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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Epitaxial thin films of YBaCuO have been prepared with (1) the a axis perpendicular to (100) SrTiO3 ; (2) the c axis perpendicular to (100) SrTiO3 ; and (3) the [110] axis perpendicular to (110) SrTiO3. Films were fabricated using a multilayer deposition technique involving three electron guns containing Y, BaF2, and Cu under a pressure of 5×10−5 Torr of O2. As deposited films, which contained polycrystalline and amorphous regions, were later annealed in a furnace under a flowing O2-H2 O atmosphere. X-ray diffraction patterns as well as scanning electron microscopy and high-resolution electron microscopy images confirm that the films are highly oriented, essentially epitaxial. The a-axis oriented film exhibits zero resistance at 90 K and a critical current density of 2.9×106 A/cm2 at 4.2 K while the c-axis oriented film exhibits a Tc of 88 K and a Jc of 0.9×107 A/cm2 at 4.2K; the Jc values were determined magnetically. The [110]-orientation film shows the sharpest transition with a transition width of 1 K and zero resistance at 85 K.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 66 (1995), S. 2795-2797 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The spatial distribution of Mg solute in polycrystalline, single-phase Al2O3 has been obtained, using a secondary ion imaging technique. Segregation of Mg to the Al2O3 grain boundaries is clearly observed—strong evidence that the principal role of MgO is to reduce the grain boundary mobility via a solute-drag mechanism. In addition, Mg (dopant) and Ca (impurity) are shown to cosegregate, shedding further light on magnesium's ability to stabilize microstructural evolution in Al2O3. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-4889
    Keywords: aluminum-lithium alloys ; oxidation ; oxide nucleation ; lateral oxide growth ; secondary ion mass spectrometry ; scanning ion microprobe
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The high-temperature oxidation behavior of binary Al-Li alloys has been characterized by scanning electron microscopy and secondary ion mass spectrometry in order to understand the mechanism of rapid oxidation in these alloys and to correlate the oxide morphology to its microchemistry. The oxide scale developed on polished specimens during short exposures in air at 530°C shows characteristic nodules that usually nucleate at grain boundaries. Examination of the alloy surface after removal of the oxide layer shows that the initial growth of the oxide nodules occurs laterally in addition to thickening normal to the oxide/alloy interface. Microchemical analysis of the oxide film with a scanning ion microprobe reveals a thick Li-oxide layer at the oxide/gas interface indicating preferential oxidation of Li at the free surface; the rest of the oxide film is composed of both Al- and Li-rich oxides, probably Li2O and LiAlO2 The presence of trace impurities (K, Na, F, and Cl) in the oxide scale was also detected. A microstructural model for the development of the oxide film in the Al-Li system is presented on the basis of both morphological and microanalytical data obtained in this study; this new model is compared with existing models.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 37 (1992), S. 23-37 
    ISSN: 1573-4889
    Keywords: aluminum-lithium alloys ; oxidation ; second-phase particles ; secondary ion mass spectrometry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Oxidation behavior of Al-Li alloys, containing a high volume fraction of Ferich second-phase particles, was studied at 530°C and 200°C. Morphological studies showed enhanced growth of Li-rich oxides in the vicinity of the insoluble second-phase particles. Microanalytical depth profiling of the oxide layer with a high resolution scanning ion microprobe indicated rapid diffusion and subsequent oxidation of Li at the free surface. Examination of the alloy surface after removal of the oxide layer suggested that the initial oxide growth occurred in the lateral direction. Secondary ion image depth profiling of the alloy surface after oxide removal revealed Li segregation to the alloy/second-phase interface, supplying Li for accelerated oxidation. A microstructural model of the oxidation process in this case is presented.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract An Al–Si–Cu–Mg alloy reinforced with alumina/silica fibres (Fiberfrax®, alumina/silica ratio=45/55) has been extensively characterized in terms of microstructure, interfacial chemical reactions and mechanical properties. The composite was fabricated by squeeze casting. The above characteristics were measured as a function of (a) calcination temperature of the fibre preform before infiltration, and (b) subsequent composite heat treatment. The main reaction that occurs during the processing of aluminium alloy matrix composites is the reduction of silica in the binder and fibres by magnesium from the matrix. When calcined below 1000°C, the fibres remain amorphous with a coating of porous silica binder. In this condition, the reinforcement reacts strongly with the matrix during heat treatment of the composite. In contrast, at high calcination temperatures (1200°C), the fibres transform partially into mullite and the silica binder densifies; these fibres are somewhat less reactive with the matrix. In both cases, the matrix/reinforcement reactions are very strong during high-temperature heat treatment, leading to a complete reduction of silica in some cases. The degradation caused by chemical reactions adversely affects the mechanical properties of these composites. Therefore, in order to optimize the mechanical properties of this composite, the fibre preform first must be calcined at high temperature, then the composite heat treatment limited to low temperature.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 21 (1994), S. 117-122 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: This article discusses the application of a scanning ion microprobe coupled with secondary ion mass spectrometry (SIMS) in the microanalytical characterization of ceramic materials. The high spatial resolution afforded by the microprobe mode, in conjunction with the analytical sensitivity of SIMS, make this technique ideally suited to explore the microchemistry of ceramics, which have complex microstructures and contain several trace and light elements. Two case studies of interface analysis are presented: YBa2Cu3O7-x superconductors and sintered silicon carbide. Sodium and chlorine impurities were found to segregate to the grain boundaries of melt-grown YBa2Cu3O7-x, accompanied by oxygen deficiency. In SiC sintered with Al2O3, Al was present along the grain boundaries in elemental from and at triple-grain junctions as Al oxide second phases.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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