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  • 1
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 686-693 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Properties of Ga2O3 thin films deposited by electron-beam evaporation from a high-purity single-crystal Gd3Ga5O12 source are reported. As-deposited Ga2O3 films are amorphous, stoichiometric, and homogeneous. Excellent uniformity in thickness and refractive index was obtained over a 2 in. wafer. The films maintain their integrity during annealing up to 800 and 1200 °C on GaAs and Si substrates, respectively. Optical properties including refractive index (n=1.84–1.88 at 980 nm wavelength) and band gap (4.4 eV) are close or identical, respectively, to Ga2O3 bulk properties. Reflectivities as low as 10−5 for Ga2O3/GaAs structures and a small absorption coefficient (≈100 cm−1 at 980 nm) were measured. Dielectric properties include a static dielectric constant between 9.9 and 10.2, which is identical to bulk Ga2O3, and electric breakdown fields up to 3.6 MV/cm. The Ga2O3/GaAs interface demonstrated a significantly higher photoluminescence intensity and thus a lower surface recombination velocity as compared to Al2O3/GaAs structures. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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  • 2
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have fabricated high power carbon-doped InGaAs/AlGaAs lasers using an impurity-induced layer disordering process to define the active region. The advantage of carbon doping is that it exhibits significantly lower diffusivity compared to other p-type dopants, thereby avoiding displacement of the p-n junction, even at the high temperatures and long diffusion times required by the disordering process. Secondary ion mass spectrometry (SIMS) measurements before and after Si diffusion show the p-n junction position to be unchanged during processing. The carbon was introduced using CCl4 as an extrinsic precursor, giving improved control over doping levels and ternary growth conditions that is not available with intrinsic carbon doping. Thresholds of 20 mA and slope efficiencies of 0.44 mW/mA at 25 °C were obtained for lasers with cavity lengths of 500 μm and coated facets.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 2296-2299 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The activation efficiencies of implanted Si, Be, and C in GaAs0.93P0.07 have been measured in the annealing range 650–950 °C. Be provides much higher sheet hole densities than C, even when the latter is coimplanted with Ar to enhance the electrical activity. The maximum activation efficiency of Be is ∼60% at a dose of 5×1014 cm2 whereas that of C is an order of magnitude lower. Si produces donor activation percentages up to ∼20% under optimized annealing conditions. Capless proximity annealing is adequate for surface preservation up to ∼950 °C, as measured by scanning electron microscopy and atomic force microscopy. Photoluminescence measurements provide evidence that nonradiative, damage-related point defects remain in the GaAsP even after annealing of 950 °C. © 1996 American Institute of Physics.
    Materialart: Digitale Medien
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  • 4
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Etch-induced surface modifications, utilizing an electron cyclotron resonance source, have been studied as a function of controllable etch parameters. InGaP was etched with BCl3 at a constant substrate temperature (100 °C) and bias voltage (−145 V) using microwave powers varying between 250 and 1000 W. The surface morphology, residual etch damage, and surface stoichiometry were strongly influenced by changes in ion flux. The etch-induced lattice damage and surface smoothness increased as the ion energy was elevated. Low ion flux etching resulted in an In-enriched P-depleted surface suggesting nonuniform desorption of InClx which gave rise to the surface roughness observed at the low microwave powers. The smooth surfaces, achieved at the higher microwave power levels, were attributed to either efficient sputter-assisted desorption of the InClx etch products or to InClx desorption via plasma-induced surface heating. Results of this study demonstrate that etching at microwave powers between 500 and 750 W induce low residual damage and smooth surfaces while maintaining a reasonable etch rate for device processing. © 1996 American Institute of Physics.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 2198-2203 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The Raman effect in semiconductor waveguides below half-gap is studied both experimentally and numerically. We report the depolarized Raman gain spectra up to 300 cm−1 in Al0.24Ga0.76As at pump wavelengths of 0.515 and 1.55 μm from the measurement of the absolute Raman scattering cross sections using GaAs as a reference scatterer. In addition, the coupled propagation equations for the AlGaAs waveguides are modified to include the Raman effect. By solving the coupled propagation equations numerically, we verify that the energy transfer between two orthogonally polarized pulses demonstrated in previous pump-probe experiments [M. N. Islam et al., J. Appl. Phys. 71, 1927 (1992)] is caused by Raman effect. We also show numerically that the Raman effect induces spectral distortions on the pulses, and the energy transfer is inversely proportional to the pulse widths. The energy transfer results in a severe cross-talk problem for sub-picosecond pulses in AlGaAs waveguides. For example, the energy exchange is about 30% for 300 fs pulses under π phase shift conditions. Therefore, the Raman effect limits the performance of semiconductor waveguides in optical switching applications for sub-picosecond pulses. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 7647-7661 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: This article investigates steady-state nonequilibrium conditions in metal–oxide–semiconductor (MOS) capacitors. Steady-state nonequilibrium conditions are of significant interest due to the advent of wide-gap semiconductors in the arena of MOS (or metal–insulator–semiconductor) devices and due to the scaling of oxide thickness in Si technology. Two major classes of steady-state nonequilibrium conditions were studied both experimentally and theoretically: (i) steady-state deep depletion and (ii) steady-state low level optical generation. It is found that the identification and subsequent understanding of steady-state nonequilibrium conditions is of significant importance for correct interpretation of electrical measurements such as capacitance–voltage and conductance–voltage measurements. Basic implications of steady-state nonequilibrium conditions were derived for both MOS capacitors with low interfaces state density Dit and for oxide semiconductor interfaces with a pinned Fermi level. Further, a photoluminescence power spectroscopy technique is investigated as a complementary tool for direct-gap semiconductors to study Dit and to monitor the interface quality during device fabrication. © 1997 American Institute of Physics.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 2061-2064 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Changes in the near-surface electrical properties of n-type (n=1×1017 cm−3) GaAs and AlGaAs after reactive ion etching in C2H6/H2/Ar or CCl2F2/O2 discharges (4 mTorr, 0.85 W cm−2) were investigated by current-voltage (I-V) and capacitance-voltage measurements on Schottky diodes. Carrier reductions of approximately an order of magnitude were observed immediately after etching GaAs and AlGaAs in ethane-hydrogen-argon; much smaller changes (∼20%) were observed using freon-12–oxygen. For both gas chemistries, annealing in the range 200–300 °C produced the most ideal I-V characteristics in GaAs, whereas 300–400 °C was required for AlGaAs. Replacing H2 by D2 allowed high sensitivity atomic profiling using secondary ion mass spectrometry. Permeation of D2 to depths of ∼0.5 μm is observed in both GaAs and AlGaAs after etching—the D2 diffuses rapidly around 400 °C where dopant reactivation occurs.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 2137-2147 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The etch rate and surface chemistry of AlxGa1−xAs after reactive ion etching (RIE) in CCl2F2:O2 was examined as a function of etch time (1–22 min), plasma power density (0.3–1.3 W cm−2), pressure (1–30 mTorr), gas composition (0%–80% O2), gas flow rate (10–50 sccm), sample temperature (50–350 °C), and Al composition (x=0.15–1). The etch rate is nonlinear with time, and decreases rapidly with increasing AlAs mole fraction. Essentially no temperature dependence of the etch rate is observed under our conditions, and there are no major differences in the surface chemistries of AlGaAs etched at different temperatures. The formation of a thin layer (50–90 A(ring)) of AlF3 during the RIE treatment appears to control the etch rate, and the surface morphology becomes progressively smoother for increasing Al composition. No residual lattice disorder is detected by cross-sectional transmission electron microscopy under any of our conditions, although current-voltage measurements on Schottky barrier diodes fabricated after RIE show higher ideality factors and barrier heights than unetched control samples. Annealing at 500 °C for 30 s almost restores the initial electrical properties of the material.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 5009-5017 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The etch rates of GaAs and AlxGa1−xAs (x=0.09–1) in C2H6/H2 were investigated as a function of time (1–12 min), gas flow rate (5–25 sccm), total pressure (4–30 mTorr), plasma power density (0.56–1.32 W cm−2), and percentage of C2H6 in the discharge (10%–50%). The etch rates are constant with time, and decrease with increasing Al content in the AlGaAs. The maximum etch rates occur at 25% by volume C2H6 in H2 and increase linearly with increasing power density. Increasing the total pressure at constant gas composition reduces the etch rates by approximately a factor of 2 between 4 and 30 mTorr. The etched surfaces have smooth morphologies for C2H6 concentrations less than ∼40% of the total gas volume. A layer of subsurface dislocations approximately 40 A(ring) deep were observed in GaAs by transmission electron microscopy for the highest-power density discharges, while the surfaces for all samples are As-deficient to a depth of ∼30 A(ring) after reactive ion etching. Polymer deposition is not significant for C2H6 volumes less than 40% of the total gas volume.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 5018-5025 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The etch rate, surface morphology and atomic composition, and depth of hydrogen passivation of Si dopants in n-type GaAs and AlGaAs have been examined as a function of the temperature of the sample during reactive ion etching in C2H6/H2. While there is no temperature dependence of the etch rate of AlGaAs over the range 50–350 °C, the etching of GaAs shows an increase of a factor of 2 between 150 and 250 °C, decreasing at higher temperatures. The As-to-Ga ratio in the near-surface region of GaAs remains unchanged over the whole temperature range investigated and there is no polymer deposition. The etched surface morphology is smooth for both GaAs and AlGaAs for all temperatures while the depth of Si dopant passivation by hydrogen shows an increase with increasing substrate temperature during the etching treatment.
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