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  • 1995-1999  (776)
  • 1980-1984
  • 1890-1899
  • 1995  (776)
  • Engineering General  (737)
  • Gas chromatography
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International archives of occupational and environmental health 67 (1995), S. 67-72 
    ISSN: 1432-1246
    Keywords: Dermal exposure ; Biological monitoring ; Gas chromatography ; Mass spectrometry ; Methylenedianiline
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Seven workers at a work site where methylenedianiline (MDA) was used as a curing agent for an epoxy resin were studied during 4 workdays and one weekend. Internal exposure was monitored by analysis of 4,4′-MDA in hydrolysed urine and blood. After acidic hydrolysis, MDA was extracted, derivatised by use of pentafluoropropionic anhydride, and determined by gas chromatography and mass spectrometry, with negative ion chemical ionization. There was wide variation of MDA concentrations in hydrolysed blood between the workers (range 10–60 nmol/l). Also, the urinary excretion rate varied considerably both between and within the individual workers (0–90 μmol/h). The urinary excretion displayed some variation in relation to exposed periods. The urinary levels were linearly related to the concentrations in blood (r s= 0.93,P = 0.02). The present results show the value of excretion of MDA in hydrolysed urine and concentrations in blood as means for the biological monitoring of MDA exposure. In this case, the exposure was probably mainly dermal, in spite of extensive protection measures.
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  • 2
    ISSN: 1432-0878
    Keywords: Adrenals ; Morphology ; Steroids ; Gas chromatography ; Mass spectrometry ; Clarias gariepinus (Teleostei)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract Interrenal-like tissue in male African catfish is localized in paired organs, situated retroperitoneally anterior of the kidney. Histological and enzyme-histochemical (3β-hydroxysteroid dehydrogenase) reactions were carried out on sections of these organs in order to localize steroid-producing cells. In vitro incubations were carried out to determine the steroidogenic capacity of the interrenal-like tissue. Twenty-one steroids could be identified and quantified in the incubation medium, by means of gas chromatography followed by mass spectrometry. Cortisol, 5α-and 5β-androstanedione and androstenedione together comprised about 80% of the total steroid content. In a previous study, twenty testicular steroids were detected in plasma after castration. In the present investigation we have shown that most of these steroids can be produced by the interrenal-like tissue, which thus can be considered as an extra-testicular source of gonadal steroids.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-0878
    Keywords: Key words: Adrenals ; Morphology ; Steroids ; Gas chromatography ; Mass spectrometry ; Clarias gariepinus (Teleostei)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract. Interrenal-like tissue in male African catfish is localized in paired organs, situated retroperitoneally anterior of the kidney. Histological and enzyme-histochemical (3β-hydroxysteroid dehydrogenase) reactions were carried out on sections of these organs in order to localize steroid-producing cells. In vitro incubations were carried out to determine the steroidogenic capacity of the interrenal-like tissue. Twenty-one steroids could be identified and quantified in the incubation medium, by means of gas chromatography followed by mass spectrometry. Cortisol, 5α- and 5β-androstanedione and androstenedione together comprised about 80% of the total steroid content. In a previous study, twenty testicular steroids were detected in plasma after castration. In the present investigation we have shown that most of these steroids can be produced by the interrenal-like tissue, which thus can be considered as an extra-testicular source of gonadal steroids.
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  • 4
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Retention-structure correlation ; Molecular descriptors ; Polycyclic aromatics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Statistical and factor analysis have been used to test the ability of several molecular descriptors to predict the retention indexes (I) of polycyclic aromatic hydrocarbons determined on SPB-5 and SPB-20 stationary phases. Regression analysis with both columns showed that linear regression with connectivity index and bending energy of the molecules as independent variables gave the best correlation coefficients. ΔI 20–5, considered to be a measure of the polar forces in retention, gave a good correlation with the van der Waals radii of the molecules, or strain, and bending energy.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 41 (1995), S. 15-22 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Average velocity of carrier gas ; Compressibility of carrier gas ; Pneumatic parameters of carrier gas
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary This report was conceived as a source for the relations between five pneumatic parameters of carrier gas-inlet and outlet pressure, inlet and outlet velocity, and average velocity. Any pair of these parameters can be independent while the remaining three can be expressed as functions of the independent pair. As the total number of the independent pairs is ten, thirty different functions describing relations between arbitrary independent pairs and dependent parameters can be identified. All thirty were derived below together with the complete set of bounds for variations of independent parameters. To derive some relations, a third order rational equation had to be solved. Some properties of that solution are discussed. A simple case of vacuum operations with zero outlet pressure has also been considered.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 41 (1995), S. 37-42 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Temperature programming ; Isothermal measurements ; Column efficiency ; Dead time
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary If the dependence of HETP on temperature is specified under isothermal conditions, it is possible to predict the HETP for programmed temperature elution and subsequently peak width at half-height. This requires knowledge of isothermal retention time at retention temperature, which is computed by means of a model including the variation with temperature of dead time estimated from 3 homologs with carbon number: n, (n+j), (n+jk), where n, j and k are any integers. Predicted and measured peak widths corresponded within 4–9%.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 41 (1995), S. 678-684 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Solid phase micro extraction ; Graphitized carbon black ; Volatile organic compounds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary This paper presents the results obtained using fused-silica fibers coated with graphitized carbon black (Carbograph-Alltech) for solid-phase microextraction (SPME). The extraction and calibration curves relative to organic micro-pollutants present in gaseous and aqueous samples are reported. Examples of applications of this extraction procedure to GC and GC-MS analysis of organic micro-pollutants in actual samples are also reported.
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  • 8
    ISSN: 1612-1112
    Keywords: Gas chromatography ; New stationary phase ; Packed columns ; Specific retention volumes ; Activity coefficients
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The synthesis of 3-bromo-4-(4-methylbenzyloxy)azobenzene (BMBOA) and its use as a stationary phase in packed columns are described. Chromatographic characteristics such as column efficiency, polarity (McReynolds constants) and operating temperature range were studied. Retention factors, specific retention volumes and activity coefficients for alcohols, esters, ketones, aromatic hydrocarbons andn-alkanes were determined. Phenols and 2,3, and 4-chlorobenzyl chlorides were separated on the new phase. Based on experimental data some assumptions were made on the possible types of intermolecular forces between solute and solvent.
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  • 9
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Linear temperature programming ; Tekler-equation extension ; Retention index precalculation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary An extension of Rohrschneider's concept to the field of the linear temperature programmed gas liquid chromatography, is proposed, which is based on Antoine's equation for the temperature dependence of the reduction index of Takács et al. and Tekler. The new method presented in this paper, applied to retention data of two stationary phases of low polarity, PS-255 and OV-105, gives a new possibility of precalculating retention data.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 40 (1995), S. 550-556 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Open tubular columns ; Short chain fatty acids ; Intestinal fluids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A capillary gas-liquid chromatography method for the analysis of free short chain fatty acids in intestinal samples was developed. Analytical results obtained with intestinal samples are influenced not only by high molecular mass matrix constituents but also by matrix components with a molecular weight smaller than 5000 daltons. To achieve a faithful transfer of SCFA into the chromatographic system it was important to avoid accumulation of involatile deposits on the surface of the inlet liner. Cleaning of the inlet linear lead to a significant weakening of matrix effects. The method described, using an Innowax column, is more effective, particularly with respect to precision and sensitivity, and is clearly superior to packed columns. The capillary is the column of choice for the separation of short fatty acids in samples from the small intestine and stomach.
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  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 41 (1995), S. 726-727 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Retention indices ; Correlation equations ; n-Alkenes ; n-Alkynes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The correlation equations between Kovats retention indices ofn-alkenes andn-alkynes, column temperature and number of carbon atoms in molecules of these compounds on OV-101, OV-225 and PEG 20M capillary columns have been calculated. The two variable equationI=A+B·n+C/T give a good fit and are the simplest for prctical use.
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  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Plant systematics and evolution 194 (1995), S. 55-67 
    ISSN: 1615-6110
    Keywords: Onagraceae ; Clarkia ; Gas chromatography ; mass spectrometry ; monoterpenes ; benzyl esters ; floral fragrances ; intraspecific variation ; moth pollination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Clarkia breweri (Onagraceae) is the only species known in its genus to produce strong floral fragrance and to be pollinated by moths. We used gas chromatography-mass spectrometry (GC-MS) to identify 12 abundant compounds in the floral headspace from two inbred lines ofC. breweri. These volatiles are derived from two biochemical pathways, one producing acyclic monoterpenes and their oxides, the other leading from phenylalanine to benzoate and its derivatives. Linalool and linalool oxide (pyran form) were the most abundant monoterpenoids, while linalool oxide (furan form) was present at lower concentrations. Of the aromatic compounds detected, benzyl acetate was most abundant, whereas benzyl benzoate, eugenol, methyl salicylate, and vanillin were present as minor constituents in all floral samples. The two inbredC. breweri lines differed for the presence of the additional benzenoid compounds isoeugenol, methyleugenol, methylisoeugenol, and veratraldehyde. We also analyzed floral headspace fromC. concinna, the likely progenitor ofC. breweri, whose flowers are odorless to the human nose. Ten volatiles (mostly terpenoids) were detected at low concentrations, but only when headspace was collected from 20 or more flowers at a time. Trans-β-ocimene was the most abundant floral compound identified from this species. Our data are consistent with the hypothesized recent evolution of floral scent production and moth pollination inC. breweri.
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  • 13
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Phosphine ; Flame photometric detection ; Anaerobic bacteria
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A gas chromatographic method is presented which distinguishes phosphine from hydrogen sulfide and other possible headspace gases of anaerobic microbial cultures. In anaerobic cultures spiked with phosphine, this gas is recovered in the liquid and gaseous phase down to 10 pg per ml of gas or liquid. No biogenically produced phosphine was found. Phosphine in amounts as small as 30 ng per 1 can be stored for several days in glass bottles covered with rubber septa, filled with nitrogen, in the presence or absence of water or of an anaerobic bacterial culture. Due to the selectivity of the detector and the retention characteristics of the porous layer open tubular polymer column alkanes, alkenes and organosulfur compounds routinely found in anaerobic bacterial headspaces do not interfere with the analytical quantification of phosphine.
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  • 14
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Liquid crystals ; Internal and external NO2 compounds ; Transition temperature ; Analytical properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Thermal and analytical properties of two liquid crystals containing internal [2-nitro, 3-methyl 4-(4-heptylbenzoyloxy) 4′-methylazobenzene] and external NO2 [2,3-dimethyl 4-(4-heptylbenzoyloxy) 4′-nitroazobenzene] have been investigated by gas chromatography. Transitions temperatures are determined by inverse gas chromatography using standard columns. Good agreement with values determined by differential scanning calorimetry are found. Analytical capabilities of the two liquid crystals are shown in glass capillary columns. Compared to examples in the literature, the crystals used separated different kinds of solutes. In addition, high molecular mass solutes were eluted at relatively low temperatures. Typical separations are observed for hydrocarbon positional isomers, aromatic hydrocarbons, geometric isomers, and volatile aroma compounds. Comparison between the performance of internal and external, NO2-liquid crystals is made.
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  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 41 (1995), S. 722-725 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Mixed stationary phases ; Distilled beverages ; Direct analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The analysis of spirits with a single stationary phase is still an unsolved problem; the two amyl alcohols, ethyl acetate and acetal are not separated on a polar column, methanol and acetaldehyde coelute from an apolar column. Trials with coupled columns of different polarities showed that optimum results were obtained with a 40 m capillary column, comprising 6 m of Carbowax 20 M, 12 m of 1∶1 Carbowax 20M:OV1 mixture and 30 m of PS 264. Best results were achieved when a 1 m retention gap was used, injecting a small amount of sample and using a 7 cm syringe needle.
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  • 16
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Column liquid chromatography ; Polychlorinated biphenyls ; Cod liver oil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary By application of a chromatographic column filled with Supelclean ENVI-Carb/Celite and elution with three solvents of different polarity three PCB fractions were obtained. Fraction A contained poly-ortho PCBs, Fraction B mono-ortho PCBs, and Fraction C non-ortho PCBs. The Supelclean ENVI-Carb/Celite column was used in combination with a sample preparation procedure for pre-cleaning of acid-stable chlorinated hydrocarbons such as DDT and its metabolites, HCH isomers, and regulation-relevant PCB congeners. The method was optimized using standard solutions of 55 PCB congeners, 8 chlorinated pesticides and contaminated cod liver oil samples. The influence of traces of remaining matrix on the elution profile of the organochlorine compounds on Supelclean ENVI-Carb/Celite was observed. Quantitation was carried out by GC-ECD with fused silica capillary columns of different polarity.
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  • 17
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Pentacyclic triterpenes ; Maytenus aquifolium Martius ; Maytenus ilicifolia Martius ; Phytopharmaceuticals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary We report a method for the analysis of triterpenes in aqueous alcoholic extracts ofM. ilicifolia orM. aquifolium leaves, using high temperature capillary gas chromatography in polar columns (OV-17-OH). These species are popularly known in Brazil as “espinheira santa” and have proven antiulcer properties. The method consists of the pre-concentration of the triterpenes from the aqueous alcoholic extract, followed by GC analysis, which permits the determination of the presence of friedelan-3-ol and friedelin. Direct comparison with several triterpenol standards that are usually found in falsified “espinheira santa” samples but are absent in the authentic drug, showed that GC analysis clearly allows detection of the presence of friedelan-3-ol and friedelin and, therefore, permits distinguishing between authentic and false “espinheira santa” aqueous alcoholic extracts.
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  • 18
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    Springer
    Chromatographia 40 (1995), S. 417-420 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Organophosphate pesticides ; Vegetables ; Pesticide residue analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A rapid and efficient multiresidue extraction procedure using ethyl acetate and sodium sulfate has been applied to the analysis of diazinon, methamidophos, chlorpyrifos, malathion, parathion, parathion-methyl, dimethoate and monocrotophos residues in many different kinds of vegetables. No cleanup step was required Concentrated extracts were analysed by gas chromatography with flame photometric detection in phosphorus mode. Recovery studies were performed in six kinds of matrices at two fortification levels. Recoveries were in the range 80–115%. The limit of quantification of the analytical method has been estimated as 0.01 ppm for diazinon, methamidophos and malathion, 0.03 ppm for chlorpyrifos, parathion, parathion-methyl and dimethoate and 0.1 ppm for monocrotophos. Experiments showed that potentially it should be possible to develop a rapid and universally applicable method for organophosphate pesticide residues in different matrices.
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  • 19
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Continuous preconcentration method ; Vitamins D2 and D3 ; Pharmaceutical preparations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A continuous-flow method that combines on-line preconcentration and isolation with gas chromatography for the direct determination of vitamins D2 and D3 in oily solutions is reported. A silica gel column permits preconcentration and isolation of analytes from the vitamin D matrix, although some triglyceride (ca. 25%) is also retained. To overcome problems associated with the low volatility of triglycerides, their retained fraction is further transesterified with potassium methylate to fatty acid methyl esters after elution. The proposed method was applied to the determination of vitamin D in pharmaceutical preparations.
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  • 20
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Cholesterol ; Direct injection ; Saponification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A rapid and direct gas chromatographic (GC) method for determining free cholesterol in milk fat using a capillary column and programmed-temperature vaporizerinjector was assayed. It was compared with other procedures involving saponification of fat, solvent extraction of unsaponifiable matter—with and without fractionation by thin-layer chromatography—and transformation of sterols into silyl derivatives prior to GC analysis. This paper proposes an alternative to other published procedures. Repeatability of the method was assessed and the coefficient of variation determined as 2.1%. The alternative saponification method exhibited comparable accuracy (coefficient of variation=1.8%). Recovery ranged from 99.1% to 105.6%.
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  • 21
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    Springer
    Chromatographia 41 (1995), S. 107-111 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Metal complex stationary phases ; Specific interactions ; N-benzoylthiourea groups
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Silica was modified with γ-aminopropyltriethoxylsilane, and then the amino group was converted into an N-benzoylthiourea compound. Treatment with anhydrous CuCl2 solution, gave a copper(II) complex on the surface. In order to estimate the ability of the complex to interact specifically with electron donors, a number of retention parameters were determined for three groups of compounds showing electron-donor properties: ketones, ethers and nitroalkanes. On the basis of the results, the effect of adsorbate structure on the strength of specific interactions was established. The packings studied may be useful for the analysis of the mixtures of ketones, ethers, and nitroalkanes.
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  • 22
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Matrix solid phase dispersion (MSPD) ; Fruit and vegetables ; Pesticide residues ; Selective detectors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A comparison between different element selective detectors for the determination of organophosphorus and organochlorine pesticide residues, from fruit and vegetables, was performed by capillary GC with electron capture detector (ECD), nitrogen phosphorus detector (NPD), flame photometric detector (FPD) in the sulphur and phosphorus modes, and mass spectrometry detector (MSD) in selected ion monitoring (SIM) mode. Pesticides were extracted from the different foodstuffs by Matrix Solid Phase Dispersion (MSPD). Recoveries of 41–108 % with relative standard deviation of 2–14 % in the concentration range 0.5–10 μg L−1 were obtained in oranges, lemons, grapefruit, pears, plums, lettuces and tomatoes. The results demonstrated that the extracts of all the samples can be analyzed by the detectors used since no interfering co-extracted compounds were detected.
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  • 23
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    Springer
    Chromatographia 41 (1995), S. 553-560 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Gas chromatography ; Experimental design ; Modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Experimental Design methodology allows the modelling and optimization of the chromatographic separation of similar pesticides (triazine family) by GC and HPLC. The GC separation of simazin and atrazin is well modelled by a first degree equation, involving injected volume, carrier gas pressure and rising oven temperature. The LC is modelled by a second degree equation, depending on injected volume, eluent flow and composition. These calculated models allow easy optimization of the separations, using isoresponse curves.
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  • 24
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Organic volatile pollutants ; Adsorbents ; Breakthrough volumes ; Thermal desorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A comparison of some adsorbents, commonly used for trapping trace volatile organic pollutants followed by thermal desorption, is presented. The evaluation has been performed on 12 compounds representative of the main classes of organic substances. Breakthrough volumes and desorption recoveries have been measured. Every adsorbent gave good results for a range of compounds, but none were able to cover all the compounds examined. Thus, a multilayer trap utilising the best features of each adsorbent was introduced with very good results.
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  • 25
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Enantiomer separation ; Chiral polysiloxane ; Amino acids ; Physicochemical properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The polysiloxane backbone of the gas chromatography phase Chirasil-Val has been modified by replacing one methyl group per dialkylsiloxy unit by pentyl and hexyl groups, respectively. The new phases offer the advantage of reduced polarities and softening points, while the separation factors (α) of enantiomeric pairs of N,O-trifluoroacetyl amino acid propyl esters show small but intriguing deviations from those determined on Chirasil-Val.
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  • 26
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Atomic emission detection ; Aqueous samples ; Solid-phase extraction ; Organophosphorus pesticides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary An on-line, solid-phase extraction gas chromatography atomic-emission detection (SPE-GC-AED) system has been set up using an on-column interface to transfer 100 μl of desorbing solvent to the GC part of the system. Analytical characteristics such as recovery, precision and linearity of calibration plots were comparable with those of the off-line combination of SPE-GC-AED using organophosphorus pesticides as test compounds. The fully on-line set-up causes a marked improvement in detection because of the quantitative transfer of the analytes from the SPE module to the GC: detection limits are as low as 5–20 ng l−1 for the analysis of 10 ml raw and spiked surface water samples using the phosphorus channel. Detection levels can be further enhanced by processing up to 100 ml samples. The integrated analytical system is robust. The potential of the on-line set up has been demonstrated for the analysis of surface water and waste water.
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  • 27
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Column liquid chromatography ; On-line coupling ; Ion-exchange membrane ; Ion-pair reagent
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary In order to enable the coupling of reversed-phase liquid chromatography (RPLC) with capillary gas chromatography (GC), the performance of an anion-exchange micromembrane device has been studied to remove the ion-pair reagent methanesulphonic acid from an acetonitrile/water LC eluent. The regenerant in the membrane was tetrabutylammonium hydroxide dissolved in acetonitrile/water, which effects an anion-exchange of methanesulphonate ions for regenerant hydroxide ions. The efficiency of the exchange process was found to be 99.9%. This enabled the direct introduction of the LC eluent, free of ions and with the proper acetonitrile/water ratio, into the GC. The applicability of the on-line LC-micromembrane-GC system has been illustrated for the potential drug eltoprazine, which is quantitatively recovered with a coefficient of variation for standard solutions of 3% at the 150 μg/ml analyte level.
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  • 28
    ISSN: 1612-1112
    Keywords: Gas chromatography ; ASPEC ; Trazodone in plasma ; Method automation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary An automated sample preparation module, (the automated sample preparation with extraction columns, ASPEC), was interfaced with a capillary gas chromatograph (GC) by means of an on-column interface. The system was optimised for the determination of the antidepressant trazodone in plasma. The clean-up of untreated plasma was carried out with disposable C18 cartridges, using several washing steps. The analyte was desorbed with methanol, the extract was diluted on-line with buffer and preconcentrated on a PLRP-S trapping column. The trapping column was dried by purging with nitrogen gas. Desorption (phase switching) of the trapping column was carried out with ethyl acetate which was introduced into a retention gap using partially concurrent solvent evaporation conditions. Trazodone was determined by GC with flame ionisation detection (FID). With a 1 ml sample, this resulted in a detection limit for trazodone in plasma of 3 ng/ml. The system showed good linearity and repeatability in the range 0.01–1 μg/ml, thus covering the range of pharmacokinetic/dynamic-to-therapeutic concentrations of trazodone in plasma. Preliminary results for benzodiazepines are promising. They indicate that the use of a selective detector such as the nitrogen/phosphorus detector, is to be recommended.
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  • 29
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Packed column separations ; C1−C4 alcohols ; Ethers ; Gasoline
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A number of oxygenated compounds such as C1−C4 alcohols, methyl tert-butyl ether (MTBE), and tertamyl methyl ether (TAME) are increasingly being used in gasoline as octane boosters and to reduce vehicular emissions. Monitoring of individual oxygenates in gasoline is important for quality control and regulatory purpose. Although, several analytical methods based on gas chromatography have been reported, a need was still felt to develop a simple and cost effective method of analysis. In this paper, a packed column gas chromatographic method is described for the analysis of C1−C4 alcohols, MTBE and TAME over a wide concentration range (2–20% V/V) in gasoline. The method involves determination of alcohols and ethers separately on two different columns. The alcohols are determined on a 20 ft column packed with poly(ethylene glycol) 400 as a stationary phase while the ethers are analysed on a 20 ft OPN-Poracil C column. The analysis of alcohols on poly(ethylene glycol) 400 column also provides data on aromatic components of gasoline.
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  • 30
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    Chromatographia 41 (1995), S. 183-186 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Correlation equation ; Alkylbenezenes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A detailed statistical analysis, comparing the validity of the best literature recommended equations for prediction of retention indices of alkylbenzenes on squalane and methylsilicone stationary phases with the unified retention index concept, is presented. A comparison with literature sources shows that the unified retention index provides the smallest residual error. Hence, it can be applied for prediction purposes.
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  • 31
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Reversed-flow technique ; Catalysis ; Ring opening
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Kinetic parameters for the ring opening of cyclohexane over modified ZSM-5 zeolites can be measured simultaneously under non-steady state conditions using reversed-flow gas chromatography. At relatively low temperatures, the main product detected and measured was propene. The mathematical relations used for the calculation of adsorption-desorption rate constants, surface reaction rate constants and adsorption equilibrium constants for the reactant cyclohexane are different from previously studied catalytic reactions, owing to the different experimental arrangement for feeding the catalytic bed. The diffusion bands obtained experimentally for reactant or product are described by the sum of two or three exponential functions of time, respectively. From the exponential coefficients of time and the pre-exponential factors, all determined by simple PC programs, the above kinetic parameters are calculated.
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  • 32
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Binary stationary phase ; Self-associating phase components ; Retention model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The dependence of specific retention by a binary stationary phase in GC can be expressed as the sum of the products of the specific retention of the pure components times their respective volume fractions. In this study, however, one component has a site, which is not only mainly responsible for the selectivity, but also participates in strong self-association. This requires introduction of a concentration-dependent factor (μx) in the corresponding term of the equation correlating Vg mix x with x. In the GC resolution of N-trifluoroacetyl-amino acid isopropyl esters on a binary phase, N-lauroyl-L-amino t-butyl amide-squalane, data for the values of μx were obtained. Adapting a previously developed LC retention model to the above GC data, an equation was derived for the dependence of μx on the weight fraction (x) of the selector, namely μx=√1/x. This relationship permits calculation of retention volumes on the binary phase for a given x, as well as corresponding resolution coefficients of enantiomeric amino acid derivatives with generally excellent agreement with experiment. The chirality of the system is not relevant to application of the equation.
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  • 33
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    Chromatographia 41 (1995), S. 419-423 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Headspace analysis ; Microcapillary columns ; Short columns ; Volatile compounds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A new method of analysis using headspace gas chromatography with microcapillary columns is proposed. Small diameter (50 μm I.D.) fused-silica capillary columns with non-extractable SE-54 and PS-255 polysiloxane stationary phases were used for the analysis of low boiling organic compounds. The small diameter columns possess the usual very high efficiency so that the method can be employed for the headspace analysis of complex mixtures. The use of short microcolumns reduces the analysis times in comparison to conventional capillary columns. Good performances were obtained in the analysis of volatile compounds in some lemon essential oil, perfumes, and water samples.
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  • 34
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    Chromatographia 41 (1995), S. 594-598 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Capillary column ; Bicyclic spiro ketones ; Tricyclic spiro ketones ; Retention index at different temperatures ; Retention vs stationary phase polarity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The separation of some aromatic bicyclic and tricyclic spiro ketones on fused silica capillary columns coated with polydimethylsiloxane, cyanopropylmethylsiloxane and poly(ethylene glycol) stationary phases was investigated. Retention indices were determined at two temperatures in order to enable understanding of the compounds' chromatographic behaviour. The respective standard deviation values were 0.8, 0.5 and 0.3 index units. The influence of the polarity of the stationary phases on the chromatographic retention of these cyclic spiro ketones is discussed.
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  • 35
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    Communications in Numerical Methods in Engineering 11 (1995), S. 13-23 
    ISSN: 1069-8299
    Keywords: mass transport problems ; error estimation ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In order to make an exact estimation of discretization error for finite/infinite element methods, it is necessary to develop analytical solutions for some transient mass transport problems in infinite media. These transient mass transport problems may be viewed as the benchmark problems for the discretization error estimation of a new numerical method so that they generally have the following characteristics: (1) their initial and boundary conditions can be exactly modelled by the finite/infinite element method; (2) their solutions can be rigorously expressed in a closed form. In this paper, several of the aforementioned problems have been constructed and solved mathematically for transient mass transport problems in both 1D and 2D infinite media.
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  • 36
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    Communications in Numerical Methods in Engineering 11 (1995), S. 25-32 
    ISSN: 1069-8299
    Keywords: Riccati equation ; transmission line modelling ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this communication, the application of the transmission line modelling (TLM) technique to the solution of the differential Riccati equation is described. A comparison is made between the TLM, fourth-order Runge-Kutta and the first-order Gear methods, for the case where one is applying the Kalman filter to the estimation of a voltage in a passive analogue circuit. In the particular example studied, the state equation is second-order. It is found that, when the system is underdamped, the fourth-order Runge-Kutta method has the best performance, followed by the TLM method. When the system is overdamped and stiff, the TLM method yields results that are closest to the analytical solution. Finally, a discussion is presented of the effects of errors in the TLM solution of the Riccati equation on the accuracy of the solution to the continuous Kalman filter estimation equation.
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  • 37
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    Communications in Numerical Methods in Engineering 11 (1995), S. 49-58 
    ISSN: 1069-8299
    Keywords: gears ; fracture mechanics ; service life ; fatigue process ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper describes the influence of contact area on the service life of dynamically loaded gears with a crack in a tooth root. Numerical results obtained with the finite element method using the program package BERSAFE are compared with the experimental results obtained on the universal testing machine INSTRON 1255. Numerical and experimental results are in good agreement. The analysis shows that the contact area directly influences the speed and direction of the crack propagation and the service life of the gear with a crack in a tooth root.
    Additional Material: 11 Ill.
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  • 38
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    Communications in Numerical Methods in Engineering 11 (1995), S. 41-47 
    ISSN: 1069-8299
    Keywords: shear correction ; laminates ; cylindrical bending hypothesis ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Mindlin-type plate and shell finite elements are the most widely used ones in the analysis of laminated composite structures. In the commercially available finite element programs, the transverse shear correction factors for these elements are usually the same as for structures made of isotropic materials. In the paper the shear correction factors are determined using energy principles for general laminates in cylindrical bending. Results for various materials and laminates are presented.
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  • 39
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    Communications in Numerical Methods in Engineering 11 (1995), S. 59-68 
    ISSN: 1069-8299
    Keywords: RLW equation ; finite elements ; splines ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A B-spline finite element method is used to solve the regularized long wave equation numerically. This approach involves a Galerkin method with quadratic B-spline finite elements so that there is continuity of the dependent variable and its first derivative throughout the solution range. Time integration of the resulting system of ordinary differential equations is effected using a Crank-Nicolson approximation. Standard problems are used to validate the algorithm, which is then used to model the smooth development of an undular bore.
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  • 40
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    Communications in Numerical Methods in Engineering 11 (1995), S. 69-72 
    ISSN: 1069-8299
    Keywords: finite element method ; thermoplasticity ; internal dissipation ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In the paper, a simple modification of the internal dissipation term in coupled thermoplastic finite element equations is presented. A modified form of the heat capacity and the thermomechanical coupling matrices are derived. These modifications are based on a decomposition of the internal dissipation term into two parts, which depend on the total strain rate and the rate of temperature change, respectively.
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  • 41
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    Communications in Numerical Methods in Engineering 11 (1995), S. 91-92 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 42
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    Communications in Numerical Methods in Engineering 11 (1995), S. 93-94 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 43
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    Communications in Numerical Methods in Engineering 11 (1995), S. 179-185 
    ISSN: 1069-8299
    Keywords: finite elements ; fluid flow ; open boundaries ; Sommerfield boundary conditions ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: We examine a method to impose boundary conditions on arbitrary boundaries, introduced to make domains of infinite extent finite for the purpose of numerical calculations, when a finite element discretization based on linear, bilinear or trilinear elements is used, in one, two or three dimensions, respectively. In particular, we look at the so-called ‘free’ boundary condition, which consists in retaining the boundary integrals generated by the weighted-residuals formulation along the open boundaries and adding them to the stiffness matrix. We show that this procedure is exactly equivalent to imposing on the boundary nodes a Sommerfeld radiation condition in one dimension, and a slightly modified form of the Sommerfeld boundary condition in two and three dimensions. We also show that the procedure is not applicable to the purely elliptic case.
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    Communications in Numerical Methods in Engineering 11 (1995), S. 189-190 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 45
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    Communications in Numerical Methods in Engineering 11 (1995), S. 187-188 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 46
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    Communications in Numerical Methods in Engineering 11 (1995) 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 47
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    Communications in Numerical Methods in Engineering 11 (1995), S. 191-198 
    ISSN: 1069-8299
    Keywords: triangulations ; mesh relaxation ; computational geometry ; planar mesh generation ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Recent advances in planar mesh generation of arbitrary domains incorporate methods for placing points as well as connecting them into a triangulation. Postprocessing techniques such as Laplacian smoothing and mesh relaxation enhance the shape of triangles in these meshes but do not address the construction of meshes near boundaries or provide a criterion to determine the number of interior points of the initial triangulation. The paper addresses these issues by investigating the construction of degree-6 triangulations, the primary goal of the mesh relaxation method.
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  • 48
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    Communications in Numerical Methods in Engineering 11 (1995), S. 227-233 
    ISSN: 1069-8299
    Keywords: finite element analysis ; distributed computing ; structures ; client-server model ; remote procedure calls ; structural mechanics ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper presents a distributed computing approach for concurrent finite element analysis of truss structures. The client-server model of distributed computation is applied to the plane frame finite element algorithm and implemented on SUN workstations. The remote procedure call combined with the ability to create threads of computation allows one to efficiently implement distributed and concurrent programs. The present approach is demonstrated through a typical truss structure to illustrate the details of the implementation. This approach can be used for very large finite element systems.
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  • 49
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    Communications in Numerical Methods in Engineering 11 (1995), S. 199-211 
    ISSN: 1069-8299
    Keywords: SUPG ; Petrov-Galerkin methods ; finite elements ; explicit scheme ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This work is devoted to the simulation by finite elements of nearly incompressible inviscid flows in real 3D geometries, by means of an Euler code based on the SUPG (streamline upwind Petrov-Galerkin) method, explicit forward Euler pseudo-temporal time integration and periodic and absorbing boundary conditions, among other features. The main goal is the application to flow around turbomachinery, with special emphasis on the performance analysis of a given machine, that involves several numerical computations at different operation points. Finally, these results are summarized in the form of characteristic curves.
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  • 50
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    Communications in Numerical Methods in Engineering 11 (1995), S. 213-226 
    ISSN: 1069-8299
    Keywords: a posteriori error estimates ; asymptotic exactness ; finite elements ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A posteriori error estimation for typical Euler-Bernoulli beam bending problems is developed using a recovery operator based on a smoothing technique that is applied in the context of one-dimensional fourth-order problems. The development exploits a discrete superconvergence property of the ‘bending moments’ of the trial space interpolant of a polynomial solution of sufficiently low degree at certain Gauss points, and the superconvegence property of the energy norm difference of the trial space interpolant (of the weak solution) and the finite element approximation. An asymptotically exact error estimator is developed.
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  • 51
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    Communications in Numerical Methods in Engineering 11 (1995), S. 243-254 
    ISSN: 1069-8299
    Keywords: fracture ; boundary elements ; superposition ; stress intensity factor ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: We discuss a two-step superposition method for calculating linear elastic stress intensity factors. The procedure requires the solution to the full cracked problem and the solution to a problem on the same mesh assuming the singularity due to a crack tip in an infinite region. We show that this is equivalent to the well known subtraction of singularity method if the two solutions are characterized by crack tip stress. The advantages of our procedure are that no modifications need to be made to a standard computer program and that once one singular solution is available on a given cracked mesh, solutions with different boundary conditions on the same mesh may be obtained in one step without including any singular crack effects. The mesh required to represent the singular crack tip field may also be studied independently of the complete problem. The additional computational cost of a two-step procedure is minimal since the solution matrix from step one may be reused with a new right-hand side. Numerical experiments using the boundary element method demonstrate the high accuracy and simplicity of the superposition approach.
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  • 52
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    Communications in Numerical Methods in Engineering 11 (1995), S. 235-242 
    ISSN: 1069-8299
    Keywords: upwinding ; iterative methods ; convection-diffusion ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The effect of upwinding on iterative performance of convection-diffusion problems is investigated. An analysis of the iterative method considered here leads to a criterion for selecting the optimal upwinding parameter to improve iterative performance for a class of two-dimensional convection-diffusion problems. Supporting numerical experiments are presented.
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  • 53
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    Communications in Numerical Methods in Engineering 11 (1995), S. 267-279 
    ISSN: 1069-8299
    Keywords: dynamic interaction ; rigid wheel ; flexible beam ; contact force ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical method is presented for the analysis of dynamic interaction between rigid wheel and flexible beam. In contrast to traditional approaches, the wheel nominal motion as well as the contact force are considered here as unknowns. The correct contact force between the wheel and the beam is computed by iteratively reducing the constraint error towards zero, and a simple time integration is employed for the solution of equations of motion. Convergence of the iterative scheme is analysed, and numerical simulations are conducted to demonstrate the accuracy of the solution.
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  • 54
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    Communications in Numerical Methods in Engineering 11 (1995), S. 255-265 
    ISSN: 1069-8299
    Keywords: boundary element method ; error estimation ; hp-version ; Galerkin BEM ; numerical results ; elasticity ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper investigates the convergence of the h-, p- and hp-versions of a variational symmetric boundary element method (BEM) in plane elasticity by numerical experiments. The study discusses mixed boundary value problems on polygonal domains, i.e. problems for which the exact solution is analytic except in a finite number of points. The convergence of the error in energy norm is displayed for all versions of the BEM. All results are also compared with those obtained by the corresponding finite element methods. The theoretically predicted asymptotic convergence rates for all versions of the method can be observed in the numerical experiments. A comparison of computer times is given as well.
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  • 55
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    Communications in Numerical Methods in Engineering 11 (1995), S. 281-282 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
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  • 56
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    Communications in Numerical Methods in Engineering 11 (1995), S. 283-284 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
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  • 57
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    Communications in Numerical Methods in Engineering 11 (1995), S. 285-286 
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    Keywords: Engineering ; Engineering General
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  • 58
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    Communications in Numerical Methods in Engineering 11 (1995) 
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  • 59
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    Communications in Numerical Methods in Engineering 11 (1995), S. 287-296 
    ISSN: 1069-8299
    Keywords: eigenvalues ; integral transforms ; analytical methods ; convection ; Sturm-Liouville system ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The integral transform method is employed in the analytical solution of the non-classical eigenvalue problem that appears in connection with the analysis of forced convection in ducts, including the effect of fluid heat diffusion in the axial direction. The related eigenfunctions are expanded in terms of eigenfunctions from a simpler auxiliary eigenvalue problem, and the original eigenvalues are determined from the associated matrix eigensystem analysis. Convergence rates of the proposed solutions are illustrated and reference results established for different values of the governing parameters.
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  • 60
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    Communications in Numerical Methods in Engineering 11 (1995), S. 355-362 
    ISSN: 1069-8299
    Keywords: permanent heavy waves ; circular shaped channels ; conformal mapping ; Fatou's method ; Levi-Civita's decomposition ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Because of the earth's curvature, all existing channels have a curvature. E. Zeidler gave an existence and uniqueness proof for permanent heavy and capillar-heavy waves in such circular shaped channels. Based on this proof and on a general computational method for constructing the solutions numerically, the case of permanent heavy waves in circular-shaped channels is considered in this work.
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    Communications in Numerical Methods in Engineering 11 (1995), S. 373-374 
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    Keywords: Engineering ; Engineering General
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    Communications in Numerical Methods in Engineering 11 (1995), S. 375-377 
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    Keywords: Engineering ; Engineering General
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    Communications in Numerical Methods in Engineering 11 (1995), S. 379-381 
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    Keywords: Engineering ; Engineering General
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  • 65
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    Communications in Numerical Methods in Engineering 11 (1995), S. 363-371 
    ISSN: 1069-8299
    Keywords: matrix multisplitting ; relaxed method ; convergence ; divergence ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this paper, I discuss the convergence and divergence rates for a class of generalized matrix multisplitting relaxation methods in a detailed manner. In particular, when the coefficient matrix is an L-matrix, I obtain several sufficient and necessary conditions ensuring the convergence of these methods.
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  • 66
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    Communications in Numerical Methods in Engineering 11 (1995), S. 383-390 
    ISSN: 1069-8299
    Keywords: finite elements analyses ; global and local analyses ; multiregion ; interfaces ; interpolation functions ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: An independent refinement and integration procedure is developed to couple together independently modelled (global and local) regions in a single analysis. The finite element models can have different levels of refinement and the nodes along the interface between them need not coincide with one another. A spline interpolation function that satisfies the linear isotropic plate-bending differential equation is used to relate the local model interface nodal displacements to the global model interface displacements. The proposed independent refinement and integration procedure is validated by applying it to problems involving in-plane and out-of-plane deformations.
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    Communications in Numerical Methods in Engineering 11 (1995), S. 391-401 
    ISSN: 1069-8299
    Keywords: boundary element method ; two-dimensional potential problems ; logarithmic kernel ; derivative kernal ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Both the logarithmic and derivative kernel integrations for potential problems, solved with quadratic isoparametric boundary elements, contain quartic functions of the integration parameter. It is shown that such functions can be written as the product of two quadratic functions with real coefficients. The derivative kernel integration is then represented as the sum of two integrals, which can be evaluated analytically. The logarithmic kernel integration can be similarly split but needs a Taylor series expansion of the Jacobian of the integration to enable analytical integration. The use of this Taylor series expansion means that the method presented is limited to problems involving weakly curved elements.
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    Communications in Numerical Methods in Engineering 11 (1995), S. 403-407 
    ISSN: 1069-8299
    Keywords: finite element method ; residual bending flexibility ; convergence ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this paper I re-examine the mechanics of the residual bending flexibility correction and show that it is an extravariational trick.
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    Communications in Numerical Methods in Engineering 11 (1995), S. 417-426 
    ISSN: 1069-8299
    Keywords: discrete elements ; dynamic analysis ; impact ; impulsive loads ; elastoplastic response ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The determination of the dynamic response of plate and shell structures is carried out employing a discrete representation of the continuum, associated with an explicit integration scheme in the time domain. Comparisons with experimental results certify the accuracy and reliability of the proposed method.
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    Communications in Numerical Methods in Engineering 11 (1995) 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Communications in Numerical Methods in Engineering 11 (1995), S. 547-548 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 72
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    Communications in Numerical Methods in Engineering 11 (1995), S. 563-573 
    ISSN: 1069-8299
    Keywords: constraints ; boundary conditions ; rigid inclusions ; inextensibility ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Constraints arise naturally in the context of rigid inclusions, incompressibility, inextensible fibres and deformed finite elements. Typical methods for handling constraints in the governing matrix equation include Lagrange multipliers, penalty weights and elimination of variables. Each procedure has a particular undesirable feature. Proposed here is an approach in which each constraint is handled directly and sequentially through a modification of the rows and columns of the governing matrix and force vector. Positive definiteness, symmetry and the dimensions of the matrix remain unchanged. Elementary examples involving both the static and dynamic response of a bar are given to illustrate the procedure.
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  • 73
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    Communications in Numerical Methods in Engineering 11 (1995), S. 549-562 
    ISSN: 1069-8299
    Keywords: plate problem ; Reissner-Mindlin ; finite elements ; hierarchic elements ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The focus of the present work is directed towards the construction of a family of special finite elements for the numerical solution of the Reissner-Mindlin plate problem. The model describes the deformation of a plate when transverse shear deformation is taken into account. The model is widely used for thin to moderately thick plates. Despite its simple formulation, the numerical approximation is not straightforward. When standard low-order finite elements are used for the approximation the solution degenerates very rapidly for small thickness (locking phenomenon). To overcome such behaviour, non-standard formulations of the problem are usually combined with low-order finite elements to weaken or possibly eliminate the locking of the numerical solution.In recent years high-order finite elements have been introduced and successfully applied in several fields. Previously we have constructed a family of hierarchic high-order finite elements to solve the Reissner-Mindlin problem in its plain formulation. The locking was strongly reduced but was still active for very thin plates. Meanwhile some mixed-interpolated finite elements have been developed and shown to be locking free. In this paper we combine the two approaches, namely, the hierarchic high-order elements and the mixed-interpolated elements. The result is a family of special finite elements that exhibits both properties of convergence and robustness.
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    Communications in Numerical Methods in Engineering 11 (1995), S. 629-629 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Communications in Numerical Methods in Engineering 11 (1995), S. 631-632 
    ISSN: 1069-8299
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 76
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    Communications in Numerical Methods in Engineering 11 (1995), S. 981-993 
    ISSN: 1069-8299
    Keywords: boundary element method ; boundary geometry ; smooth modelling ; Lagrange elements ; Overhauser elements ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper reveals the conditions under which the approximations of the normal vector and global coordinates of interior points of two segments on a smooth contour can fail using the C1-continuous Overhauser elements. A new continuous modelling of the normal vector is developed using the standard Lagrange elements. The derivation is consistent with the assumptions employed in the boundary element method formulations of potential problems. Test numerical examples are considered in order to analyse the accuracy of the approximations based on the use of standard C0-continuous elements, Overhauser C1-continuous elements and the proposed ‘smooth’ C0 elements.
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    Communications in Numerical Methods in Engineering 11 (1995), S. 1039-1045 
    ISSN: 1069-8299
    Keywords: pure advection ; Lagrangian treatment ; control volume ; QUICKEST scheme ; large Courant numbers ; accuracy ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper describes a new numerical algorithm for pure advection at large Courant numbers. The DISCUS scheme uses an accurate and proven control volume algorithm (QUICKEST) within a Lagrangian treatment of advection. By being in sympathy with the information flow dictated by characteristic lines, the scheme performs exceedingly well at Courant numbers greater than one. In contrast to existing Lagrangian schemes which use the characteristics to determine the grid points from which concentrations are interpolated, in DISCUS the characteristics are used to determine the appropriate location for the control volume. The scheme is of comparable accuracy to Eulerian schemes at Courant numbers less than one, but it increasingly outperforms them as the Courant number increases. Indeed, the results reported illustrate the futility of using an Eulerian scheme at high Courant numbers.
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  • 78
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    Journal of High Resolution Chromatography 18 (1995), S. 19-27 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Large volume injection ; PTV injectors ; PTV splitless injection ; PTV solvent split injection ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Temperature programmable injectors with liner diameters ranging from 1 to 3.5 mm are evaluated and compared for solvent split injection of large volumes in capillary gas chromatography. The liner dimensions determine whether a large sample volume can be introduced rapidly or has to be introduced in a speed controlled manner. The effect of the injection technique used on the recovery of n-alkanes is evaluated. Furthermore the influence of the liner diameter on the occurrence of thermal degradation during splitless transfer to the analytical column is studied. Guidelines are given for the selection of the PTV liner internal diameter best suited for specific applications.
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  • 79
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    Journal of High Resolution Chromatography 18 (1995), S. 289-294 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Supercritical fluid chromatography ; FT-IR spectrometry ; Characterization ; Silicones ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Materials used in the manufacture of silicone breast prostheses were analyzed by supercritical fluid chromatography (SFC) and high temperature gas chromatography (GC) coupled with direct deposition FT-IR detection. The chromatographic resolution and deposition quality were found to be unsatisfactory for SFC/FT-IR; however, high temperature GC/FT-IR produced excellent results. The chromatograms and spectra obtained allowed for the identification of poly-dimethyl silicones and mono-, di-, and tri-diphenylsubstituted poly-dimethyl silicones. An automated method of baseline correction was developed that allowed functional group chromatograms due to molecules containing Si-phenyl bonds to be constructed without significant interference from Si-methyl bonds despite the fact that the Si-C stretching mode of Si-phenyl bands overlapped significantly with the strong bands due to Si-CH3 groups.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 421-432 
    ISSN: 0029-5981
    Keywords: grid generation ; locally analytic ; elliptic equations ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: One technique for obtaining grids for irregular geometries is to solve sets of elliptic partial differential equations. The solution of the partial differential equations yields a grid which discretizes the physical solution domain and also a transformation for the irregular physical domain to a regular computational domain. Expressing the governing equation of interest in the computational domain requires the derivatives of the physical to computational domain transformation, i.e., the metrics. These metrics are typically determined by numerical differentiation, which is a potential source of error. The locally analytic method uses the analytic solution of the locally linearized equation to develop numerical stencils. Thus, the locally analytic method allows numerical differentiation with no loss of accuracy. In this paper, the locally analytic method is applied to the solution of the Poisson and Brackbill-Saltzman equations. Comparison with an exact solution shows the locally analytic method to be more accurate than the finite difference method, both in solving the partial differential equation and evaluating the metrics. However, it is more computationally expensive.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 509-522 
    ISSN: 0029-5981
    Keywords: Laplace transform ; finite element ; viscoelastic beam ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The quasi-static and dynamic responses of a linear viscoelastic beam are solved numerically by using the hybrid Laplace transform/finite element method. In the analysis, the Timoshenko beam theory, which includes the transverse shear and rotatory inertia effect and conventional beam theory, are used to solve this problem. The temperature field is assumed to be constant and homogeneous and that the relaxation modulus has the form of the Prony series. In the hybrid method, the Laplace transform with respect to time is applied to the coupled equations and the finite element model is developed by applying Hamilton's variational principle without any integral transformation. The numerical results of quasi-static and dynamic responses for the models of Maxwell fluid and three parameter solid types are presented and discussed.
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    International Journal for Numerical Methods in Engineering 38 (1995) 
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    Keywords: Engineering ; Engineering General
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 685-716 
    ISSN: 0029-5981
    Keywords: hourglass and locking control ; large strains ; thermomechanical coupling ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this paper, a class of ‘assumed strain’ mixed finite element methods based on the Hu-Washizu variational principle is presented. Special care is taken to avoid hourglass modes and shear locking as well as volumetric locking. An unified framework for the 4-node quadrilateral solid and thermal as well as thermomechanical coupling elements with uniform reduced integration (URI) and selective numerical integration (SI) schemes is developed. The approach is simply implemented by a small change of the standard technique and is applicable to arbitrary non-linear constitutive laws including isotropic and anisotropic material behaviours. The implementation of the proposed SI elements is straightforward, while the development of the proposed URI elements requires ‘anti-hourglass stresses’ which are evaluated by classical constitutive equations. Several numerical examples are given to demonstrate the performance of the suggested formulation, including static/dynamic mechanical problems, heat conduction and thermomechanical problems.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 717-734 
    ISSN: 0029-5981
    Keywords: finite elements ; arbitrary Lagrange-Euler ; free surfaces ; surface tension ; contact angles ; multiphase flow ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The arbitrary Lagrange-Euler (ALE) kinematic description has been implemented in a 3-D transient finite element program so as to simulate multiple fluid flows with surfaces and interfaces of general shapes.The description of fluid interfaces includes continuity of velocity and a discontinuous tangential and normal stress appropriate for fluids of variable interfacial tension.The formulation is particularly relevant to the description of low and intermediate Reynolds number flow dominated by interfacial tension.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 667-683 
    ISSN: 0029-5981
    Keywords: Navier-Stokes ; pseudospectral element method ; multi-grid method ; domain decomposition ; Schwarz Alternating Procedure (SAP) ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A new multi-grid (two-grid) pseudospectral element method has been carried out for solution of incompressible flow in terms of primitive variable formulation. The main objective of the proposed method is to apply the multi-grid technique solving the incompressible flow problems associated with three commonly encountered multi-grid environments. In domain decomposition terminology, it includes (I) partially overlapped subdomains, each of which has same types of grids; (II) partially overlapped subdomains, each of which has different types of grids; (III) local adaptive subdomains fully overlapped with the original computational domain (composite grids).The approach for flow problems, complex geometry or not, is to first divide the computational domain into a number of subdomains with the inter-overlapping area (partially or fully overlapped). In categories I and II, the fine-grid or coarse-grid subdomains can be defined by their representation, while in category III the fine-grid or coarse-grid subdomains are defined as usual. Next, implement the Schwarz Alternating Procedure (SAP) to exchange the data among subdomains, where the coarse-grid correction is used to remove the high frequency error that occurs when the data interpolation from the fine-grid subdomain to the coarse-grid subdomain is conducted. The strategy behind the coarse-grid correction is to adopt the operator of the divergence of velocity field, which intrinsically links the pressure equation, into this process. The solution of each subdomain can be efficiently solved by the direct (or iterative) eigenfunction expansion technique or preconditioned method with the least storage requirement, i.e. O(N2) in 2-D.Numerical results of (i) driven cavity flow (Re = 100,400) with Cartesian grids (category I) in each subdomain, (ii) driven cavity flow (Re = 3200) with local adaptive grids (category III) in each subdomain, and (iii) flow over a cylinder (Re = 250) with ‘O’ grids in one subdomain and Cartesian grids in another (category II) will be presented in the paper to account for the versatility of the proposed multi-grid method.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 735-754 
    ISSN: 0029-5981
    Keywords: inverse problem ; contact conductance determination ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The conjugate gradient method using two search step sizes is used to solve the inverse problem of simultaneously estimating the periodic thermal contact conductance, hc(t), and the heat transfer coefficient of the exhaust gases, hg(t), between the exhaust valve and seat in an internal combustion engine. The importance of the determination of hc(t) and hg(t) lie in that they are the critical factors for designing the cooling system and the insulation of the exhaust valve.The inverse analysis is based on the temperature measurements taken from the sensors placed in both the valve and seat regions during the transient process of operation. In this study two unknown timewise-varying functions hc(t) and hg(t) are to be estimated at the same time, thus two search step sizes with each one corresponding to each unknown function are derived. The results show that the CPU time for the inverse solutions using two search step sizes are greatly reduced than using just one search step size1 for the determination of two unknowns, besides, it also shows that the inverse solutions are reliable even when the measurement errors are considered.The advantage of the conjugate gradient method is that no a priori information is needed on the variation of the unknown quantities, since the solution automatically determines the functional form over the domain specified. The successful development of the present technique can be applied to any kind of two-dimensional periodic contact problems, such as the determination of a two-dimensional contact conductance problem2 and the temperature or heat flux behaviour on the inside wall of internal combustion engines3.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 775-795 
    ISSN: 0029-5981
    Keywords: computational mechanics ; finite element method ; a posteriori error estimation ; finite elasticity ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Methods for a posteriori error estimation for finite element solutions are well established and widely used in engineering practice for linear boundary value problems. In contrast here we are concerned with finite elasticity and error estimation and adaptivity in this context. In the paper a brief outline of continuum theory of finite elasticity is first given. Using the residuals in the equilibrium conditions the discretization error of the finite element solution is estimated both locally and globally. The proposed error estimator is physically interpreted in the energy sense. We then present and discuss the convergence behaviour of the discretization error in uniformly and adaptively refined finite element sequences.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 755-773 
    ISSN: 0029-5981
    Keywords: staggering ; numerical simulation ; bounded dispersion ; cost ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper presents a cost-effectiveness analysis of explicit Finite Difference (FD) methods for the numerical integration of the wave equation. Formal notions of computational cost (expressed in floating point operations) and numerical dispersion error are introduced. Restricting the analysis to leapfrog timemarching, for sake of simplicity, various spatial discrete differentiators are examined. For each scheme, by minimizing the cost at a given error threshold, a cost-effective operating poin (time sampling rate and number of gridpoints per shortest wavelength) is obtained, which is remarkably different from the stability limit. Different schemes, each operated at its cost-effective point, are then compared. High-order dispersion-bounded operators, in the sense of Holberg,1 are found to be competitive with the Pseudo-spectral (PS) method.New optimal schemes improving over the Holberg's spatial differentiators are introduced together with accurate expansions of the convolutional weights is terms of the design error threshold. It is also shown that the composition of two distinct Holberg's operators of consecutive orders, with opposite phase properties, minimizes dispersion and yields cost-effective schemes.Numerical experiments illustrate the suitability of the new methods for large-scale wave-equation seismic modelling.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 797-808 
    ISSN: 0029-5981
    Keywords: bounding-surface ; plasticity ; non-linear ; space structures ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper presents a method for the non-linear analysis of space structures subjected to static and cyclic loading. A bounding-surface kinematic hardening plasticity model is used to simulate the hardening and hysteritic material behaviour. The model is used in conjunction with the lumped plasticity assumption coupled with the concept of a yield surface in force space. A hardening coefficient matrix which is a function of the plastic strain and the elastic stiffness matrix is introduced while the vectorial nature of the material memory parameters is maintained. This provides a smooth transition from the elastic to the plastic regime which simulates the hysteresis loops quite accurately. An updated Lagrangian formulation is used together with a predictor/corrector solution method. Several examples are presented to demonstrate the accuracy and efficiency of the method.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 809-821 
    ISSN: 0029-5981
    Keywords: moment method ; non-linear electromagnetics ; scattering ; dielectrics ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this paper, we explore the possibility of applying the moment method to determine the electromagnetic field distributions inside three-dimensional bounded non-linear dielectric objects of arbitrary shapes. The moment method has usually been employed to solve linear scattering problems. We start with an integral equation formulation, and derive a non-linear system of algebraic equations that allows us to obtain an approximate solution for the harmonic vector components of the electric field. Preliminary results of some numerical simulations are reported.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 823-839 
    ISSN: 0029-5981
    Keywords: numerical algorithms ; path following technique ; non-linear equations ; non-linear finite elements ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A general and robust solution procedure for non-linear finite element equations with limit points is developed. At each equilibrium iteration the magnitude of the load is adjusted such that the residual force is orthogonal to the current displacement increment from the last equilibrium state. The method implements the physical condition that the orthogonal residual force will neither increase nor decrease the magnitude of the current displacement increment vector. The orthogonality condition is formulated directly in terms of conjugate variables and therefore does not contain any scaling parameters. Passage of load and displacement limit points is discussed as well as the relation to line search, minimum residual, and are-length methods. The method is illustrated by two examples.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 841-860 
    ISSN: 0029-5981
    Keywords: constitutive modelling ; large strain ; creep ; elastoplasticity ; damage ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A three-dimensional fully coupled creep elastoplastic damage model at finite strain for isotropic non-linear material is developed. The model is based on the thermodynamics of an irreversible process and the internal state variable theory. A hyperelastic form of stress-strain constitutive relation in conjunction with the multiplicative decomposition of the deformation gradient into elastic and inelastic parts is employed. The pressure-dependent plasticity with strain hardening and the damage model with two damage internal variables are particularly considered. The rounding of stress-strain curves appearing in cycling loading is reproduced by introduction of the creep mechanism into the model. A numerical integration procedure for the coupled constitutive equations with three hierarchical phases is proposed. A consistent tangent matrix with consideration of the fully coupled effects at finite strain is derived. Numerical examples are tested to demonstrate the capability and performance of the present model at large strain.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 881-881 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 861-879 
    ISSN: 0029-5981
    Keywords: wet snow accretion ; rotating sleeves ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: It is the purpose of this paper to construct a mathematical/computational model for the accretion of snow on rotating snow sleeves attached to conductor rods, and to consider some of the limitations in the use of the assumption of perfect cylindrical-sleeve growth, as currently employed to provide estimates of snow-loading intensity.For purposes of illustration, three rotating snow accretion regimes are considered, in which the direction of the airflow is always taken as perpendicular to the axis of the conductor rod. Firstly, a horizontal conductor rod is free to rotate and is initially bare. Rotation of the system (conductor rod and accreted snow) is initiated by snow torque, due to eccentric snow loading on the windward side of the conductor, and is driven by aerodynamic torque generated by the windflow past the evolving, rotating, asymmetrical sleeve growth. Secondly, a vertical conductor rod is free to rotate and the bare rod is given an initial small angular velocity; the rotation of the accreting system is then driven by aerodynamic torque alone. Thirdly, a horizontal rod is fixed and is initially covered by an annulus of snow, supported by a thin layer of (unfrozen) water existing between the conductor and the snow sleeve. In this case, the rotation of the snow sleeve is due to the combined snow and aerodynamic torques and is now retarded by the viscous torque due to the rotating thin film of water.Asymptotic solutions obtained for small accretion time supplement numerical results derived from the computational models. Numerical results on these rotating non-periodic snow accretion regimes are presented as a function of the wind speed, snow precipitation rate and diameter of the conductor rod.
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 883-884 
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    Keywords: Engineering ; Engineering General
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    International Journal for Numerical Methods in Engineering 38 (1995) 
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    Keywords: Engineering ; Engineering General
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 885-886 
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    Keywords: Engineering ; Engineering General
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    International Journal for Numerical Methods in Engineering 38 (1995), S. 887-903 
    ISSN: 0029-5981
    Keywords: plates ; foundation ; boundary elements ; boundary integrals ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper introduces an efficient boundary element approach for the analysis of thin plates, with arbitrary shapes and boundary conditions, resting on an elastic Winkler foundation. Boundary integral equations with three degrees-of-freedom per node are derived without unknown corner terms. A fundamental solution based upon newly defined modified Kelvin functions is formulated and it leads to a simple solution to the problem of divergent integrals. Reduction of domain loading terms for cases of distributed and concentrated loading is also provided. Case studies, including plates with free-edge conditions, are demonstrated, and the boundary element results are compared with corresponding analytical solutions. The presented formulations provide a very accurate boundary element solution for plates with different shapes and boundary conditions.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 38 (1995) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 100
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 38 (1995), S. 927-942 
    ISSN: 0029-5981
    Keywords: quasi-conforming FEM ; geometrical non-linearity ; degenerated solid shell element ; plates ; shells ; pitch test ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this paper, a geometrically non-linear quasi-conforming nine-node quadrilateral degenerated solid shell element has been constructed from generalization of a linear quasi-conforming nine-node quadrilateral degenerated solid shell element,10 based upon the non-linear quasi-conforming finite element method. First, the geometrical description and displacement model of the nine-node quadrilateral degenerated solid shell element is given. Then, the non-linear quasi-conforming finite element method is discussed and assumed strains and weighed functions are given. Last, analysis of numerical examples for a clamped square plate, a circular arch, a spherical shell, two cylindrical shells, the patch test and a simply supported square plate is carried out. The results are compared with exact and other finite element solutions. The results indicate that the shell element in the paper is accurate and efficient.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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