between 2 and 4nm are collected. Among the organic compounds tested (aromatics, alcohols, ketones and others), only aromatic compounds appear to yield unstable clusters which grow into detectable particles (〉2nm) through Brownian coagulation. The other compounds either do not undergo the gas-to-particle conversion process or are too small to be detected. Furthermore, the presence of moisture seems to be of fundamental importance in the particle generation phenomenon. The addition of alcohols to the vapor mixture inhibits particle formation.