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  • 1985-1989  (11,100)
  • 1900-1904  (2,159)
  • General Chemistry  (7,244)
  • Chemical Engineering  (3,542)
  • Engineering General  (2,473)
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Year
  • 101
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1403-1404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 102
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1409-1427 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Supercritical fluids (SCF's) are powerful solvents with many unique properties. They have great potential for many extraction processes, but reliable and versatile mathematical models of the phase equilibrium thermodynamics are needed for their use in process design and economic feasibility studies. This paper reviews existing experimental data and analytical methods and attempts to delineate their strengths and limitations. Also discussed are new data needs and possible new directions for a better fundamental understanding of the molecular processes in SCF solutions.
    Additional Material: 13 Ill.
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  • 103
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1457-1464 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Parameterization with respect to the aqueous reflux ratio has been carried out for the steady-state analysis of a tower to dehydrate secbutanol using disecondary butyl ether as the entrainer. With an equilibrium-stage model, singularities are observed as the second liquid phase is introduced on the trays and regions of steady-state multiplicity are demonstrated. Furthermore, a critical aqueous reflux ratio, in the vicinity of which two liquid phases are introduced on most of the trays, varies only slightly with the number of trays in the tower. The model predicts that the product purities and recoveries remain high using one-third of the trays in the industrial SBA-II tower. Bifurcation analysis for a single stage does not explain these observations, and the effect of recycle is suspected.
    Additional Material: 14 Ill.
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  • 104
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1487-1496 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This work presents a phenomenological correction to improve a classical equation of state for representing phase equilibria and densities in the vapor-liquid critical region. This correction consists of two steps. The first step is a volume translation which locates the correct critical point; this volume translation also improves density predictions for pure fluids and mixtures. The second step provides a near-critical contribution to the residual Helmholtz energy which accounts for aomalous behavior near the critical point. For pure fluids, the near-critical contribution flattens the coexistence curve and pressure-density isotherms near the critical point. For mixtures, the near-critical contribution has only a small effect on the calculated coexistence curve; this effect is often masked by the choice of binary parameters in the classical equation which have a more profound effect on the calculated results.
    Additional Material: 11 Ill.
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  • 105
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1678-1684 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mass transfer system has been designed to allow transport of only one component and over small changes in concentration. One of the phases was always lamellar liquid crystals, the other was micellar or its inverse structure. It can be argued that the kinetics of phase transformation at the interphase would be important in such systems; in fact, the measurements of individual phase volumes show overshoots that are not explained by classical mass transfer mechanisms. It is suggested that the intermediate structures that are formed during transport are not thermodynamically favored, and consequently the condition of local equilibrium does not hold. Using developments for such systems in diffusion in polymers, the breakdown of local equilibrium has been shown to be adequate in explaining the observations qualitatively. A parallel development for adsorption has not been undertaken.
    Additional Material: 7 Ill.
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  • 106
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1701-1709 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The axial distribution of solid holdup was investigated in a bubble column of 0.07 m in diameter and 4.25 m in height. The particle phase was glass beads of diameter 66, 118, 243, 465 or 1,300 μm. The effective slip velocity and the axial dispersion coefficient of the solid particles were evaluated in batch operation without solids feed and were correlated on the basis of mixing length theory. The equations obtained were applied to analyze axial profiles of particle concentration with a continuous feed of solids, and experimental data in the literature were simulated successfully over a wide range of solid concentration.
    Additional Material: 14 Ill.
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  • 107
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1728-1734 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pulse gas chromatography experiments at ambient pressure are often limited by an overwhelming contribution of axial dispersion to the observed variance and the inability to obtain a quantitative correction for this factor. Theoretically, the axial dispersion contribution can be reduced and at the same time the contribution due to particle diffusion can be enhanced by operating at elevated pressures. Our experiments on methane/helium diffusion in 0.32-cm-diameter commercial catalyst particles confirm this, and a new means of accounting for axial dispersion is demonstrated.
    Additional Material: 8 Ill.
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  • 108
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1749-1752 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 109
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1761-1769 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Methods are described for calculating the effects of hydrodynamic interactions on the hindered transport of solid spherical macromolecules in ordered or disordered fibrous media. These methods are applied to a medium made up of a square lattice of straight, bead-and-string-type fibers. Hydraulic permeabilities and coefficients governing hindered diffusion and convection are obtained from a detailed hydrodynamic model, and the hindered transport coefficients are shown to be in very good agreement with an effective medium approach based on Brinkman's equation. The use of Brinkman's equation for the calculation of hindered transport rates in fibrous membranes and gels is validated further by comparing with experimental data from the literature.
    Additional Material: 7 Ill.
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  • 110
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1803-1812 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Artificial neural networks have capacity to learn and store information about process faults via associative memory, and thus have an associative diagnostic ability with respect to faults that occur in a process. Knowledge of the faults to be learned by the network evolves from sets of data, namely values of steady-state process variables collected under normal operating condition and those collected under faulty conditions, together with information about the degree of the faults and their causes.Here, we describe how to apply artificial neural networks to fault diagnosis. A suitable two-stage multilayer neural network is proposed as the network to be used for diagnosis. The first stage of the network discriminates between the causes of faults when fed the noisy process measurements. Once the fault is identified, the second stage of the network estimates the degree of the fault. Thus, the diagnosis of incipient faults becomes possible.
    Additional Material: 6 Ill.
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  • 111
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1980-1992 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study was made of phenol degradation by bacteria immobilized onto particles of calcined diatomaceous earth in a draft-tube, three-phase fluidized-bed reactor.A mathematical model is used to describe simultaneous diffusion and reaction of oxygen and phenol in the reactor. Kinetic parameters for the growth of nonsupported cells were obtained in batch and chemostat experiments. Liquid-solid mass transfer coefficients were determined experimentally and showed good agreement with literature values for conventional three-phase fluidized beds. Experimental steady-state degradation data were used to calculate biofilm substrate diffusivities. These were found to decrease as the biofilm density increased.The transition from phenol to oxygen-limiting biofilm kinetics predicted by the model was shown to exist experimentally. A critical ratio of phenol/dissolved oxygen concentration was found at which this transition occurred. This provides a criterion for establishing whether increased aeration will increase the volumetric degradation rate.
    Additional Material: 7 Ill.
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  • 112
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 2043-2047 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 113
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 869-872 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 114
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 875-875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 115
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1876-1882 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The precipitation of organic particles from supercritical fluids (SF) by expansion (SFX) has become an interesting alternative to milling without thermal decomposition. Through the rapid expansion process, a dramatic change of the solute supersaturation ratio is created causing subsequent precipitation with a narrow particle-size distribution. It was found that β-carotene precipitates from SF ethylene and ethane have the feed material crystallinity. However, SF CO2 reacted with β-carotene and did not give characteristic β-carotene X-ray spectra. The mean particle sizes of these precipitates were in the submicron range (ca 0.3 μm). Increased solubility was obtained by addition of toluene as cosolvent in SF ethylene. It was found that the mean size of β-carotene particles, generally remained unchanged if the toluene concentration was less than 11/2 mol %. The SFX process appears to be in a single fluid phase when up to 11/2 mol % toluene cosolvent is used.
    Additional Material: 12 Ill.
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  • 116
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1912-1914 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 117
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 2053-2057 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 118
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 97-103 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Given the intrinsic kinetics, the tortuosity factor of a Ni/MgAl2O4 catalyst was determined under reaction conditions by minimizing the sum of squares of residuals of the experimental and the simulated conversions. The parallel cross-linked pore model with uncorrelated pore size distribution and orientation was used in the calculation of the effective diffusivities. A modified collocation method was used to obtain the partial pressure profiles of the reacting components in the catalyst pellet. The simulation of the experimental reactor during the optimization of the tortuosity factor also yielded the effectiveness factors of the reactions. The results of the simulation of an industrial steam reformer are also discussed.
    Additional Material: 7 Ill.
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  • 119
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 104-108 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Particle to gas heat transfer studies were carried out for the exothermic benzene hydrogenation and endothermic cyclohexane dehydrogenation reactions on the same catalyst bed. A recirculation type reactor and eggshell type commercial platinum on alumina catalyst were used. When the thermodynamic value for the heat of reaction is used for both reactions in the steady-state energy balance, local JH factors for the exothermic reaction were found to be, in general, higher than those for the endothermic reaction. This was attributed to product molecules leaving the catalyst surface with excess vibrational energy, which implies that the actual heat of reaction would be different than the thermodynamic value used in the JHfactor calculations. The study also indicated significant variations in the local JH factors; these were attributed to variations in the linear velocity in the radial direction.
    Additional Material: 7 Ill.
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  • 120
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 109-119 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bimetallic Mo-Fe and Mo-Co sulfide clusters were anchored on Al2O3 and used for CO hydrogenation. In addition to methane, significant amounts of dimethyl ether were produced. The reaction orders obtained from power rate laws for methanation indicated that the surfaces of the catalytic ensembles were not completely saturated by CO, in contrast to the observations for most conventional CO hydrogenation catalysts. A kinetic analysis and parameter estimation was performed to identify the rate-determining step for methanation. A catalytic cycle was postulated that could account not only for the formation of methane and higher hydrocarbons, but also for dimethyl ether as a primary product.
    Additional Material: 9 Ill.
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  • 121
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 88-96 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Intrinsic rate equations were derived for the steam reforming of methane, accompanied by water-gas shift on a Ni/MgAl2O4 catalyst. A large number of detailed reaction mechanisms were considered. Thermodynamic analysis helped in reducing the number of possible mechanisms. Twenty one sets of three rate equations were retained and subjected to model discrimination and parameter estimation. The parameter estimates in the best model are statistically significant and thermodynamically consistent.
    Additional Material: 9 Ill.
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  • 122
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 670-672 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 123
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 676-678 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Tab.
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  • 124
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 700-700 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 125
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 875-875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 126
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 881-890 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An on-line procedure is developed that uses estimates of the dominant eigenvalues of a reactor-exchanger system to detect impending unstable operating behavior. In the event reactor stability is threatened, changes are made in the reactor's nominal operating state through a procedure that ensures the attainment of an accessment is made through estimation of closed-loop eigenvalues derived from a physically-based dynamic model. The guiding of the reactor to safe and stable conditions is carried out through a multiloop control system that receives optimal process setpoints found from an interative search. Experiments were made on a laboratory autothermal reactor system to assess the correspondence of the predicted and observed degrees of reactor stability.
    Additional Material: 9 Ill.
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  • 127
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 931-942 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamic gas disengagement technique is discussed comprehensively in this paper. Also outlined is the procedure for estimating holdup structures and bubble rise velocities in a bubble column, which is extended to include the methodology for estimating the Sauter mean bubble diameter and therefore the specific gas-liquid interfacial area. The error limits for the estimated quantities are established using two extreme cases to describe the disengagement process: constant rate disengagement and interactive disengagement of bubbles. The analysis is done assuming a bimodal bubble size distribution; however, generalized equations for a multimodal bubble size distribution are also presented. Sensitivity of results to the two cases is illustrated using results obtained from experiments conducted with the air-tap water system in two bubble columns (0.05 and 0.23 m in diameter, 3 m tall). Sauter mean bubble diameters and specific interfacial areas estimated using the two approaches provide lower and upper limits for values reported in the literature.
    Additional Material: 8 Ill.
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  • 128
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1631-1638 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Calculations of the ionization constant of H2O are presented for densities ranging from those of subcritical water to those of supercritical steam. A recently-proposed semicontinuum model is used to calculate the standard-state hydration properties for the ions, H3O+, and OH- (Tanger and Pitzer, 1989). Calculated ionization constants are in good agreement with reported measurements at pressures from vapor-liquid saturation to 500 MPa and temperatures from 273 to 1,073 K. These measurements cover H2O densities ranging from ∼ 1,000 to 450 kg · m-3. At H2O densities less than 400 kg · m-3, our calculated ionization constants should be more reliable than those obtained from the commonly-used equation of Marshall and Franck (1981).
    Additional Material: 7 Ill.
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  • 129
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    AIChE Journal 35 (1989), S. 1659-1666 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental results are reported for equilibrium adsorption and diffusivities of CH4, C2H6 and CO2 in type A zeolite containing mixed Na and K cations ranging from 0 to 100% in composition, at two temperatures and 1 atm. Two simple theoretical solutions are given for the diffusivity. One is for diffusion with pore (aperture) blocking using the effective medium approximation, which is readily available from the literature on percolation theory. The other is a kinetic solution derived in this work for cavities containing heterogeneous sites, which is a case where the percolation theory is not applicable. The equilibrium adsorption results show that K+ has a preference for the aperture (or pore-blocking) sites (site type II), and these results are interpreted by the bond percolation theory. The diffusivity results are successfully interpreted by the poreblocking theory in zeolites containing less than 25% K+ and by the kinetic theory for zeolites with higher K+ contents.
    Additional Material: 11 Ill.
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  • 130
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1692-1700 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Previously published conversion data for turbulent diffusion-controlled acid-base reactions in two different multijet reactors are used to extract the mixing parameters, tracer probability density function, and variance. The PDF is obtained with this instantaneous reaction method by differentiating twice the reactive mixing plot of mean reactant concentrations. The limiting behavior for the cases of complete segregation and complete mixing is derived and turns out to be piecewise linear on the reactive mixing plot. The variance is shown to be twice the area between the actual reactive mixing curve and the limiting curve for complete mixing; it can be computed by numerical integration without any foreknowledge of the PDF shape. The method, in principle, allows detection of Dirac delta functions (which represent unmixed virgin fluid) and indeed shows significant amounts of virgin fluid close to the inlet of one of the reactors.
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  • 131
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1735-1738 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 132
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    AIChE Journal 35 (1989), S. 1745-1748 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 133
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    AIChE Journal 35 (1989), S. 1791-1802 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of the char-steam gasification reaction and the accompanying pore structure changes have been investigated experimentally and interpreted through the use of the random pore model of Bhatia and Perlmutter (1980) and its extensions developed in this study. To allow model evaluations, surface areas and pore-size distributions were obtained for various partially-reacted char samples. Surface areas follow the reaction rates as a function of conversion, supporting the interpretation that the reaction of porous char with steam is governed by the structural changes that occur as conversion proceeds. Reaction rate constants were obtained from the kinetic data.A pyrolytic change of char mass was observed during the heatup period from room temperature to reaction temperature for each of the two char samples tested. This results in a significant increase in surface area and a decrease in pore structure parameter. It is shown that this pore structure parameter is very sensitive to changes in conversion when the initial parameter is large and the conversion is small.
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  • 134
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    AIChE Journal 35 (1989), S. 1821-1828 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of partial external wetting of catalyst particles on conversion for hydrodesulfurization of dibenzothiophene in a white oil was studied in a 25-mm trickle-bed reactor at 10 MPa and 330-370°C with Mo/SiO2 catalyst. The superficial liquid velocity (Lm) was varied from 0.092 to 0.557 kg · m-2 · s-1. Measurements of conversion were augmented by tracer, kinetics and solubility experiments. The objectives were to determine the parameters of a reactor model based on the multizone external wetting (MZEW) model for the overall effectiveness factor, ηo, and to compare the measured and predicted values of ηo. As the wetting efficiency, f, increases, ηo also increases, but, even at the highest Lm, catalyst wetting was not complete and consequently ηo was lower than the value corresponding to f = 1. The MZEW model describes the experimental data better than the simpler two-zone model, based on a particular interpretation of f. The difference between the two models can be as high as 200%.
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  • 135
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    AIChE Journal 35 (1989), S. 1856-1868 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The paper presents a design procedure to generate parity equation models for analytical failure detection and isolation. The models are in “statistically-isolable” structure that prevents incorrect isolation decisions under marginal failure size if the residuals are tested in parallel. Of the combinatorial multitude of structurally-suitable models, a choice is made on the basis of sensitivities with respect to different failures and robustness relative to uncertainties in selected parameters of an underlying model. A complete set of parity equations fitting the isolable structure is first generated from a state-space model. The equations unsuitable for sensitivity are eliminated, and a suboptimally-robust diagnostic model is obtained in a constrained discrete search over the remaining set.
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  • 136
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    AIChE Journal 35 (1989), S. 1894-1894 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 137
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    AIChE Journal 35 (1989), S. 511-513 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 138
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    AIChE Journal 35 (1989), S. 775-792 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A quantitative model of softening coal pryolysis is developed and tested against observed behavior. The model treats intraparticle transport of gases and metaplast throughout the softening stage of pyrolysis via growth of bubbles uniformly dispersed in the molten coal. The model quantitatively describes the transient softening behavior including the initiation, duration, and magnitude of plasticity and swelling of the particle. The model kinetic parameters are derived from experiments, in which a highly softening Pittsburgh No. 8 bituminous coal was pyrolyzed, and total weight loss, and yields and molecular weight distributions of tars and pyridine extractables of cooled chars were measured. Model predictions of effects of pressure, particle diameter and temperature on tar yields and weight losses, of effects of pressure on swelling ratio, and of effects of heating rate on plasticity are presented. The model provides good fits to the laboratory data and predicts trends in pyrolysis behavior in good qualitative accord with expectations based on published data.
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  • 139
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    AIChE Journal 35 (1989), S. 845-848 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 140
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    AIChE Journal 35 (1989), S. 490-499 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Orthogonal collocation is used to analyze the dispersion and chemical conversion of a multicomponent fluid pulse in a laminar isothermal flow in a catalytic tube. Homogeneous and heterogeneous first-order chemical reactions are included, and a full matrix diffusion law is used. The collocation method represents the dynamics well over wide ranges of system parameters and reaction time. Radial averaging approaches prove less convenient, since the dispersion coefficients thus introduced are complicated functions of time, transport properties and chemical kinetics.
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  • 141
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    AIChE Journal 35 (1989), S. 523-526 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 142
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    AIChE Journal 35 (1989), S. 876-876 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 143
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  • 144
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    AIChE Journal 35 (1989), S. 690-693 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 145
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    AIChE Journal 35 (1989), S. 701-701 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 146
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    AIChE Journal 35 (1989), S. 714-724 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Using the principles of conservation of mass and momenturn for each phase, a theory is developed for describing quantitatively the sedimentation of colloidal particles in vessels having electrodes that are inclined to the vertical.As a limiting case, a kinematic settling formula was derived that describes the motion of settling fronts of colloidal alumina particles suspended in tetralin as a function of angle of inclination and strength of applied electric field in terms of electrophoretic mobilities. A hydrodynamic computer model shows the flow patterns and settling behavior of such lamella settlers with and without an applied electric field. The predicted motions of the settling fronts and the thicknesses of the clear boundary layers above the upper wall of the inclined vessels globally agreed with the experimental observations.
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  • 147
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    AIChE Journal 35 (1989), S. 755-763 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The loading of organic molecules adsorbed on high surface area carbon materials can be influenced by the potential of the surface. This phenomenon can form the basis for carbon regeneration and for separation processes. A theoretical treatment demonstrates that adsorption loading becomes more sensitive to potential change when the double layer capacitance of the interface and the size of the organic species are increased. An experimental method was developed to estimate isotherm parameters. The technique was demonstrated on model adsorbates, pentanol and heptanol. The values of the measured isotherm parameters (B = 3.4-9.1 V-2: Emax = 0.36-0.5 V vs. Hg/Hg2 SO4) are in the range of expected values based on literature values for similar systems. Although only 5% of activated carbon surface area was shown to be electrochemically accessible, it still has ten times the area available for electrosorption as compared to the graphite, thus making it attractive for industrial application.
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  • 148
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    AIChE Journal 35 (1989), S. 700-701 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 149
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    AIChE Journal 35 (1989), S. 1177-1185 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical and experimental study has been carried out on flow, dissolution, and precipitation in porous media. Flow experiments were performed on linear carbonate cores using acidic ferric chloride solutions. Dissolution of the carbonate by the acid causes an increase in the solution pH, thereby precipitating ferric hydroxide. This precipitate plugs up the pore throats in the medium and increases the resistance to fluid flow. Fluctuations in the permeability ratio were observed during core flood experiments, confirming the competition between channel formation due to dissolution and pore plugging due to precipitation. The evolution of the pore structure was characterized by Wood's metal castings.A network model has also been developed to describe flow and reaction in porous media. The model was used to simulate the ferric chloride system, and pressure oscillations predicted by the model show identical trends to those observed experimentally. Additionally, the evolution of pores in the network were graphically represented.
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  • 150
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    AIChE Journal 35 (1989), S. 1215-1218 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 151
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    AIChE Journal 35 (1989), S. 1227-1228 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 152
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  • 153
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  • 154
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 1725-1729 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 155
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 1769-1785 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Methods are described for modelling of phase change processes using the finite element method to simulate freezing and melting including convection in the melt. Evaluation of several enthalply/specific heat methods and time marching schemes is also included. Suppression of velocities in the solid region is described, and example problems are given. Comparison is made to simulations performed by other researchers using finite difference methods. Substantially different results were found for one of these problems, and this result is shown to be caused by numerical problems in the earlier work.
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  • 156
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 1813-1825 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The plane stress problem of a parallel fibre, rectangular composite sheet with variable fibre content is investigated. The resulting sheets are governed by partial differential equations that have variable coefficients, which are generally unsolvable exactly. A Ritz method is used to approximate the solution and is checked against known problems having exact solutions. The method is found to determine closely both the displacements and the stresses with fewer than 200 degrees of freedom. It is then applied to two interesting problems for which no exact solutions exist, including that of uniform normal stress applied in the direction of the fibres.
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  • 157
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 1891-1908 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper addresses the question of the optimal selection of the shape functions for p-type finite elements and discusses the effectivity of the conjugate gradient and multilevel iteration method for solving the corresponding linear system.
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  • 158
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2466-2466 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 159
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    International Journal for Numerical Methods in Engineering 28 (1989) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 160
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2517-2540 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The problem of static, non-linear, large three-dimensional deformation of riser bundles used in offshore oil and gas production is studied within the limits of small strain theory. The mathematical model consists of the models of component-risers and connectors which hold risers together. Each riser is modelled as a thin walled, slender, extensible or inextensible tubular beam-column. It is subject to non-linear three-dimensional deformation dependent hydrodynamic loads, torsion and distributed moments, varying axial tension, and internal and external fluid forces. The problem is solved numerically by developing an algorithm which features substructuring, condensation and non-linear incremental finite elements. Substructuring is used to decompose the riser bundle problem into those of individual component-risers and equilibria of connectors. Condensation is used along with the connector equilibrium equations to produce connector forces and moments. Strong non-linearities present in the model are handled by an incremental finite element approach. Accuracy of the computer code is verified by solving simple three-dimensional cases. Two three-dimensional applications are solved for a bundle with seven component-risers and up to a total of 1267 degrees of freedom. Finally, a comparison is made with numerical results of a two-dimensional analysis code. The influence of problem size on total CPU time is discussed.
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  • 161
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2609-2634 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The conceptual framework of a least squares rate variational approach to the formulation of continuously deforming mixed-variable finite element computational scheme for a single evolution equation was presented in Part I.1 In this paper (Part II), we extend these concepts and present an adaptively deforming mixed variable finite element method for solving general two-dimensional transport problems governed by a system of coupled non-linear partial differential evolution equations. In particular, we consider porous media problems that involve coupled heat and mass transport processes that yield steep continuous moving fronts, and abrupt, discontinuous, moving phase-change interfaces. In this method, the potentials, such as the temperature, pressure and species concentration, and the corresponding fluxes, are permitted to jump in value across the phase-change interfaces. The equations, and the jump conditions, governing the physical phenomena, which were specialized from a general multiphase, multiconstituent mixture theory, provided the basis for the development and implementation of a two-dimensional numerical simulator. This simulator can effectively resolve steep continuous fronts (i.e. shock capturing) without oscillations or numerical dispersion, and can accurately represent and track discontinuous fronts (i.e. shock fitting) through adaptive grid deformation and redistribution. The numerical implementation of this simulator and numerical examples that demonstrate the performance of the computational method are presented in Part III2 of this paper.
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  • 162
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2161-2174 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: An a-posteriori error estimator for finite element analysis proposed by Zienkiewicz and Zhu is analysed and shown to be effective and convergent. In addition we analyse wider classes of estimators of which the Zienkiewicz-Zhu estimator is a special case. It is shown that some of these estimators will be asymptotically exact. Numerical evidence is presented supporting the analysis.
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  • 163
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2175-2190 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In the case of nearly incompressible elastic materials the strain energy, the shear stress and the difference of normal stresses can be computed accurately by direct methods when the p-version of the finite element method is used. Computation of the sum of the normal stresses requires special procedures. In this paper such procedures are described and examples are presented.
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2123-2142 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Considerable progress has been made in recent years toward advancing the state-of-the-art in solid mechanics boundary element technology. In the present work, much of this new technology is applied in the development of a general-purpose boundary element method (BEM) for steady-state heat conduction. In particular, the BEM implementation involves the use of higher-order conforming elements, self-adaptive integration and multi-region capability. Two- and three-dimensional, as well as axisymmetric analyses, are incorporated within a unified framework. In addition, techniques are introduced for the calculation of boundary flux, and for the inclusion of thermal resistance across interfaces. As a final extension, an efficient formulation is developed for the analysis of solid three-dimensional bodies with embedded holes. For this last class of problems, the new BEM formulation is particularly attractive, since use of the alternatives (i.e. finite element or finite difference methods) is not practical. A number of detailed examples illustrate the suitability and robustness of the present approach for steady-state heat conduction.
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    International Journal for Numerical Methods in Engineering 28 (1989) 
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    Keywords: Engineering ; Engineering General
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  • 166
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2191-2202 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This note reports numerical experiments on the efficiency of simple error estimates derived earlier1 applied to incompressible mixed or related penalty type formulations. The rate of convergence and performance of various mixed elements is compared. Numerical results from a driven cavity and an incompressible elastic problem demonstrate that the T6B1/3D and T6/3C elements give a faster rate of convergence than the T6/1D element. However, in the case of a plane extrusion analysis (stronger singularity), the rate of convergence for the T6B1/3D element drops and is inferior to that of the T6/1D, while the T6/3C element still proves superior to the other two elements.
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2839-2853 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The Zienkiewicz-Zhu error estimator is shown to be effective in problems of plate flexure. When used in conjunction with triangular elements and an adaptive mesh generator allowing a prescribed size of elements to be developed, very fast adaptive convergence for results of specified accuracy is achieved.
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  • 168
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2889-2906 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The construction of changing sequences of irregular and nested triangulations, based on the use of conforming refinement/derefinement algorithms for triangulations, is presented and discussed. This strategy is particularly appropriate to combine adaptivity and full multigrid algorithms for dealing with moving fronts or fluid dynamics problems. It is shown that the quality of all the triangulations iteratively generated depends only on the geometric characteristics of the initial grid. A data structure suitable to create, manage and modify series of nested triangulations as well as the main features of the DEREF prototype package are described, and numerical examples are given.
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  • 169
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2923-2941 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A unified presentation of some popular continuation procedures used in the non-linear finite element analysis of structural mechanics is introduced. An extension of the elliptical constraint equation proposed by Crisfield is given. It is shown that in the proposed procedure real roots can always be obtained in solving the iterative change of the load parameter. Updated weighting factors are introduced in the constraint equation in order to get better convergence characteristics in the case when localized deformations occur. For bifurcation points a modification of Rheinboldt's branching procedure is presented. Post critical response after limit and bifurcation points is determined in some numerical examples.
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    International Journal for Numerical Methods in Engineering 27 (1989), S. 21-35 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical model system is developed to describe waves and wave-induced currents in a breakwater situation, where refraction, diffraction, reflection and wave-current interaction may all play important roles in the transformation of waves. A turbulence transport model is employed to estimate the eddy viscosity, and the friction factors associated with the major variables are clearly defined using a high level closure of combined flow bed friction. The model system is tested against a laboratory situation, and the effects of reflection are demonstrated on the wave-induced currents as well as on the wave distribution.
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    International Journal for Numerical Methods in Engineering 27 (1989), S. 3-20 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: During the past ten years various methods have been devised to deal with the solution of the Navier-Stokes equations. In the meantime, different models have been worked out to represent turbulent incompressible flows. At LNH, deep participation in this enthusiastic research is still going on, together with a closely related development of physical modelling and metrology. In this paper, we will give an insight into a set of numerical codes which are now currently in use at our laboratory and some of their main applications to coastal engineering. This will include thermohydraulic internal flows and free surface flows. For each code a short presentation of the algorithm of solution is described.
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  • 172
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    International Journal for Numerical Methods in Engineering 27 (1989), S. 71-85 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A study of linear monochromatic wave propagation is presented, based on a theory of potentials. The usual Berkhoff equation has been extended by the addition of partially pervious solid boundary effects and the bed friction.The problem has been solved by a hybrid finite element method including the effect of singular local elements such as the end of breakwaters or wharfs. This numerical method confirms the interest in quadratic Lagrangian finite elements.The comparisons with analytical solutions and existing numerical results show the validity of the method. Some original examples also prove the good performance of the proposed computation method.As an example, the study of the erosion of the beach of Calvi Bay in Corsica, France is presented. The phenomenon had started already in 1960, but the problem began to be very severe four years ago, after the implementation of a new harbour in 1982 and buildings, hotels, restaurants, and a main sewer on the beach. To consider the impact of these constructions and other factors like waves, currents and geomorphological aspects, the studies were divided into four parts: sedimentological, currents, wave propagation and geomorphological.This paper will describe the results of a complete two years study on the site, from February 1986 to December 1987.Findings show that the erosion process is due to the rise of the relative sea level with, as a catalyst, tourist behaviour and the implementation of the new constructions.
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  • 173
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    International Journal for Numerical Methods in Engineering 27 (1989), S. 469-481 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Piecewise linear finite element approximations to two-dimensional Poisson problems are treated. For simplicity, consideration is restricted to problems having Dirichlet boundary conditions and defined on rectangular domains Ω which are partitioned by a uniform triangular mesh. It is also required that the solutions u ∊ H3 (Ω). A method is proposed for recovering the gradients of the finite element approximations to a root mean square accuracy of O(h2), both at element edge mid-points and element vertices, using simple averaging schemes over adjacent elements. Piecewise linear interpolants (respectively discontinuous and continuous) are then fitted to these recovered gradients, and are shown to be O(h2) estimates for ∇u in the L2-norm, and thus superconvergent. A discussion is given of the extension of the results to problems with more general region and mesh geometries, boundary conditions and with solutions of lower regularity, and also to other second-order elliptic boundary value problems, e.g. the problem of planar linear elasticity.
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  • 174
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 109-126 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper presents the development of a straightforward displacement type triangular finite element for bending of a flat plate with the inclusion of transverse (or lateral) shear effects. The element has twenty two degrees of freedom consisting of ten for the lateral displacement of the midplane and six for rotations of the normal to the undeformed midplane of the plate. The latter are taken as independent of the slopes of the deformed midplane in order to include deformation due to transverse shear. The element is fully conforming and may be orthotropic. At interelement boundaries, the element matches adjacent elements both with respect to lateral displacement of the midplane and the rotations of the normal. The result is an efficient ‘linear moment’ triangular element but with transverse shear deformation included. Numerical computations for a number of examples are presented. The results show the element to be more flexible than most other finite element models and agree closely with those from a numerical solution of the three dimensional elasticity equations. The results also converge to those from thin plate theory when the thickness to length ratio becomes small or when the transverse shear moduli are artificially increased.
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  • 175
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 237-237 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 176
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 279-293 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: An iterative solution procedure for a frictionless contact problem is presented. Convergence to the exact solution is guaranteed by an error reduction method, and the rate of convergence is drastically improved by reduction of the ratio of extreme eigenvalues of the iteration matrix. For an ordinary linear equation, the present technique has the same theoretical value of convergence rate as the Chebyshev acceleration technique. The present acceleration technique can be directly extended for complicated frictional contact problems.
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  • 177
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 415-430 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Moving finite element methods are adaptive gridding procedures especially designed for systems of partial differential equations whose solutions contain steep gradients. A new moving finite element method based on quadratic approximation functions is presented. Both the theoretical and computational aspects are outlined. Performance of the method is illustrated with solutions to Burgers' equation. The solution is accurate and remarkably smooth in the entire domain.
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  • 178
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 1461-1473 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: An enriched finite element model for linear elastic fracture mechanics is developed for a mixed variational statement. The independent approximations for the displacement and stress components are enriched by adding the near-field analytic expressions for a cracked body to the polynomial approximations of a conventional element. This allows for an accurate representation of the stress and displacement fields near the crack tip and also results in the direct calculation of the appropriate stress intensity factors. The accuracy of this formulation is demonstrated through several numerical examples.
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  • 179
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    International Journal for Numerical Methods in Engineering 28 (1989) 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 180
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 1521-1537 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The nature of the crack and the structure behaviour can range from ductile to brittle, depending on material properties, structure geometry, loading condition and external constraints. The influence of variation in fracture toughness, tensile strength and geometrical size scale is investigated on the basis of the π-theorem of dimensional analysis. Strength and toughness present in fact different physical dimensions and any consistent fracture criterion must describe energy dissipation per unit of volume and per unit of crack area respectively. A cohesive crack model is proposed aiming at describing the size effects of fracture mechanics, i.e. the transition from ductile to brittle structure behaviour by increasing the size scale and keeping the geometrical shape unchanged.For extremely brittle cases (e.g. initially uncracked specimens, large and/or slender structures, low fracture toughness, high tensile strength, etc.) a snap-back instability in the equilibrium path occurs and the load-deflection softening branch assumes a positive slope. Both load and deflection must decrease to obtain a slow and controlled crack propagation (whereas in normal softening only the load must decrease). If the loading process is deflection-controlled, the loading capacity presents a discontinuity with a negative jump. It is proved that such a catastrophic event tends to reproduce the classical LEFM-instability (KI = KIC) for small fracture toughnesses and/or for large structure sizes. In these cases, neither the plastic zone develops nor slow crack growth occurs before unstable crack propagation.
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  • 181
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2113-2122 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Finite element partitioning (or substructuring) is employed to estimate the eigenproperties of large-scale structural systems. A homotopy equation is constructed and its solutions are characterized by a number of curves which connect the eigensolutions of the partitions with those of the complete system. A step-by-step tracing procedure is developed to follow these curves. At each step, prediction and correction are performed. The Rayleigh-Ritz procedure and the conjugate gradient method are used as predictor and corrector, respectively. Compared with the sole use of either the Rayleigh-Ritz or gradient methods, the proposed method is more reliable and more efficient for large-scale problems. Numerical implementation is well suited for supercomputers.
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  • 182
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    Notes: A finite element formulation has been developed to take into account the warping effect of composite beams undergoing large deflection or finite rotation. This formulation is to be used to model combined bending, torsional and extensional behaviour of composite helicopter rotor blades. The new approach can model thin to moderately thick walled composite beams with complicated cross-sections, tapers and arbitrary planforms. The warping effects are incorporated by assuming warping displacements superimposed over cross-sections normal to the beam axis in the deformed configuration of a shear flexible beam. The strain is assumed to vary linearly through the wall thickness. The fixed or total Lagrangian description is adopted in the present formulation and the Newton-Raphson method is used to solve the non-linear equilibrium equation resulting from the finite element approximation. Numerical tests of example problems demonstrate the validity and effectiveness of the present approach.
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  • 183
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2275-2292 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A plate bending element based on the generalized laminate plate theory (GLPT) developed by the senior author is described and its accuracy is investigated by comparison with the exact solutions of the generalized plate theory and the 3D-elasticity theory. The element accounts for transverse shear deformation and layer-wise description of the inplane displacements of the laminate. The element has improved description of the inplane as well as the transverse deformation response. A method for the computation of interlaminar (transverse) stresses is also presented.
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  • 184
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2323-2338 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Application of a weak form of the Kirchhoff constraints in the formulation of triangular assumed shear strain C0 plate element is described. It is shown that, compared to a similar formulation of the quadrilateral elements, formulation of the triangles requires some additional considerations which lead to additional terms in the energy expression. With those terms performance of the assumed shear strain triangular elements is comparable to that of the quadrilateral elements.
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  • 185
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2397-2421 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Robinson's viscoplastic model, a representative of the so-called overstress models, is integrated by use of the generalized midpoint rule. The solution of the non-linear system of algebraic equations arising from time discretization of the constitutive equations is determined using a projection method in combination with Newton's method. Consistent tangent moduli are calculated and the quadratic convergence of the global Newton equilibrium iteration is shown. The time increment size is controlled by the convergence behaviour of the equilibrium iteration and the accuracy of the numerical integration. Various numerical examples are considered to demonstrate the efficiency of the methods.
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  • 186
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2711-2711 
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    Keywords: Engineering ; Engineering General
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  • 187
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2761-2776 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The performance of group implicit algorithms is assessed on actual concurrent computers. We show that, as the number of subdomains is increased, performance enhancements are derived from two sources: the increased parallelism in the computations; and a reduction in equation solving effort. Moreover, we show that these two performance enhancements are synergistic, in the sense that the corresponding speed-ups are multiplied, rather than merely added. Our numerical simulations demonstrate that, if n is the number of degrees of freedom of the structure, p the number of processors used in the computations, and s ≥ p is the number of subdomains in the partition, the net speed-up is \documentclass{article}\pagestyle{empty}\begin{document}$ O\left({p\sqrt s} \right) $\end{document} in 2D and O(ps) in 3D, asymptotically as n/s → ∞. In particular, speed-ups with respect to Newmark's method of \documentclass{article}\pagestyle{empty}\begin{document}$ O\left({p\sqrt s} \right) $\end{document} in 2D and O(s) in 3D are obtained on a single-processor machine. Finally, simulations on a 32-node hypercube are presented for which the interprocessor communication efficiencies obtained are consistently in excess of 90 per cent.
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  • 188
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2813-2827 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A new element - a partial hybrid stress element - is proposed in this paper for the analysis of thick laminated composite plates. The variational principle of this element can be derived from the Hellinger-Reissner principle through dividing six stress components into a flexural part (σx, σy, σxy, σz) and a transverse shear part (τxy, τyz). The element stiffness matrix can be formulated by assuming a stress field only for transverse shear stresses, while all the others are obtained from an assumed displacement field. Consequently, this new element combines the benefits of the conventional displacement method and the hybrid stress method. A twenty-node hexahedron element is employed in each layer for the displacement field. For the assumed transverse shear stress field, only the traction-free boundary conditions and interface traction continuity are satisfied. The equilibrium equation is enforced by the variational principle. Hence, the complicated work of searching an equilibrating stress field for all the six stress components in the hybrid stress method can be avoided. Furthermore, the interlaminar traction discontinuity, especially transverse shear, encountered by the conventional displacement method and higher-order plate element for laminated plate analysis can also be overcome. Examples are illustrated to demonstrate the accuracy and efficiency of this proposed partial hybrid stress element.
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  • 189
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 2877-2888 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Exact postbuckling stresses usually vary fairly smoothly. Unfortunately, finite element postbuckling stresses tend to be much less well behaved. The result is that second order postbuckling constants determined by the finite element method may be highly inaccurate. The reason is that in finite element solutions transverse displacements associated with the buckling fields furnish too rapidly varying postbuckling strain contributions, while the postbuckling axial or membrane displacements contribute strain components that are sufficiently smooth, thus creating an internal postbuckling strain and stress mismatch.The present study suggests a modified finite element method that handles the problem, which is a special example of membrane locking, by introducing the postbuckling strains as independent variables. In general, the method provides rather complicated finite element expressions. However, by a suitable choice of interpolating functions, the resulting finite element equations themselves may be found to be the usual ones, and yet provide smooth postbuckling stresses and therefore good values of the postbuckling constants.
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  • 190
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    International Journal for Numerical Methods in Engineering 27 (1989) 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 191
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    International Journal for Numerical Methods in Engineering 27 (1989), S. 153-167 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Jacket structures have many sub-sea appurtenances attached to them. For example, a typical jacket structure has hundreds of sacrificial anodes attached to its members. The fluid loading of these structures is calculated using Morison's formula. The force coefficients used in the equation are based on experiments carried out, for the most part, on single cylinders in laboratories in ideal flow. There are very few experimental data available for the fluid loading of cylinders with appurtenances. Moreover, it is not possible to calculate theoretically the loading on such configurations in flows of practical interest using approaches such as the finite element method. However, appurtenances can contribute significantly to the overall loading on a structure. This paper presents the preliminary theoretical work that has been carried out as part of a programme to establish a rational method for estimating the fluid loading on tubular members with appurtenances.
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  • 192
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    International Journal for Numerical Methods in Engineering 27 (1989) 
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  • 193
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    International Journal for Numerical Methods in Engineering 27 (1989), S. 257-269 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The multilayer degenerated 3-D shell element, for which the stiffness matrix is calculated by numerical integration ply by ply, gives accurate results even for moderately thick composite panels, but needs an important linear and non-linear generation time when the number of plies is high (N 〉 10). In order to reduce this time some pre-integration and homogenization techniques are investigated. Different pre-integration methods have been reviewed and discussed. Then, two new homogenization methods, based on a series expansion of an equivalent Hooke matrix over the thickness, are presented. Next, simple numerical validation tests of these new methods are discussed, indicating necessary further investigations. Finally, a general discussion about the properties of the pre-integration and homogenization techniques tends to define their respective application domain.
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  • 194
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    International Journal for Numerical Methods in Engineering 27 (1989), S. 343-359 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper deals with the static and dynamic (free vibrations) analysis of plates built up with a symmetric series of orthotropic layers. The formulation of a new simple triangular finite element having three nodes and three degrees of freedom per node is presented. The element called DST (Discrete Shear Triangle) is free of shear locking and has a proper rank. It coincides with DKT (Discrete Kirchhoff Triangle) when the transverse shear effects are negligible. A large number of classical problems is considered to evaluate the performance of the element for the analysis of composite plates. Very satisfactory results are obtained for displacements, stresses and frequencies.
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  • 195
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    International Journal for Numerical Methods in Engineering 27 (1989), S. 403-427 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In general, plates and shells out of composite laminates are more susceptible to transverse shear than those out of homogeneous isotropic material. By means of different shear flexible theories the effect on buckling and postbuckling behaviour is studied. It turns out that there is a rather limited range of plates where the transverse shear is of considerable influence. Results obtained with Mindlin- or Reissner-type theories prove almost as adequate as those obtained with Reddy's theory. For the buckling analysis of shells the Kirchhoff-Love theory is precise enough. Snap-through buckling and imperfection sensitivity appear in composite shells, too, especially if they are optimized with respect to high bifurcation buckling loads.
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 27-41 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Owing to the failure of the finite element analyst to employ a properly refined computational model, the accuracy of preliminary finite element computations is often low. Thus, it is useful to introduce a computational procedure for improving the results obtained from a preliminary finite element solution. Such a procedure is presented in this paper. In this procedure the solution error components are decomposed into two parts. One of the error components is assumed to have a long period variation. The other component is assumed to have a short period variation. Multiplicative and additive correction procedures are introduced to iteratively eliminate the two error components. The multiplicative and additive correction procedures are implemented using multi-level solution techniques.
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 181-191 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The dynamic substructure method is extended to multilevel (recursive) substructures. The obvious distinction of the two approaches is that the stiffness and mass matrices before condensation are no longer frequency independent. The dynamic stiffness matrix at any substructure level is proved to be a function of the vibrating frequency in terms of some constant matrices which are derivable from the dynamic stiffness matrix at one lower substructure level. The method can accurately predict more modes than the number of degrees of freedom retained. The computational procedure, the generalized inverse iteration, the stationary principle of the system natural frequency and the generalized Rayleigh's quotient are derived for the frequency dependent matrices. Numerical examples are given to illustrate some engineering applications. A transcendental dynamic stiffness matrix can be transformed to a more convenient algebraic form by the present method.
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 955-965 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A method is presented for determining the natural frequencies and the corresponding mode shapes of isotropic bimodular beams at certain supporting conditions. Although only the lowest three modes of the single-layer and two-layer bimodular beams were studied, in principle, the method may also be used to determine higher-mode natural frequencies and shapes of the multi-layer beams. Numerical analysis shows that the approach is suitable for the free-vibration analysis of clamped/free and hinged/hinged bimodular beams.
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 980-980 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 200
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    International Journal for Numerical Methods in Engineering 28 (1989), S. 1061-1076 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A general finite element is derived for beams or beam-columns with or without a continuous Winkler type elastic foundation. The need to discretize members into shorter elements for convergence towards an ‘exact’ solution is eliminated by employing in the derivation of the element exact shape functions obtained from the equation of the elastic line. Inter-nodal values of deflections, bending moments and shear forces are obtained using the exact shape functions and trigonometric series. The effect of heavy compressive or tensile axial forces on bending stiffness is treated as a linear problem by considering the axial force as a constant parameter affecting the stiffness. FORTRAN subroutines to compute the stiffness matrix, equivalent nodal forces, deflected shape, bending moments and shear forces are provided and verified by an example.
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