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  • 1960-1964  (729)
  • 1963  (729)
  • Organic Chemistry  (690)
  • Biochemistry and Biotechnology  (39)
  • Nuclear reactions
  • Physics
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  • 1960-1964  (729)
Year
  • 1
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 309-330 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Biological purification of water pollutants depends upon a complex balance of organisms and environment conducive to effective metabolism. The bench scale test is useful to determine effects of a given waste water on that balance and to suggest controls promoting optimum purification. Applicability of laboratory results depends, in part, upon an experimental design similating anticipated operating conditions. This paper discusses advantages and limitations of historical bench-tests as a guide for design of tests giving data that are more useful during full-scale operation.
    Additional Material: 5 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963) 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A 50-gal. growth chamber is described together with its air filter and humidifier. The unit was designed especially for the production of Neurospora crassa, and was found to be effective in producing bulk amounts of mycelia with a high specific activity of tryptophan synthetase.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 87-89 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Addition of the S-2-hydroxyethyl-, S-2-chloroethyl-, S-n-propyl-, and S-iso-propyl-derivatives of homocysteine, and methoxinine to S. aureofaciens (ATCC 13900) fermentations resulted in production of 7-chloro-6-demethyltetracycline in addition to the normally synthesized 7-chlortetracycline.
    Additional Material: 1 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 123-129 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of inoculating nutrient surfaces uniformly with bacterial cells has been developed. The method is based on controlled exposure of samples in a humidified chamber to a spray produced from a bacterial suspension. Factors affecting uniformity of inoculation (ionic strength of suspension, force of spray, distance between spray nozzle and sample, and exposure time) were studied in detail. Under optimum condition using agar medium in Petri plates, differences between total counts for six plates inoculated simultaneously, or between counts for individual 2 cm.2 areas taken at any location on any of the plates, were not statistically significant at the 5% level. The coefficient of variability for counts on 2 cm.2 areas renged from 8 to 12% between tests of 216 counts each.
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963) 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 185-192 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By growing Aspergillus parasiticus (C.M.I. 15957) under controlled conditions on sterilized peanuts an average of 265 mg. of aflatoxin per kilogram of peanuts has been produced and subsequently isolated. Other strains from the A. flavus-oryzae group gave lower yields of aflatoxin and one such strain gave aflatoxin from which certain normal components were absent. The aflatoxin produced on sterilized peanuts by any particular strain of A. flavus-oryzae was shown by thin-layer chromatography to contain the same major components as were produced by that strain on unsterilized whole peanuts.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 221-230 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A process has been developed giving over-all yields of about 50%: which could be increased to about 80% with higher material costs and processing time. The preferred method of recovering nucleotides from the cytoplasm has been thermal extraction by means of a heat exchanger followed by filtration, protein precipitation, and carbon adsorption. The concentrated eluate from the carbon is absorbed onto Dowex 1 ion-exchange resin, and groups of nucleotides are removed by pH-defined eluents and recovered by a second carbon adsorption. Finally, standard ion-exchange resolutions have been used to recover individual nucleotides. Other biochemicals in the extract have been investigated, and preliminary work has been done on the combination of nucleotide extraction with the recovery of nucleic acids from the residual cells.
    Additional Material: 3 Tab.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 231-242 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the present paper the authors described laboratory fermentors used in the Antibiotics Research Institute since 1958 for research concerning the technology of the biosynthesis of antibiotics and amino acids and other aerobic fermentations. The lids of the fermentors are made from stainless steel, the vessels are made from glass. The fermentors are placed, always four each, in eight water baths with automatic temperature regulation within a range of ±0.5°C. Details regarding construction, auxiliary equipment, and working procedures used for the sterilization of fermentors and media, inoculation, injection of additives, and defoaming are given. The set-up for one-stage and multi-stage, batch and continuous cultivation are discussed.
    Additional Material: 5 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963) 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 131-146 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A sensitive cup plate assay method for lysine on large plates using S. faecalis ATCC 6057 as the test organism is described in detail. Well-defined zones of dense growth were obtained in a rectilinear dose - response range from 5 to 3000 μg. of L-lysine/ml. Comparative assays on twelve different samples were carried out using the turbidimetric tube assay method with Leuc. mesenteroides ATCC 8042 and the cup plate method with S. faecalis ATCC 6057. Good agreement between the two assay methods was obtained for five samples. For the remaining seven samples the tube assay values were appreciably higher than those obtained by the plate method. This discrepancy is discussed. Pure lysine added to various sample extracts could be quantitatively recovered. The specificity of the lysine requirement of S. faecalis ATCC 6057 in the plate assay was also investigated. Under certain experimental conditions, a weak and variable response was obtained with D-lysine and the polyamines cadaverine, spermine, and spermidine. There was generally no difficulty in distinguishing the D-lysine and polyamine growth zones from the L-lysine growth zones. This growth effect of D-lysine and polyamines could be diminished and even completely abolished by increasing the DL-hydroxylysine hydrochloride level in the plate medium. The lysine peptides glycyl-L-lysine and L-lysylglycine gave excellent growth zones of the same appearance as those produced by L-lysine. The activity of these two peptides in cup tests were on a molar basis about 70% of that of L-lysine.
    Additional Material: 2 Ill.
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  • 13
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 9-15 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method by which a paramagnetic oxygen analyzer is used to determine oxygen consumption and carbon dioxide production during aerobic fermentation of Torulopsis utilis is described. The volume of carbon dioxide produced is not necessarily related to the volume of oxygen consumed by the microorganisms. For this reason, all carbon dioxide is removed from the effluent gas before it enters the analyzer when determining oxygen consumption. A method for calibrating the analyzer to correct for this removal is outlined. When determining carbon dioxide, effluent gas bypasses the carbon dioxide absorption tower before entering the analyzer. The carbon dioxide which it contains dilutes the oxygen remaining in the gas. The magnitude of this dilution can be used to calculate the percentage of carbon dioxide produced in terms of the air flow to the fermentor. Equipment required to alternately measure and record oxygen consumption and carbon dioxide production is described.
    Additional Material: 4 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 21-25 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Cobamide production by Butyribacterium rettgeri Barker and Haas (ATCC 10825) was studied on a laboratory scale. Yields of the order of 5 μg./ml. were obtained when this anaerobe was grown for 6 days at 37°C. in a medium containing glucose, cornsteep liquor, cobalt nitrate, calcium carbonate, and sufficient ammonium hydroxide to keep the pH between 6.0 and 7.2. All of the vitamin was found associated with the bacterial cells, and examination of extracts of these cells showed the presence of 5,6-dimethylbenzimidazolylcobamide coenzyme in large quantities. Supplementation of the fermentation medium with a number of benzimidazoles resulted in formation of traces of “new” cobamides with these bases in the nucleotide protion of the cobamide. Supplementation with a number of purines did not result in incorporation of these moieties in the cobamide portion of the molecule.
    Additional Material: 1 Ill.
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  • 15
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 49-52 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An investigation was made of the stability of product limited continuous cultures of Saccharomyces carlsbergensis and Pseudomonas ovalis. No oscillations were found in pH or glucose concentration during the steady state, and no overshoot resulted from changing from one steady state to another.
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  • 16
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 41-48 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bacillus subtilis NRRL B-2612, isolated at this laboratory, was used to produce polyglutamic acid from devitalized wheat gluten. Conditions for production of the polypeptide were investigated. When NRRL B-2612 was grown on wheat gluten in shaken flasks with phsophate buffer and salts at pH 6.5, yields of polymer reflected a 25-40% incorporation of glutamic acid into polyglutamic acid. Repeated alcoholic precipitation yielded peptides containing between 45 and 90% D-glutamic acid. Physical and chemical properties of a typical purified polyglutamic acid indicated that the product was a gamma-linked polypeptide composed of 75% D-glutamic acid and 25% L-glutamic acid with a molecular weight of approximately 200,000.
    Additional Material: 3 Ill.
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  • 17
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 109-121 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microbiological production of beta-carotene previously investigated in shakenflask culture has been scaled-up to 20-liter fermentors containing an operating volume of 10-liters. Yields obtained in shaken flasks, approximately 100 mg./100 ml. have been reproduced with a fermentation time of 72 hr. Factors affecting the fermentation: inoculum, mash ingredients, and environmental conditions, were investigated. Typical data are presented. A preliminary cost analysis indicates a “cost to make” of $31.35/kg. of carotene contained in the dried fermentation solids.
    Additional Material: 12 Ill.
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  • 18
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 167-184 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Shock pressure waves with a frequency of 50/sec. and a maximal pressure of 60-70 kg./cm.2 greatly reduced the viability of E. coli. A similar effect was obtained also on staphylococci, enterococci, Salmonella Zanzibar, and coliphages T2. On the contrary no effect on spores of B. subtilis was found. The effect was practically independent of the maximal pressure within the range from 30-80 kg./cm.2, the highest pressure tested. The effect decreased with increasing cell density of the bacterial suspension. Bacteria surviving shock treatment died considerably more rapidly when stored at 4°C. than bacteria treated in the same way except for exposure to pressure waves. Morphological examinations with the aid of ordinary light microscopy as well as electron microscopy suggest that the effect was due to mechanical action on the bacterial cell walls.
    Additional Material: 10 Ill.
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  • 19
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963) 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
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  • 20
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 287-307 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Sphaerotilus is usually present in biological waste treatment processes and is considered to be a nuisance organism because it may cause bulking of activated sludge. However, it may play an important role in the decomposition of putrescible organic matter in properly operated biological waste treatment processes. The research described herein is a study of the variety of types of organic compounds which may be decomposed by Sphaerotilus and the effect of some environmental factors upon the rate of decomposition. Although there are some types of compounds which cannot be decomposed by Sphaerotilus, it is shown that this organism is able to assimilate and oxidize a large variety of organic compounds and that it is tolerant of an extremely wide range of environmental conditions. The role of Sphaerotilus in biological waste treatment is discussed in the light of the data presented.
    Additional Material: 9 Ill.
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  • 21
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 355-365 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It has been found that a bacterium (isolant C12B) grew poorly on 6 and 8 carbon alcohols, well on 10 and 12 carbon alcohols, and slowly but well on the 14 to 18 carbon compounds. Unexpectedly, resting cells oxidized the 6 and 8 carbon compounds most readily and cell-free extracts oxidized 6, 8, and 10 carbon alcohols. Extracts from cells adapted to sodium lauryl sulfate oxidized the 12 carbon alcohol as well, if small concentrations of substrate were used. The bacterium grew on benzene sulfonate and adapted resting cells oxidized that compound. Pure culture degradation studies revealed that isolant C12B used only 11% of tetrapropylene ABS supplied as a sole carbon source, whereas 66% of sodium lauryl sulfate was degraded. Intermediate quantities of kerosene-based alkyl benzene sulfonate and a tallow-derived detergent were utilized. Extracts of another bacterium, TEG-5, grown on tetraethylene glycol, contained enzymes which oxidized polyethylene glycols up to an average molecular weight of 600, but not any larger polymers. This oxidation was visualized by coupling to reduction of ferricyanide.
    Additional Material: 9 Ill.
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  • 22
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 17-20 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The applicability of physicochemical adsorption laws to the sorption of methylene blue by dead Penicillium chrysogenum was studied. The specific area (area/mass) of the mold was measured.
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  • 23
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 147-165 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A number of factors was found to affect the cup plate assay for lysine with Streptococcus faecalis ATCC 6057. Hydroxylysine, aspartic acid, and Tween 80 were found to be among the essential components of the assay medium. Removal of any of these three components produced diffuse growth zones or otherwise unsatisfactory plates. The inclusion of asparagine and additional dipotassium phosphate to the medium was found to be advantageous but not an absolute requirement. It was important not to autoclave the hydroxylysine and the additional dipotassium phosphate together with the rest of the assay medium, but to add these components to the sterilized medium immediately before pouring the plates. With certain concentrations of hydroxylysine in the medium, the addition of L-glutamine was found to potentiate the effect of hydroxylysine and thereby improve the lysine plates. The effect of graded amounts of the above mentioned medium components and of the pH of the assay medium was also studied. Increasing the sterilization time of the medium from 5 to 10 min. at 120°C. improved the readability of the lysine plates and led to more easily reproducible results. Factors influencing the preparation of the inoculum for the lysine plates were also studied: the age of the stab culture, the amount of inoculum used per plate, and the influence of the nature of the suspension medium used for washing the inoculum.
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  • 24
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 193-199 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ferrocyanide-treated beet molasses was fermented in fully baffled mechanically agitated, 2.5-liter, tank-type fermenters using pellets of Aspergillus niger grown in shake flasks as an inoculum. The object of the study was to adapt the fermentation method previously developed in an unstirred tower-type fermenter to a conventional tank-type fermenter. Under selected conditions of stirring (agitator speed 400-700 rpm) and sparging (medium porosity sintered disk), high yields of citric acid (8.6% citric acid, 70% conversion of available sugar) were obtained in 140 hr. of fermentation. There was little relation between citric acid yield and aeration conditions in the fermenter as judged by mash viscosity measurements and sulfite oxidation studies.
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  • 25
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 53-58 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The design of a cabinet for the aseptic manipulation of material is described. The interior surfaces of the cabinet are sterilized by swabbing with a germicide. Germ-free conditions are maintained during operation by means of a positive pressure of sterile air. A fan and filter unit attached to the cabinet is used to blow sterile air into the cabinet in sufficient quantity so as to flow out of the hand ports at a velocity of 50 ft./min. In the design, careful consideration was given to the ease of manipulations in the cabinet.
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  • 26
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Removal of the pungent factor, allyl isothiocyanate, will partly determine whether mustard seed can become a commerical source for oil and meal in the United States. In processing studies at the Northern Laboratory, the mustard glucoside was converted enzymatically and the pungent oil was removed. This process has now been extended to pilot-plant scale by using filtration-extraction equipment at the Southern Laboratory. After desolventization and further steam stripping, the extracted meal had a residual content of 2.9% crude fat and 0.004% allyl isothiocyanate.
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  • 27
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    Biotechnology and Bioengineering 5 (1963), S. 59-74 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The distribution of dissolved oxygen in agitated, sparger-aerated aqueous solutions has been investigated by polarographic techniques. The results of the investigations are discussed in relation to earlier studies in bubble distribution in such systems. Liquid-phase mixing is good at agitation intensities well below that necessary to disperse bubbles throughout the liquid.Suspended solids interfere with the transfer of oxygen unless they are freely suspended. Discrete fibers (paper-pulp) are much easier to suspend than molds in either filamentous or pellet forms. Mass-transfer at the cell-liquid interface appears to be unaffected, in both bacterial and mold suspensions, by the intensity of agitation, provided that the organisms are freely suspended.
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  • 28
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    Biotechnology and Bioengineering 5 (1963), S. 83-85 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The inclusion of ethionine in Streptomyces rimosus fermentation resulted in the production of N-methylethyloxytetracycline. The compound has been isolated, crystallized, and a number of its chemical properties determined.
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  • 29
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    Biotechnology and Bioengineering 5 (1963), S. 101-107 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An adsorption colorimetric method is proposed for the determination of the percentage of dead cells in suspensions of Penicillium chrysogenum, based on the observed fact that a linear relation exists between that percentage and the dye concentration at the equilibrium point.
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  • 30
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    Biotechnology and Bioengineering 5 (1963), S. 91-99 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microbial polysaccharides which have many potential industrial applications are receiving more and more attention. One of the economic obstacles to the commercialization of these polysaccharides has been the cost of isolating them from fermented broth. To reduce this cost a recycling process was developed. The polyanionic polysaccharide synthesized from glucose by the activity of the bacterium Xanthomonas campestris NRRL B-1459 is precipitated from the fermented broth with a quaternary ammonium compound (QAC).QAC is removed from the precipitate with methanol leaving the water-soluble polysaccharide. Evaporation of the methanol wash removed the methanol and substantially all the QAC was recovered in the concentrate. This was recycled for subsequent precipitations. Chemical assay and the viscosity of water solutions of the isolated polysaccharide indicate no adverse effects on it from recycled QAC. The cost to make this polysaccharide by the described procedure is estimated to be $1.14/lb. This cost estimate includes land, buildings, raw materials, equipment, labor and supervision, utilities, factory supplies, working capital, and plant overhead.
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  • 31
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    Biotechnology and Bioengineering 5 (1963), S. 211-220 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A disposable plastic tetrahedron bag is described which is suitable for holding a 50 ml. culture on a shaker table. Bags can be made out of polypropylene or Teflon and they are quite simple and inexpensive. The tetrahedrons make excellent use of the shaker table space and they give a threefold increase in aeration efficiency over Erlenmeyer flasks.
    Additional Material: 4 Ill.
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  • 32
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    Biotechnology and Bioengineering 5 (1963), S. 243-251 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The metabolic pathway of degradation of naphthalene to salicylic acid has been studied by several investigators. The rates of conversion and of cell growth are the basis for the present study. In the early phase of the fermentation, the salicylic acid accumulation followed an exponential curve, as did the bacterial cell accumulation. In the second phase, most of the salicylic acid was produced according to a linear or zero reaction, at rates of 0.3 to 0.5 g./l./hr. A linear accumulation of microbial cell weight accompanied the linear salicylic acid formation. Despite the correlation of growth and salicylic acid production, the type or amount of nitrogen supplied for growth had only a small effect on yield over broad limits. The optimum pH for salicylic acid accumulation was approximately 6.5. Below this value a slower rate of production and lower final yield was seen. Above pH 6.5, a rapid degradation of salicylic acid was observed. A temperature range from 25 to 30°C. was optimum. At 35°C., no growth occurred, while at 20°C. very slow salicylic acid accumulation resulted.
    Additional Material: 9 Ill.
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  • 33
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    Biotechnology and Bioengineering 5 (1963), S. 255-273 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Stabilization ponds have been widely accepted in recent years, following studies that established deeper understanding of the phenomena associated with the stabilization process. A compilation of information on the use of both sewage and industrial ponds is presented showing types and geographical location in the United States. A total of 1,304 stabilization ponds currently are used as the principal method of sewage treatment serving a population of 2,138,085. Ponds are used for tertiary treatment serving a population of 2,146,951, in 343 instances. Use of 827 industrial ponds by 31 industries in 44 States is also indicated. Indiana ranks first in usage with 159 ponds and Callfornia second with 140. Ponds were classed as effective by 66 percent of the 455 users who reported on this item. Of 149 reports on odors, 73% indicated nuisances. Insect problems were reported in only a small number of instances. Data are presented on design considerations and the mechanism of waste stabilization ponds. Aerobic ponds are given greatest emphasis. Photosynthesis and its dependence upon the algal mass, suitable temperature, incident light penetration, nutrient supply, and induced vertical mixing by wind are of prime importance in the stabilization mechanism. Odors are associated with prolonged anaerobic conditions, and these may persist up to 4 weeks following extended ice cover in cold climates, if BOD loadings are 25 lbs. per acre per day or greater. Nitrogen and carbon may be limiting factors in the development of an algal mass. Coliform, BOD, and nutrient removals are presented for various physical, chemical, and climatic conditions. Although fecal streptococci removal averaged 97% in a study pond, they were still discharged in the effluent at a rate of 700,000 per second in winter and 70,000 per second in summer. A striking similarity exists generally among the algal speciation in stabilization ponds, regardless of geographic location. The algal mass is, however, dependent upon unique pond conditions and location, and may vary upwards to nearly 5 million algal cells per milliliter, 34,000 p.p.m. by volume, or 30-35 tons per acre per year. The problem of blue-green algal mats and resultant pigpen odors in extremely localized areas is duscussed. Midges and midge larvae may have an impact on the nutrient cycle in a stabilization pond, and may pose a potential localized nuisance in some areas. Mosquito problems have usually been associated with growth of aquatic vegetation. Suggestions for minimizing the potential problem are discussed.
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  • 34
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    Biotechnology and Bioengineering 5 (1963), S. 201-209 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is a well-known fact that choosing a sequence of optimal control variables in each reactor tank of a multistage reactor system can result in a considerable increase of the desired product for a consecutive reaction system. The discrete maximum principle is applied to a generalized optimization problem of first order consecutive biochemical reaction system. A detailed numerical solution as an example is also presented for illustration.
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  • 35
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    Biotechnology and Bioengineering 5 (1963), S. 275-285 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Phenol-bearing waste waters continue to be an area of wide concern for various industries faced with the task of cleaning up effluents containing relatively small amounts of these materials. The microbiological aspects of the degradation of these materials in pure culture and waste treatment plants is reviewed. Actual operating experiences at three plants of The Dow Chemical Company, where phenols are present in combination with other widely varying waste constituents, are discussed.
    Additional Material: 6 Ill.
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  • 36
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    Biotechnology and Bioengineering 5 (1963), S. 331-345 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: These experiments show that ABS can be adsorbed and desorbed from microbial cell surfaces. The adsorption equilibria between the free and adsorbed phases are primarily influenced by the pH of the system. The effects of ABS upon the biochemical activities of bacteria depended upon the amount of ABS adsorbed and the type of bacteria present. The behaviour of ABS is essentially the same whether in the presence of pure or mixed bacterial cultures. Two desorption experiments with soil from a reclaimed water spreading basin which has received sewage over a six month period showed that at least 82% of the ABS “loss” was recoverable from the soil. In all the experiments carried out in this study no evidence was obtained for the biochemical degradation of ABS.
    Additional Material: 15 Ill.
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  • 37
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    Biotechnology and Bioengineering 5 (1963), S. 347-354 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: With the emphasis being given to the development of biologically soft detergents, it is necessary to establish eriteria defining biodegradability of these materials. It is the authors' opinion that a biologically soft detergent should have the following characteristics: (1) Under normal operations the material should be 85% removable by activated sludge. (2) Normally high discharges of the detergent should not influence biological activity. (3) The detergent should ultimately degrade to carbon dioxide and water.
    Additional Material: 6 Ill.
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  • 38
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    Biotechnology and Bioengineering 5 (1963), S. 367-384 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Because branched-chain alkyl benzene sulfonate (ABS) is well known to create water pollution problems in surface water and ground water, a study was made on the biodegradation of this surfactant along with other anionic and nonionic surfactants in detergents by water bacteria. Biodegradation was evaluated by the conventional river die-away test employing the methylene-blue method or surface-tension techniques as analytical tools. Under anaerobic conditions, sugar detergents (sucrose esters) seem to be an ultimate solution to water problems created by branched-chain ABS; in aerated water, straight-chain ABS, sulfo tallow methyl esters, and nonionic surfactants are preferable to branched-chain ABS to improve water problems.
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  • 39
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    Biotechnology and Bioengineering 5 (1963), S. 1-7 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A cost analysis of the continuous fermentation of penicillin G shows that materials cost and product yields are more significant than throughput rate. Number of fermentation stages, productivity, and the implications for research and development are discussed.
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  • 40
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 37-44 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch die Anwendung von Methylal als Lösungsmittel gelang erstmalig die Herstellung einer GRIGNARD-Lösung von Chlordimethyläther. Die Stabilität der GRIGNARD-Verbindung des Chlordimethyläthers ist von der Temperatur abhängig. Bereits bei Zimmertemperatur tritt Zerfall in Äthylen, Propylen, Cyclopropan und Chlormagnesiummethylat ein. Der Chemismus dieser Zerfallsreaktion wird diskutiert.
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  • 41
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 68-70 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Verteilungsdaten von Vanadium(V) zwischen HCl verschiedener Konzentration und Tributylphosphat sowie nach der Jobschen Methode der isomolaren Serie wird die Existenz eines Disolvates VOCl3 · 2TBP bei höheren HCl-Konzentrationen (〉 6n HCl) nachgewiesen. Das Vorliegen eines Trisolvates VOCl3 · 3TBP bei niederen HCl-Konzentrationen (3-4n HCl) ist wahrscheinlich.
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  • 42
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 88-90 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mit Hilfe von substituierten Phenolen und p-Cymol werden neue substituierte Chromone beschrieben.
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  • 43
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 101-105 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: N.N-Bis-(β-chloräthyl)-amin reagiert mit Schwefelkohlenstoff unter Bildung von 2,3,5,6-Tetrahydro-thiazolo-[2,3-b]-thiazolium-chlorid. Die Struktur der daraus entstehenden Pseudobase wird diskutiert.
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  • 44
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 309-314 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Chromatographie an Polyamidpulver gelang die Trennung eines Gemisches von Methylolverbindungen des 4,4′-Dihydroxydiphenylsulfons. Die so isolierten Methylolverbindungen konnten identifiziert und weiterhin durch Reduktion entsprechender Carbonsäuren des 4,4′-Dihydroxydiphenylsulfons mit LiAlH4 dargestellt werden.
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  • 45
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 324-326 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: N,N-Bis-(β-chloräthyl)-hydrazin reagiert mit Schwefelkohlenstoff unter Bildung von 2-Thio-4-(β-chloräthyl)-tetrahydro-1,3,4-thiadiazin.
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  • 46
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 1-13 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Unter den in der Polyenkette unsymmetrisch durch die CN-Gruppe substituierten basischen Trimethincyaninen(1) waren bisher nur Farbstoffe bekannt, die sich vom 2-Cyanmethyl-benzthiazol und vom 2- und 4-Cyanmethyl-chinolin ableiten. Die Reihe dieser Farbstoffe wird nunmehr durch solche mit Benzoxazol-, Benzimidazol-(2) und Benzselenazol-Kern in Nachbarschaft zum CN-Substituenten ergänzt und der Einfluß der Heterokerne und der CN-Gruppe auf die Lage des Absorptions-Maximums untersucht. Die beschriebenen Farbstoffe sensibilisieren fotografische Halogensilberemulsionen.
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  • 47
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 48
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 117-124 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2-Hydroxymethylencyclanone wurden unter verschiedenen Bedingungen mit Äthylendiamin bzw. o-Phenylendiamin kondensiert. In neutraler Lösung entstanden Bis-Kondensationsprodukte unterschiedlicher Stabilität. Die Reaktion im sauren Medium führte mit o-Phenylendiamin zu 2,3-benzkondensierten bicyclischen Diazepiniumsalzen, die auch aus den Bis-Kondensationsprodukten der 2-Hydroxymethylencyclanone hergestellt werden konnten. Cyclisierungsversuche mit den Äthylendiaminderivaten schlugen fehl.
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  • 49
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 161-165 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Darstellung eines Triphenylmethanfarbstoffes, dessen Benzolkerne durch Sauerstoff-brücken miteinander verbunden sind.
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  • 50
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 51
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 150-161 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1,1-disubstituierte Semicarbazide setzen sich in Gegenwart von Natriumäthylat mit Cyanessigsäureester zu substituierten N-Aminouracilen um, die nach dem Vorbild der TRAUBE-schen Synthese in weitere Derivate des Uracils umgewandelt werden können. Die UV-Spektren der erhaltenen Verbindungen werden diskutiert.
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  • 52
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 180-185 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Sowohl cis- als auch trans-1,2-Dimethyl-1,2-dihydroxy-acenaphthen erleiden bei der Behandlung mit Thionylchlorid eine Umlagerung zum bisher unbekannten 1-Methyl-2-chlormethyl-acenapthylen. Dadurch werden 1,2-Dimethyl-acenaphthylen und seine Derivate leicht zugänglich. Sie neigen wie Acenapthylen selbst zur anionischen Polymerisation.
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  • 53
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 192-201 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von o- und Novovanillin wurden einige Chalkone und Benzalacetone aus den n-Propyl- und n-Butyl-äthern dieser Verbindungen synthetisiert. Sie wurden bezüglich ihrer Additionsfähigkeit gegenüber Nitroparaffinen geprüft, wobei ein Mol des Chalkons bzw. substituierten Benzalacetons mit einem Mol Nitroparaffin reagierte. Es entstanden im Falle der Kondensation von 2,3-Dialkoxychalkonen 1-Phenyl-3-[2′,3′-dialkoxyphenyl]-4-nitroalkanone-(1), im Falle der 2-Alkoxy-3-methoxybenzalacetone 4-[2′-Alkoxy-3′-methoxyphenyl]-5-nitroalkanone-(2). Aus 2-Propoxy- und 2-Butoxy-3-äthoxybenzalaceton ließen sich mit Nitroparaffinen keine beständigen und eindeutigen Addukte gewinnen.
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  • 54
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 229-237 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The composition and stability of aluminium-alizarin 3-sulphonate chelate has been studied by spectrophotometric and electrical conductance measurements. The red coloured chelate (λmax 470 mμ) has a composition 1:2 (metal: chelating agent). The chelate is stable between pH 2.5 and 4.5. The values of log K as calculated by two different methods are 7.2 ± 0.3 and 7.5 ± 0.2 at 25°C (pH 3.5 ± 0.2). Suggestions have also been made about the position of the chelate ring in the metal chelate.
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  • 55
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 331-336 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird ein Verfahren zur Synthese von vicinalen Aminoalkoholen der Steroidreihe beschrieben. Durch Aufspaltung von Steroidepoxyden mit Ammoniak in Äthylenglykol entstehen Aminoalkohole mit diaxialer Stellung der funktionellen Gruppen.
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  • 56
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    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 27-31 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über die Synthese von Aminoacylderivaten des Norephedrins berichtet, die durch Umsetzung von N-Phthalaminosöurechloriden mit Norephedrin gelingt.
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  • 57
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 4,4′-Dihydroxydiphenylmethan, -sulfid, -sulfoxyd und -sulfon werden im alkalischen pH-Bereich der Formaldehydkondensation unterworfen. Die ermittelten Reaktivitäten dieser Verbindungen verhalten sich in der Reihenfolge -CH2-:-S-:-SO-:-SO2- wie 130:65:6,5:1. Der Einfluß von Substituenten auf die Kondensationsgeschwindigkeit wurde an Hand des nitro-, chlor-, carboxyl- und methylgruppensubstituierten 4,4′-Dihydroxy-diphenylsulfons untersucht. Durch papierchromatographische Untersuchung der zu verschiedenen Zeiten entnommenen Proben konnten Art und Bildungsgeschwindigkeit entstehender Methylolverbindungen ermittelt werden.
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  • 58
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    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 327-329 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electro- and physico-chemical studies of Indian (Agra) sandy loam soil reveal that the clay mineral present in it is mainly illites.
    Additional Material: 1 Ill.
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  • 59
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 14-19 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3,3′-Dibrom-dipropyläther wurde unter Verwendung von Tetrahydrofuran als Lösungsmittel in die entsprechende bifunktionelle Grignard-Verbindung überführt, diese mit aliphatischen Aldehyden oder Aceton zu 4,4′-Dihydroxy-dialkyläthern umgesetzt und daraus die Bromäther hergestellt. Außerdem wurden Bis-(4-brombutoxy)-octan-(2,7) und 3,3′,4,4′,-Tetrabrom-dibutyläther Synthetisiert.
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  • 60
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 62-69 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Darstellung und Eigenschaften von trans- und cis-p-Terphenyläthylenen werden beschrieben.
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  • 61
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 87-91 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Konstitution der von uns aus 3-Alkoxypyrenen erhaltenen isomeren 3-Alkoxypyrenaldehyde wird weiterhin gesichert, so daß auch die 3,10-Alkoxyaldehyde klar definiert sind.Verschiedene Dialkoxypyrene werden beschrieben.Das Reaktionsvermögen der 3,8- und 3,10-Alkoxypyrenaldehyde wird durch Kondensation mit methylenaktiven Verbindungen studiert. In fast allen Fällen reagiert 1 Mol des Aldehyds mit 1 Mol der letzteren, bis auf die Umsetzung des 3,8-Propoxypyrenaldehyds mit Acetessigester, bei welcher sich die Bis-acetessigesterverbindung bildete.
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  • 62
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 105-112 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reactions of aluminium isopropoxide and aluminium chloride with salicylic, mandelic and lactic acids in different stoichiometric ratios have been studied under absolutely anhydrous conditions. Mandelic and lactic acids were found to give tri-derivatives, whereas the salicylic acid gave only di-salicylate when the ratios of alkoxide and the acid was 1:3 (or slightly higher) or an equimolecular mixture of di-and tri-salicylate when the ratio was increased to 1:3.4 (or 3.4).
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  • 63
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Unter Hinweis auf die Bedeutung der Säulenchromatographie für die Differenzierung von Gemischen aus strukturell nahe verwandten Verbindungen werden ausgewählte Materialien (Kieselgel, einheimisches Kieselgur, Aerosil, Ton, Seesand, Glaspulver, Aluminium-oxyd, lepidoide Kieselsäure) auf ihre Eignung als säulenchromatographisches Filterhilfsmittel bei der Trennung von Saccharidgemischen an Aktivkohle überprüft. Für diese Zwecke ist lediglich die lepidoide Kieselsäure geeignet. Trotz ihrer relativ großen inneren Oberfläche treten unerwünschte Adsorptivkräfte gegenüber Sacchariden bzw. beeinträchtigende Auswirkungen auf das Adsorptionsvermögen der Kohle nicht in Erscheinung. Die lepidoide Kieselsäure kann daher im Austausch mit dem bisher fast ausschließlich verwendeten Celite bei der Säulenchromatographie an Aktivkohle eingesetzt werden.
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  • 64
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 178-186 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Synthese von ω-[Benzimidazolyl-(2)]-propion- bzw. -buttersäuren beschrieben, die in 5-Stellung durch eine Stickstofflostgruppe und in 1-Stellung durch eine Methyl-, Äthyl- oder Phenylgruppe substituiert sind.
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  • 65
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 187-196 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eine Auswahl CH-acider Substanzen wurde mit Formalin und Bis-(2-chloräthyl)-amin-hydrochlorid zu Mannich-Basen aminomethyliert.
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  • 66
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 219-224 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The composition and stability of the chelate formed between uranyl ion (II) and 1 (o-arsonophenylazo) 2 naphthol 3:6 disulphonate (Thoron) have been investigated using spectrophotometric method. The chelate is red in colour and has λmax at 510mμ. The composition as determined by different methods is 1:1. The chelate is stable between pH 2.5 and 5.0. The values of log K as determined by two different methods are 4.2 ± 0.25 and 4.54 ± 0.15 respectively at pH 3.0 and at 25°.
    Additional Material: 4 Ill.
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  • 67
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 275-278 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Synthese einer Anzahl neuer Phenylisopropylaminoacetonitrile beschrieben.
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  • 68
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 255-262 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: p-Methoxy- und p-Äthoxy-phenylhydrazin-hydrochlorid bilden mit Kaliumrhodanid die 1-(p-Alkoxy-phenyl)-thiosemicarbazide. Aus p-Hydroxy-, p-Methoxy- und p-Äthoxy-phenylhydrazin erhält man mit Methyl- und Äthylsenföl 2,4-disubstituierte Thiosemicarbazide, mit Phenylsenföl 1,4-disubstituierte Thiosemicarbazide und mit Allylsenföl Derivate des Hydrazin-N,N′-bis-thiocarbonsäure-allylamids. Die 2-(p-Methoxy-phenyl)-4-alkyl-thiosemicarbazide lassen sich durch Erhitzen über den Schmelzpunkt in die isomeren 1,4-disubstituierten Thiosemicarbazide umlagern. Diese werden durch p-Benzochinon zu den p-Alkoxy-phenylazo-thioformamiden dehydriert.
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  • 69
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 285-290 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1-Oxo-cycleno(3,2-d)-2-methyl-thiazole werden durch Bleisalzpyrolyse der entsprechenden Thiazoldicarbonsäuren oder HANTZSCHsche Thiazolsynthese mit 2-Chlor-cyclandionen-(1,3) erhalten.
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  • 70
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 320-322 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es gelang 2,6-Dioxybenzaldehyd, γ-Resorcylaldehyd, nach einer neuen Synthese und 4-Brom-3-amino-dimethylanilin sowie 4-Brom-3-hydroxy-dimethylanilin darzustellen.
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  • 71
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    Journal für Praktische Chemie/Chemiker-Zeitung 22 (1963), S. 202-213 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Reaktion zwischen Natriummethylat und p-, m-, bzw. o-Cl-α-Br-Propiophenonen untersucht. Es wird festgestellt, daß die Reaktionen nicht nur unter der Bildung der entsprechenden Epoxyden verlaufen, wie es in der Literatur(1)(2) angenommen ist, sondern auch unter der Bildung aliphatischer Ketone, die sich als Isomerisationsprodukte der Epoxyde erwiesen. Die Struktur der erhaltenen neuen Verbindungen (Epoxyde und aliphatische Ketone) wurde chemisch wie auch spektroskopisch bewiesen.
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  • 72
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    Journal für Praktische Chemie/Chemiker-Zeitung 22 (1963), S. 214-224 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch physikalisch-chemische Methoden wurden über 300 binäre Systeme der Alkoxysilane, Aroxysilane, Methylsiloxane und ihrer organischen Analoga mit organischen Elektronen-akzeptoren und -donatoren untersucht. Sowohl die Elektronen-donator- als auch die -akzeptor-Eigenschaften der Alkoxysilane nehmen mit Verringerung der Zahl der Alkoxygruppen am zentralen Siliciumatom zu. Das ist höchstwahrscheinlich durch sterische Hinderung bedingt.Es wurde eine neue Art der zwischenmolaren Wechselwirkung zwischen Alkoxysilanen und den polaren Derivaten des Benzols (C6H5X) gefunden.Die Donator-Akzeptor-Eigenschaften der Si---O-(Si)-Bindung in den Polymethylsiloxanen gegenüber organischen Molekeln treten nur in seltenen Fällen auf.Die Elektronen-donator-Eigenschaften des Sauerstoffatoms fallen in der Reihenfolge und die -akzeptor-Eigenschaften des Siliciumatoms in der Reihenfolge \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm C} - {\rm O} - {\rm C} 〉 {\rm C}_{\left({{\rm alk}} \right)} - {\rm O} - {\rm SiC}_{\left({{\rm ar}} \right)} - {\rm O} - {\rm Si} \gg {\rm Si} - {\rm O} - {\rm Si} \gg \left({\rm O} \right){\rm Si} - {\rm O} - {\rm Si} $$\end{document} und die -akzeptor-Eigenschaften des Siliciumatoms in der Reihenfolge \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm C}_{\left({{\rm ar}} \right)} - {\rm O} - {\rm Si} 〉 - {\rm C}_{\left({{\rm alk}} \right)} - {\rm O} - {\rm Si} \gg {\rm Si} - {\rm O} - {\rm Si}{\rm .} $$\end{document}.
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  • 73
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    Journal für Praktische Chemie/Chemiker-Zeitung 22 (1963), S. 255-258 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über Umsetzungen von Dimethylberyllium mit Piperidin und Morpholin berichtet.
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  • 74
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    Journal für Praktische Chemie/Chemiker-Zeitung 22 (1963), S. 113-124 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Relative Reaktivitäten substituierter Methane, Äthane und Toluole (Benzylverbindungen) bei der H-Abspaltung durch tert.-Butoxyradikale werden bestimmt. Im wesentlichen bedingen Konjugations- und polare Effekte der Substituenten die Reaktionsfähigkeit der genannten Verbindungen. Die Logarithmen der Reaktivitätswerte sind den Hammettschen σp-Konstanten der Substituenten proportional, im Verhältnis zum Wasserstoff erhöhen jedoch alle Substituenten unabhängig von ihrer Polarität die Reaktionsfähigkeit. Die Reaktionskonstante σ beträgt -2,0 für Methylverbindungen, -1,9 für Äthylverbindungen und -0,5 für Benzylderivate.
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  • 75
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    Journal für Praktische Chemie/Chemiker-Zeitung 22 (1963), S. 186-191 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Trialkylphosphite lassen sich bei Temperaturen zwischen 20 und 80° mit molekularem Sauerstoff in die entsprechenden Trialkylphosphate überführen; die Reaktion wird durch UV-Bestrahlung beschleunigt, durch Zugabe von Hydrochinon gehemmt. Triphenyl-, Tri-(o-kresyl)-, Trixylenyl- und Monophenyl-di-(2-äthylhexyl)-phosphit sowie Dialkylphosphite lassen sich unter den angewandten Versuchsbedingungen nicht autoxydieren.
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  • 76
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    Journal für Praktische Chemie/Chemiker-Zeitung 22 (1963), S. 225-227 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird eine adsorptionschromatographische Methode zur Trennung der isomeren Nitraniline unter Verwendung von Aluminiumoxyd als Adsorbens beschrieben. Dabei werden die Löslichkeitsunterschiede der Isomeren in Benzol, das als Elutionsmittel dient, zur Trennung ausgenutzt.
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  • 77
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    Journal für Praktische Chemie/Chemiker-Zeitung 22 (1963), S. 241-249 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die katalytische Aktivität von Chelaten Schiffscher Basen des Salizylaldehyds und des 2-Amino-benzaldehyds mitgeteilt. Untersucht wurde die Zersetzung von H2O2 durch Co2+-Chelate. Co2+ wird verglichen mit dem Saliziylaldehydäthylendiimin durch 2-Aminobenzaldehydäthylendiimin weiter stark aktiviert. Die Reaktionsgeschwindigkeitskonstanten sowie die Aktivierungsenergien der Reaktion werden ermittelt.
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  • 78
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    Journal für Praktische Chemie/Chemiker-Zeitung 22 (1963), S. 304-313 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Darstellung von 1-Methyl-4-nitro-5-alkylamino-imidazolen beschrieben. Ihre katalytische Hydrierung und die des 1-Methyl-4-nitro-5-amino-imidazols führt zu unbeständigen Diaminen, deren Isolierung und Cyclisierung mißlangen. Acetylierungsreaktionen des Nitramins ergaben nur das N-Diacetylderivat. Die Nitro-alkylamino-Verbindungen lassen sich glatt formylieren und acetylieren. Durch Hydrierung entstehen daraus stabile Acylderivate des 4,5-Diamino-imidazols. Ihre Cyclisierung zum Imidazo[d]imidazolgerüst gelang nicht.
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  • 79
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    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 272-276 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Von fünf α-Ketocarbonsäuren wurden durch Reaktion mit N, N-Bis-(β-chloräthyl)-hydrazin die entsprechenden Hydrazone erhalten. Die Hydrazone der Brenztraubensäure, α-Ketobuttersäure und α-Ketovaleriansäure ließen sich mit PtO2/H2 zu den α-[N, N-Bis-(β-chloräthyl)-hydrazino]-carbonsäuren hydrieren. Bie den Hydrazonen der Glyoxylsäure und phenylglyoxylsäure gelang die Hydrierung nicht.
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  • 80
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    Journal für Praktische Chemie/Chemiker-Zeitung 22 (1963), S. 14-28 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die IR-Spektren der verschiedenen optisch aktiven Formen einiger Carnitinderivate werden aufgenommen. Die Absorptionen werden weitgehend den Schwingungen der einzelnen funktionellen Gruppen zugeordnet. Die IR-Spektren der razemischen und optisch aktiven Formen stimmen beim Carnitinäthylester und Acetylcarnitinnitril überein, bei den Carnitinnitriltetrachloroauraten treten nur geringe Unterschiede auf, während sich die Spektren des razemischen und des (+)- bzw. (-)-Acetylcarnitins sehr deutlich voneinander unterscheiden.
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  • 81
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 151-160 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden die Gleichgewichte zwischen Flüssigkeit und Dampf des Systems Methanol-Dimethylformamid (DMFA) isobar bei 130, 250, 400, 550 und 760 Torr in einer Umlaufapparatur gemessen. Aus einer Anwendung des Konsistenzkriteriums von Redlich und Kister auf die Messungen bei 130 Torr ergab sich eine Mischungsenthalpie von - 63J mol-1. Über ein Näherungsverfahren wurden für isotherme Schnitte die Konstanten des Ansatzes von Redlich-Kister berechnet. Die Meßwerte konnten damit innerhalb eines Fehlers von ± 3% rückwärts berechnet werden. Die thermodynamischen Excessfunktionen wiesen auf stärkere zwischenmolekulare Wechselwirkungen (ΔGE〈0,δHM〈0) und kooperative Orientierung hin (ΔSE〉 0).
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  • 82
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 197-201 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Oxalylbromid substituiert aromatische Kohlenwasserstoffe in Abwesenheit von Katalysatoren an den Kohlenstoffatomen, an denen der Index der freien Valenz am höchsten ist. Die Bromwasserstoff-Entwicklung bei der Reaktion gehorcht einer Kinetik II. Ordnung, die Kohlenmonoxyd-Entwicklung gehorcht gegen Ende der Reaktion einer Kinetik I. Ordnung.
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  • 83
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 210-218 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Autoxydation der tricyclischen Systeme Cyclopent-[c.d]-indan (I) und Cyclohept-[c.d]-indan (II) wurde untersucht. Nur Cyclohept-[c.d]-indanyl-hydroperoxyd (IV) gibt mit p-Nitrobenzoesäure einen Perester, der bei Criegee-Umlagerung in den Lactolester (XIII) übergeht. Der Lactolester XIII gibt bei Verseifung das Halbketal XV, das alkalisch zum 10-Ringsystem des Ketophenols XV a isomerisiert.Der Vergleich mit den bereits in der Literatur mitgeteilten Ergebnissen am Tetraphthen und Hexahydrophenalin zeigt in Übereinstimmung mit Modellvorstellungen, daß der Einschub des Sauerstoffs als „transannulare“ Brücke (wie ihn die Bildung der Lactol aus den Persäureestern erfordert) eines 9- und 10-Ringsystems möglich ist, den aber beim 8-gliedrigen Ringsystem (aus I) sterische Gründe verhindern. Die Isomerisierung der Lactolformen zu Ketophenolen gelingt, ebenfalls sterisch bedingt, nur, falls die Ausgangsverbindungen die Bildung eines zum Hydroxyl peripheren Ringes mit mindestens 10 C-Atomen gestatten.
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  • 84
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    Journal für Praktische Chemie/Chemiker-Zeitung 20 (1963), S. 244-249 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch katalytische Dampfphasen-Dehydrierung von 1,3-Dihydroisothionaphthen (IV) wird erstmalig Iso-thionaphthen (I) erhalten, dessen Eigenschaften beschrieben werden. Das neu dargestellte 3,4-Tetramethylen-thiophen (III) ließ sich nicht zu I dehydrieren.
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  • 85
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    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 39-49 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend von 2-Mercaptothiazolen und imidazolen und aromatischen bzw. aliphatischen Sulfenylchloriden wurde eine Reihe unsymmetrischer Disulfide hergestellt. Die eingesetzten Ausgangsprodukte zeichnen sich durch deutliche Unterschiede in der Reaktionsfreudigkeit aus. Ein Teil der erhaltenen Disulfide wurde, zwecks näherer Charakterisierung, der Dünnschichtchromatographie unterworfen. Es wurden einige Zusammenhänge zwischen der Konstitution der Verbindungen und deren Rf-Werten aufgezeigt.
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    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 99-102 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch thermische Zersetzung bzw. Solvolyse einiger einfacher α-Halogenäthern bzw. -ester wurden in guten Ausbeuten wasserfreier Monochloracetaldehyd sowie Derivate von Glykolaldehyd und Glyoxal dargestellt.
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  • 87
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    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 92-98 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden Versuche zur Trennung der Ionen des Kaliums, Rubidiums und Caesiums mit Hilfe von Flußsäure als Elutionsmittel durchgeführt. Als Ionenaustauscherharz diente Wofatit KPS in der 16% vernetzten Form. Die Versuche wurden mit Säulen aus Polyäthylen durchgeführt, die eine Länge von 50 cm und einen Durchmesser von 1 cm besaßen. Im Eluat erschienen nacheinander Kalium, Rubidium und Caesium. Dabei konnte das Kalium vollständig vom Caesium getrennt werden, während die Trennungen Kalium/Rubidium und Rubidium/Caesium noch nicht quantitativ erfolgten. Es wird versucht, die erhaltenen Ergebnisse auf einfache Art zu deuten.
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    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 149-162 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von Triarylsilanen mit Allylbromid in Gegenwart von AlCl3 gestattet es, die entsprechenden Triarylbromsilane in guten Ausbeuten zu erhalten. Erstmalig wurden dargestellt: Tris(p-fluorphenyl)bromsilan, Tris(p-chlorphenyl)bromsilan und Tritolylbromsilan.Aus dem bisher noch unbekannten Tris(p-bromphenyl)silan wurde durch Bromierung in CCl4 das Tris(p-bromphenyl)bromsilan erhalten. In Gegenwart von Katalysatoren wird Allylbromid von Triorganosilanen zu Triorgano-3-brompropylsilanen addiert. Es werden einige typische Reaktionen mit diesen Verbindungen beschrieben.Beim Umsatz von Triarylsilanen mit Vinyl- und Allylhalogeniden bei Temperaturen von 580-640° erhält man Triarylalkenylsilane und Triarylhalogensilane. Einige neue Silane und zwar Tritolylallylsilan, Tris(p-chlorphenyl)allylsilan und Tris(p-chlorphenyl)-vinylsilan wurden isoliert.Von den Triarylsilanen und einigen anderen hocharylierten Silanen wurden die IR-Spektren aufgenommen und aus der SiH-Valenzschwingung die Elektronegativität der Silylgruppe und die Kraftkonstante der SiH-Bindung annähernd berechnet.
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    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 184-185 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über eine Gewinnung von Isopren aus p-Cymol mittels eines Laboratoriumsgenerators berichtet. Als Nebenprodukt konnte Propylen nachgewiesen werden.
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  • 90
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    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 208-213 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus dem Vergleich berechneter und gemessener Dipolmomente werden Rückschlüsse auf die Dipolrichtung der C—OH-Gruppe in nichtaromatischen Systemen gezogen. An Hand von IR-Spektren werden die Wasserstoffbrückenbindungsverhältnisse bei cyclischen Halohydrinen diskutiert.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
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  • 91
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 250-265 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Analyse hochmolekularer Produkte der Erdölverarbeitung erfordert wegen des komplexen Charakters dieser Produkte einen großen Aufwand an Trennleistung und -güte. Im vorliegenden Beitrag wird die intensive Zerlegung der bei der chromatographischen Gruppentrennung eines Phenolextraktes aus Neutralöl I (Tuimasa) erhaltenen KW -stoffgruppen beschrieben. Über die Gewinnung des Ausgangsproduktes und dessen chromatographische Gruppentrennung sowie über die angewendeten Methoden der Strukturgruppenanalyse wurde bereits berichtet.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 92
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 286-294 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eine Reihe von aliphatischen, aromatischen und heterocyclischen s-Trithianen wurde nach dem H2S-Verfahren hergestellt. Ferner wurden erstmalig aromatische s-Trithiane durch die Umsetzung der entsprechenden Aldehyde mit Natriumthiosulfat in Gegenwart von Salzsäure gewonnen. Die biociden Eigenschaften der s-Trithiane wurden untersucht.
    Additional Material: 3 Tab.
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  • 93
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 17-32 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Zur Analyse von Mono-, Di- und Cycloolefinen, wie sie in technischen C6-Kohlenwasserstoff-Fraktionen vorliegen, wurde eine Kombination von Feindestillation und Gaschromatographie benutzt. Als wesentliches Hilfsmittel erwies sich die Hydrierung der Proben unter gaschromatographischen Bedingungen. Eine Anzahl von Flüssigphasen unterschiedlicher Polarität wurde hinsichtlich ihrer Trenneigenschaften untersucht. Die Retentionsvolumina der interessierenden Kohlenwasserstoffe sind angegeben.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 94
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 56-63 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Synthese einiger am Stickstoff durch Aryl und Heteroaryl substituierter Propansultame-(1, 3) wird beschrieben, ebenso eine verbesserte Darstellung des nichtsubstituierten Propansultams-(1, 34). Es folgt die Beschreibung einiger am Stickstoff durch Heteroaryl substituierter Butansultame-(1, 4). Der Umsatz von Hydrazin und Phenyl-hydrazin mit Chlorpropansulfochlorid und Chlorbutansulfochlorid führt zu verschiedenen Sulfonamiden. Das Chlorpropansulfonsäure-phenylhydrazid konnte in ein Pyridazinderivat übergeführt werden.
    Type of Medium: Electronic Resource
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  • 95
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    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 117-122 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Potentiometrische und konduktometrische Messungen an sauren Tonen der Provenienz von Tehra zeigen u. a. mit zunehmender geologischer Tiefe einen mineralogischen Wechsel.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 96
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 135-137 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurde das System Natriumnitrit-Phosphoroxychlorid untersucht, um die neben Nitrosylchlorid entstehenden Reaktionsprodukte zu bestimmen. Dabei konnte entgegen früherer Darstellung kein NO gefunden werden. Die Reaktionsprodukte, die mittels gravimetrischer Analyse, stöchiometrischer Berechnung, der Destillation der gasförmigen Produkte und der röntgenographischen Untersuchung des festen Rückstandes bestimmt worden sind, bestätigen den durch Gleichung (1) dargestellten Reaktionsablauf: Das Infrarotspektrum eines CCl4-Eluats des festen Rückstandes zeigt, daß keine POCl3-Additionsprodukte enthalten sind.
    Type of Medium: Electronic Resource
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  • 97
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 174-179 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Pinakole der allgemeinen Formel ergeben bei der Behandlung mit Thionylchlorid in Gegenwart katalytischer Mengen Pyridin entweder cyclische Schwefligsäureester, Allylhalogenide oder Pinakolone. Beim 1,2-Dimethyl-cyclohexandiol-1,2 liefert nur das cis-Isomere einen cyclischen Schwefligsäureester.
    Type of Medium: Electronic Resource
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  • 98
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 33-36 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über die Darstellung von Phenyl-methyl-, Phenyl-α,o-trimethylen- und Phenyl-α-naphthyl-keten, über deren Eigenschaften sowie über ein Verfahren zur titrimetrischen Bestimmung von Ketenen berichtet.
    Type of Medium: Electronic Resource
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  • 99
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 64-67 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Für verschiedene TBP-Konzentrationen (10, 30, 50, 80  -  100 Vol.-%) wird die Abhängigkeit des Verteilungskoeffizienten des Vanadium(V) von der HCl-Konzentration (1  -  9n) im System Vanadium(V) [VOCl3]/HCl-n-TBP/Benzin bestimmt.
    Additional Material: 3 Ill.
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  • 100
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1963), S. 74-82 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der Einfluß von Lösungsmittel, Verdünnungsverhältnis und Waschmittelmenge auf Quantität und Qualität der bei einem Entparaffinierungsprozeß anfallenden Öle und Gatsche wird durch Untersuchungen an Schmierölfraktionen aus Tuimasinsker Erdöl, vornehmlich Neutralöl I, gezeigt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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