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  • 1970-1974  (756)
  • 1970  (756)
  • Industrial Chemistry  (356)
  • Analytical Chemistry and Spectroscopy  (346)
  • Engineering General  (54)
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Years
  • 1970-1974  (756)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 3-3 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 2-2 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 5-32 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The program given here assembles and solves symmetric positive-definite equations as met in finite element applications. The technique is more involved than the standard band-matrix algorithms, but it is more efficient in the important case when two-dimensional or three-dimensional elements have other than corner nodes. Artifices are included to improve efficiency when there are many right hand sides, as in automated design. The organization of the program is described with reference to diagrams, full notation, specimen input data and supplementary comments on the ASA FORTRAN print-out.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 33-43 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In the design of a guyed mast the design specification often imposes limits on the allowable deflection of the mast under wind and other lateral loads. While the deflected form of a mast depends on many different design parameters, the guy erection tensions form one of the simplest means of controlling the lateral displacements. The paper describes a procedure for calculating these tensions in the case of a mast required to have a specified set of displacements under a given set of lateral loads. It also discusses the case where specified deflections are not to be exceeded under a number of different loading conditions.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 45-59 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper is concerned with the development of a computational algorithm for the solution of the uncoupled, quasi-static boundary value problem for a linear viscoelastic solid undergoing thermal and mechanical deformation. The method evolves from a finite element discretization of a stationary value problem, leading to the solution of a system of linear integral equations determining the motion of the solid. An illustrative example is included.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 61-71 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The transient field problem of the type encountered in heat conduction problems is formulated in terms of the finite element process using the Galerkin approach. Curved two-dimensional and three-dimensional, isoparametric elements are used in a time-stepping solution and their advantages illustrated by means of several examples.
    Additional Material: 6 Ill.
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  • 8
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The proposed finite element model is based on separate assumptions of interior and interelement displacements and on the assumed boundary tractions of each individual element. The associated variational functional for this model is presented. This method has the same merits of the assumed stress method (References 3 and 4) in that a compatible displacement function at the interelement boundary can be easily constructed, while it can easily be used for shells with distributed loads.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 117-131 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical method for the analysis of field problems is described. The algorithm is based upon the generalized Betti-Maxwell theorem. Using a set of known solutions to problems with similar boundary conditions produces a set of ‘integral’ equations for the required solution. Using any convenient numerical integration formula reduces the problem to the solution of a set of simultaneous algebraic equations. The accuracy of the solution depends upon the accuracy of the integration formula as applied to the problem under consideration and is independent of the known auxiliary solutions. The method is described in detail as applied to harmonic problems.
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 85-98 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Considerable attention has been devoted in the literature on numerical methods towards securing energy convergence of solutions for, say, linearly elastic plate bending problems. Although energy convergence is necessary it by no means follows that the derived bending moments and shearing forces converge uniformly at a given point and it is this kind of feature which the engineer is really seeking.This question is examined in the context of a problem which is of particular interest to the civil engineering field and concerns the bending of a square plate under uniformly distributed load; the plate has simply supported edges and contains a central square hole with free edges. The solution to this multiply connected and mixed boundary value problem is obtained through a recently developed modification to the Rayleigh-Ritz method which has very general application and renders the solution mathematically valid up to the internal corner points where the bending moments are singular. Use is made of triangular equilibrium finite elements in conjunction with continuous eigenfunctions. Although it is already known that the order (i.e. the eigenvalue) of the singularity at the internal corners is available by inspection, it is an interesting feature of the present solution that a good approximation to the amplitude is also obtained by an inspection of the finite element results.
    Additional Material: 5 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 99-116 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The convergence rates of eigenvalue solutions using two finite plate bending elements are studied. The elements considered are the well-known 12 degree of freedom, non-conforming rectangular element and the 16 degree of freedom, conforming rectangular element. Three problems are analysed, a square plate simply supported on two opposite sides with the other two sides clamped, simply supported, or free. Closed form, finite element solutions for these problems are obtained by using shifting E-operators.With few exceptions, eigenvalue solutions found with the non-conforming element converge from below the exact answers at an asymptotic rate of n-2, where n is the number of elements on a side. However, since the array size needed for such convergence is very large, little can be said about the convergence rates for practical arrays. The conforming element solutions converge from above at an asymptotic rate of n-4. A comparison of the errors involved in using these two elements shows that the conforming element is far superior to the non-conforming element.
    Additional Material: 9 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 145-146 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 146-147 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 133-144 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper presents a labour-saving method of discretizing irregular and inhomogeneous two-dimensional continua into triangular elements. The method uses a magnetic pen to record node point data and a computer program to generate element data. This technique eliminates the tedium in the manual generation of data and the delay due to mistakes which would otherwise arise frequently for a complex mesh.
    Additional Material: 10 Ill.
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  • 16
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 151-157 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A finite element formulation which includes the piezoelectric or electroelastic effect is given. A strong analogy is exhibited between electric and elastic variables, and a ‘stiffness’ finite element method is deduced. The dynamical matrix equation of electroelasticity is formulated and found to be reducible in form to the well-known equation of structural dynamics, A tetrahedral finite element is presented, implementing the theorem for application to problems of three-dimensional electroelasticity.
    Additional Material: 1 Ill.
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  • 17
    Electronic Resource
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 175-188 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical method is presented for the solution of the radially symmetric heat conduction problem in a melting sphere. The method employs the embedding technique; this permits the solution to be written in the form of an ordinary integro-differential equation which is readily solved numerically by means of a forward integration scheme. The accuracy of the method is briefly discussed and numerical results for both constant and variable heat inputs are presented.
    Additional Material: 8 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 159-174 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper is concerned with the development of general discrete models for the analysis of boundary-value problems in the first strain-gradient theory of elasticity. Extensions of the finite element method are constructed for this purpose, and general equations of motion are derived for finite elements of a class of micro-polar materials which are characterized by strain energy functions involving strains and second gradients of strains or displacements. The notion of generalized nodal doublets is introduced. The problem of a composite consisting of a strain-gradient sensitive microlayer embedded between semi-infinite bodies is examined as an example problem. Some of the results are compared with available exact solutions.
    Additional Material: 7 Ill.
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  • 19
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Methods for the analysis of complex, highly redundant structures subjected to intermittent loads causing biaxial membrane stress and stress reversal into the plastic range are presented. The Bauschinger effect in multi-axial stress is taken into account by the use of Ziegler's modification of Pragers kinematic hardening theory. The implementation of this plasticity theory in the discrete element methods involves the application of the loading in small increments. A linear relationship between increments of plastic strain and of stress, arising out of the theory, is used in conjunction with a linear matrix equation that governs the elastic behaviour of the structure. In the latter equation, plastic strains are interpreted as initial strains. A solution to the linear matrix equation, expressed in terms either of stress or of total strain, may be obtained by utilizing one of two alternative procedures. The methods are capable of treating materials which exhibit elastic-plastic behaviour involving ideal plasticity, linear or non-linear strain hardening, or limited strain hardening. Application is made to several representative structures. Comparison of some of the results with existing test data for both monotonic and reversed loading shows good correlation.
    Additional Material: 7 Ill.
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  • 20
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 221-228 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A general digital computer method based on a Sturm sequence procedure is described for determining the natural frequencies and associated modes of undamped free vibration of frames and other structures whose stiffness and mass matrices are of band form. A program which uses the method for the analysis of plane multi-storey building frames is outlined, and numerical results are presented for a simple test case and for a 19-storey frame.
    Additional Material: 2 Ill.
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  • 21
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 207-219 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A newly developed numerical Laplace transform inversion technique is described. A derivation of the method, termed the ‘multidata method’, is presented along with a description of a similar collocation method. Similarities and differences between the two numerical methods are described and discussed. Results of parameter studies of both methods are presented which demonstrate the sensitivity to error displayed by the collocation method and the magnitude of the improvement in accuracy obtainable with the multidata method as compared with the collocation method, especially when errors exist in the function to be inverted.
    Additional Material: 6 Ill.
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  • 22
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 229-241 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this study, finite element solution procedures are developed for an elastica problem of inextensible beams. The element stiffness matrices are obtained by using Galerkin's method. Results of a numerical example compare reasonably well with those obtained by using the elliptical integral.Extensions of this research are currently being made to include membrane effects of beams and to develop plate element stiffness matrices for elastica problems of plate structures.
    Additional Material: 4 Ill.
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  • 23
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 243-252 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This report summarizes an experimental application of the finite element approach to two-dimensional inviscid fluid flow.The method results in a matrix equation relating the vector of velocities at the nodal points with the vector of singularities. The singularities, which are concentrated at the nodes, consist of a source and a vortex.On solution of this equation (defining the flow in the region), boundary conditions must te stipulated. This usually involves setting the internal singularities to zero and making certain modifications ro those lying on the boundary of the region.Some results of the application to a particular problem are included in the paper.
    Additional Material: 6 Ill.
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  • 24
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 253-257 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Some typical results of an extensive series of evaluations of parallelogram-shaped plate bending elements with increasing levels of sophistication are presented. It is shown that, contrary to experience in other fields of stress analysis, this sophistication does not lead to striking improvements in accuracy in the solution of simple rectangular and skew plate problems. A computational procedure is described whereby stiffness matrices may be automatically generated from the minimum of input data specifying the displacement modes prescribed for the element.
    Additional Material: 2 Ill.
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  • 25
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 259-264 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A conforming plate bending solution using simple polynomial deflection functions of third-degree inside each triangular element is presented. In order to avoid normal slope discontinuities along the sides of the elements, the plate displacement parameters are subjected to ‘slope continuity conditions’ acting as constraints to the minimum potential energy problem. This is then solved by the classical method of Lagrange introducing multipliers as new auxiliary variables. If a special variational formulation of the problem is used, it can be shown that the Lagrangean multipliers are generalized stress parameters. The suggested solution is therefore basically a ‘mixed’ solution, the unknown variables of the problem being both displacement and stress parameters. Several numerical results are presented.
    Additional Material: 2 Ill.
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  • 26
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 265-275 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Approximate formulations of non-uniform beam element stiffness matrices for dynamic and elastic instability analysis are derived. Displacement functions for the uniform beam segment are employed in this development. Moment of inertia and area of the element are prescribed by arbitrary powers of the axial co-ordinate. Numerical results are obtained and compared with both analytical solutions and numerical solutions based upon stepped representations using uniform section elements. The significance of the inclusion of taper considerations within individual elements upon solution accuracy and convergence characteristics is also examined. This subject problem and solution approach demonstrates that the upper bound character of minimum energy solutions may be difficult to exploit under practical circumstances.
    Additional Material: 8 Ill.
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  • 27
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 277-282 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This article describes-a new method, suitable for use on a digital computer, for evaluating the singular double integral of Hayes which determines the transonic wave drag of a slender body. Comparison with known exact results and with an earlier computer program described by Eminton shows the present method to be accurate as well as economic in computer time.
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  • 28
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 283-293 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The complementary variational principle has been used to derive the differential equations and the associated boundary conditions of the vibrating plate in terms of bending moments. It is shown that in this formulation, the plate possesses an infinite number of zero frequency modes in which the plate remains in a state of constant strain under a set of self-equilibrating bending moments. In applying the Rayleigh Ritz procedure for the non-zero frequency modes of the plate, it is shown that it the assumed functions are orthogonal to only a finite number of zero frequency modes, then one may obtain frequencies which are lower than the true frequencies of the plate. An iliustrative example is given in the paper.
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  • 29
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 30
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 299-299 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 31
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 301-303 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 32
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 33
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 307-310 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Convergence of a finite element procedure for the solution of the fourth-order equations is proved. A generalization of this result is mentioned and some remarks concerning the numerical results obtained at the Computing Centre of the Technical University in Brno are given.
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  • 34
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 311-333 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Digital filters are finding wide applications in signal processing aspects of such fields as engineering, geophysics and biosignal analysis. The design of a digital filter and its realization with near minima computer word length are two problems which can be solved by computer-aided design techniques In this paper, the automated design of the initial filter (recursive type) only is considered. Both of the basic design methods - the direct and indirect approaches - have been analysed, and compute programs have been written to implement the various design techniques. The present program are limited to the design of flat loss type filters specified by their gain rather than their phase character istics. although provision has been made to allow for other types of design in the indirect approach Design examples are given, and the results analysed with a view to the suitability and limitations of the different design techniques.
    Additional Material: 9 Ill.
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  • 35
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 353-361 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper demonstrates the applicability of general non-linear programming methods to the solution of buckling problems. The minimum energy formulation of the buckling condition is shown to yield an unconstrained non-linear programming problem, for which several numerical methods of solution are readily available. Some of these methods are discussed and numerical results are presented for stiffened plates with in-plane as well as lateral loads.
    Additional Material: 6 Ill.
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  • 36
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 335-352 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Stiffness matrices are formulated for the torsional and lateral stability analysis of structures composed of flexural members by the matrix displacement method. The formulations are based upon approximate displacement fields which represent the action of the element in simple flexure. Example problems, for which exact solutions are known, illustrate the accuracy and convergence characteristics of the derived formulations.
    Additional Material: 8 Ill.
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  • 37
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 363-385 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A solution has been formulated, which allows one to analyse all the major performance characteristics in a chain of impacting elastic ‘rods’. By allowing one end of the elastic chain to impact against a surface which resists penetration according to a specified penetration law it is possible to analyse the impact system of a variety of mechanical devices such as percussive tools and squeeze film dampers. Virtually, unlimited variety in the number and geometry of the impacting rods, and virtually unlimited complexity in the form of the reaction of the terminal face is permitted. A computer program for treating one or two elastic rods has been developed. The program prints out all important stresses as well as the stress history at several selected points. It also prints out the depth of penetration, the energy transferred from rod to rod, the overall energy transfer into the receiver, rebound velocities and times of separation between rods and between rod and 4receiver. Agreement with exact solutions and experiments is demonstrated.
    Additional Material: 14 Ill.
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  • 38
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 387-395 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A technique of differential displacements is presented whereby problems involving elastic contact are solved by the finite element method. The technique is applied to axisymmetric situations in which statically indeterminate conditions occur and is shown to provide a means for resolving these conditions in terms of contact stresses. Three typical engineering problems are analysed to demonstrate the technique in cases where body forces, thermal gradients and external applied forces are acting.
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  • 39
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 415-418 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Recent advances in finite element techniques have enabled full three-dimensional stress analyses to be undertaken. Economy and accuracy can only be achieved simultaneously if the characteristics of the element are understood. Preparatory work is described in which suitable pitching and disposition of brick-type elements are established for the analysis of cylinders.The information derived is put to use in the analysis of a cylinder-cylinder intersection. A favourable comparison is made with an independently computed solution.
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  • 40
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 397-414 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The velocity field of a semi-contained turbulent jet, as constructed by Abramovich, is used to arrive at the temperature distributions in the initial region of a turbulent flow film cooling situation taking into account both the development of the jet boundary layer and the wall boundary layer. After suitable profiles of eddy thermal conductivity are established, a finite difference form of the thermal energy equation is derived, shown to be unconditionally stable, and solved numerically with the aid of an IBM System 360 computer to yield the temperature distributions. Wieghardt's parameter for collapsing the temperature profiles onto a single curve in film cooling situations, when suitably modified, also collapse the analytical results to essentially a single curve even as near as 2·7 slot heights from the injection point, thus verifying the temperature similarity in film cooling which has been experimentally observed even very near the injection point. Results in graphical form are presented which allows one to construct the actual temperature profile for a fairly wide range of the relevant parameters.
    Additional Material: 15 Ill.
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  • 41
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    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 42
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 453-454 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Additional Material: 1 Ill.
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  • 43
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 419-451 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A general formulation for the curved, arbitrary shape of thick shell finite elements is presented in this paper along with a simplified form for axisymmetric situations. A number of examples ranging from thin to thick shell applications are given, which include a cooling tower, water tanks, an idealized arch dam and an actual arch dam with deformable foundation.A new process using curved, thick shell finite elements is developed overcoming the previous approximations to the geometry of the structure and the neglect of shear deformation.A general formulation for a curved, arbitrary shape of shell is developed as well as a simplified form suitable for axisymmetric situations.Several illustrated examples ranging from thin to thick shell applications are given to assess the accuracy of solution attainable. These examples include a cooling tower, tanks, and an idealized dam for which many alternative solutions were used.The usefulness of the development in the context of arch dams, where a ‘thick shell’ situation exists, leads in practice to a fuller discussion of problems of foundation deformation, etc., so that practical application becomes possible and economical.
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  • 44
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Additional Material: 2 Ill.
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  • 45
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 459-476 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The stiffness equation is derived for curved elements of orthotropic axi-symmetric thin shells, and equivalent applied loads are found for shells subjected to initial strains, applied surface loads and body forces. The Lure approximation of thin shells and displacement field approximation by polynomials of arbitrary degree are included in the formulae derived.
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  • 46
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 477-494 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A computational procedure based on gradient iterative techniques is proposed for the solution of large problems to which the finite element method is applicable. In linear problems the procedure can be used either for solving the set of algebraic equations or for the complete inversion of the matrix of coefficients. Special attention is focused on the practical aspects of the procedure concerning its realization on the digital computer.
    Additional Material: 7 Ill.
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  • 47
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 495-507 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A finite element method to determine unsteady aerodynamic influence coefficients, consistent with the stiffness and inertia properties of a lifting surface in supersonic flow, is described. This is basically a kinematic method, which reduces the dynamical equations of a non-conservative system to a simple and elegant form. It is illustrated by application to a delta wing using triangular elements to calculate steady and unsteady lift and moment coefficients. Throughout the calculations only a coarse grid system has been employed and the answers have been compared with available results.
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  • 48
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 509-522 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A simple program carrying out various vector operations in two- or three-dimensional spaces is presented. The listings are given in A.S.A. FORTRAN IV. The program is of particular application in various forms of three-dimensional and shell analysis as it can create and transform locally orthogonal co-ordinates, etc. While these applications motivated its design, it is of very general use one such application is illustrated by applying the program to general perspective projection.
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  • 49
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 523-533 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A procedure is presented for the automatic renumbering of network type equations prior to solution by sparse matrix techniques. The method takes an arbitrary input sequence and creates an order which makes possible solution of complex network systems by reducing demand for computer storage and time.Examples are presented to demonstrate the procedure in action and show that, even in cases where the system has been carefully numbered, considerable improvement can be achieved. The procedure is also applicable to band matrix solution techniques.
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  • 50
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 579-595 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The feasibility of achieving a preassigned stress state by changing the stiffness of determinate and indeterminate pin connected structures is presented. A new force method with all element forces (or stresses or areas) as independent variables is developed. The possibility but futility of getting the element areas by inverting and pre-multiplying the coefficient matrix with the external load vector when areas are chosen as variables is shown. The relationship existing between the compatibility equations and the plastic strength of pin connected structures is illustrated. Possible design methods for trusses under single or multiplicity of load conditions, the design of truss geometry and the relations between fully stressed and minimum weight structures are examined and illustrated through several examples.
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  • 51
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 563-577 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper deals with solving two-dimensional variational problems of second- and third-order by the finite element method. To each meshpoint are associated three or six basic functions of class C1 or C2. The expression of the admissible functions on a triangular and rectangular element are given here in a general form which is specially suitable for computation.
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  • 52
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 535-549 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The eigenvalue method is well-known as an aid to the solution of a wide range of engineering problems. In power system analysis it has relevance to travelling wave phenomena,1 sensitivity and dynamic stability in synchronous multimachine2 systems, critical speed calculation, vibration of structures and other related topics. The method of numerical solution of eigenvalues depends on the size and nature of the problem and often where large matrices are involved presents great difficulties.This paper describes in detail the application of the escalator method and diakoptics to large eigenvalue problems. The escalator method is a well-established one which consists of a systematic way of escalating from a 2 × 2 matrix up to any desired order in steps of one row and column at a time. The diakoptical method reduces computer storage, calculation time and improves accuracy. This results in the more economical solution of large and complicated problems which cannot be conveniently solved by any orthodox method. The paper deals with problems of degeneracy and means of overcoming these by simple routine processes. It concludes by indicating the particular advantages of the method and its usefulness for a wide variety of general engineering problems.
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  • 53
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 551-561 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A novel integral equation technique is employed for the analysis of dynamic stability problems. The governing equation of the linearized parametric resonance problem is transformed into an integral equation. The kernel of the integral equation is computed as the influence function for the deflection and/or bending moment of a corresponding beam.The highest derivative of the governing function (in our case fourth derivative of the displacement function) is chosen as the basic unknown. Using the formal analogy with the differential equation of the beam flexure this highest derivative is comprehended as some unknown transverse ‘load’. The distribution of this ‘load’ is a priori assumed to be polygonal. Using elementary methods of structural analysis, the displacements due to the assumed ‘load’ are determined. These displacements, arrayed into a square matrix, approximate the kernel of the governing integral equation.The subsequent procedure via Hill's determinant is a conventional one. The results prove to be accurate enough even for a very modest number of points of integration. This reflects the fact that the method is based on numerical integration rather than on numerical differentiation.
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  • 54
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 597-600 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In any mesh, rules exist that interrelate the number of internal and external sides, vertices, etc. and the total number of elements. These are given explicitly for plane meshes of triangles and quadrilaterals, and for solid meshes of tetrahedra and cuboidal elements. The method is quite general and discovers all such independent rules that exist. Thus, for a plane mesh of T elements having Vi internal and Vb boundary vertices and Si internal and Sb boundary sides, then \documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{l} T = \frac{1}{3}\left({S_b + 2S_i} \right) = V_b + 2V_i + 2H - 2\quad{\rm (for\,triangular\,elements)}\\ T = \frac{1}{4}\left({S_b + 2S_i} \right) = \frac{1}{2}\left({V_b + 2V_i} \right) + H - 1\quad{\rm (for\,quadrilateral\,elements)} \\ \end{array} $$\end{document} where H is the number of internal boundaries (holes) there might be. For solid meshes, these two-dimensional equations relating elements to sides generalize to \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} T = \frac{1}{6}\left({F_b + 2Fi} \right){\rm\quad (for\,cuboid\,elements)} \\ T = \frac{1}{4}\left({F_b + 2Fi} \right){\rm\quad (for\,tetrahedral\,elements)} \\ \end{array} $$\end{document} where there are Fb boundary and Fi internal faces. Unfortunately, there is no direct generalization of the two-dimensional equations relating vertices and elements: it is only possible to do this by including the Ei internal and Eb boundary edges: \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} T = \frac{1}{8}E_b + \frac{1}{2}\left({E_i - V_i + H - h - 1} \right){\rm\quad (for\,cuboid\,elements)} \\ T = \frac{1}{3}E_b + E_i - V_i + H - H - 1{\rm\quad (for\,tetrahedral\,elements)} \\ \end{array} $$\end{document} where there are H through holes and h cavities.
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  • 55
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 51-51 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 56
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 59-63 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Am Beispiel der Isomerisierung von Dikaliumphthalat zu Dikaliumterephthalat wird die Entwicklung eines diskontinuierlich arbeitenden Reaktors und am Beispiel der Disproportionierung von Kaliumbenzoat zu Dikaliumterephthalat und Benzol die eines kontinuierlich betriebenen Reaktors beschrieben. Trotz der Phasenumwandlungen während der Umsetzungen ermöglichen beide Reaktortypen durch geeignete Einbauten und Auslegungen einen wirtschaftlichen Chargenbetrieb bzw. eine kontinuierliche Arbeitsweise, wobei das Endprodukt als freifließendes Pulver anfällt und das Reaktorinnere frei von agglomerierten und angebackenen Feststoffteilchen bleibt.
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  • 57
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    Chemie Ingenieur Technik - CIT 42 (1970) 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 58
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bei der Berechnung des isothermen Trocknungsverlaufs hygroskopischer, nicht poröser Kunststoffe muß berücksichtigt werden, daß der Diffusionskoeffizient von der Feuchte abhängt. Da eine numerische Lösung keinen Überblick über den Einfluß der verschiedenen Größen auf den Trocknungsverlauf gibt, wurde nach einer allgemeinen Darstellung des Trocknungsverlaufs hygroskopischer Kunststoffkörper gesucht. Es zeigt sich, daß der isotherme Trocknungsverlauf solcher Körper von nur zwei Kennzahlen abhängt, wenn der Einfluß der Feuchte auf den Diffusionskoeffizienten in Abhängigkeit von der angestrebten Restfeuchte dargestellt wird und wenn weiterhin für die analytische Wiedergabe dieser Abhängigkeit nur zwei Konstanten gebraucht werden. Die allgemeinen Lösungen für die unendlich ausgedehnte planparallele Platte, die Kugel und den unendlich langen Zylinder werden angegeben, wobei zugrunde gelegt wird, daß der Diffusionskoeffizient sich mit der Feuchte linear ändert.
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  • 59
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 52-52 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 60
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    Chemie Ingenieur Technik - CIT 42 (1970) 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 61
    ISSN: 0009-286X
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Die bekannten Verfahrensprinzipien zur Herstellung von Acetylen aus leichten Kohlenwasserstoffen wurden auf die Synthese von Cyanwasserstoff aus leichten Kohlenwasserstoffen und Ammoniak übertragen. Die Cyanwasserstoff-Bildung erfordert reaktive Zwischenprodukte, die nur bei der partiellen Oxidation von Kohlenwasserstoff/Ammoniak-Gemischen in ausreichender Konzentration entstehen. Ein Zweistufenprozeß (Pyrolyse) scheidet daher aus. Der Einstufeprozeß (partielle Oxidation) kann dadurch günstig beeinflußt werden, daß man das Reaktionsgemisch als Strahlflammen in einer Umgebung von Hilfsgasen abbrennen läßt. Hilfsgase können die Reaktionskomponente Ammoniak sowie an der Synthesereaktion nicht unmittelbar beteiligte Gase wie Wasserstoff und Kohlenmonoxid sein.
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  • 62
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 87-95 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 63
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 99-101 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 64
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    Chemie Ingenieur Technik - CIT 42 (1970) 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 65
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 105-108 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Die Bedingungen, unter denen eine Stabilisierung von Flammen stattfindet, sind bisher nicht ausreichend definiert. Konzentrationsverteilung, Flammengeschwindigkeit und Strömungsgeschwindigkeit müssen in bestimmter Weise zusammenwirken, damit stabiles Brennen von Flammen möglich wird. Die Unterschiede zwischen dem Stabilisierungsvorgang von Diffusionsflammen und dem von Vormischflammen werden anhand der Geometrie und Wärmebilanz der Stabilisierungszone dargestellt und die Einflüsse der Turbulenz auf die Stabilisierung von Diffusionsflammen beschrieben.
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  • 66
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Um verschiedene Verfahren zur Berechnung des Druckverlustes einem zahlenmäßigen Vergleich unterziehen zu können, wurden für jeweils drei Glocken- und Ventilböden unterschiedlicher Größbe und Belastung die Teildruckverluste sowie der Gesamtdruckverlust ermittelt. Bei den Glocken- und Ventilböden liefern die einzelnen Verfahren Ergebnisse mit teilweise beträchtlichen Abweichungen. Eine zuverlässige Vorherbestimmung des Druckverlustes ist somit nicht ohne weiteres möglich.
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  • 67
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 135-149 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 68
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 108-123 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Zur Erfassung der Grenzflächenreaktionen wurde die bei rd. 750 Torr und 25 °C stattfindende Absorption von CO2, O2 und N2 in sehr dünne Wasserfilme gemessen, die an einer rotierenden Walze kontinuierlich neu gebildet werden. Die in Abhängigkeit von der Phasenkontaktzeit zwischen 10-1 und 2 · 10-4 s bestimmten Absorptionen wurden nach den Gesetzen der instationären Diffusion ausgewertet. Dabei ergab sich, daß die experimentell ermittelten Absorptionsraten bei der Übertragung von O2 und N2 deutlich kleiner sind als bei der streng durch Diffusion begrenzten Absorption. Aus diesen Abweichungen werden die Grenzflächenwiderstände und daraus die Akkommodationskoeffizienten α berechnet. Für den O2- und N2-Übergang in die Flüssigphase ergibt sich für α rd. 10-6, bei dem rückläfigen Übertritt in die Gasphase erhält man für α rd. 10-4.
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 123-128 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Radionuklid-Batterien gewinnen wegen ihrer hohen Beständigkeit, ihrer völligen Wartungsfreiheit und ihres geringen Platzbedarfs in zunehmendem Maße vor allem im Nachrichtenwesen und in der Medizin an Bedeutung. In diesem Beitrag wird ein kurzer Überblick über die gebräuchlichen Verfahren zur Umwandlung von Strahlungsenergie in elektrische Energie sowie über die Gewinnung und die Eigenschaften einiger wichtiger Nuklide gegeben. Dabei werden die Grenzen, die allgemein der Verwendung solcher Energiequellen gezogen sind, und die Schwierigkeiten, die vor allem in der BRD dem kommerziellen Bau dieser Geräte noch entgegenstehen, diskutiert.
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 150-152 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 71
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 132-134 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Es wird der Einfluß der Spaltweite auf die Messung der Viskosität von Emulsionen und Suspensionen in Couette-Viskosimetern mit sehr geringer Spaltweite nachgewiesen. Der Effekt beruht auf einer Verdrängung der Teilchen aus den wandnahen Schichten. Zahlenwerte für die Dicken der entmischten Schichten werden mitgeteilt.
    Additional Material: 3 Ill.
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  • 72
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    Chemie Ingenieur Technik - CIT 42 (1970) 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 73
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Organische Anionen, Natriumazid und Grignard-Verbindungen lassen sich an Platin-Anoden oxidativ an Olefine addieren. Das Primäraddukt dimerisiert zu additiven Dimeren, ergibt durch gemischte Kupplung bzw. Ein-Elektronenoxidation zu Carbonium-Ionen 1,2-disubstituierte Olefine oder reagiert unter Wasserstoff-Abspaltung zu Alkyl- und Alkenyl-Derivaten. Arylolefine, Butadien und Enoläther werden an Graphit-Elektroden zu Radikal-Kationen oxidiert, die unter gleichzeitiger Knüpfung einer C-C-Bindung und Einführung eines Nukleophils oder einer Doppelbindung Schwanz/Schwanz-Dimere bilden. Dadurch werden Butan-Derivate, Diene und 1,4-Dicarbonyl-Verbindungen einstufig zugänglich.
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  • 74
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 153-164 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bei der Elektrosynthese organischer Verbindungen ist es von Vorteil, daß die Selektivität und damit die Ausbeute hoch ist, daß man stöchiometrische Parallelprodukte vermeidet und den Prozeß leicht automatisieren kann und daß man schließlich Normaldruck und Raumtemperatur als Verfahrensparameter hat, wodurch die breite Anwendung von Kunststoffen und Ionenaustauscher-Membranen möglich ist. Viele spezifische Probleme bezüglich der Elektroden, des Elektrolyten, des Lösungsmittels, der optimalen Zellenkonstruktion und nicht zuletzt der Kosten für die Elektroenergie konnten in der letzten Zeit gelöst werden. Dies wird an einigen Beispielen, wie der Elektrosynthese von Adipinsäuredinitril, von Bleialkylen, von Sebacinsäureester und von Salicylaldehyd, aufgezeigt. Die Elektrosynthese von Adipinsäuredinitril demonstriert auch, welche Umstände die Einführung eines elektrochemischen Verfahrens zwingend erscheinen lassen und gegen welche Konkurrenzverfahren dieses sich im Laufe der Zeit behaupten muß.
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  • 75
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 180-184 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Äthylen- und Propylenchlorhydrin können durch Elektrolyse von Chlorid-Lösungen, in die gleichzeitig das Olefin eingeleitet wird, mit guter Stromausbeute erhalten werden. Die Einflüsse verschiedener Variablen, z. B. der Chlorid-Konzentration, der Zellengröße und der Konzentration des gebildeten Chlorhydrins, auf die Ausbeute wurden untersucht und die Ergebnisse, von denen das auffallendste die Abhängigkeit der Ausbeute von der Zellengröße ist, gedeutet. In der Technik ist das Chlorhydrin vor allem als Zwischenprodukt bei der Herstellung des Olefinoxids von Bedeutung. Es wird eine kurze Übersicht über neuere, in der Patentliteratur veröffentlichte Versuche gegeben, bei denen die Bildung des Chlorhydrins im Anodenraum mit dessen Verseifung im Kathodßnraum gekoppelt wird.
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  • 76
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 170-175 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Zur Synthese bifunktioneller organischer Verbindungen bietet die Kolbe-Elektrolyse viele Möglichkeiten, die jedoch bisher technisch kaum genutzt wurden. In dieser Arbeit wird die Elektrolyse von Di-, Amino- und Oxycarbonsäuren näher untersucht. Die hierfür entwickelte Vibratorzelle erlaubt es, trotz der starken Gasentwicklung während der Reaktion, mit einem geringen Elektrodenabstand und folglich mit einer niedrigen Zellspannung zu arbeiten. Die Abhängigkeit der Ausbeuten vom Substrat und den Elektrolysebedingungen, wie Neutralisationsgrad, Stromdichte und Lösungsmittel, wird an einigen Beispielen aufgezeigt.
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  • 77
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Die Oxidation von Carbonsäuren, Alkoholen, Aldehyden u. ä. organischen Verbindungen ist auf elektrochemischem Wege meist nur an katalytisch aktiven Elektroden mit metallischem Leitungscharakter möglich. An belichteten Halbleitern mit großer Bandlücke hat sich durch die Erzeugung energiereicher Defektelektronen eine andere Möglichkeit für solche Oxidationen ergeben. Ein besonderer Reaktionsablauf führt zu einer Erhöhung der Quantenausbeute für den Strom durch zusätzliche Injektion von Leitungselektronen, wie mit verschiedenen organischen Substanzen beobachtet werden kann. Die in Frage kommenden Mechanismen werden diskutiert.
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  • 78
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 189-189 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 79
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In zahlreichen aprotischen, organische Kationen enthaltenden Lösungsmitteln läßt sich molekularer Sauerstoff elektrochemisch zum O2--Ion reduzieren. Die Kinetik der Reaktion hängt entscheidend vom Elektrodenmaterial ab. Lösungen mit O2--Ionen bzw. Ionen, die eine O2--Gruppe enthalten, haben basische, nukleophile und Redox-Eigenschaften. Die Autoxidation aromatischer Kohlenwasserstoffe wird durch O2--Ionen katalytisch beschleunigt; eine Oxidation ist auch in Abwesenheit von molekularem Sauerstoff möglich. Die nukleophile Substitution von Halogen-Atomen oder ähnlichen Gruppen führt in guter Ausbeute über Hydroperoxid-Radikale zu organischen Peroxiden. Einige weitere nukleophile und Redox-Reaktionen des O2--Ions werden kurz erläutert.
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  • 80
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 190-195 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Die Kombination von Elektronenspinresonanz und elektrochemischen Methoden wird in den letzten Jahren in zunehmendem Maße zur Klärung von Reaktionsmechanismen in der organischen Elektrochemie angewendet. Nach einer kurzen Einführung in das Prinzip der Elektronenspinresonanz und in die experimentelle Methodik bei elektrochemischer Radikalerzeugung werden summarisch die Möglichkeiten veranschaulicht, durch Anwendung der Elektronenspinresonanz Beiträge zu elektrochemischen Fragestellungen zu leisten. Neben dem bloßen Nachweis von Radikalen, ihrer Konzentrationsbestimmung (z. B. für kinetische Untersuchungen) sowie Informationen von theoretischem Interesse (Molekülorbital-Energien, Kinetik von Elektronen-Austauschprozessen, Wechselwirkung mit dem Medium, Konformation) sind es vor allem definitive Aussagen über die Molekülstruktur der Radikale, die elektrochemische Mechanismen aufzuklären vermögen; dies wird an einigen Beispielen erläutert.
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  • 81
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 196-199 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Durch eine galvanostatische Impulsmethode mit Stromumkehr wird die Ladungsausbeute an Magnesium-Elektroden in Lösungen von Grignard-Reagens in Diäthyläther gemessen. Die charakteristischen Wirkungen von Sauerstoff, Aceton und einigen Halogenkohlenwasserstoffen - durch alle drei Zusätze wird z. B. die Ladungsausbeute verringert - werden beschrieben und diskutiert. Abschließend werden einige Anwendungsmöglichkeiten der Methode auf andere Probleme vorgeschlagen.
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  • 82
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 199-202 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Elektrochemisch reduzierbare organische Substanzen, besonders aromatische Nitro-Verbindungen, werden wegen ihrer hohen theoretischen Energiedichte als Elektrodenmaterial in energiereichen galvanischen Primärzellen verwendet. Der heutige Stand der Entwicklung solcher Organo-Primärzellen wird dargestellt. Im Laboratorium hergestellte Zellen mit m-Dinitrobenzol als positiver und Magnesium als negativer Elektrode erreichen heute Energiedichten von 100 bis 160 Wh/kg. Eine industrielle Fertigung solcher Zellen ist bisher nicht bekannt geworden.
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  • 83
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Für Batterien großer Energiedichte werden elektrochemische Systeme mit sehr elektronegativen Metallen in protonen-freien organischen Lösungsmitteln erwogen. Theoretische Überlegungen zeigen, daß aus physikalisch-chemischen und technischen Gründen neben einer Lithium-Anode für die Kathode nur eine sehr begrenzte Auswahl von Elektroden-Materialien in Frage kommt, was experimentell bestätigt werden konnte. Dreieckspannungsmessungen in Propylencarbonat ergaben, daß als Anode Lithium am besten geeignet ist, während für die Kathoden nur die Chloride des Silbers und Kupfers sowie für geringe Stromdichten noch die Fluoride dieser Metalle brauchbar sind. Die technischen Möglichkeiten derartiger Hochenergiebatterien sowie ihre Vor- und Nachteile gegenüber herkömmlichen Systemen werden diskutiert.
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  • 84
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Verschiedene aromatische Nitro-Verbindungen sind aufgrund ihrer hohen theoretischen Coulomb-Kapazität als Depolarisator für Primärbatterien interessant. Zur Herstellung von Elektroden muß die organische Substanz mit elektronenleitenden Stoffen verarbeitet werden, welche bezüglich der Reduktionsreaktion eine ausreichende elektrochemische Aktivität aufweisen. Am besten geeignet sind hierfür bestimmte Aktivkohle-Pulver. Die richtige Auswahl der verwendeten Kohle sowie die Herstellungsmethode sind von entscheidendem Einfluß auf die Elektrodeneigenschaften. Durch ein spezielles Verfahren ist es gelungen, Elektroden zu entwickeln, die mit Stromdichten bis zu 1 A/g aktiver Masse im Dauerbetrieb belastet werden können. Herstellung und Eigenschaften dieser Elektroden werden beschrieben.
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  • 85
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 213-218 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bei der Erzeugung von elementarem Phosphor hält der Trend zur weiteren Produktionssteigerung auf der ganzen Welt an. Für den Anfang der siebziger Jahre rechnet man mit einer jährlichen Gesamterzeugung von rd. 1 Mio t. In diesem Beitrag wird ein kurzer Überblick über den gegenwärtigen Stand der Technologie auf diesem Gebiet gegeben. Außerdem werden wirtschaftliche Tendenzen für die Herstellung von Phosphorsäure nach dem thermischen und dem nassen Aufschlußverfahren sowie die Möglichkeiten zu leistungsstärkeren Einheiten diskutiert.
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  • 86
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Die Untersuchung elektrochemischer Zellen mit nichtwäßrigem Elektrolyten hat zur Konstruktion einer praktisch verwendbaren Li/CuS-Primärbatterie mit einer spezifischen Energie bis zu 300 Wh/kg geführt. Darüber hinaus wurden wiederaufladbare Systeme mit Li/CuCl2-Elektrodenpaaren und halogenhaltigen Lösungsmitteln entwickelt. Ihre Energiedichten liegen vier- bis sechsmal höher als die konventioneller Systeme.
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  • 87
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 226-230 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 88
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 230-232 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 89
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Wesentlich für den optimalen Ablauf elektrothermischer Verfahren mit Anfall von Schlacke ist der Widerstand, den der elektrische Strom im Ofen findet. Es ist für die einzelnen Produkte von Bedeutung, welche Temperatur im Reaktionsraum erreicht wird, weiterhin auch die Lage des Reaktionsraumes im Ofen. Nach ausführlicher Besprechung der Möglichkeiten zur Beeinflussung des elektrischen Widerstandes wird der Einfluß der Schlacken-Zusammensetzung auf die Herstellung von Ferrochrom-Legierungen behandelt. Bei den Schlacken der Ferromangan-Legierungen führen nur bauliche Maßnahmen, d. h. große Elektrodenabstände, zu günstigen Reduktionsergebnissen.
    Additional Material: 3 Ill.
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  • 90
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Für die Chloralkali-Elektrolyse wurden Anoden mit einem Gerüst aus Titan entwickelt, das mit einem Gemisch von Oxiden bedeckt ist. Die neuen Anoden zeichnen sich durch gute chemische und mechanische Beständigkeit aus. Das entstehende Gas kann aus dem Elektrodenzwischenraum gut entweichen. Die Elektrodenoberfläche ist über lange Zeit elektrokatalytisch wirksam und verhältnismäßig unempfindlich gegen eine Berührung mit Quecksilber und Amalgam. Zellen mit den neuen Anoden arbeiten wirtschaftlicher als Zellen mit Graphit-Anoden.
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  • 91
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 233-234 
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 92
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 235-235 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 93
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 236-237 
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 94
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    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 95
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 238-240 
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 96
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 237-238 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 97
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Es wurde ein neues mathematisches Modell der Filtration aufgestellt, das den funktionellen Zusammenhang der abhängigen und unabhängigen Betriebsvariablen eines Trommelzellenfilters für den stationären Betrieb beschreibt. Durch Versuche an einer Drehfilteranlage technischer Größe wurde das theoretische Modell überprüft. Einige fehlende Zusammenhänge mußten ergänzt werden, so vor allem die Berechnung des spezifischen Filterkuchenwiderstandes in Abhängigkeit von der KornGrößenverteilung des suspendierten Feststoffes.
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  • 98
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 255-258 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bei Taumelsieben ergibt sich der Transport des Siebgutes über die Siebfläche aus der Überlagerung zweier Förderwirkungen. Einmal erzeugt die Taumelbewegung einen Guttransport längs einer logarithmischen Spirale. Daneben entsteht durch die gegenseitigen Stöße der Teilchen untereinander eine zweite Transportwirkung, die dem Gefälle der Teilchendichte vom Gutzulauf zum Austrag, entsprechend dem Fickschen Gesetz der Diffusion, folgt. Beide Transportkomponenten hängen von der Maschinen-einstellung ab. Die Daten für die Auslegung von Taumelsieben können aus Modell-versuchen an Plansieben gewonnen werden.
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  • 99
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    Chemie Ingenieur Technik - CIT 42 (1970), S. 258-263 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Aus mehreren Chemiebetrieben sind Unfälle bekannt geworden, die sich beim Filtrieren lösungsmittelhaltiger Suspensionen und beim Ausschälen von Filterkuchen in Siebzentrifugen ereigneten. Nach einer Beschreibung der möglichen Explosionsgefahren werden verschiedene Sicherheitsmaßnahmen auf ihre Eignung für Siebzentrifugen untersucht. Auf die Methode der Inertgas-Absicherung mit dauernder Sauerstoff-Messung wird näher eingegangen. Die Untersuchungen beziehen sich im wesentlichen auf Dreisälen-Pendelzentrifugen mit Oben- oder Untenentleerung sowie auf horizontale Schälzentrifugen.
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  • 100
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    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An kleinen, mit Öl, Wasser oder Druckluft betriebenen Zyklonmodellen von 100 mm Dmr. wurden die Wandreibungs- und Druckverlustbeiwerte aus Geschwindigkeits- und Druckmessungen ermittelt, wobei der Auswertung die Zyklontheorie von W. Barth zugrunde lag. Die Wandreibungsbeiwerte wurden erstmalig in einem Diagramm in Abhängigkeit von einer Reynolds-Zahl und der relativen Wandrauhigkeit dargestellt. Der mit diesen Beiwerten berechnete Druckverlust im Abscheideraum steht in guter Übereinstimmung mit Meßwerten. Die Druckverlustbeiwerte des Tauchrohrs sind mit größerer Genauigkeit als bisher ermittelt und in Abhängigkeit vom Verhältnis der Umfangs- zur Axialgeschwindigkeit aufgetragen, wozu auch noch die Reynolds-Zahl als Parameter kommt. Aus Messungen an sehr langen zylindrischen Zyklonröhren wurden die größtmöglichen Wirbellängen ermittelt und in Abhängigkeit von der Reynolds-Zahl angegeben. Alle Ergebnisse können unmittelbar für die technische Auslegung von Zyklonabscheidern verwendet werden.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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