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  • 1985-1989  (726)
  • 1987  (726)
  • Chemical Engineering  (726)
  • Nuclear reactions
  • Physics
  • 101
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 663-667 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 102
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 672-676 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 103
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 104
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1761-1775 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Previous attempts to model the effect of deposition on removal efficiency in deep-bed filtration have relied heavily on the determination of empirical parameters even for monosized suspensions. A newly developed mathematical model not only significantly reduces this reliance, but takes full account of the polydispersity of suspensions. The results of eight runs on an experimental filter are compraed with the predictions of the mathematical model. Qualitative agreement is good; quantitative agreement is fair.
    Additional Material: 12 Ill.
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  • 105
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1334-1343 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new unit operation is presented that utilizes a rapid feed pressure swing cycle in a bed packed with catalyst and adsorbent to effect both reaction and separation. This hybrid device combines features of a cyclic-steady-state pressure swing adsorber with those of a flow-forced catalytic reactor. Feed sequences for the periodic separating reactor (PSR) are those of rapid, single-bed pressure swing adsorbers (PSA). Only the case of extremely fast reactions is considered here. A perturbed reaction-sorption equilibrium model is formulated and solved for isothermal operation for different equilibrium constants and reaction stoichiometries. The capacity and separation performance for an equilibrium-limited PSR (EPSR) can be of the same order of magnitude as PSA alone. For reactions involving a single reactant or single product, the principal component in a particular exit stream depends upon both the reaction stoichiometry and feed fraction of the process cycle. The pressure dependency of the reaction equilibrium expression is the cause of separation reversals as parameters are varied.
    Additional Material: 12 Ill.
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  • 106
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1344-1350 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper is focused on the analysis of interaction of free convection and exothermic chemical reaction. As a consequence of the chemical reaction, free convection effects can result. It is difficult to perform an analytical bifurcation analysis of the full nonlinear governing equations; however, Fourier expansion combined with a Galerkin approximation results in a small set of ordinary nonlinear differential equations (initial-value problem) that are amenable to analysis. Conditions for branching of the solution can be determined in an analytical way. A continuation algorithm makes it possible to calculate the branches of stability. The results of the approximative analysis are supported by the numerical integration of the full governing nonlinear equations.
    Additional Material: 9 Ill.
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  • 107
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1359-1370 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The local bubble frequency, the local phase holdups and the local bed porosity in three-phase fluidized beds were measured. Air, water, and 250 μm glass beads were used as the gas, liquid, and solid phases. The effects of gas and liquid velocities on phase holdups were studied. Time-averaged local gas holdup and bubble frequency were measured by an optical fiber probe. Mass balances were performed at various axial positions along the fluidized beds to check the accuracy of the measurements.
    Additional Material: 12 Ill.
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  • 108
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1387-1390 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 109
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 110
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1426-1434 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple and convenient method for predicting optimum chromatographic conditions from linear gradient elution experiments with a small column is presented and verified experimentally. The method was found to be very useful for a rapid survey of the nature of unknown proteins, for the estimation of optimum chromatographic conditions, and for scaling up the separation of proteins in ion exchange and hydrophobic interaction chromatography.Two applications were successfully carried out on the basis of the proposed method: (1) Separation of a protein mixture of ovalbumin and β-lactoglobulins A and B with both anion and cation ion exchange columns by means of column switching technique. In this method, the sample is always subjected to the elution process until it is collected as a purified fraction through the two columns. A special valving system is devised for this method. (2) Large-scale ion exchange chromatography separation of β-galactosidase. Linear gradient elution of crude β-galactosidase was carried out with a 30 L ion exchange gel column on the basis of data obtained with a small (23 mL) column.
    Additional Material: 16 Ill.
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  • 111
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1466-1472 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the analysis of countercurrent adsorption processes, an equilibrium theory in which local equilibrium between the fluid and the adsorbent phases is assumed has been used in the past to determine the composition of the pinch state that would be obtained for long columns. It is shown that this equilibrium theory is deficient and that certain mass transfer parameters, which are lost in the procedure by which the model equations for the equilibrium theory are formulated, can have a profound effect on the composition of the pinch.
    Additional Material: 5 Ill.
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  • 112
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1448-1465 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A one-dimensional model is developed to describe reaction between a nonvolatile liquid reactant and a dissolved gas reactant in an isothermal catalytic pellet partially wetted by a flowing liquid film. The kinetics are assumed to be first order and zero order with respect to the dissolved gas and liquid reactant, respectively. The model applies to cases in which there are negligible intraparticle gradients in the direction normal to the wetted surface. A modification of the overall transport coefficients enables the model to approximate cases in which these gradients are important, for both washcoated and uniformly impregnated catalysts. The analytical solutions enable an efficient examination of the interplay between the reaction and several mass transport processes. Conditions are determined for which the catalyst effectiveness is maximized at an intermediate wetting efficiency. It is shown that the maximum is a result of two counteracting processes. As the wetting efficiency is decreased from unity the effectiveness increases if the supply of the gas reactant is more effective on the nonwetted than the wetted part; i.e., effectiveness enhancement. However, if the wetting efficiency is sufficiently reduced, the excess liquid reactant depletes within the pellet, resulting in a decreased effectiveness. A criterion is derived that predicts the minimal activity necessary to initiate depletion of the liquid reactant for a given wetting efficiency. This is useful for determining the conditions for which the common literature assumption of an excess liquid reactant is violated. The model shows good agreement with published data in which the overall rate exhibits a maximum for an intermediate liquid flow rate.
    Additional Material: 13 Ill.
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  • 113
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1481-1495 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Optimal linear-quadratic (LQ) controller design is usually associated with state space techniques. However, when one has measurements of the outputs to be controlled, there are many advantages to designing these LQ controllers using input-output transfer function models. The design procedure leads to a discrete equivalent of the Wiener-Hopf equation, which can be solved using a spectral factorization approach.In this paper the design procedure is presented and various interpretations of the resulting controllers are discussed. In particular, the controllers are shown to be of the internal model controller (IMC) form, and the Wiener-Hopf procedure is shown to be a powerful way of selecting approximate model inverses and filters that yield good performance and robustness characteristics. The approach treats the problem of simultaneous disturbance rejection and set-point tracking, and it easily handles nonsquare systems.The design approach, its performance/robustness trade-offs, and the structure of the resulting controllers are demonstrated using models for several processes, including a two-input/one-output sheet forming process, a (3 × 3) multivariable level control problem, and a (2 × 2) multivariable catalytic reactor.
    Additional Material: 10 Ill.
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  • 114
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1563-1566 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 115
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1571-1575 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 116
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1580-1580 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 117
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 118
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1719-1726 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Changes in the pore structure of calcium oxide sorbents derived from calcium carbonate (c-CaO) and calcium hydroxide (h-CaO) reacting with sulfur dioxide are determined. Results show that the pore shape of c-CaO approximates a cylinder while that of h-CaO appears to be slit- or platelike. The pore volume of c-CaO is located in much smaller pores than that of h-CaO when compared on the basis of an equivalent pore shape model. The effect of sintering was to reduce surface area through coalescence of smaller pores, while only minor effects were observed upon pore volume and conversion from calcium oxide to calcium sulfate. Both sorbents expand to allow greater reaction than is possible given the initial porosity and formation of a larger volume product. The h-CaO reacts to higher levels of conversion than the c-CaO because the pore shape of the h-CaO allows for greater particle expansion and, therefore, reaction beyond the limits of the initial porosity.
    Additional Material: 8 Ill.
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  • 119
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1738-1742 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 120
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1747-1750 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 121
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1754-1756 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 122
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1757-1759 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 123
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1776-1780 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is shown that the solubility of organic solids in binary mixtures of partially miscible liquids is singular at the immiscibility critical point. The theoretically predicted maximum of solubility in the vicinity of the critical point is found experimentally. The effect is similar to the phenomenon observed near the gas-liquid critical point. The similarity of these two critical phenomena may have interesting technical applications and may provide guidelines for identifying promising new solvents for separation processes.
    Additional Material: 6 Ill.
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  • 124
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    AIChE Journal 33 (1987), S. 1-10 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model for surface shear in the contact line region of a steady state two-component evaporating thin film in the shape of a meniscus is developed. A constant vapor pressure boundary condition at the liquid-vapor interface is combined with experimental meniscus profile data to obtain temperature and composition profiles. The results are used to delineate the relative effects of meniscus shape, temperature, and composition on fluid flow toward the higher temperature in an evaporating meniscus. For the system analyzed, it is found that surface shear due to composition gradients and temperature gradients is the single most important contribution to flow in the evaporating, two-component capillary meniscus in the film thickness range 10-6 m ≤ δ ≤ 10-5 m. The effect of concentration on the vapor pressure leads to a maximum evaporation rate at a thickness of approximately 6 μm for the conditions studied. Theoretical results are discussed in the light of experimental observations.
    Additional Material: 18 Ill.
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  • 125
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 19-25 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Numerical calculations of the velocity and temperature fields were conducted for unsteady flows over a single circular cylinder and a bundle of cylinders. Periodic disturbances, natural or externally imposed, were considered. Periodic and averaged heat transfer rates were examined. Results compare favorably with experimental data. Calculations were carried out to predict heat transfer rates in regimes of unsteady flows that have not been tested experimentally.
    Additional Material: 10 Ill.
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  • 126
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 26-35 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A two-phase approach to the control and operation of complex chemical processes at their optimum operating conditions is presented. The first phase consists of on-line parameter identification and state estimation of approximate nonlinear dynamic process models using on-line and off-line measurements. In the second phase, the optimum operating strategy is determined by integrating and optimizing this identified process model over a selected time horizon into the future. The method is particularly suited to those processes that exhibit slow dynamic responses and are subject to disturbances that have a significant economic impact. Examples include batch chemical reactors, large distillation towers, and processes with significant holdup times such as large fluidized-bed reactors.
    Additional Material: 13 Ill.
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  • 127
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    AIChE Journal 33 (1987), S. 43-53 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental results for the batch extraction of amines using emulsion liquid membranes with an internal aqueous HCI solution are presented. Four amines and mixtures of one binary pair were studied. Reversibility of the acid-amine reaction within the internal droplets affected extraction rates. The reversible reaction model presented earlier satisfactorily predicts these experimental results.
    Additional Material: 9 Ill.
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  • 128
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    AIChE Journal 33 (1987), S. 36-42 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In chemical process control, the application of an optimal control strategy, dictated by the theory of the linear quadratic problem, does not always guarantee the best process performance. The main problem is that the unspecified weighting matrices in the quadratic performance index have a pronounced effect on the optimal control law derived from linear quadratic theory. In the past, values of the weighting matrices have been selected by experimenting with the process in much the same manner as a PID controller is tuned. The objective of the present study is to resolve the inverse problem of optimal regulator control, limiting the performance index in the quadratic form with two independent weighting matrices which are investigated. A new criterion has been developed such that the computation of determining those matrices can be carried out off-line in advance, and then stored in a computer for real-time use.
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  • 129
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    AIChE Journal 33 (1987), S. 99-108 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Human blood (blood bank, expired) sheared through stainless steel capillary tubing (508 μm ID) is analyzed for plasma hemoglobin to study the effect of shear-induced blood damage within the low-stress regime (stress ≤ 20 Pa). Blood damage results are described in terms of capillary length (related to blood residence time) and wall shear rate for assessing bulk and surface effects. A phenomenological model is proposed to explain these experimental results, obtained over a shear rate range to 7,000 s-1.
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  • 130
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    AIChE Journal 33 (1987), S. 109-120 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In centrifugal filtration, centrifugal forces serve as the driving force in the production of cakes. Centrifugal sedimentation leads to formation of a clear supernatant followed by a slurry and a cake that grows and compacts simultaneously. The slurry concentration is independent of radius but decreases everywhere within the suspension at the same rate with respect to time. The theoretical analysis of centrifugal filtration presented here takes cake compressibility and variable permeability into account. Experiments were carried out under low driving forces with a centrifuge having a diameter of 150 mm and speeds of 1,000-2,000 RPM. With centrifugal accelerations of 75-300 g and pressure differentials under 1 atm, the sedimentation process was relatively slow and could be observed experimentally with ease.
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  • 131
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    AIChE Journal 33 (1987), S. 141-145 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 132
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    AIChE Journal 33 (1987), S. 146-151 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 133
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    AIChE Journal 33 (1987), S. 152-156 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 134
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    AIChE Journal 33 (1987), S. 161-163 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 135
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    AIChE Journal 33 (1987), S. 169-169 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 136
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    AIChE Journal 33 (1987), S. 170-170 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 137
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    AIChE Journal 33 (1987), S. 170-171 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 138
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    AIChE Journal 33 (1987), S. 171-172 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 139
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    AIChE Journal 33 (1987), S. 172-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 140
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    AIChE Journal 33 (1987) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 141
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    AIChE Journal 33 (1987), S. 177-177 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 142
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    AIChE Journal 33 (1987), S. 202-210 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid phase mass transfer in a ternary system [R - A] + (B + E) has been analyzed according to the Nernst-Planck equation. The equilibrium isotherm was represented by the mass action law. In the case of DA 〉 DB 〉 DE, the resin phase concentration of B ion with time showed a peak. The height of the peak was influenced by the diffusivity ratio, equilibrium constant, and ionic valence. When the modified equilibrium constant K′ ≧ 100 in the case of A ion and K′ ≧ 500 in the case of B and E ions, the exchange rates of the ions could be obtained by approximating K′ = ∞.Experimental data on the change of the resin phase concentration y with time are represented. In a [R - H+] + (Na+ + Zn2+) system, the change of yNa with time showed a high peak. In a [R - H+] + (Na+ + Li+) system, the change of yLi with time showed a small peak. No peaks arose in a [R - Na+] + (H+ + Li+) system. The data agreed reasonably well with the values calculated according to the theoretical equations.
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  • 143
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    AIChE Journal 33 (1987), S. 218-224 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experiments were carried out on the electrodissolution of iron from a disk electrode rotating at 900 rpm in 1 M H2SO4. Current was measured as a function of applied potential. Potentiostatic current oscillations, all of which were chaotic, occurred over a range of applied potential. The characteristics of these chaotic oscillations were studied with the aid of state space plots and Poincaré sections, and with the calculation of ν, the correlation dimension; the latter quantity varied smoothly between 2.4 and 6.0 throughout the range of applied potential studied. The attractor for which ν = 2.4 can be represented by a three-dimensional state space plot.
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  • 144
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    AIChE Journal 33 (1987), S. 232-238 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A modified sealed-tube apparatus has been developed for the measurement of the critical temperatures of thermally unstable fluids. The apparatus has been used to measure the critical temperatures of the normal alkanes from n-octane to n-hexadecane. Since the higher alkanes (with more than 10 carbon atoms) decompose at temperatures well below their critical temperatures, a new method of analysis of the apparent critical temperature vs. time data has been developed. This method employs reaction kinetics based on an irreversible first-order reaction and is used to linearize the data and to perform an unambiguous extrapolation to the critical temperature of the undecomposed substance. The method is successful because the temperature history of the substance is recorded by computer, and ampoule contents are analyzed at the completion of the experiment. The critical temperatures of the n-alkanes reported in this paper have been compared with values found in previous studies.
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  • 145
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    AIChE Journal 33 (1987), S. 250-257 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Many techniques that are used for analyzing the structure of large-scale, interactive systems (including the structural dominance analysis and singular-value decomposition methods) require a careful scaling of input and output variables to yield useful results. A suitable scaling procedure motivated by physical arguments and aimed at expressing input and output variables in common terms is presented and illustrated through several examples, including nonlinear lumped-parameter and distributed-parameter models.
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  • 146
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    AIChE Journal 33 (1987), S. 267-273 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dissolution kinetics of alumina in aqueous solution was studied in batch and continuous systems. Data were correlated by the kinetic equation C(t) = 1 - exp(-ktα). The parameter k was a function of temperature and acid concentration, while the parameter α remained constant.The temperature variation of k was accurately represented by an Arrhenius-type equation with a temperature coefficient, 18,200 kJ/kmol. The data obtained in batch experiments were free of mass transport and mixing effects. Adsorption-desorption equilibrium of hydrogen ion at the alumina surface was observed. The results supported postulated reactions reported in the literature for alumina dissolution. The basic features of the mechanism include hydration of the aluminum oxide surface, hydrogen ion adsorption followed by reaction to form a positively charged surface species [Al(OH)2+], formation of stable surface species [AlOOH and (Al(OH)2)2 SO4], and desorption of products.
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  • 147
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    AIChE Journal 33 (1987), S. 282-296 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An efficient and rigorous strategy is presented for evaluating the first-order sensitivity of the optimal solution to changes in process parameters or process models. An algorithm that constructs a reduced Hessian in the null space of the equality constraints is used to solve the sensitivity equations; the resulting effort to solve these equations depends only on the space of the decision (independent) variables. Consequently, large computational savings can be realized because the solution procedure eliminates the need for obtaining second partial derivatives with respect to tear (dependent) variables explicitly. The method is applied to several flowsheeting examples in order to determine efficiently the sensitivity of the optimal solution to parametric and physical property model changes.
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  • 148
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    AIChE Journal 33 (1987), S. 297-302 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dispersion of artificially produced softwood pulp flocs in controlled, plane, turbulent Couette flow was studied by using both monocular and stereoscopic film techniques. The mechanisms of controlled floc formation and of dispersion are proposed. For the latter, two mechanisms were observed, one global that involves deformation, breaking, and fragmentation, and one local that involves surfac erosion. The effect of the flow field stress level on the time and rate of dispersion is presented.
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    AIChE Journal 33 (1987), S. 312-315 
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    AIChE Journal 33 (1987), S. 319-321 
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    AIChE Journal 33 (1987), S. 328-330 
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    AIChE Journal 33 (1987), S. 336-340 
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    AIChE Journal 33 (1987), S. 347-350 
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    AIChE Journal 33 (1987) 
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    AIChE Journal 33 (1987), S. 500-502 
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  • 156
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    AIChE Journal 33 (1987), S. 515-518 
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    AIChE Journal 33 (1987), S. 524-527 
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  • 159
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    AIChE Journal 33 (1987), S. 711-721 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model for the physical vapor deposition of compound semiconductor films that describes film growth from component molecular beams is presented. Constitutive relationships are used in the model to account for incomplete adsorption from the incident molecular beams, emission of adsorbed components into vacuum, and surface reactions of the elemental species. The model predicts film composition and growth rate as a function of incident fluxes and substrate temperature. It is applicable for important binary and ternary alloy semiconductors including the II-VI and III-V compounds over the range of deposition conditions yielding both stoichiometric and two-phase films. In this paper the model equations and the behavior predicted by the model are described for a number of material systems including (CdHg)Te, (CdZn)S, and CuInSe2.
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    AIChE Journal 33 (1987), S. 747-752 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data on the rate of dissociation of methane hydrates are presented. The data were obtained from hydrate mass loss measurements using an electrobalance. A resistance heater with a known heat flux was used in the dissociation experiments. A mathematical model describing the dissociation process is also presented. The model, based upon first principles, assumes that the water formed during dissociation is blown away by the methane gas produced so that the dissociation process may be regarded as a moving-boundary ablation problem. Agreement between the model and the data is within 10%.
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    AIChE Journal 33 (1987), S. 753-765 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A corner flow hydrodynamic theory is outlined for the time to snap-off of a gas bubble moving through a smoothly constricted noncircular capillary as a function of the pore geometry and the capillary number, Ca. Above a transition capillary number the time to snap-off is independent of Ca, while below it the time to snap-off is inversely proportional to the capillary number. Thin films of liquid deposited along the capillary walls are shown to play a minor role; they are accordingly neglected in the analysis. The proposed theory is compared to new experimental results for snap-off in two constricted square capillaries (dimensionless constriction radii of 0.3 and 0.5) over a range of capillary numbers (10-5 to 10-3), wetting-liquid viscosities (1.0 to 8.5 mPa · s), and surfactant types. Good agreement is found between theory and experiment.
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    AIChE Journal 33 (1987), S. 776-783 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The production of bakers' yeast in a fed-batch bioreactor can be maximized by controlling the substrate feed rate. This leads to a singular optimal control problem. An exact solution initially based on a heuristic argument and later quantified by the generalized Legendre-Clebsch convexity condition is obtained. A numerical technique, obtained by embedding the singular problem in a sequence of nonsingular problems that converge to the singular one in a limit as ∊ → ∞ is demonstrated.
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    AIChE Journal 33 (1987), S. 792-800 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental determination of the steady state behavior for the supported platinum catalyzed oxidation of carbon monoxide in a recycle reactor was performed. Steady state multiplicity was observed. The effects of the size of catalyst charge, feed flow rate, feed composition, and reactor temperature on the location of the boundaries of the steady state multiplicity region were determined. The sensitivity of these bifurcation points to variations in reactor parameters was used to discriminate among five reaction mechanisms. Only an elementary step model incorporating carbon monoxide self-exclusion from the catalyst surface could quantitatively describe all observed steady state data. An explicit rate function based on this model is presented.
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    AIChE Journal 33 (1987), S. 808-818 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The devolatilization mechanism of polystyrene was studied by scanning electron microscopy. Strands of molten polystryene, containing 2,300 ppm styrene, and molten polystyrene containing 5% pentane, were extruded into a heated vacuum chamber. The strands were abruptly frozen, then fractured under liquid nitrogen and their morphology studied with scanning electron microscopy. A rich variety of morphological features in the core and on the surface of strands was discovered. These include micro- and miniblisters, fibrous structures, and crusty nodules on the inner surfaces of large macrobubbles. The source of these morphological features and their relevance to devolatilization is discussed.
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    AIChE Journal 33 (1987), S. 819-833 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general analysis of the reaction wave propagation in nonlinear exothermic nonadiabatic diffusion-convection-reaction systems is presented. The following topics are considered: approximation of temperature profiles based on the idea of infinitesimaly thin reaction front, estimation of maximum temperature, estimation of the conversion at the hot spot, a priori calculation of the front velocity, analysis of the self-ignition phenomena and their relation to wave propagation, and discussion of the effect of the heat loss parameter on the direction of propagation and shape of traveling waves. A comparison of the analytical work with exact numerical results reveals excellent agreement. The main objective of this paper is to provide a definite analysis of reaction wave propagation in reacting flow systems.
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    AIChE Journal 33 (1987), S. 843-847 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 33 (1987), S. 853-857 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 33 (1987), S. 862-866 
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  • 169
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    AIChE Journal 33 (1987), S. 871-875 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 33 (1987), S. 876-879 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 33 (1987), S. 898-915 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An efficient nonlinear programming strategy is presented for integration of heat engines and heat pumps with chemical processes. The strategy utilizes the temperature interval method and shows how to use negative heat deficits to obtain lower cost designs. Two important situations are presented in which the resulting designs are less costly when the heat engines and heat pumps are integrated with temperature intervals having negative heat deficits.
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    AIChE Journal 33 (1987), S. 916-925 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A hydrodynamic model is developed relating the movement of printed circuit panels to solution flow in through-holes. Qualitative and quantitative model verification is experimentally established. Effects of external gas bubbling on hole solution transport are elucidated. Based on the hydrodynamic model, panel motion criteria for contamination-free and fast chemical processing are introduced. Limits of mechanical panel movement as a method for processing holes of different geometry with typical wet chemical process baths are addressed.
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    AIChE Journal 33 (1987), S. 940-951 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Prior experimental study by Haldeman and Botty has demonstrated that catalyst regeneration rates vary with conversion, showing a nearly constant rate of reaction in the early stages of regeneration and falling off rapidly at higher conversion levels. This peculiar reaction behavior calls for explanation in terms of pore structural changes. In this work a mathematical model is developed based on the interaction between catalyst pore structure and coke distribution in the pores. The model is able to associate overall regeneration kinetics with alternative pore-distributed coke deposition patterns. Results exhibit a slight shallow rate maximum at an intermediate conversion level, in agreement with the prior experimental report. The model makes coke distribution in the pores accessible to experimental determination. The numerical results indicate that among pore structures with the same mean and overall pore volume, a larger variance offers a higher threshold for coke loading; for a given degree of dispersion, a smaller mean allows a higher coke loading.
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    AIChE Journal 33 (1987), S. 976-986 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis of parallelism for modular process flowsheet calculations is given. The central idea is to examine various algorithms that allow one to decouple and decentralize flowsheet calculations for computation in a multiprocessor environment. Specific algorithms are evaluated which make use of quasi-Newton updates to converge the flowsheet equations. From the analysis presented and example problems solved, it is clear that parallel processing can be used to enhance the computational speed of modular flowsheet calculations. In particular, various formulations of the simultaneous modular approach are analyzed to show how parallelism may be taken advantage of in flowsheet solutions.
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    AIChE Journal 33 (1987), S. 996-1007 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Reaction rates for the hydration of isobutene were measured at 323 K and atmospheric pressure in a trickle-bed reactor over a sixfold range of liquid rates. Three widely different feed conditions were used to vary the effect of mass transfer and wetting efficiency. The effect of wetting efficiency on the rate was analyzed using the additive procedure of Tan and Smith. The results showed that mass transfer from liquid to particle, wetting efficiency, and intraparticle kinetics all influenced the total rate, but that the gas-to-liquid mass transfer resistance was unimportant. Most of the resultant values of wetting efficiency and liquid-to-mass transfer coefficients were a little lower than literature values. This may be due to the high surface tension of our aqueous system. The derived total rate equations agreed well with the experimental rates, suggesting that the additive procedure is a satisfactory method of accounting for wetting efficiency.
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    AIChE Journal 33 (1987), S. 1025-1027 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 33 (1987), S. 1028-1033 
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    AIChE Journal 33 (1987), S. 1089-1101 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental study of the effect of turbulent mixing on the selectivity of a parallel-consecutive reaction system (A + B → R; R + B → S) has been carried out in an unmixed feedstream (multijet) tubular reactor. Fluid mechanical characterization of the reactor by pulsed ultrasound Doppler velocimetry reveals that the mean and rms velocity fields are nearly constant over eight-ninths of the reactor length. Axial profiles of mean product concentration (R and S) have been measured spectro-photometrically with a fiber-optic probe under constant hydrodynamic conditions but with variable feed concentration conditions. The concentration profiles (particularly the S profile) show very large deviations from the perfect mixing (classical plug flow reactor) limit. These data provide a good basis for discriminating among the many models of mixing and reaction available in the literature. This is demonstrated with two examples: the four-environment model, which fits the data well, and the interaction by exchange with the mean model, which does not.
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  • 179
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    AIChE Journal 33 (1987), S. 54-63 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Significant errors can result in modeling dissolution processes if the polydispersity of the solid particles is ignored and the sample is treated as a collection of monodisperse spheres having the average size of the mixture. Population balance modeling provides an effective analytical means of predicting the effect of polydispersity on a wide variety of heterogeneous reaction systems including dissolution processes.
    Additional Material: 13 Ill.
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  • 180
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    AIChE Journal 33 (1987), S. 70-82 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Classification of variables and measurements in multicomponent flow networks is treated in this paper. Classification rules are derived that exploit the relationship between cutsets of the process graph and certain graphs derived from it, and the solvability of the relevant equations. These rules are incorporated in two graph-oriented algorithms for observability and redundancy classification.
    Additional Material: 13 Ill.
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  • 181
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    AIChE Journal 33 (1987), S. 83-98 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental evaluation of methods to analyze process resilience based on internal model control (IMC) has been performed. A pilot plant consisting of two coupled distillation columns was instrumented for control studies using an LSI 11/23 microcomputer. Two alternative sets of inputs were chosen and the two full 7 (all outputs) × 4 (all inputs) transfer matrix models of the pilot plant were identified. From these models, a large number of potential 3 × 3 control structures were first screened for different levels of achievable control performance using the newly developed tools for resilience analysis. Without the need for simulation and with minimal computational effort these new techniques allow prediction of the effect of nonminimum phase characteristics, input constraints, and model uncertainty on achievable closed-loop performance. The resilience analysis results were found to be in agreement with qualitative physical intuition. To more fully investigate the usefulness and precision of the resilience analysis, three control structures for maintaining three product compositions from a distillation system were studied experimentally. The design and performance of IMC for this complex system is demonstrated and compared with single-loop PID controllers combined with a dynamic decoupler.
    Additional Material: 14 Ill.
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  • 182
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    AIChE Journal 33 (1987), S. 121-129 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two distinctly different mechanisms that lead to growth rate dispersion have been observed experimentally. One of the mechanisms involves an initial growth rate distribution among nuclei, while the other allows crystal growth rates to fluctuate. The model formulated in the present work includes both phenomena. Solutions to population balances in a continuous mixed-suspension, mixed-product removal continuous crystallizer and a constant-supersaturation batch crystallizer are obtained in terms of parameters characterizing the two mechanisms.
    Additional Material: 6 Ill.
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  • 183
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    AIChE Journal 33 (1987), S. 130-140 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An approach to chemical plant fault diagnosis is presented that utilizes patterns of violation and satisfaction of the quantitative constraints governing the process. Process knowledge consists of a list of the operational constraints on the plant together with sufficient conditions for violation of each constraint. Interpretation of the pattern of constraint violations is treated by Boolean and non-Boolean techniques. It is shown that non-Boolean reasoning techniques increase the stability and sensitivity of the diagnosis in the presence of noise. The techniques introduced in this paper are easily implemented in rule-based expert systems using certainty factors.
    Additional Material: 7 Ill.
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  • 184
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    AIChE Journal 33 (1987), S. 157-160 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 185
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    AIChE Journal 33 (1987), S. 164-166 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 186
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    AIChE Journal 33 (1987), S. 167-168 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 187
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    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 188
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    AIChE Journal 33 (1987), S. 171-171 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 189
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    AIChE Journal 33 (1987) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 190
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    AIChE Journal 33 (1987), S. 1241-1256 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper addresses the question of the relative amounts of liquid removed during filtration and expression as a function of cake compressibility. As liq uid flows through a porous cake, the accumulative drag collapses the particulate structure, thereby increasing the solid content and displacing the liquid. The use of pump pressure in filtration represents the simplest hydraulic deliquoring process. In expression operations, pistons, membranes, rollers or belts are employed to squeeze the particulate cake after filtration is complete.Filtration followed by expression at constant pressures ranging from 0.6 to 24.7 MPa (6.1-243.6 atm) was investigated theoretically and experimentally. During filtration and the early stages of expression, the flow rate and average liquid content of highly compressible attapulgite were virtually unaffected by increasing pressure in the range investigated.
    Additional Material: 18 Ill.
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  • 191
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    AIChE Journal 33 (1987), S. 1271-1287 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theory for flow through permeable media with equilibrium precipitation/dissolution interactions is rigorously established. The general solution in terms of waves, which represent the propagation of concentration changes is developed, and the detailed structure of a precipitation/dissolution wave in the presence of dissipation (diffusion and dispersion) is derived; this structure plays a vital role in the general solution. The solution is based on Riemann invariants and thus exhibits certain similarities to wave solutions of related problems in gas dynamics and chromatography. However, a discontinuity peculiar to the precipitation/dissolution problem prevents unification of these similar solutions into a single, more general theory.
    Additional Material: 10 Ill.
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  • 192
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    AIChE Journal 33 (1987), S. 1257-1270 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Many chemical engineering problems require the optimization of systems of differential and algebraic equations. Here a method is presented based on finite-element collocation, which converts differential equations to algebraic residual equations with unknown coefficients. A nonlinear program is then formulated, with residuals incorporated as equality constraints and coefficients as decision variables. Also, adaptive knot placement is used to minimize the approximation error, with necessary and sufficient conditions for optimal knot placement incorporated as additional equality constraints in the nonlinear program. All equality constraints are then solved simultaneously with the optimization problem, thus requiring only a single solution of the approximated model. Finally, problems with discontinuous control profiles can be treated by introducing an extra level of elements (superelements) as decisions in the optimization problem. This approach is demonstrated on a simple optimal control problem as well as a reactor optimization problem with steep temperature profiles and state variable constraints.
    Additional Material: 12 Ill.
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  • 193
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    AIChE Journal 33 (1987), S. 211-217 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The intrinsic rate constant for the rate of reaction of SO2 with porous CaO in an excess of O2 to form CaSO4 has been determined from SO2 sorption data on a wide range of particle diameters (1 μm- 1mm), SO2 partial pressures (60 Pa to 5 kPa), and temperatures (973- 1,478 K). An intrinsic SO2 reaction order of unity has been validated through current fixed-bed experiments in the 60 to 300 Pa SO2 partial pressure range, while fluidized-bed data were used to validate the reaction order from 500 Pa to 5 kPa SO2 partial pressure. The absolute value of the rate constant and the activation energy was derived from data on small (1 μm) particles, which approach the limit of kinetic control. While analysis of this data base does minimize the role of intraparticle diffusion through the porous sorbent particle, the filling of the small pores by the product deposits and the associated loss of internal surface area is critical to the data reduction. It is believed that the intrinsic rate constant is known to the accuracy to which the reactivity and the BET surface area may be measured.
    Additional Material: 10 Ill.
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  • 194
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    AIChE Journal 33 (1987), S. 239-249 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experiments on phenol biodegradation by a mixed culture in a draft-tube, three-phase fluidized-bed biofilm reactor (DTFBR) at the steady state were performed. The characteristics of biofilms developed in the DTFBR were identified. A steady state biofilm model was proposed that considers the simultaneous diffusion and reaction of oxygen and phenol within the biofilm and the external mass transfer resistance between the biofilm and the completely mixed bulk liquid phase. The proposed model assumes a double-substrate limiting mechanism for microbial growth kinetics, and Haldane and Monod type expressions were used to characterize the dependence of microbial specific growth rate on phenol and oxygen, respectively. The experimental results were used to test the validity of the proposed model.
    Additional Material: 7 Ill.
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  • 195
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    AIChE Journal 33 (1987), S. 258-266 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The high-temperature removal of SO2 by sorbents consisting of sodium and lithium salts supported on α-Al2O3 has been investigated with emphasis on the chemistry of regeneration. The sulfated sorbents were regenerated by reduction with CO at 700-800°C in a thermogravimetric analyzer and a packed-bed microreactor. Sulfur removal from the sorbent and distribution of gaseous products were measured at different alkali loadings, temperatures, and CO concentrations. The results are interpreted in terms of a network of reactions wherein alumina is important as a catalyst and as a reactant. During regeneration sulfate is converted to aluminate and sulfide, the fraction of aluminate defining the extent of regeneration. The rate and extent of sulfur removal increase with the ratio of alumina to alkali and are higher in the presence of lithium. The product gas consists of SO2, COS, and elemental sulfur, the latter compound constituting up to 35% of the sulfur removed.
    Additional Material: 14 Ill.
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  • 196
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    AIChE Journal 33 (1987), S. 274-281 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental values are presented for the wall and interfacial shear stresses in stratified gas-liquid flow in a pipe. The wall and Reynolds shear stresses were measured using a hot-film anemometry technique. The interfacial shear stress was determined using two methods: from a momentum balance, using the wall shear stresses and void fraction measurements, and from an extrapolation of the Reynolds shear profile at the gas-liquid interface. The predicted interfacial shear stress data were approximated by the formula relating the interfacial friction factor with the void fraction and gas and liquid Reynolds numbers, and were compared with other reported data.
    Additional Material: 13 Ill.
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  • 197
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    AIChE Journal 33 (1987), S. 303-306 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 198
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    AIChE Journal 33 (1987), S. 307-311 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 199
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    AIChE Journal 33 (1987), S. 316-318 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 200
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    AIChE Journal 33 (1987), S. 322-324 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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