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  • 1965-1969  (1,504)
  • Chemical Engineering  (1,448)
  • Physical Chemistry  (56)
  • 101
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 463-465 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 102
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 469-470 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 103
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 471-472 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 104
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 504-507 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Numerical solutions of the equations of motion and energy are presented in the form of pressure-loss, flow-rate relationships for the laminar, nonisothermal flow of Newtonian and non-Newtonian fluids being heated and cooled in tubes at constant wall temperature. The flow properties are represented by a temperature-dependent form of the power law equation. The numerical results are shown to be in good agreement with experimental data for a wide range of fluid properties and flow conditions.
    Additional Material: 5 Ill.
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  • 105
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 581-585 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer and pressure-drop studies were made on a series of electrically heated tubes containing full-diameter, full-length twisted tapes. The A nickel tubes had a nominal inside diameter of 0.4 in. (10.1 mm.) and a heated length of 12 in. (30.5 mm.). Nitrogen at 200 lb./sq.in. gauge (14.6 atm.) was the working fluid, and the tests covered the Reynolds number range from 20,000 to 200,000. Twist ratios, defined as the ratio of the tube length per 180 deg. twist to the tube diameter, were varied from 2.5 to 14. The effect of tube wall-to-gas temperature ratio was studied for values of up to 1.8 and the heat flux was varied from 104 to 105 B.t.u./hr. · sq.ft. (3 × 104 to 3 × 105 w./sq.m.).The results were compared with the results of previous heat transfer and pressure-drop studies and were generally found to be in good agreement. An empirical correlation was developed for the heat transfer results that accounts for the effects of twist ratio, wall-to-gas temperature ratio, and tube length and includes most of the previous single-phase results.
    Additional Material: 5 Ill.
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  • 106
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 575-580 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple means for predicting composition distributions in copolymers is used to illustrate the strong influence of segregation effects in the reactor. A recycle loop reactor can be used to produce uniform copolymers by narrowing the macroscopic composition distribution, but there is a limiting microscopic distribution which results from probabilistic effects.
    Additional Material: 9 Ill.
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  • 107
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 454-459 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The onset of rotational flow instability was determined experimentally for dilute solutions of six polymers. In general, the onset of secondary motions occurred later than for a Newtonian liquid of equal apparent viscosity, although, depending upon geometric ratios, some instabilities occurred earlier than in the Newtonian liquid. The stability theory of Ginn and Denn was used to calculate viscometric normal stress functions for ten solutions, with excellent agreement obtained with rheogoniometric measurements of the primary normal stress measurements in all but three cases. Torque measurements of the laminar secondary motion following instability showed some frictional drags significantly less than those observed in Newtonian liquids, a phenomenon analogous to the turbulent drag reduction observed previously in dilute polymer solutions.
    Additional Material: 8 Ill.
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  • 108
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 642-793 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
    Type of Medium: Electronic Resource
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  • 109
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 660-665 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Manning, Wolf, and Keairns' model for continuous flow-stirred tank reactors has been extended to include adiabatic as well as isothermal operation. The adiabatic, steady state yield of a continuous flow-stirred tank reactor was measured experimentally using the second-order, homogeneous, exothermic reaction between sodium thiosulfate and hydrogen peroxide. Model predictions of overall tank yield agreed closely with the data, thus verifying the applicability of this model to explain the effects of operating variables such as impeller size, impeller type, agitator speed, feed location, feed concentration, and flow rates.
    Additional Material: 8 Ill.
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  • 110
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 680-685 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The mechanism of solid state polycondensation has been subjected to a fundamental analysis. Equations were formulated for combined diffusion and chemical reaction for two separate situations. One was for solid state polycondensation in polymer flakes or chips. The other dealt with polymer powders. The resultant solutions related molecular weight changes to rate functions. A technique for deriving the rate functions from experimental data is described.Solid state polycondensations were then studied for nylon 66, nylon 6-10, and polyethylene terephthalate. These data which ranged from 120 to 200°C. were tested with various mechanisms. The most appropriate one was found to be that developed in the present work. Chemical reaction was found to be the rate controlling step in solid state polycondensation in nylon 66, polyethylene terephthalate, powders of nylon 6-10 and larger particles of nylon 6-10 at and above 160°C. Diffusion of byproduct through the solid was the rate controlling step for larger particles of nylon 6-10 at temperatures below 160°C. Thermograms of nylon 6-10 indicated morphological changes which possibly influenced the behavior of the larger nylon 6-10 particles. The Arrhenius relation was fitted to the situations where chemical reaction controlled.
    Additional Material: 11 Ill.
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  • 111
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 686-689 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The structure of thin circular films, formed over a flat water surface during the dissolving (influenced by surface forces) of isobutanol, is examined by performing film thickness and surface velocity measurements. The thicknesses were obtained by light absorption determinations, and the velocities by a stroboscopic method. The film profiles and the dynamic wetting angles obtained differ markedly from those corresponding to a static lens. This is explained by considering the equilibrium between dynamic surface tensions instead of that between static surface tensions.
    Additional Material: 7 Ill.
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  • 112
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 837-842 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The phenomenon of reversing axial flow in swirling incompressible flow through a tube has been investigated experimentally. The study was carried out in a 2 in. I.D. test section of plexiglass tubing 10 ft. long. The swirl was introduced by injection of the total fluid stream through two symmetric tangential inlets perpendicular to the tube. Measurements have been made with specially constructed stagnation and static pressure probes.Velocity and pressure profiles obtained for tests conducted at four Reynold's Numbers in one fixed geometrical configuration are presented and discussed in general terms. Swirl decay rate is characterized in a plot of weighted tangential velocity/inlet velocity ratio versus distance along the test section from the inlets. A model presented by a previous investigator to explain the flow reversal phenomenon is discussed in the light of present work. Finally the data is used in an order of magnitude analysis to reduce the turbulent Navier-Stokes equation describing the flow to simpler (though still indeterminate) form.
    Additional Material: 10 Ill.
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  • 113
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 872-884 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of natural convection on polarization and flow patterns in liquid phase convective diffusion in a vertical duct with semipermeable membrane walls has been investigated theoretically. It is found that at low flow rates, gravitational fields can play a significant role in distorting the velocity profiles and thereby they affect the transition from laminar to turbulent flow. Natural convection also significantly affects mass transfer rates and therefore the extent of polarization at low flow rates. Results are presented for both momentum and mass transfer in upward and downward flows for different wall Peclet numbers. The hydrodynamic stability of the system also has been investigated and critical values of the buoyancy parameters are reported. Also, these results enable one to estimate when natural convection may create errors in membrane testing systems.The analysis and results are of practical interest in reverse osmosis and other membrane separation processes. The more productive the system, the more likely it will be that buoyancy effects are important.
    Additional Material: 21 Ill.
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  • 114
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 890-897 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data are presented for wall temperatures and heat transfer coefficients for solid-vapor mixtures of parahydrogen and nitrogen flowing in an electrically heated straight tube of length 40 times its diameter. These are interpreted by the application of flat plate, constant property boundary-layer theory to models in which the solid particle geometrical distribution takes on simple limiting forms. The observed enhancement of the heat transfer coefficient over that for gas alone traveling at the same velocity is qualitatively predicted as a function of a dimensionless heat flux, the Sterman parameter qw/ρvUλ.
    Additional Material: 10 Ill.
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  • 115
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 902-910 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Positive feedback control systems sometimes can be used to make stable chemical reactors generate periodic outputs. For one set of system parameters the time average conversion obtained from the oscillating reactor was approximately 20% higher than the economic optimum steady state value; for another case the time average operating cost was approximately 5% lower than that corresponding to the optimum steady state design. A general method for predicting when an improvement can be obtained is presented.
    Additional Material: 5 Ill.
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  • 116
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 932-933 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
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  • 117
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 950-951 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
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  • 118
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 942-947 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
    Additional Material: 7 Ill.
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  • 119
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 51-56 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A knowledge of liquid-film flow rates is important for design purposes when accurate predictions are required of the conditions under which dryout heat flux occurs in nuclear reactors and boilers. Liquid-film flow rates were measured for a steam-water mixture in cocurrent, upward annular flow in a tube at a pressure of 1,000 lb./sq.in.abs. Sinters located at the test section exit were used to extract the liquid film after the method of the Harwell group. Sinter lengths of 2, 1, and 1/2 in. were employed to investigate the effect of length on the extracted liquid flow rates. The test section was a stainless steel pipe of inside diameter 0.493 in., approximately 200 diam. in length. The total mass flux ranged from 0.2 to 0.7 × 106 lb.m/hr.sq.ft. and the quality varied from 0.3 to 0.92.The experimental film flow rates were found to increase with decreasing quality. In the range of parameters investigated, the curves of film flow rate at constant quality vs. mass flux showed a maximum at a fixed value of steam velocity. At the same total mass flux and quality the film flow from the 1/2 in. sinter was lowest, suggesting that the crests of high amplitude roll waves overshot the sinter. Film flow rates were consistently higher than the theoretical predictions using Levy/s model. About one-third of the measured flow rates were twice as high as predicted.
    Additional Material: 10 Ill.
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  • 120
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 73-80 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data are presented on the solubility in and permeation through polyolefin films of a number of gases and liquids. The permeation rates are found to be dependent on the type of film, the concentration and the temperature. A classical diffusion model explains the permeation mechanism and other relations serve to correlate the data.
    Additional Material: 16 Ill.
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  • 121
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 141-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 122
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 151-153 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 123
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 124
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 164-170 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical study has been made on the effect of pulsations in the flow field on interphase mass transfer. The phenomenon is of interest in studies of the cardiovascular system as well as in traditional engineering applications. The physical situation studied corresponds to fully developed flow in a long conduit with a periodic pressure gradient. The mass transfer problem was solved analytically for low amplitude pulsations for the two limiting cases of very small and very large frequencies. In addition, several numerical solutions were developed in the intermediate region where the asymptotic solutions are least accurate. The solutions taken together give a good quantitative overall view of the phenomenon.One of the most interesting and unexpected results is that at very low frequencies it is possible for a pulsatile flow to yield a lower interphase mass flux than a steady Poiseuille flow with the same velocity.
    Additional Material: 7 Ill.
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  • 125
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Calculations of the molar heat and entropy of adsorption for pure methane and pure ethane on silica gel at 25°C. show the heterogeneity of the adsorbent when plotted as functions of the spreading pressure. Plots are given for the activity coefficient of methane and ethane in the adsorbed phase based on experimental data for the entire range of compositions at 25°C. up to a maximum pressure of 1,400 lb./sq.in.abs. Similar results were obtained at 5, 15, and 35°C. The activity coefficients deviate from unity at intermediate compositions.
    Additional Material: 6 Ill.
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  • 126
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 235-239 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The nonuniform distribution of vapor across a distillation plate causes a reduction in the Murphree plate efficiency. The magnitude of the reduction has been evaluated and the maximum effect occurs when the liquid mixing is intermediate between the perfectly mixed and the plug flow cases.
    Additional Material: 11 Ill.
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  • 127
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 269-271 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The free volume equation for liquid viscosities is generalized to multicomponent mixtures. No experimental mixture data are needed in order to use the correlation. Calculated viscosities for liquid mixtures composed of molecules which approximately obey the Lennard-Jones 6, 12 potential law show very good agreement with experimental data for eight binary systems.
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  • 128
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 289-290 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 129
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 128-131 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 130
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 137-141 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 131
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 132
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 133
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 184-189 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Drag coefficients of aerodynamically smooth spheres varying in diameter from 0.0625 to 1.004 in. and in density from 0.195 to 7.80 g./cc. were obtained at acceleration rates ranging from 120 to -30 ft./sq.sec. The particles were subjected to relative turbulence intensities of 7 to 35% and to ratios of Eulerian macroscale to particle diameter of about 0.4 to 5.Quantitative measurement of particle drag coefficients was made possible by the use of a new particle tracing technique which permits the resolution of time to the nearest tenth of a millisecond. The resulting data extend farther into the supercritical flow regime than any other measurements previously reported.The variation in drag coefficient with Reynolds number indicates a continuous alteration in the flow pattern around a sphere in this region. The effect of turbulence is, essentially, to increase supercritical drag, although this effect was found to diminish with increasing Reynolds number. Possible mechanisms for the effects of Reynolds number and turbulence on the particle drag coefficient are suggested.
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  • 134
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    AIChE Journal 15 (1969), S. 383-386 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The breakup of a low speed horizontal jet is investigated. Weber's theory for the Newtonian jet is extended to a linear viscoelastic fluid. The theory predicts a dependence of breakup length on the elasticity number. Breakup lengths are measured for low concentration solutions of polyisobutylene in tetralin. Two molecular weights, several concentrations, and five capillary diameters were studied. A single correlation is obtained for all data which gives the breakup length as a function of the elasticity number, and the parameters of Weber's theory. At constant values of the Ohnesorge number and Weber number, the breakup length decreases with increasing elasticity number. The effect of the length of the capillary is studied. At large elasticity numbers short tubes give rise to slightly shorter breakup lengths than long tubes under identical flow conditions.
    Additional Material: 5 Ill.
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  • 135
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 226-234 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The hydrogenation of alpha-methylstyrene to cumene at 20 to 50°C. was studied experimentally with a trickle-bed reactor comprising a single vertical column of spherical porous palladium-on-alumina catalyst pellets. Other studies with powdered catalyst and studies in which catalyst pellets were swirled in a reactor allowed the intrinsic kinetics and effectiveness factor of the catalyst pellets to be determined. At 50°C. the reaction rate in the trickle-bed was about one-half of that in the absence of mass transfer limitations in the outside liquid film. The effectiveness factor of the pellets alone at 50°C. was 0.0057, and the tortuosity factor was 7.5. Experimental results are compared with four theoretical models for tricklebed reactors and criteria are presented for estimating whether mass transfer through the outside film is a significant resistance in an industrial trickle-bed reactor.
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  • 136
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 250-256 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Entrance region and fully developed mass transfer from the inner core of annuli was investigated for a fully developed velocity profile and a Schmidt number of 760. Constant wall concentration was the satisfied boundary condition of the inner core.The ranges of parameters investigated were 21,400 to 75,600 for Reynolds number, 0.164 to 0.741 for the annulus diameter ratio, and 0.018 to 3.85 for the length to hydraulic diameter ratios.Experiments were performed in an open water flow loop. Mass transfer coefficients were obtained from weight loss measurements of benzoic acid life saver elements of various diameters and lengths. These elements were assembled as an integral part of the inner core of the annulus. Concentricity was maintained by a tensioning device.The local Sherwood number is found to be significantly affected by the annulus diameter ratio, Reynolds number, and the length to hydraulic diameter ratio. A correlation is developed which predicts 93% of the data used for its development to within ± 10%.
    Additional Material: 11 Ill.
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  • 137
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    AIChE Journal 15 (1969), S. 305-306 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 138
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    AIChE Journal 15 (1969), S. 450-454 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The onset of secondary motions between rotating concentric cylinders is related to the viscometric normal stress functions for a class of viscoelastic liquids which includes dilute polymer solutions. Both increased and decreased stability relative to a corresponding Newtonian liquid are possible for a given material, depending upon the particular relation between the viscometric functions and the geometric constants of the equipment. This predicted behavior is in agreement with experimental observations.
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  • 139
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    AIChE Journal 15 (1969), S. 461-462 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Tab.
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  • 140
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 141
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    AIChE Journal 15 (1969), S. 489-494 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Analytic equations describing cyclic steady state diffusion in which the diffusivity depends on the direction of transfer, as well as on the system, have been obtained.By imposing the cyclic steady state constraint, of periodically repetitive concentration profiles, simultaneous solution of separate Fick's diffusion equations for the on-off segments of the cycle results in the desired equatins. The method of solution can be extended to more complex diffusion problems, such as coupled diffusion processes. Shallow bed experiments have been performed on particle-diffusion controlled, cyclic steady state ion exchange. Agreement between the predicted and experimental transfer was obtained. Variables and parameters affecting cyclic steady state diffusion are discussed.
    Additional Material: 4 Ill.
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  • 142
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    AIChE Journal 15 (1969), S. 564-567 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Drag reduction data for five concentrations of a water-soluble polymer and three tube diameters are presented. The data are correlated by a single curve relating two dimensionless parameters; these have been obtained from a phenomenological analysis of the mechanism of drag reduction.
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  • 143
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    AIChE Journal 15 (1969), S. 619-623 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 144
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    AIChE Journal 15 (1969), S. 627-630 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 145
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    AIChE Journal 15 (1969), S. 793-794 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
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  • 146
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    AIChE Journal 15 (1969), S. 654-659 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas absorption, pressure drop, liquid holdup, and loading behavior in a packed column have been investigated using packing materials almost geometrically identical but fabricated from three different materials (ceramics, Saran, and polyethylene). For the absorption of oxygen into sodium sulfite solution, observed values of the liquid-side, composite, overall mass transfer coefficient, KLa, were about 25% larger for the ceramic packing than for the polymeric packings. It was also observed that liquid loading occurs more readily in the case of the polymeric packing materials and it appears that the usual type of correlation is inadequate for predicting loading when polymeric packings are employed. In the case of liquid operating holdup no differences were observed from packing to packing. These observations are discussed in terms of the nature of the interaction between liquid and packing surface and it is pointed out how these phenomena may be fundamentally different from those of previous investigations, which relied upon surface-active agents added to the liquid.
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  • 147
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    AIChE Journal 15 (1969), S. 715-718 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical equation was developed to predict the enrichment produced by a single stage porous Vycor diffusion cell as a function of temperature. The separations of five binary gas mixtures were measured experimentally over a temperature range of 80 to 600°K. The agreement between theoretical predictions and experimental results was good over most of the temperature range. The largest deviations occurred when the operating temperature approached the critical temperatures of the gases. Mixtures of oxygen-carbon dioxide and helium-nitrogen were observed to become nonseparative at predicted temperatures. Overall, both separation and separative capacity were observed to increase with a decrease in temperature.
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  • 148
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    AIChE Journal 15 (1969), S. 735-744 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is presented to account for reduced mass transfer to drops falling through a continuous phase which contains a surface active agent. The fluid flow patterns are essentially laminar. The reduction in mass transfer is said to be due to a reduction in available interfacial transfer area and to changes in both velocity and pattern of internal circulation. These are shown to be functions of contact time and can be characterized. Experimental values agreed with the theoretically predicted ones with a deviation of less than 10%.
    Additional Material: 10 Ill.
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  • 149
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    AIChE Journal 15 (1969), S. 745-749 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theory has been developed for heat or mass transfer between phases which may have unsteady time dependent velocity fields. The configuration analyzed involves two concentric tubes, but the analysis can be extended to more than two phases, or streams, and to noncylindrical cross sections. For the configuration considered, the dispersion coefficient is found from first principles.It is noteworthy that the dispersion model given by Equation (15) or (63) and (64), which is consistent with the basic continuum model of Equations (8) and (9), is based on the superficial velocity rather than the interstitial velocity. This strongly suggests that experimental observations on packed beds, or other multiphase systems, should be interpreted on the basis of um, the superficial velocity, rather than the interstitial velocity which has been used often in the past.
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  • 150
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    AIChE Journal 15 (1969), S. 782-784 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
    Additional Material: 3 Ill.
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  • 151
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    AIChE Journal 15 (1969), S. 786-790 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
    Additional Material: 4 Ill.
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  • 152
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    AIChE Journal 15 (1969), S. 802-802 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
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  • 153
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    AIChE Journal 15 (1969), S. 823-828 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general numerical-analysis procedure is presented for the screw extrusion of a non-Newtonian material. The full Navier-Stokes energy and continuity equations are used in the numerical procedure. The flow is taken as steady and incompressible, and the viscosity is written according to the Ostwald-de Waele model in which the viscosity is assumed to be inversely proportional to the square root of the second invariant of the rate of deformation tensor and exponentially dependent on the temperature.The procedure allows the prediction of vorticity, stream-function, swirl velocity, internal energy, and viscosity over any cross section of a groove containing plastic. Calculations for the mass extrusion rate and power consumption (shear rate) for the screw extruder are also given. Typical cases are considered for which all the quantities listed above are determined. The results compare favorably with other theoretical work.
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  • 154
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    AIChE Journal 15 (1969), S. 624-626 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 155
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    AIChE Journal 15 (1969) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 156
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    AIChE Journal 15 (1969), S. 941-942 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
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  • 157
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    AIChE Journal 15 (1969), S. 689-699 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The stability theory is used to predict jet length from jet inception to disruption for injection of one Newtonian liquid into a second immiscible Newtonian liquid. Knowledge of the length is essential for predicting the size of drops formed from jets. At low velocities jet length is controlled by the amplification of symmetrical waves which travel at the interfacial velocity of the jet. At higher velocities an abrupt lengthening of the jet may occur as a result of drop merging, and the jet length is then controlled by the growth rate of sinuous waves which are strongly velocity dependent. Jet disruption results from a geometrical limitation on the maximum amplitude of the sinuous waves. Predictions show good quantitative agreement with experimental data for thirteen mutually saturated systems over a wide range of variables and qualitative agreement with limited experimental data on the effects of initial disturbance level and mass transfer.
    Additional Material: 6 Ill.
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  • 158
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    AIChE Journal 15 (1969), S. 719-726 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method utilizing a diffusion controlled electrochemical reaction was used to measure average and instantaneous mass transfer coefficients at the solid-liquid interface in upward gasliquid climbing film flow in a vertical annular duct. These measurements give some indication of the mechanics of flow of the film, the extent of turbulence at the inner wall, and the effect of film thickness and wave motion on the mass transfer process at the inner wall. Predictions of incipient downflow of the film, shear stress at the inner wall, and interfacial shear stress were obtained from these measurements. Fluctuations in the velocity gradient at the inner wall were also studied. Results of this study are in good agreement with previous work and with theoretical predictions based on simplified momentum balance concepts.
    Additional Material: 13 Ill.
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  • 159
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    AIChE Journal 15 (1969), S. 772-779 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The design of an experimental cocurrent spray dryer and its method of operation are described. The rationale for the development of some new measurement techniques and modifications to existing ones is discussed. These techniques were used to obtain profiles at several dryer levels of the air velocity, air humidity, and spray mass velocity for the case of a 30% sodium nitrate solution sprayed into 100°C. air. Somewhat less detailed measurements of the spray moisture and radial turbulent diffusivity were also made.The humidity and spray moisture measurements gave very nearly identical results for the progress of the evaporation along the length of the dryer. The axial injection of the spray was found to result in steep gradients for the air velocity, air humidity, and salt mass velocity but these were found to decay under the influence of turbulent mixing which is also generated by the spray injection.
    Additional Material: 11 Ill.
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  • 160
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    AIChE Journal 15 (1969), S. 764-771 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A step-by-step prediction procedure has been developed to predict the evaporation of a sodium nitrate spray consisting of small drops moving at terminal velocity through the drying air. The procedure accounts both for the existence of radial gradients as well as radial mixing in the dryer and is selfsustaining except for values of the local air velocity.Because the procedure can be applied only to the free-fall zone, at some distance below the nozzle, a method was developed for the indirect determination of the amount of water remaining in the partly evaporated droplets at the beginning of the free-fall zone. This procedure was then applied to experimental data on drop size distributions obtained at the beginning of this zone. Owing to uncertainties concerning the salt concentration in the drops, a number of assumptions had to be made and the procedure was only partially successful in describing the spray evaporation, although it did compute the radial spray transfer. It was possible, however, to indicate by means of a model drop distribution the general validity of the procedure.
    Additional Material: 7 Ill.
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  • 161
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    AIChE Journal 15 (1969), S. 948-960 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
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  • 162
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The mechanism by which oxygen is transported from capillaries into tissue for cell respiration has been a subject of interest since the work of August Krogh in 1919. Mathematical analyses of the diffusion process have been obtained by several investigators (11, 12, 18), but are limited in scope by the complicated nature of the problem. However, the solutions that exist give enough insight to inspire a more rigorous treatment. With the advant of electronic computers more complete analyses are now within reach (16).The human brain accounts for less than 4% of the total body weight, yet it uses 15 to 20% of the total body oxygen consumption. This high metabolic rate makes the brain particularly vulnerable to any change in the normal oxygen supply. The fact that following a cessation of cerebral blood flow, unconsciousness develops within 10 sec., and irreversible damage within 10 min., demonstrates the importance of understanding the dynamics of oxygen supply to the brain.
    Additional Material: 12 Ill.
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  • 163
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    AIChE Journal 15 (1969), S. 3-3 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 164
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    AIChE Journal 15 (1969), S. 10-17 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The use of heuristic structuring strategies in the development of computer programs for the synthesis of process designs is examined. By the employment of selection weights which are adjusted as experience is gained from past successes and failures, the computer is able to learn the sequence of structuring decisions which leads toward the optimal process design. The computer can develop competence in the synthesis of systems in a limited area of technology.
    Additional Material: 8 Ill.
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  • 165
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    AIChE Journal 15 (1969), S. 85-88 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized drying program that can simulate any drying conditions has been solved on a computer. The program includes the variation of humidity, temperature, and wind velocity over drying material. These three variables can be treated as functions of time. The correlations require knowledge of several basic properties of the material to be dried and were solved for the case of one directional heat and mass flow.The computer calculated results are checked with experimental data. The effective diffusivity and the solid surface resistance to mass transfer were evaluated by data obtained in three experiments.Solutions for constant drying conditions are presented in graphical form. Variations of such variables as humidity in a drier can be estimated from these curves but the computer program is more reliable.
    Additional Material: 7 Ill.
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  • 166
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    AIChE Journal 15 (1969), S. 111-116 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new throttling flow calorimeter has been incorporated into the recycle facility of the Thermal Properties Laboratory. Energy is added to the expanding gas while it flows through a stainless steel capillary tubing from an insulated resistance wire located inside the entire length of the capillary. The calorimeter is designed to operate at pressures up to 2,000 lb./sq.in.abs. in the temperature range from -240 to +250°F.Data on the isothermal effect of pressure on enthalpy for a mixture containing 5 mole % propane in methane are presented and compared with data from the literature.
    Additional Material: 5 Ill.
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  • 167
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    AIChE Journal 15 (1969), S. 162-162 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 168
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    AIChE Journal 15 (1969), S. 320-320 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 169
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    AIChE Journal 15 (1969), S. 47-50 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The evaporation of n-decane into air from the surface of Celite particles, has been used for the establishment of mass transfer factors for both packed and fluidized bed systems. For these calculations log mean partial pressure differences were used. Actual concentration profiles of the transferable component were also experimentally measured by monitoring, at different bed heights, the concentration of n-decane vapor present in air used as the carrier gas. This was made possible through the use of an extremely sensitive hydrocarbon analyzer. The resulting profiles were used to obtain, by graphical integration, the actual driving force prevailing for each run. A nearly one-to-one correspondence was found to exist between the actual driving force and the corresponding log-mean value for both packed and fluidized bed runs.
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  • 170
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    AIChE Journal 15 (1969), S. 199-205 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Electrochemical techniques are developed to study the details of the flow around a single particle in a packed bed. Initial work has been done with a dumped bed of 1 in. spheres. Results are presented on the variation of the mass transfer coefficient and the shear stress around the surface of one of the spheres, the overall mass transfer rates to a sphere in a bed of inert spheres, and the effect of Reynolds number on the local mass transfer coefficient and the shear stress.
    Additional Material: 10 Ill.
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  • 171
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    AIChE Journal 15 (1969), S. 291-292 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 172
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    AIChE Journal 15 (1969), S. 264-269 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An improved free volume theory is presented, and is shown to predict the variation of viscosity with temperature and pressure satisfactorily for liquids composed of simple, nonpolar molecules, when the density is greater than twice the critical value. Allowance is made for the temperature dependence of the minimum free volume for a jump, and for the density dependence of the activation energy at constant volume. Corresponding states relationships are provided for these quantities, the reducing parameters being the temperature and molal volum at the melting point.
    Additional Material: 7 Ill.
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  • 173
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    AIChE Journal 15 (1969), S. 272-275 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Calculations concerning the production of heavy water by the hydrogen sulfide dual-temperature exchange process require precise data on the physical properties of dry hydrogen sulfide and hydrogen sulfide-water mixtures for temperatures between 25 and 170°C., and for pressures between 200 and 340 lb./sq.in.abs. However, data on enthalpy of hydrogen sulfide-water mixtures were not found in the literature, and data published on hydrogen sulfide-water compositions at equilibrium were given at such large intervals of temperature and pressure that they could not be interpolated accurately enough by ordinary means. 1Specific volume and enthalpy of dry, superheated hydrogen sulfide vapor,2Composition of hydrogen sulfide-water vapor and liquid in equilibrium,3Enthalpy of hydrogen sulfide vapor saturated with water vapor,4Enthalpy of water liquid saturated with hydrogen sulfide vapor,5Deuterium distribution constants for vapor-liquid equilibrium.A study was undertaken to express the properties, listed below, with equations suitable for solution on a digital computer and useful in mathematical models of the process.New correlating constants were derived where needed. The equations and typical results are presented in this paper.
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  • 174
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    AIChE Journal 15 (1969), S. 294-297 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 175
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    AIChE Journal 15 (1969), S. 298-300 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 176
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    AIChE Journal 15 (1969), S. 306-307 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 177
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    AIChE Journal 15 (1969), S. 480-480 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 178
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    AIChE Journal 15 (1969), S. 351-356 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A perturbation series solution is derived for isothermal bubble dissolution and bubble growth from an initially finite size. The new solution is superior in several aspects to the quasi-stationary and quasi-steady state approximations derived previously. The accuracy and range of validity of the new results are investigated by comparison with finite-difference solutions of the equations governing bubble growth or dissolution. In addition, previous numerical solutions of the problem are compared to the finite-difference results of this study.
    Additional Material: 4 Ill.
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  • 179
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    AIChE Journal 15 (1969), S. 367-370 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The steady, two-dimensional, incompressible laminar boundary-layer flow of power law fluids past a semi-infinite flat plate is studied analytically by the method of series expansion and the method of steepest descent (Meksyn's method). The shear stress of the fluids considered is proportional to the nth power of the velocity gradient. The solution obtained is a series of gamma function with the coefficient being a function of the material constant, n. The first ten terms of the series solution are then considered for the sum to determine the velocity gradient at the plate, fηη(0). The results obtained for fηη(0) and the coefficient of skin friction are in excellent agreement with the numerical solutions available in the range of 0.1 ≤ n ≤ 2.5.
    Additional Material: 2 Tab.
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  • 180
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    AIChE Journal 15 (1969), S. 370-378 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An apparatus was constructed for making isochoric measurements of P-V-T properties. Experimental compressibility factors were obtained and are presented for methane, ethylene, and four intermediate mixtures at 60, 40, and 20°F., with pressures from 260 to 2,220 lb./sq.in.abs. Second and third virial coefficients and interaction virial coefficients were determined from the data. The compressibility factors and the virial coefficients are compared with the Benedict-Webb-Rubin equation of state, applied in its original form and in a recent generalized form.
    Additional Material: 2 Ill.
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  • 181
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    AIChE Journal 15 (1969), S. 405-409 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The definition of filtration resistance is modified by considering relative solid-liquid velocity.The internal flow mechanism in a filter cake is reexamined in view of the movement of solids during compression. Under conditions of short filtrations involving highly concentrated slurries, the velocity of solids is shown to be comparable to the velocity of the liquid. A differential equation is proposed for the flow through compressible cakes in which the pressure gradient is assumed proportional to the difference in average velocities of the liquid and solid rather than to the average velocity of the liquid alone.An improved definition of the average filtration resistance is developed on the basis of the new flow equation.
    Additional Material: 7 Ill.
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  • 182
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    AIChE Journal 15 (1969), S. 293-294 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 183
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    AIChE Journal 15 (1969), S. 521-526 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new theory for convection-free rinsing of flat plates was developed to include the drop dispersal mechanism as well as the previously considered diffusion mechanism. Cases where carryover is unequal to dragout were also included in the model. Based on film distribution data, the model offers better agreement with rinse data. The effect of drain time on film distribution and bottom drop volume was also investigated.
    Additional Material: 5 Ill.
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  • 184
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    AIChE Journal 15 (1969), S. 548-553 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Equations are given that relate the entrance length to Reynolds number for pipe and channel geometries with a flat velocity profile as the initial condition. These equations are linear combinations of the creeping flow and boundary layer solutions. The former is obtained by minimization of the viscous dissipation using the finite element method. The equation for the pipe entrance is shown to be in good agreement with experimental data.
    Additional Material: 11 Ill.
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  • 185
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    AIChE Journal 15 (1969), S. 507-514 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An expression is derived for the analysis of gas-phase mass transport in porous media in the presence of gradients in pressure and mole fraction. The behavior of porous media is contrasted with that of capillary tubes. A continuous-flow diffusion and permeation apparatus was employed for studies of mass transport in a fritted glass diaphragm. Measurements were obtained at varying levels of pressure and cover both isobaric binary diffusion and the permeation of pure gases and gas mixtures. These experimental results and previous data obtained by Hewitt and Sharratt and by Mason, et al. bear out the form of the equation and successfully provide independent checks of the three constants necessary to characterize a given porous medium.
    Additional Material: 4 Ill.
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  • 186
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    AIChE Journal 15 (1969), S. 527-532 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental values of the wave length and wave velocity have been obtained for dilute solutions of valeric and hexanoic acid for a vertical falling liquid film. The wave length was unaffected by the surfactants for Reynolds numbers in the range 5 to 100; however, the wave velocity was decreased for increased surface concentrations of the two acids. This is in direct contradiction to previous theoretical work, and the explanation for the anomaly is that the free surface velocity is greatly retarded by the adsorption of the surface active agents. In an effort to determine the extent of this retardation, an approximate form of the diffusion equation and the equations of motion were solved subject to boundary conditions describing the effect of the absorbed surfactant on the surface stress. The results indicate that the entrance length can be increased several orders of magnitude by the addition of small amounts of surfactant.
    Additional Material: 11 Ill.
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  • 187
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    AIChE Journal 15 (1969), S. 604-611 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study has been made of the mechanics of flow of low viscosity liquids through swirl spray nozzles. Discharge coefficients and spray angles have been measured for a series of nozzles designed to systematically determine dimensional effects not predicted by frictionless theory, in particular the effect of the ratios of swirl chamber diameter to orifice diameter and of orifice length to orifice diameter. It was found that a unique relationship exists between discharge coefficient and spray angle dependent only upon the value of the orifice length/diameter ratio. This result has been explained on the basis of an ideal flow theory extended to take into account the frictional decay of the vortex motion. A general expression has been derived which permits correlation of the flow characteristics of nozzles covering a wide range of designs.
    Additional Material: 21 Ill.
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  • 188
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    AIChE Journal 15 (1969), S. 597-604 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The turbulent transport of mass, energy, and momentum was studied in a 4 in. diameter cylindrical column packed with 0.3 in. diameter stoneware spheres. Helium was used as a tracer material, with air as the mainstream fluid. The concentration of tracer present, the temperature, and the velocity of the gas were measured at several axial and radial increments. These data were analyzed numerically to obtain the radial component of the effective thermal conductivity and the radial component of the mass-dispersion coefficient as functions of radial position. Experimental conditions covered isothermal determinations at room temperature and nonisothermal determinations in which a temperature gradient was established in the radial direction. Significant differences were found between the isothermal and strongly nonisothermal results, primarily for the velocity profiles and thermal conductivities. Correlations were developed for the local values of the parameters.
    Additional Material: 17 Ill.
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  • 189
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    AIChE Journal 15 (1969), S. 617-619 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 190
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    AIChE Journal 15 (1969), S. 627-627 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 191
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    AIChE Journal 15 (1969), S. 466-466 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 192
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    AIChE Journal 15 (1969), S. 466-469 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 193
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    AIChE Journal 15 (1969), S. 636-638 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 194
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    AIChE Journal 15 (1969), S. 495-501 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The photodecomposition of acetone vapor was studied in a tubular flow, differential reactor at atmospheric pressure and from 82 to 112°C. The products included significant amounts of biacetyl along with carbon monoxide and ethane. A rate equation was developed from a sequence of elementary reactions believed to explain the photolysis of acetone. The effects of light intensity and acetone concentration, indicated in the derived rate equation, were confirmed by the data.The rate is less than first-order with respect to acetone, and this is believed to be due to reformation of stable acetone molecules by deactivation of CH3COCH3*.
    Additional Material: 7 Ill.
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  • 195
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    AIChE Journal 15 (1969), S. 501-504 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Metal surfaces of titanium, aluminum, copper, lead, and zinc were irradiated by a 25 joules pulsed laser with an energy flux ranging from 106 to 108 cal./(sq.cm.) (sec.). The resulted cavities were sectioned, polished and measured to compare with the isotherms computed from several heat conduction models. Reasonable agreement was found between the experimental cavity diameters at the interface and those calculated from the disk source model. Also, a graphical correlation between the cavity depth and its interface diameter is presented.
    Additional Material: 5 Ill.
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  • 196
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical analysis of the operation of a Schildknecht type of column crystallizer is presented and simplified to three special cases. Experimental determinations were made of concentration profiles established during the purification of benzene with cyclohexane as impurity under steady state, batch conditions of operation. Benzene containing 34 to 500 ppm. cyclohexane was obtained by processing feed material with 5,000 to 30,000 ppm. cyclohexane. It was found that experimental data obtained under conditions of normal operation are well correlated by theoretical expressions if it is assumed that the crystals are not pure but contain cyclohexane at the level of 34 to 100 ppm. It was further established that the resistance to mass transfer between the liquid which adheres to the crystals and the wash liquid is negligible in comparison to backmixing effects as represented in the model by an eddy diffusion term. Smooth operation of the column was obtained at crystal rates below a limiting upper value and at oscillation frequencies above a lower limit.
    Additional Material: 8 Ill.
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  • 197
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    AIChE Journal 15 (1969), S. 568-575 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this paper the concept of a mass transfer section is applied to problems involving packed distillation columns and packed absorbers. When this concept is employed, the resulting equations required to describe packed distillation columns and packed absorbers are identical in form to those required to describe distillation columns and absorbers with plates. Data from the results of two field tests are presented and analyzed.
    Additional Material: 8 Ill.
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  • 198
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    AIChE Journal 15 (1969), S. 758-763 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Graetz-Nusselt problem for polymeric flow in a constant wall temperature tube was studied, using a temperature-dependent power law rheological model and temperature dependent fluid properties. Theoretical results compare within 6% of experimental results. The fluid model predicts an experimentally observed temperature maxima at a reduced radius between 0.7 and 0.8 for cooling at low flow rates.
    Additional Material: 9 Ill.
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  • 199
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    AIChE Journal 15 (1969), S. 780-782 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
    Additional Material: 2 Ill.
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  • 200
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    AIChE Journal 15 (1969), S. 790-792 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstracts.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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