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  • 1965-1969  (8)
  • 1960-1964  (18)
  • 1920-1924
  • Alkaloids
  • Dyes/Pigments
  • Fibers
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Calcified tissue international 4 (1969), S. 210-223 
    ISSN: 1432-0827
    Keywords: Invertebrate ; Tetracycline ; Growth ; Fibers ; Test
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine , Physics
    Description / Table of Contents: Résumé La croissance de la carapace deStrongylocentrotus intermedius est étudiée à l'aide de la tétracycline. Des specimens de l'été ne présentent pas de fluorescence dans les plaques, sauf dans le système apical et les régions voisines. Un faisceau d'éléments fibreux, présentant une autofluorescence blanche laiteuse, est orienté perpendiculairement à chaque ligne de suture. Les spécimens de l'hiver ne présentent ces éléments qu'après décalcification des coupes. La croissance de chaque plaque, chez ces derniers s'effectue de la façon suivante: suture longitudinale » surface interne = mamelon et bosse du tubercule 〉 suture transversale 〉 surface externe de la base de l'épine dorsale 〉 surface externe de la plaque. La carapace adulte augmente de taille selon deux mécanismes de croissance: d'une part, par adjonction de nouvelles plaques au système apical et, d'autre part, par apposition sur des régions données de chaque plaque. Il apparait que des éléments fibreux sont intéressés par la croissance de la carapace et qu'un mécanisme différent de croissance s'observe dans les carapaces de l'été et de l'hiver. Le système apical semble se calcifier selon un mécanisme spécifique qui permet une formation active de plaques nouvelles pendant toute l'année.
    Abstract: Zusammenfassung Das Wachstum des Skeletes vonStrongylocentrotus intermedius wurde mit Hilfe von Tetracyclin untersucht. Bei Sommerexemplaren konnte die Tetracyclinfluorescenz in den Platten nicht beobachtet werden, außer im apicalen System und seiner anliegenden Umgebung. Eine Menge von fibrösen Elementen mit einer milchig-weißen Autofluorescenz war senkrecht zu jeder Nahtlinie angeordnet. Bei Winterexemplaren waren diese Elemente nur in demineralisierten Schnitten deutlich sichtbar. Der Wachstumsgradient jeder Platte war bei Winterexemplaren der folgende: Longitudinalnaht » innere Oberfläche = Terminalknopf und Hals der Tuberkel 〉 Latitudinalnaht 〉 Oberfläche der Basis des Stachels 〉 äußere Oberfläche der Platte selbst. Das ausgewachsene Skelet als Ganzes vergrößert seinen Umfang auf zwei Wachstumsarten, einerseits durch Zusatz von neuen Platten zum apikalen System, anderseits durch Zuwachs an bestimmten Stellen von jeder Platte. Die Resultate lassen vermuten, daß fibröse Elemente am Skeletwachstum beteiligt sind und daß der Mechanismus dieses Wachstums bei Sommer- und bei Winterexemplaren verschieden ist. Es wäre denkbar, daß das apikale System auf einen spezifischen Mechanismus der Verkalkung ansprechen würde, welcher eine aktive Bildung neuer Platten während des ganzen Jahres erlaubt.
    Notes: Abstract Growth of the test ofStrongylocentrotus intermedius was examined with the aid of tetracycline. In summer specimens, tetracycline fluorescence was not observable in the plates, except in the apical system and its adjacent area. An array of fibrous elements with a milky white autofluorescence was oriented perpendicularly to each suture line. In winter specimens the elements were evident only in demineralized sections. The growth gradient of each plate estimated on winter specimens was as follows: longitudinal sture » inner surface = mammelon and part of boss in tubercle 〉 latitudinal suture 〉 outer surface of base of spine shaft 〉 outer surface of plate itself. The mature test as a whole increases in size by two modes of growth, an addition of new plates to the apical system and an accretion on fixed sites of each plate. The results suggest that fibrous elements are involved in the test growth, and that there is a different mechanism of the test growth between summer and winter specimens. The apical system may be equipped with a specific mechanism of calcification which permits an active formation of new plates throughout the year.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Cell & tissue research 101 (1969), S. 323-337 
    ISSN: 1432-0878
    Keywords: Vitreous body ; Hyalocytes ; Three-dimensional network ; Fibers ; Ultrastructure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The vitreous body of the rat eye was studied by scanning electron microscopy. The freeze-dried specimens were either unfixed, freshly frozen or fixed and rinsed before being frozen. The vitreous body is surrounded by a coat of intercellular material covering a thin sheath of chiefly parallel fibers. The latter forms the base for a regularly organized three-dimensional network of fibers. The interfibrillar spaces are filled with ground substance and also contain a few cells. The shape of the cells varies from bipolar to polyhedronal. Their interconnected processes are usually undivided. The functional importance of this complex regular organization of the fibers and cells in the vitreous body is stressed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 7 (1968), S. 530-535 
    ISSN: 0570-0833
    Keywords: Cyclobutenediylium dyes ; Dyes/Pigments ; Squaric acid ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In agreement with the aromaticity and electrophilic behavior of squaric acid, a cyclobutenediyliumtetroxide ion is formulated as a limiting form of the squarate dianion. These views are confirmed by the structure of a series of new compounds that are readily obtainable from squaric acid or its derivatives, and most of which are deeply colored. The compounds contain the cyclobutenediyliumdioxide grouping as the chromophore, and form a new class of dyes, for which the name cyclobutenediylium dyes is proposed.
    Additional Material: 6 Tab.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 7 (1968), S. 278-285 
    ISSN: 0570-0833
    Keywords: Polyamides ; Fibers ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: High molecular weight poly-β-amides with fiber-forming properties (repeating unit—NH—CR2—CR2—CO—) differ from the polyamides of the nylon series in that the amide groups are much more closely spaced. These polymers are thus the nearest of the synthetic polyamides to natural silk. The production of poly-β-amides was made possible by a recent synthesis of β-lactams from olefins and chlorosulfonyl isocyanate. The anionic polymerization of the β-lactams gives poly-β-amides containing up to 10 000 monomer units in the chain. The molecular weight can be controlled as desired by means of initiators and chain terminators, and the properties can be varied within wide limits by the choice of the β-lactam or by copolymerization of several β-lactams. Remarkable differences are observed between polymers containing structural units in the threo form and those containing erythro structural units. The poly-β-amides can be spun into fibers having valuable textile properties.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 5 (1966), S. 984-993 
    ISSN: 0570-0833
    Keywords: Dyes/Pigments ; Polymethine dyes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dye molecules containing two or more polymethine structural units, or at least one polymethine and one polyene structural unit, generally exhibit coupling effects that determine the spectroscopic behavior and other physicochemical properties of the substance. The coupling concept can be used inter alia to fit the quinone dyestuffs, the indigoids, and the indanthrenes into a general poymethine color system and to perdict new dye structures.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 4 (1965), S. 619-635 
    ISSN: 0570-0833
    Keywords: Dyes/Pigments ; Photoelectric semiconductors ; Semiconductors ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Photoconduction in organic dyes is caused by the formation and migration of electronic charge carriers, and is not due to impurities or photochemical decomposition. The phenomena of dark and light-induced conduction in dyes can therefore be interpreted in the same way as in inorganic semiconductors.
    Additional Material: 14 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 4 (1965), S. 312-321 
    ISSN: 0570-0833
    Keywords: Cotton dyes ; Dyes/Pigments ; Reactive dyes ; Pyridazones ; Basazol dyes ; Primazin P dyes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The present paper deals with new cotton dyes, approaching the subject from two directions. In the first section the synthesis of a new type of reactive dye from products of Peppeacetylene chemistry is reported. The second part describes a dyeing process which does not stat with reactive dyes. Instead, the homopolar bonding between dye and cotton is formed by linking the dye to the substrate via polyfunctional bridges. These two programs have led to the development of the ®Primazin P and ®Basazol dyes.
    Additional Material: 2 Ill.
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  • 8
    ISSN: 0570-0833
    Keywords: Free radicals ; Polyamides ; Fibers ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The formation of free radicals during the process of drawing of spun fibers was observed for the first time with two polyoxamides. The fibers turn red, and an ESR signal can be detected. Both, color and ESR absorption are not permanent. The decrease in the intensity of the ESR absorption and the change in the optical reflectance with time, as well as the dependence of the decoloration on temperature were investigated. The action of high-energy radiation on the polyoxamides also leads to a red coloration and gives rise to ESR signals. It is concluded that the red color is due to free radicals associated with the oxamido group.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 3 (1964), S. 408-416 
    ISSN: 0570-0833
    Keywords: Reactive dyes ; Dyes/Pigments ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two new groups of reactive dyestuffs have been developed. One group (Levafix® dyes) comprises compounds which contain —SO2NH—CH2—CH2—OSO3H or —CH2—N(alkyl)-CH2—CH2—OSO3H as reactive groups. The dyes of this group react with cellulose fibers to form cellulose ethers, e.g. R—SO2NH—CH2—CH2—O—cellulose. The substances in the second group (Levafix-E® dyes) consist of the amides formed from 2,3-dichloroquinoxaline-6-carboxylic acid and dyestuffs containing primary or secondary amino groups.
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 3 (1964), S. 460-470 
    ISSN: 0570-0833
    Keywords: Heat resistance ; Fibers ; Polymers ; Materials science ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This survey is principally concerned with papers published since 1959 on hydrocarbon polymers, aliphatic poly(terephthalamide) fibers, poly(hydroxybenzoic acid) films, poly(oxadiazole) fibers, poly(benzimidazole) films, poly(phenyltriazole) films, poly(pyromellitimide) films, and fibers from cyclized poly(acrylonitrile). All these materials have extremely high melting points and satisfactory in-use characteristics at high temperatures.
    Additional Material: 5 Ill.
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  • 11
    ISSN: 0570-0833
    Keywords: Phenolic bases ; Alkaloids ; Condensation ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Provided they contain quaternary nitrogen, simple phenolic bases can undergo oxidative condensation under conditions similar to those of biogenesis to form alkaloids of the isoquinoline series with good yields. By means of such oxidative condensations, more than sixty alkaloids of various structural types have become more easily obtainable. Of the numerous possible condensations of the intermediate mesomeric radicals only those which lead to naturally occurring alkaloids give good yields and few by-products. The results suggest that oxidative condensations of quaternary bases are also involved in the biosynthesis of alkaloids in the plant cell.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 20-23 
    ISSN: 0570-0833
    Keywords: Reactive dyes ; Dyes/Pigments ; Reactive dyes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Compounds and dyes containing vinylsulfonyl groups or groupings which readily yield vinylsulfonyl groups possess a marked ability to add onto many compounds containing active hydrogen under alkaline conditions. They also react with natural substances of high molecular weight, e.g. wool and cellulose, which contain amino- or hydroxyl groups. These reactions lead to the formation of strong covalent bonds between the reactants. As a result of this finding, reactive dyes for nitrogenous and cellulose fibers have been developed.
    Type of Medium: Electronic Resource
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  • 13
    ISSN: 0570-0833
    Keywords: Polycondensation ; Dyes/Pigments ; Bunte salts ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dyes which contain only thiosulfate residues as water-solubilizing groups are readily polycondensed on cellulose under mild conditions in the presence of condensing agents such as sodium sulfide to give insoluble, high molecular-weight dyes. This type of fixation leads to wash-fast dyeings and, in contrast to reactive dyes, involves no reaction with the fiber. The preparation and application of the dyes are described.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 243-247 
    ISSN: 0570-0833
    Keywords: Ergot alkaloids ; Alkaloids ; Biosynthesis ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In this article the biogenesis of the ergoline ring in lysergic acid derivatives and the clavines is discussed. T·yptophan and mevalonic acid are the precursors. The N-methyl group is supplied by formate or methionine. Concepts and results dealing with the manner in which the compounds are formed are discussed. Finally, the known biogenetic relationships among the ergot alkaloids are discussed in connection with their biogenesis.
    Additional Material: 1 Tab.
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  • 15
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 341-357 
    ISSN: 0570-0833
    Keywords: Biosynthesis ; Alkaloids ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 410-420 
    ISSN: 0570-0833
    Keywords: Oligomers ; Pleionomers ; Polymers ; Fibers ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The term “oligomer” is defined, and a survey of methods for the isolation and synthesis of cyclic and linear oligoesters, oligourethanes, oligo(acrylonitriles), and oligoamides is presented. The oligomers serve a valuable function as model substances for the investigation of many properties of the corresponding high polymers. This is shown using several examples (infrared spectroscopy, X-ray spectroscopy, viscosity).
    Additional Material: 1 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 441-458 
    ISSN: 0570-0833
    Keywords: Biosynthesis ; Alkaloids ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 41-45 
    ISSN: 0570-0833
    Keywords: Dyes/Pigments ; Rutile structure ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Until the present time, new color pigments have been developed by isotypic and homotypic mixed-phase formation. This paper deals primarily with heterotypic mixed-phase formation for the preparation of new colored and white pigments with the rutile structure. Dioxides and difluorides crystallizing in the rutile lattice-form were chosen as host-lattices for the mixed-phase formation. Hosts of the general formula AB2 can accommodate, as guests, in the form of solid solutions, oxides and/or fluorides with different structures. Characteristically, the mean statistical cation-radius lies between 0.55 and 0.98 Å, with single radii between 0.46 and 0.98 Å. Relative quantities are so chosen that the cation to anion ratio of 1:2 prescribed by the host lattice, as well as electroneutrality, is maintained.
    Additional Material: 6 Ill.
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  • 19
    ISSN: 0570-0833
    Keywords: Azo dyes ; Dyes/Pigments ; Oxidative coupling ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New findings in the field of oxidative coupling reactions are reported. These involve: extension of this type of reaction to amidrazone system displaying (vinylogous) tautomerism and to unsymmetrical diarylhydrazines; elucidation of the coupling mechanism for these arylhydrazines and for the amidrazone systems previously described; the properties of some dyes, complexed with heavy metals, and the synthesis of tetraazapentamethine and penta-azapentamethine dyes.
    Additional Material: 1 Tab.
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  • 20
    ISSN: 0570-0833
    Keywords: Copolymers ; Fibers ; Vinylidenedicarbonitrile ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vinyldendicarbonitrile (Vinylidene cyanide) on free redical catalyzed copolymerization shows a much stronger tendency to form 1:1 alternating copolymers than acrylonitrile. While bulk poly(vinylidene cyanide) fails to crystallize, despite its molecular symmetry, several alternating copolymers are readily crystallizable, notably those containing butadiene, isoprene, isobutylene, or vinylidene chloride. Fibers have been prepared from a number of the higher melting copolymers and examined for physical properties. Fibers from the vinyl acetate and vinyl chloride copolymers show expectional elastic behavior both when dry and wet. The fiber from the vinylidene cyanide |vinyl acetate alternating copolymer (Darvan® nytril fiber) is only moderately oriented and is characterized by exceptional softness and excellent elastic recovery and resilience, both when dry and wet.
    Additional Material: 9 Ill.
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  • 21
    ISSN: 0570-0833
    Keywords: Pyrrolidone ; Polyamides ; Fibers ; Lactams ; Polymerization ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The industrial production of capryllactam (1-azacyclononan-2-one) and of laurolactam (1-azacyclotridecan-2-one) starts with cyclization of acetylene or butadeine to give cyclooctatetraene or cyclooctadiene, or cyclization of butadiene to give cyclododecatriene. Further steps are: oxidation of the cyclic hydrocarbon to the ketone, formation of the oxime, and rearrangement of the latter with sulfuric acid. Pyrrolidone can be prepared from acetylene and formaldehyde by way of butyrolactone. The behavior of the lactams during polycondensation is described and the properties of the resulting fibers are compared with those of the known polyamide fibers.
    Additional Material: 2 Ill.
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  • 22
    ISSN: 0570-0833
    Keywords: Long periods ; Polyethylene ; Fibers ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Meridional reflections appearing in small-angle X-ray diffraction diagrams of drawn polyethylene are caused by a nearly periodic arrangement of crystalline and disordered regions. The long period, which is determined by the average distance between two consecutive crystallites, depends on the method of preparing the sample. The time and temperature dependences of the positions of the small-angle reflections have been investigated. The growth of the long period of unoriented bulk polyethlene and polyethylene single crystal follows the same time dependence as that of stretched films. However, characteristic differences were obseved in the relationship between density and long period; they are attributed to the fact that in single crystals and in material crystallized from the melt, the chains are folded at the boundaries of the crystallites, whereas this in not the case in stretched polyethylene.
    Additional Material: 25 Ill.
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  • 23
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 568-572 
    ISSN: 0570-0833
    Keywords: Trichloropyrimidyl dyes ; Dyes/Pigments ; Dichloropyrimidyl dyes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several examples are used to show that the reactivity of dichloro- and trichloropyrimidyl dyes and the sensitivity of their dyeings to hydrolysis are determined by the nature of the bridge unit between the chromophore and the reactive system. The tendency of the dyeings to hydrolyze in acid and, more particularly, in alkaline media increases with increasing reactivity of the dyes. In alkaline media, dyeings made with dyes containing oxygen bridges are cleaved mainly between the reactive system and the chromophore, while in dyeings made with dyes containing imino or methylimino bridges, the linkage between the reactive system and the cellulose is hydrolyzed.
    Additional Material: 4 Ill.
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  • 24
    ISSN: 0570-0833
    Keywords: Elastomers ; Fibers ; Polyurethanes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Highly elastic polyurethanes suitable for fiber production can be obtained by various synthetic routes based on diisocyanate polyaddition processes. Macrodiisocyanates obtained from long chain diols and diisocyanates are allowed to react with polyamines during fiber formation (chemical spinning process) or the macrodiisocyanates are treated in solvents (e.g. dimethylformamide) with polyamines to give highly viscous, spinnable solutions of polymer. Both methods yield highly elastic polymers with wide-mesh network structures. The production of polyurethane fibers and their structures and physical properties are described.
    Additional Material: 6 Ill.
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  • 25
    ISSN: 0570-0833
    Keywords: Lactams ; Polymerization ; Fibers ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Lactams can be prepared by cyclization of β-aimno acid esters. Recently they have become available also from olefins by addition of N-carbonysulfamyl chloride (isocyanatosulfonyl chloride) and from aldehydes by reaction with N-carbonylsulfamyl chloride and ketene. Condensative or anionic polymerization results in polyamides the chains of which contain many more amide groups than the chains of polyamides of the nylon-6 type. Hence the new polymers resemble silk moreclosely. Fibers and films can be prepared from solution.
    Additional Material: 7 Ill.
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  • 26
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 532-537 
    ISSN: 0570-0833
    Keywords: Polyacrylonitrile ; Fibers ; Azatrimethinecyanines ; Dyes/Pigments ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Like all basic dyes, azatrimethinecyanines possess a good dyeing affinity for acrylic fibers. Compounds with isolated nitrogen atoms in the trimethine chain show insufficient light fastness, whereas good to excellent fastness to light is displayed by compounds having neighboring nitrogen atoms in the chain. Thus, a working hypothesis stating that the light fastness of trimethinecyanines on acrylic fibers is improved by progressive replacement of methine groups by nitrogen atoms has been partially confirmed.
    Additional Material: 3 Tab.
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