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  • 1970-1974  (400)
  • 1970  (400)
  • Analytical Chemistry and Spectroscopy  (346)
  • Engineering  (54)
  • Engineering General  (54)
Materialart
Erscheinungszeitraum
  • 1970-1974  (400)
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 3-3 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 2-2 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 5-32 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The program given here assembles and solves symmetric positive-definite equations as met in finite element applications. The technique is more involved than the standard band-matrix algorithms, but it is more efficient in the important case when two-dimensional or three-dimensional elements have other than corner nodes. Artifices are included to improve efficiency when there are many right hand sides, as in automated design. The organization of the program is described with reference to diagrams, full notation, specimen input data and supplementary comments on the ASA FORTRAN print-out.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 33-43 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: In the design of a guyed mast the design specification often imposes limits on the allowable deflection of the mast under wind and other lateral loads. While the deflected form of a mast depends on many different design parameters, the guy erection tensions form one of the simplest means of controlling the lateral displacements. The paper describes a procedure for calculating these tensions in the case of a mast required to have a specified set of displacements under a given set of lateral loads. It also discusses the case where specified deflections are not to be exceeded under a number of different loading conditions.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 45-59 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper is concerned with the development of a computational algorithm for the solution of the uncoupled, quasi-static boundary value problem for a linear viscoelastic solid undergoing thermal and mechanical deformation. The method evolves from a finite element discretization of a stationary value problem, leading to the solution of a system of linear integral equations determining the motion of the solid. An illustrative example is included.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 61-71 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The transient field problem of the type encountered in heat conduction problems is formulated in terms of the finite element process using the Galerkin approach. Curved two-dimensional and three-dimensional, isoparametric elements are used in a time-stepping solution and their advantages illustrated by means of several examples.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 8
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The proposed finite element model is based on separate assumptions of interior and interelement displacements and on the assumed boundary tractions of each individual element. The associated variational functional for this model is presented. This method has the same merits of the assumed stress method (References 3 and 4) in that a compatible displacement function at the interelement boundary can be easily constructed, while it can easily be used for shells with distributed loads.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 117-131 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A numerical method for the analysis of field problems is described. The algorithm is based upon the generalized Betti-Maxwell theorem. Using a set of known solutions to problems with similar boundary conditions produces a set of ‘integral’ equations for the required solution. Using any convenient numerical integration formula reduces the problem to the solution of a set of simultaneous algebraic equations. The accuracy of the solution depends upon the accuracy of the integration formula as applied to the problem under consideration and is independent of the known auxiliary solutions. The method is described in detail as applied to harmonic problems.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 85-98 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Considerable attention has been devoted in the literature on numerical methods towards securing energy convergence of solutions for, say, linearly elastic plate bending problems. Although energy convergence is necessary it by no means follows that the derived bending moments and shearing forces converge uniformly at a given point and it is this kind of feature which the engineer is really seeking.This question is examined in the context of a problem which is of particular interest to the civil engineering field and concerns the bending of a square plate under uniformly distributed load; the plate has simply supported edges and contains a central square hole with free edges. The solution to this multiply connected and mixed boundary value problem is obtained through a recently developed modification to the Rayleigh-Ritz method which has very general application and renders the solution mathematically valid up to the internal corner points where the bending moments are singular. Use is made of triangular equilibrium finite elements in conjunction with continuous eigenfunctions. Although it is already known that the order (i.e. the eigenvalue) of the singularity at the internal corners is available by inspection, it is an interesting feature of the present solution that a good approximation to the amplitude is also obtained by an inspection of the finite element results.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 11
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 99-116 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The convergence rates of eigenvalue solutions using two finite plate bending elements are studied. The elements considered are the well-known 12 degree of freedom, non-conforming rectangular element and the 16 degree of freedom, conforming rectangular element. Three problems are analysed, a square plate simply supported on two opposite sides with the other two sides clamped, simply supported, or free. Closed form, finite element solutions for these problems are obtained by using shifting E-operators.With few exceptions, eigenvalue solutions found with the non-conforming element converge from below the exact answers at an asymptotic rate of n-2, where n is the number of elements on a side. However, since the array size needed for such convergence is very large, little can be said about the convergence rates for practical arrays. The conforming element solutions converge from above at an asymptotic rate of n-4. A comparison of the errors involved in using these two elements shows that the conforming element is far superior to the non-conforming element.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 12
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 145-146 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 13
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 14
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 146-147 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 15
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 133-144 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper presents a labour-saving method of discretizing irregular and inhomogeneous two-dimensional continua into triangular elements. The method uses a magnetic pen to record node point data and a computer program to generate element data. This technique eliminates the tedium in the manual generation of data and the delay due to mistakes which would otherwise arise frequently for a complex mesh.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 16
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 151-157 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A finite element formulation which includes the piezoelectric or electroelastic effect is given. A strong analogy is exhibited between electric and elastic variables, and a ‘stiffness’ finite element method is deduced. The dynamical matrix equation of electroelasticity is formulated and found to be reducible in form to the well-known equation of structural dynamics, A tetrahedral finite element is presented, implementing the theorem for application to problems of three-dimensional electroelasticity.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 17
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 175-188 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A numerical method is presented for the solution of the radially symmetric heat conduction problem in a melting sphere. The method employs the embedding technique; this permits the solution to be written in the form of an ordinary integro-differential equation which is readily solved numerically by means of a forward integration scheme. The accuracy of the method is briefly discussed and numerical results for both constant and variable heat inputs are presented.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 18
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 159-174 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper is concerned with the development of general discrete models for the analysis of boundary-value problems in the first strain-gradient theory of elasticity. Extensions of the finite element method are constructed for this purpose, and general equations of motion are derived for finite elements of a class of micro-polar materials which are characterized by strain energy functions involving strains and second gradients of strains or displacements. The notion of generalized nodal doublets is introduced. The problem of a composite consisting of a strain-gradient sensitive microlayer embedded between semi-infinite bodies is examined as an example problem. Some of the results are compared with available exact solutions.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 19
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Methods for the analysis of complex, highly redundant structures subjected to intermittent loads causing biaxial membrane stress and stress reversal into the plastic range are presented. The Bauschinger effect in multi-axial stress is taken into account by the use of Ziegler's modification of Pragers kinematic hardening theory. The implementation of this plasticity theory in the discrete element methods involves the application of the loading in small increments. A linear relationship between increments of plastic strain and of stress, arising out of the theory, is used in conjunction with a linear matrix equation that governs the elastic behaviour of the structure. In the latter equation, plastic strains are interpreted as initial strains. A solution to the linear matrix equation, expressed in terms either of stress or of total strain, may be obtained by utilizing one of two alternative procedures. The methods are capable of treating materials which exhibit elastic-plastic behaviour involving ideal plasticity, linear or non-linear strain hardening, or limited strain hardening. Application is made to several representative structures. Comparison of some of the results with existing test data for both monotonic and reversed loading shows good correlation.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 20
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 221-228 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A general digital computer method based on a Sturm sequence procedure is described for determining the natural frequencies and associated modes of undamped free vibration of frames and other structures whose stiffness and mass matrices are of band form. A program which uses the method for the analysis of plane multi-storey building frames is outlined, and numerical results are presented for a simple test case and for a 19-storey frame.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 21
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 207-219 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A newly developed numerical Laplace transform inversion technique is described. A derivation of the method, termed the ‘multidata method’, is presented along with a description of a similar collocation method. Similarities and differences between the two numerical methods are described and discussed. Results of parameter studies of both methods are presented which demonstrate the sensitivity to error displayed by the collocation method and the magnitude of the improvement in accuracy obtainable with the multidata method as compared with the collocation method, especially when errors exist in the function to be inverted.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 22
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 229-241 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: In this study, finite element solution procedures are developed for an elastica problem of inextensible beams. The element stiffness matrices are obtained by using Galerkin's method. Results of a numerical example compare reasonably well with those obtained by using the elliptical integral.Extensions of this research are currently being made to include membrane effects of beams and to develop plate element stiffness matrices for elastica problems of plate structures.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 23
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 243-252 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This report summarizes an experimental application of the finite element approach to two-dimensional inviscid fluid flow.The method results in a matrix equation relating the vector of velocities at the nodal points with the vector of singularities. The singularities, which are concentrated at the nodes, consist of a source and a vortex.On solution of this equation (defining the flow in the region), boundary conditions must te stipulated. This usually involves setting the internal singularities to zero and making certain modifications ro those lying on the boundary of the region.Some results of the application to a particular problem are included in the paper.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 24
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 253-257 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Some typical results of an extensive series of evaluations of parallelogram-shaped plate bending elements with increasing levels of sophistication are presented. It is shown that, contrary to experience in other fields of stress analysis, this sophistication does not lead to striking improvements in accuracy in the solution of simple rectangular and skew plate problems. A computational procedure is described whereby stiffness matrices may be automatically generated from the minimum of input data specifying the displacement modes prescribed for the element.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 25
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 259-264 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A conforming plate bending solution using simple polynomial deflection functions of third-degree inside each triangular element is presented. In order to avoid normal slope discontinuities along the sides of the elements, the plate displacement parameters are subjected to ‘slope continuity conditions’ acting as constraints to the minimum potential energy problem. This is then solved by the classical method of Lagrange introducing multipliers as new auxiliary variables. If a special variational formulation of the problem is used, it can be shown that the Lagrangean multipliers are generalized stress parameters. The suggested solution is therefore basically a ‘mixed’ solution, the unknown variables of the problem being both displacement and stress parameters. Several numerical results are presented.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 26
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 265-275 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Approximate formulations of non-uniform beam element stiffness matrices for dynamic and elastic instability analysis are derived. Displacement functions for the uniform beam segment are employed in this development. Moment of inertia and area of the element are prescribed by arbitrary powers of the axial co-ordinate. Numerical results are obtained and compared with both analytical solutions and numerical solutions based upon stepped representations using uniform section elements. The significance of the inclusion of taper considerations within individual elements upon solution accuracy and convergence characteristics is also examined. This subject problem and solution approach demonstrates that the upper bound character of minimum energy solutions may be difficult to exploit under practical circumstances.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 27
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 277-282 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This article describes-a new method, suitable for use on a digital computer, for evaluating the singular double integral of Hayes which determines the transonic wave drag of a slender body. Comparison with known exact results and with an earlier computer program described by Eminton shows the present method to be accurate as well as economic in computer time.
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
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  • 28
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 283-293 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The complementary variational principle has been used to derive the differential equations and the associated boundary conditions of the vibrating plate in terms of bending moments. It is shown that in this formulation, the plate possesses an infinite number of zero frequency modes in which the plate remains in a state of constant strain under a set of self-equilibrating bending moments. In applying the Rayleigh Ritz procedure for the non-zero frequency modes of the plate, it is shown that it the assumed functions are orthogonal to only a finite number of zero frequency modes, then one may obtain frequencies which are lower than the true frequencies of the plate. An iliustrative example is given in the paper.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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  • 29
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 30
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 299-299 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 31
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 301-303 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 32
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 33
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 307-310 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Convergence of a finite element procedure for the solution of the fourth-order equations is proved. A generalization of this result is mentioned and some remarks concerning the numerical results obtained at the Computing Centre of the Technical University in Brno are given.
    Materialart: Digitale Medien
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  • 34
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 311-333 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Digital filters are finding wide applications in signal processing aspects of such fields as engineering, geophysics and biosignal analysis. The design of a digital filter and its realization with near minima computer word length are two problems which can be solved by computer-aided design techniques In this paper, the automated design of the initial filter (recursive type) only is considered. Both of the basic design methods - the direct and indirect approaches - have been analysed, and compute programs have been written to implement the various design techniques. The present program are limited to the design of flat loss type filters specified by their gain rather than their phase character istics. although provision has been made to allow for other types of design in the indirect approach Design examples are given, and the results analysed with a view to the suitability and limitations of the different design techniques.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 35
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 353-361 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper demonstrates the applicability of general non-linear programming methods to the solution of buckling problems. The minimum energy formulation of the buckling condition is shown to yield an unconstrained non-linear programming problem, for which several numerical methods of solution are readily available. Some of these methods are discussed and numerical results are presented for stiffened plates with in-plane as well as lateral loads.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 36
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 335-352 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Stiffness matrices are formulated for the torsional and lateral stability analysis of structures composed of flexural members by the matrix displacement method. The formulations are based upon approximate displacement fields which represent the action of the element in simple flexure. Example problems, for which exact solutions are known, illustrate the accuracy and convergence characteristics of the derived formulations.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 37
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 363-385 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A solution has been formulated, which allows one to analyse all the major performance characteristics in a chain of impacting elastic ‘rods’. By allowing one end of the elastic chain to impact against a surface which resists penetration according to a specified penetration law it is possible to analyse the impact system of a variety of mechanical devices such as percussive tools and squeeze film dampers. Virtually, unlimited variety in the number and geometry of the impacting rods, and virtually unlimited complexity in the form of the reaction of the terminal face is permitted. A computer program for treating one or two elastic rods has been developed. The program prints out all important stresses as well as the stress history at several selected points. It also prints out the depth of penetration, the energy transferred from rod to rod, the overall energy transfer into the receiver, rebound velocities and times of separation between rods and between rod and 4receiver. Agreement with exact solutions and experiments is demonstrated.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 38
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 387-395 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A technique of differential displacements is presented whereby problems involving elastic contact are solved by the finite element method. The technique is applied to axisymmetric situations in which statically indeterminate conditions occur and is shown to provide a means for resolving these conditions in terms of contact stresses. Three typical engineering problems are analysed to demonstrate the technique in cases where body forces, thermal gradients and external applied forces are acting.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 39
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 415-418 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Recent advances in finite element techniques have enabled full three-dimensional stress analyses to be undertaken. Economy and accuracy can only be achieved simultaneously if the characteristics of the element are understood. Preparatory work is described in which suitable pitching and disposition of brick-type elements are established for the analysis of cylinders.The information derived is put to use in the analysis of a cylinder-cylinder intersection. A favourable comparison is made with an independently computed solution.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 40
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 397-414 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The velocity field of a semi-contained turbulent jet, as constructed by Abramovich, is used to arrive at the temperature distributions in the initial region of a turbulent flow film cooling situation taking into account both the development of the jet boundary layer and the wall boundary layer. After suitable profiles of eddy thermal conductivity are established, a finite difference form of the thermal energy equation is derived, shown to be unconditionally stable, and solved numerically with the aid of an IBM System 360 computer to yield the temperature distributions. Wieghardt's parameter for collapsing the temperature profiles onto a single curve in film cooling situations, when suitably modified, also collapse the analytical results to essentially a single curve even as near as 2·7 slot heights from the injection point, thus verifying the temperature similarity in film cooling which has been experimentally observed even very near the injection point. Results in graphical form are presented which allows one to construct the actual temperature profile for a fairly wide range of the relevant parameters.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 41
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 42
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 453-454 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 43
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 419-451 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A general formulation for the curved, arbitrary shape of thick shell finite elements is presented in this paper along with a simplified form for axisymmetric situations. A number of examples ranging from thin to thick shell applications are given, which include a cooling tower, water tanks, an idealized arch dam and an actual arch dam with deformable foundation.A new process using curved, thick shell finite elements is developed overcoming the previous approximations to the geometry of the structure and the neglect of shear deformation.A general formulation for a curved, arbitrary shape of shell is developed as well as a simplified form suitable for axisymmetric situations.Several illustrated examples ranging from thin to thick shell applications are given to assess the accuracy of solution attainable. These examples include a cooling tower, tanks, and an idealized dam for which many alternative solutions were used.The usefulness of the development in the context of arch dams, where a ‘thick shell’ situation exists, leads in practice to a fuller discussion of problems of foundation deformation, etc., so that practical application becomes possible and economical.
    Zusätzliches Material: 25 Ill.
    Materialart: Digitale Medien
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  • 44
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 45
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 459-476 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The stiffness equation is derived for curved elements of orthotropic axi-symmetric thin shells, and equivalent applied loads are found for shells subjected to initial strains, applied surface loads and body forces. The Lure approximation of thin shells and displacement field approximation by polynomials of arbitrary degree are included in the formulae derived.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 46
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 477-494 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A computational procedure based on gradient iterative techniques is proposed for the solution of large problems to which the finite element method is applicable. In linear problems the procedure can be used either for solving the set of algebraic equations or for the complete inversion of the matrix of coefficients. Special attention is focused on the practical aspects of the procedure concerning its realization on the digital computer.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 47
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 495-507 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A finite element method to determine unsteady aerodynamic influence coefficients, consistent with the stiffness and inertia properties of a lifting surface in supersonic flow, is described. This is basically a kinematic method, which reduces the dynamical equations of a non-conservative system to a simple and elegant form. It is illustrated by application to a delta wing using triangular elements to calculate steady and unsteady lift and moment coefficients. Throughout the calculations only a coarse grid system has been employed and the answers have been compared with available results.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 48
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 509-522 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A simple program carrying out various vector operations in two- or three-dimensional spaces is presented. The listings are given in A.S.A. FORTRAN IV. The program is of particular application in various forms of three-dimensional and shell analysis as it can create and transform locally orthogonal co-ordinates, etc. While these applications motivated its design, it is of very general use one such application is illustrated by applying the program to general perspective projection.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 49
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 523-533 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A procedure is presented for the automatic renumbering of network type equations prior to solution by sparse matrix techniques. The method takes an arbitrary input sequence and creates an order which makes possible solution of complex network systems by reducing demand for computer storage and time.Examples are presented to demonstrate the procedure in action and show that, even in cases where the system has been carefully numbered, considerable improvement can be achieved. The procedure is also applicable to band matrix solution techniques.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 50
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 579-595 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The feasibility of achieving a preassigned stress state by changing the stiffness of determinate and indeterminate pin connected structures is presented. A new force method with all element forces (or stresses or areas) as independent variables is developed. The possibility but futility of getting the element areas by inverting and pre-multiplying the coefficient matrix with the external load vector when areas are chosen as variables is shown. The relationship existing between the compatibility equations and the plastic strength of pin connected structures is illustrated. Possible design methods for trusses under single or multiplicity of load conditions, the design of truss geometry and the relations between fully stressed and minimum weight structures are examined and illustrated through several examples.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 51
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 563-577 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper deals with solving two-dimensional variational problems of second- and third-order by the finite element method. To each meshpoint are associated three or six basic functions of class C1 or C2. The expression of the admissible functions on a triangular and rectangular element are given here in a general form which is specially suitable for computation.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 52
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 535-549 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The eigenvalue method is well-known as an aid to the solution of a wide range of engineering problems. In power system analysis it has relevance to travelling wave phenomena,1 sensitivity and dynamic stability in synchronous multimachine2 systems, critical speed calculation, vibration of structures and other related topics. The method of numerical solution of eigenvalues depends on the size and nature of the problem and often where large matrices are involved presents great difficulties.This paper describes in detail the application of the escalator method and diakoptics to large eigenvalue problems. The escalator method is a well-established one which consists of a systematic way of escalating from a 2 × 2 matrix up to any desired order in steps of one row and column at a time. The diakoptical method reduces computer storage, calculation time and improves accuracy. This results in the more economical solution of large and complicated problems which cannot be conveniently solved by any orthodox method. The paper deals with problems of degeneracy and means of overcoming these by simple routine processes. It concludes by indicating the particular advantages of the method and its usefulness for a wide variety of general engineering problems.
    Zusätzliches Material: 3 Ill.
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  • 53
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 551-561 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A novel integral equation technique is employed for the analysis of dynamic stability problems. The governing equation of the linearized parametric resonance problem is transformed into an integral equation. The kernel of the integral equation is computed as the influence function for the deflection and/or bending moment of a corresponding beam.The highest derivative of the governing function (in our case fourth derivative of the displacement function) is chosen as the basic unknown. Using the formal analogy with the differential equation of the beam flexure this highest derivative is comprehended as some unknown transverse ‘load’. The distribution of this ‘load’ is a priori assumed to be polygonal. Using elementary methods of structural analysis, the displacements due to the assumed ‘load’ are determined. These displacements, arrayed into a square matrix, approximate the kernel of the governing integral equation.The subsequent procedure via Hill's determinant is a conventional one. The results prove to be accurate enough even for a very modest number of points of integration. This reflects the fact that the method is based on numerical integration rather than on numerical differentiation.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 54
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 597-600 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: In any mesh, rules exist that interrelate the number of internal and external sides, vertices, etc. and the total number of elements. These are given explicitly for plane meshes of triangles and quadrilaterals, and for solid meshes of tetrahedra and cuboidal elements. The method is quite general and discovers all such independent rules that exist. Thus, for a plane mesh of T elements having Vi internal and Vb boundary vertices and Si internal and Sb boundary sides, then \documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{l} T = \frac{1}{3}\left({S_b + 2S_i} \right) = V_b + 2V_i + 2H - 2\quad{\rm (for\,triangular\,elements)}\\ T = \frac{1}{4}\left({S_b + 2S_i} \right) = \frac{1}{2}\left({V_b + 2V_i} \right) + H - 1\quad{\rm (for\,quadrilateral\,elements)} \\ \end{array} $$\end{document} where H is the number of internal boundaries (holes) there might be. For solid meshes, these two-dimensional equations relating elements to sides generalize to \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} T = \frac{1}{6}\left({F_b + 2Fi} \right){\rm\quad (for\,cuboid\,elements)} \\ T = \frac{1}{4}\left({F_b + 2Fi} \right){\rm\quad (for\,tetrahedral\,elements)} \\ \end{array} $$\end{document} where there are Fb boundary and Fi internal faces. Unfortunately, there is no direct generalization of the two-dimensional equations relating vertices and elements: it is only possible to do this by including the Ei internal and Eb boundary edges: \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} T = \frac{1}{8}E_b + \frac{1}{2}\left({E_i - V_i + H - h - 1} \right){\rm\quad (for\,cuboid\,elements)} \\ T = \frac{1}{3}E_b + E_i - V_i + H - H - 1{\rm\quad (for\,tetrahedral\,elements)} \\ \end{array} $$\end{document} where there are H through holes and h cavities.
    Zusätzliches Material: 3 Ill.
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  • 55
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 427-427 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 56
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970) 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 57
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 431-438 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The proton magnetic resonance spectra of 1,4-benzodithiin and 1,4-benzodioxin have been fully analyzed. The effects of the substituent heteroatoms on the chemical shifts of the various protons in the two molecules have been discussed.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 58
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: In the course of configurational and conformational investigations on substituted cyclohexanes, 220 MHz spectra of di- and tri- substituted derivatives were obtained. In many cases the higher frequency permits detailed assignments of all ring protons. Special features of the spectra are discussed.
    Notizen: Im Zuge der Konfigurations- und Konformationsuntersuchungen an substituierten Cyclohexanen wurden 220 MHz-Spektren von di- und trisubstituierten Verbindungen gemessen. In vielen Fällen gestattet die höhere Frequenz eine weitgehende Zuordnung aller Ringprotonen. Spezielle Eigenheiten der Spektren werden diskutiert.
    Zusätzliches Material: 6 Tab.
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  • 59
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 457-465 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Cellulose derivatives are used as examples to show how NMR spectroscopy - at 100 and particularly at 220 MHz - may be applied in structural studies of polysaccharides, namely to distinguish between hexoses and pentoses, to determine the configuration and conformation of the monomer units in the polymer as well as the type of the glycosidic bond. For such investigations the acetyl, benzoyl or methyl derivatives are required. The degree of polymerization (Pw) of the acetates or methyl ethers should be Pw 〈 200 and in the case of benzoates Pw 〈 100.
    Notizen: Am Beispiel der Cellulosederivate wurde gezeigt, wie es mit Hilfe der PR-Spektroskopie - speziell bei einer Meßfrequenz von 220 MHz - möglich ist, in Polysacchariden zwischen einer Hexose und Pentose zu unterscheiden, die Konfiguration und die Konformation des Monomerbausteins im Polymeren sowie die Art der glycosidischen Bindung zu bestimmen. Voraussetzung für diese Untersuchungen sind die Acetyl-, Benzoyl- oder Methylderivate des Polysaccharids, wobei der Polymerisationsgrad bei den Acetaten und den Methyläthern Pw 〈 200, bei den Benzoaten sogar Pw 〈 100 sein sollte.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 60
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 581-604 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: 13C NMR absorption spectra of 50 bicyclic hydrocarbons, alcohols and ketones have been measured, in addition to some terpenes. The 13C chemical shifts are approximately additive for similar compounds and can be used for the determination of molecular structure; they differ for endo- and exo-isomers, just as in proton spectra. These quite regular and predictable 13C shift differences are much larger and are caused by the 1,4-nonbonded interaction between atoms heavier than hydrogen, not by magnetic anisotropy effects.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 61
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 605-611 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The treatment of nitromethane or dinitromethane in aqueous alkaline solutions (1 to 2·5 M hydroxide) with nitrogen dioxide yields the dianion radical of dinitronitrosomethane [C(NO2)2(NO)\documentclass{article}\pagestyle{empty}\begin{document}$ \buildrel\textstyle.\over= $\end{document}] which at 30° has hfsc of aNNO2 = 10·75 and 0·65 and aNNO = 5·80 g. Restricted rotation about the C—NO bond causes magnetic non-equivalence of the two nitro groups which can slowly exchange giving rise to line broadening. The use of 15N labeled nitrogen dioxide gave the dianion radical \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm [C(}^{{\rm 15}} {\rm NO}_{\rm 2} {\rm)(}^{{\rm 14}} {\rm NO}_{\rm 2} {\rm)(}^{{\rm 15}} {\rm NO)} \buildrel\textstyle.\over= {\rm]} $$\end{document} which exists in two equally populated conformations, each of which shows the expected line broadening for a ‘slow exchange’ process in which the nitro groups are being interconverted.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 62
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 619-624 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: NMR parameters for three 3-aza-bicyclo [3.1.0]hexanes are reported, which have been determined from the 100 and 220 MHz spectra, using methods of partial analysis and iterative computer calculations, respectively. A brief discussion of the parameters obtained, with respect to the structure of the 3-aza-bicyclo[3.1.0]hexane system, is given.
    Notizen: Es werden die kernresonanzspektroskopischen Parameter von drei 3-Aza-bicyclo[3.1.0]hexanen mitgeteilt, die aus den 100- und 220 MHz- Spektren durch Teilanalyse bzw. Durch iterative Computerberechnungen ermittelt wurden. Eine kurze Diskussion der erhaltenen Parameter in Hinblick auf die Struktur des 3-Aza-bicyclo[3 1.0]hexan-Systems schließt sich an.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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  • 63
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 625-627 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 64
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 1-6 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: When as many as four vicinal couplings occur between four protons situated on three carbon atoms of a cyclobutane ring, one can employ the Karplus relation to assign the configuration of substituents at the remaining positions and make some inferences about the stereochemistry. Four examples are described; the spectra and data are analyzed.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 65
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: The conformational free energies of CN, Cl and COOC2H5 substituents have been evaluated from the PMR spectra of 4-substituted 3,3,6,6-d4-cyclohexene.The PMR spectra of trans-1,2-dicyano-3,3,6,6-d4-cyclohexane permit the conformational equilibrium (in different solvents) and the gauche diequatorial interaction energy between the two CN substituents to be estimated.
    Notizen: Les enthalpies libres conformationnelles des substituants CN, Cl et COOC2H5 ont été évaluées à partir de l'étude des spectres RMN des cyclohexènes (D4-3,3,6,6) monosubstitués en 4.Les spectres RMN du dicyano-1,2cyclohexane (D4-3,3,6,6)trans ont permis une estimation de l'équilibre conformationnel (dans différents solvants) ainsi que de l'énergie d'interaction gauche diéquatoriale entre les deux groupements CN.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 66
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 165-172 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Proton magnetic resonance spectra of a series of alkyl(oxinato)tin(IV) complexes, alkyl(oxinato)thallium(III), dimethylbis(oxinato)lead(IV), 8-methoxyquinoline, 2-methyl-8-hydroxyquinoline and 8-hydroxyquinoline were studied. The indirect spin-spin coupling constants J23, J34 and J24 of the oxinato ligand in the alkyl(oxinato)tin(IV) complexes and of 8-methoxyquinoline were found to be 4.4 ± 0.2, 8.3 ± 0.2 and 1.7 ± 0.2 Hz, respectively. When the interaction between tin and nitrogen in the oxinato ligand is not strong as in trialkyl(oxinato)tin(IV), the resonance of the 2-proton of the ligand shifts to high magnetic field relative to that of 8-methoxyquinoline, but in the case of the strong interaction, as in dimethyl(oxinato)halogenotin(IV), the resonance is shifted to low magnetic field. The 4-proton signals, however, shift monotonously to low magnetic field with increasing interaction. The behaviour of the 2-proton signals was explained by a paramagnetic anisotropic effect of a nitrogen lone pair of the oxinato ligand and an intramolecular electric field effect and that of the 4-proton by the latter effect. By comparing the change of the δ-values of the 2-, 3- and 4-protons of the alkyl(oxinato)tin(IV) complexes and those of 8-hydroxyquinoline by altering the solvents, from methylene chloride to benzene, it was found that the electron density around the 2-carbon is reduced in the complexes compared with that of 8-hydroxyquinoline.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 67
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Alkali salts of 1-hexyl sulfonate were ionized by laser irradiation and the positive ions were analyzed by time-of-flight mass spectrometry. The sodium, potassium, rubidium and cesium salts produce relatively simple spectra. The major organic ions observed are due to the salt plus a cation or the dimer plus a cation. No molecular or fragment ions were detected. The instrumentation and the method of interpreting these data are described.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 68
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 387-393 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A probability distribution of internal energies is derived for aromatic molecular ions which can decompose to give only a single product whose relative intensity and appearance potential are each a function of Hammett sigma constants, with certain simplifying assumptions.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 69
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. i 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 70
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 455-477 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The technique of ion kinetic energy spectroscopy has been applied to the study of the aromatic hydrocarbons benzene, toluene, naphthalene, 2-methyl naphthalene, biphenyl and anthracene. The method is illustrated by a complete study of naphthalene in which transitions of metastable doubly- and singly-charged ions are listed, including reactions in which singly-charged ions are formed by collision induced charge-exchange reactions of doubly-charged ions and by the double process of charge-exchange and metastable decomposition with loss of one or two hydrogen atoms. Decompositions of doubly-charged ions into two singly-charged ions, together with the kinetic energies released in these decompositions, are also given for all the compounds studied.
    Zusätzliches Material: 22 Ill.
    Materialart: Digitale Medien
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  • 71
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Mass spectra of 3-phenylnitropropane and of its analogues, specifically deuterated in the aliphatic chain and in the phenyl ring, show that the molecular ion loses a molecule of water in two different modes, viz. either with both α-hydrogen atoms or with a γ- and an ortho-hydrogen atom. Moreover, a molecule of nitric oxide is eliminated from the molecular ion and the resulting [M - NO]+-ion appears to decompose further in many complicated ways. This loss of nitric oxide does not arise from an isomerization of the nitro group to a nitrite group, because the [M - NO]+-ion of 3-phenylpropyl nitrite breaks down in an altogether different manner than that of 3-phenylnitropropane. This is demonstrated by the spectra of specifically deuterated analogues of 3-phenylpropyl nitrite.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 72
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: The apparently equal binding of all 9 H-atoms, demonstrated with the aid of deuterium labeling by N. M. M. Nibbering et al.,3 in [C8H9]+-ions generated from β-phenylethyl bromides has been confirmed. This result has been explained by a cyclooctatrienyl structure (a) of the ions. A comparison of the heats of formation of [C8H9]+-ions of different origin reveals, however, that this is not true for [C8H9]+-ions of β-phenylethyl bromide in the ground state. As a result of a study of the influence of substituents at the phenylring of β-phenylethyl bromide on the intensities of the [M — Br]+-ions, R. H. Shapiro et al.4 proposed a phenonium structure (c) for the [C8H9]+-ions. The substituent effect on intensities and AP of [M — CH2Br]+- and [M — Br]+-ions of β-phenylethyl bromides is quite different and can be explained much better by a ‘classical’ structure of the [C8H9]+- ions. This structure can also be deduced by a comparison of the IP and AP of [M — Br]+-ions of benzyl-, β-phenylethyl- and γ-phenylpropyl-bromide.
    Notizen: Die von N. M. M. Nibbering et al.3 aufgrund von Deuteriummarkierungen nachgweisene scheinbar gleichartige Bindung aller 9 H-Atome in [C8H9]+-Ionen, die durch Br-Abspaltung aus β-Phenyläthylbromid im Massenspektrometer entstehen, konnte bestätigt werden. Dieser Befund ist durch eine cyclooctatrienyl-Struktur (a) erklärt worden. Ein Vergleich der Bildungsenthalpien von [C8H9]+-Ionen verschiedenen Ursprungs beweist jedoch, daß dies für die aus ß-Phenyläthylbromid im Grundzustand entstehenden [C8H9]+-Ionen nicht zutrifft. R. H. shapiro et al.4 leiten aus dem Einfulß von substituenten am Phenylkern ovn ß-Phenyläthylbromid auf die Intensität von [M — Br]+-Ionen eine Phenonium-Struktur (c) für die [C8H9]+-Ionen ab. Der substituenteneffekt auf die Intensitäten und AP der [M — CH2Br]+-Ionen substituierter ß-Phenyläthylbromide ist jedoch deutlich anderer Art und läßt sich viel besser mit einer ‘Klassischen’ Struktur der [C8H9]+-Ionen vereinbaren. Für diese Struktur spricht auch ein Vergleich der IP und AP der [M — Br]+-Ionen von Benzyl-, ß-Phenyläthyl- und γ-Phenylpropylbromid.
    Zusätzliches Material: 5 Tab.
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  • 73
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 171-180 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The [56.5*]/[105]+ ratios observed in the spectra of N-(nitrophenyl)benzamides are greater than those observed in the spectra of N-(methoxyphenyl)benzamides. These results differ from those observed in the spectra of monosubstituted benzophenones. An explanation, based on energy distribution and breakdown curves, is employed to rationalize these results, as well as other phenomena reported in the literature.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 74
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 231-235 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Mass spectra of triphenylboroxine, tricyclohexylboroxine, tri-t-butylboroxine and tri-n-butylboroxine are reported and discussed.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 75
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 239-240 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of halogenosubstituted diphenylacetylenes show hydrogen scrambling between the two phenyl rings. As with the halogenobenzenes the randomization process occurs i the molecular ion rather than in the [M - 1] ion as is the case for methyldiphenylacetylene (I, × = CH3).
    Materialart: Digitale Medien
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  • 76
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 261-270 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of O-methyl and O-ethyl thiobenzoates and their derivatives have been recorded together with those of the corresponding S-alkyl thiobenzoates. The direct fragmentations of the O-alkyl thiobenzoates are almost identical to those of alkyl benzoates and of S-alkyl thio-benzoates. Several important differences in rearrangements upon electron-impact can be observed between them, however. These are the migration of the alkyl group from the alkoxy oxygen to the thiocarbonyl sulphur and the migration of a hydrogen from the alkoxy group to the thiocarbonyl group. O-methyl and O-ethyl thioacetates behave similarly. The mass spectra of the thioesters obtained with low electron-accelerating voltages have also been studied.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 77
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 321-331 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of some 14,15-deoxymeliacins are reported and discussed in relation to the previously published fragmentation patterns of the epoxymeliacins. The fragmentation patterns of a few compounds with structures closely related to those proposed for the principal ions in the spectra of the epoxymeliacins are also examined.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 78
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 367-377 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of 1,2,3-benzotriazole and some derivatives with substituents at the 1-position and in the benzenering have been examined. The loss of N2from the molecularion is characteristic; loss of N2 plus the 1-substituent is also common. Structures are proposed for these fragment ions. The relative ease of loss of N2, NO and NS from the molecular ions of benzotriazole, 2,1,3-benzodiazole, 1,2,3- and 2,1,3-benzothiadiazoles is compared.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 79
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 395-398 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: An unexpected correlation of ion intensities with sigma constants was observed for the loss of substituents from biphenyl molecular ions. The observation is more easily reconciled with an argument based upon energy distributions in molecular ions than on interpretation in terms of rates.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 80
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 413-414 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The loss of both HCN and C2H2 from the phenyl nitrenium cation radical generated from 2,4,6-d3-phenyl azide is preceded by H/D randomization.
    Zusätzliches Material: 2 Tab.
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  • 81
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970) 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 82
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectral fragmentation of a number of specially synthesized amino esters and ketones has been studied in which the distance between the two functionalities has been varied. The principal fragments formed following initial ionization are the even-electron immonium ions a and b. Further fragmentation of ion a in the amino esters occurs via non-specific processes. Therefore it is difficult to establish the degree of mobility of the positive charge in the fragment ions, notably whether the species with the charge present on the oxygen atom makes a significant contribution to the fragmentation. The β-(IIb) and γ-(IV) amino ketones show no McLafferty rearrangements after α-fission, thus demonstrating that uncoupling of the carbonyl π electrons is not a feasible trigger in lieu of charge localization.
    Zusätzliches Material: 5 Ill.
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  • 83
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 993-1007 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of o-nitrobenzoic acid, o-nitroanisole, o-nitrosobenzoic acid, o-nitrobenzamide, o-nitrobenzyl alcohol and o-nitrosobenzaldehyde have been studied. Fragmentation mechanisms are proposed for the above compounds; their elucidation was aided by isotopic labeling with D and O18. Two ‘ortho-effects’ are discussed; one involving H atom transfer between substituents and the other migration of an atom or group to a charge carrying vacant ortho position. The importance of nitro to nitrite conversion in molecular and fragment ions is discussed.
    Zusätzliches Material: 7 Ill.
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  • 84
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of diethyl and diphenyl N-phenylphosphoramidate are reported. Their electron-impact behavior is similiar to that observed for the corresponding phosphate esters. High resolution mass measurements are used to confirm the elemental composition of all the peaks in the spectra. Some interesting rearrangement fragments are observed in the spectrum of the diphenyl N-phenylphosphoramidate ester.
    Zusätzliches Material: 2 Ill.
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  • 85
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 1055-1066 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The electron-impact mass spectra and the field ionization mass spectra of 1-chloro-2-nitrosocyclohexane and 1-chloro-2-nitrosocyclopetane are presented and discussed. The two compounds investigated exist in dimeric form in the gaseous phase.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 86
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 1089-1092 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectrum of valeraldehyde o-nitrophenylhydrazone displays only a low intensity peak (3% relative abundance) corresponding to the loss of 35 mass units from its molecular ion contrary to data previously published. Mention is also made of the fragmentation of 5-nonanone 2,4-dinitrophenylhydrazone in view of a recent challenge to a published rationalization for the electron impact promoted fragmentation for this compound.
    Zusätzliches Material: 2 Ill.
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  • 87
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 1098-1098 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 88
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of 3,8-dichloro-11H-dibenzo[c,f] [1,2]diazepine, the corresponding diazepin-11-01 and diazepin-11-one and their dihydro and N-oxide derivatives have been recorded. The most important fragmentation of the molecular ions of all diazepines studied was an initial loss of m/e 28, with further fragmentation depending on the 11-substituent. No general pathway was observed for the corresponding N-oxides and dihydro compounds.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 89
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The characteristic mass spectral fragmentation patterns of the basic structure of the steroidal sapogenin, (25R)-5α-spirostan, have been elucidated through the preparation of analogs with deuterium labels at positions 11, 12, 14, 15, 16, 17, 20, 21, 23, 24, 25, 26 and 27. In addition, the effects of a change of stereochemistry at positions 14 and 20, of the introduction of oxygencontaining functionalities mostly in ring F, and of the incorporation of olefinic unsaturation have been determined through synthesis of many examples.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 90
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 1527-1533 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Evidence for an acetylenic rearrangement, involving the ring-closure of ions containing the N-propargylaniline substructure to the corresponding quinoline ions, has been obtained in a study of the electron-impact induced fragmentation of 1,4-dihydro-4-oxo-2-phenyl-1-propargylquinazoline (I) and 1,2,3,4-tetrahydro-2-oxo-3-phenyl-1-propargylquinazoline (II). The N-propargylaniline moiety is formed from compounds I and II through the RDA process. N-Methyl-N-propargylaniline (III), which was examined as a model compound, was also found to undergo this rearrangement but N-methyl-N-propargyl-2,6-xylidine (IV), on the other hand, exhibits a quite different fragmentation pattern due to its blocking methyl groups, which prevent the rearrangement. Exact mass measurement and specific deuterium labelling were used to establish the fragmentation routes.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 91
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 1325-1331 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The molecular ion-minus-ammonia [M - NHJ] fragmentation of (3-phenylpropyl) primary amines is a major contributor to the total ion current. This fragmentation occurs to a lesser extent in the lower and higher homologs, (2-phenethy1)- and (4-phenylbuty1)amine. The loss of methylamine and dimethylamine from N-methyl-(3-phenylpropyl)amine and N,N-dimethyl-(3-phenylpropy1)amine respectively is essentially absent. Deuterium labeling has shown that C-3 is the primary source of hydrogen abstracted in the [M — NHJ] fragmentation of (3-pheny1propyl)amine.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 92
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970) 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 93
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 65-80 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: The mass spectrometric study of 1-methylcyclopentene, methylenecyclopentane, cyclohexene, 1-hexyne and 2-hexyne enabled determination of the ionization potentials of these molecules together with the appearance potentials of their principal fragment ions. The heats of formation of these ions have been calculated and the values are discussed. There is evidence for hydrogen atom rearrangements occurring during the formation of some fragment ions. Adiabatic ionization energies of 1-methylcyclopentene and methylenecyclopentane have been determined by photoionization.
    Notizen: L'étude par spectrométrie de masse du 1-méthylcyclopentène, du méthylèncyclopentane, du cyclohexéne, de l'hexyne-1 et de l'hexyne-2 nous a permis de mesurer les potentiels d'ionisation de ces substances ainsi que les potentiels d'apparition de leur principaux ions fragmentaires. Les chaleurs de formation de ces ions ont été calculées et les valeurs trouvées sont discutées. La structure de certains ions fragmentaires implique un réarrangement d'atomes d'hydrogène au moment de leur formation. Les potentiels d'ionisation adiabatiques du 1-méthylcyclopentène et du méthylènecyclopentane ont été déterminés par photoionisation.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 94
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 133-138 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: All the fluoro derivatives investigated exhibit strong molecular ions, which in many instances are also the base peaks. All the compounds with the exception of the p-acetyl derivative exhibit ions due to the loss of COCF3 and (CO + COCF3) from the molecular ion. Loss of CO from the molecular ion ranks as an important fragmentation except in cases where loss of a methyl group gives rise to ions which probably possess a tropylium structure. Alkyl ring substituted compounds exhibit intense hydrocarbon ions, which are also consistent with a tropylium structure.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 95
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The McLafferty rearrangements in the mass spectra of butyrophenone, l-phenyl-2-pentanone, l-phenyl-3-hexanone, 4-phenyl-4-methyl-2-pentanone, 2-butyronaphthone and 2-butyryl-anthracene are compared with photochemical Norrish Type II reactivity. As a rule, the McLafferty process occurs in these compounds even when the Norrish Type II process does not; the simple analogy of production of similar reactivities by the removal of an electron (in the McLafferty rearrangement) and the promotion of an electron to a non-interacting orbital (in the Norrish Type II process) should thereforebe viewed as complicated by the intervention of electronically excited molecular ions in which the McLafferty process can occur.
    Zusätzliches Material: 5 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 96
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 211-214 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Comparisons of the mass spectral behaviour of the [M - 42] ions from enol acetates and that of the corresponding ketones indicate that the elimination of a ketene molecule from enol acetates proceeded through a four-membered cyclic transition state to afford fragment ions with an enolic structure.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 97
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 237-240 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: This paper describes the mass spectra of some di-trimethylsilyl derivatives of aromatic amines. Numerous doubly-charged ions of low relative intensity are found in all spectra. An intense doubly-charged ion is found at m/e [M - 30]/2, whereas the singly-charged counterpart is very small in all cases.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 98
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 41-53 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of several 4,5-disubstituted-2-oxazolidones and several related N-methyl derivatives have been determined. Fragmentation has been found to be a function of three factors: (1) the size of the alkyl function at C-5, (2) the location of the aryl substituent, and (3) replacement of N—H by N—CH3. In particular, aryl or bulky alkyl groups substituted at C-5 result in protonated aldehyde derived from hydrogen rearrangement from nitrogen. With other substituents, the most intense ions are nitrogen containing fragments. In the latter case the fragmentation pathway has been elucidated with the aid of metastable peaks observed using defocusing techniques.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 99
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of some alkyl thioureas, alkyl-aryl and aryl thioureas are presented and discussed. The main primary fragmentation pathways are cleavage next to the central carbon atom, with the charge residing on either fragment, and the loss of sulphydryl or substituted sulphydryl radicals. The differences in behaviour of the methyl ureas and thioureas are discussed on the basis of a preferred charge location on sulphur in the thioureas but on nitrogen in the ureas. Also, where appropriate, the spectra of all the alkyl compounds are compared with those of the alkyl guanidines. The effect of chain length of alkyl groups and of charge location on the fragmentation pattern is discussed using the spectra of the ethyl and butyl thioureas and the ethyl ureas. The sensitivity of alkyl thioureas to pyrolysis is noted and the sensitivity of phenyl substituted thioureas to pyrolysis confirmed.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 100
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: The influence of source temperature on the mass spectra of eight ketones with the formula CH3—CO—CnH2n+1(n = 3,4,5)have been studied. By a simple treatment we have determined: (1)the approximative amplitude of the activation energies (we have observed the activation energies in the increasing order: the fragmentation leading to the ion [M - CH3], the McLafferty rearrangement and the α cleavage giving the ion [M - CnH2n+1]); (2) the ions giving raise to important secondary decompositions (in particular), the [M - CH3] ions coming from the α cleavage; (3) the fragmentations having a low activation energy and a low frequency factor (mainly the ions [M - CH3] which are issued from the γ and δ cleavages); (4) the influence of the effective number of oscillators on the fragmentation process.
    Notizen: Nous avons étudié l'influence de la température de source sur le spectre de masse de huit cétones de formules CH3—CO—CnH2n+1 (n = 3,4,5). L'utilisation d'un traitement simple nous a permis de mettre en évidence: (1)l' ordre de grandeur des énergies d'activation (ainsi, par ordre d'énergie croissante nous avons la rupture en α, conduisant à l'ion [M - CH3], le réarrangement de McLafferty et la rupture en α donnant l'ion [M - CnH2n+1]); (2) les ions donnant lieu à des décompositions secondaires importantes (notamment les ions) [M - CH3] issus de la rupture en α; (3) les ruptures avant une énergie d'activation et un facteur de fréquence faibles (essentiellement les ions [M - CH3] issus des ruptures en γ ou δ); (4) l'incidence du nombre d'oscillateurs effectifs sur le processus de fragmentation.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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