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  • 1960-1964  (797)
  • 1950-1954
  • 1963  (797)
  • Inorganic Chemistry  (758)
  • Biochemistry and Biotechnology  (39)
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Years
  • 1960-1964  (797)
  • 1950-1954
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 331-345 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: These experiments show that ABS can be adsorbed and desorbed from microbial cell surfaces. The adsorption equilibria between the free and adsorbed phases are primarily influenced by the pH of the system. The effects of ABS upon the biochemical activities of bacteria depended upon the amount of ABS adsorbed and the type of bacteria present. The behaviour of ABS is essentially the same whether in the presence of pure or mixed bacterial cultures. Two desorption experiments with soil from a reclaimed water spreading basin which has received sewage over a six month period showed that at least 82% of the ABS “loss” was recoverable from the soil. In all the experiments carried out in this study no evidence was obtained for the biochemical degradation of ABS.
    Additional Material: 15 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 347-354 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: With the emphasis being given to the development of biologically soft detergents, it is necessary to establish eriteria defining biodegradability of these materials. It is the authors' opinion that a biologically soft detergent should have the following characteristics: (1) Under normal operations the material should be 85% removable by activated sludge. (2) Normally high discharges of the detergent should not influence biological activity. (3) The detergent should ultimately degrade to carbon dioxide and water.
    Additional Material: 6 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 367-384 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Because branched-chain alkyl benzene sulfonate (ABS) is well known to create water pollution problems in surface water and ground water, a study was made on the biodegradation of this surfactant along with other anionic and nonionic surfactants in detergents by water bacteria. Biodegradation was evaluated by the conventional river die-away test employing the methylene-blue method or surface-tension techniques as analytical tools. Under anaerobic conditions, sugar detergents (sucrose esters) seem to be an ultimate solution to water problems created by branched-chain ABS; in aerated water, straight-chain ABS, sulfo tallow methyl esters, and nonionic surfactants are preferable to branched-chain ABS to improve water problems.
    Additional Material: 10 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 83-85 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The inclusion of ethionine in Streptomyces rimosus fermentation resulted in the production of N-methylethyloxytetracycline. The compound has been isolated, crystallized, and a number of its chemical properties determined.
    Additional Material: 1 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 101-107 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An adsorption colorimetric method is proposed for the determination of the percentage of dead cells in suspensions of Penicillium chrysogenum, based on the observed fact that a linear relation exists between that percentage and the dye concentration at the equilibrium point.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 167-184 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Shock pressure waves with a frequency of 50/sec. and a maximal pressure of 60-70 kg./cm.2 greatly reduced the viability of E. coli. A similar effect was obtained also on staphylococci, enterococci, Salmonella Zanzibar, and coliphages T2. On the contrary no effect on spores of B. subtilis was found. The effect was practically independent of the maximal pressure within the range from 30-80 kg./cm.2, the highest pressure tested. The effect decreased with increasing cell density of the bacterial suspension. Bacteria surviving shock treatment died considerably more rapidly when stored at 4°C. than bacteria treated in the same way except for exposure to pressure waves. Morphological examinations with the aid of ordinary light microscopy as well as electron microscopy suggest that the effect was due to mechanical action on the bacterial cell walls.
    Additional Material: 10 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963) 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 287-307 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Sphaerotilus is usually present in biological waste treatment processes and is considered to be a nuisance organism because it may cause bulking of activated sludge. However, it may play an important role in the decomposition of putrescible organic matter in properly operated biological waste treatment processes. The research described herein is a study of the variety of types of organic compounds which may be decomposed by Sphaerotilus and the effect of some environmental factors upon the rate of decomposition. Although there are some types of compounds which cannot be decomposed by Sphaerotilus, it is shown that this organism is able to assimilate and oxidize a large variety of organic compounds and that it is tolerant of an extremely wide range of environmental conditions. The role of Sphaerotilus in biological waste treatment is discussed in the light of the data presented.
    Additional Material: 9 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 355-365 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It has been found that a bacterium (isolant C12B) grew poorly on 6 and 8 carbon alcohols, well on 10 and 12 carbon alcohols, and slowly but well on the 14 to 18 carbon compounds. Unexpectedly, resting cells oxidized the 6 and 8 carbon compounds most readily and cell-free extracts oxidized 6, 8, and 10 carbon alcohols. Extracts from cells adapted to sodium lauryl sulfate oxidized the 12 carbon alcohol as well, if small concentrations of substrate were used. The bacterium grew on benzene sulfonate and adapted resting cells oxidized that compound. Pure culture degradation studies revealed that isolant C12B used only 11% of tetrapropylene ABS supplied as a sole carbon source, whereas 66% of sodium lauryl sulfate was degraded. Intermediate quantities of kerosene-based alkyl benzene sulfonate and a tallow-derived detergent were utilized. Extracts of another bacterium, TEG-5, grown on tetraethylene glycol, contained enzymes which oxidized polyethylene glycols up to an average molecular weight of 600, but not any larger polymers. This oxidation was visualized by coupling to reduction of ferricyanide.
    Additional Material: 9 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 201-209 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is a well-known fact that choosing a sequence of optimal control variables in each reactor tank of a multistage reactor system can result in a considerable increase of the desired product for a consecutive reaction system. The discrete maximum principle is applied to a generalized optimization problem of first order consecutive biochemical reaction system. A detailed numerical solution as an example is also presented for illustration.
    Additional Material: 1 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 193-199 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ferrocyanide-treated beet molasses was fermented in fully baffled mechanically agitated, 2.5-liter, tank-type fermenters using pellets of Aspergillus niger grown in shake flasks as an inoculum. The object of the study was to adapt the fermentation method previously developed in an unstirred tower-type fermenter to a conventional tank-type fermenter. Under selected conditions of stirring (agitator speed 400-700 rpm) and sparging (medium porosity sintered disk), high yields of citric acid (8.6% citric acid, 70% conversion of available sugar) were obtained in 140 hr. of fermentation. There was little relation between citric acid yield and aeration conditions in the fermenter as judged by mash viscosity measurements and sulfite oxidation studies.
    Additional Material: 3 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963) 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
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  • 13
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A 50-gal. growth chamber is described together with its air filter and humidifier. The unit was designed especially for the production of Neurospora crassa, and was found to be effective in producing bulk amounts of mycelia with a high specific activity of tryptophan synthetase.
    Additional Material: 3 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 87-89 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Addition of the S-2-hydroxyethyl-, S-2-chloroethyl-, S-n-propyl-, and S-iso-propyl-derivatives of homocysteine, and methoxinine to S. aureofaciens (ATCC 13900) fermentations resulted in production of 7-chloro-6-demethyltetracycline in addition to the normally synthesized 7-chlortetracycline.
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  • 15
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 123-129 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of inoculating nutrient surfaces uniformly with bacterial cells has been developed. The method is based on controlled exposure of samples in a humidified chamber to a spray produced from a bacterial suspension. Factors affecting uniformity of inoculation (ionic strength of suspension, force of spray, distance between spray nozzle and sample, and exposure time) were studied in detail. Under optimum condition using agar medium in Petri plates, differences between total counts for six plates inoculated simultaneously, or between counts for individual 2 cm.2 areas taken at any location on any of the plates, were not statistically significant at the 5% level. The coefficient of variability for counts on 2 cm.2 areas renged from 8 to 12% between tests of 216 counts each.
    Additional Material: 3 Ill.
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  • 16
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963) 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 185-192 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By growing Aspergillus parasiticus (C.M.I. 15957) under controlled conditions on sterilized peanuts an average of 265 mg. of aflatoxin per kilogram of peanuts has been produced and subsequently isolated. Other strains from the A. flavus-oryzae group gave lower yields of aflatoxin and one such strain gave aflatoxin from which certain normal components were absent. The aflatoxin produced on sterilized peanuts by any particular strain of A. flavus-oryzae was shown by thin-layer chromatography to contain the same major components as were produced by that strain on unsterilized whole peanuts.
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  • 18
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 9-15 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method by which a paramagnetic oxygen analyzer is used to determine oxygen consumption and carbon dioxide production during aerobic fermentation of Torulopsis utilis is described. The volume of carbon dioxide produced is not necessarily related to the volume of oxygen consumed by the microorganisms. For this reason, all carbon dioxide is removed from the effluent gas before it enters the analyzer when determining oxygen consumption. A method for calibrating the analyzer to correct for this removal is outlined. When determining carbon dioxide, effluent gas bypasses the carbon dioxide absorption tower before entering the analyzer. The carbon dioxide which it contains dilutes the oxygen remaining in the gas. The magnitude of this dilution can be used to calculate the percentage of carbon dioxide produced in terms of the air flow to the fermentor. Equipment required to alternately measure and record oxygen consumption and carbon dioxide production is described.
    Additional Material: 4 Ill.
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  • 19
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 21-25 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Cobamide production by Butyribacterium rettgeri Barker and Haas (ATCC 10825) was studied on a laboratory scale. Yields of the order of 5 μg./ml. were obtained when this anaerobe was grown for 6 days at 37°C. in a medium containing glucose, cornsteep liquor, cobalt nitrate, calcium carbonate, and sufficient ammonium hydroxide to keep the pH between 6.0 and 7.2. All of the vitamin was found associated with the bacterial cells, and examination of extracts of these cells showed the presence of 5,6-dimethylbenzimidazolylcobamide coenzyme in large quantities. Supplementation of the fermentation medium with a number of benzimidazoles resulted in formation of traces of “new” cobamides with these bases in the nucleotide protion of the cobamide. Supplementation with a number of purines did not result in incorporation of these moieties in the cobamide portion of the molecule.
    Additional Material: 1 Ill.
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  • 20
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Removal of the pungent factor, allyl isothiocyanate, will partly determine whether mustard seed can become a commerical source for oil and meal in the United States. In processing studies at the Northern Laboratory, the mustard glucoside was converted enzymatically and the pungent oil was removed. This process has now been extended to pilot-plant scale by using filtration-extraction equipment at the Southern Laboratory. After desolventization and further steam stripping, the extracted meal had a residual content of 2.9% crude fat and 0.004% allyl isothiocyanate.
    Additional Material: 5 Ill.
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  • 21
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 17-20 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The applicability of physicochemical adsorption laws to the sorption of methylene blue by dead Penicillium chrysogenum was studied. The specific area (area/mass) of the mold was measured.
    Additional Material: 2 Ill.
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  • 22
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 147-165 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A number of factors was found to affect the cup plate assay for lysine with Streptococcus faecalis ATCC 6057. Hydroxylysine, aspartic acid, and Tween 80 were found to be among the essential components of the assay medium. Removal of any of these three components produced diffuse growth zones or otherwise unsatisfactory plates. The inclusion of asparagine and additional dipotassium phosphate to the medium was found to be advantageous but not an absolute requirement. It was important not to autoclave the hydroxylysine and the additional dipotassium phosphate together with the rest of the assay medium, but to add these components to the sterilized medium immediately before pouring the plates. With certain concentrations of hydroxylysine in the medium, the addition of L-glutamine was found to potentiate the effect of hydroxylysine and thereby improve the lysine plates. The effect of graded amounts of the above mentioned medium components and of the pH of the assay medium was also studied. Increasing the sterilization time of the medium from 5 to 10 min. at 120°C. improved the readability of the lysine plates and led to more easily reproducible results. Factors influencing the preparation of the inoculum for the lysine plates were also studied: the age of the stab culture, the amount of inoculum used per plate, and the influence of the nature of the suspension medium used for washing the inoculum.
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  • 23
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 211-220 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A disposable plastic tetrahedron bag is described which is suitable for holding a 50 ml. culture on a shaker table. Bags can be made out of polypropylene or Teflon and they are quite simple and inexpensive. The tetrahedrons make excellent use of the shaker table space and they give a threefold increase in aeration efficiency over Erlenmeyer flasks.
    Additional Material: 4 Ill.
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  • 24
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 243-251 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The metabolic pathway of degradation of naphthalene to salicylic acid has been studied by several investigators. The rates of conversion and of cell growth are the basis for the present study. In the early phase of the fermentation, the salicylic acid accumulation followed an exponential curve, as did the bacterial cell accumulation. In the second phase, most of the salicylic acid was produced according to a linear or zero reaction, at rates of 0.3 to 0.5 g./l./hr. A linear accumulation of microbial cell weight accompanied the linear salicylic acid formation. Despite the correlation of growth and salicylic acid production, the type or amount of nitrogen supplied for growth had only a small effect on yield over broad limits. The optimum pH for salicylic acid accumulation was approximately 6.5. Below this value a slower rate of production and lower final yield was seen. Above pH 6.5, a rapid degradation of salicylic acid was observed. A temperature range from 25 to 30°C. was optimum. At 35°C., no growth occurred, while at 20°C. very slow salicylic acid accumulation resulted.
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  • 25
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 255-273 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Stabilization ponds have been widely accepted in recent years, following studies that established deeper understanding of the phenomena associated with the stabilization process. A compilation of information on the use of both sewage and industrial ponds is presented showing types and geographical location in the United States. A total of 1,304 stabilization ponds currently are used as the principal method of sewage treatment serving a population of 2,138,085. Ponds are used for tertiary treatment serving a population of 2,146,951, in 343 instances. Use of 827 industrial ponds by 31 industries in 44 States is also indicated. Indiana ranks first in usage with 159 ponds and Callfornia second with 140. Ponds were classed as effective by 66 percent of the 455 users who reported on this item. Of 149 reports on odors, 73% indicated nuisances. Insect problems were reported in only a small number of instances. Data are presented on design considerations and the mechanism of waste stabilization ponds. Aerobic ponds are given greatest emphasis. Photosynthesis and its dependence upon the algal mass, suitable temperature, incident light penetration, nutrient supply, and induced vertical mixing by wind are of prime importance in the stabilization mechanism. Odors are associated with prolonged anaerobic conditions, and these may persist up to 4 weeks following extended ice cover in cold climates, if BOD loadings are 25 lbs. per acre per day or greater. Nitrogen and carbon may be limiting factors in the development of an algal mass. Coliform, BOD, and nutrient removals are presented for various physical, chemical, and climatic conditions. Although fecal streptococci removal averaged 97% in a study pond, they were still discharged in the effluent at a rate of 700,000 per second in winter and 70,000 per second in summer. A striking similarity exists generally among the algal speciation in stabilization ponds, regardless of geographic location. The algal mass is, however, dependent upon unique pond conditions and location, and may vary upwards to nearly 5 million algal cells per milliliter, 34,000 p.p.m. by volume, or 30-35 tons per acre per year. The problem of blue-green algal mats and resultant pigpen odors in extremely localized areas is duscussed. Midges and midge larvae may have an impact on the nutrient cycle in a stabilization pond, and may pose a potential localized nuisance in some areas. Mosquito problems have usually been associated with growth of aquatic vegetation. Suggestions for minimizing the potential problem are discussed.
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  • 26
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963) 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
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  • 27
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 131-146 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A sensitive cup plate assay method for lysine on large plates using S. faecalis ATCC 6057 as the test organism is described in detail. Well-defined zones of dense growth were obtained in a rectilinear dose - response range from 5 to 3000 μg. of L-lysine/ml. Comparative assays on twelve different samples were carried out using the turbidimetric tube assay method with Leuc. mesenteroides ATCC 8042 and the cup plate method with S. faecalis ATCC 6057. Good agreement between the two assay methods was obtained for five samples. For the remaining seven samples the tube assay values were appreciably higher than those obtained by the plate method. This discrepancy is discussed. Pure lysine added to various sample extracts could be quantitatively recovered. The specificity of the lysine requirement of S. faecalis ATCC 6057 in the plate assay was also investigated. Under certain experimental conditions, a weak and variable response was obtained with D-lysine and the polyamines cadaverine, spermine, and spermidine. There was generally no difficulty in distinguishing the D-lysine and polyamine growth zones from the L-lysine growth zones. This growth effect of D-lysine and polyamines could be diminished and even completely abolished by increasing the DL-hydroxylysine hydrochloride level in the plate medium. The lysine peptides glycyl-L-lysine and L-lysylglycine gave excellent growth zones of the same appearance as those produced by L-lysine. The activity of these two peptides in cup tests were on a molar basis about 70% of that of L-lysine.
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  • 28
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 221-230 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A process has been developed giving over-all yields of about 50%: which could be increased to about 80% with higher material costs and processing time. The preferred method of recovering nucleotides from the cytoplasm has been thermal extraction by means of a heat exchanger followed by filtration, protein precipitation, and carbon adsorption. The concentrated eluate from the carbon is absorbed onto Dowex 1 ion-exchange resin, and groups of nucleotides are removed by pH-defined eluents and recovered by a second carbon adsorption. Finally, standard ion-exchange resolutions have been used to recover individual nucleotides. Other biochemicals in the extract have been investigated, and preliminary work has been done on the combination of nucleotide extraction with the recovery of nucleic acids from the residual cells.
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  • 29
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 231-242 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the present paper the authors described laboratory fermentors used in the Antibiotics Research Institute since 1958 for research concerning the technology of the biosynthesis of antibiotics and amino acids and other aerobic fermentations. The lids of the fermentors are made from stainless steel, the vessels are made from glass. The fermentors are placed, always four each, in eight water baths with automatic temperature regulation within a range of ±0.5°C. Details regarding construction, auxiliary equipment, and working procedures used for the sterilization of fermentors and media, inoculation, injection of additives, and defoaming are given. The set-up for one-stage and multi-stage, batch and continuous cultivation are discussed.
    Additional Material: 5 Ill.
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  • 30
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 275-285 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Phenol-bearing waste waters continue to be an area of wide concern for various industries faced with the task of cleaning up effluents containing relatively small amounts of these materials. The microbiological aspects of the degradation of these materials in pure culture and waste treatment plants is reviewed. Actual operating experiences at three plants of The Dow Chemical Company, where phenols are present in combination with other widely varying waste constituents, are discussed.
    Additional Material: 6 Ill.
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  • 31
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 49-52 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An investigation was made of the stability of product limited continuous cultures of Saccharomyces carlsbergensis and Pseudomonas ovalis. No oscillations were found in pH or glucose concentration during the steady state, and no overshoot resulted from changing from one steady state to another.
    Additional Material: 2 Ill.
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  • 32
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 53-58 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The design of a cabinet for the aseptic manipulation of material is described. The interior surfaces of the cabinet are sterilized by swabbing with a germicide. Germ-free conditions are maintained during operation by means of a positive pressure of sterile air. A fan and filter unit attached to the cabinet is used to blow sterile air into the cabinet in sufficient quantity so as to flow out of the hand ports at a velocity of 50 ft./min. In the design, careful consideration was given to the ease of manipulations in the cabinet.
    Additional Material: 1 Ill.
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  • 33
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 91-99 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microbial polysaccharides which have many potential industrial applications are receiving more and more attention. One of the economic obstacles to the commercialization of these polysaccharides has been the cost of isolating them from fermented broth. To reduce this cost a recycling process was developed. The polyanionic polysaccharide synthesized from glucose by the activity of the bacterium Xanthomonas campestris NRRL B-1459 is precipitated from the fermented broth with a quaternary ammonium compound (QAC).QAC is removed from the precipitate with methanol leaving the water-soluble polysaccharide. Evaporation of the methanol wash removed the methanol and substantially all the QAC was recovered in the concentrate. This was recycled for subsequent precipitations. Chemical assay and the viscosity of water solutions of the isolated polysaccharide indicate no adverse effects on it from recycled QAC. The cost to make this polysaccharide by the described procedure is estimated to be $1.14/lb. This cost estimate includes land, buildings, raw materials, equipment, labor and supervision, utilities, factory supplies, working capital, and plant overhead.
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  • 34
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 109-121 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microbiological production of beta-carotene previously investigated in shakenflask culture has been scaled-up to 20-liter fermentors containing an operating volume of 10-liters. Yields obtained in shaken flasks, approximately 100 mg./100 ml. have been reproduced with a fermentation time of 72 hr. Factors affecting the fermentation: inoculum, mash ingredients, and environmental conditions, were investigated. Typical data are presented. A preliminary cost analysis indicates a “cost to make” of $31.35/kg. of carotene contained in the dried fermentation solids.
    Additional Material: 12 Ill.
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  • 35
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
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  • 36
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    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 309-330 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Biological purification of water pollutants depends upon a complex balance of organisms and environment conducive to effective metabolism. The bench scale test is useful to determine effects of a given waste water on that balance and to suggest controls promoting optimum purification. Applicability of laboratory results depends, in part, upon an experimental design similating anticipated operating conditions. This paper discusses advantages and limitations of historical bench-tests as a guide for design of tests giving data that are more useful during full-scale operation.
    Additional Material: 5 Tab.
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  • 37
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    Biotechnology and Bioengineering 5 (1963), S. 41-48 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bacillus subtilis NRRL B-2612, isolated at this laboratory, was used to produce polyglutamic acid from devitalized wheat gluten. Conditions for production of the polypeptide were investigated. When NRRL B-2612 was grown on wheat gluten in shaken flasks with phsophate buffer and salts at pH 6.5, yields of polymer reflected a 25-40% incorporation of glutamic acid into polyglutamic acid. Repeated alcoholic precipitation yielded peptides containing between 45 and 90% D-glutamic acid. Physical and chemical properties of a typical purified polyglutamic acid indicated that the product was a gamma-linked polypeptide composed of 75% D-glutamic acid and 25% L-glutamic acid with a molecular weight of approximately 200,000.
    Additional Material: 3 Ill.
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  • 38
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    Biotechnology and Bioengineering 5 (1963), S. 59-74 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The distribution of dissolved oxygen in agitated, sparger-aerated aqueous solutions has been investigated by polarographic techniques. The results of the investigations are discussed in relation to earlier studies in bubble distribution in such systems. Liquid-phase mixing is good at agitation intensities well below that necessary to disperse bubbles throughout the liquid.Suspended solids interfere with the transfer of oxygen unless they are freely suspended. Discrete fibers (paper-pulp) are much easier to suspend than molds in either filamentous or pellet forms. Mass-transfer at the cell-liquid interface appears to be unaffected, in both bacterial and mold suspensions, by the intensity of agitation, provided that the organisms are freely suspended.
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  • 39
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    Biotechnology and Bioengineering 5 (1963), S. 1-7 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A cost analysis of the continuous fermentation of penicillin G shows that materials cost and product yields are more significant than throughput rate. Number of fermentation stages, productivity, and the implications for research and development are discussed.
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  • 40
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    Zeitschrift für anorganische Chemie 319 (1963), S. 230-235 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The preparation and isolation of tetramethyl titanium is described. Ti(CH3)4 forms bright yellow crystals which are very sensitive to air and moisture and undergo thermal decomposition at temperatures above approximately -78°C forming metallic titanium.
    Notes: Die Darstellung und Isolierung von Tetramethyltitan wird beschrieben. Ti(CH3)4 bildet glänzende gelbe Kristalle, die sehr luft- und feuchtigkeitsempfindlich sind und sich bei Temperaturen oberhalb von etwa -78°C unter Abscheidung von metallischem Titan thermisch zersetzen.
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  • 41
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    Zeitschrift für anorganische Chemie 319 (1963), S. 236-243 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: By the reaction of hydrogen cyanide with niobium pentachloride under various conditions, specially in the presence of organic solvents, the compounds NbCl4CN · (C2H5)2O, H(NbCl5CN) and H(NbBr5CN) are prepared. H(NbCl5CN) has the constitution of an acid and forms a salt with triethyl amine, the solution of this salt in organic solvents having electrolytic character.
    Notes: Durch Einwirkung von Cyanwasserstoff auf Niobpentachlorid oder Niobpentabromid unter verschiedenen Bedingungen, insbesondere in Gegenwart organischer Lösungsmittel, wurden die Verbindungen NbCl4CN · (C2H5)2O, H(NbCl5CN) und H(NbBr5CN) dargestellt. H(NbCl5CN) ist eine Säure und vermag mit Triäthylamin ein Salz zu bilden, dessen Lösungen in organischen Solvenzien Elektrolytcharakter besitzen.
    Additional Material: 4 Ill.
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  • 42
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: According to the nucleophilic character of lower-valent phosphorus atoms, diphosphorus tetraiodide reacts readily with oxygen even under mild conditions, the oxygen uptake of CS2 solutions amounting from 0.6 to 1.0 mole per mole P2I4. In the reaction a new polymeric phosphorus oxide iodide of the average composition (P3I2O6)n (containing about 40 per cent of the reactant phosphorus) and PI3 (about 60 per cent of P) are formed. The oxidation approximately follows the equation: .The new phosphorus oxide iodide is amorphous by X-ray examination, insoluble in indifferent solvents, and undergoes a strongly exothermic hydrolysis yielding HI, H4P2O6, H3PO4, and H3PO3 in addition to smaller quantities of H4P2O5 and PH3, during which elementary iodine occurs as an intermediate. The IR spectrum is remarkably similar to that of P4O10 and  -  agreeable to the chemical behavior  -  supports the assumption of the group as preferred structure element. Polymerization of this group should predominantly bring about longer chains, besides possibly smaller cyclic aggregates which are mainly linked with each other by P—P bonds distributed not quite regularly within the polymer.
    Notes: Das Diphosphor-tetrajodid reagiert entsprechend dem nucleophilen Charakter der Phosphoratome bereits unter milden Bedingungen lebhaft mit Sauerstoff. Dabei werden in CS2-Lösung bei 20°C etwa 0,6 bis 1,0 Mol O2 pro Mol P2J4 aufgenommen und als Reaktionsprodukte ein neues polymeres Phosphor-oxid-jodid der mittleren Zusammensetzung (P3J2O6)n (etwa 40% des eingesetzten Phosphors) und außerdem PJ3 (etwa 60%) gebildet. Die Umsetzung verläft angenähert nach der Gleichung: .Das Phosphor-oxid-jodid ist röntgenamorph, in indifferenten Solvenzien unlöslich und hydrolysiert in stark exothermer Reaktion zu HJ, H4P2O6, H3PO4, H3PO3 sowie etwas H4P2O5 und PH3, wobei intermediär elementares Jod gebildet wird. Das IR-Spektrum zeigt beträchtliche Ähnlichkeit mit dem des P4O10 und läßt  -  in Übereinstimmung mit dem chemischen Verhalten  -  als bevorzugtes Strukturelement der polymeren Substanz die Gruppierung annehmen. Diese dürfte vor allem zu größeren kettenförmigen, daneben eventuell auch zu kleineren ringförmigen Aggregaten polymerisieren, die vorwiegend über P—P-Bindungen in nicht ganz regelmäßiger Verteilung verknüpft sind. Das zu erwartende Primärprodukt P2J4O2 ist offenbar wegen der unterschiedlichen Elektronegativität der Substituenten am Phosphor instabil und daher nicht nachweisbar.
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  • 43
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    Zeitschrift für anorganische Chemie 319 (1963), S. 244-252 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A favourable process for synthesizing alkoxy disilazanes, [(RO)3Si]2NH, is based on the direct introduction of NH3 into a reaction mixture consisting of SiCl4 and the respective alcohols, followed by distillation of the reaction products (tetraalkoxy silanes, hexaalkoxy disilazanes, alkoxy poly- and cyclosilazanes) from the reaction vessel. This method is applicable to SiCl4, RSiCl3, RR′SiCl2 (R, R′ = CH3; CH2CH) as well as to alcohols containing the groups —CH2OH; 〉CHOH; —CH = CH—CH2OH. There is no difficulty to prepare kg-quantities in 30% to 50% yields.New disilazanes are described.
    Notes: Alkoxydisilazane lassen sich am günstigsten in einer Eintopfreaktion darstellen, indem man direkt in das Reaktionsgemisch aus Alkoholen und Siliciumtetrachlorid Ammoniak einleitet und die in ihren Siedepunkten weit auseinanderliegenden Produkte  -  Tetraalkoxysilane, Hexaalkoxydisilazane und Alkoxypoly- sowie Alkoxycyclosilazane  -  destilliert. Das Verfahren ist anwendbar bei primären, sekundären, substituierten und ungesättigten Alkoholen einerseits und Siliciumtetrachlorid, Mono- und Diorganochlorsilanen andererseits. Die Ausbeuten betragen 30-50%; es lassen sich ohne Schwierigkeit kg-Mengen an Disilazanen erzeugen. Die neu dargestellten Verbindungen sind mit ihren physikalischen Daten aus Tab. 3 zu ersehen.
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  • 44
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    Zeitschrift für anorganische Chemie 319 (1963), S. 337-349 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Experiments are described to prepare pure S2O by reaction of gaseous sulfur with sulfur monoxide. It was possible to obtain a gaseous mixture with a molar composition of S:O = 1.6:1 corresponding to a S2O content of 85%. Repeating experiments of Kondratjewa and Kondratjew it was not possible to reproduce their result, that the gaseous phase should have the composition S:O = 1:1 if SO2 is subtracted.It is found that monomeric SO is a short-lived very reactive molecule which can react according to 3 SO = S2O + SO2 or with gaseous sulfur according to 2 SO + S2 = S2O.
    Notes: Es wird über Versuche zur Reindarstellung des S2O durch Umsetzung von Schwefeldampf mit Schwefelmonoxid berichtet. Es gelang ein Gasgemisch mit einer molaren Zusammensetzung von S:O = 1,6:1 entsprechend einem Gehalt von 85% S2O zu erhalten. Versuche von Kondratjewa und Kondratjew, nach denen die neben SO2 in der Gasphase vorliegende Substanz die molare Zusammensetzung S:O = 1:1 haben soll, konnten nicht reproduziert werden. Das monomere SO erweist sich als kurzlebige sehr reaktionsfähige Molekel, die entweder nach 3 SO = S2O + SO2 oder mit Schwefeldampf nach 2 SO + S2 = 2 S2O reagieren kann.
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  • 45
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 320 (1963) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 46
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    Zeitschrift für anorganische Chemie 320 (1963), S. 261-266 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Spectrophotometrische Untersuchungen zeigten die Anwesenheit von Mono- und Di-semicarbazid-Kupferkomplexen. Die beiden Chlorid-Komplexe wurden isoliert, ebenso das Di-semicarbazid-nitrat und die Chlorid- und Sulfat-Komplexe mit Acetonsemicarbazon.
    Notes: Spectrophotometric studies of the complexes of copper with semicarbazide salts revealed the presence of mono- and di-semicarbazide complexes which were isolated in the case of the chloride. The di-semicarbazide nitrate was also isolated as well as the copper acetone semicarbazone chloride and sulphate.
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  • 47
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    Zeitschrift für anorganische Chemie 320 (1963), S. 274-282 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition metal polyamine-OH-complexes as [Fe(trien) (OH)2]+, [Co2(tren)2(OH)3]+ or [Ni2(tren)2(OH)3]+ show a catalytic influence on the decomposition of hydrogen peroxide. Bivalent ions of other transition metals such as Zn2+, Cd2+, Cu2+ and Fe2+ form similar compounds: [Zn2(tren)2(OH)2]2+, [Cd2(tren)2(OH)2]2+, [Fe2(tren)2(OH)3]+ and [Cut(ren)(OH)]+, also trien can be substituted for tren. Of these compounds, the complex of copper, [Cu(tren)(OH)]+, was found to catalyze the decomposition of H2O2.
    Notes: Übergangsmetall-Polyamin-OH-Komplexe wie [Fe(trien) (OH)2]+, [Co2(tren)2(OH)3]+ oder [Ni2(tren)2(OH)3]+ haben katalytische Eigenschaften trien = Triäthylentetramin tren = Tri-(2-aminoäthyl)-amin . Zweiwertige Ionen anderer Übergangsmetalle wie Zn2+, Cd2+, Cu2+ und Fe2+ bilden ähnliche Komplexe: [Zn2(tren)2(OH)2]2+, [Cd2(tren)2(OH)2]2+, [Fe2(tren)2(OH)3]+ und [Cu(tren) (OH)]+; an Stelle von tren kann auch trien stehen. Von den untersuchten Komplexen erweist sich die Verbindung des Kupfers, [Cu(tren) (OH)]+ als katalytisch wirksam bei der Zersetzung von Wasserstoffperoxid.
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  • 48
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 321 (1963) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 49
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    Zeitschrift für anorganische Chemie 321 (1963), S. 56-69 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die elektrische Leitfähigkeit der Lewis-Säuren SnCl4, TiCl4, TeCl4, AlCl3, SO3, FeCl3, SbCl5 und SbCl3 in Äthylacetat ist relativ groß und zeigt Solvatbildung an. Das große Dipolmoment beweist den ionogenen Aufbau dieser Solvate. Aus Leitfähigkeits- und Löslichkeitsuntersuchungen sowie aus konduktometrischen Titrationen geht hervor, daß hierbei das CH3CO+ und das OC2H5 -Ion eine Rolle spielen; das CH3COO-Ion tritt nicht auf.
    Notes: A study of the conductivity of the solutions of the Lewis acids SnCl4, TeCl4, TeCl4, AlCl3, SO3, FeCl3, SbCl5, and SbCl3 in ethyl acetate indicates a comparatively high conductivity of the solutions and the formation of compounds possessing high dipole moments. The existence of CH3CO+ is supported by the conductivity of various ansolvo acids. Absence of acetate ions is indicated by the insolubility of metal acetates and low conductivity of the acetates of tertiary bases. Although ethoxides are also insoluble, the existance of CH3CO+ and OC2H5 is supported by conductometric titrations.
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  • 50
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    Zeitschrift für anorganische Chemie 319 (1963), S. 209-210 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 51
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    Zeitschrift für anorganische Chemie 321 (1963), S. 180-183 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es wird über die Bildung und Zusammensetzung schwerlöslicher Verbindungen berichtet, die durch Reaktion von 1,2,3-Benzotriazolhydrochlorid mit Cyanokomplexen von Übergangsmetallen entstehen.
    Notes: The chemistry of the interaction of 1,2,3-benzotriazole hydrochloride and negative cyanocomplexes of certain transition metals is reported and discussed.
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  • 52
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    Zeitschrift für anorganische Chemie 321 (1963), S. 161-174 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The influence of the additions of aluminum on the crystallization of zink melts has been investigated. The systems zink-tin and tin-zink have been studied, in the former case the addition being surface active, while in the latter one surface inactive. The measurements of the dimensions of the crystal grains in the ingots indicate that in all cases investigated, in the presence of an addition, the grains become smaller. It is supposed that the addition being practically insoluble in the crystal phase forms a passivation layer on the surface on the grains decreasing further growth, thus making the formation of new grains more probable. The influence of the addition of aluminum on the recrystallization of zink has also been studied and found to be analogical.
    Notes: Es wird der Einfluß von Aluminiumzusätzen auf die Kristallisation von Zink aus der Schmelze untersucht, ferner die Systeme Zink-Zinn und Zinn-Zink. Im Falle Zn-Sn ist der Zuschlag oberflächenaktiv, im umgekehrten Falle inaktiv. Die Untersuchung der Größe der Kristallkörner in den Erstarrungsprodukten ergeben, daß in allen untersuchten Fällen durch den Zuschlag eine Kornverkleinerung eingetreten ist. Da das zugeschlagene Metall in der festen Phase des Hauptmetalls praktisch unlöslich ist, wird angenommen, daß das Zuschlagmetall eine passivierende Schicht auf der Oberfläche des Korns bildet, die das Wachstum behindert und die Wahrscheinlichkeit der Bildung neuer Kristallite erhöht. Der Einfluß eines Aluminiumzuschlages auf die Rekristallisation von Zink ist ebenfalls untersucht worden; hier liegen analoge Verhältnisse vor.
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  • 53
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Fe(CO)5 and Fe2(CO)9 react with liquid ammonia at 20°C forming NH4-carbonylferrates and urea (see equations (I) and (II) in „Inhaltsübersicht“); these reactions correspond with the hydrolysis of the two carbonyl compounds occuring with alkali hydroxide.Equation (V) is the over-all ammonolysis reaction of Fe3(CO)12 which is characterized by the intermediate formation of [Fe(NH3)6] [Fe3(CO)11] and Fe(CO)5 (equations (III) and (IV) above).
    Notes: Die Reaktionen von Fe(CO)5 und Fe2(CO)9 mit flüssigem NH3, die bei 20° gemäß verlaufen, werden durch Bestimmung der gebildeten Mengen von Carbonylferrat und Harnstoff quantitativ untersucht und mit den entsprechenden „Basenreaktionen“ der beiden Carbonyle mit Alkalilauge im Aquosystem verglichen.Im Falle des Fe3(CO)12 erfolgt zunächst Disproportionierung, wobei das freigesetzte CO gemäß weiter reagiert. Das hierbei entstehende Fe(CO)5 setzt sich dann in einer langsam verlaufenden Reaktion gemäß obiger Gleichung zu (NH4)2[Fe(CO)4] und CO(NH2)2 um, so daß sich der Gesamtverlauf der Umsetzung von Fe3(CO)12 mit flüssigem NH3 nach 14 Tagen durch die folgende Gesamtgleichung wiedergeben läßt: .
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  • 54
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 320 (1963), S. 43-53 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The number of surface silanol groups on “Aerosil”, an amorphous fine particle size silica, was determined by reaction with SOCl2. Their number decreases sharply between 250° and 350°C. After reaction with anhydrous AlCl3 and BCl3. the “Aerosil” was analyzed for Al or B and Cl. The results show, that free, strongly adsorbed water is bound to the surface even after high vacuum heat treatment. From 100° to 350°C, there is one water molecule bound per two silanol groups. Above 350°C, the water content decreases to a greater extent than the number of silanol groups.
    Notes: An Aerosil, einem feinteiligen amorphen Siliciumdioxyd, wurde die Menge der an der Oberfläche gebundenen Silanolgruppen in Abhängigkeit von der Temperatur durch Umsetzung mit SOCl2 bestimmt. Ihre Menge fiel zwischen 250° und 350° stark ab. Die Umsetzungen mit wasserfreiem AlCl3 und BCl3 und Bestimmung der gebundenen Mengen Al bzw. B und Cl ergab, daß die Oberfläche des bei erhöhter Temperatur im Hochvakuum entgasten Aerosils noch freies, fest adsorbiertes Wasser enthielt. Zwischen 100° und 350° war eine Wassermolekel auf zwei Silanolgruppen gebunden. Über 350° nahm der Wassergehalt stärker ab, als die Zahl der Silanolgruppen.
    Additional Material: 3 Ill.
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  • 55
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 184-192 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The H atoms of the thionitrosyl complex Ni(HN2S2)2 can be substituted by organic groups. A monomethyl, dimethyl, and monoethyl derivative have been isolated being deeply coloured stable compounds which are soluble in organic solvents. The dimethyl compound has completely plane molecules in which two CH3NSNS groups are linked with the Ni atom giving a chelate-like trans configuration (monoclinic; lattice constants a = 3.93 Å, b = 14.09 Å, c = 8.29 Å, β = 105.7°; two molecules per unit cell; space group C52 h-P 21/c).
    Notes: Die Wasserstoffatome im Thionitrosylkomplex des Nickels, Ni(HN2S2)2, lassen sich durch organische Reste ersetzen. Ein Monomethyl-, ein Dimethyl- und ein Monoäthylderivat konnten isoliert werden. Es sind tief gefärbte, in organischen Lösungsmitteln gut lösliche, beständige Substanzen. Die Struktur der Dimethylverbindung, Ni(CH3N2S2)2 wurde röntgenographisch bestimmt. Die Verbindung kristallisiert monoklin, mit den Gitterkonstanten a = 3,93 Å, b = 14,09 Å, c = 8,28 Å, β = 105,7°. In der Elementarzelle sind 2 Molekeln. Die Raumgruppe ist C52 h - P 21/c. Die Struktur wurde bestimmt mittels zwei- und dreidimensionaler PATTERSON- und FOURIER-Synthesen. Danach sind am Nickel zwei CH3NSNS-Gruppen chelatförmig gebunden. Die vollkommen ebene Molekel besitzt trans-Konfiguration.
    Additional Material: 1 Ill.
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  • 56
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 224-238 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reaction of trimethyl boron with acetic acid leads in the first step to dimethyl boron acetate which is monomolecular in the vapour state and polymerized (by acetate groups) in the solid state, as is indicated by IR spectra. In the second step, methyl boron diacetate is formed which decomposes at room temperature yealding acetic anhydride and B, B′-diacetyldimethyldiborate. A structure for the latter compound is proposed. All attempts to prepare boron triacetate led to pyroboron acetate.
    Notes: Die Umsetzung von Bortrimethyl mit Essigsäure ergibt in erster Stufe Dimethylboracetat, das nach den IR-Spektren in Dampfform monomolekular und im festen Zustand über Acetatgruppen polymerisiert vorliegt. Das in zweiter Stufe entstehende Methylbordiacetat spaltet bereits bei Zimmertemperatur Essigsäureanhydrid ab und geht in das B, B′-Diacetyldimethyldiborat über. Auch für diese Substanz wird ein Strukturvorschlag gemacht. Alle Versuche zur Darstellung von Bortriacetat ergeben Pyroboracetat.
    Additional Material: 1 Ill.
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  • 57
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 286-296 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: From AgNO3, AgF, and AgClO4 solutions, silver(III) oxide phases have been prepared by anodic oxidation. These are steel-gray, magnetite-like octahedra having a cubic face-centered unit cell (a = 9.842-9.890 Å).All the specimen obtained differ from the ideal composition Ag2O3, as analysis and pyenometric measurements show; they are supposed to be Ag2O3 defect compounds being only stable in the presence of foreign anions and Ag(I)ions (approximate formulae: Ag3+5 Ag+2O8NO3; Ag2(O, F)3; the perchlorate-containing phase has no stoichiometric composition). Their chemical properties and thermal decomposition are described.The alleged oxide Ag4O5 (SELBIN and USATEGUI) does not exist.
    Notes: 1. Es wurden aus AgNO3-, AgF- und AgClO4-Lösungen höhere Silberoxidpräparate durch anodische Oxydation dargestellt. Diese bestehen alle aus stahlgrauen, magnetitähnlichen Oktaedern, die Kantenlänge der kubisch flächenzentrierten Zelle ist a = 9,842-9,890 Å.2. Die Präparate wurden analysiert; ihre Dichte wurde gemessen und daraus der Zelleninhalt in Atomen bestimmt. Daraus geht hervor, daß das Gitter defekt ist. Die Zusammensetzung der nitrathaltigen Verbindung ist mit guter Annäherung Ag7NO11 oder Ag3+5 Ag+2O8NO3. Die fluorhaltige Phase kann als Ag2(O, F)3 formuliert werden, die perchlorathaltige hat keine stöchiometrische Formel.3. Alle diese Oxide stellen eine kubisch flächenzentrierte Phase mit der „idealen Zusammensetzung“ Ag2O3 dar, die aber nur in Gegenwart von Fremdanionen stabil ist und in welcher Ag3+ und Ag+-Ionen in verschiedenen Proportionen vorliegen.4. Die chemischen Eigenschaften werden beschrieben und die thermische Zersetzung (mit Derivatogrammen) wurde eingehend studiert.5. Das von SELBIN und USATEGUI angegebene Oxid „Ag4O5“ existiert nicht.
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  • 58
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The kinetics of the reaction between nitrite and azide in hydrogensulfite-sulfite buffer solutions has been investigated under conditions which inhibit the formation of hydroxylamine disulfonate. From the rate expression, it can be concluded that the reaction has the same preceding equilibrium as the synthesis of hydroxylamine according to RASCHIG.
    Notes: Es wurde die Kinetik der Umsetzung von Nitrit mit Azid in Hydrogensulfit-Sulfit-Pufferlösungen unter Bedingungen ermittelt, bei welchen die Hydroxylamin-Synthese inhibiert wird. Aus dem Geschwindigkeitsgesetz  -  dcNO2-/dt = 8,45 cNO2 cN3 cHSO32/ cSO32-Mol/min (25°C, μ = 1,2) ist zu schließen die Umsetzung über dasselbe vorgelagerte Gleichgewicht verläuft wie die RASCHIGSCHE Hydroxylamin-Synthese.
    Additional Material: 2 Ill.
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  • 59
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 326-336 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Darstellung und Eigenschaften SCHIFFscher Basen aus 3-Aldehydosalicylsäure und verschiedenen Aminen bzw. Aminosäuren sowie von Metallchelaten dieser SCHIFFschen Basen werden beschrieben. Die Basen aus Monaminen und Aminosäuren wirken gegenüber Cu2+, Ni2+, Co2+ und UO2+2 als dreizähnige, diejenigen aus Diaminen als vierzähnige Liganden. Die Messung der magnetischen Momente der Metallkomplexe ergab, daß diese - mit Ausnahme zweier Durchdringungskomplexe des Nickels mit wahrscheinlich planarer dsp2-Konfiguration - Normalkomplexe sind.
    Notes: The present paper describes the preparation and properties of SCHIFF's bases derived from 3-aldehydo-salicylic acid and aniline, ethylenediamine, orthophenylenediamine, glycine, anthranilic acid, sulfanilic acid or sulfanilamide, as well as the metallic complexes of them. The SCHIFF's bases with mono-amines or amino-acids behave as tridentate ligands with acidic group of the amino-component remaining free, while those with diamines behave as quadridentate ligands with both the carboxyl groups of the 3-aldehydo acid remaining unattached. The magnetic moment values of the metal complexes reveal that all of them, with the exception of the two nickel compounds of the SCHIFF's bases of ethylenediamine-3-aldehydosalicylic acid and orthphenylenediamine-3-aldehydo salicylic acid, are of ionic or outer-level covalent type. The two nickel compounds, just mentioned, are diamagnetic and orangeyellow in colour and should, therefore, be represented as penetration or innerlevel complexes with planar dsp2 hybrid bonds.
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  • 60
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 28-34 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammensetzung und Stabilität der aus Fe37+ und o-Kresotinsäure gebildeten blauvioletten Chelatverbindung wurden spektrophotometrisch bei αDmax = 550 mμ ermittelt. Es ist ein 1 : 1-Komplex, für dessen Beständigkeitskonstante bei 35,5°C und pH 1,93; 2,90 und 3,92 folgende Werte erhalten wurden: log k = 4,61; 4,15 bzw. 3,40.
    Notes: The formation of a bluish violet chelate between iron(III) and o-cresotic acid with absorption maximum at 550 mμ has been observed. The composition of the chelate has been determined spectrophotometrically using methods of continuous variation, slope ratio and mole-ratio; the ratio of iron(III) to o-cresotate corresponded to 1 : 1. These data were further utilised for the computation of stability constant (log k) at pH 1.93, 2.90 and 3.92, which at 35.5°C worked out to be 4.61, 4.15 and 3.40 respectively.
    Additional Material: 7 Ill.
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  • 61
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    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 44-56 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The phosphates, arsenates, and vanadates of the rare earth metals occur in two structure types: Most of them crystallize in the zircon structure, some of them, salts of the rare earths having larger ions, in the huttonite and monazite type, respectively. Both types have been found in the case of TbPO4.The dimensions of the unit cells of the zircon-type compounds are comunicated. There is no discontuniity of the alteration of the cell dimensions and lattice constants of the arsenates and vanadates with increasing atomic number at the gadolinium salts.ScPO4, ScAsO4, and ScVO4 have zircon structure; BiPO4 exists in a low-temperature modification of huttonite type and still another, hitherto unkwon form; BiAsO4 has huttonite structure.
    Notes: Bei den Phosphaten, Arsenaten und Vanadaten der Seltenen Erden treten zwei Strukturtypen auf. Die überwiegende Zahl kristallisiert mit der Struktur des Zirkons. Eine Reihe von Verbindungen mit den größeren Ionen der Seltenen Erden zeigt die Struktur des Huttonits bzw. Monazits. Beim TbPO4 konnten beide Strukturtypen nachgewiesen werden. Die Abmessungen der Elementarzellen für die Verbindungen mit Zirkonstruktur werden mitgeteilt. Der Verlauf der Gitterkonstanten und Elementarzellenvolumina zeigt bei den Arsenaten und Vanadaten in Abhängigkeit von der Ordnungszahl der Seltenen Erden keine Unstetigkeit beim Gadolinium. Auch ScAsO4 und ScVO4 kristallisieren wie das schon länger bekannte ScPO4 mit Zirkonstruktur. Beim BiPO4 existiert neben einer Niedertemperaturmodifikation mit der Struktur des Huttonits, die auch für BiAsO4 beobachtet wird, eine weitere, bisher unbekannte Modifikation.
    Additional Material: 7 Ill.
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  • 62
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 35-43 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: By partial hydrolysis of TiCl4 · 2 CH3CN in acetonitrile as the solvent, Ti2Cl6O · 4 CH3CN and Ti2Cl6O · 6,5 CH3CN have been prepared. From Ti2Cl6O · 4 CH3CN, analogous addition compounds with benzonitrile and dioxane as ligands are obtained. The determination of the molecular weight of the dioxane compound agrees with the formulation as Cl3Ti-O-TiCl3 · 4 dioxane.Ti2Cl6O · 4 CH3CN shows in acetonitrile a small electric conductivity which is supposed to be due to a partial dissoziation into TiCl3+ and TiOCl3- ions. This is confirmed by the interaction with [NR]4Cl yielding [NR4]2TiCl6 and [NR4]2TiOCl4 (R = C2H5).The thermal decomposition leads only in the case of Ti2Cl6O · 6,5 CH3CN to a definite reaction product; here, Ti2Cl6O · 3 CH3CN being amorphous to X-rays is formed.
    Notes: Bei der partiellen Hydrolyse von TiCl4 · 2 CH3CN in Acetonitril entsteht die Verbindung Ti2Cl6O · 4 CH3CN. Unter bestimmten Bedingungen wird die acetonitrilreichere Verbindung Ti2Cl6O · 6,5 CH3CN erhalten, die leicht in Ti2Cl6O · 4 CH3CN übergeht. Durch Umlösen aus Dioxan bzw. Benzonitril läßt sich Ti2Cl6O · 4 CH3CN in Ti2Cl6O · 4 Dioxan bzw. Ti2Cl6O · 4 C6H5CN überführen. Die Molekulargewichtsbestimmung der Dioxanverbindung ergibt den der Formel entsprechenden Wert. Daraus folgt die Strukturformel Cl3Ti-O-TiCl3 · 4 Dioxan.In Acetonitril zeigt Ti2Cl6O · 4 CH3CN eine geringe elektrolytische Leitfähigkeit. Sie wird durch die Annahme einer partiellen Dissoziation in solvatisierte TiCl3+- und TiOCl3--Ionen gedeutet. Hierfür spricht auch die Bildung von [N(C2H5)4]2TiCl2 und [N(C2H5)4];2TiCl2O bei der Umsetzung von Ti2Cl6O · 4 CH3CN mit [N(C2H5)4]Cl.Die Solvensmolekeln lassen sich durch thermische Behandlung nicht ohne gleichzeitige Zersetzung des Hexachlordititanoxids abspalten. Die Bildung eines einheitlichen Zersetzungsproduktes wird nur bei der thermischen Zersetzung von Ti2Cl6O · 6,5 CH3CN beobachtet. Es ist röntgenamorph und hat die Zusammensetzung Ti2Cl6O · 3 CH3CN.
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  • 63
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    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 83-88 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Analyse sowie potentiometrische und amperometrische Titration eines blauvioletten Hydrazin-Chrom(II)-chlorides ergaben die Zusammensetzung [Cr(N2H4)3]Cl2 · 3 H2O. Das magnetische Moment von 3.4 Bohrschen Magnetonen entspricht zwei ungepaarten Elektronen.
    Notes: The composition of the hydrazine chromous chloride complex was determined using potentiometric and amperometric methods. The complex is bluish violet in colour and its composition may be represented as [Cr(N2H4)3]Cl2 · 3 H2O. Data obtained by the analysis of the dried product also give the same information about the composition of the complex. Further, the value of magnetic moment came out to be 3.4, which indicates the presence of two unpaired electrons.
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  • 64
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    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 126-136 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: It has been experimentally shown that a continuous series of lithium ferrites can be prepared in the direct current arc. The individual compounds of this series correspond to the general formula .Diffractometer diagrams and the determination of the specific magnetisation shown that a three-phase mixture, (γ-Fe2O3, α-Fe2O3,ε-Fe2O3), is formed first at low lithium content, followed by the conversion to the tetragonal γ-Fe2O3. Higher lithium contents lead to a gradual and continuous lattice rearrangement to the spinel phase LiFe5O8 which in turn changes over to the rock salt type of the f. c. c. phase LiFeO2.
    Notes: Es konnte experimentell im Gleichstromlichtbogen eine lückenlose Reihe von Lithiumferriten (Lichtbogenoxide) dargestellt werden. Die einzelnen Glieder dieser Reihe entsprechen der allgemeinen Formel .Zählrohraufnahmen und Messungen der spezifischen Magnetisierung ergeben, daß bei geringem Lithiumgehalt das unter den angewandten Bedingungen zunächst entstehende Dreiphasengemisch (γ -Fe2O3, α-Fe2O3 und -Fe2O3) zugunsten der tetragonalen Phase γ-Fe2O3 verschwindet Weiterer Lithiumeinbau führt über eine allmähliche kontinuierliche Gitterumordnung über die Spinellphase LiFe5O8 zu dem kubisch-flächenzentrierten Kochsalztyp der Phase LiFeO2.
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  • 65
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    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 13-27 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The behaviour of SC(SH)2 in aqueous solutions between 0 and 22°C was investigated by means of conductivity and pH measurements. The equivalent conductivities (Δ0T) of CS32- and of H2CS3, as well as the dissociation constants Ka1 und Ka2 of H2CS3 were determined. The enthalphy ΔHD, the entropy ΔSD and GIBBS free energy ΔGD were calculated.From electrical and optical data it is concluded that the decomposition of H2CS3 in aqueous solution is a first-order reaction. The decomposition constant, the activity energy, and the half-life were determined.Furthermore, the Stokes radius of the CS32- ion, the radius of the hydrated ion and its diffusion coefficient were calculated.
    Notes: Mit Hilfe von Leitfähigkeits- und pH-Messungen wurde unter variablen Bedingungen das Verhalten von SC(SH)2 in wäßrigen Lösungen zwischen 0°C und 22°C untersucht. Neben den Äquivalentleitfähigkeiten von CS32- und H2CS3, die sich durch die Temperaturfunktionen (in cm2 Mol-1 Ω-1; T in °K) beschreiben lassen, wurden die beiden Dissoziationskonstanten der H2CS3 bei 20,0°C zu bestimmt. Für die Dissoziationsenthalpie ΔLHD, Dissoziationsentropie ΔHD und Gibbssche freie Enthalpie (Dissoziationsarbeit) ΔGD der 1. Stufe folgt bei 20,0°C Sowohl durch leitfähigkeits- als auch durch Absorptionsmessungen zwischen 0°C und 22°C konnte nachgewiesen werden, daß der Zerfall der H2CS3 in wäßriger Lösung formal 1. Ordnung ist; Zerfallskonstante: (k in Min.-1; T in °K): log k = -3,62 · 10-3 · T-1 + 12,852; Aktivierungsenergie des Zerfalls: ΔHA = 16,6 ± 0,2 kcal/Mol; Halbwertszeit bei 20,0°C: 0,217 Min.Für das CS32- wurden bei 20,0°C der STOKESSCHE Radius zu rs = 1,98 Ä, der Radius des hydratisierten Ions zu rHyder. = 3,60 Ä und der Grenzwert des Diffusionskoeffizienten zu D0 = 0,93 ± 0,01 cm2/Tag berechnet.
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  • 66
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 65-82 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The alkylation and catalytic exchange of alkyl groups of chlorosilanes have been investigated.The reactivity of the Si—Cl bond decreases with increasing number of the same substituents being in the molecule. It is supposed that the transition complex which determines the rate of the investigated reactions is formed by an electrophilic attack.
    Notes: Es wurde die Alkylierung und die katalytische Äquilibrierung von Chlorsilanen unter weitgehend variierten Bedingungen untersucht und festgestellt, daß die Reaktivität der Bindung Si—Cl mit der Anzahl der gleichen Substituenten in der Molekel abnimmt. Da die verschiedenen Versuchsbedingungen keinen Einfluß auf dieses Verhalten ausüben, kann eine Erklärung nur in der Struktur der Molekel, bzw. in der Natur der Bindung gesucht werden. Es wurde die Annahme gemacht, daß der Übergangskomplex, welcher für die Geschwindigkeit der Elementarvorgänge ausschlaggebend ist, im Gegensatz zur anderweitigen Reaktion der Si—Cl-Bindung in den untersuchten Fällen durch einen elektrophilen Angriff entsteht. Diese Annahme steht im Einklang mit den Versuchsergebnissen.
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  • 67
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    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 57-64 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The degree of electric charging of metal surfaces due to retarding of neutral metallic and semiconducting particles having various velocities has been determined. The effects are supposed to result from the exo-emission of electrons the amount of which depends on the velocities, masses, and impact angles of the particles.From the strong differences between the reactivities of solid substances during and after mechanical working it is concluded that the observed exo-emission is caused by exitation states at submicroscopic surface points.
    Notes: Die elektrische Aufladung von Metalloberflächen bei der Impuls-Bremsung nicht geladener, fliegender, metallischer und halbleitender Partikel verschiedener Geschwindigkeiten wird gemessen. Die beobachteten Erscheinungen lassen sich aus der Exo-Emission von Elektronen herleiten. Diese ergibt sich u. a. aus dem Zusammenhange zwischen der Elektronen-Austrittsarbeit der beteiligten Partner und der Größe der gebremsten Impulse. Die Ladungs-Übergänge hängen Übersichtlich vom Quadrat der Geschwindigkeiten, von der Masse und vom Auftreffwinkel der Körner ab. Einflüsse mechanischer Vorbehandlung der Festkörper, entsprechend früheren Beobachtungen, werden bestätigt.Im Zusammenhange mit den beobachteten großen Unterschieden des Reaktionsvermögens von Festkörpern während der Bearbeitung und nach ihrem Abschluß lassen die beobachteten Exo-Emissionen auf das Auftreten erhöhter Anregungszustände an submikroskopischen Orten während der Impuls-Bremsung schließen.
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  • 68
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 97-107 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The following compounds are prepared by several methods: CH3OSeO3Na, CH3OSeO3K, CH3OSeO3NH4, C2H5OSeO3Na, C2H5OSeO3K, and C2H5OSeO3NH4. The best yields result in the alkylation of acetates with (CH3O)2SeO2 or (C25O)2SeO2. CH3OH and C2H5OH esterify hydrogenselenates and solvolize diselenates, whereby alkylselenates are formed. CH3OSeO3K and C2H5OSeO3K can prepared by mixing methanolic resp. ethanolic solutions of H2SeO4 and CH3COOK. The same compounds are formed by addition of alcoholic CH3COOK solutions to such of Na- or NH4-alkylselenates. Alkylselenates are transformed by ester interaction. Alkali alkylselenates decompose on heating under evolution of dialkyl ethers and formation of diselenates. Densities and solubilities of the prepared salts are communicated.
    Notes: Es werden mehrere Verfahren zur Darstellung der folgenden Verbindungen angegeben: CH3OSeO3Na, CH3OSeO3K, CH3OSeO3NH4, C2H5OSeO3Na, C2H5OSeO3K und C2H5OSeO3NH4. Die besten Ausbeuten liefert die Alkylierung von Acetaten mit (CH3O)2SeO2 oder (C2H5O)2SeO2. Alkylselenate entstehen auch durch Veresterung von Hydrogenselenaten und durch Solvolyse von Diselenaten mit CH3OH bzw. C2H5OH. CH3OSeO3K und C2H5OSeO3K können auch durch Umsetzung methanolischer bzw. äthanolischer Lösungen von H2SeO4 und CH3COOK dargestellt werden. Diese Verbindungen werden auch durch Fällung alkoholischer Na- oder NH4-Alkylselenatlösungen mit CH3COOK gebildet. Alkylselenate lassen sich umestern. Alkalialkylselenate pyrolysieren beim Erhitzen unter Abspaltung von Dialkyläthern und Bildung von Alkalidiselenaten. Die Dichten und die Löslichkeiten der dargestellten Salze werden mitgeteilt.
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  • 69
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 149-159 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The oxidation and co-ordination numbers of coloured cations being in the analytically used borax and polyposphate bead, respectively, have been studied by means of absorption spectra. The mutual interaction between the cations and the oxygen-containing polyanions is discussed in comparison with the state of coloured silicate glasses.
    Notes: Mit Hilfe der Absorptionsspektren werden Wertigkeit und Koordinationsverhältnisse der Farbkationen in den Borax- und Phosphorsalzperlen untersucht. In Anlehnung an die Theorie der gefärbten Silicatgläser wird die Wirkung der eingebauten Kationen über die Sauerstoffkomplexe gedeutet. Die Abhängigkeit der Färbung vom Alkaligehalt des Glases und von der Art der verwendeten Alkalien wird als Folge der unterschiedlichen Polarisierbarkeit des Brückensauerstoffs erklärt.
    Additional Material: 7 Ill.
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  • 70
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 48-59 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The formation of anomalous mixed crystals in the systems ThO2—Eu2O3 and ThO2—Yb2O3 has been investigated by means of X-ray powder diffraction. In both systems a marked influence of temperature on the range of solid solubility in the existent cubic phase has been observed. Phase diagrams are given for the temperature range of investigation. The solubility of the sesquioxides in ThO2 varies from 7.3 to 10 Mol-% YbO1.5 and from 36 to 53 Mol-% EuO1.5, respectively, depending on the temperature.
    Notes: Die Bildung von anomalen Mischkristallen in den Systemen ThO2—Eu2O3 und ThO2—Yb2O3 wurde röntgenographisch untersucht. Bei beiden Systemen besteht eine starke Temperaturabhängigkeit der Grenzzusammensetzungen der auftretenden kubischen Mischkristalle. Für den untersuchten Temperaturbereich wurden Phasendiagramme aufgestellt. ThO2 vermag je nach der Temperatur 7,3 bis 10 Mol-% YbO1,5 oder 36 bis 53 Mol-% EuO1,5 zu lösen.
    Additional Material: 3 Ill.
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  • 71
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 78-85 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The fluorination of organosilicon compounds by means of SF4 is described and compared with the fluorination of carbon compounds.SF4 converts monotopic Si-Cl bonds into Si-F groups; Si-O-Si bridges are cleaved funder formation of Si-F bonds; from silanols and silanediols, fluorosilanes and difluorosilanes, respectively, are formed; alkoxysilanes yield the corresponding fluorosilanes, alkyl fluorides and, additionally, dialkyl sulphites.
    Notes: Im Gegensatz zu den vorher bekannten Fluorierungsmitteln werden von Schwefeltetrafluorid in der Kohlenstoffchemie besonders die Gruppierungen fluoriert. Die der Umsetzung mit anderen Fluorierungsmitteln leicht zugängigen CCl-Bindungen dagegen bilden mit SF4 nur schwer CF-Bindungen. In der Siliciumchemie werden aber auch monotope SiCl- von Schwefeltetrafluorid in SiF-Bindungen umgewandelt. Si-O-Si- werden unter Entstehung von SiF-Bindungen gespalten. Silanole und Silandiole gehen in Fluorsilane bzw. Difluorsilane über. Alkoxysilane geben das entsprechende Fluorsilan und Alkylfluorid, außerdem entstehen Dialkylsulfite.
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  • 72
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 86-89 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Interactions between SOF2 and organosilicon compounds are described.SOF2 reacts with dialkyl dialkoxysilanes forming dialkyl sulphites and dialkyl difluorosilanes. The Si—Cl bond of alkyl chlorosilanes is partly converted to Si—F. Si—OH groups of silanols and silanedioles react easily yielding fluorosilanes and difluorosilanes, respectively. There is no reaction of the Si—O—Si bridge of hexamethyl disiloxane with SOF2.
    Notes: Thionylfluorid reagiert mit Dialkyldialkoxysilanen unter Bildung von Dialkylsulfit und Dialkyldifluorsilan. Die SiCl-Bindung in Alkylchlorsilanen läßt sich in geringem Umfang in die entsprechende SiF-Bindung umwandeln. Die Si-O-Si-Gruppierung des Hexamethyldisiloxans wird von Thionylfluorid nicht umgesetzt. Verhältnismäßig hohe Reaktionsbereitschaft zeigen Silanole und Silandiole, aus denen die entsprechenden Fluorsilane bzw. Difluorsilane gewonnen werden.
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  • 73
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 112-112 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 74
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 157-161 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die Elementarzellen und wahrscheinlichen Raumgruppen wurden für NiSeO4 · H2O und NiSeO4 bestimmt.
    Notes: The lattice constants and probable space groups of NiSeO4 · H2O and NiSeO4 were determined. Both are isomorphous with the corresponding sulphates.The powder patterns of NiSeO4 · 4 H2O and NiSeO4 · 2 H2O are given. The linear coefficients of thermal expansion in the three axial directions were determined for NiSeO4 to 500° C.
    Additional Material: 5 Tab.
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  • 75
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 185-196 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die Eisencarbonylbildung wird durch Schwefelwasserstoff ebenfalls sensibilisiert.The activating influence of inorganic sulfur compounds (FeS, FeS, MoS2, NiS, H2S, S) on the formation of Ni(CO4) has been investigated with and without mechanical working.The sensitizing properties of this compounds depend on the energy content of both the metallic nickel and the sensitizer, and are therefore considerably improved by mechanical working.The catalytic activation is due to the intermediate formation of γ-NiS.The analogous mechanochemical formation of Fe(CO)5 is sensitized by H2S, too.
    Notes: In systematischen Untersuchungen wurde der sensibilisatorische Einfluß zahlreicher Fremdstoffe (FeS2, FeS, MoS2, NiS, S, H2S) auf die Carbonylreaktion in Ruhe und unter Bedingungen der Bearbeitung untersucht.Die sensibilisatorische Fähigkeit der untersuchten Stoffe ist vom Energieinhalt des Nickels und des Sensibilisators abhängig und wird deshalb bei mechanischer Bearbeitung erheblich gesteigert.Die Wirkung der Sensibilisatoren besteht darin, daß bei der Nickelcarbonylsynthese γ-NiS als Zwischenprodukt auftreten kann. Zur Beschleunigung dieser Reaktion werden nur katalytische Mengen des Sensibilisators benötigt. Die Carbonylbildung läuft nach dem Prinzip einer Zwischenstoffkatalyse ab. Größere Mengen fester Sensibilisatoren vermindern hingegen durch Deckschichtenbildung die Carbonylreaktion.
    Additional Material: 11 Ill.
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  • 76
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 197-201 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The analytical separation of the five silicon compounds SiHxCl4-x (x = 0 → 4) having boiling points between -111.6 and + 57.6° C has been achieved by a combined gas solid and gas liquid chromatography using two columns. In the first one, loaded with silicone oil, the constituents of technical grade trichlorosilane, SiH3Cl, SiH2Cl2, SiHCl3 and SiCl4, were determined whereas SiH4 being sensitive to oxygen was separated from nitrogen in a second silica gel column.
    Notes: Die analytische Trennung der fünf Siliciumhomologen SiHxCl4-x (x = 0 → 4), deren Siedepunkte zwischen -111,6°C liegen, gelang durch Kombination von Adsorptions- und Verteilungs-Gas-Chromatographie an zwei hintereinander und gleichzeitig arbeitenden Apparaturen. In der ersten wurden an Silikonöl voneinander die in technischem Trichlorsilan mit Sicherheit vorhandenen Verbindungen SiH3Cl, SiH2Cl2, SiHCl3 und SiCl4 getrennt, während das unter Umständen vorhandene sauerstoffempfindliche Monosilan (SiH4) neben Stickstoff als Spülgas erst an der sich anschließenden zweiten Trennsäule nachgewiesen werden konnte. Als stationäre Phase wurde hierbei Silicagel verwendet, das nach Durchgang des SiH4 vor den nachfolgenden Chlorsilanen durch Zwischen-schalten einer mit Kaliumhydroxid gefüllten Reaktionssäule geschützt wurde.
    Additional Material: 2 Ill.
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  • 77
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 208-213 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es wurde die Zusammensetzung von Lanthanmolybdat-Niederschlägen untersucht, die sich aus Lanthannitrat und Lösungen verschieden kondensierter Na-Molybdate bilden. Die Reaktionen wurden bei verschiedenem pH, in rein wäßrigem oder wäßrig-alkoholischem Medium durch amperometrische und konduktometrische Titration verfolgt. Im pH-Bereich von 5,0-6,0 bildet sich das Orthomolybdat La2O3 · 3 MoO3, bei pH = 3,5-4,5 das Paramolybdat La2O3 · 7 MoO3.
    Notes: The formation and precipitation of lanthanum molybdates obtained by the interaction of lanthanum nitrate and different alkali molybdates (normal, di, para and meta) have been studied by means of amperometric and conductometric titrations between the reactants at different pH ranges, in aqueous and aqueous-alcoholic media, with each of the reagents alternately used as the titrant. Electrometric experiments provide definite evidence for the formation of normal lanthanum molybdate La2O3 · 3 MoO3 at pH range 5.0-6.0 and para-molybdate La2O3 · 7 MoO3 at pH range 3.5-4.5. The precipitation of normal molybdate is almost quantitative.
    Additional Material: 4 Ill.
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  • 78
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 250-258 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The reactions between C6H11PH2 and anhydrous salts of Ni, Pd, Co, Fe(II), Cr(III), and Cu(I) result in the formation of complexes of different constitutions. Thus the following compounds could be obtained: [(C6H11PH2)2NiBr2], [C6H11PH2-m̈-C6H11 PHPdCl]2, [(C6H11PH2)6Co][CoX4], [(C6H11PH2)22FeCl2], [(C6H11PH2)3 FeBr2], [(C6H11PH2)2CrCl3]2, and [C6H11PH2CuBr]2. Their structural configuration is proposed on the basis of magnetic measurements, molecular weight determinations and such of the conductivities.
    Notes: Cyclohexylphosphin reagiert mit den wasserfreien Salzen des Ni, Pd, Co, Fe(II), Cr(III) und Cu(I) unter Bildung von Komplexen verschiedener Zusammensetzung. Das Umsetzungsverhältnis von Metallsalz: C6H11PH2 beträgt nicht nur 1:2, wie in den Komplexen [(C6H11PH2)2NiBr2], [m̈-C6H11PHPdClC6H11PH2] 2, [(C6H11PH2)2FeCl2] und [(C6H11PH2)2CrCl3]2, sondern auch 1:3 in (C6H11PH2)3CoX2 oder [(C6H11PH2)3FeBr2] und 1:1 im Falle des Zweikernkomplexes [C6H11PH2CuBr]2. An Hand magnetischer Untersuchungen, Molekulargewichtsbestimmungen und Leitfähigkeitsmessungen werden die Cyclohexylphosphinkomplexe hinsichtlich ihres strukturellen Aufbaus näher charakterisiert.
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  • 79
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 287-296 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The binary systems Bi2O3-SiO2, Bi2O3-GeO2, and Bi2O3-SnO2 were studied by X-rays over the whole range (data see “Inhaltsübersicht”).
    Notes: Die binären Systeme Bi2O3-SiO2, Bi2O3-GeO2 und Bi2O3-SnO2 wurden im gesamten Konzentrationsbereich röntgenographisch untersucht:System Bi2O3-SiO2: γ*-Bi2O3: a = 10,098 ± 0,004 Å für Si2Bi24O40; Eulytin-Typ: a = 10,299 ± 0,008 Å für Bi4(SiO4)3; δ*-Bi2O3: a = 5,542 ± 0,006 Å für 6 Bi2O3 · SiO2.System Bi2O3-GeO2: γ*-Bi2O3: a = 10,145 ± 0,005 Å für Ge2Gi24O40; Eulytin-Typ: a = 10,526 ± 0,003 Å für Bi4(GeO4)3; δ*-Bi2O3: a = 5,572 ± 0,008 Å für 6 Bi2O3 · GeO2.System Bi2O3-SnO2: Stark gestörter Pyrochlor-Typ für Bi2Sn2O7; β*-Bi2O3: a = 10,93 ± 0,01 Å, c = 5,56 ± 0,01 Å für 6 Bi2O3 · SnO2.
    Additional Material: 2 Ill.
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  • 80
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 313-320 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Apatitic calcium phosphates with Ca/P ratios different from that of hydroxylapatite were investigated by chemical and physical methods and their compositions established. Defects occur not only in calcium, but also in OH-positions. the general formula for apatites of this kind is Ca10-x-y(HPO4)6-x(OH)2-x-2y. In carbonateapatites first order defects can partially be refilled: Ca10-x+y(CO3)x (PO4)6-x(OH)2-x+2y.
    Notes: Apatitische Calciumphate mit vom Hydroxylapatit abweichenden Ca/P-Verhältnissen wurden chemisch und physikalisch untersucht und ihre Zusammensetzung bestimmt. Fehlstellen können nicht nur in Calcium-, sondern auch in OH-Positionen vorhanden sein. Die allgemeine Formel für Apatite dieser Art ist Ca10-x-y(HPO4, CO3)x (PO4)6-x(OH)2-x-2y. in Carbonatapatiten können Defekte 1. Ordnung teilweise wieder aufgefüllt sein: Ca10-x+y (CO3)x(PO4)6-x(OH)2-x+2y.
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  • 81
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 325 (1963) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 82
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: It is shown by Raman spectroscopic investigations, that HOSeO′3 and Se2O′7-ions are converted in alcoholic solutions to soluble alkyl selenates. Raman and IR spectra of the following compounds are given and discussed: CH3OSeO3Na,  - K,  - NH4; C2H5OSeO3Na,  - K,  - NH4. The force constants of CH3OSeO′3 and HOSeO′3 ions are calculated. Their knowledge allows an estimation of the bond properties in CH3OSeO′3, HOSeO′3 and CH3OSO′3 ions. It is supposed that ethyl selenate ions exist in solution in two rotationally isomeric configurations caused by hindered rotation of the CH3 group.
    Notes: Mit Hilfe der Raman-Spektroskopie wird gezeigt, daß Hydrogenselenationen und Diselenationen in alkoholischen Lösungen als Alkylselenationen vorliegen. Es folgt die Mitteilung und Zuordnung der Raman- und IR-Spektren der Verbindungen CH3OSeO3Na,  - K,  - NH4 und C2H5OSeO3Na,  - K,  - NH4. Die Kraftkonstanten des CH3OSeO′3 und des HOSeO′3-Ions werden berechnet. Ihre Kenntnis erlaubt eine Beurteilung der Bindungsverhältnisse in CH3OSeO′3-, HOSeO′3- und CH3OSO′3-Ionen. Äthylselenationen existieren in Lösung vermutlich in zwei rotationsisomeren Konfigurationen, verursacht durch behinderte Drehbarkeit der CH3-Gruppe.
    Additional Material: 6 Ill.
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  • 83
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    Zeitschrift für anorganische Chemie 325 (1963), S. 77-88 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A cubic, As-containing modification of Al2S3 has been prepared by reaction of Al + As + 4 S.Crystallographic data: cubic, a = 9.93 ± 0.01 Å; Fd3m - 07h; d20°C = 2.80 g/cm3, dx = 2.78 g/cm3.Atomic positions: 32 S atoms in 32e with x = 3/8; 16 Al-atoms in 16c; 5.33 Al atoms statistically in tetrahedral positions (8b).
    Notes: Versuche zur Darstellung von AlAsS4 lieferten statt der gesuchten Verbindung hexagonales Al2S3, wenn AlAs mit Schwefel umgesetzt wurde. Aus einem stöchiometrischen Gemenge von Al, As und 4 S dagegen bildete sich ein bisher unbekanntes, kubisches Al2S3. in dem etwa 2 Atom%% Al durch As ersetzt sind.Kristallographische Daten: Kubisch  -  Raumgruppe Fd3m  -  O7h; a = 9,93 ± 0,01 Å; d20°C = 2,80 g/cm3; dx = 2,78 g/cm3.Punktlagen: 32 Schwefelatome in 32e mit x = 3/8; 16 Aluminiumatome in Oktaederlücken (16c) bei 1/8 1/8 1/8 und 5,33 Aluminiumatome statistisch in Tetraederlücken (8b) bei 1/2 1/2 1/2.
    Additional Material: 3 Ill.
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  • 84
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 325 (1963), S. 119-121 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Durch spektrophotometrische Messungen wurde die Bildung von Komplexen im System Eisen(III)-Bis(2-Hydroxymethyl-5-hydroxy-4-pyron-6)keton untersucht. Im ersten Reaktionsschritt wird ein (1:1)-Komplex gebildet, danach sind ein (2:3)- und ein (1:2)-Komplex nachzuweisen.
    Notes: The interaction between iron(III) and bis(2-hydroxymethyl-5-hydroxy-4-pyrone-6)-ketone has been investigated by spectrophotometric methods. Continuous variation and mole ratio curves show evidence that 2:3 and 1:2 complexes are formed. The first step of the reaction involves the formation of an 1:1 complex.
    Additional Material: 2 Ill.
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  • 85
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 325 (1963), S. 122-129 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The conditions for preparing well crystallized niobium pentaiodide from the elements are described. The crystal lattice of NbJ5 belongs to the monoclinic system with a = 10.58; b = 6.58; c = 13.88 Å; β = 109.14°. The space group is P21/c, and there are 4 NbJ5 units in the unit cell. NbJ5 crystallizes in twins, the twin plane is (100). The structure is based on a hexagonal close-packing of the iodine ions. The Nb5+ ions are distributed on such octahedral holes that layers parallel to (100) result.
    Notes: Es wird eine geeignete Ausführungsform der Synthese von gut kristallisiertem Niobpentajodid aus den Elementen beschrieben. Strukturuntersuchungen an Einkristallen von NbJ5 führen zu einer monoklinen Elementarzelle mit 4 Formeleinheiten, den Gitterkonstanten a = 10,58 Å, b = 6,58 Å, c = 13,88 Å, β = 109, 14° und der Raumgruppe P21/c. Niobpentajodid kristallisiert bei den angewandten Präparationsbedingungen stets verzwillingt nach (100). Dem Gitter liegt eine hexagonal dichteste Jodpackung zugrunde; die Nb5+-Ionen sind derart auf Oktaederlücken dieser Packung verteilt, daß ein Schichtengitter parallel (100) resultiert.
    Additional Material: 2 Ill.
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  • 86
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 325 (1963), S. 191-195 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Using a dropping Bi electrode, the polarographic behaviour of heavy-metal ions in the molten LiCl—KCl eutectic has been investigated at 450°C. The half-wave potentials are communicated. An estimation of the Nernst factors shows that the Heyrovsky-Ilkovič equation is valid.
    Notes: Unter Verwendung einer tropfenden Wismutelektrode wird das polarographische Verhalten von Schwermetallionen im geschmolzenen LiCl—KCl-Eutektikum bei 450°C untersucht. Es werden die Halbstufenpotentiale ermittelt und an Hand der Nernst-Faktoren gezeigt, daß auch hier die Heyrovsky-Ilkovičsche Gleichung gilt.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 87
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 155-161 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The heat capacities of H2S2, H2S3, H2S4, H2S5, and H2S6 have been determined over a range of temperature from -38°C to + 40°C. The following equation gives a good approximation of the shift of the molar heats within the above named range of temperature: CpH2Sx = 7.50 + (7.26 + 0.0029 θ) · x. The constant value of 0.333 cal/g · deg., found by BUTLER and MAASS, for the heat capacity of liquid H2S2 between -89.6°C and room temperature, was found to be in agreement with our measurements within the error of ± 5%, given by the authors.
    Notes: Die spezifischen Wärmen cp von H2S2, H2S3, H2S4, H2S5 und H2S6 wurden über einen Temperaturbereich von -38°C bis + 40°C gemessen. Die Temperaturabhängigkeit der Molwärmen der Sulfane wird innerhalb des vermessenen Temperaturintervalls in guter Näherung durch die folgende Gleichung wiedergegeben: CpH2Sx = 7,50 + (7,26 + 0,0029 θ) · x. Der von BUTLER und MAASS für die spezifische Wärme des flüssigen Disulfans zwischen - 89,6°C und Raumtemperatur ermittelte konstante Wert von 0,333 cal-g · Grad stimmt innerhalb der von den Autoren angegebenen Fehlergrenze von ± 5% mit dem Ergebnis der vorliegenden Messungen überein.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 88
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 162-171 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: An apparatus is described which allows the measurements of molar heats of sulfanes in the gaseous state at pressures near 10-2 torr. From the molar heats of disulfane measured by means of this apparatus at different temperatures, the mean height of the two potential barriers restricting the internal rotation of the H2S2 molecule, has been determined to be V0 = 3,0 ± 0,5 kcal/mole, with respect to dimensions and normal vibration frequencies of the molecule.
    Notes: Es wird eine Meßanordnung beschrieben, die die Bestimmung der Molwärmen von Sulfanen im Gaszustand bei Drucken der Größenordnung von 10-2 Torr gestattet. Aus den mit Hilfe dieser Anordnung bei verschiedenen Temperaturen gemessenen Molwärmen des Disulfans wurde unter Berücksichtigung der geometrischen Daten und Normalschwingungsfrequenzen der Disulfanmolekel für die mittlere Höhe der beiden die innere Rotation behindernden Potentialschwellen ein Wert von 3,0 ± 0,5 kcal/Mol ermittelt.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 89
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 172-180 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A description is given for the process of determining the heats of formation of chlorosulfanes. The following values of standard heats of formation (1 atm; 298.2°K; liquid state) are obtained from the experimental data: δH°fS2Cl2 = - 13.9 kcal/mole; δH°fS3Cl2 = - 12.4 kcal/mole; δH°fS4Cl2 = - 10.2 kcal/mole; δH°fS5Cl2 = - 8.8 kcal/mole. The result is a linear dependence of the measured standard heats of formation on the length of the sulfurchain of the chlorosulfanes. This linear dependence allows the calculation of the corresponding quantities of further members of the homologous series of chlorosulfanes, by way of extrapolation: δH°fS4Cl2 = - 7.0 kcal/mole; δH°fS7Cl2 = - 5.3 kcal/mole; δH°fS8Cl2 = - 3.5 kcal/mole.
    Notes: Es wird ein Verfahren zur Bestimmung der Bildungsenthalpien der Chlorsulfane beschrieben. Aus den experimentellen Größen resultieren folgende Werte für die Normalbildungsenthalpien (1 Atm., 298,2°K, flüssiger Zustand): δH°bS2Cl2 = - 13,9 kcal/Mol; δH°bS3Cl2 = - 12,4 kcal/Mol; δH°bS4Cl2 = - 10,2 kcal/Mol; δH°bS3Cl2 = - 8,8 kcal/Mol. Es ergibt sich eine lineare Abhängigkeit zwischen den gemessenen Normalbildungsenthalpien und der Schwefelkettenlänge der Chlorsulfane. Diese Beziehung erlaubt es, die entsprechenden Daten weiterer Glieder der homologen Reihe der Chlorsulfane durch Extrapolation zu bestimmen: δH°bS6Cl2 = - 7,0 kcal/Mol; δH°bS7Cl2 = - 5,3 kcal/Mol; δH°bS8Cl2 = - 3,5 kcal/Mol. Die unter Verwendung der gefundenen Bildungsenthalpien der Chlorsulfane und der bereits bekannten Bildungsenthalpien der Sulfane berechneten Wärmetönungen einiger für die präparative Sulfanchemie wichtiger Kondensationsreaktionen werden angegeben.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 90
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 212-214 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The decomposition of NH3 on quartz has an activation energy of 33.7 kcal/mol. A special pretreatment for the purification of the quartz is described.
    Notes: Der Ammoniakzerfall an Quarz erfolgt mit einer Aktivierungsenergie von 33,7 kcal/Mol. Der Quarz wurde einer besonderen Reinigung unterworfen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 91
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 215-216 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: No Abstracts.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 92
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 322 (1963), S. 239-247 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Trimeric phosphorus nitridedichloride and its diphenyl derivative react with methylene diamines, H2N-(CH2)2-4-NH2, forming ansa compounds in which two different P atoms of the 6-membered P-N ring system are connected by one polymethylene diamine group.
    Notes: Trimeres Phospbornitrid-dichlorid sowie das Diphenylderivat des trimeren Phosphornitriddichlorids reagieren mit Methylendiaminen mit einer Kette von 2 bis 4C-Atomen in der Weise, daß Ansaverbindungen gebildet werden, bei denen die Polymethylendiamin-Gnxppe an zwei verschiedene P-Atome des sechsgliedrigen Ringsystems gebunden ist.
    Type of Medium: Electronic Resource
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  • 93
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 94
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 326 (1963), S. 47-52 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Dichloroboron azide, Cl2BN3, is formed from BCl3 and LiN3 in CH2Cl2 as a crystalline substance which is heavily attacked by water. At 200°C, N2 is split off and hexachloroborazole is formed by migration of Cl.
    Notes: Dichlorborazid bildet sich aus BCl3 und LiN3 in CH2Cl2 als kristalline, sehr wasserempfindliche Substanz. Bei 200° tritt Stickstoffabspaltung und Chloridwanderung unter Bildung von Hexachlorborazol ein.
    Type of Medium: Electronic Resource
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  • 95
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 323 (1963), S. 137-148 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A new camera for x-ray diffraction having a parafocussing arrangement is described. In this camera the diffraction rays impinge perpendicular to the film. Thus it is possible to determine particle size and lattice distortion from one photograph simultaneously. Geometrical and mathematical considerations prove the advantages of the new camera type.For measurements of particle sizes by means of a Guinier camera (diffraction rays impinge against the film transversally) a formula for correction is given.
    Notes: Es wird eine neue Röntgenkammer beschrieben, die nach dem GUINIER-Prinzip arbeitet, aber für jede abgebeugte Interferenz senkrechten Strahlenauffall auf den Film ermöglicht. Dadurch lassen sich Teilchengrößen und Gitterstörungen aus einer Aufnahme gleichzeitig bestimmen. Geometrische und mathematische Überlegungen erweisen die Vorteile der neuen Kammer.Für Messungen von Teilchengrößen mit der GUINIER-Kammer (schräger Strahlenauffall) wird eine Korrekturformel angegeben.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 96
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 326 (1963) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 97
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 326 (1963), S. 127-138 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The interaction between PCl5 and [NH3OH]Cl or between PCl5, PCl3 and [NH3OH]Cl yields, according to the experimental conditions, the compounds [Cl3P=N—PCl3]Cl, [Cl3P=N—PCl3][PCl6], and Cl3P=N—P(O)Cl2. The first one, P2NCl7, is the first stable reaction product which can be isolated.From C6H5PCl2, PCl5, and [NH3OH]Cl, the salt-like compounds [C6H5 P(Cl)2=NP(Cl2)C6H5]Cl and [C6H 5P(Cl2)=N—P(Cl)2C6H5][PCl6] are formed.A mechanism of this reaction type is proposed.
    Notes: Bei der Umsetzung zwischen PCl5 und Hydroxylammoniumchlorid bzw. von PCl5, PCl3 und [NH3OH]Cl, entstehen je nach den Versuchsbedingungen die Substanzen [Cl3P=N—PCl3]Cl, [Cl3P=;N—PCl3][PCl6] und Cl3P=N—P(O)Cl2. Die erstgenannte Verbindung, P2NCl7, ist das erste faßbare Produkt der Reaktion. Bei der entsprechenden Umsetzung von C6H5PCl2, PCl5 und [NH3OH]Cl erhält man [C6H5P(Cl2)=N—P(Cl2)C6H5]Cl und [C6H5P(Cl2)=N—P(Cl2)C6H5][PCl6]. Ein Vorschlag für den Bildungsmechanismus wurde gemacht.
    Type of Medium: Electronic Resource
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  • 98
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 69-77 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The gaschromatographic microreactor technique was used to determine the selectivity of Ni-ZnO catalysts which were prepared by decomposition of the mixed oxalates. While monoalkylcyclopentanes were cracked to a high degree even at 280°-440°, the cyclohexanes were converted to aromatics in good yields at 360°. Increasing the Ni content of the catalysts or further raising the temperatur stimulated the ring cleavage in this case too.
    Notes: Mit Hilfe der gaschromatographischen Mikroreaktor-Technik wurde die Selektivität von Ni-ZnO-Kontakten untersucht, die durch reduzierende Zersetzung der Mischoxalate gewonnen wurden. Die Umwandlung einiger Monoalkylcyclopentane und -hexane zwischen 280° und 440° ergab, daß die Cyclopentane weitgehend gespalten werden. Bei den Cyclohexanen überwiegt bis 360° die Dehydrierung zu Aromaten, wenn der ZnO-Gehalt der Kontakte hoch ist.
    Additional Material: 5 Ill.
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  • 99
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963), S. 90-95 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die thermische Zersetzung der Oxalathydrate von Lanthan (4H2O), Praseodym (4H2O) und Neodym (5H2O) zum betreffenden Oxid verlauft im Gegensatz zu den Oxalaten anderer Seltenerdmetalle über basische Carbonate. Dies wurde durch thermogravimetrische Untersuchungen ermittelt. Für eine intermediare Bildung niederer Hydrate ergaben sich jedoch keine Anzeichen. Nach vollständiger Entwässerung, die bei 350-390 °C erreicht ist, erfolgt eine rasche Zersetzung der wasserfreien Oxalate. Durch eine besondere Zersetzungstechnik wurde erfunden, daß wasserfreies Lanthanoxalat bei 300°C noch stabil ist.
    Notes: Thermal decomposition studies of the oxalate-hydrates of lanthanum, praseodymium and neodymium on a Stanton thermobalance have shown that these form a group, giving stable intermediate products (basic carbonates) before final decomposition t o the oxide. Intermediate weight levels corresponding to lower hydrates have not been obtained. The final stage of dehydration of these oxalates is followed by rapid decomposition, indicating that the anhydrous oxalates are unstable. The mechanism of decomposition of lanthanum oxalate is investigated in detail. modified decomposition procedure on the thermobalance has, however, shown that anhydrous lanthanum oxalate is fairly stable at 300°C.
    Additional Material: 1 Ill.
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  • 100
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 324 (1963) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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