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  • 1985-1989  (1.748)
  • 1960-1964
  • 1987  (1.748)
  • General Chemistry  (1.002)
  • Chemical Engineering  (726)
  • Catalysis
  • Phosphorus
  • Recombinant DNA
Materialart
Erscheinungszeitraum
  • 1985-1989  (1.748)
  • 1960-1964
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Biology and fertility of soils 5 (1987), S. 230-234 
    ISSN: 1432-0789
    Schlagwort(e): Earthworm casts ; Microbial respiration ; Microbial biomass ; Nitrogen ; Phosphorus ; Aporrectodea caliginosa
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary Microbial respiration, microbial biomass and nutrient requirements of the microflora (C, N, P) were studied in the food substrate (soil taken from the upper 3 cm of the mineral soil of a beech wood on limestone), the burrow walls and the casts of the earthworm Aporrectodea caliginosa (Savigny). The passage of the soil through the gut caused an increase in soil microbial respiration of about 90% over a 4-week period. Microbial biomass was increased only in freshly deposited casts and decreased in aging faeces to a level about 10% lower than in soil. Microbial respiration of the burrow walls was only increased over a shorter period (about 2 weeks). The microflora of the soil and the burrow walls was limited by P, whereas in earthworm casts, microbial growth was limited by the amount of available C. In aging faeces the P requirement of the microflora increased and approached that of the soil. Immobilization of phosphate in earthworm casts is probably caused by mainly abiotic processes. C mineralization by soil microflora fertilized with glucose and P was limited by N, except in freshly deposited casts. Ammonium, not nitrate, was responsible for this process. N dynamics in earthworm casts are discussed.
    Materialart: Digitale Medien
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  • 2
    ISSN: 1432-0983
    Schlagwort(e): Schizophyllum commune ; Transformation ; Gene isolation ; Basidiomycetes ; Recombinant DNA
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary We have developed a routine way to isolate genes directly from the basidiomycete fungus, Schizophyllum commune. Plasmid DNA from a genomic gene library was used to isolate five specific genes by complementation of Schizophyllum mutations via transformation. The mutant strains were deficient in the ability to synthesize either adenine (ade2 and ade5), uracil (ural, encoding orotidine-5′-phosphate decarboxylase; OMPdecase), tryptophan (rpl, encoding indole-3-glycerol phosphate synthetase; IGPS) or para aminobenzoic acid (pab1). In each case, Southern analysis revealed that transformation to prototrophy was concomitant with the integration of vector sequence into the genome of the S. commune mutant. Total DNA from transformants was restricted, religated, and used to transform E. coli. Ampicillin resistant plasmids were recovered from E. coli and tested for their ability to transform the corresponding mutant of S. commune. Plasmids complementing the ade2, adeS, pabl, trpl, and ural mutations were recovered.
    Materialart: Digitale Medien
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  • 3
    ISSN: 1573-0867
    Schlagwort(e): Phosphorus ; potassium ; fertilizer placement ; triple-superphosphate ; partially acidulated phosphate rock ; hybrid squash ; Cucurbita maxima L.
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Two experiments examined options for reducing the inputs of P and K fertilizers for hybrid squash (Cucurbita maxima L.) at Pukekohe, New Zealand. The first experiment examined the effects of elevating the NaHCO3-soluble P from 32 to 130 mg kg−1 and the exchangeable K from 140 to 350 mg kg−1 within strips from 0 to 0.75 m around rows of hybrid squash planted 1.5 m apart. From both P and K, crop yield increased as the width of the fertilized strip was increased up to 0.25 m, while wider fertilized strips had no further effect. These results followed similar effects on plant dry matter and tissue P or K concentration during early growth, and are explained in terms of the P and K accumulation by the crop, the decline during growth of the sensitivity of the crop to soil P and K fertility associated with declining rates of P and K uptake per unit length of root. Implications for fertilizer management for hybrid squash are also discussed. The second experiment compared the effects of partially acidulated phosphate rock and triple-superphosphate on soil P fertility, growth and yield of hybrid squash. Partially acidulated phosphate rock had smaller effects than those of triple-superphosphate on NaHCO3-soluble P levels in the soil, plant dry weight and tissue P concentration soon after emergence, and subsequently crop yield. On average, partially acidulated phosphate rock increased crop yield by about 70% of that following the application of the same quantity of P as triple-superphosphate. This lower effectiveness of partially acidulated phosphate rock for hybrid squash is explained in terms of its lower solubility and hence smaller effect on NaHCO3-soluble P in the soil during early growth, when the crop is most sensitive to soil P fertility.
    Materialart: Digitale Medien
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  • 4
    ISSN: 1432-069X
    Schlagwort(e): Collagen ; Fibroblasts ; Scleroderma ; Recombinant DNA
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Summary Fibroblast cultures were started from affected and unaffacted skin areas of six patients with localized scleroderma in an active stage. The cell lines were studied for synthesis of procollagens and fibronectin by metabolic labeling with 3H-proline and for their contents of mRNAs for pro α1(I) and pro α2(I) collagen. For this purpose a cDNA clone for human pro α1(I) collagen mRNA was constructed. The clone was identified by restriction site mapping and hybridization to the specific mRNAs. All the scleroderma fibroblast lines produced increased amounts of type I and type III collagens and fibronectin during the early passages. The cell lines gradually reduced their elevated synthesis of collagen and fibronectin to normal or near normal levels by the tenth passage. The ratios of α1(I) and α2(I) chains and of type I and type III collagens, and the extent of type I procollagen processing, remained relatively unchanged in all the cultures. The cellular levels of type I procollagen mRNAs were increased in all the cells exhibiting an increased synthesis of collagen. The results suggest that in localized scleroderma the fibroblasts have undergone a coordinated activation of collagen synthesis at transcriptional level.
    Materialart: Digitale Medien
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  • 5
    ISSN: 1432-2013
    Schlagwort(e): Cholesterol ; 1,25 Vitamin D3 ; Calcium ; Phosphorus ; Calcemia ; Hypocholesterolemia ; 7-Dehydrocholesterol reductase ; Epidermis ; Rat UV radiation ; Skin vitamin D3 synthesis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Abstract Vitamin D3 is generated in skin by UV irradiation of 7-dehydrocholesterol (7-DEHC). Whether the 7-DEHC amount in skin affects vitamin D3 formation, and thereby the plasma level of 25-hydroxyvitamin D3 (25[OH]D3) is not known. In the present work we report on the influence on vitamin D and Ca metabolism of a new hypocholesterolemic agent, HCG-917 (0-2-[hydroxy-3-]N′-(2-chlorophenyl)-N-piperazinyl-1-[propyl]-4-chloro-benz-aldoxim-hydrochloride) which inhibits 7-DEHC reductase and thereby increases skin 7-DEHC. Rats were treated with HCG 917 (0.3 and 5.0 mg/kg, orally) for 13 days. HCG 917 caused a dose-dependent decrease in cholesterol and concomitant accumulation of 7-DEHC in plasma and skin. In skin, 7-DEHC was: control: 1.05±0.20; HCG 917, 0.3 mg/kg: 1.41±0.22; HCG 917, 5.0 mg/kg: 2.35±0.35 mg/g. At a dose of 0.3 mg/kg, HCG 917 had no significant influence on the plasma level of neither 25(OH)D3 nor 1,25(OH)2D3. However, at a dose of 5.0 mg/kg, HCG 917 induced a significant increase in plasma 25(OH)D3 (control: 36.2±2.2; HCG 917 5.0 mg/kg: 57.6±6.5 nmol/l) and a slight but not significant rise in 1,25(OH)2D3. Calcium balance studies indicated that HCG 917 did not influence intestinal Ca absorption nor urinary Ca excretion. At a dose of 5.0 mg/kg HCG 917 slightly induced a decrease in total plasma Ca. In conclusion, HCG 917 treatment can induce a significant rise in skin 7-DEHC with an increase in plasma 25(OH)D3. These results suggest that variation in the skin level of 7-DEHC can directly influence the cutaneous production of vitamin D3 and thereby the vitamin D status of the organism.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Oecologia 71 (1987), S. 541-547 
    ISSN: 1432-1939
    Schlagwort(e): Ericaceae ; Nitrogen ; Phosphorus ; Deciduous ; Evergreen
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary Aboveground growth, reproduction, and foliar nitrogen and phosphorus contents of two ericaceous shrub species were compared over two seasons in (a) an undisturbed shrub bog (pocosin), and (b) a factorial fertilization design in which three levels each of nitrogen and phosphorus were added in all possible combinations. One species, Zenobia pulverulenta, is deciduous whereas the other species, Lyonia lucida, is evergreen. In the nutrient-poor undisturbed pocosin the two species exhibited similar foliar nitrogen and phosphorus concentrations and aboveground growth rates. Neither species flowered. In response to nutrient-addition Zenobia increased growth rates more than Lyonia. Foliar phosphorus concentrations of both species increased in response to enhanced phosphorus availability. in the first season neither species flowered in any treatment. In the second season Zenobia flowered only in the fertilized plots, with the most flowering in the high phosphorus treatments. I conclude that, by virtue of high growth rates and efficient use of nutrients and despite differences in leaf phenology and morphology, both Lyonia and Zenobia are successful in a competitive community under conditions of extremely low phosphorus availability. However, unlike Lyonia, Zenobia can take advantage of temporarily increased nutrient availability, which occurs following fire in the pocosin, to increase growth and reproduction.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Oecologia 73 (1987), S. 268-271 
    ISSN: 1432-1939
    Schlagwort(e): Foliar nutrients ; Resorption ; Succession ; Nitrogen ; Phosphorus
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary Leaves were sampled in a successional, southern Appalachian forest to estimate autumn foliar nutrient dynamics. Resorption of N and P in a successional forest equaled, or exceeded, resorption estimates for a more mature control forest. Foliar nutrient leaching was not sufficient to account for changes in autumn leaf N, P, Ca and Mg concentrations. The resorption process conserves nutrients by reducing nutrient losses from leaching and litter-fall, thereby closing the nutrient cycle in successional forests. We hypothesize that rapid recovery of primary productivity early in forest regeneration is the result of maximum nutrient resorption of limiting nutrients. Implications of these results for successional nutrient cycling theory are discussed.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Oecologia 74 (1987), S. 370-376 
    ISSN: 1432-1939
    Schlagwort(e): Costa Rica ; Miconia ; Piper ; Nitrogen ; Phosphorus
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary Six speices of shrubs and one large herb with contrasting life history patterns were used as bioassays of nutrient availability in a Costa Rican lowland rain forest soil. Growth responses of the herb (Phytolacca rivinoides, Phytolaccaceae) confirmed soil measurements indicating high availability of N and potentially limiting levels of P, K, Mg and Ca. Growth responses of the shrub species (Miconia spp., Melastomataceae and Piper spp., Piperaceae) to a complete nutrient fertilizer were generally less than that of Phytolacca. Lack of a strong shrub response to +P fertilization is probably due to mycorrhizal associations and slower growth rates of woody species. In general, increased growth did not occur at the expense of phenolic production in the leaves. The results emphasize that assessment of specific nutrient limitations to plant growth vary depending on species selected for the bioassay, even among species from the same community.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Journal of industrial microbiology and biotechnology 2 (1987), S. 117-121 
    ISSN: 1476-5535
    Schlagwort(e): Fermentation ; Recombinant DNA ; Hepatitis B surface antigen
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Summary Fermentations were performed to determine parameters affecting the expression of hepatitis B surface antigen (HBsAg) in the yeastSaccharomyces cerevisiae containing the HBsAg gene. These studies emphasized inereasing both the relative abundance (HBsAg: cell mass) and total production of HBsAg. Specific activity was increased 70-fold when cells were grown in shake flasks containing nonselective rather than selective medium. The addition of adenine, ammonium sulfate or glucose to the complex medium reduced the production of antigen. Results similar to those achieved in shake flasks were obtained when the growth was performed in fermenters. A nutrient addition system was employed to increase the production of cells and HBsAg. The addition of glucose to the culture medium increased cell mass 6-fold but decreased the production of antigen. This imbalance was corrected by supplementing the glucose with complex nutrients.
    Materialart: Digitale Medien
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  • 10
    ISSN: 1617-4623
    Schlagwort(e): Recombinant DNA ; Methionine metabolism ; Negative control ; Regulatory regions
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary In Saccharomyces cerevisiae, the expression of several genes implicated in methionine biosynthesis is coregulated by a specific negative control. To elucidate the molecular basis of this regulation, we have cloned two of these genes, MET3 and MET25. The sequence of MET25 has already been determined (Kerjan et al. 1986). Here, we report the nucleotide sequence of the MET3 gene along with its 5′ and 3′ flanking regions. Plasmids bearing different deletions upstream of the transcribed region of MET3 were constructed. They were introduced into yeast cells and tested for their ability to complement met3 mutations and to respond to regulation by exogenous methionine. The regulatory region was located within a 100 bp region. The sequence of this regulatory region was compared with that of MET25. A short common sequence which occurs 250–280 bp upstream of the translation initiation codon of the gene was found. This sequence is a good candidate for the cis-acting regulatory element.
    Materialart: Digitale Medien
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  • 11
    Digitale Medien
    Digitale Medien
    Springer
    Molecular genetics and genomics 209 (1987), S. 570-574 
    ISSN: 1617-4623
    Schlagwort(e): Recombinant DNA ; Methylase ; Plasmid vector ; Gel electrophoresis ; Clearage map
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary The modification genes of Flavobacterium okeanokoites and Haemophilus galinarum have been cloned into the vector pBR322 and expressed in Escherichia coli cells. FokI methylase gene is contained on a 3.80 kb piece of F. okeanokoites DNA. Plasmid constructs carrying this fragment of DNA are resistant to digestion by FokI restriction endonuclease but are sensitive to cleavage by HindIII, EcoRI and PstI. Unmodified λ DNA molecules, exposed in vitro to cell extracts prepared from cells habouring this plasmid, became resistant to digestion by FokI. The smallest HgaI methylase clone carries the pBR322 plasmid containing a 3.50 kb piece of H. galinarum DNA. This plasmid is resistant to digestion by HgaI. Neither the FokI nor the HgaI restriction endonuclease was detected in either clone. This is the first report of cloning modification genes whose protein products recognise asymmetric nucleotide sequences.
    Materialart: Digitale Medien
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  • 12
    Digitale Medien
    Digitale Medien
    Springer
    Journal of industrial microbiology and biotechnology 1 (1987), S. 277-282 
    ISSN: 1476-5535
    Schlagwort(e): Recombinant DNA ; Gene expression ; Genetic engineering ; Biotechnology
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Summary A variety of factors affect the expression of foreign proteins inEscherichia coli. These include: promoter strength, efficiency of ribosome binding, stability of the foreign protein inE. coli, location of the foreign protein inE. coli, the codons used to encode the foreign protein, the metabolic state of the cell, and the location, stability and copy number of the foreign gene. This paper contains a critical review of these factors with the idea that a detailed understanding of them is the key to the development of strategies for the efficient large-scale production of foreign proteins inE. coli.
    Materialart: Digitale Medien
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  • 13
    ISSN: 1434-9949
    Schlagwort(e): Senile Osteoporosis ; Phosphorus ; Salmonn Calcitonin
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Summary Twenty-five patients with radiological and clinical evidence of osteoporosis were studied. Nineteen patients received oral phosphorus at a dose of 1,000 mg/die for 10 days followed by salmon calcitonin (100 U MRC/die) for 20 days. Six patients received only oral calcium at a dose of 1,000 mg/die). In the first group, a significant increase in serum osteocalcin and parathyroid hormone, after administration of phosphorus and persisting after treatment with salmon calcitonin, was found. No variation in the controls was observed. In a later study, a significant increase in serum 1,25 dihydroxyvitamin D (1,25(OH)2D3), after receiving phosphorus and persisting after salmon calcitonin, was demonstrated. In accordance with the authors' results, phosphorus could be considered a useful activator of bone formation and this stimulus by parathyroid hormone was mediated. Finally, the positive effects of phosphorus on circulating 1,25(OH)2D3 must be considered for a good treatment protocol of osteoporosis.
    Materialart: Digitale Medien
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  • 14
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 97 (1987), S. 369-379 
    ISSN: 1573-5036
    Schlagwort(e): Bark ; Calcium phosphate ; Eucalyptus marginata ; Fertilizer ; Leaf ; Lignotuber ; Phosphorus ; Shoot growth ; Wood
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary Effects of calcium phosphate supply on plant dry matter and phosphorus concentrations of parts of jarrah (Eucalyptus marginata) seedlings grown in a lateritic topsoil from the jarrah forest were examined in two glasshouse trials. Phosphorus deficiency depressed root and shoot dry weights and severely deficient leaves were smal and purple with prominent red major veins. Phosphorus deficiency severely reduced stem phosphorus levels (0.5% to 0.02%, experiment 1). Phosphorus concentrations were higher in bark than wood and the amount of phosphorus in the bark was sensitive to stem age and phosphate supply. Phosphorus adequate plants had bark phosphorus concentrations in the range 0.2–0.9% compared to 〈0.1% in deficient plants (experiment 2). Jarrah leaves accumulated dry matter up to 80 days after expansion and some leaves exported phosphorus during this period. Bark analysis may therefore be preferable to leaf analysis for detecting phosphorus deficiency in this species.
    Materialart: Digitale Medien
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  • 15
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 99 (1987), S. 185-196 
    ISSN: 1573-5036
    Schlagwort(e): Antibody ; H+-ATPase ; Membrane ; Recombinant DNA ; Transport
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary Mineral transport across the plasma membrane of plant cells is controlled by an electrochemical gradient of protons. This gradient is generated by an ATP-consuming enzyme in the membrane known as a proton pump, or H+-ATPase. The protein has a catalytic subunit of Mr=100,000 and is a prominent band when plasma membrane proteins are analyzed by sodium dodecyl sulfate-polyacrylamide gel electrophoresis. We generated specific rabbit polyclonal antibody against the Mr=100,000 H+-ATPase and used the antibody to screen λgtll expression vector libraries of plant DNA. Several phage clones producing immunoreactive protein, and presumably containing DNA sequences for the ATPase structural gene, were isolated and purified from a carrot cDNA library and a Arabidopsis genomic DNA library. These studies represent our first efforts at cloning the structural gene for a plant plasma membrane transport protein. Applicability of the technique to other transport protein genes and the potential for use of recombinant DNA technology in plant mineral transport research are discussed.
    Materialart: Digitale Medien
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  • 16
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 97 (1987), S. 279-283 
    ISSN: 1573-5036
    Schlagwort(e): Copper ; Dazomet ; Field experiment ; Leek ; Phosphorus ; Pretransplant inoculation ; VA mycorrhiza ; Zinc
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary Leek plants were preinoculated with a mixed inoculum ofGlomus caledonium, Glomus fasciculatum andGlomus sp., and transplanted to Dazomet disinfected and untreated field plots of moderate P deficiency. Successive harvests were made until 99 days after transplanting. Preinoculated leeks attained marketable weights 25 days earlier than uninoculated leeks from untreated soil and their final dry matter yields were 5.7 and 1.5 times as high as those of uninoculated leeks from disinfected and untreated soil, respectively. Phosphorus concentration in preinoculated leeks remained highest for at least 22 and 75 days after transplanting in untreated and disinfected soil, respectively. Preinoculation had a similar, although smaller, influence on Cu and Zn concentrations. Infection levels produced by introduced and indigenous VA endophytes in leeks reached plateaus of 90% and 40%, respectively, 47 days after transplanting. It is concluded that VAM is essential to leeks grown in moderately P deficient soils, and the potential for inoculating seedlings in commercial leek production is discussed.
    Materialart: Digitale Medien
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  • 17
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 98 (1987), S. 99-109 
    ISSN: 1573-5036
    Schlagwort(e): Allelopathy ; Ferulic acid ; Magnesium ; Mineral content ; Phosphorus ; PotassiumSorghum bicolor
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary Two week old sorghum seedlings (Sorghum bicolor L. Moench) were treated with ferulic acid added to the nutrient solution. Effects on tissue concentration of P, K, Mg, Ca, Fe, and Zn were evaluated after 3 and 6 days. Treatemnts of 0.25 mM ferulic acid approximated the growth inhibition threshold, and after 6 days 0.5 mM treated plants weighed less than controls. Both treatments reduced the P content of the roots and shoots at the 3- and 6-day harvests in three replicate experiments. Roots of treated plants at both harvests had a lower concentration of K and Mg. These reductions in P, K, and Mg were most extensive from the 0.5 mM ferulic acid regime. In some cases at both harvests, shoot K was lower and Mg was higher than control tissue. Ferulic acid effects at the 3-day harvest included an elevation of Ca and depression of Fe in shoots. Changes in nutrient content preceded measurable differences in plant weight. These data indicate that one mechanism of growth inhibition by this allelochemical may be an alteration of nutrient balance.
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  • 18
    Digitale Medien
    Digitale Medien
    Springer
    Plant and soil 98 (1987), S. 363-375 
    ISSN: 1573-5036
    Schlagwort(e): Ammonium ; Forest soil samples ; Nitrate ; pH ; Phosphorus ; Potassium ; Sample storage ; Seasonal variation ; Soil analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary This study was carried out in order to assess the importance of storage procedures and time of sampling for the results of routine chemical analyses of forest soils. Humus and mineral soil samples were collected at five-week intervals during two growing seasons from a sample plot in a coniferous forest in northern Sweden. The samples were either air-dried (+35°C) or frozen (−20°C). After a few months they were analysed for ‘easily available’ and ‘relatively available’ phosphorus (P-AL and P-HCl) and potassium (K-AL and K-HCl), ammonium, nitrate and pH. In some cases there was a significant difference between the two sample treatments. In humus, the concentrations of P-AL and NH4-N were 51% and 76% higher in samples which had been frozen than in those which had been air-dried while the concentrations of NO3-N were 75% higher. in air-dried than in frozen samples. In mineral soil samples, 21–64% higher concentrations of K-AL were found in frozen samples compared to air-dried and 80–427% higher concentrations of NO3-N in air-dried than in frozen samples. No distinct seasonal variations were found for any of the parameters.
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  • 19
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1021-1034 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Equations are derived that relate the orientation of “pseudo-affine” reoriented structural units after a biaxial deformation to the degrees and the directions of the effective drawings. The connection between these drawing parameters and those externally applied is analyzed in detail. It is shown how a comparison of these two sets of drawing parameters allows conclusions regarding the distribution throughout the material of the stresses that cause the deformation, the inhomogeneity of the deformation, and the role of non-orienting flow during deformation. In particular, the orientation of biaxially drawn poly(ethylene terephthalate) films is investigated, and it is shown what general information can be obtained on the deformation behavior of this material on the basis of these considerations.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 20
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1059-1068 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Scale-up from small laboratory size extruders to large production size extruders is a procedure of great practical importance. Many scale-up rules and theories have been proposed in the past, however it is not always clear how the different scale-up methods will affect extruder performance. A basic analysis of scale-up in plasticating single screw extruders is developed from which the effect of a certain scale-up strategy on extrusion performance can be evaluated in terms of solids conveying, melting, melt conveying, mixing, residence time, heat transfer, power consumption, and specific energy consumption. Various existing scale-up theories are evaluated and compared using the basic analysis. A number of existing scale-up theories have some significant drawbacks, in particular with non-constant specific energy consumption and imbalance between melting rate and pumping rate. Conditions that are desirable to achieve in scale-up are enumerated and ranked in terms of importance. This leads to two new scale-up methods that result in constant mechanical specific energy consumption and high throughput rates. The first scale-up method keeps the specific surface area constant. This scale-up should work well for high values of the Brinkman number. However, at low values of the Brinkman number, the melting rate may be insufficient. The second scale-up method keeps the melting rate at low Brinkman number equal to the pumping rate and, thus, should be useful in cases where the first scale-up method cannot be used.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 21
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
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  • 22
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1128-1136 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The plane strain fracture toughness and fracture mechanisms of several tough engineering plastics have been studied and compared with poly(methyl methacrylate) (PMMA), a relatively brittle polymer. The tough polymers all are observed to form a multiple craze zone at the crack tip, which is shown to be the primary source of plane strain fracture toughness in these materials. The multiple craze zone is retained during slow crack growth but is metastable, and at a critical stress intensity and associated crack velocity, the system passes through a transition to a greatly accelerated single craze mode of unstable propagation.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 23
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1148-1155 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The optical properties of bisphenol-A polycarbonate resin as described by the complex index of refraction, N = n - ik, are derived by Kramers-Kronig analysis of experimental absorption and reflectance data obtained in the range 40μm ≥ λ ≥ 105 nm. Electronic absorption processes in polycarbonate are characterized by two broad absorption peaks centered at ∼200 and ∼100 nm.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 24
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1182-1186 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Three-layer coextruded blown (either blend or composite) films, made of low-density polyethylene and linear lowdensity polyethylene (1:1 ratio) of identical density, were compared. The tensile properties of both systems are nearly as high as those of the linear polyethylene while high strain rate properties including impact strength and tear resistance of the composite film are superior. Some structural insight was obtained by thermal analysis and thermoelastic measurements. Structure property relationships are discussed in light of the unique behavior, structure, and morphology of linear low-density polyethylene. The two polyethylenes are only compatible to a rather limited extent mainly affecting their blend behavior. However, a strong mutual reinforcement effect was observed.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 25
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1203-1208 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A Viton copolymer containing vinylidene fluoride (VF2) and hexafluoropropylene (HFP), and a terpolymer containing VF2, HFP, and tetrafluoroethylene (TFE) were cross linked using varying amounts of Bisphenol AF to yield two series of fluoroelastomer networks, Stress-strain isotherms in elongation were determined for these samples at several temperatures and at two degrees of swelling with phenyl acetate. Strain-induced crystallization was observed, as evidenced by upturns in the isotherms at high elongations. It appears to be more pronounced in the terpolymer samples, presumably because the TFE units not only can crystallize themselves, but can co-crystallize with the VF2 units. The crystallization was found to persist upon moderate increase in temperature, but was suppressed when the networks were swollen, Thermoelastic (force-temperature) measurements were used to obtain values of the fraction fe/f of the elastic force that is due to energetic effects. Negative values were obtained for both types of samples and, in the case of two samples studied in detail, their magnitudes increased with increase in elongation. The magnitudes were larger and the increases more pronounced in the case of the terpolymer networks, as would be expected from a greater tendency for straininduced crystallization.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 26
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1221-1228 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The transesterification reaction of molten ethylene and vinyl alcohol copolymers (EVA), in presence of paraffinic alcohols and basic catalysts, leads to high conversion of the ester groups to secondary alcohol in both discontinuous and continuous processing equipment. Various kinds of alcohols and two different catalysts were used. Sodium methoxide is a powerful catalyst for the equilibrated transesterification reaction, but we also observed side reactions, such as cross-linking with low-molecular-weight alcohols and hydrolysis of the catalyst followed by partial saponification of the EVA. Kinetic studies were performed in the presence of dibutyltin dilaurate, an efficient catalyst without any side reactions. The solubility of the main alcohol reagents was verified by diffusion measurements. The general reaction scheme and the related kinetics, corresponding to a homogeneous system, lead to a fair evaluation of the rate constants.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 27
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1252-1257 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The mechanical properties of polyurethane-unsaturated polyester interpenetrating polymer networks (IPNs) that were prepared by reaction injection molding (RIM) process were measured with variations In composition, cross-link density, and relative reaction rate. From dynamic mechanical analysis (DMA), it was found that the two component polymers had a good compatibility over the whole composition range. The tensile strengths of the blends were greater than those of the pure components and had a maximum value at 50/50 composition. The modulus of elasticity and surface hardness decreased and the impact strength increased as the polyurethane content was increased, but the changes were not high at low polyurethane content, below 50%. For higher cross-link density, the compatibility was enhanced and the mechanical properties were improved. When the reaction rates of the components were different, some extent of phase separation was found in DMA and the properties were affected adversely.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 28
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Forced Rayleigh scattering, a relatively recently developed optical technique, is used to measure tracer diffusion coefficients in polymer-solvent mixtures near the system glass transition temperature, Tg. The technique has a wider range of potential application than has yet been realized, and so is presented in some detail. The objectives were to obtain data necessary to scrutinize free volume theory, and to understand so-called anomalous, non-Fickian diffusion effects observed by others in polymer-solvent mixtures near Tg. Data on dye tracer diffusion coefficients in the systems polyvinyl acetate-toluene, polystyrene-toluene, and polystyrene-tri-m-tolyl phosphate were obtained over a polymer concentration range from infinite dilution to 96 wt. %. Small molecule diffusion coefficients are seen to vary by as much as nine orders of magnitude (10-14 to 10-5 cm2/s) over this concentration range. The data are in reasonable accord with expectations based on the Duda-Vrentas version of free-volume theory.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 29
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 604-618 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Microflow calorimeter design for heats of mixing is surveyed. Precise temperature equilibration of the fluids before mixing, the elimination of frictional energy effects from the instrument response, and the absence of flow-rate and physical-property-dependent heat leaks are particularly important. A design using a differential mode of operation is based on a careful analysis of entropy generation in flows with mixing and friction. The compensation for frictional heating and the lack of dependence of measurements on flow rate and mixture physical properties other than hE represents a major advance. Measured data for the welltested cyclohexane-hexane system had an average deviation of only 0.41%. For the more viscous cyclohexane-1-hexanol system, measured data of similar precision are considered the best available.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 30
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 643-653 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Energy requirements of four different thermally coupled distillation systems were minimized for an assumed ideal ternary solution being separated. Minimum vapor flows and values of decision variables have been found in the form of analytical expressions. This enables making a quick and simple comparison of these systems. The solution method can be used for synthesis of separation systems or for screening calculations.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 31
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 628-642 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A mathematical model is presented for the codeposition of cadmium and tellurium onto a rotating-disk electrode. The treatment incorporates the equation of convective diffusion for liquid phase mass transport, Butler-Volmer expressions for charge-transfer reactions, and a thermodynamic model for individual component activities in the solid state. Because of the formation of CdTe, a compound that has a large negative free energy of formation, the cadmium deposition reaction occurs at potentials substantially positive to its standard electrode potential (Uθ = -0.40 V). This reaction, along with the deposition of tellurium (Uθ = + 0.55 V), produces an electrodeposit that contains cadmium, tellurium, and cadmium telluride. The model can be used to calculate transient current-potential relationships, ionic concentration profiles, and deposit compositions. Transport and kinetic parameters for cadmium and tellurium deposition are reported; a multidimensional optimization routine is used to evaluate physiochemical parameters from experimental data for the codeposition process.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 32
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 668-671 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 33
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 677-680 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 34
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 686-689 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 35
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 694-696 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 36
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 701-702 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 37
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 705-710 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Studies of the attack of gel-stabilized suspensions of hydroxyapatite show dissolution at the boundary of the solid region and reprecipitation within this region. The results are apparently consistent with a theory which assumes that porous solid dissolution is diffusion-controlled but constrained by nonlinear solubility products.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 38
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1829-1834 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A test has been designed and used to compare flow hydrodynamics in different thermogravimetric analysis (TGA) systems used as pulse microreactors. The test involves passing a pulse of injectant over the sample pan containing an adsorbent. Water and zeolite are used in the present case. The technique is easily performed and is insensitive to variations in temperature. A model is developed by which the fraction of gas pulse bypassing the sample pan within the TGA can be obtained. In gas/solid reactions, either catalytic or noncatalytic, the test should prove useful for comparing TGA extent-of-conversion data to similar measurements taken from other reactor configurations, carrier flow rates, and flow geometries.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 39
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1835-1843 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Published models for gas-solid reactions have been used with certain modifications to interpret sulfation data for CaO, MgO, and ZnO with SO2 and SO3. None of the models evaluated gave an adequate interpretation for high solid conversions, which were found to exceed 90% in some cases. Such high conversions are inconsistent with the current models, and a new mechanism must be postulated to explain the reaction after the solid product theoretically fills the initial pores of the particle. An important factor in successfully interpreting the experimental data is the distributed nature of the pore sizes within the solid particle.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 40
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1844-1849 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Contact nucleation studies were performed with the dextrose-water system. Under some conditions two crystallographic phases were formed, which were identified in situ using a laser Raman microprobe. In addition, the growth of the contact nuclei was monitored in situ using photomicroscopy. The results are discussed in the context of contact nucleation and growth models.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 41
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1873-1881 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An efficient frequency domain methodology for the design of set point regulators for high-order process models involving relatively large pure time delay is presented. The unique advantage of the methodology is that it enables the designer to rapidly visualize the structure of the required controller as soon as the time and frequency domain specifications are stipulated for the closed-loop system. Optimizing the parameters of an appropriate structure improves the robustness of the controller. The method does not require order reduction of the original model, and time delay is handled directly. Also, only output feedback is utilized.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 42
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1865-1872 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A new bubble diameter correlation is derived to predict bubbling characteristics of fluidized beds of varieties of powders. The present model is founded on the postulate that the steady bubble size, which is often called the maximum stable diameter, observed in a bed of Geldart group A powder is formed as a result of an equilibrium of successive coalescence and splitting. For the cases of group B powders the present correlation automatically converges to the conventional correlation of Mori and Wen (1975), whose predictions are close to those of Rowe (1976) and Darton et al. (1977). For group A powders the present correlation is validated by comparison with experimental data in the literature. Based on this correlation a theoretical explanation is presented for the fact that the maximum bubble diameters observed were up to 50 to 100 times as large as those from the stable bubble theory of Harrison et al. (1961).
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 43
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1850-1864 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Global bifurcations are frequently encountered in the dynamic behavior of chemically reacting systems and their models. They cause dramatic qualitative changes in the system response, such as the birth and death of oscillations and even the onset of chaos. They involve entire regions of the system phase space, and due to their nature they are in general not predictable by standard local bifurcation methods, analytical or numerical. Special methods and algorithms must therefore be developed to locate and analyze them in parameter space. This paper presents such methods and algorithms and illustrates them through standard chemical engineering examples. Test cases include lumped chemical reactor models (homogeneous and heterogeneous, autonomous and periodically forced), a problem of compressible gas flow in porous media, and a case of two coupled oscillators. The phenomena discussed include infinite-period bifurcations, saddle connections, frequency locking, and the creation and extinction of multifrequency responses through global manifold interactions (homoclinic tangles).
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 44
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1882-1887 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The general collinearity conditions at phase boundaries for mixtures are proved by thermodynamic identities for density and for entropy as functions of temperature, pressure, and composition. In the case of density/temperature/pressure/composition collinearity is always found at the cricondentherm or any temperature extremum, whereas for entropy/temperature/pressure/composition collinearity is always found at the cricondenbar or any pressure extremum. Qualitative phase diagrams for a typical binary system are presented in accordance with the derived inequalities. Whether a particular slope, involving the above variables, from the homogeneous side of the phase boundary is greater or less than that from the heterogeneous side depends on location on the phase boundary with respect to cricondentherm, critical point, and cricondenbar.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 45
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1899-1902 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 46
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1895-1898 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 47
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1888-1893 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Average and local heat transfer coefficients were measured for transfer from circulating fluidized beds of sand particles (mean size 188 and 356 μm) to two water-cooled membrane wall surfaces located on one face of a 152 mm square by 7.3 m tall column. The measurements cover a range of superficial gas velocities from about 4 to 7 m/s, suspension densities from about 8 to 130 kg/m3, suspension temperatures from 150 to 400°C, and secondary-to-primary air ratios of 0 to 1.5. Heat transfer coefficients, averaged over a 1.53 m length of the membrane waterwall surfaces, depend strongly on suspension density, but show almost no separate dependence on gas velocity, bed temperature, or secondary-to-primary air ratio for the conditions studied. For the surface nearest the top of the unit, the coefficient decreases with distance measured downward from the top, suggesting that particles travel downward along the surface. As a result, averaged coefficients are lower and the influence of particle size is less than for previously reported circulating fluidized bed heat transfer measurements where miniature heat transfer surfaces were employed.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 48
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1903-1907 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 49
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1908-1911 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
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  • 50
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1912-1915 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 51
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1916-1920 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 52
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1921-1925 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 53
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1926-1929 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 54
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1932-1932 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 55
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1933-1933 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 56
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987) 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 57
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1930-1932 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 58
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1949-1958 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The role of inter- and intraparticle transport resistances in the sensitivity behavior of a fixed-bed catalytic reactor is fully elucidated. The parametric sensitivity regions obtained using a heterogeneous one-dimensional plug flow model are reported for various values of the involved dimensionless parameters. Comparisons with previous sensitivity criteria and with experimental data are also presented.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 59
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1937-1948 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A flash-evaporation technique is used to obtain vapor deposition characteristics for the binary alkali sulfates K2SO4 + Na2SO4 at 1 atm above 1, 100 K. This technique gives results of immediate engineering interest, such as dewpoint temperatures, condensate composition and rates of vapor deposition as well as useful data on the system's thermodynamic characteristics. It is concluded that alkali sulfate deposition and vaporization in combustion environments are inevitably influenced by chemical reactions such as hydroxide formation. It is also concluded that solution nonideality is important even for homologous alkali-salt mixtures.Predictions are made using convective-diffusion mass transfer theory, accounting for chemical reactions by means of effective volatilities, and assuming regular, nonideal condensate solutions. The predicted dewpoints, condensate compositions and deposition rates are quantitatively consistent with experimental observations. This approach, validated here, can be extended to more extreme conditions of engineering interest, including turbulent, high-temperature/pressure systems.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 60
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1959-1970 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: New data and analyses are presented for describing gas and solids behavior in a slurry bubble column. Axial solids concentration and bubble size distributions were measured in a 0.108 m ID slurry bubble column apparatus operated at steady state conditions. The column was operated with and without internal baffles. The slurry and gas superficial velocities ranged from 0.0077 to 0.009 m/s and from 0.031 to 0.24 m/s, respectively. The solid phase consisted of glass spheres in a narrow size range with a mean diameter of 96.5 μm; the liquid phase consisted of tap water.With a one-dimensional sedimentation-dispersion model, the data have been used to predict average solids loadings and axial distributions of the solids for specified operating conditions. Local bubble size and concentration measurements indicate that the slurry bubble column was operated in the churn-turbulent flow regime throughout the entire range of operating conditions used in this study. The impact of internal baffles and solids concentration on the gas and solids behavior is discussed.
    Zusätzliches Material: 21 Ill.
    Materialart: Digitale Medien
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  • 61
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1977-1985 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A finite-element method is given for efficient simulation of multiphase distillation systems. Breakpoints are adaptively located to coincide with phase discontinuities. Thermodynamic criteria for the states at these discontinuities are included in the equation system. The adjustable breakpoint locations are calculated simultaneously with the other system variables by global Newton iteration. Worked examples demonstrate the accuracy and efficiency of the method.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 62
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1986-1992 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Fuzzy set theory is used to describe similarity of chemical engineering systems. The development of system similarity is given, and methods of determining a similarity relation are discussed. The system similarity relation is applied to the problems of measuring correlation confidence and quantifying modeling error. Sample problems are examined.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 63
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1971-1976 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The oxidation of CO over aluminum-supported Ag was studied at 147°C using transient experiments. Long-time-scale dynamics were observed that could not be explained by previously postulated kinetic mechanisms for this reaction system. A model is presented with kinetic parameters estimated from steady state and transient data that is able to reproduce a variety of cycled feed stream experiments. The model incorporates a slow reversible step which forms an adsorbed oxygen species that blocks reaction sites.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 64
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1993-1997 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Diffusion and chemical reaction in a catalyst pore is simulated as a Monte Carlo process. In this analysis the average diffusion distance, calculated for a large number of wall collisions, and the reaction probability are computed as two independent statistical events. This formulation yields results that compare very well with the theoretical values, yet uses minimal computer time. Results reported include typical concentration profiles and effectiveness factors for first- and second-order isothermal reactions using the method described. These results show promise of extension to more complex systems where analytical solutions are not available.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 65
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1998-2002 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In turbulent flow the equations governing the development of conversion vs. distance are not closed because of the contribution of the concentration fluctuations to the average reaction rate. Toor's hypothesis permits closure from data obtained for mixing without reaction. This paper presents a critical review of the derivation of the hypothesis and discusses its validity.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 66
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2003-2007 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A new, unobtrusive method for liquid-liquid two-phase flow data collection was proved to be reliable in this research. Drop size distributions and concentration profiles were determined for a dilute water-inkerosene system under horizontal straight pipe flow using this technique, and the Segev model for predicting concentration profiles was tested with the data collected here.The drop size distributions were found to follow a Rosin-Rammler function for a limited droplet diameter range, and the average value of the exponent in the Rosin-Rammler equation was determined to be 2.0. The velocity where the flow regime makes a transition from stratified to adequately dispersed flow was found to be between 2.0 and 2.2 m/s. Concentration profiles predicted by the Segev model were in general agreement with the profiles determined in this work, and using the proper choice of model parameters noticeably improves the model predictions.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 67
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2017-2026 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The reaction rate constant was adjusted continuously over two orders of magnitude for the unimolecular decomposition of α-chlorobenzyl methyl ether using the supercritical fluid solvent 1, 1 diffluoroethane. Activation volumes were observed as low as -6,000 cm3/mol, which is about an order of magnitude more negative than those reported previously in the literature for a homogeneous reaction. Spectral shift (solvatochromic) data were measured for phenol blue in the same fluid in order to interpret the rate data. A method is presented to predict solvent effects on rate constants at supercritical fluid conditions.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 68
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2027-2036 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Pressure-drop in cocurrent gas-liquid downflow through packed beds was experimentally measured for nonfoaming, foaming Newtonian, and non-Newtonian liquids. The variables include the column diameter, packing size and shape, flow rates of the phases, and their physical properties. Unified correlations are presented for the data of the present study as well as data available in literature in terms of Lockhart-Martinelli parameters and flow variables and packing characteristics. The data were modeled using a dynamic interaction model.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 69
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2037-2046 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: To understand better the impact of gas phase reactions on chemical vapor deposition, a new experimental method has been developed to isolate and study homogeneous reactions separately from heterogeneous reactions. This new system heats reactant gases by rapidly compressing them to temperatures greater than 1,000 K; the walls of the reactor remain constant at 500 K or less. Pressure and volume measurements determine the mean temperature of the gas. Results from a series of test reactions and simple models show that this apparatus and measurement method work well. The apparatus is inexpensive and simple to use, and has advantages over shock tubes and static systems.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 70
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2008-2016 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Mass transfer rates in laminar and turbulent nonseparated boundary layers are asymptotically expanded for small values of the diffusivity DAB, with a uniform state on the mass transfer surface. Results for heat transfer follow by analogy. The thermal or binary Nusselt number at small net mass transfer rates is given asymptotically by a generalized penetration expression \documentclass{article}\pagestyle{empty}\begin{document}$$ \langle Nu\rangle \, = \,a_{00} Pe^{1/2} \, + \,a_{01} Pe^0 \, + \,.\,.\,.\,{\rm (A)} $$\end{document} for short times, or for boundary layers that duplicate the surface tangential motion. For flows past rigid interfaces, the long-time average of 〈Nu〉 is given asymptotically by a generalized Chilton-Colburn relation \documentclass{article}\pagestyle{empty}\begin{document}$$ \langle \overline {Nu} \rangle \, = \,b_{00} Pe^{1/3} \, + \,b_{01} Pe^0 \, + \,.\,.\,.\,{\rm (B)} $$\end{document} in regions of nonrecirculating motion. The measurable functions aij and bij depend only on the system shape and laminar or turbulent velocity field. Formal expressions for a00 are given, and an expression for b00 in steady flows. These results agree well with data on mass transfer operations in tubes, packed beds, and fluid-fluid contactors.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 71
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2057-2066 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A two-parameter, corresponding-states form for direct correlation function integrals in liquids is applied to many types of systems with one substance being supercritical. This gives a quantitative correlation for volumetric behavior, pure and mixed solvent Henry's constants, and Henry's Law deviations over wide ranges of conditions using only pure-component information and a single binary parameter. Details of the method and results are given for H2, N2, CO, CH4, and other gases in pure and mixed simple, polar, and aqueous solvents and coal oils. Because of its reliable predictive capability, the present approach can serve as a generator of data for parameter estimation by other models such as equations of state.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 72
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2047-2056 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Data and finite-element simulations are presented for the blade coating of a series of Newtonian and non-Newtonian fluids. Numerical simulations for purely viscous fluids show good agreement with coating thickness data for Newtonian and relatively inelastic non-Newtonian liquids, including geometries for which lubrication theory is inaccurate. These simulations account for the shape of the free surface, with surface tension included, and incorporate realistic inflow and outflow boundary conditions. By comparing pressure distributions generated with the finite-element technique to those calculated using lubrication theory, it is shown that the simple lubrication theory analysis suffers from inadequate inflow and outflow boundary conditions. Comparison of these simulations with new experimental results for three well-characterized viscoelastic liquids, having nearly identical steady shear viscosities but different normal stress behavior, confirms speculations of earlier work with respect to the effect fluid rheology has on coating thickness.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 73
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2067-2076 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A detailed kinetic model for the bulk styrene polymerization initiated by symmetrical diperoxyester bifunctional initiators is presented. When chain termination occurs via a combination termination mechanism, six distinct polymeric species are identified in accordance with the nature of the polymer end units. It is shown that the unequal thermal decomposition characteristics of the peroxides of the bifunctional initiator system lead to the formation of polymers having considerably higher molecular weight than those obtained by the monofunctional intiator systems. It has also been found that high monomer conversion, high molecular weight, and narrow molecular weight distribution can be obtained simultaneously by using the bifunctional initiators at high reaction temperatures. This is due to the reinitiation and propagation of inactive polymers carrying undecomposed peroxides. The molecular-weight-increasing effect of the bifunctional initiator is more pronounced at high reaction temperatures. The new possibilities of increasing the monomer conversion and controlling the polymer molecular weight properties more effectively through the use of bifunctional initiators are discussed.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 74
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2080-2083 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 75
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2077-2079 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 76
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2084-2086 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 77
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2087-2090 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 78
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2091-2092 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 79
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2092-2093 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 80
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2092-2092 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 81
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2093-2093 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 82
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 83
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2094-2094 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 84
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2095-2096 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 85
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 86
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2096-2096 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 87
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2094-2095 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 88
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2096-2097 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 89
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2097-2097 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 90
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2098-2100 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 91
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1187-1196 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A model including the effects of diffusion and convection can be used to predict the etch rate of crystalline silicon in a plasma discharge of nitrogen trifluoride. The case of a radial flow reactor with crystalline silicon wafers located at discrete positions can be solved using a finite-element solution to a boundary value problem. Such a model is useful to predict the effects of pressure, flow rate of etchant gas, percent silicon exposed, and wafer position on both inter-and intrawafer etch rates. It was found from modeling that greater uniformity in etch rate is achieved by lowering the pressure and percent exposure of silicon, and to a lesser degree the volumetric flow rate.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 92
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1207-1211 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 93
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1197-1206 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A model of an isothermal bubble column slurry reactor for an arbitrary reaction network of R independent reactions and S reacting species has been developed. The model accounts for gas velocity variations due to a change in total number of moles during reaction, and for nonuniform catalyst distribution due to gravity settling. It is assumed that the gas phase is in plug flow and the batch liquid phase is unmixed, which is characteristic of pilot plant reactors with high aspect ratios. The minimum number of differential equations required for the complete description of the system is shown to be equal to the total number of independent reactions. A system of two series-parallel reactions, representative of Fischer-Tropsch synthesis, was used to study the effect of catalyst dispersion and model parameters on reactor performance. It was found that nonuniform catalyst distribution generally has a negative effect on conversion.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 94
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1218-1221 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 95
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1225-1227 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 96
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1229-1230 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 97
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1230-1230 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 98
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 99
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 173-176 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 100
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 179-193 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A general model is presented and used to predict the dynamic behavior of the adsorption and wash stages of biospecific adsorption (affinity chromatography) in a finite bath. The model accounts for film and diffusional mass transfer resistances as well as for the rates of interaction between adsorbates and ligands. The model is applicable to single and multicomponent biospecific as well as nonspecific adsorption, and the adsorbates may be monovalent or multivalent. The predictions of the model are compared with the experimental data of the adsorption of β-galactosidase onto immobilized anti-β-galactosidase.The results of biospecific adsorption of bivalent adsorbates indicate that a competition for ligands occurs between molecules forming one-site interaction and two-site interaction complexes. This competition can lead to the displacement of the adsorbate from the adsorbate-ligand complex whose formation is least favored.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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