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  • 1970-1974  (400)
  • 1970  (400)
  • Analytical Chemistry and Spectroscopy  (346)
  • Engineering General  (54)
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  • 1970-1974  (400)
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  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 3-3 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 2-2 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 5-32 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The program given here assembles and solves symmetric positive-definite equations as met in finite element applications. The technique is more involved than the standard band-matrix algorithms, but it is more efficient in the important case when two-dimensional or three-dimensional elements have other than corner nodes. Artifices are included to improve efficiency when there are many right hand sides, as in automated design. The organization of the program is described with reference to diagrams, full notation, specimen input data and supplementary comments on the ASA FORTRAN print-out.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 33-43 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In the design of a guyed mast the design specification often imposes limits on the allowable deflection of the mast under wind and other lateral loads. While the deflected form of a mast depends on many different design parameters, the guy erection tensions form one of the simplest means of controlling the lateral displacements. The paper describes a procedure for calculating these tensions in the case of a mast required to have a specified set of displacements under a given set of lateral loads. It also discusses the case where specified deflections are not to be exceeded under a number of different loading conditions.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 45-59 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper is concerned with the development of a computational algorithm for the solution of the uncoupled, quasi-static boundary value problem for a linear viscoelastic solid undergoing thermal and mechanical deformation. The method evolves from a finite element discretization of a stationary value problem, leading to the solution of a system of linear integral equations determining the motion of the solid. An illustrative example is included.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 61-71 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The transient field problem of the type encountered in heat conduction problems is formulated in terms of the finite element process using the Galerkin approach. Curved two-dimensional and three-dimensional, isoparametric elements are used in a time-stepping solution and their advantages illustrated by means of several examples.
    Additional Material: 6 Ill.
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  • 8
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The proposed finite element model is based on separate assumptions of interior and interelement displacements and on the assumed boundary tractions of each individual element. The associated variational functional for this model is presented. This method has the same merits of the assumed stress method (References 3 and 4) in that a compatible displacement function at the interelement boundary can be easily constructed, while it can easily be used for shells with distributed loads.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 117-131 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical method for the analysis of field problems is described. The algorithm is based upon the generalized Betti-Maxwell theorem. Using a set of known solutions to problems with similar boundary conditions produces a set of ‘integral’ equations for the required solution. Using any convenient numerical integration formula reduces the problem to the solution of a set of simultaneous algebraic equations. The accuracy of the solution depends upon the accuracy of the integration formula as applied to the problem under consideration and is independent of the known auxiliary solutions. The method is described in detail as applied to harmonic problems.
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 85-98 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Considerable attention has been devoted in the literature on numerical methods towards securing energy convergence of solutions for, say, linearly elastic plate bending problems. Although energy convergence is necessary it by no means follows that the derived bending moments and shearing forces converge uniformly at a given point and it is this kind of feature which the engineer is really seeking.This question is examined in the context of a problem which is of particular interest to the civil engineering field and concerns the bending of a square plate under uniformly distributed load; the plate has simply supported edges and contains a central square hole with free edges. The solution to this multiply connected and mixed boundary value problem is obtained through a recently developed modification to the Rayleigh-Ritz method which has very general application and renders the solution mathematically valid up to the internal corner points where the bending moments are singular. Use is made of triangular equilibrium finite elements in conjunction with continuous eigenfunctions. Although it is already known that the order (i.e. the eigenvalue) of the singularity at the internal corners is available by inspection, it is an interesting feature of the present solution that a good approximation to the amplitude is also obtained by an inspection of the finite element results.
    Additional Material: 5 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 99-116 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The convergence rates of eigenvalue solutions using two finite plate bending elements are studied. The elements considered are the well-known 12 degree of freedom, non-conforming rectangular element and the 16 degree of freedom, conforming rectangular element. Three problems are analysed, a square plate simply supported on two opposite sides with the other two sides clamped, simply supported, or free. Closed form, finite element solutions for these problems are obtained by using shifting E-operators.With few exceptions, eigenvalue solutions found with the non-conforming element converge from below the exact answers at an asymptotic rate of n-2, where n is the number of elements on a side. However, since the array size needed for such convergence is very large, little can be said about the convergence rates for practical arrays. The conforming element solutions converge from above at an asymptotic rate of n-4. A comparison of the errors involved in using these two elements shows that the conforming element is far superior to the non-conforming element.
    Additional Material: 9 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 145-146 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 146-147 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 133-144 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper presents a labour-saving method of discretizing irregular and inhomogeneous two-dimensional continua into triangular elements. The method uses a magnetic pen to record node point data and a computer program to generate element data. This technique eliminates the tedium in the manual generation of data and the delay due to mistakes which would otherwise arise frequently for a complex mesh.
    Additional Material: 10 Ill.
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  • 16
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 151-157 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A finite element formulation which includes the piezoelectric or electroelastic effect is given. A strong analogy is exhibited between electric and elastic variables, and a ‘stiffness’ finite element method is deduced. The dynamical matrix equation of electroelasticity is formulated and found to be reducible in form to the well-known equation of structural dynamics, A tetrahedral finite element is presented, implementing the theorem for application to problems of three-dimensional electroelasticity.
    Additional Material: 1 Ill.
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  • 17
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 175-188 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical method is presented for the solution of the radially symmetric heat conduction problem in a melting sphere. The method employs the embedding technique; this permits the solution to be written in the form of an ordinary integro-differential equation which is readily solved numerically by means of a forward integration scheme. The accuracy of the method is briefly discussed and numerical results for both constant and variable heat inputs are presented.
    Additional Material: 8 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 159-174 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper is concerned with the development of general discrete models for the analysis of boundary-value problems in the first strain-gradient theory of elasticity. Extensions of the finite element method are constructed for this purpose, and general equations of motion are derived for finite elements of a class of micro-polar materials which are characterized by strain energy functions involving strains and second gradients of strains or displacements. The notion of generalized nodal doublets is introduced. The problem of a composite consisting of a strain-gradient sensitive microlayer embedded between semi-infinite bodies is examined as an example problem. Some of the results are compared with available exact solutions.
    Additional Material: 7 Ill.
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  • 19
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Methods for the analysis of complex, highly redundant structures subjected to intermittent loads causing biaxial membrane stress and stress reversal into the plastic range are presented. The Bauschinger effect in multi-axial stress is taken into account by the use of Ziegler's modification of Pragers kinematic hardening theory. The implementation of this plasticity theory in the discrete element methods involves the application of the loading in small increments. A linear relationship between increments of plastic strain and of stress, arising out of the theory, is used in conjunction with a linear matrix equation that governs the elastic behaviour of the structure. In the latter equation, plastic strains are interpreted as initial strains. A solution to the linear matrix equation, expressed in terms either of stress or of total strain, may be obtained by utilizing one of two alternative procedures. The methods are capable of treating materials which exhibit elastic-plastic behaviour involving ideal plasticity, linear or non-linear strain hardening, or limited strain hardening. Application is made to several representative structures. Comparison of some of the results with existing test data for both monotonic and reversed loading shows good correlation.
    Additional Material: 7 Ill.
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  • 20
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 221-228 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A general digital computer method based on a Sturm sequence procedure is described for determining the natural frequencies and associated modes of undamped free vibration of frames and other structures whose stiffness and mass matrices are of band form. A program which uses the method for the analysis of plane multi-storey building frames is outlined, and numerical results are presented for a simple test case and for a 19-storey frame.
    Additional Material: 2 Ill.
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  • 21
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 207-219 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A newly developed numerical Laplace transform inversion technique is described. A derivation of the method, termed the ‘multidata method’, is presented along with a description of a similar collocation method. Similarities and differences between the two numerical methods are described and discussed. Results of parameter studies of both methods are presented which demonstrate the sensitivity to error displayed by the collocation method and the magnitude of the improvement in accuracy obtainable with the multidata method as compared with the collocation method, especially when errors exist in the function to be inverted.
    Additional Material: 6 Ill.
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  • 22
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 229-241 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this study, finite element solution procedures are developed for an elastica problem of inextensible beams. The element stiffness matrices are obtained by using Galerkin's method. Results of a numerical example compare reasonably well with those obtained by using the elliptical integral.Extensions of this research are currently being made to include membrane effects of beams and to develop plate element stiffness matrices for elastica problems of plate structures.
    Additional Material: 4 Ill.
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  • 23
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 243-252 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This report summarizes an experimental application of the finite element approach to two-dimensional inviscid fluid flow.The method results in a matrix equation relating the vector of velocities at the nodal points with the vector of singularities. The singularities, which are concentrated at the nodes, consist of a source and a vortex.On solution of this equation (defining the flow in the region), boundary conditions must te stipulated. This usually involves setting the internal singularities to zero and making certain modifications ro those lying on the boundary of the region.Some results of the application to a particular problem are included in the paper.
    Additional Material: 6 Ill.
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  • 24
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 253-257 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Some typical results of an extensive series of evaluations of parallelogram-shaped plate bending elements with increasing levels of sophistication are presented. It is shown that, contrary to experience in other fields of stress analysis, this sophistication does not lead to striking improvements in accuracy in the solution of simple rectangular and skew plate problems. A computational procedure is described whereby stiffness matrices may be automatically generated from the minimum of input data specifying the displacement modes prescribed for the element.
    Additional Material: 2 Ill.
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  • 25
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 259-264 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A conforming plate bending solution using simple polynomial deflection functions of third-degree inside each triangular element is presented. In order to avoid normal slope discontinuities along the sides of the elements, the plate displacement parameters are subjected to ‘slope continuity conditions’ acting as constraints to the minimum potential energy problem. This is then solved by the classical method of Lagrange introducing multipliers as new auxiliary variables. If a special variational formulation of the problem is used, it can be shown that the Lagrangean multipliers are generalized stress parameters. The suggested solution is therefore basically a ‘mixed’ solution, the unknown variables of the problem being both displacement and stress parameters. Several numerical results are presented.
    Additional Material: 2 Ill.
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  • 26
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 265-275 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Approximate formulations of non-uniform beam element stiffness matrices for dynamic and elastic instability analysis are derived. Displacement functions for the uniform beam segment are employed in this development. Moment of inertia and area of the element are prescribed by arbitrary powers of the axial co-ordinate. Numerical results are obtained and compared with both analytical solutions and numerical solutions based upon stepped representations using uniform section elements. The significance of the inclusion of taper considerations within individual elements upon solution accuracy and convergence characteristics is also examined. This subject problem and solution approach demonstrates that the upper bound character of minimum energy solutions may be difficult to exploit under practical circumstances.
    Additional Material: 8 Ill.
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  • 27
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 277-282 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This article describes-a new method, suitable for use on a digital computer, for evaluating the singular double integral of Hayes which determines the transonic wave drag of a slender body. Comparison with known exact results and with an earlier computer program described by Eminton shows the present method to be accurate as well as economic in computer time.
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  • 28
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 283-293 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The complementary variational principle has been used to derive the differential equations and the associated boundary conditions of the vibrating plate in terms of bending moments. It is shown that in this formulation, the plate possesses an infinite number of zero frequency modes in which the plate remains in a state of constant strain under a set of self-equilibrating bending moments. In applying the Rayleigh Ritz procedure for the non-zero frequency modes of the plate, it is shown that it the assumed functions are orthogonal to only a finite number of zero frequency modes, then one may obtain frequencies which are lower than the true frequencies of the plate. An iliustrative example is given in the paper.
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  • 29
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 30
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 299-299 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 31
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 301-303 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 32
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 33
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 307-310 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Convergence of a finite element procedure for the solution of the fourth-order equations is proved. A generalization of this result is mentioned and some remarks concerning the numerical results obtained at the Computing Centre of the Technical University in Brno are given.
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  • 34
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 311-333 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Digital filters are finding wide applications in signal processing aspects of such fields as engineering, geophysics and biosignal analysis. The design of a digital filter and its realization with near minima computer word length are two problems which can be solved by computer-aided design techniques In this paper, the automated design of the initial filter (recursive type) only is considered. Both of the basic design methods - the direct and indirect approaches - have been analysed, and compute programs have been written to implement the various design techniques. The present program are limited to the design of flat loss type filters specified by their gain rather than their phase character istics. although provision has been made to allow for other types of design in the indirect approach Design examples are given, and the results analysed with a view to the suitability and limitations of the different design techniques.
    Additional Material: 9 Ill.
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  • 35
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 353-361 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper demonstrates the applicability of general non-linear programming methods to the solution of buckling problems. The minimum energy formulation of the buckling condition is shown to yield an unconstrained non-linear programming problem, for which several numerical methods of solution are readily available. Some of these methods are discussed and numerical results are presented for stiffened plates with in-plane as well as lateral loads.
    Additional Material: 6 Ill.
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  • 36
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 335-352 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Stiffness matrices are formulated for the torsional and lateral stability analysis of structures composed of flexural members by the matrix displacement method. The formulations are based upon approximate displacement fields which represent the action of the element in simple flexure. Example problems, for which exact solutions are known, illustrate the accuracy and convergence characteristics of the derived formulations.
    Additional Material: 8 Ill.
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  • 37
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 363-385 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A solution has been formulated, which allows one to analyse all the major performance characteristics in a chain of impacting elastic ‘rods’. By allowing one end of the elastic chain to impact against a surface which resists penetration according to a specified penetration law it is possible to analyse the impact system of a variety of mechanical devices such as percussive tools and squeeze film dampers. Virtually, unlimited variety in the number and geometry of the impacting rods, and virtually unlimited complexity in the form of the reaction of the terminal face is permitted. A computer program for treating one or two elastic rods has been developed. The program prints out all important stresses as well as the stress history at several selected points. It also prints out the depth of penetration, the energy transferred from rod to rod, the overall energy transfer into the receiver, rebound velocities and times of separation between rods and between rod and 4receiver. Agreement with exact solutions and experiments is demonstrated.
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  • 38
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 387-395 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A technique of differential displacements is presented whereby problems involving elastic contact are solved by the finite element method. The technique is applied to axisymmetric situations in which statically indeterminate conditions occur and is shown to provide a means for resolving these conditions in terms of contact stresses. Three typical engineering problems are analysed to demonstrate the technique in cases where body forces, thermal gradients and external applied forces are acting.
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  • 39
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 415-418 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Recent advances in finite element techniques have enabled full three-dimensional stress analyses to be undertaken. Economy and accuracy can only be achieved simultaneously if the characteristics of the element are understood. Preparatory work is described in which suitable pitching and disposition of brick-type elements are established for the analysis of cylinders.The information derived is put to use in the analysis of a cylinder-cylinder intersection. A favourable comparison is made with an independently computed solution.
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  • 40
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 397-414 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The velocity field of a semi-contained turbulent jet, as constructed by Abramovich, is used to arrive at the temperature distributions in the initial region of a turbulent flow film cooling situation taking into account both the development of the jet boundary layer and the wall boundary layer. After suitable profiles of eddy thermal conductivity are established, a finite difference form of the thermal energy equation is derived, shown to be unconditionally stable, and solved numerically with the aid of an IBM System 360 computer to yield the temperature distributions. Wieghardt's parameter for collapsing the temperature profiles onto a single curve in film cooling situations, when suitably modified, also collapse the analytical results to essentially a single curve even as near as 2·7 slot heights from the injection point, thus verifying the temperature similarity in film cooling which has been experimentally observed even very near the injection point. Results in graphical form are presented which allows one to construct the actual temperature profile for a fairly wide range of the relevant parameters.
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  • 41
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    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 42
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 453-454 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 43
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 419-451 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A general formulation for the curved, arbitrary shape of thick shell finite elements is presented in this paper along with a simplified form for axisymmetric situations. A number of examples ranging from thin to thick shell applications are given, which include a cooling tower, water tanks, an idealized arch dam and an actual arch dam with deformable foundation.A new process using curved, thick shell finite elements is developed overcoming the previous approximations to the geometry of the structure and the neglect of shear deformation.A general formulation for a curved, arbitrary shape of shell is developed as well as a simplified form suitable for axisymmetric situations.Several illustrated examples ranging from thin to thick shell applications are given to assess the accuracy of solution attainable. These examples include a cooling tower, tanks, and an idealized dam for which many alternative solutions were used.The usefulness of the development in the context of arch dams, where a ‘thick shell’ situation exists, leads in practice to a fuller discussion of problems of foundation deformation, etc., so that practical application becomes possible and economical.
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  • 44
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 45
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 495-507 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A finite element method to determine unsteady aerodynamic influence coefficients, consistent with the stiffness and inertia properties of a lifting surface in supersonic flow, is described. This is basically a kinematic method, which reduces the dynamical equations of a non-conservative system to a simple and elegant form. It is illustrated by application to a delta wing using triangular elements to calculate steady and unsteady lift and moment coefficients. Throughout the calculations only a coarse grid system has been employed and the answers have been compared with available results.
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  • 46
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 509-522 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A simple program carrying out various vector operations in two- or three-dimensional spaces is presented. The listings are given in A.S.A. FORTRAN IV. The program is of particular application in various forms of three-dimensional and shell analysis as it can create and transform locally orthogonal co-ordinates, etc. While these applications motivated its design, it is of very general use one such application is illustrated by applying the program to general perspective projection.
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  • 47
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 523-533 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A procedure is presented for the automatic renumbering of network type equations prior to solution by sparse matrix techniques. The method takes an arbitrary input sequence and creates an order which makes possible solution of complex network systems by reducing demand for computer storage and time.Examples are presented to demonstrate the procedure in action and show that, even in cases where the system has been carefully numbered, considerable improvement can be achieved. The procedure is also applicable to band matrix solution techniques.
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  • 48
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 563-577 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper deals with solving two-dimensional variational problems of second- and third-order by the finite element method. To each meshpoint are associated three or six basic functions of class C1 or C2. The expression of the admissible functions on a triangular and rectangular element are given here in a general form which is specially suitable for computation.
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  • 49
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 535-549 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The eigenvalue method is well-known as an aid to the solution of a wide range of engineering problems. In power system analysis it has relevance to travelling wave phenomena,1 sensitivity and dynamic stability in synchronous multimachine2 systems, critical speed calculation, vibration of structures and other related topics. The method of numerical solution of eigenvalues depends on the size and nature of the problem and often where large matrices are involved presents great difficulties.This paper describes in detail the application of the escalator method and diakoptics to large eigenvalue problems. The escalator method is a well-established one which consists of a systematic way of escalating from a 2 × 2 matrix up to any desired order in steps of one row and column at a time. The diakoptical method reduces computer storage, calculation time and improves accuracy. This results in the more economical solution of large and complicated problems which cannot be conveniently solved by any orthodox method. The paper deals with problems of degeneracy and means of overcoming these by simple routine processes. It concludes by indicating the particular advantages of the method and its usefulness for a wide variety of general engineering problems.
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  • 50
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 597-600 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In any mesh, rules exist that interrelate the number of internal and external sides, vertices, etc. and the total number of elements. These are given explicitly for plane meshes of triangles and quadrilaterals, and for solid meshes of tetrahedra and cuboidal elements. The method is quite general and discovers all such independent rules that exist. Thus, for a plane mesh of T elements having Vi internal and Vb boundary vertices and Si internal and Sb boundary sides, then \documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{l} T = \frac{1}{3}\left({S_b + 2S_i} \right) = V_b + 2V_i + 2H - 2\quad{\rm (for\,triangular\,elements)}\\ T = \frac{1}{4}\left({S_b + 2S_i} \right) = \frac{1}{2}\left({V_b + 2V_i} \right) + H - 1\quad{\rm (for\,quadrilateral\,elements)} \\ \end{array} $$\end{document} where H is the number of internal boundaries (holes) there might be. For solid meshes, these two-dimensional equations relating elements to sides generalize to \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} T = \frac{1}{6}\left({F_b + 2Fi} \right){\rm\quad (for\,cuboid\,elements)} \\ T = \frac{1}{4}\left({F_b + 2Fi} \right){\rm\quad (for\,tetrahedral\,elements)} \\ \end{array} $$\end{document} where there are Fb boundary and Fi internal faces. Unfortunately, there is no direct generalization of the two-dimensional equations relating vertices and elements: it is only possible to do this by including the Ei internal and Eb boundary edges: \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} T = \frac{1}{8}E_b + \frac{1}{2}\left({E_i - V_i + H - h - 1} \right){\rm\quad (for\,cuboid\,elements)} \\ T = \frac{1}{3}E_b + E_i - V_i + H - H - 1{\rm\quad (for\,tetrahedral\,elements)} \\ \end{array} $$\end{document} where there are H through holes and h cavities.
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  • 51
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 459-476 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The stiffness equation is derived for curved elements of orthotropic axi-symmetric thin shells, and equivalent applied loads are found for shells subjected to initial strains, applied surface loads and body forces. The Lure approximation of thin shells and displacement field approximation by polynomials of arbitrary degree are included in the formulae derived.
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  • 52
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 477-494 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A computational procedure based on gradient iterative techniques is proposed for the solution of large problems to which the finite element method is applicable. In linear problems the procedure can be used either for solving the set of algebraic equations or for the complete inversion of the matrix of coefficients. Special attention is focused on the practical aspects of the procedure concerning its realization on the digital computer.
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  • 53
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 551-561 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A novel integral equation technique is employed for the analysis of dynamic stability problems. The governing equation of the linearized parametric resonance problem is transformed into an integral equation. The kernel of the integral equation is computed as the influence function for the deflection and/or bending moment of a corresponding beam.The highest derivative of the governing function (in our case fourth derivative of the displacement function) is chosen as the basic unknown. Using the formal analogy with the differential equation of the beam flexure this highest derivative is comprehended as some unknown transverse ‘load’. The distribution of this ‘load’ is a priori assumed to be polygonal. Using elementary methods of structural analysis, the displacements due to the assumed ‘load’ are determined. These displacements, arrayed into a square matrix, approximate the kernel of the governing integral equation.The subsequent procedure via Hill's determinant is a conventional one. The results prove to be accurate enough even for a very modest number of points of integration. This reflects the fact that the method is based on numerical integration rather than on numerical differentiation.
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  • 54
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 579-595 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The feasibility of achieving a preassigned stress state by changing the stiffness of determinate and indeterminate pin connected structures is presented. A new force method with all element forces (or stresses or areas) as independent variables is developed. The possibility but futility of getting the element areas by inverting and pre-multiplying the coefficient matrix with the external load vector when areas are chosen as variables is shown. The relationship existing between the compatibility equations and the plastic strength of pin connected structures is illustrated. Possible design methods for trusses under single or multiplicity of load conditions, the design of truss geometry and the relations between fully stressed and minimum weight structures are examined and illustrated through several examples.
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  • 55
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    Biological Mass Spectrometry 3 (1970), S. 399-401 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Some of the observed fragmentation reactions of long-chain aliphatic methoxyesters necessitate the interaction of both functional groups, even when these are located far apart: both alcohol eliminations from the ion formed by α-cleavage to the ether function which contains the ester group are highly specific: they involve a hydrogen atom in the position adjacent to the methoxyl-bearing carbon.
    Notes: Certaines des fragmentations des méthoxyesters aliphatiques à longue chaíne nécessitent l'interation des deux fonctions: les deux éliminations d'alcool que subit l'ion par rupture en α de la fanction éther et comprenant le groupe ester, sont trés spécifiques: elles mettent en cause un atome d'hydrogéne en position adjacente au carbone qui porte le groupe méthoxyle.
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  • 56
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    Biological Mass Spectrometry 3 (1970), S. i 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 57
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    Biological Mass Spectrometry 3 (1970), S. 455-477 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The technique of ion kinetic energy spectroscopy has been applied to the study of the aromatic hydrocarbons benzene, toluene, naphthalene, 2-methyl naphthalene, biphenyl and anthracene. The method is illustrated by a complete study of naphthalene in which transitions of metastable doubly- and singly-charged ions are listed, including reactions in which singly-charged ions are formed by collision induced charge-exchange reactions of doubly-charged ions and by the double process of charge-exchange and metastable decomposition with loss of one or two hydrogen atoms. Decompositions of doubly-charged ions into two singly-charged ions, together with the kinetic energies released in these decompositions, are also given for all the compounds studied.
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  • 58
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass spectra of 3-phenylnitropropane and of its analogues, specifically deuterated in the aliphatic chain and in the phenyl ring, show that the molecular ion loses a molecule of water in two different modes, viz. either with both α-hydrogen atoms or with a γ- and an ortho-hydrogen atom. Moreover, a molecule of nitric oxide is eliminated from the molecular ion and the resulting [M - NO]+-ion appears to decompose further in many complicated ways. This loss of nitric oxide does not arise from an isomerization of the nitro group to a nitrite group, because the [M - NO]+-ion of 3-phenylpropyl nitrite breaks down in an altogether different manner than that of 3-phenylnitropropane. This is demonstrated by the spectra of specifically deuterated analogues of 3-phenylpropyl nitrite.
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  • 59
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectral fragmentation of some maleimides, isomaleimides, bis-maleimides, bis-isomaleimides and diazatetracyclotetraones (intramolecular photocyclization products of bis-maleimides) have been investigated. The elimination of carbon dioxide from the molecular ions of these compounds is not generally an important process. Fragment ions arising from the transfer of one or more hydrogen atoms from the eliminated to the charge retaining moiety (and vice versa) are prevalent and the variation in fragment ion intensity with changes in structure is consistent with the mechanisms of the analogous fragmentations of succinimides established by Djerassi's group. The apparently unusual fragmentations of the diazatetracyclotetraones may be rationalized on the basis that the molecular ion consists of three or more different species.
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  • 60
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    Biological Mass Spectrometry 3 (1970), S. 549-555 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of the C3 to C9 n-alkanals and a number of branched aldehydes have been obtained at a resolution sufficient to resolve the O—CH4 doublets. From the resolved spectra, a study of metastable transitions, and the spectrum of one deuterium-labelled alkanal, (n-hexanal-2,2-d2) the major fragmentation reactions have been elucidated. Of particular interest are the γ-cleavage reaction, leading to [C3H5O]+ in the n-alkanals, which proceeds both by a simple cleavage and by cleavage preceded by hydrogen interchange, and the loss of C2H4, which involves loss of the C2 and, probably C3, carbons.
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  • 61
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The molecular ion of hydrocinnamaldehyde (C6H5CH2CH2CHO) chiefly loses fragments C2H2O and C3H4O. Mass spectra of specifically deuterated analogues show that in the loss of C2H2O an α-hydrogen atom (with respect to the aldehyde group) is transferred to the aromatic part. A shift of the aldehydic hydrogen to one of the ortho positions of the phenyl ring and loss of C2H2O by a McLafferty rearrangement is not observed.In the loss of C3H4O also an α-hydrogen atom migrates to the aromatic part. Both reactions appear to occur with an extensive randomization of all hydrogen atoms in the molecular ion.
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  • 62
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    Biological Mass Spectrometry 3 (1970), S. 321-331 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of some 14,15-deoxymeliacins are reported and discussed in relation to the previously published fragmentation patterns of the epoxymeliacins. The fragmentation patterns of a few compounds with structures closely related to those proposed for the principal ions in the spectra of the epoxymeliacins are also examined.
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  • 63
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The [CH3O=CHCH3]+ ions observed in the mass spectra of ethers of formula CH3OCH (CH3)R(R = H or alkyl) undergo two rearrangement fragmentation reactions to form [C2H5]+ and [CH2OH]+. The scope of the rearrangements has been investigated and it is shown that enlargement of the alkyl group on either side of the ether linkage leads to alternative fragmentation routes. From a study of metastable intensities it is concluded that the fragmentations probably occur directly from the [CH3O=CHCH3]+ structure through four centred rearrangements rather than through the intermediacy of the [C2H5O=CH2]+ ion.
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  • 64
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    Biological Mass Spectrometry 3 (1970), S. 661-668 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The transition, [C12H10]+3→[C11H7]+2 + [CH3]+, has been detected both in the ion kinetic energy spectrum and in the mass spectrum of biphenyl. The width of a resulting ‘metastable peak’ has been measured by setting the magnetic field to accept [C11H7]+2 ions and scanning the high voltage at fixed electric sector voltage. The kinetic energy released in the decomposition, calculated from the peak width, amounted to 4.5 eV. With the assumption that this energy release is due entirely to charge separation, the charge distribution in [C12H10]+3 is discussed. The derivation of the equations used to calculate the energy released is given in the Appendix.
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  • 65
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of hexanal, heptanal and nonanal variously labeled with deuterium confirm γ-hydrogen migration and β cleavage as the mechanism leading to [C2H4O]+· and [M — C2H4O]+·, although the data on the latter are complicated by contributions from other, related paths. In addition, they show that three other major primary decomposition products, [M — C2H4]+·, [M — H2O]+· and [C3H5O]+, all arise in large part by processes involving γ-hydrogen migration to the oxygen atom. The ethylene lost to yield the first of these products consists of the α and β methylene groups. The loss of ethylene most likely occurs by way of a cyclobutanol intermediate, which, via alternative reaction paths, may well contribute to the yields of the other two products as well. These findings further extend the range of parallelism between photochemical and electron-impact-induced reactions.
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  • 66
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    Biological Mass Spectrometry 3 (1970), S. 969-969 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 67
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    Biological Mass Spectrometry 3 (1970), S. 993-1007 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of o-nitrobenzoic acid, o-nitroanisole, o-nitrosobenzoic acid, o-nitrobenzamide, o-nitrobenzyl alcohol and o-nitrosobenzaldehyde have been studied. Fragmentation mechanisms are proposed for the above compounds; their elucidation was aided by isotopic labeling with D and O18. Two ‘ortho-effects’ are discussed; one involving H atom transfer between substituents and the other migration of an atom or group to a charge carrying vacant ortho position. The importance of nitro to nitrite conversion in molecular and fragment ions is discussed.
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    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of diethyl and diphenyl N-phenylphosphoramidate are reported. Their electron-impact behavior is similiar to that observed for the corresponding phosphate esters. High resolution mass measurements are used to confirm the elemental composition of all the peaks in the spectra. Some interesting rearrangement fragments are observed in the spectrum of the diphenyl N-phenylphosphoramidate ester.
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  • 69
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    Biological Mass Spectrometry 3 (1970), S. 1055-1066 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electron-impact mass spectra and the field ionization mass spectra of 1-chloro-2-nitrosocyclohexane and 1-chloro-2-nitrosocyclopetane are presented and discussed. The two compounds investigated exist in dimeric form in the gaseous phase.
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  • 70
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectrum of valeraldehyde o-nitrophenylhydrazone displays only a low intensity peak (3% relative abundance) corresponding to the loss of 35 mass units from its molecular ion contrary to data previously published. Mention is also made of the fragmentation of 5-nonanone 2,4-dinitrophenylhydrazone in view of a recent challenge to a published rationalization for the electron impact promoted fragmentation for this compound.
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  • 71
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    Biological Mass Spectrometry 3 (1970), S. 1457-1461 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
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  • 72
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    Biological Mass Spectrometry 3 (1970), S. 1467-1469 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The most abundant fragment produced by electron bombardment of esters of the type R1R2C(OR3)CO2R4 is the R1R2C = \documentclass{article}\pagestyle{empty}\begin{document}$ \mathop {\rm O}\limits^{{\rm + } \cdot } $\end{document}R3 ion. Methyl glycollate (R1 = R2 = R3 = H, R4 = Me) eliminates the HCO· radical by a complex rearrangement involving the methylenic hydrogen atoms. The methyl and ethyl esters of methoxyacetic acid (R1 = R2 = H, R3 = Me, R4 = Me or Et) eliminate formaldehyde by the McLafferty rearrangement.
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  • 73
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The characteristic mass spectral fragmentation patterns of the basic structure of the steroidal sapogenin, (25R)-5α-spirostan, have been elucidated through the preparation of analogs with deuterium labels at positions 11, 12, 14, 15, 16, 17, 20, 21, 23, 24, 25, 26 and 27. In addition, the effects of a change of stereochemistry at positions 14 and 20, of the introduction of oxygencontaining functionalities mostly in ring F, and of the incorporation of olefinic unsaturation have been determined through synthesis of many examples.
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  • 74
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    Biological Mass Spectrometry 3 (1970), S. 1233-1237 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of the tetraphenylcyclobutadiene complexes (C6H5)4C4Fe(CO)3, C5H5CoC4(C6H5)4 and C9H7CoC4(C4H5)4 are reported. Evidence is presented for the loss of the tetraphenylcyclobutadiene ring by a two-step sequence involving successive losses of two (C6H5)2C2 fragments. Significant differences are observed in the fragmentations of the monopositive and dipositive molecular ions of C9H7CoC4(C6H5)4.
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  • 75
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    Biological Mass Spectrometry 3 (1970), S. 1293-1305 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of three groups of tanshinones have been examined and a number of characteristic features noted which might be helpful in the micro-identification of the natural products. The fragmentation patterns are similar to each other except for the relative intensity within the same group of tanshinones and are accounted for in terms of the general fragmentations of furans and quinones. Characteristic ions at m/e 178, 165 and 152 found in all kinds of tanshinones may be considered to be of highly aromatized hydrocarbon fragments and are of good for the structure elucidation of these compounds.
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  • 76
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    Biological Mass Spectrometry 4 (1970), S. 17-39 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A system is described in which a medium-sized double-focusing mass spectrometer is coupled on-line to a small (4K memory words) computer. The system can produce complete elemental composition data within two minutes after the completion of the mass spectral scan.The inherent speed of the processor and memory sub-systems is effectively retained through the utilization of a low-cost random-access bulk-storage device and other high-speed peripherals.An attempt is made to define both the theoretical and practical considerations necessary in utilizing a small digital computer as an integral part of a chemical experiment, specifically as applied to high-resolution mass spectrometry. Important aspects include the interaction of resolution and errors of mass measurement, the contribution of noise to observed errors, the effect of peak shape on such errors, the techniques of analog and digital signal processing, the criteria of efficient system design and the fundamental validity of applying a mathematical model, such as the centroid, to a basically statistical situation.The centroid method of calculating peak centers is shown to be fundamentally correct and the resultant error due to statistics diminishes in absolute value as the peak width decreases, that is, as the resolution increases, errors being approximately one-half as large at R = 10,000 as those at R = 2200. The overall mass measuring accuracy has been investigated at resolutions up to R = 10,000 using several different organic compounds and has been shown to be about 12 ppm for a single scan. Multiple scan averaging reduces this error by approximately the square root of the numbers of scans.
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  • 77
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    Biological Mass Spectrometry 4 (1970), S. 237-240 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper describes the mass spectra of some di-trimethylsilyl derivatives of aromatic amines. Numerous doubly-charged ions of low relative intensity are found in all spectra. An intense doubly-charged ion is found at m/e [M - 30]/2, whereas the singly-charged counterpart is very small in all cases.
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  • 78
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    Biological Mass Spectrometry 4 (1970), S. 229-235 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A study has been made of the spectra of a series of compounds containing both a styryl and a benzoyl π-electron system separated by one to four methylene groups. Of particular interest is a fragmentation process which involves both functional groups, yet only proceeds when they are separated by at least four methylene units.
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  • 79
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    Biological Mass Spectrometry 4 (1970), S. 249-256 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of nine pyrrolizidine alkaloids retronecine, heliotridine, 7-angeloylretronecine, 7-angeloylheliotridine, echimidine, heliosupine, lasiocarpine, heliotrine and echinatine -  were studied. Particularly the structures of the ions m/e 214, 197 and 156 in the spectrum of heliotrine are discussed. The ionization and appearance potentials for selected ions were measured for the first six alkaloids, which are pairs of epimers.
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  • 80
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    Biological Mass Spectrometry 4 (1970), S. 299-313 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A number of impurities have been extracted from yellow phenolphthalein by thin layer chromatography and characterized on the basis of their mass spectra. One of these by-products appears to be fluoran while the structure proposed for a second accounts for the properties ascribed to it by previous investigations. The bulk of the impurity appears to consist of condensation products of three molecules of phenol with two of phthalic anhydride.
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  • 81
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The influence of source temperature on the mass spectra of eight ketones with the formula CH3—CO—CnH2n+1(n = 3,4,5)have been studied. By a simple treatment we have determined: (1)the approximative amplitude of the activation energies (we have observed the activation energies in the increasing order: the fragmentation leading to the ion [M - CH3], the McLafferty rearrangement and the α cleavage giving the ion [M - CnH2n+1]); (2) the ions giving raise to important secondary decompositions (in particular), the [M - CH3] ions coming from the α cleavage; (3) the fragmentations having a low activation energy and a low frequency factor (mainly the ions [M - CH3] which are issued from the γ and δ cleavages); (4) the influence of the effective number of oscillators on the fragmentation process.
    Notes: Nous avons étudié l'influence de la température de source sur le spectre de masse de huit cétones de formules CH3—CO—CnH2n+1 (n = 3,4,5). L'utilisation d'un traitement simple nous a permis de mettre en évidence: (1)l' ordre de grandeur des énergies d'activation (ainsi, par ordre d'énergie croissante nous avons la rupture en α, conduisant à l'ion [M - CH3], le réarrangement de McLafferty et la rupture en α donnant l'ion [M - CnH2n+1]); (2) les ions donnant lieu à des décompositions secondaires importantes (notamment les ions) [M - CH3] issus de la rupture en α; (3) les ruptures avant une énergie d'activation et un facteur de fréquence faibles (essentiellement les ions [M - CH3] issus des ruptures en γ ou δ); (4) l'incidence du nombre d'oscillateurs effectifs sur le processus de fragmentation.
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  • 82
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    Biological Mass Spectrometry 4 (1970), S. 383-393 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A mass spectrometric examination of five homoannularly chlorinated ferrocenes of the general formula (C5H(5-n))Fe(C5H5) where n = 1 to 5 (Series 1), and five heteroannularly chlorinated ferrocenes of the general formula (C5H(5-n)Cln)2Fe where n = 1 to 5 (Series 2) has been made. This study affords the first look at the mass spectral results of incremental additions of the same substituent up to the ultimate replacement of all hydrogens in the ferrocene molecule. The molecular ion is the most intense peak in both series. The primary fragmentation processes are, for Series 1: [M - FeCl2], [M - C5H(5-n)Cln], [M - C5H5] and [M - HCl]; and for series 2: [M - FeCl2] and [M - C5H(5-n)Cln]. The [M - FeCl2]+. peak is speculatively attributed to a fulvalene derivative. A heteroannular pathway is proposed for HCl elimination. Significant [Fe]+. and [FeCl]+ peaks occur in all compounds. In all compounds having three or more hydrogens on one ring, a peak due to [C3H3]+ is seen. Metastable studies, precise mass measurements and isotopic abundance ratios of chlorine were used to confirm many of the fragmentation processes.
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  • 83
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    Biological Mass Spectrometry 4 (1970), S. 165-174 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We report the mass spectra of a series of O-alkyl-N-p-toluenesulfonyl carbamates with the following alkyl substituents: methyl, ethyl, n-propyl, isobutyl, neopentyl, β-phenethyl, isopropyl, sec-butyl, cyclohexyl, α-phenethyl, tert-butyl and tert-amyl. The fragmentation of the primary and secondary alkyl substituents involves a rearrangement accompanied by the loss of SO2 followed by fragmentation of the [M - 64] radical-ion to produce cresol as one of the principal fragments. The [M - 64] fragment of branched alkyls also undergoes a McLafferty rearrangement to yield either O-p-tolyl carbamate or N-p-tolyl carbamic acid and the corresponding olefin. In contrast, O-tert-alkyl-N-arylsulfonyl carbamates yield fragmentation patterns similar to those observed for N-tert-alkyl arylsulfonamides. The spectrum of O-tert-butyl-N-p-methoxybenzenesulfonyl carbamate exhibits strong [M - 44] and [M - 59] peaks which correspond to the loss of CO2 followed by a methyl radical from the molecular ion. Introduction of methyl groups either to the sulfonyl carbamate nitrogen atom or the ortho positions of the aryl substituent of O-tert-butyl derivatives forces the molecular ion to rearrange with a loss of SO2 instead of CO2.
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  • 84
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    Biological Mass Spectrometry 4 (1970), S. 195-201 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fragmentation of six and eight membered methyl substituted cyclocarbosiloxanes of general formula (CH3)6Si3O3 — n(CH2)n (n = 1 or 2) and (CH3)8 Si4O4-n(CH2)n (n = 1, 2 or 3) under electron-impact (70 eV) is reported. The behaviour of these compounds under electron-impact is intermediate between that of the corresponding cyclosiloxanes and cyclocarbosilanes. In every case the most intense singly and doubly charged ions correspond to the loss of one and two methyl groups respectively. In going from the cyclosiloxanes to the cyclocarbosilanes the intensity of the primary ions is reduced and the intensity of those fragment ions whose formation involves the rearrangement or breakdown of the cyclic framework of the molecule is increased. These ions are the [M —CH3—(CH3)4Si]+ ions in the eight membered and the [(CH3)3Si]+ ions in both cases. The data on doubly charged and metastable ions in the mass spectra of the cyclocarbosiloxanes are presented and discussed.The fragmentation of six and eight membered methyl substituted cyclocarbosiloxanes of general formula (CH3)6Si3O3 — n(CH2)n (n = 1 or 2) and (CH3)8 Si4O4-n(CH2)n (n = 1, 2 or 3) under electron-impact (70 eV) is reported. The behaviour of these compounds under electron-impact is intermediate between that of the corresponding cyclosiloxanes and cyclocarbosilanes. In every case the most intense singly and doubly charged ions correspond to the loss of one and two methyl groups respectively. In going from the cyclosiloxanes to the cyclocarbosilanes the intensity of the primary ions is reduced and the intensity of those fragment ions whose formation involves the rearrangement or breakdown of the cyclic framework of the molecule is increased. These ions are the [M — CH3—(CH3)4Si]+ ions in the eight membered and the [(CH3)3Si]+ ions in both cases. The data on doubly charged and metastable ions in the mass spectra of the cyclocarbosiloxanes are presented and discussed.
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  • 85
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    Biological Mass Spectrometry 4 (1970), S. 241-248 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass spectra of cyclopenin (I), viridicatin (III), 3-benzylidene-3,4-dihydro-4-methyl-1H-1,4-benzodiazepin-2,5-dione (VI) and derivatives of these systems were measured. Fragmentation schemes are proposed based on high resolution data, metastable peaks and, where appropriate, on deuterium labeling. The decomposition of I is found to follow pathways different in several respects from those proposed by Luckner et al. on the basis of low resolution spectra.
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  • 86
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    Biological Mass Spectrometry 4 (1970), S. 373-382 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of twenty-seven C-19 modified cholestane derivatives have been determined, and have been compared with the mass spectra of similar compounds reported1 in the cholesteryl series. In the spectra of 2α,19-dihydroxy-5α-cholestane (la), initial loss of the 10β-hydroxymethyl group was observed followed by loss of water, whereas with the 2α-methoxy and 2α-acetoxy derivatives (Ib, Ic), loss of the 2α-substituent as methanol and acetic acid respectively, preceded the elimination of the 10β-hydroxymethyl group. Loss of the 10β-hydroxymethyl group was also observed in Δ1-, Δ2- and 2-oxo derivatives (VI, Va and VII), whilst loss of both the 1 substituent and the 10β-hydroxymethyl group from the molecular ion was observed with the 1α-ol (IIa) and the 1β-yl-chloride (III).In a series of 19-acetoxy derivatives loss of acetic acid [M - 60] from the 19-acetoxy group, involving abstraction of a sterically favourable hydrogen, always occurred, although this was usually accompanied by loss of the 10β-acetoxymethyl residue [M - 73].The mass spectra of a series of 10β-carboxylic acids and their methyl esters were more complex with three or more fragmentation patterns being observed. 1,3-Diaxial interactions, similar to those observed in chemical reactions, were observed in the mass spectra of three 2β-oxygenated-19-substituted compounds.
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    Biological Mass Spectrometry 4 (1970), S. 513-517 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The negative-ion mass spectra of some pyridines, pyrazines and their N-oxides are reported. All of the compounds examined fragment by generation of CN- ions. The alkylated derivatives readily form [M - 1] anions. Most of the N-oxides yield O- and OH- ions. Polar substituents control the fragmentation processes involving the heterocyclic ring to which they are bonded.
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  • 88
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electron-impact induced fragmentation of four N,N′-di-t-alkyl-substituted diaziridinones (I to IV) has been studied by both conventional and high resolution mass spectrometry. All diaziridinones exhibit weak molecular ions. Ejection of an alkyl isocyanate, corresponding to the N-alkyl substituent, from the molecular ion, is a dominant and general fragmentation process. Isocyanate-type odd-electron fragment ions occur only in III and IV (where at least one R group is phenyl) and are of low abundance. Elimination of a hydrocarbon radical from the tertiary alkyl substituents is observed in all compounds investigated. McLafferty rearrangement with elimination of a neutral alkene occurs in all compounds. Abundant even-electron hydrocarbon ions corresponding to the mass of the N-alkyl substituent are prevalent. The complete absence of elimination of carbon monoxide is noted. Loss of oxygen from the [M — RCH2]+ species has been confirmed by accurate mass measurement. Several remarkable rearrangement reactions have been uncovered by high resolution studies and deuteration experiments.
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  • 89
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The fragmentation pattern of metal complexes of 2-butyl-8-hydroxyquinoline depends essentially upon the ability of the metal ion to absorb an electron, i.e. to exist in a stable monovalent form. In this case the main fragment is formed by loss of a molecule of 2-n-butyl-8-hydroxyquinoline, otherwise an ethyl radical is eliminated.
    Notes: Das Fragmentierungsmuster der Metallkomplexe des 2-Butyl-8hydroxychinolins hängt im wesentlichen davon ab, ob das Metall-Ion unter Aufnahme eines Elektrons in eine stabile einwertige Form übergehen kann oder nicht. Im ersten Fall entsteht das Hauptfragment durch Verlust eines Moleküls 2-n-Butyl-8hydroxychinolin, im zweiten durch Abspaltung eines Äthyl radikals.
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  • 90
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    Biological Mass Spectrometry 3 (1970), S. 1085-1088 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The use of bisulfite derivatives of liquid aldehydes and cyclic ketones is reported to facilitate sample handling in mass spectral analysis of these compounds. The carbonyl compounds can be regenerated from their sulfinate derivatives in the direct probe. Precautions must be taken to avoid back exchange of enolizable deuterium atoms in labeled carbonyl compounds.
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    Biological Mass Spectrometry 3 (1970), S. 1097-1097 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 92
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    Biological Mass Spectrometry 3 (1970) 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 93
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The mass spectra of stereoisomers of polymethoxy cycloalkanes depend on the geometry of the molecular ions. The magnitude of the stereochemical effect is influenced by the stability of the cyclic molecular ions. Due to energetically favourable ring-fragmentations the effect is cancelled by vicinal methoxy substituents and diminished by a methyl group next to a methoxy substituent.Stereochemically controlled fragmentations are the eliminations of a methoxy group in the form of a methanol or formaldehyde molecule from the molecular ions. By an investigation of di- and trimethoxy cyclohexanes, specifically labelled with deuterium, it is shown that both reactions are initiated by a transfer of an H-atom from a carbinol-C-atom to an O-atom of a methoxy group. Whether or not these energetically favourable reactions will occur depends on how close the H- and O-atoms involved can approach each other in the possible conformations of the molecular ion.The stereochemical control of the fragmentation of 1,3-dimethoxy cyclopentane, containing a more or less fixed five membered ring is small, that of dimethoxy cycloheptanes with a flexible seven membered ring is of comparable magnitude as the steric effect in the mass spectra of cyclohexane derivatives.
    Notes: Ein Vergleich der Massenspektren von Stereoisomeren der Polymethoxycycloalkane läßt eine deutliche Abhängigikeit von der Geometrie der Molekül-Ionen erkennen. Die Größe des stereochemischen Effekts wird beeinflußt von der cyclischen Molekü-Ionen. Wegen energetisch günstiger Ringspaltungen wird der Effekt durch vicinale Methoxysubstituenten aufgehoben, durch Methylsubstituenten benachbart zu Methoxygruppen vermindert.Die wichtigsten steeochemisch kontrollierten Fragmentierungen sind Elilminierung einer Methoxygruppe als Methanol- oder Formaldehydmolekül aus den Molekü-Ionen. Durch Untersuchung spezifisch mit Deuterium markierter Di- und Tri-methoxycyclohexane wird gezeigt, daß beide Reaktionen mit der Übertragung eines leicht abspaltbaren H-Atoms von einem Carbinol-C-Atom an das O-Atom einer Methoxygruppen beginnen. Der Eintritt beider energetisch günstiger Reaktionen hängt davon ab, ob in den möglichen Konformationen der Molekül-Ionen eine hinreichende räumliche Annäherung der beteiligten H- und O-Atome möglich ist.Die Stereochemische Kontrolle der Fragmentierung von 1,3-Dimethoxycyclopentan mit dem wenig beweglichen Fünfring ist gering, die der Fragmentierung von Di-methoxycycloheptanen mit dem flexiblen Siebenring ist von vergleichbarer Größe wie der sterische Effekt in den Massenspektren von Cyclohexanderivaten.
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    Biological Mass Spectrometry 3 (1970), S. 1215-1217 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Examination of the mass spectra of several 3-arylpropionic acids and methyl esters showed that one of the major fragmentation processes corresponded to the expulsion of a molecule of formic acid or methyl formate directly from the molecular ion.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 95
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 1223-1224 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Evidence is adduced from steric effects on relative intensities that the [YC6H6N]+ ions from substituted acetanilides have the aniline structure.
    Additional Material: 1 Tab.
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  • 96
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 1227-1232 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The positive ion mass spectra of the π-pyrrolyl derivatives C4H4NMn(CO)2L (L = (C6H5)3E or CO; E = P, As, or Sb), the π-indenyl derivatives C9H7Mn(CO)2L (L = (C6H5)3E or CO; E = P, As, or Sb) and the π-fluorenyl derivatives C13H9Mn(CO)2L (L = (C6H5)3P or CO) have been investigated. The relative tendencies of ions of the type [QMnE(C6H5)3]+ (Q = π-pyrrolyl, π-indenyl, or π-fluorenyl; E = P, As, or Sb) to fragment by losses of the Q ring system and the (C6H5)3E ligand are compared. Phenyl transfers from phosphorus, arsenic, or antimony to manganese to form relatively high abundances of [C6H5Mn]+ are also observed. Other processes typical of metal carbonyl derivatives (CO losses), aromatic derivatives (C2H2 eliminations) and (C6H5)3E derivatives (phenyl losses, conversion of [(C6H5)3E]+ directly to [C6H5E]+, and formation of [C12H8E]+ 9-heterofluorenyl ions) are observed in these mass spectra and are supported in many cases by the presence of appropriate metastable ions.
    Additional Material: 3 Tab.
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  • 97
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 23-29 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Many reports on the mass spectra of organotransition-metal complexes have appeared in recent years,1 whilst there have only been a few reports on the mass spectra of transition metal olefin complexes, some metal carbonyl olefin complexes234 and π-cyclooctenyl-π-cyclooctadienyl cobalt.5 Recently fragmentation paths of π-cyclopentadienyl-cyclooctadiene rhodium were elucidated by King.6 The present authors found metastable ions in the mass spectra of π-cyclopentadienyl-diene cobalt complexes as well as in the mass spectra of π-cyclopentadienyl-diene rhodium complexes.7.In the present paper the authors wish to report the mass spectra of several π-cyclopentadienyl diene cobalt complexes.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 98
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The expulsion of a bromine atom from the molecular ion of β-bromoethyl benzoate displays a kinetic behavior which resembles that of a rearrangement reaction. The two oxygen atoms in the resulting [M — Br]+ ion become equivalent before or during the secondary decomposition of this ion, as shown by oxygen labeling. In addition, the primary ions generated from benzophenone ethylene ketal and acetophenone ethylene ketal by phenyl and methyl expulsion, respectively, undergo subsequent fragmentation in the same way as the [M — Br]+ from β-bromoethyl benzoate. These results strongly indicate that the carbonyl-oxygen atom participates in the expulsion of bromine. The effect of ring substituents on the competing loss of bromine and McLafferty rearrangement is also discussed.
    Additional Material: 1 Tab.
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  • 99
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of six phenanthro(9,10-d)-oxazoles, thiazoles and imidazoles are reported. The decompositions of the phenanthro(9,10-d) derivatives resemble the corresponding benzo heterocycles. A C13H7 fragment was found to be characteristic of these phenanthro compounds. Deuterium labeling was used to show that there is no correlation between the formation of the C13H7 from the phenanthro compounds and the C13H9 observed in the spectra of 4,5-diphenyl substituted heterocycles.
    Type of Medium: Electronic Resource
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  • 100
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass spectra of some selenides, sulphides and ethers of furan, thiophene and selenophene series are described. A new fragmentation reaction, consisting in splitting off alkyl, insertion of heteroatom in the cycle and loss of one of heteroatoms as C=X, is discussed in detail.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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