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  • 1985-1989  (540)
  • 1985  (540)
  • Engineering General  (422)
  • Physical Chemistry  (118)
  • 201
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 265-269 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The reactivity of tert-butoxy radicals with methyl substituted aromatic compounds is almost exclusively determined by the aromatic moiety and almost independent of the methyl group position. The hydrogen abstraction from the carbon α to the aromatic ring is hardly sensitive to the produced radical stabilization. This lack of dependence can be explained in terms of the large exothermicity of the process.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 202
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 303-313 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Rate coefficients for OH reactions with the 2-5 carbon aliphatic aldehydes have been measured under pseudo first-order conditions in OH. OH was generated by flash photolysis of H2O at wavelengths greater than 165 nm and its concentration monitored using time-resolved resonance fluorescence spectroscopy. Two reactions were studied only at 298 K while five reactions were studied over the temperature range 250-425 K; negative activation energies were observed for all five reactions. Aldehyde reactivity toward OH is nearly independent of the identity of the hydrocarbon side chain. Our results are compared with those obtained in previous studies of OH-aldehyde reaction kinetics and their mechanistic implications are discussed.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 203
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 327-335 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: New determinations of the disproportionation and combination ratios between CF2H and C2H5 radicals yield (the hydrogen acceptor radical is given first) Δ(CF2H, C2H5) = 0.068 ± 0.008, and Δ(C2H5, CF2H) = 0.37 ± 0.01. A reevaluation of the existing data on CFH2 and CF3 radicals leads to the following recommended values, Δ(CFH2, C2H5) = 0.038 ± 0.006, and Δ(CF3, C2H5) = 0.11 = ± 0.02.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 204
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 337-343 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The gas-phase eliminations of several tert-butyl esters, in a static system and in vessels seasoned with allyl bromide, have been studied in the temperature range of 171.5-280.1°C and the pressure range of 23-98 torr. The rate coefficients for the homogeneous unimolecular elimination of these esters are given by the following Arrhenius equations: for tert-butyl pivalate, log k1(s-1) = (13.44 ± 0.30) - (169.1 ± 3.1) kJ · mol-1 (2.303RT)-1; for tert-butyl trichloroacetate, log k1(s-1) = (12.41 ± 0.08) - (141.1 ± 0.7) kJ · mol-1 (2.303RT)-1; and for tert-butyl cyanoacetate log k1(s-1) = (11.31 ± 0.44) - (137.8 ± 4.1) kJ · mol-1 (2.303RT)-1. The data of this work together with those reported in the literature yield a good linear relationship when plotting log k/k0 vs. σ* values (ρ* = 0.635, correlation coefficient r = 0.972, and intercept = 0.048 at 250°C). The positive ρ* value suggests that the movement of negative charge to the acyl carbon in the transition state is rate determining. The present results along with previous investigations ratify the generalization that electron-withdrawing substituents at the acyl side of ethyl, isopropyl, and tert-butyl esters enhance the elimination rates, while electron-releasing groups tend to reduce them. The negative nature of the acyl carbon and the polarity in the transition state increases slightly from primary to tertiary esters.
    Zusätzliches Material: 1 Ill.
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  • 205
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 389-399 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Cis- and trans-buten-2-yl free radicals are shown to react with butene-2 cis (Bc) and D2S in the following metathetical steps: giving rise to butenes-1 (B1). The initial formations of butene-1,3 d1 and total butene-1 in D2S—Bc mixtures have been studied in the initial pressure range 20-200 torr for Bc, 0-41 torr for D2S and at 717-817 K. The main initiation and termination steps are shown to be: Assuming a rapid equilibrium between cis- and trans-C4H7⋅, ki ≃ 1015.5 exp(-85.5/RT) s-1 (RT in kcal mol-1) and kt ≃ 1013 mol-1 cm3 s-1, we get: k2c′ = 1.1 k2t′ = 1012.0 exp[(-9.25 ± 2)/RT] mol-1 cm3 s-1 and k2 + 1.5 k2′ ≃ 1012.1 exp[(-15.2 ± 2)/RT] mol-1 cm3 s-1. Isotopic effects relating to processes (2c′) + (2t′) and to (i′) have been evaluated.
    Zusätzliches Material: 6 Ill.
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  • 206
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 413-417 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: In this article, we present low-pressure steady-state results for carbon monoxide oxidation over Rh(100). The results are comparable to those found for other Group VIII transition metals. For a fixed oxygen pressure, the reaction rate is first order in CO pressure until a critical pressure is reached, above which the reaction rate sharply diminishes and the order becomes negative in CO pressure. Coverages of carbon monoxide under steady-state working conditions have been measured.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 207
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985) 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 208
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 477-501 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: n-C3H7ONO was photolyzed with 366 nm radiation at -26, -3, 23, 55, 88, and 120°C in a static system in the presence of NO, O2, and N2. The quantum yields of C2H5CHO, C2H5ONO, and CH3CHO were measured as a function of reaction conditions. The primary photochemical act is and it proceeds with a quantum yield φ1 = 0.38 ± 0.04 independent of temperature. The n-C3H7O radicals can react with NO by two routes The n-C3H7O radical can decompose via or react with O2 via Values of k4/k2 ≃ k4b/k2 were determined to be (2.0 ± 0.2) × 1014, (3.1 ± 0.6) × 1014, and (1.4 ± 0.1) × 1015 molec/cm3 at 55, 88, and 120°C, respectively, at 150-torr total pressure of N2. Values of k6/k2 were determined from -26 to 88°C. They fit the Arrhenius expression: \documentclass{article}\pagestyle{empty}\begin{document}$$ \log (k_6 /k_2) = - 2.17 \pm 0.20 - (879 \pm 117)/2.303{\rm T}{\rm .} $$\end{document} For k2 ≃ 4.4 × 10-11 cm3/s, k6 becomes (2.9 ± 1.7) × 10-13 exp{-(879 ± 117)/T} cm3/s. The reaction scheme also provides k4b/k6 = 1.58 × 1018 molec/cm3 at 120°C and k8a/k8 = 0.56 ± 0.24 independent of temperature, where
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 209
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985) 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 210
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 55-81 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: An eigenvalue-eigenvector analysis is used to extract meaningful kinetic information from linear sensitivity coefficients computed for several species of a reacting system at several time points. The main advantage of this method lies in its ability to reveal those parts of the mechanism which consist of strongly interacting reactions, and to indicate their importance within the mechanism. Results can be used to solve three general kinetic problems. Firstly, an objective condition for constructing a minimal reaction set is presented. Secondly, the uncovered dependencies among the parameters are shown to confirm or deny validity of quasi-steady-state assumptions under the considered experimental conditions. Thirdly, taking into account only sensitivities of observed species, the analysis is used to yield error estimates on unknown parameters determined from the experimental observations, and to suggest the parameters that should be kept fixed in the estimation procedure. To illustrate we chose the well-known hydrogen-bromine reaction and the kinetics of formaldehyde oxidation in the presence of CO.
    Zusätzliches Material: 2 Ill.
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  • 211
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 95-108 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The kinetics of the homolytic substitution of several trialkyltin iodides by iodine atoms are presented. Rate constants have been determined at three different temperatures and the following activation parameters calculated: A, Ea, and ΔS°≠. The observation that the activation energy, ΔG≠, is related to the driving force of the ion-pair formation, leads to the conclusion that the charge-transfer model is a valid approach for substitution in the reaction between R3SnI compounds and iodine atoms.
    Zusätzliches Material: 7 Ill.
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  • 212
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 109-116 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Di-tert-butyl nitroxide (DTBN) decomposes in aqueous solutions producing 2-methyl-2-nitroso propane (MNP) and tert-butanol. The process is acid catalyzed, it is of second order in DTBN, and takes place with a rate constant of (1.0 ± 0.1) M-2 s-1. The reaction is also catalyzed by the anionic surfactant sodium dodecyl sulfate and by Fe(II) and Fe(III) ions. The catalysis by Fe(III) involves a very fast reduction of Fe(III) ions with concomitant formation of 2-methyl-2-nitroso propane. The reaction catalyzed by Fe(II) also produces 2-methyl-2-nitroso propane with a formation rate given by: d[MNP]/dt = (0.25 ± 0.10) [Fe(II)] [DTBN]. This reaction rate is nearly pH independent.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 213
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 613-628 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Relative rate constants for the removal of vibrationally excited OH in the ninth vibrational level of its ground electronic state [designated hereafter by OH† (9)] by interaction with a series of simple hydrocarbons at room temperature are reported. The reaction of hydrogen atoms with ozone was used to generate OH†(9) in a fast flow discharge system at 1.1 ± 0.1 torr total pressure. The decrease in the (9 → 3 band) Meinel band chemiluminescent emission intensity at 626 nm was followed as a function of the concentration of added organic or of a reference deactivator (O2), respectively, at a fixed reaction time; these data gave relative rate constants, k2X/k2O2, for the removal of OH†(9) by the organic. The relative rate constants determined in this study are as follows: C2H6, 2.7 ± 0.2; C3H8, 4.4 ± 0.4; n-C4H10, 7.5 ± 0.6; iso-C4H10, 7.3 ± 0.8; n-C5H12, 10.4 ± 0.7; C2H4, 22.9 ± 1.8; C3H6, 43.4 ± 1.4; cis-2-C4H8, 47.7 ± 3.1; C6H6, 29 ± 7. (Errors are two standard deviations of the weighted mean of experiments in two flow tubes with different wall coatings and carrier gases.) The implications of the trends in these rate constants for the relative contributions of energy transfer and reaction to the net removal of OH† (9) are discussed.
    Zusätzliches Material: 7 Ill.
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  • 214
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 709-711 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 215
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 831-833 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 216
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Kinetic studies of oxidation of L(-) arginine, L(+) ornithine, L(-) histidine, L(-) tryptophan, L(-) threonine have been carried out in alkaline medium. The reaction showed an inverse fractional order in OH- and first-order dependence on both amino acid and chloroamine-T concentration. The effect of varying ionic strength (KCl) on the rate of oxidation is negligible. A general mechanism for the oxidation has been suggested by considering interaction between anionic species of amino acid and p-toluene-sulphochloramide. The effect of solvent and temperature have been also discussed. The fractional order obtained in OH- is due to the fact that a fraction of overall reaction proceeds via an alternative OH- independent path. The combined rate law in accordance to observed kinetics is derived as \documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{d[{\rm CAT}]}}{{dt}} = \frac{{2k_1 K_1 [{\rm AA}]_T [{\rm CAT}]_T }}{{[{\rm OH}^ - ]}} + 2k_3 K_1 K_3 [{\rm AA}]_T [{\rm CAT}]_T $$\end{document} The rate constants predicted by the derived rate law as the concentration of OH- ions change, are in excellent agreement with the observed rate constants, thus further justifying these rate laws and hence the proposed mechanistic schemes.
    Zusätzliches Material: 5 Ill.
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  • 217
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985) 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 218
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 991-1006 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Pulsed laser photolysis of N2O5 near 290 nm coupled with fluorescence detection (calibrated by NO2 photolysis) showed that the O(3P) quantum yield is ≤0.1. A pulsed laser optoacoustic technique in a flow tube (ca. 6 torr of N2) was tested by photolysis of NO2 and then applied to N2O5. Nitric oxide was added to react with NO3 free radical and the resulting increase in the optoacoustic signal confirmed the presence of NO3 free radicals. Based on the relative optoacoustic signals observed for NO2 and N2O5, the quantum yield for NO3 production is 0.8 ± 0.2.
    Zusätzliches Material: 8 Ill.
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  • 219
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 957-966 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Rate constants for the gas-phase reactions of NO3 radicals with a series of cycloalkenes have been determined at 298 ± 2 K, using a relative rate technique. Using an equilibrium constant for the NO2 + NO3 ⇄ N2O5 reactions of 3.4 × 10-11 cm3 molecule-1, the following rate constants (in units of 10-13 cm3 molecule-1 s-1) were obtained: cyclopentene, 4.52 ± 0.52; cycloheptene, 4.71 ± 0.56; bicyclo[2.2.1]-2-heptene, 2.41 ± 0.28; bicyclo[2.2.2]-2-octene, 1.41 ± 0.17; bicyclo[2.2.1]-2,5-heptadiene, 9.92 ± 1.13; and 1,3,5-cycloheptatriene, 12.6 ± 2.9. When combined with previous literature rate constants for cyclohexene and 1,4-cyclohexadiene, these data show that the rate constants for the nonconjugated cycloalkenes studied depend to a first approximation on the number of double bonds and the degree and configuration of substitution per double bond. No obvious effects of ring strain energy on these NO3 radical addition rate constants were observed. Our previous a priori predictive techniques for the alkenes and cycloalkenes can now be extended to strained cycloalkenes.
    Zusätzliches Material: 4 Ill.
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  • 220
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1007-1015 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The rate of oxygen exchange between trans-[Re(py)4O2]+ and solvent water in pypyH+ buffer solution follows simple first-order kinetics and both oxygens are equivalent. The half-life for isotopic oxygen exchange is about 12 h at a pH of 5.0, 25°C, and [py] = 0.10 M. The observed rate constant for exchange increases with acidity, in the pH range 4 to 6, decreases with [py], and is nearly independent of ionic strength. A small but significant increase of kobs occurs with increasing complex concentration. The rate of exchange follows the rate equation kobs/2 = k0 + k1/[py] with k0 = 1.4 × 10-5(2) s-1 and k1 = 4.7 × 10-7(1) M, s-1 at 25°C. The activation parameters for the reaction at pH = 7.15 (predominately the k0 term) are: ΔH* = +137.(1) kJ/M and ΔS* = +126.(1) J/MK. The pH effect and complex concentration effect are discussed in mechanistic terms. These results are compared to those found for [Re(en)2O2]+ and [Re(CN)4O2]3-.
    Zusätzliches Material: 2 Ill.
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  • 221
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1085-1090 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The condensed-phase thermal decomposition of aliphatic nitrate ester explosives is generally autocatalytic. The object of this article is to show that the agent of the autocatalysis is not the product NO2, as is generally believed, but to suggest that it may be the product formaldehyde.
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  • 222
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Part I: Kinetic data for the static system silane pyrolysis (from 640-703 K, 60-400 torr) are presented. For conversion from 3-30%, first-order kinetics are obtained, with silane loss rates equal to half the hydrogen formation rates. At conversions greater than 40%, rate inhibition attributable to the back reaction of hydrogen with silylene occurs. Overall reaction rates are not surface sensitive, but disilane and trisilane yield maxima under some conditions are. A nonchain mechanism capable of describing quantitatively all stages of the silane pyrolysis is proposed. Post 1.0% initiation is both homogeneous (gas phase) and heterogeneous (on the walls), and reaction intermediates are silylenes and disilenes. Free radicals are not involved at any stage of the reaction. Rate data at high conversions and with added hydrogen provide kinetics for the addition of silylene to hydrogen [reaction (-1)1] relative to its addition to silane [reaction (2)]: k-1,/k2 = 10-0.65 × e-3200 cal/RT. With E2 = 1300 cal, this gives a high pressure activation energy for silylene insertion into hydrogen of E-1 = 8200 cal.Part II: An analysis is made of each rate constant of the silane mechanism and the modeling results are compared with experimental results. Agreement is excellent. It is concluded that the dominant sink reaction for silylene intermediates is 1,2 - H2 elimination from disilane (followed by Si2H4 polymerization and wall deposition). The model is in accord with slow isomerization between disilene and silylsilylene and near exclusive 1,2 - H2 elimination from Si2H6. It is also concluded that disilene is about 10 kcal/mol more stable than silylsilylene and that the activation energy for isomerization of silylsilylene to disilene is greater than 26 kcal/mol.
    Zusätzliches Material: 6 Ill.
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  • 223
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1119-1123 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: In the case of catalytic dehydrogenation of cyclohexane, the linear relation between reaction rate and affinity holds at an appreciable distance away from equilibrium on both sides. In fact, in order to explain this observation, it is necessary to invoke a high value of three for the stoichiometric number of the rate determining step. This in turn can be explained by a reasonable mechanism for the reaction.
    Zusätzliches Material: 2 Ill.
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  • 224
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1155-1167 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Singlet molecular oxygen, O2(1Σg+), is one of the important intermediate species in the atmospheres of Earth, Mars, and Venus. To elucidate the chemistry of this excited molecular oxygen, a series of kinetic measurements have been undertaken using the flow-discharge/optical-emission technique. By monitoring the characteristic emission (762 nm for 1Σg+), the quenching rates for several important molecules have been obtained at room temperature. The following table summarizes measurements. TextQuencherRate Constants (cm3/s)CH2(4.6 ± 0.5) × 10-13H2(7.0 ± 0.3) × 10-13N2(1.7 ± 0.1) × 10-15Cl2(4.5 ± 0.8) × 10-16CO(4.5 ± 0.5) × 10-15O3(2.2 ± 0.3) × 10-112,3 DBM-2(6.0 ± 0.1) × 10-13The error limits represent one standard deviation. The systematic error is estimated to be about 15%. For CO2 and O3 molecules, the quenching rate constants were also measured in the temperature range of 245-362 K. In both reactions, negligible temperature dependences (with the activation energy less than 0.6 kcal/mole) were observed.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 225
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    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1187-1190 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Decomposition of (R1R2CXON=)2 (R1 = R2 = Ph; R1 = R2 = p—ClC6H4; R1 = Ph, R2 = CH3; X = H or D) in hydrocarbon solvents at 31-75°C afforded R1R2CO in 6-8% lower yield when X = D than when X = H. This result is ascribed to cage escape of secondary alkoxyl radicals in competition with dismutation. Deuterium isotope effects for alkoxyl cage dismutation of 1.35-2.4 are estimated from the data. It is suggested that this same competition may account for the experimentally slower termination rate constants in solution of primary and secondary alkylperoxyl radicals on α-deuteration.
    Zusätzliches Material: 1 Tab.
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  • 226
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 967-990 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The origin of autocatalysis in the pyrolysis of methane has been investigated by kinetic modeling. A mechanism is presented that provides good agreement with experimental data at 1038 K and 433 torr into the autocatalytic region. The main causes of autocatalysis are secondary initiation by hydrocarbon products larger than C2H6 and chain radical methylation sequences.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 227
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1067-1083 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Kinetic data and product studies are reported for the silane pyrolysis in the presence of olefins and acetylene. The kinetics of silane loss in the presence of acetylene was found to be identical to the initial gas phase silane decomposition step (SiH4 + M → SiH2 + H2 + M) when corrected for pressure fall-off effects. This result and the absence of methane or ethane from the pyrolysis of SiH4 in the presence of 1-butene or 1-pentene demonstrate that silyl radicals and H atoms are not involved in silane-olefin or silane-acetylene reactions. Qualitative aspects and kinetic data from the SiH4 pyrolysis in the presence of propylene are in accord with propylsilane formation via propylsilylene formed by silylene addition to propylene.
    Zusätzliches Material: 4 Ill.
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  • 228
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    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1103-1118 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: An ArF excimer laser was used to perturb radical concentrations and a tunable dye laser was used to follow the rise and subsequent decay of OH and CH in rich (φ = 1.6-1.8) atmospheric pressure methane flames. The excimer beam is only slightly focussed to minimize temperature excursions and the influence of diffusion and convection on the decay rates. The observed OH decay is consistent with that predicted using a detailed kinetic mechanism. The observed CH decay is much faster than predicted. The effects of equivalence ratio and height above burner suggests that a major CH decay channel involving an intermediate with higher concentration in rich flames is not properly treated in the mechanism.
    Zusätzliches Material: 11 Ill.
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  • 229
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1153-1154 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 230
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1191-1199 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Low pressure (4.67 kPa) CH4/O2/Ar flames were seeded with approximately 5300 ppm NH3. The concentration profiles of stable and radical species in lean (φ = 0.92) and rich (φ = 1.13) flames were determined by molecular beam sampling mass spectrometry. Temperature profiles in these flames were measured with thermocouples whose readings were corrected for radiative losses by the Na-line reversal method. Regions of the flames were selected where the principal reaction leading to the destruction of NH3 was By correcting the measured concentrations for diffusion, the net rate of NH3 loss rate was determined in the temperature range 2080-2360 K. The rate constant k1 was determined from the net loss rate with correction for the reaction using measured values of (O) and k2 values given by Salimian, Hanson, and Kruger [1]. The best-fit Arrhenius expression for k1 in the temperature range 2080-2360 K is 1013.88 exp(-4539/T) cm3/mol-s. The results of this study combined with previous lower temperature data confirm the non-Arrhenius behavior of k1 suggested by Salimian, Hanson, and Kruger [1]. The best-fit modified three parameter expression for the range 300-2360 K is 106.33±0.2 T2 exp(-169/T) cm3/mol-s.
    Zusätzliches Material: 6 Ill.
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  • 231
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1169-1185 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A discharge-flow apparatus with resonance fluorescence and chemiluminescence detection has been used to monitor O2(b 1σg+) production from several reactions of the HO2 radical at 300 K and 1-torr total pressure. O2(b), HO2, and OH were observed when F atoms were added to H2O2 in the gas phase. Signal strengths of O2(b) were proportional to initial concentrations of H2O2 and HO2. These observations were analyzed by using a simple three step mechanism and a more complete computer simulation with 22 reaction steps. The results indicate that the F + HO2 reaction yields O2(b) with an efficiency of (3.6 ± 1.4) × 10-3. By monitoring [O2(b)] and [HO2] upon addition of an excess second reactant to HO2, O2(b) yields from the reactions of HO2 with O, Cl, D, H, and OH were found to be 〈1 × 10-2, 〈5 × 10-4, 〈2 × 10-3, 〈8 × 10-3, and 〈1 × 10-3, respectively. Yields of O2(b) from the HO2 ± HO2 reaction were found to be less than 3 × 10-2.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 232
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1231-1245 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The kinetics of the chlorination of various tertiary alcoholamines by hypochlorite have been studied in alkaline media. A reaction mechanism consistent with the experimental results is put forward, and a relationship is established between the rate constants and the polar parameter (Σσ*) of the substituents.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 233
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    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 269-280 
    ISSN: 0271-2091
    Schlagwort(e): Navier-Stokes Equations ; Finite Element Method ; Solenoidal Approach ; Penalty Function Approach ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: In this paper the integrated solution approach, the penalty function approach and the solenoidal approach for the finite element solution of the stationary Navier-Stokes equations are compared. It is shown that both the penalty function approach and the solenoidal approach compare favourably to the integrated solution method. For fine meshes the solenoidal approach appears to be the cheapest method.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 234
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 281-292 
    ISSN: 0271-2091
    Schlagwort(e): Finite Elements ; Steady Flow ; Navier-Stokes equations ; Multiplier Methods ; Pseudo-Time-Iteration Method ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: In this paper a fully explicit finite element method (FEFEM) is presented for solving steady incompressible viscous flow problems. This full explicitness is achieved by combining the multiplier (or augmented Lagrangian) method with a pseudo-time-iteration method. FEFEM needs no global matrix at all and is of great advantage to large-scale problems because they can be solved within the limit of core memory.The optimum choice of a time increment and a penalty parameter is discussed and the driven cavity flow at a Reynolds number of 1000 is computed with a refined mesh (60 × 60 elements).
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 235
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 293-297 
    ISSN: 0271-2091
    Schlagwort(e): Transport Equation ; Polynomial Initial Conditions ; Convergence ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 236
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    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985) 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 237
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 311-329 
    ISSN: 0271-2091
    Schlagwort(e): Cavity Flows ; Finite-differences ; Numerical Accuracy ; Velocity Measurements ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A numerical and an experimental study of the flow of an incompressible fluid in a polar cavity is presented. The experiments included flow visualization, in two perpendicular planes, and quantitative measurements of the velocity field by a laser Doppler anemometer. Measurements were done for two ranges of Reynolds numbers; about 60 and about 350. The stream function-vorticity form of the governing equations was approximated by upwind or central finite-differences. Both types of finite-difference approximations were solved by a multi-grid method. Numerical solutions were computed on a sequence of grids and the relative accuracy of the solutions was studied. Our most accurate numerical solutions had an estimated error of 0.1 per cent and 1 per cent for Re = 60 and Re = 350, respectively. It was also noted that the solution to the second order finite difference equations was more accurate, compared to the solution to the first order equations, only if fine enough meshes were used. The possibility of using extrapolations to improve accuracy was also considered. Extrapolated solutions were found to be valid only if solutions computed on fine enough meshes were used. The numerical and the experimental results were found to be in very good agreement.
    Zusätzliches Material: 22 Ill.
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  • 238
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 402-403 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 239
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 427-438 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The problem under investigation is that of fluid flow within an enclosed rectangular cavity. It is assumed that one wall is maintained at a constant temperature T1 (hot wall) and the other wall is maintained at a constant temperature T0 (cold wall). At the remaining walls, two separate cases are studied. In the first, an adiabatic boundary condition is assumed. That is, the normal derivative of the temperature function is assumed to be 0. In the second, it is assumed the temperature varies linearly from T0 to T1.The purpose of this paper is the application of a second order numerical technique to the problem of fluid flow within a heated closed cavity. The method is a modification of a method developed by Shay1 and applied to the driven cavity problem. In order to test the viability of this technique, it was decided to extend the technique to the problem of natural convection in a square. Jones2 proposed that this problem is suitable for testing techniques that may be applied to a wide range of practical problems such as reactor insulation, cooling of radioactive waste containers, solar energy collection and others.3The technique makes use of second-order finite difference approximations to all derivatives in the governing equations. Furthermore, second-order approximations are also used to determine boundary vorticities and, when the adiabatic boundary condition is used, for the boundary temperatures as well. In some works, where second-order approximations are used at interior points, second-order boundary approximations have been sacrificed in favour of a more stable, but first-order boundary approximation.The current approximations are generated by writing the unknown value of a function at a given interior node as a linear combination of unknown function values at all of the neighbouring nodes. Then the function values at these neighbouring nodes are expanded in a Taylor series about the given node. Through appropriate regrouping of terms and the use of the equations to the solved, constraints are imposed on the coefficients of the linear combination to yield a second-order approximation. As it turns out, there are more unknowns than constraints and, as a result, we are left with some freedom in choosing coefficients. In this work this freedom was used to choose coefficients in such a way as to maximize stability of the resulting system of equations. In other words, the approximations to the governing partial differential equation are individually determined at each point dependent on the direction of flow in order to generate the best possible stability. This idea is analogous to that used in the derivation of the upwind method. However, the current method is second-order accurate where the upwind method is only first-order accurate. Thus, what is generated is an easily implemented second-order method that yields a system of equations that has proved easy to solve.The system of equations is solved via the method of successive overrelaxation. The stability of the method is shown in the convergence for a wide range of Rayleigh numbers, Prandtl numbers and mesh sizes. Level curves of the stream, vorticity and temperature functions are provided for Rayleigh numbers (Ra) as large as 100,000, Prandtl numbers (Pr) as small as 0.0001, and mesh sizes as small as 0.0125. Values of the Nusselt number have also been calculated through the use of Simpson's rule, and a second order approximation to the normal derivative of the temperature along the cold wall. Comparisons are made with other current works to aid in the verification of this methods' accuracy and also with the first-order upwind method to demonstrate superiority over the first-order method.
    Zusätzliches Material: 9 Ill.
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  • 240
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 505-513 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: Computational difficulties arise in the non-linear free-surface problem for water waves both at large amplitudes when the crest becomes nearly singular and at small amplitudes when the wave is very close to the alternative uniform flow solution. Since the limiting wavelengths for small amplitude waves are known from the Stokes linearized theory, these are used in checking results for finite-amplitude programs. When Southwell and Vaisey1 first tried this, their methods gave an unexplained overestimate, by 6 per cent, of the limiting wavelength. This paper shows how coarse mesh effects can create such an overestimate, gives very accurate solutions at small amplitudes and considers accuracy in relation to the mesh for short and long waves.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 241
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 545-560 
    ISSN: 0271-2091
    Schlagwort(e): Boundary Layer Flows ; Time-like ; Co-ordinate ; Space-like ; Domain ; Inviscid ; Tangential ; Velocity ; Pressure Gradient ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A numerical procedure was developed to solve the two-dimensional and axisymmetric incompressible laminar boundary layer equations using the semi-discrete Galerkin finite element method. Linear Lagrangian, quadratic Lagrangian, and cubic Hermite interpolating polynomials were used for the finite element discretization; the first-order, the second-order backward difference approximation, and the Crank-Nicolson method were used for the system of non-linear ordinary differential equations; the Picard iteration and the Newton-Raphson technique were used to solve the resulting non-linear algebraic system of equations. Conservation of mass is treated as a constraint condition in the procedure; hence, it is integrated numerically along the solution line while marching along the time-like co-ordinate. Among the numerical schemes tested, the Picard iteration technique used with the quadratic Lagrangian polynomials and the second-order backward difference approximation case turned out to be the most efficient to achieve the same accuracy. The advantages of the method developed lie in its coarse grid accuracy, global computational efficiency, and wide applicability to most situations that may arise in incompressible laminar boundary layer flows.
    Zusätzliches Material: 2 Ill.
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  • 242
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 761-762 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 243
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 727-744 
    ISSN: 0271-2091
    Schlagwort(e): Shallow Water Equations ; Boundary Fitted Grids ; Comparison of Boundary Fitted Grid Model with x-y Cartesian Grid Model ; Annular Ring Solutions ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: Many problems of applied oceanography and environmental science demand the solution of the momentum, mass and energy equations on physical domains having curving coastlines. Finite-difference calculations representing the boundary as a step function may give inaccurate results near the coastline where simulation results are of greatest interest for numerous applications. This suggests the use of methods which are capable of handling the problem of boundary curvature.This paper presents computational results for the shallow water equations on a circular ring of constant depth, employing the concept of boundary fitted grids (BFG) for an accurate representation of the boundary. All calculations are performed on a rectangle in the transformed plane using a mesh with square grid spacing. Comparisons of the simulations of transient normal mode oscillations and analytic solutions are shown, demonstrating that this technique yields accurate results in situations (provided that there is a reasonable choice of grid) involving a curved boundary. The software developed allows application to any two-dimensional area, regardless of the complexity of the geometry.Simulation runs were made with two co-ordinate systems. For the first system, the grid point distribution was obtained from polar co-ordinates. For the second one, grid point positions were calculated numerically, solving Poisson's equation. It was found that small variations in the metric coefficients do not deteriorate the accuracy of the simulation results.Moreover, comparisons of surface elevation and velocity components at grid points near the inner and outer radii obtained from an x-y Cartesian grid model with the BFG simulation were made. The former model produced inacccuracies at grid points near boundaries, and, owing to the large number of mesh points used to yield the necessary fine resolution, the computation time was found to be a factor of three higher.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 244
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 805-816 
    ISSN: 0271-2091
    Schlagwort(e): Diffusion-Convection ; Finite Element Method ; Hermite Interpolation Function ; Numerical Analysis ; Stability ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The paper is concerned with stability and accuracy of an nth order Lagrangian family of finite element steady-state solutions of the diffusion-convection equation, and furthermore is concerned with the stability and the accuracy of on mth kind Hermitian family of finite element solutions. We discuss the stability of the numerical solution based on the fact that the characteristic finite element solution can be expressed approximately as a rational function of cell Peclet number Pec ( = uh/k). Moreover, it is shown that by eliminating derivatives and by using the interpolation method over elements a stable solution is obtained over the domain independent of Pec for P1,3, and for P2,5 the stable solution is obtained for Pec less than 44.4.
    Zusätzliches Material: 11 Ill.
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  • 245
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 847-848 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 246
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 849-871 
    ISSN: 0271-2091
    Schlagwort(e): Random Vortex Method ; Wind Engineering ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The random vortex method of Chorin1 provides a numerical simulation of high-Reynolds number flow in two dimensions. The method can be used to model the viscous interaction of wind with a surface-mounted obstacle of arbitrary cross-section. In this paper the method has been used to investigate the flow of wind over common building shapes; an inlet profile is chosen to represent the stationary aspects of the atmospheric boundary layer. The evolution of flow over a short time-interval after flow initialization is depicted, and a mean value of pressure coefficient, Cp, is calculated over the building perimeter. Some comparison is made with published wind-tunnel measurements for the case of a surface-mounted square-section block and for a building model with 10° roof pitch.
    Zusätzliches Material: 8 Ill.
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  • 247
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 891-909 
    ISSN: 0271-2091
    Schlagwort(e): Green's Functions ; Boundary Element Method ; Waves ; Special Functions ; Series ; Convergence ; Acceleration ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: We have studied the problem of calculating Green's functions in three dimensional hydrodynamic gravity wave problems. A number of new expressions for these functions are presented for both finite and infinite depths. Various techniques for accelerating the convergence of some infinite series in these expressions are investigated and compared with the normal methods of evaluation. A significant improvement in the efficiency of the calculation is found using the results described in this paper.
    Zusätzliches Material: 2 Ill.
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  • 248
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 939-939 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 249
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 943-955 
    ISSN: 0271-2091
    Schlagwort(e): Finite Element ; Reservoir ; Hydrostatic Pressure ; Numerical Accuracy ; Stratified Flow ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: Experiences relating to the application of finite element models for laterally averaged stratified flow are discussed and modifications to the basic approach are suggested that alleviate these difficulties. An example problem is used to demonstrate the revised model and to make a preliminary assessment of the hydrostatic pressure assumption when applied to reservoir analysis.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 250
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985) 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 251
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 1047-1057 
    ISSN: 0271-2091
    Schlagwort(e): Transonic Flow ; Modified Potential ; Finite Elements ; Non-isentropic Flow ; Conservative Method ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The classical potential formulation of inviscid transonic flows is modified to account for non-isentropic effects. The density is determined in terms of the speed as well as the pressure, which in turn is calculated from a second-order mixed-type equation derived via differentiating the momentum equations.The present model differs in general from the exact inviscid Euler equations since the flow is assumed irrotational. On the other hand, since the shocks are not isentropic, they are weaker and are placed further upstream compared to the classical potential solution. Furthermore, the streamline leaving the aerofoil does not necessarily bisect the trailing edge.Results for the present conservative calculations are presented for non-lifting and lifting aerofoils at subsonic and transonic speeds and compared to potential and Euler solutions.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 252
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 1035-1045 
    ISSN: 0271-2091
    Schlagwort(e): Laminar Boundary Layer ; Splines ; Incompressible ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: An inverse method is presented which accurately determines the pressure distribution for assigned wall shear in a two-dimensional, laminar, incompressible boundary layer. The method reformulates the mechul function scheme of Cebeci and Keller to produce a stable solution in the marching direction and to increase accuracy in the normal direction. In the reformulation a modified pressure gradient parameter variation in the normal direction is used in conjunction with three-point backward differences for streamwise derivatives and fourth-order accurate splines for normal derivatives. The resulting spline-finite difference equations are solved by Newton-Raphson iteration together with partial pivoting. Numerical solutions are presented for self-similar and non self-similar flows and compared with published results.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 253
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 399-401 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 254
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 381-391 
    ISSN: 0271-2091
    Schlagwort(e): Matrix Iterative Methods ; Strongly Implicit Procedure ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A new method for solving elliptic difference equations is derived based on the strongly implicit method. This parametrized strongly implicit method has three free parameters which may be functions of the field's nodal point. The method has some resemblance to the SOR techniques, but in the present method the off-diagonal entries are also over-relaxed. The main application of this method is for transport equations such as those governing the fluid flow and heat transfer fields.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 255
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 439-442 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 256
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 463-481 
    ISSN: 0271-2091
    Schlagwort(e): Trailing-edge Flow ; Laminar Flow ; Turbulent Flow ; Generalized Co-ordinates ; Group Finite-element Method ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A consistent three-level time-split group finite-element method, suitable for the computation of viscous compressible flows in irregular geometric domains, is described. Exploitation of the group12 formulation permits an accurate and economical algorithm to be developed in a generalized-co-ordinate (ζ,η) space. A variable sweep cycle is used to accelerate convergence to the steady state. The method is demonstrated by computing laminar and turbulent flow past a trailing edge. The method uses an algebraic eddy viscosity model to represent turbulence and produces results in close agreement with the experiments and computations of Viswanath et al8.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 257
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 502-503 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 258
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985) 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 259
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 529-543 
    ISSN: 0271-2091
    Schlagwort(e): Shallow Water Equations ; Analytic Solutions ; Three-dimensional ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: Exact periodic solutions are generated for the 3-D hydrodynamic equations in linearized form. A linear slip condition is enforced at the bottom, based on the velocity at the bottom. It is shown that the bottom stress can be equivalently expressed in terms of the vertically averaged velocity, and expressions for this bottom stress coefficient are derived in terms of the primary parameters of the problem. As a result, the three-dimensional structure may be assembled from conventional solutions to (a) the 1-D vertical diffusion equation; and (b) the 2-D vertically averaged shallow water equations. In the latter, the bottom stress effects are shown to be complex and frequency-dependent, and an additional rotational term is required for their representation.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 260
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 593-596 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: In this note we show that the numerical solution of the advection-diffusion equation can be improved by considering the asymptotic behaviour of its analytical solution. This is accomplished by including a correction term based on the numerical differentiation of the asymptotic (Pe » 1, Pe being the Peclet number) solution. This correction forces the usual oscillations associated with centred schemes to disappear.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 261
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 601-614 
    ISSN: 0271-2091
    Schlagwort(e): Finite Elements ; Stokes Equations ; Periodically Constricted Tubes ; Quadrilateral Elements ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The use of the finite element method in solving the problem of flow of a Newtonian fluid in periodically constricted tubes is explored. The performance of eight node serendipity and nine node Lagrangian elements is compared. It was found that the Lagrangian element results in unstable velocity fields when stagnant or recirculation regions are present. This is characteristic of tubes with large expansion zones. The eight node element does not exhibit instabilities. Both elements give accurate pressure fields. This behaviour is contrary to traditional results obtained for flow problems with similar geometrical characteristics. This suggests that the periodicity of the boundary conditions might be the cause of the instabilities in the numerical solution.The use of the continuity equation to simplify the viscous terms in the Stokes equations resulted, in this particular case, in a deterioration of the rate of convergence of the algorithm.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 262
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 627-635 
    ISSN: 0271-2091
    Schlagwort(e): Pressure Gradient Method ; Unsteady Flow ; Cavity Flow ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The pressure gradient method using velocity components and components of a pressure gradient as dependent variables has been modified to solve incompressible Newtonian fluid flow problems numerically. Applying this modified method to unsteady-state development of flow in a circular cavity shows that, at least for the case of a low Reynolds number flow, relative errors produced by the proposed method are smaller for most time intervals than those produced by the primitive velocity-pressure variable method and by the standard pressure gradient method. Also it is found that the modified and standard pressure gradient methods can be applied to the unsteady circular cavity flow at a moderate Reynolds number of at least up to 200.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 263
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 665-666 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 264
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 599-600 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 265
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 685-707 
    ISSN: 0271-2091
    Schlagwort(e): Navier-Stokes Problem ; Monochromatic Dynamic Behaviour ; Uzawa Algorithm ; Darcy's Law ; Conforming Finite Element Methods ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: In this paper computations in the two dimensional case of a harmonic Navier-Stokes problem with periodic boundary conditions are presented. This study of an incompressible viscous fluid leads to a non-symmetric linear problem (very low Reynolds number). Moreover unknown functions have complex values (monochromatic dynamic behaviour). Numerical treatment of the incompressibility condition is a generalization of the classical treatment of Stokes problem. A mixed formulation, where discrete pressure plays the role of Lagrange multipliers is used (Uzawa algorithm).Two conforming finite element methods are tested on different meshes. The second one uses a classical refinement in the shape function: the so-called bulb function. All computational tests show that the use of a bulb function on each element gives better results than refinement in the mesh without introducing too many degrees of freedom. Finally numerical results are compared to experimental data.
    Zusätzliches Material: 23 Ill.
    Materialart: Digitale Medien
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  • 266
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 762-762 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 267
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 831-845 
    ISSN: 0271-2091
    Schlagwort(e): Non-Newtonian ; Finite Element Method ; Optimal Control ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: Modern lubricants often exhibit shear-thinning due to the presence of high molecular weight polymers as additives. Therefore the influence of such non-Newtonian effects on the performances of lubricating systems must be predicted. The corresponding fluid film flow is governed by a non-linear partial differential equation, which generalizes the classical Reynolds equation. Having prescribed adequate boundary conditions, this equation is solved by a finite element method with optimal control. The problem of the square slider bearing lubricated by the Rabinowitsch fluid is solved in order to test the accuracy of the numerical scheme. The pressure and velocity fields are given and compared with the corresponding ones obtained for the Newtonian fluid.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 268
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 911-928 
    ISSN: 0271-2091
    Schlagwort(e): Incompressible ; Finite Elements ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: We present a numerical procedure to eliminate internal nodes from elements designed to approximate incompressible flow problems. We compare six elements in academic and industrial like flow problem and we discuss their relative qualities. A surprising conclusion is that richer elements may behave less well than simple ones if a good enforcement of incompressibility is not maintained.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 269
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 940-941 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 270
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 929-938 
    ISSN: 0271-2091
    Schlagwort(e): Non-Newtonian Fluid Flow ; Nine-Node Lagrangian Element ; Broyden's Method ; Frontal Method ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: When the Galerkin finite-element method with a nine-node isoparametric Lagrangian element is applied to solve non-Newtonian fluid flow problems, a considerable amount of computing time is required to solve the discretized non-linear system of equations by Newton's method. A method proposed by Broyden has been modified to compute the Jacobian matrix associated with Newton's method. This modified Broyden's method can be combined with the frontal method to efficiently solve the linearized finite-element equations during the iteration. Numerical results of a sample problem concerning the determination of the pressure-drop/flow-rate relationship for power-law fluids in rectangular ducts show that the application of this new method can reduce computing time substantially.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 271
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 995-1013 
    ISSN: 0271-2091
    Schlagwort(e): Boussinesq Approximation ; Porous Media ; Finite Element ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The regions of applicability of the Boussinesq approximation are investigated for natural convection in a fluid-saturated porous medium. A perturbation method is used to assess the relative importance of individual terms in the differential equations which describe the natural convection process. Specific limits to the validity of the Boussinesq approximation are identified for water and air. For water, it is shown that the restrictions imposed by the classical Boussinesq approximation can be relaxed by allowing for the variation of thermophysical properties with temperature while still retaining the incompressible form of the continuity relation. Results of the analysis are verified through numerical calculations performed for steady natural convection in a planar, water-saturated porous region.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 272
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 981-993 
    ISSN: 0271-2091
    Schlagwort(e): Finite Element Method ; Velocity Correlation Method ; Density Flow ; Density Flume ; Linear Interpolation ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A finite element method is proposed for the analysis of density flow which is induced by a difference of density. The method employs the idea that density variation can be pursued by using markers distributed in the flow field. For the numerical integration scheme, the velocity correction method is successfully used, introducing a potential for the correction of velocity. This method is useful because one can use linear interpolation functions for velocity, pressure and potential based on the triangular finite element. The final equations can be formulated using the quasi-explicit finite element method. A flume in a tank with sloping bottom has been analysed by the present method. The computed results show extremely good agreement with the experimental observations.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 273
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 1059-1060 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 274
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 245-255 
    ISSN: 0271-2091
    Schlagwort(e): Orthogonal Body-Fitted Grid ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The procedure proposed is based on the solution by finite difference means of a set of Laplace's equations, by the application of a relaxation method.The curvilinear orthogonal grid so generated is fitted to a 2-D physical domain with closed boundary and the contribution of the present work consists in the arbitrary choice of grid points on two adjacent boundaries, in order to achieve the desired density of grid points where the geometry of the boundaries varies rapidly.The method proposed is rapid and stable. Some characteristic examples are finally presented.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 275
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 303-304 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 276
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 299-302 
    ISSN: 0271-2091
    Schlagwort(e): Compressible ; Fictitious Gas ; Finite Elements ; Error Estimates ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: We summarize here some theoretical results for fictitious gas regularization of compressible flow and give error estimates for the finite element approximation to the regularized problem.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 277
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 305-310 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The commonly accepted linear stability analysis for the forward-time centred-space (FTCS) algorithm applied to the transport equation has led to the concept of a cell Reynolds number restriction on the spatial grid size. This paper shows where the commonly accepted original analysis is in error and presents the correct stability restrictions, which are restrictions on the time step, not the spatial grid size. There is no cell Reynolds number restriction. The results are confirmed by numerical computations for the two-dimensional driven cavity problem.
    Zusätzliches Material: 1 Ill.
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  • 278
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 304-305 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
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  • 279
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 331-345 
    ISSN: 0271-2091
    Schlagwort(e): Turbomachines ; Design ; Finite Element ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: In this paper the development of a compatible mixed design and analysis method is presented for the quasi-three-dimensional finite element blade-to-blade program FINSUP. The method consists of two parts. The first is concerned with a method of modelling changes to a blade shape using a surface transpiration model. The second is concerned with determining the relationship between the displaced blade surface and the surface velocity distribution. It is shown that with the Newton-Raphson procedure adopted in the method a very efficient manner of introducing the design option is possible. As a consequence the resulting program is fast and completely interactive. A number of examples are given to illustrate how the mixed design and analysis mode can be used in practical blade design.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
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  • 280
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985) 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 281
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 443-462 
    ISSN: 0271-2091
    Schlagwort(e): Turbulent flow ; Boundary Layer Flow ; Swirl ; Surface Mass Transfer ; Finite Element Method ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The Dorodnitsyn finite element method for turbulent boundary layer flow with surface mass transfer is extended to include axisymmetric swirling internal boundary layer flow. Turbulence effects are represented by the two-layer eddy viscosity model of Cebeci and Smith1 with extensions to allow for the effect of swirl. The method is applied to duct entry flow and a 10 degree included-angle conical diffuser, and produces results in close agreement with experimental measurements with only 11 grid points across the boundary layer. The introduction of swirl (we/ue = 0.4) is found to have little effect on the axial skin friction in either a slightly favourable or adverse pressure gradient, but does cause an increase in the displacement area for an adverse pressure gradient. Surface mass transfer (blowing or suction) causes a substantial reduction (blowing) in axial skin friction and an increase in the displacement area. Both suction and the adverse pressure gradient have little influence on the circumferential velocity and shear stress components. Consequently in an adverse pressure gradient the flow direction adjacent to the wall is expected to approach the circumferential direction at some downstream location.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 282
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 405-425 
    ISSN: 0271-2091
    Schlagwort(e): DuFort-Frankel ; Saul'ev ; Instability ; Sea Model ; Hydrodynamic ; Three-dimensional Time-splitting ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A three dimensional hydrodynamic sea model of an arbitrary sea area is formulated using sigma co-ordinates in the vertical. The solution of the equations using finite difference grids in the horizontal and the vertical is described.Discretization of the vertical viscosity term in the hydrodynamic equations using the DuFort-Frankel and Saul'ev methods is developed. Some numerical instabilities occur with the DuFort-Frankel method which can be overcome by splitting the hydrodynamic equations into equations describing the mean flow and equations describing the deviations from it. The computational advantages of solving these equations with different time steps are discussed.The accuracy and stability of the various methods is demonstrated for wind induced flow in a simple rectangular basin having dimensions representing the North Sea.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 283
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 501-501 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 284
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 483-500 
    ISSN: 0271-2091
    Schlagwort(e): Three-dimensional Vortex flow ; Pseudo-unsteady Euler Equations ; Finite Volume ; Multiple Grid ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The unsteady Euler equations are numerically solved using the finite volume one-step scheme recently developed by Ron-Ho Ni. The multiple-grid procedure of Ni is also implemented. The flows are assumed to be homo-enthalpic; the energy equation is eliminated and the static pressure is determined by the steady Bernoulli equation; a local time-step technique is used. Inflow and outflow boundaries are treated with the compatibility relations method of ONERA. The efficiency of the multiple-grid scheme is demonstrated by a two-dimensional calculation (transonic flow past the NACA 12 aerofoil) and also by a three-dimensional one (transonic lifting flow past the M6 wing). The third application presented shows the ability of the method to compute the vortical flow around a delta wing with leading-edge separation. No condition is applied at the leading-edge; the vortex sheets are captured in the same sense as shock waves. Results indicate that the Euler equations method is well suited for the prediction of flows with shock waves and contact discontinuities, the multiple-grid procedure allowing a substantial reduction of the computational time.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 285
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 515-528 
    ISSN: 0271-2091
    Schlagwort(e): Solution Adaptive ; Grids (SAG) ; Mesh Generation ; Techniques ; Burgers Equation ; Falkner-Skan Equation ; Viscous Aerofoil Flows ; Navier-Stokes Equations ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A solution adaptive grid (SAG) method which redistributes the nodal points of a function according to its curvature is presented. A single, user-selected step parameter, P, is available for controlling the maximum step size, allowing the application of the technique to a wide variety of problems. Three test cases are cited: (1) the 1-dimensional inviscid Burgers equation, (2) the Falkner-Skan equation and (3) the finite-volume form of the Navier-Stokes equations for transonic aerofoil flows. In all three cases, significant solution improvement in terms of accuracy and convergence acceleration were achieved.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 286
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 561-575 
    ISSN: 0271-2091
    Schlagwort(e): Cavity Flow ; Incompressible Flow ; Control-Volume Formulation ; Navier-Stokes Equations ; QUICK ; Convection Scheme ; Taylor-Görtler Vortices ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: Previous three-dimensional simulations of the lid-driven cavity flow have reproduced only the most general features of the flow. Improvements to a finite difference code, REBUFFS, have made possible the first completely successful simulation of the three-dimensional lid-driven cavity flow. The principal improvement to the code was the incorporation of a modified QUICK scheme, a higher-order upwind finite difference formulation. Results for a cavity flow at a Reynolds number of 3200 have reproduced experimentally observed Taylor-Görtler-like vortices and other three-dimensional effects heretofore not simulated. Experimental results obtained from a unique experimental cavity facility validate the calculated results.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 287
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 667-683 
    ISSN: 0271-2091
    Schlagwort(e): Laminar Flows ; Complex Geometry ; Numerical Methods ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: This paper reports on the outcome of a workshop of the IAHR Working Group on Refined Modelling of Flows on the subject of computing laminar flows in complex geometries. Flow inside a channel with a smooth expansion was chosen by the organizers of the workshop as a suitable test case for assessing the capabilities of current numerical methods. The results obtained by fifteen participant groups are presented and compared against a suitable benchmark solution. The most important considerations that emerged at the workshop are briefly reported and the conclusions arising from an analysis and comparison of the various solutions are finally provided.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 288
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 577-592 
    ISSN: 0271-2091
    Schlagwort(e): Unsteady ; Separation ; Discrete Vortex ; Aerofoil ; Wake ; Inviscid ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: Presented in this paper is a new method for the prediction of unsteady, incompressible separated flow over a two-dimensional aerofoil. The algorithm was developed from an existing unsteady potential flow model1 and makes use of an inviscid formulation for the flow field. The aerofoil is represented by vortex panels of linearly varying strength which are piecewise continuous at the corners. Discrete vortices with finite cores are used to model the separating shear layers.Following a brief summary of unsteady separation modelling, the theoretical framework is presented and the subsequent numerical implementation is discussed in detail.Results are given for flows which tend asymptotically to the steady state and conclusions are drawn regarding the usefulness of the method.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 289
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985) 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 290
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 637-656 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: This paper presents finite element methods for the non-stationary Euler equations of a two dimensional inviscid and incompressible flow. For the time discretization, we compare numerical results obtained by the use of a leap-frog scheme and a semi-implicit scheme of order two.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 291
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 745-760 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: Dynamic and thermal results for developing laminar pulsed flows in a duct are presented. They have been investigated by means of a finite difference model. This flow is described in terms of an unsteady pulsed flow superimposed on a steady incompressible one with the following main assumptions: a sinusoidal modulation for the pulsation and a uniform wall temperature. Results emphasize the importance of this entry region, where four simultaneous developments occur: steady - dynamic and thermal - and unsteady - dynamic and thermal.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 292
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985) 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 293
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 785-803 
    ISSN: 0271-2091
    Schlagwort(e): Variable Penalty Method ; Penalty Finite Element Analysis ; Rotating Flow ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A new scheme is applied for increasing the accuracy of the penalty finite element method for incompressible flow by systematically varying from element to element the sign and magnitude of the penalty parameter λ, which enters through ∇.v + p/λ = 0, an approximation to the incompressibility constraint. Not only is the error in this approximation reduced beyond that achievable with a constant λ, but also digital truncation error is lowered when it is aggravated by large variations in element size, a critical problem when the discretization must resolve thin boundary layers. The magnitude of the penalty parameter can be chosen smaller than when λ is constant, which also reduces digital truncation error; hence a shorter word-length computer is more likely to succeed. Error estimates of the method are reviewed. Boundary conditions which circumvent the hazards of aphysical pressure modes are catalogued for the finite element basis set chosen here. In order to compare performance, the variable penalty method is pitted against the conventional penalty method with constant λ in several Stokes flow case studies.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
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  • 294
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 763-783 
    ISSN: 0271-2091
    Schlagwort(e): Solenoidal Vector Fields ; Fast Poisson Solvers ; Boundary Integral Methods ; Far Field Approximations ; Navier-Stokes Equations ; Capacitance Matrices ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: We develop a new method for the efficient calculation of solenoidal vector fields on general regions. The method takes advantage of fast direct methods and uses boundary integral equations to satisfy boundary conditions. For the latter we give an effective scheme for computing far-field boundary influences (based on discrete charges). Examples and numerical results are given. The method is applicable to incompressible Navier-Stokes calculations.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 295
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 817-830 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The problem of computing the vibration modes of a structure vibrating in a fluid is examined with specific application to ship hulls. In particular, methods which take proper account of the three-dimensional nature of the water movements are described. Fluid singularities involving either a line doublet on the intersection of the water surface with the plane of symmetry or distributed sources on retracted boundaries are particularly effective at modelling the fluid flow and appear to give better numerical efficiencies than finite element or boundary element methods. The effects of the extra coefficients in the mass matrix arising from added mass on the various methods of eigensolution are discussed.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 296
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985) 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 297
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 873-890 
    ISSN: 0271-2091
    Schlagwort(e): Incompressible Navier-Stokes Equations ; Finite Element Method ; Direct Time ; Integration Method ; Vortex Shedding Behind an Obstacle ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: A numerical procedure for solving the time-dependent, incompressible Navier-Stokes equations is presented. The present method is based on a set of finite element equations of the primitive variable formulation, and a direct time integration method which has unique features in its formulation as well as in its evaluation of the contribution of external functions. Particular processes regarding the continuity conditions and the boundary conditions lead to a set of non-linear recurrence equations which represent evolution of the velocities and the pressures under the incompressibility constraint. An iteration process as to the non-linear convective terms is performed until the convergence is achieved in every integration step. Excessively artificial techniques are not introduced into the present solution procedure. Numerical examples with vortex shedding behind a rectangular cylinder are presented to illustrate the features of the proposed method. The calculated results are compared with experimental data and visualized flow fields in literature.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 298
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985) 
    ISSN: 0271-2091
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 299
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985) 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 300
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The gas phase pyrolysis of 1,1,1,2-tetrachloropropane was studied in a static system and seasoned vessel over the temperature range of 393.0-452.8°C and pressure range of 27.5-118.5 torr. The reaction is homogeneous, unimolecular, follows a first-order rate law, and is not affected by the presence of the free radical inhibitor, toluene, or propene. The main dehydrochlorination products are 1,1,1-trichloro-2-propene and 1,1,2-trichloro-1-propene. The temperature dependence of the rate coefficient is given by the Arrhenius equation \documentclass{article}\pagestyle{empty}\begin{document}$$ \log {\rm }k_1 ({\rm s}^{{\rm - 1}}) = (11.98 \pm 0.34) - (205.1 \pm 4.6){\rm kJ/mol/2}{\rm .303}RT $$\end{document}The Arrhenius parameters of this reaction are apparently low. Consequently, in estimating the transition state of A = 1013.5, the following expression is obtained \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm log }k_1 ({\rm s}^{ - {\rm 1}}) = 13.5 - 225.1{\rm kJ/mol/2}{\rm .303}RT $$\end{document} The partial rates and kinetic parameters for the parallel elimination products have been estimated and reported. The trichloromethyl substituent has been found to affect this elimination process through its electron withdrawing effect.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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