ISSN:
0032-3888
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The synthesis and characterization of novel thermotropic liquid crystalline poly(aryl ether ketone)s based on the reaction of a liquid crystalline mesogen containing monomer, biphenol, and a crystal-disrupting substituted monomer, t-butyl- or phenyl-, hydroquinone with 4,4′-difluorobenzophenone are described. Two families of copolymers - a biphenol/t-butylhydroquinone series of 90,75,50, 25, and 0% biphenol, and a biphenol/phenylhydroquinone series of 75, 50, 25, and 0% - are evaluated. Thermotropic liquid crystalline behavior was observed in the copolymers containing 50 and 75% biphenol. The first order and second order transitions associated with melting, crystallization, thermotropic liquid crystalline mesophases, and glass transition temperatures (Tgs) of each copolymer are investigated. The thermal transitions are correlated with optical microscopy and X-ray and/or electron diffraction characteristics. It was observed that the Tg increases and end group concentration decreased after isothermal heat treatment indicative of further polymerization. These materials are believed to be the first known thermotropic liquid crystalline poly(aryl ether ketone)s.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pen.760341002
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