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  • 2010-2014
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  • Industrial Chemistry and Chemical Engineering  (746)
  • 101
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 155-160 
    ISSN: 0268-2605
    Schlagwort(e): tungsten trioxide ; electrochromism ; thin films ; chemical vapor deposition (CVD) ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Crystalline and amorphous thin films of tungsten(VI) oxide can be prepared by chemical vapor deposition using a variety of volatile precursors below 500 °C. Deposition parameters for preparation of WO3 films from tungsten hexacarbonyl [W(CO)6], tungsten hexafluoride (WF6), tungsten ethoxides [W(OEt)x, x = 5, 6] and tetra(allyl)tungsten [W(η3-C3H5)4] are summarized. The electrochromic behavior of these films is comparable with that observed for WO3 films prepared by evaporation, sputtering and electrodeposition. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 102
    ISSN: 0268-2605
    Schlagwort(e): chemical vapor deposition ; platinum ; palladium ; rhodium ; heterogeneous catalysts ; fluidized bed ; MOCVD ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A new one-step method, entitled fluidized-bed metal-organic chemical vapor deposition (FBMOCVD) of preparing highly dispersed metal-supported catalysts is reported. The following complexes were studied and used as CVD precursors in presence of H2: [Rh(μ-Cl)(CO)2]2, Rh(allyl)3, Rh(acac)(CO)2, Pd(allyl)(hfac), Pd(allyl)(Cp), Pt(COD)(CH3)2. (acac, acetylacetonato; hfac, hexafluoroacetylacetonato; Cp, cyclopentadienyl; COD, cyclooctadienyl). In a first approach, depositions on planar substrates were carried out to establish the best experimental conditions to obtain good-quality deposits. X-ray diffraction, X-ray photo-electron spectroscopy and electron microprobe studies were realized on the resulting thin films. Analyses of the products contained in the gas phase after and during deposition were performed by mass spectrometry and GC-MS. Finally, catalysts prepared by FBMOCVD were characterized by transmission electron microscopy-energy dispersion spectroscopy (TEM-EDS), metal-loading determinations and specific-surface measurements (BET). Dispersed nanosized aggregates were obtained, showing high activities in alkene hydrogenation and alcohol hydrocarbonylation. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 103
    ISSN: 0268-2605
    Schlagwort(e): Metal-organic chemical vapor deposition (MOCVD) ; precursors ; titanium ; vanadium ; carbonitride ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Ceramic thin films containing titanium, vanadium, carbon, oxygen and nitrogen were obtained on steel substrates at 873 K, under nitrogen and helium gases and at low pressure, by chemical vapor deposition (CVD) from two organometallic precursors, CpTiCl2N(SiMe3)2 and Cp2VMe2 (Cp, cyclopentadienyl). Independent TG-DTA-MS and CVD studies of the two precursors showed their ability to co-decompose within compatible temperature and pressure domains. The mechanism of the reactions occurring inside the CVD apparatus was also approached by GC-MS and NMR analyses of the condensed decomposition products. CVD conducted under He gas confirmed that the formation of nitride resulted from the nitrogen atoms of the precursor, but the nitrogen content in the films remained lower than approx. 5%. Higher nitrogen contents (up to 12%) were only obtained when using ammonia as a carrier gas. Both precursors being air- and moisture-sensitive, high-purity CVD equipment was used to reduce oxycarbide formation. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 104
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 189-199 
    ISSN: 0268-2605
    Schlagwort(e): single-source precursor ; tetrakis(diethylamido)chromium ; pyrolysis mechanism ; MOCVD ; low-temperature deposition ; chromium carbonitride thin films ; hard metallurgical coatings ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Amorphous chromium carbonitride coatings with a low nitrogen content (3-8 at%) were deposited by low-pressure MOCVD in the temperature range 573-793 K using Cr(NEt2)4 as single-source precursor. This poor nitrogen incorporation is in agreement with the trends predicted by thermochemical calculations. XPS data, resistivity measurements and annealing experiments suggest that the films grown at 573 K are contaminated by organic species due to incomplete elimination of the ligands. The films deposited at higher temperature crystallize upon annealing at 873 K to form an orthorhombic ternary chromium carbonitride phase. The major volatile by-products of the MOCVD reaction were analyzed by 1H and 13C NMR. Their amount and the quasi-equimolar EtN=CHMe/HNEt2 ratio suggest that most of the NEt2 ligands are removed by a stepwise mechanism which probably occurs with other diethylamido complexes of transition metals when they are used as single-source precursors in MOCVD. The incorporation of the metalloid elements in the film is discussed in comparison with recent literature data. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 105
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 201-220 
    ISSN: 0268-2605
    Schlagwort(e): MOCVD ; molybdenum oxycarbide ; chromium oxycarbide ; coating ; kinetics ; microstructure ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A review of the coating kinetics of molybdenum and chromium oxycarbides and a study on the properties of deposited films are reported. Molybdenum carbonyl, chromium carbonyl and their mixture were used to prepare coatings at temperatures between 170 and 450 °C on SS304 or SiC substrates by a process of metal-organic chemical vapor deposition (MOCVD). The processing parameters of the coatings, such as the evaporation of precursors, coating pressure and temperature, are discussed along with the coating rates, compositions and other microstructural information, so to reveal the kinetics of the coating process on two different substrates. In addition, the chemical composition, crystalline phases and microstructure of the coatings obtained in various conditions are presented with the evidence interpreted by various electron-microscopic and spectroscopic techniques, including XRD, EDS, EPMA and XPS. The dependence of some properties, such as hardness, adhesive strength and corrosive resistance of the coatings on SS 304, on their composition and the deposited phases, i.e. as a function of coating temperature and pressure, is reviewed. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 106
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 221-236 
    ISSN: 0268-2605
    Schlagwort(e): MOCVD ; barium ; liquid delivery ; mixed-metal species ; aerosol-assisted CVD ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Conventional MOCVD techniques require molecules displaying volatility and constant vapor pressure. Metal oxide precursors, i.e., β-diketonates, or classical or functionalized metal alkoxides are mostly solids. The various approaches used to tailor volatility are discussed with barium derivatives as an example. The relationships between sublimation temperature and molecular weight suggest that volatility can be optimized on the basis of molecular weight.   Aerosol-assisted CVD (AACVD) can use a larger range of precursors since volatility is no longer crucial. The solvent is an undesired ballast in a CVD process. High solubility of the precursors in the selected solvent is thus desirable. ‘Stability’ here includes the absence of precipitation which would change the stoichiometry of the feed solution for multicomponent oxides. Precipitation is often promoted by hydrolysis; stability toward moisture is thus desirable. The use of mixtures of precursors based on different ligands (β-diketonates, β-ketoesterates, alkoxides) can lead to ligand exchange reactions giving homometallic species, sometimes of low solubility, or mixed-metal species by self-assembly, thus improving solubility and stability toward moisture. These aspects are illustrated in compositions related to high-Tc superconductors. Novel copper, yttrium, cerum(IV), barium-copper, yttrium-copper and praseodynium-copper species are reported. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 107
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 293-293 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 108
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 109
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 294-294 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 110
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 294-295 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 111
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 295-296 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 112
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 296-296 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 113
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 114
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 296-297 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 115
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 297-297 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 116
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 117
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 298-298 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 118
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 237-241 
    ISSN: 0268-2605
    Schlagwort(e): tin ; iodomethane ; solubilization ; methyltin species ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The dissolution of tin metal by iodomethane-water mixtures has been studied and the influence of several parameters on both the extent and rate of reaction investigated. The rate-determining step shows a pseudo-first-order dependence on iodomethane (CH3I). The reaction is strongly dependent upon both water and oxygen. The activation energy of only 16 kJ mol-1 is interpreted in terms of a facile bond-breaking and making process at the metal surface, generating methyltin species. Analysis by hydride generation and GC-AA confirmed the formation of methylated species ranging from monomethyl- to tetramethyl-tin; inorganic tin (from hydrolysis) was the major form, however. These findings are similar to those made earlier by us on the solubilization of arsenic from GaAs by alkyl halide-water mixtures, and a similar multi-step scheme is proposed. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 119
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 243-251 
    ISSN: 0268-2605
    Schlagwort(e): arsenic ; speciation ; algae ; Fucus gardneri ; arsenosugar ; high-performance liquid chromatography (HPLC) ; inductively coupled plasma-mass spectrometry (ICP-MS) ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Arsenic speciation in a brown alga, Fucus gardneri, collected in Vancouver, B.C., Canada, was carried out by using high-performance liquid chromatography-inductively coupled plasma-mass spectrometry (HPLC-ICP-MS). Hydride generation-atomic absorption spectrometry (HG-AAS) was used for total arsenic determination. The relative amounts of some arsenosugars 1 in growing tips are found to be different in comparison with the remainder of the plant. Fucus samples collected in summer contain 9 ppm of total arsenic. Most of the arsenic species are extractable. Fucus samples collected in winter contain relatively higher amounts of arsenic, 16-22 ppm, but only low amounts of this are extractable. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 120
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 253-256 
    ISSN: 0268-2605
    Schlagwort(e): disilane ; gas source MBE ; synchrotron radiation ; silicon hydride ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Surface hydrogen and growth mechanisms are investigated for synchrotron radiation (SR)-assisted gas source molecular beam epitaxy (SR-GSMBE) using Si2H6 on the Si(100) surface in the low-temperature region. The surface silicon hydrides (deuterides) are monitored in situ during the epitaxial growth by means of infrared reflection absorption spectroscopy with a Si(100) substrate and a CoSi2 buried metal layer. It is concluded that the chemisorption of gas-phase reactive species such as SiHn and H generated by SR irradiation and the subsequent hydrogen desorption are the key mechanisms of SR-GSMBE at low substrate temperatures. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 121
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 257-264 
    ISSN: 0268-2605
    Schlagwort(e): Rochow reaction ; cesium chloride ; rubidium chloride ; silicon impurities ; action of promoters ; scanning electron microscopy (SEM) ; energy-dispersive X-ray spectroscopy (EDX) ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Cesium chloride- and rubidium chloride-promoted Rochow contact masses based on both technical-grade and highly pure silicon have been investigated in the Rochow reaction and by REM/EDX surface analysis. The alkali-salt promoters seem to act analogously to the well-known zinc promoter, by localizing the reaction to distinct reactive areas and keeping free the surface area for the reaction, probably for the formation of catalytically active Cu-Si surface species. The alkali salts exhibited their promoting action only in combination with the impurities within the technical-grade silicon. Otherwise, they acted as blocking poisons. The promoter action of alkali chlorides in contact masses based on technical-grade silicon is possibly connected with the formation of salt melts, containing alkali chlorides and impurities. These melts, analogously to zinc chloride, could dissolve oxidic impurities from the silicon surface which otherwise would enhance the blocking of potentially active surface by extensive copper deposition. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 122
    ISSN: 0268-2605
    Schlagwort(e): carbohydrate surfactants ; wetting behaviour ; siloxane ; silane ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The wetting behaviour of carbohydrate surfactants bearing siloxane, carbosilane, polysilane or silane moieties has been investigated. By static surface tension (γlv, σ) and wetting tension (γsv-γsl, α) measurements on a non-polar perfluorinated surface (FEP®), the contact angles of aqueous surfactant solutions above the critical micelle formation concentration (cmc) were determined. Surface tension and wetting tension react independently on defined changes in the chemical structure of the surfactant molecules. Siloxane surfactants reduce the surface tension most effectively, whereas for a neopentyl-substituted silane derivative the lowest solid/liquid interfacial tension was found. The data for isomeric siloxanes, carbosilanes and silanes suggest that donor-acceptor forces at solid interfaces have a maximum range of about 4.5 Å. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 123
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 277-284 
    ISSN: 0268-2605
    Schlagwort(e): carboxylation ; methane ; carbon monoxide ; ytterbium(III) acetate ; manganese(II) acetate ; sodium hypochlorite ; acetic acid ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A new method of synthesis of acetic acid in water has been developed from the carboxylation of methane with carbon monoxide using lanthanide catalysts. Ytterbium(III) acetate has been found to be the most active catalyst among the compounds of the lanthanide series in the carboxylation reaction of methane with carbon monoxide. Sodium hypochlorite or hydrogen peroxide was used as the oxidant in this reaction. Sodium hypochlorite exhibited more favorable activity than hydrogen peroxide in the reaction. The catalytic activity was improved by the addition of transition-metal salts such as manganese(II) acetate. The best result has been found at a ratio of manganese(II) acetate to ytterbium(III) acetate of 1:10. The optimum reaction conditions (reaction temperature, 40 °C; time, 20 h; methane, 20 atm; carbon monoxide, 5 atm) have been obtained. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 124
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 298-299 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 125
    ISSN: 0268-2605
    Schlagwort(e): Nickel-σ-organyl complexes ; dispersed atomic Ni(0) ; Ni(I) ions ; silica ; EPR ; FMR ; spectrum calculation ; strain ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Dispersed atomic nickel(0) is formed during the reaction of the nickel-σ-organyl complexes with silanol groups at temperatures below 373 K. That nickel is oxidized to Ni(I) by protons of the silanol groups in a consecutive step. The Ni(I) portion amounts to about 70% w/w of the Ni used. Six different Ni(I) species are detected by electron paramagnetic resonance. They are stabilized by interaction with the silica surface and the organic moieties; they act as anchor ions for the Ni(0) atoms. Ni(0) crystallites stabilized in this way are about 0.5 nm in diameter after a treatment at 373 K. The influence of the Ni(I) ions on the collective, magnetic properties of the clusters is revealed by calculation of ferromagnetic resonance (FMR) spectra using the independent-grain approach according to Schlömann and Kotyukov. A strain of about 10 GPa is brought about in the nickel crystallites by the interaction with Ni(I) ions. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 126
    ISSN: 0268-2605
    Schlagwort(e): magnetization reversal ; iron oxide particles ; SQUID ; atomic force microscopy ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: We report first measurements of the magnetization reversal of monodisperse 30 nm and 50 nm ferromagnetic Fe3O4 particles. These particles are produced in a carrier gas as an aerosol by spray pyrolysis. After production and size selection, they are precipitated on a silicon chip with a niobium SQUID (superconducting quantum interference device) incorporated on its surface. By changing a magnetic field in the plane of the SQUID, we can measure the magnetization reversal of the particles by the flux they induce into the SQUID. The angular dependence of this reversal is determined by rotating the magnetic field around the SQUID. Scanning electron microscope (SEM) images have confirmed the particle size and revealed the position of the collected particles. If the particle concentration is too high, we cannot detect changes in the magnetic moment of a single particle, but measure the magnetic properties of the whole assembly. If only a few particles are found on the SQUID loop the angular dependence of the magnetic reversal of a single particle can be measured; this result is compared with a simple model of magnetization reversal. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 127
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 337-340 
    ISSN: 0268-2605
    Schlagwort(e): porous silicon ; luminescence ; light-assisted etching ; atomic force microscopy ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: We present an investigation into a new technique for producing luminescent porous silicon with controlled lateral microstructure. The process is based on the effect of laser-assisted stain etching of silicon with hydrofluoric acid solution. With the further goal of preparing two-dimensional periodical arrays of luminescent microdots, we studied the accuracy of the technique by etching single submillimetre structures with a low-power laser. The size and exact position of the etched area are controlled by laser focusing and movement, respectively, with submillimetre accuracy. Samples exhibit orange luminescence when illuminated with UV or blue light.We have studied the dependence of the efficiency of the luminescence, the structure and the rate of etching on parameters such as the HF concentration, the intensity and wavelength of illumination and the doping level of the silicon wafer. Optimization of the process parameters, and consistency with assumed mechanisms of luminescence and etching process, are discussed. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 128
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 341-346 
    ISSN: 0268-2605
    Schlagwort(e): silver halides ; nanoparticles ; pseudoisocyanine ; stability ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Pseudoisocyanine (PIC) was adsorbed on colloidal silver halide nanoparticles where it formed aggregates (J-aggregates). The nanoparticles were prepared using a surfactant (AOT)/n-heptane/water microemulsion. The molecules of pseudoisocyanine replaced the molecules of surfactant (AOT) on the surface of the nanoparticles and caused an instability of the silver bromide dispersion. The stability could be improved by two methods: either by using an adsorption inhibitor (e.g. p-xylene) or by adding another surfactant (CTAB). The adsorption has also been carried out at low temperature: the stability of the particles was then improved, and the J-aggregates are smaller. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 9 Ill.
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  • 129
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 387-391 
    ISSN: 0268-2605
    Schlagwort(e): colloidal manganese ; ESR ; susceptibility ; antiferromagnetism ; superparamagnetism ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The reduction of MnBr2·2THF (THF = tetrahydrofuran) using K[BEt3H] yields the organosol [Mn·0.3THF]x. According to the UV/Vis, ESR (electron spin resonance spectroscopy), HRTEM (high-resolution transmission electron microscopy), XPS (X-ray photoelectron spectroscopy) and XAS (X-ray absorption spectroscopy) data, this nanosized metal colloid consists of small THF-stabilized Mn0 particles which show, in susceptibility investigations, a diminished magnetic coupling as deduced from the Weiss temperature, Θ = 96 K. The Neél temperature TN is likewise strongly reduced in comparison with the bulk value (95 K). The THF-stabilized Mn0 particles exhibit superparamagnetism below 20 K, with a partial blocking at 10 K, and to our knowledge represent the first colloid consisting of particles of an elemental antiferromagnetic metal. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 6 Ill.
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  • 130
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 305-314 
    ISSN: 0268-2605
    Schlagwort(e): mesoporous ; oxides ; nanostructures ; luminescence ; zeolites ; guest/host ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Ordered porous inorganic compounds can now be synthesized with pore sizes between 0.3 nm and several tens of nanometers. The sharp pore size distribution of such materials and the ordered pore arrangement open possibilities for using them to organize matter on the nanometer scale. This overview highlights different aspects of this topic, using four selected examples: the spatial organization of molecules with high molecular hyperpolarizability to create a frequency-doubling element; the encapsulation of a laser dye which results in a new class of solid-state lasers; the encapsulation of small metal clusters in mesoporous ordered oxides; and the encapsulation of semiconductor clusters in such oxides. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 10 Ill.
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  • 131
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 401-408 
    ISSN: 0268-2605
    Schlagwort(e): Metallocene ; Ziegler-Natta ; Polypropylene ; α-Olefins ; Catalysis ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The polymerization of propylene using a mixture of racemic metallocenes and Ziegler-Natta catalysts was investigated. The polypropylene was obtained as a mixture of a fine powder and beads, with the powder being absorbed partially on the beads. The relative amount of the powder can be controlled by the concentration of the metallocene. The compatibility between the components of the mixed catalytic systems and the effect of the components on the rate of polymerization and on the properties of the new polymers were studied. The metallocene system dramatically affects the melt viscosity, isotacticity and molecular weight of the polymers. The two catalytic systems are able to act jointly, producing different polymers, for which separate melting and crystallization temperatures are obtained. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 2 Ill.
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  • 132
    ISSN: 0268-2605
    Schlagwort(e): density functional calculation ; binuclear metal carbonyl ; Cr2(CO)6+ ; laser ablation ; molecular beam ; optimized structures ; dissociation energy ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Density functional calculations have been made on a binuclear metal carbonyl ion Cr2(CO)6+ found in our laser ablation-molecular beam (LAMB) experiment. Optimized structures are calculated for three different conformations: T33 of D3d symmetry with three terminal carbonyl groups on each chromium atom, B2T22 of D2h symmetry with two bridging carbonyl groups and two terminal carbonyl groups on each chromium atom, and B4T11 of D4h symmetry with four bridging carbonyl groups and one terminal carbonyl group on each chromium atom. The most stable conformation is T33 which is 36.76 and 286.44 kJ mol-1 lower in energy than B2T22 and B4T11, respectively. The difference of conformation exerts a significant influence on the internuclear distance between chromium and the carbon of terminal CO, but hardly on the Cr-Cr bond length. For B2T22 and B4T11, longer C-O distances for bridging carbonyls compared with those for terminal ones indicate effective π*-back donation from the chromium atom to the bridging carbonyl groups. Furthermore, the relative abundance of Cr2(CO)n+ (n = 0-6) observed in our previous experimental study can be explained qualitatively by comparison of the excess energy produced in the formation of a Cr+-Cr bond with the CO dissociation energy of Cr2(CO)6+. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 2 Ill.
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  • 133
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 467-468 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 134
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 468-468 
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 135
    ISSN: 0268-2605
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 136
    ISSN: 0268-2605
    Schlagwort(e): metal clusters ; quantum-size effect ; nanostructures ; size effects ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Meta-cluster compounds can be exploited advantageously to study the evolution, with increasing size of the molecules of the physical properties of metal clusters from molecular to bulk-metal behavior. The metal-cluster molecules are well-defined, stoichiometric, chemical compounds. The molecules consist of a metal core of a variable number of atoms, surrounded by a shell of ligand atoms or molecules. Depending on the compound, the type of metal atom may be varied, whereas the core size can be changed from a few up to several thousands of atoms. Accordingly, these materials provide excellent model systems for monodisperse metal particles, embedded in a dielectric matrix, and can be investigated by the well-known experimental techniques of solid-state physics. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 4 Ill.
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  • 137
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 815-818 
    ISSN: 0268-2605
    Schlagwort(e): desilylation ; hydroxyquinones t-butyldimethylsilyl ethers ; potassium fluoride ; tetra-n-butylammonium fluoride ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Desilylation of a series of hydrolytically stable hydroxyquinone t-butyldimethylsilyl ethers was achieved in high yields by the use of potassium fluoride in the presence of catalytic amounts of aqueous 48% hydrobromic acid (HBr), or basic aluminium oxide (Al2O3), and tetra-n-butylammonium fluoride (Bu4NF) as cleaving agents. Copyright © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 2 Tab.
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  • 138
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 541-549 
    ISSN: 0268-2605
    Schlagwort(e): organotin speciation ; analytical validation procedure ; organotin sediment extraction ; Grignard derivatization ; organotin extraction stability ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The effect of several extraction variables such as acid concentration and strength (e.g. for HCl and HOAc), the presence of complexing agents (e.g. tropolone, sodium diethyldithiocarbamate) in the extracting mixture, solvent polarity (e.g. hexane, toluene) and sonication time for native butyl- and phenyl-tin compounds from sediment was evaluated. A toluene-HOAc mixture (10:4) yields the highest extraction efficiency for all the analytes and minimizes the degradation of trialkyl- and triaryl-tins during the extraction under sonication. In addition, losses of underivatized monobutyltin and monophenyltin were minimized in several steps of the analytical procedure. The analytical procedure developed was validated against existing CRMs for butyltin determination. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 7 Ill.
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  • 139
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 667-673 
    ISSN: 0268-2605
    Schlagwort(e): polysilanes ; poly(dimethylsiloxane) ; polyphosphazenes ; atom transfer radical polymerization ; controlled/‘living’ radical polymerization ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Recent advances in the synthesis of block, graft and star polymers containing inorganic macromolecular species are described. Anionic copolymerization techniques were used in the for-­mation of diblock copolymers of poly(styrene-block-methylphenylsilylene) and poly(isoprene-block-methylphenylsilylene) by the ring-opening polymerization of 1,2,3,4-tetramethyl-1,2,3,4-tetraphenylcyclotetrasilane initiated by living anionic polystyrene and isoprene respectively. Hydrosilation of an attachable initiator onto telechelic vinyl- or hydrosilyl-terminal or­-pendant poly(dimethylsiloxane) (PDMS) yielded a PDMS macroinitiator. This macroinitiator was used in atom transfer radical polymerization (ATRP) of styrene and isobornyl acrylate to produce ABA triblock copolymers. As a model for graft copolymers from a polyphosphazene backbone, chemical trans-­formation of hexachlorocyclotriphosphazene­resulted in hexafunctional molecules containing either benzyl bromide or bromopropionyl moieties. The initiator 1,1,3,3,5,5-hexakis[4-(2-bromopropionyloxymethyl)phenoxy]cyclotriphosphazene was used in the ATRP of styrene to yield a polymer with a narrow, monomodal molecular weight distribution. Chain extension of this star polymer with isobornyl acrylate is also described. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 1 Ill.
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  • 140
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 695-705 
    ISSN: 0268-2605
    Schlagwort(e): poly(silylenemethylene) ; polycarbo-­silane ; silicon carbide ; precursor ; polysilaethy-­lene ; disilacyclobutane ; pyrolysis ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Work carried in the authors laboratory on Si-CH2-Si bridged polycarbosilanes is reviewed. In pursuit of high-yield polymeric precursors to silicon carbide, convenient synthetic routes to both linear and hyperbranched polycarbosilanes having a ‘[SiH2CH2]n’ compositional formula have been developed. The linear [SiH2CH2]n polymer was prepared by ring-opening polymerization of a substituted disilacyclobutane, and was studied both as an analogue of polyethylene and as a high-yield precursor to SiC. Elaboration of the methods employed to prepare this polymer has yielded a wide range of new poly(silylenemethylene)s (PSMs) of the type [SiRR′CH2]n, where R and R′ can be a wide range of different groups, including a series of symmetrically disubstituted polymers with R = R′ = F, alkyl and alkoxy which form crystalline solid phases and various amorphous, atactic polymers having different R and R′ groups. By using (Si)-Cl replacement reactions analogous to those developed previously for polydichlorophosphazene, as well as hydrosilation reactions similar to those used for [Si(H)(Me)O]n, a series of side-chain polymers having various groups attached to Si through Si-C or Si-O bonded linkages were obtained. Similar polymer modification reactions have recently been developed for the branched oligomer/polymer analogue of these linear polycarbosilanes, leading to hyperbranched species with functional substituents, including a di(ethyleneoxy) methyl ether-terminated derivative which readily dissolves lithium salts. The results of studies of these novel ‘inorganic/organic’ hybrid polycarbosilanes are described and their properties are compared with those of related carbon-backbone and siloxane polymers. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 1 Tab.
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  • 141
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 787-792 
    ISSN: 0268-2605
    Schlagwort(e): tetrakis(dimethylamino)titanium ; amminolysis ; precursor ; pyrolysis ; titanium nitride ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Precursors possessing Ti-N bonds were prepared by the reactions between Ti(NMe2)4 and each of three diamines H2NCH2CH2NH2, Me(H)NCH2CH2N(H)Me, HN(CH2CH2)2NH (Ti(NMe2)4:diamine = 1:2), and were converted into ceramics by pyrolysis. The reactions with H2NCH2CH2NH2 and HN(CH2CH2)2NH led to the formation of insoluble solids, whereas a soluble oil was obtained by the reaction with Me(H)NCH2CH2N(H)Me. The pyrolyses under argon gave carbon-rich Ti(N,C,O) phases,­but those under NH3- N2 resulted in the formation of Ti(N,C,O) phases with higher nitrogen contents. Despite the difference in precursor structures the pyrolysis behavior of three precursors under argon was rather similar, suggesting that the precursor obtained from Me(H)NCH2CH2N(H)Me was effectively cross-linked during pyrolysis. © 1998 John Wiley & Sons, Ltd.
    Zusätzliches Material: 3 Ill.
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  • 142
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
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  • 143
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 17-22 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Mass transfer with chemical reaction by liquid/liquid phase tranfer catalysis (LLPTC) for an isothermal batch reactor was analyzed. The results for the phase transfer catalyzed reaction system can be generally described by a pseudo first-order hypothesis, whereas the reaction system can be controlled by simultaneous mass transfer of the catalysts between two liquid phases and chemical reaction in the organic phase. The mass transfer limitation is mainly from the mass transfer step of QX from the organic phase to the aqueous phase. The concept of catalyst-effectiveness vs. physically meaningful parameters in a liquid/liquid phase transfer catalyzed reaction is introduced. The catalyst effectiveness is increased as the mass transfer factors increase, the ratio of reaction rate coefficients of aqueous forward reaction to organic increases, and the equilibrium constant in the aqueous solution increases.
    Zusätzliches Material: 7 Ill.
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  • 144
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 40-42 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The use of ozone and hydrogen peroxide for the simultaneous oxidation of nitrogen and sulfur oxides was studied in experiments carried out in a stirred cell. It was found that in a gas mixture, containing both nitrogen and sulfur oxides, only the nitrogen oxides are oxidized by ozone. Contrary to earlier results, sulfur dioxide does not disturb the oxidation of nitrogen oxides under dry conditions. The consumption of ozone in the oxidation of nitric oxide was slightly below the stoichiometric level because the ozone was introduced into the reactor in the oxygen flow. When the molar ratio between ozone and nitric oxide was more than 0.4, some of the nitric oxide was oxidized to higher oxides of nitrogen, the final product being a solid mixture of N2O5 and (NO)2S2O7. Some nitrosyl sulfuric acid was formed in the aqueous solution of hydrogen peroxide in addition to sulfuric acid under wet conditions. Some white solid was found on the walls of the reactor. This solid is said it the literature to consist of H2SO4, HNOSO4 and (NO)2S2O7.
    Zusätzliches Material: 4 Ill.
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  • 145
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
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  • 146
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 564-570 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The modern urea plants are using a stripping process to reduce the energy consumption. The potential, very severe corrosion problems have been mastered by special grades and strict process control. The different grades are reviewed. After more than 20 years operation the results are very satisfying.In ammonia plants, an often forgotten corrosion problem is found in the heat exchangers. After about 3-6 years failures caused by chloride continuing cooling water may appear on carbon steel or low alloyed austenitic stainless steels. Corrosion mechanism is reviewed. Duplex stainless steels has been used with success and the properties are presented. An example of life-cycle cost shows that duplex stainless steel is an inexpensive way to solve chloride related corrosion problems.Condensation and evaporation of nitric acid in heat exchangers in nitric acid plants cause severe corrosion on conventional stainless steel grades. Low impurity in combination with high chromium content has proved to result in stainless steel with improved corrosion resistance.
    Zusätzliches Material: 5 Ill.
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  • 147
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 550-556 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Bubble break-up, gas holdup, and the gas-liquid volumetric mass transfer coefficient are studied in a bubble column reactor with simultaneous injection of a gas and liquid through a T-junction nozzle. The theoretical dependence of bubble break-up and the volumetric mass transfer coefficient on liquid velocity in the nozzle is developed on the basis of isotropic turbulence theory. It is shown that correlations which are developed based on liquid jet kinetic power per nozzle volume explain average gas holdup and the volumetric mass transfer coefficient within an error of 15% for all gas and liquid flow rates and nozzle diameters used. Experiments with a larger scale column, height 4.64 m and diameter 0.98 m, show a transition from homogeneous to heterogeneous flow at a certain liquid flow rate through the nozzle. Liquid composition was found to have a significant effect on gas-liquid mass transfer. A phenol concentration of 10-30 mg/l in water increases the volumetric mass transfer coefficient of oxygen by 100%. This phenomenon may have significance in the chemical oxidation of wastewater.
    Zusätzliches Material: 10 Ill.
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  • 148
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
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  • 149
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 582-588 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The shape-selective transalkylation of biphenyl with pentamethylbenzene over ultrastable Y-faujasites to produce para-methylated biphenyls was studied in the liquid slurry phase. The reaction was carried out in a discontinuously operated stainless steel autoclave using n-heptane as the solvent with a temperature range of 513 to 533 K and a pressure of 3 MPa. As for the progress of the reaction the presence of strong Brønsted acid sites was essential, an ultrastable faujasite treated with aqueous hydrochloric acid having a high content of those sites was used as the catalyst. Thus, a yield of the target product 4,4′-dimethylbiphenyl of above 11% referring to biphenyl could be achieved. The effect of the operating conditions on the formation of the target product was investigated. The decisive influence was acted out by the molar ratio of biphenyl to alkylating agent, in so far as a surplus of pentamethylbenzene of 7:1 referring to biphenyl enhanced the yield of the target product to 14%. The kinetics of the reaction could be successfully descibed with a lumped reaction scheme, introducing pseudo components, summarizing structural isomers, and pseudo reactions, such as the formation of coke.
    Zusätzliches Material: 7 Ill.
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  • 150
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 624-632 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The oxidation of sulfide in oxygen-saturated aqueous solutions is accelerated by dissolved or silica-bonded cobalt phthalocyanines. On the basis of thermodynamical considerations it is postulated that the catalyst enhances the formation of disulfide as the initial elementary reaction step. The following reaction steps are largely unaffected by the catalyst, as indicated by a product ratio sulfate/thiosulfate=0.86, comparable to that of the uncatalyzed autoxidation. A Langmuir-Hinshelwood formalism is developed for the catalytic reaction step and is demonstrated to fit best with the kinetics. In addition, from the kinetic data free enthalpies for the adsorption of HS- (i) at the dissolved phthalocyanine (ΔG = -17.6 kJ/mole) and (ii) at the immobilized complex (ΔG = -20.0 kJ/mole) are calculated.
    Zusätzliches Material: 8 Ill.
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  • 151
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 641-645 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An In-HZSM 5 honeycomb catalyst is used for the experimental investigations of the NO reduction with methane. The catalyst is prepared by the ion-exchange method. The influence of temperature and concentration of oxygen and methane is studied. In addition to methane, natural gas is used as reductant for the reduction of nitric oxide. The results are compared with those of other authors who use zeolithe pellets.
    Zusätzliches Material: 7 Ill.
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  • 152
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 71-75 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Chemical engineering is taught at German universities in three different types of curricula: chemical engineering proper, process engineering (“Verfahrenstechnik”), and industrial chemistry (“Technische Chemie”). Independent departments resp. faculties of chemical engineering exist at four universities. At other universities process engineering is offered as a complete curriculum with a smaller amount of chemistry than chemical engineering curricula, mostly by the departments of mechanical engineering. Industrial chemistry is an essential component of chemistry courses at most technical universities and optional subject at several classical universities. The cause of this diversity of approaches to chemical engineering can be traced back to the beginning of the production of high-value organics (dyes, pharmaceuticals) in Germany in the second half of the 19th century.
    Zusätzliches Material: 6 Ill.
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  • 153
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 293-296 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: When mechanical foambreakers are used in chemical engineering processes to control an undesired primary foam, a secondary foam is often produced. Secondary foams consist of small bubbles, have a high liquid hold-up, and cannot be condensed further by mechanical foambreakers. Secondary foams can be converted into liquid and gas in a coalescence column by drainage, diffusion, and breakage of the lamellas. This paper presents a new model to determine the velocity of bubble growth and the time of coalescence of secondary foams. The experimental investigations have been carried out with surfactants in aqueous solutions.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 154
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 309-312 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Errors caused by the use of sensitivity tables may become very large in some cases because of the tables' total disregard of nonlinearities and interaction effects. We introduce a new and improved approach which calculates the effect of disturbances simultaneously by solving a set of linear equations. The approach offers simplicity, speed, insight and accuracy.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 155
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A ‘carbon source controlled shift technique’ was developed for fermentation medium optimization in continuous culture with the objective to maximize growth rate and growth-linked product formation of a biological system. An automatic culture medium preparation system was operated together with 2 parallel stirred tank reactors and a HPLC system for on-line analysis of the carbon source concentration in the reactors. A genetic algorithm was applied for experimental design. The concentrations of 7 medium components (mineral salts and vitamins) were optimized automatically within 40 continuous experiments to result in a maximum growth rate of the methylotrophic yeast Candida boidinii and growth-linked production of the formate dehydrogenase enzyme (FDH). The specific growth rate of Candida boidinii and the specific activity of the FDH enzyme at a set-point of 420 mM methanol in the reactor were, thus, improved by 19% to 0.16 h-1 and 26% to 164 U g-1, respectively, compared to the previously used medium, which has already been previously optimized in shake flask experiments. The results of the continuous medium optimization were evaluated with a full second order seven-dimensional polynomial model (regression coefficient 96.8%).
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 156
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 414-418 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In the present work, we employ a fuzzy logic controller (FLC) to control the unstable state of a nonlinear biological reaction. The state variable vectors consist of cell density and substrate concentration. The dilution rate is used as a manipulated variable to control the reaction dynamics. An analytic form of FLC employing Zadeh AND logic along with Center of Mass defuzzification method is considered. Simulations reveal that for servo response test, the FLC shows satisfactory performance for natural unsteady states for which a conventional PI controller is known to fail. Further simulations also show that the FLC gives satisfactory regulatory response and is relatively insensitive to the deviations in model parameters.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 157
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 429-433 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: When in contact with water, organoalkoxysilanes and other alkoxy metal compounds react to organofunctionalized polysiloxanes or heteropolysiloxanes. A new method for the continuous preparation of porous organopolysiloxane spheres was developed. Droplets of the precursor mixture are injected into the vertical reactor column. Movement of the gelating droplets is controlled by flow of the aqueous reaction medium. Advantages are adjustable residence time, minimized coalescence and low reactor height. An example shows typical product characteristics like narrow particle size distribution and macroporosity.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 158
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 462-468 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The autoxidation of aqueous sulfide solutions by dioxygen is studied at pH 9 and 14 and at initial sulfide concentrations between 1 and 100 mM. Disulfide as a primarary intermediate is proposed to enhance the sulfide oxidation by autocatalytically forming polysulfies. The postulate is supported by the observed acceleration of the process at increasing pH favoring the presence of disulfide rather than that of sulfur. The final reaction products thiosulfate and sulfate are proposed to result from the hydrolysis of the highly instable intermediate polythiosulfite in parallel parallel reaction pathways, assuming probabilities for breaking the sulfur chain at the α (sulfate) and β (thiosulfate) positions to be responsible for the selectivity. A reaction scheme is proposed, considering all experimental observations.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 159
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 485-490 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A dynamic model of the liquid fluidized bed containing two or more solid particle species of different size and density is presented. The model incorporates the particle mass transport mechanisms of the convection and the dispersion. The movement of the upper interface of the bed subject to a change in the liquid velocity is specified using the mass balance constraint. The particle velocities and dispersion coefficients are evaluated using correlations. The model is capable of describing the bed expansion, concentration profiles of the individual particle species, the bulk density profile, and the occurrence of layer inversion.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 160
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 221-229 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: To review mass transfer trays from a process point of view, the dependence of efficiency on the loadings, the loading range and the maximum loadings with an acceptable tray efficiency have to be known. Comparing the results taken from experiments on Dualflex trays and from other types of trays which have been in industrial applications for many years and which are recognized as “industrial standard”, has been evaluated in this review.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 161
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 259-267 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In this study, a scale-down approach has been used for the simulation of the imperfect mixing on the growth processes by considering several configurations of continuous stirred tank reactor (CSTR, aerated) and plug flow tubular reactor (PFTR, not aerated). The steady-state concentrations of biomass and enzyme in a continuous culture were calculated as a function of dilution rate using modified Monod growth kinetics. A mathematical model for each combination of two bioreactors was developed to account for growth, substrate utilization (oxygen and glucose) and enzyme synthesis and decay. The model was then used to investigate biomass production and enzyme expression in relation to the volumetric fraction Uf = VPFTR/(VCSTR + VPFTR) and the recirculation ratio R = fr/(f + fr) of the fermentation system. These two mixing parameters were found to be significant factors in the biomass and enzyme production from the fermentation system. This model was also compared with some of the existing models.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 162
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 23-28 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In the present study, a mass transfer model for Type-1 facilitated transport in liquid surfactant membrane is developed by taking into consideration a size distribution of emulsion drops, and analytical solution of the model equations has been presented. The model takes into account the continuous phase and outer liquid membrane phase resistances along with diffusion through composite emulsion drop. Effort has been made to highlight the effect of the various system parameters on the extraction rate including computation of reaction front position. The results of this work are found to be in good agreement with the published experimental results on batch extraction of phenol using NaOH as internal reagent. The model would thus provide an insight of the separation mechanism involved in the mass transfer processes in this type of system.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 163
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 43-46 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Liquid-phase cyclohexanone ammoximation over titanium silicate was carried out in a batch reactor. The influence of the solvent, duration of kinetic run, catalyst amount and reactant concentrations was investigated. Byproducts were formed in considerable amounts, leading to catalyst deactivation by pore blocking. The values of initial reaction rates were calculated taking into account deactivation phenomenon. Theses values indicated that within the range of studied concentration (Ccyclohexanone = 0.4 to 1.70 mol/l; Cammonia = 1 to 4 mol/l; Chydrogen peroxide = 0.4 to 1.8 mol/l) the reaction rates plotted as a function of all the reagent concentrations go through a maximum. Special experiments on hydrogen peroxide decomposition and cyclohexanone oximation by hydroxylamine demonstrated that the rates of these reactions are essentially higher than the ammoximation rates.A kinetic equation for initial ammoximation rates was developed on the basis of a mechanistic model. The advanced model permits description of the observed kinetic regularities.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 164
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 63-70 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The following deliberations are concerned with the application of economy criteria to the optimization of process-engineering plants. We are therefore not concerned here with criteria for investment decisions, i.e., decisions on the implementation orabandonment of an investment project, nor with criteria for the selection of the most profitable investment options from a series of alternatives. Instead, we are interested here in the question of how a plant, while at the planning stage, can best be designed, i.e., the most rational method of selecting process parameters, such as throughputs, pressures, temperatures, concentrations, etc. The problem of plant optimization only occurs, however, when there are design parameters which can be selected at will or can, at least, be varied within certain limits. This is however, virtually always the case. There is then a need for an optimization strategy in the form of an objective function which is either reduced to a minimum, where lowest possible production costs are the target, for instance, or advanced to a maximum, where high profitability is the aim. The inclusion of engineering economy functions, in the form, namely, of the net present value function and the internal rate of return function for definition of such objective functions, provides better defined information on the best possible choice of process parameters than was possible with methods previosly used, such as the annuity method, for instance. One obtains different values for the process parameters to be optimized, depending on the objective functionused, and therefore different investment costs and utility consumptions. These differences are delineated and quantified using a process-engineering example in the course of the following discussion. The example selected is a gas scrubber, the function of which is to remove and recover useful components from a flow of gas. The specific problem examined is one of heat recovery.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 165
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 90-92 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The effect of sodium lauryl sulphate (anionic) and Triton X-100 (nonionic) on the solid-liquid mass transfer at a gas-sparged fixed bed of copper Raschig rings was studied by measuring the diffusion-controlled dissolution of copper rings in acidified chromate solution. The variables studied were the nitrogen flow rate, the type of surfactant, and the surfactant concentration. It was found that an increase occurs in the solid-liquid mass transfer coefficient with increasing the nitrogen flow rate. Increasing the surfactant concentration was found to decrease the mass transfer coefficient. For a given surfactant concentration, it was found that Triton X-100 reduces the mass transfer coefficient more than sodium lauryl sulphate.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 166
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 118-130 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A dynamic model is developed for a fluid catalytic cracking (FCC) unit to describe the dynamic behavior of both the riser and the regenerator reactors and their interactions. The cracking reactions are simulated by the four-lumped kinetic model [1]. The reactions in the riser occur in a transported bed with the fluid and the solids in ideal plug flow. The two-phase nature of the regenerator-fluidized bed is considered and the kinetic model for the coke combustion on the cracking catalyst [2,3] is incorporated. The proposed model is validated using steady-state plant data from an industrial unit and the results are found to be in good agreement. One of the main advantages of the model is that it does not include any partial differential equations. This facilitates the solution of the equations and makes the model particularly suitable for control studies. Simulation studies are performed to investigate the effect of changing various process variables, such as catalyst circulation rate, gas oil feed rate, and oxygen feed concentration.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 167
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 168
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 182-191 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The uncatalyzed esterification of acetic acid is described in the literature as a typical example of reactive distillation. Many rigorous models were validated using this esterification as an example. Process proposals for the production of pure ethyl acetate from ethanol and acetic acid have been determined using short-cut methods with the assumption of chemical equilibrium only. In this publication, the limitations of this esterification are clarified, using a rigorous model that was developed. The reasons why reactive distillation appears to be unfavorable for this esterification are explained. It is, however, theoretically possible to obtain ethyl acetate in high purity with different variants of the process. Different process variants are examined in this work. Construction variables that are important for the design of reactive columns, such as the number of reactive separation stages and the holdup in the column, are analyzed. Furthermore, the influence of variables dependent on the component system, such as the phase equilibrium of the reactive system and the reaction kinetics on the conversion in the column, are described. It can be shown that the short-cut methods published so far for reactive distillation, which assume chemical equilibrium, are inadequate.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 169
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 203-207 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Transient heat transfer in a mechanically agitated vessel is studied in the case of an anchor and an helical ribbon impeller using Newtonian and shear thinning fluids. Temperature stratification is found more pronounced with the anchor, making this impeller clearly inadequate for heat transfer. The impact of natural convection is evaluated first using the classical Gr/Re2 ratio. It is shown that the use of this criterion in viscous mixing is somewhat misleading. A new Grashof number is then proposed to assess the significance of the viscous and buoyancy effects in non-isothermal, non-Newtonian mixing applications. It is shown that the interpretation of this new number is strongly related to the concept of process viscosity.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 170
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 240-246 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The rate of the homogenous exothermic hydrolysis reaction of acetic anhydride catalyzed by sulfric acid in solvent acetic acid was estimated from nonisothermal experimental batch reactor transient temperature data. Rate equations based on three different reaction mechanisms of hydrolysis published in the literature were fitted to the experimental rate data. The experimental results on runaway and limit cycle behavior obtained with this reaction were explained by using the mechanism-based rate equations for hydrolysis in the reactor dynamic models, and good agreement was obtained between the predicted and the experimental dynamic data.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 171
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 282-284 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 172
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 268-276 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: As an alternative to the existing bioheat transfer models a new system of two energy equations is proposed by considering the human body as a deformable porous medium. One equation is developed for the blood and the other for the peripheral skeletal tissue. It includes such significant factors as the vascular geometry and size, the blood flow and direction, thermal diffusion and the local thermal nonequilibrium between the blood and peripheral tissue. Discussion and application of both equations are given.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 173
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 285-286 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An ortho-experiment design and the analysis method of mathematical statistics are adopted to study the conversion of gypsum and potassium chloride to potassium sulfate in the system of K+, Ca2+, NH4+ ‖ Cl-, SO42- in H2O. Optimal reaction parameters and engineering mean are acquired to attain a conversion yield of potassium chloride of 94.52%.
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
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  • 174
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 297-303 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Electrochemical gas absorption or biotechnical purification processes using structured packing as electrode or as biological support, respectively, may operate in bubble columns in presence of suspended solids. In both systems the knowledge of mass transfer rates from the liquid to the packing is important for the design of equipment. In the present investigation, the fluid dynamic behavior of a simple bubble column and a bubble column containing small size particles, both in presence of structured packing, was studied. Furthermore, mass transfer coefficients between the liquid and the structured packing were obtained by the electrochemical method. The influence of physical properties of the liquid phase, gas flow rate, kind and concentration of the suspended particles on both gas holdup and mass transfer was investigated. Correlations of the experimental data of mass transfer using dimensionless groups were derived and compared to previous correlations. Similarity with a heat transfer expression already used in two-phase systems was found.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 175
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 333-337 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The reaction of anisole hydroxylation with hydrogen peroxide to form methoxyphenols over TS-1 was studied. Four C1-C3 alcohols and the two aprotonic solvents acetone and acetonitrile were used. Product conversion was almost proportional to the titanium content of the catalyst sample. The highest conversion and p-selectivity were observed in ethanol. Some speculations, based on the formation of substrate-solvent or titanium-solvent-oxidant complexes, about the role of the solvent are presented. It was found that in all the solvents studied the p/o ratio increased with time.
    Zusätzliches Material: 4 Ill.
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  • 176
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 378-383 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Catalytic decontamination of waste gases in a fixed bed reactor, operating at non-steady state conditions achieved by periodic gas flow reversal, is simulated on the basis of a mathematical model. The opportunity to utilize a significant part of the reaction heat is discussed and the effect of catalyst inactivation upon reactor performance is analyzed. Stable temperature regime and conversion exceeding 99.5% could be ensured by a more than eightfold reduction of catalyst activity.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 177
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 396-402 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A packed column has been used to study the absorption of nitrogen oxide in an alkaline solution of potassium permanganate. The reactions taking place during the absorption have been examined and the rate constants have been estimated from experimental data. The experiments show that potassium permanganate is an excellent absorbent for nitrogen oxide. However, to avoid formation of MnO2, the hydroxide concentration has to be very high, i.e. 〉 3 mol/l. It was found that the reaction could be expressed as first-order with respect to NO and with respect to KMnO4. The rate constant may be expressed in terms of the hydroxide concentration as follows: kmn = 6114.9 101.9208 10-4 CNaOH m3 mol-1 s-1.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 178
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 424-428 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In paper coating make-down, a poor dispersion of pigments in coating colors may lead to coater runnability problems. This is manifested by coat defects at the paper surface, excessive coater blade wear, and an over-consumption of pigments. For this reason, high shear impellers operated at high speed are used, yielding a high energy consumption. A new method to disperse high solids mix at low energy consumption is presented. This method based on the use of a rod impeller scraping the fluid surface in the vessel, is tested on a slurry composed of calcined and delaminated clays up to a solids content of 66.7 wt.% without dispersing aids.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 179
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 445-454 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Two different layouts for the liquid-liquid extraction section of an industrial caprolactam process are evaluated. Laboratory mass transfer measurements on streams obtained from an industrial and a demonstration plant with different extraction sections are interpreted by a model describing the effect of surface contaminants on mass transfer coefficients. Indications of the impact of these layouts on the complexity of the extraction section, quality of products and efficiency of the extraction processes are given.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 180
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 469-474 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Bubble columns are commonly used in industry for polluted gas treatment. Based on the same principle, the droplet column which is not widely known in the literature, uses much higher gas velocities, up to 14 m/s. This study concerns the hydrodynamics and mass transfer in this apparatus, in presence or absence of solid particles. Our results have demonstrated the impact of dusts on mass transfer performance giving rise to an increase in the kL aL coefficient with decreasing particle size. However, no influence of dust on the hydrodynamics of the column has been demonstrated within the studied particle size range.A study of liquid holdups obtained by three different methods is also carried out. Our results are comparable, thus validating the methods used.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 181
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 491-494 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experiments were carried out in a conventional circulating fluidised bed to measure the axial pressure profile and total pressure drop, which covered a wide range of operating conditions. Material belonging to the Geldart A (fine material) as well as the Geldart B (course material) categories have been used in the present work. Slip velocity is determined from the total pressure drop and noticed that the slip velocity is much higher than the free fall velocity of single particle for Geldart A type material, while it is approximately equal to the free fall velocity of single particle for the Geldart B type materials.A model is developed for slip velocity taking into account all the hindrance effects: particle-particle, and particle-wall, and particle agglomeration. Predictions of the present model are validated with the data due to present study and the data reported in the literature.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 182
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 502-509 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Dust explosion hazard exists in plants and facilities wherever combustible dusts are hardled. Minimum explosible concentration of dust clouds is an important factor requiring special attention for hazard evaluation if any technological equipment is to be protected by inertisation. The mathematical models available for prediction of this parameter have been analysed for their application to organic dust clouds. Solution of the most general mode for determination of minimum explosible concentration of dust clouds proposed by Mitsui and Tanaka is presented, together with the comparison with experimental data. It has been found that the model is not successful in predicting the minimum explosible concentration for organic dusts. Recommendations on requirement of development of a new model for prediction of minimum explosible concentration of an organic dust such as polyethylen have been given.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 183
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 557-563 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Capillary viscometry is used to characterize viscosity, entrance pressure loss and apparent wall slip of paper coating colors at high shear rates. Special emphasis is laid on the dependence of these phenomena on solids content in order to account for changes in the rheology due to the dewatering of the color during the coating process. Coating colors with substantially different runnability have been investigated. Differences in apparent wall slip and high shear viscoelasticity (manifesting itself in extremely high entrance pressure losses) are observed at increased concentration, even if these phenomena do not show up at the initial solids content. Poor runnability is observed when viscosity, entrance pressure loss and wall slip increase strongly with increasing solids content. But all rheological features change simultaneously with the coating color recipe and it is not possible to separate out the contribution of the particular rheological features on the runnability of the coating colors or to correlate the runnability to a single rheological prorameter. Future work will have to focus on a numerical analysis of the blade coating process taking into account all the rheological features described here. First simulations including slip at the color/blade interface indicate that wall slip may cause severe runnability problems, at least when the apparent slip velocity exceeds the web velocity.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 184
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 581-581 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 185
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 589-595 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: New data of gas-liquid mass transfer for cocurrent downflow through packed beds of non-porous particles are presented. Mass transfer parameters for air/carbon dioxide/water and air/carbon dioxide/sodium hydroxide systems were evaluated by least squares fit of the calculated CO2 concentration profiles in the gas phase to the experimental values. The dependence of kGa on gas and liquid flow rates is caused by the dependence of gas-liquid interfacial area, not by the gas-side mass transfer coefficient kG. In the case of the absorption of dilute carbon dioxide the gas-side resistance is considerably smaller than the liquid-side resistance. In the pulse flow regime, gas-liquid interfacial area calculated from kLa and kL values obtained by physical, respectively, chemical absorption are lower than the gas-liquid interfacial area evaluated from the measurements under reaction conditions.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 186
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 617-623 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Designing an appropriate methanol steam reformer requires detailed knowledge about the processes within such a reactor. Thus, the axial temperature and concentration gradients and catalyst ageing were investigated. It was found that for a fresh catalyst load, the catalyst located in the reactor entrance was most active during the experiment. The activity of this part of the catalyst bed decreased after some time of operation due to ageing. With further operation, the most active zone moved through the catalyst bed. From the results concerning hydrogen production and catalyst degradation, the necessary amount of catalyst for a mobile PEMFC-system can be estimated.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 187
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 633-640 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The size-dependent breeding of sodium chlorate crystals can be determined by carrying out experiments with seed crystals of optical antipodes of different sizes that undergo absolutely identical experimental conditions. Small portions of right- and left-handed seed crystals of different sizes were used. The number density distributions of the two opposite forms led to the total numbers of D- and L-crystals. The nucleation from different seed sizes under identical experimental conditions was found to be proportional to L4 in agreement with Clontz et al. [1] and Bennett et al. [2]. A computer program for the modelling of batch crystallization was used to calculate the development of the nucleation process. The data for the supersaturation course and for the development of the population of the right- and left-handed crystals are in good agreement with the experimental results. Only few generations (one or two) of secondary nucleation are being built during the process because of the strong influence of the size of crystals on the nucleation rate. The formation of two generations of secondary nuclei could be observed during three-hour batch crystallization runs.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 188
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 14 (1997), S. 283-289 
    ISSN: 0934-0866
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The influence of the surface roughness of solid conducting spheres on the response of a phase-Doppler anemometer (PDA) is described by using a ray theory model. A rough particle surface is modeled as an ensemble of distorted spheres. First- and second-order reflection and diffraction are considered for far-field calculations of the PDA phase difference. The numerical simulations are accompanied and supported by experimental results. Single rough Sn spheres are captured inside an electro-dynamic trap and investigated with a standard phase-Doppler system.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 189
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 14 (1997), S. 295-303 
    ISSN: 0934-0866
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A new method is introduced to analyze the accuracy of phase-Doppler anemometry (PDA) for sizing large particles in two-phase flows. The method is based on Fourier optics theory (FOT) and geometrical optics theory (GOT) to calculate the intensity ratio of refractive and reflective light scattered by a sphere under a slit constraint. To examine the accuracy in calculating the light intensity, the results from the GOT method were compared with those of the direct simulation based on the generalized Lorenz-Mie theory (GLMT). This newly developed FOT/GOT method also predicts the results of phase jump due to the slit constraint. The performance of dual-mode phase-Doppler anemometry can also be simulated by this method.
    Zusätzliches Material: 17 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 190
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 14 (1997), S. 290-294 
    ISSN: 0934-0866
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A compact and commercial aerosol generator capable of generating narrowly size-distributed aerosols with high mass concentrations was designed, fabricated and tested. The aerosol generator, consisting of a Delavan simplex nozzle (Model 30610-4), an L-shaped settling chamber and a virtual impactor with a clean air core, was modified and improved from Chein and Lundgren's work [20] to be more compact and readily commercial. The performance of the aerosol generator was evaluated using corn-oil, sodium chloride and uranine solutions. The results indicated that the cornoil droplets produced by the generator had a mass medium aerodynamic diameter (MMAD) of 7.20 ± 0.32 μm with a geometric standard deviation (GSD) of 1.48 ± 0.01 and the aerosol generation rate was 13.8 ± 1.3 mg/min. Solid aerosols generated from NaCl solution were found to have an MMAD in the range 1.39-4.88 μm with a GSD of 1.34-1.47 with the volumetric solution concentration varying from 0.1% to 9%. At the same time, the aerosol generation rate varied from 0.27 ± 0.05 to 15.8 ± 1.8 mg/min. depending on the solution concentration and the particle size produced. In addition, a 0.01% uraniane solution was tested to generate a submicron aerosol with an MMAD of 0.93 μm and a GSD of 1.48.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 191
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 14 (1997), S. 307-309 
    ISSN: 0934-0866
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 192
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 14 (1997), S. 304-306 
    ISSN: 0934-0866
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 193
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 93-100 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Distillation columns with multiple feeds are often used in processes for the separation of multicomponent mixtures. The minimum energy demand of such columns is determined via the minimum reflux and reboil, respectively.A novel method for directly calculating the minimum reflux ratio is presented in this paper. Applicable to ideal, nonideal and azeotropic mixtures the method is based merely on the knowledge of vapor-liquid equilibrium of the feed mixtures. This knowledge allows the determination of the internal concentration profile near the feed entry and, in turn, the calculation of both minimum reflux and optimal sequence of feeds. This sequence of feeds depends on feed compositions and product compositions, as well. Surprisingly, sometimes a multiple feed entry requires a higher energy demand than premixing the feed streams.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 194
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 131-137 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Hydrogenation of 10% aqueous solution of 3-hydroxypropanal (HPA) was adiabatically carried out over cylindrical Ni/SiO2/Al2O3-catalyst pellets (∅ 0.8 + 5 mm) in a trickle bed (∅ 76 × 5200 mm) at 2.6 to 8.0 MPa. The concentration and temperature profiles in the trickle-bed were measured at different flow rates of liquid. A mathematical model was developed under consideration of heat transfer, interphase mass transfer, intraparticle diffusion and deactivation of catalyst pellets at partial wetting with different wetting geometries. The model fits the measured data satisfactorily when its kinetics of deactivation is modified by a factor determined by regression of data measured in the trickle bed.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 195
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 171-181 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Hydrodynamic parameters have been determined in common equipment, i.e., same column and liquid and gas distributors, for cocurrent and countercurrent two-phase flow through fixed beds. The piston/dispersion exchange model (PDE) with usual Danckwerts' boundary conditions (closed/closed system) has been used to describe the liquid flow. A new imperfect pulse method has been used to estimate the PDE model parameters directly from the experimentally nonideal input and output response. The transition between trickle flow and pulse flow, for two-phase downflow, and the occurrence of flooding, for countercurrent flow, has been investigated using a macroscopic model for the two-phase flow.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 196
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 192-198 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Two devices were developed, mechanical and electrical, to measure the mechanical power relative to superficial gas velocity and stirring speed in a mechanically agitated reactor. Two bubble regimes were demonstrated. The study of gas holdup, obtained from the residence time distribution, and the bubble size, determined by interfacial area measurement, confirm these two regimes of flow. Our results show that the gas holdup, the interfacial area, and the liquid-side mass transfer coefficient are increasing functions of the energy dissipated in the solution.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 197
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 198
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 230-239 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In this contribution, a new method is proposed for determining effective macropore diffusion coefficients in porous media by digitized microphotographs of porous support materials and random walk simulations. The method introduced allows calculation of the effective diffusion coefficient as a function of the mean free path length over a wide variety of values. A versatile method for the preparation of porous substances for light microscopy is described.The frequently applied model of an active shell, which is used to model particle/solid collisions, was found to give incorrect results in conjunction with the application of the first passage time algorithm, which was applied to save computing time in the simulation of gas diffusion. It was possible to show that more realistic results are obtained if a Knudsen layer is used to model particle/solid collisions. Furthermore, in investigating diffusion in two- and three-dimensional representations of capillary tubes, it was found that results of simulations performed to calculate transport properties of fluids in porous media, based on two-dimensional model systems, cannot in any case be transferred to the corresponding three-dimensional systems.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 199
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 85-89 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A comparative study of reported theoretical and experimental investigations evaluating the numbers and sizes of bubbles emerging from submerged orifices reveals that the lack of consistency can be attributed largely to faulty experimental techniques. Errors are attributed to an inadequate knowledge of the influence of the surface properties of the solid and liquid media on the emission process and to the lack of standardization of the equipment geometries especially regarding the pressure chambers and orifice plates. The analyses provide guidance to designing standardized equipment to produce reproducible bubbles.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 200
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 108-117 
    ISSN: 0930-7516
    Schlagwort(e): Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: On the basis of the balance of forces acting on droplets falling down inside a co- or counter-current spray tower, a model of scrubber aerodynamic characteristics was developed. Relations between pressure drop caused by spray, droplet concentration and residence time distribution of the dispersed phase were found analytically for slurry droplet motion in the range of 400〈Re〈2500. The differences between the simplified model solutions and complete solutions are presented. The model was verified by the experimental data collected in two large pilot plant scrubbers applied for flue gas desulfurization (FGD).
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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