Bibliothek

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • Digitale Medien  (549)
  • 1980-1984  (549)
  • 1981  (549)
  • Chemical Engineering  (460)
  • Gas chromatography  (89)
  • Nuclear reactions
Materialart
  • Digitale Medien  (549)
Erscheinungszeitraum
  • 1980-1984  (549)
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Naunyn-Schmiedeberg's archives of pharmacology 315 (1981), S. 219-225 
    ISSN: 1432-1912
    Schlagwort(e): 3-Methoxytyramine ; Haloperidol ; Dopamine release ; Dopamine agonists ; Gas chromatography ; Mass Spectrometry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Summary The value of 3-methoxytyramine (3-MT) as an indicator of impulse-related dopamine (DA) release has been assessed in rat corpus striatum. Moreover, the turnover of 3-MT was estimated by measuring its disappearance rate after COMT inhibition. Quantitation of 3-MT and DA was performed by gas chromatography/mass spectrometry (selected ion monitoring). Haloperidol in doses between 0.05 and 3 mg/kg p.o. did not increase endogenous 3-MT levels at any time up to 24 h after its administration, whereas it dose-dependently increased homovanillic acid and 3,4-dihydroxyphenylacetic acid. However, in doses above 0.1 mg/kg p.o., it enhanced the accumulation of 3-MT in clorgyline-pretreated animals. Conversely, baclofen in doses of 2 mg/kg i.p. and above decreased endogeneous 3-MT levels, but reduced the accumulation of this amine only poorly at 20 mg/kg i.p. in clorgyline-pretreated rats. A number of dopamine agonists, apomorphine (0.5 mg/kg i.v.), dipropyl-ADTN (0.03 mg/kg i.v.), but not bromocriptine (1 mg/kg i.v.) reduced endogenous 3-MT levels 10 min after administration by approximately 50%. The DA releasing agents d-amphetamine and methylphenidate showed different effects: the former increased endogenous 3-MT greatly, whereas the latter was without effect. The difference is likely to be related to the MAO inhibitory properties of amphetamine. 3-MT disappeared rapidly after COMT inhibition with 50 mg/kg i.v. tropolone (half-life of the initial disappearance about 1 min). The curve flattened off after 5–10 min. Turnover was calculated to be about 7 nmol/g/h, which corresponds to about a third of the turnover of DA. Our results suggest that an important part of DA metabolism occurs through 3-MT and that this amine is very effectively deaminated by MAO-A, so effectively indeed that increased formation does not increase its endogeneous levels. It appears, therefore, that 3-MT is not suitable as an indicator of increased DA release. However, it seems to have some value for an assessment of lowered DA release.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Digitale Medien
    Digitale Medien
    Springer
    International archives of occupational and environmental health 48 (1981), S. 319-324 
    ISSN: 1432-1246
    Schlagwort(e): Chlorophenols ; Gas chromatography ; Hexachlorocyclohexane ; Metabolites
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Summary A sensitive and specific gas chromatographic method is described for the simultaneous determination of ten chlorinated phenols that appear in the urine of persons exposed to hexachlorocyclohexane (HCH). The phenolic compounds in the urinary samples are hydrolysed in an acidic medium and derivatised with acetic anhydride. This sample treatment permits routine application. The stationary phase (8% DC 200 on Chromosorb G AW-DMCS possesses a high separating capability for the acetic esters of the chlorophenols. The detection limits lie between 4.9 and 18.6 μg/l and allow determinations even in the environmentally interesting concentration range. The recoveries determined using aqueous standards range between 87 and 119% and the relative standard deviations are between 4.4 and 10.1%.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Psychopharmacology 75 (1981), S. 179-183 
    ISSN: 1432-2072
    Schlagwort(e): DMT ; Gas chromatography ; Hyperactivity ; Pargyline ; SKF-525A ; Mice
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Abstract Mice pretreated with the monoamine oxidase inhibitor pargyline showed a dose-dependent increase in hyperactivity for up to 2 h following injections of N,N-dimethyltryptamine (DMT: 0.5–8.0 mg/kg). Hyperactivity was related to a linear increase in whole brain concentrations of DMT as measured by a new sensitive gas chromatographic assay. The duration of this behaviour paralleled the concentration of DMT in the brain from 15–120 min. However, at 15 min, there was no significant difference in brain DMT concentrations between mice receiving pargyline and those given distilled water at the two dose levels of DMT studied (2.0 and 8.0 mg/kg). Pre-treatment with the microsomal enzyme inhibitor SKF-525A, alone or in combination with pargyline, had no effect on the DMT-induced behaviour or on the brain levels of DMT.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Digitale Medien
    Digitale Medien
    Springer
    International archives of occupational and environmental health 48 (1981), S. 99-106 
    ISSN: 1432-1246
    Schlagwort(e): Urine analysis metabolites ; Gas chromatography ; Hexane ; Cyclohexane ; Biological monitoring
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Summary A gas chromatographic method for analyzing the urinary metabolites of n-hexane (2-hexanol, 2,5-hexanedione, 2,5-dimethylfuran and γ-valerolactone), of 2-methylpentane (2-methyl-2-pentanol), of 3-methylpentane (3-methyl-2-pentanol), and of cyclohexane (cyclohexanol) was developed. Processing of urine and the gas chromatographic conditions are described. The recovery rate of all hexane metabolites, except 2,5-dimethylfuran, ranged between 92 and 100%. The variation coefficient of metabolites determination was between 1.5 and 5%, apart from 2,5-dimethylfuran determination for which the variation coefficient was 15%. The detection limits ranged between 0.2 and 0.7 mg/1 and between 0.05 and 0.1 mg/1 when a packed or capillary column was used. Results obtained from a packed and capillary column are discussed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    Digitale Medien
    Digitale Medien
    Springer
    International archives of occupational and environmental health 49 (1981), S. 115-123 
    ISSN: 1432-1246
    Schlagwort(e): Blood analysis of solvents ; Gas chromatography ; Head space ; Toxicokinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Summary The determination of toluene, benzene, ethylbenzene and trichloro-ethylene in blood by means of a gas chromatographic head space technique is presented. Internal standards are added to the blood samples in the form of water solutions of volatile hydrocarbons in proportion 2:1. This enables application of the internal standard within the broad range of concentrations and in addition increases significantly the concentrations of investigated compounds in the gas phase of incubation vessel. Elaborated methods were applied for determinations of ethylbenzene in blood samples collected after experimental inhalation exposure and for evaluation of the rate of disappearance of benzene, toluene and trichloro-ethylene from blood after acute accidental or suicidal intoxications.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 14 (1981), S. 601-602 
    ISSN: 1612-1112
    Schlagwort(e): Ethanolamines ; Ethylene glycols ; Direct separation ; Gas chromatography ; Short glass capillaries
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary An effective and rapid GC separation of ethanolamines, even in the presence of ethylene glycols, using short glass capillary columns is developed. No preliminary derivatisation of the sample is necessary. The separation is completed in 6 minutes.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 14 (1981), S. 143-147 
    ISSN: 1612-1112
    Schlagwort(e): Capillary columns ; Gas chromatography ; Retention index ; Structure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary The retention index of twenty different homologous series of esters have been determined experimentally on polar (Carbowax 1540) and non-polar (squalane) columns. General equations to calculate retention index have been established by statistical methods. The influence of the length and inductive effect of acid and alcohol chains and the relative position of the carboxylic group are discussed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 14 (1981), S. 285-288 
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; Porous layer open tubular columns ; Kaolin as support ; Column performance
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary PLOT columns have been prepared with kaolin as the liquid phase support. These columns show good efficiency with different stationary phases and good thermal stability with polar phases. The performance of columns is shown by the separation of various mixtures such as fatty acids, phenols and anilines which are of analytical importance.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 9
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; Urea herbicides ; Catalytic hydrolysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary A method is described for the rapid catalytic hydrolysis of phenylurea herbicides on silica gel at elevated temperatures. After derivatisation of the anilines produced with heptafluorobutyric acid anhydride final analysis is done on a gas chromatograph equipped with an electroncapture detector. Detection limits are in the 1–5 picogram range. The method has successfully been applied to residue analysis of water samples at the 1 ppb level. The determination of free anilines present in water samples and the potential of various techniques to be used to discriminate between free anilines and parent herbicides are also discussed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 10
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; Polycyclic aromatic hydrocarbons ; Retention index ; Average molecular polarizabilities
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary A significant correlation has been found between the retention indices of polycyclic aromatic hydrocarbons on non-polar stationary phases and the average molecular polarizabilities of the molecules separated on these phases. Equations have been derived for the determination of the average molecular polarizabilities, directly from the retention indices.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 11
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 14 (1981), S. 69-72 
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; Polynuclear aromatic hydrocarbons ; Retention index ; Vapour pressure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary The retention index of a planar polynuclear aromatic hydrocarbon on the GC phases OV-101, SE-52, and OV-17 is strictly related only to the boiling point, and less closely to the relative molecular mass. The very approximates relation with connectivity index ins only a consequence of the latter. On a nematic lqiuid crystal phase, a variation of activity coefficient, expressed in terms of a shape factor, also influences the retention of PAH.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 12
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 14 (1981), S. 269-276 
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; Detector performance ; Trace analysis ; Catalytic conversion ; Multidimensional gas chromatography
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary Relationships are derived describing how the detection limit of a chromatographic system depends on the minimum detectable limit of the detector and the chromatographic parameters such as column length, efficiency, carrier gas flow rate and the capacity factor. Performance data of detectors developed in the last 25 years at the Dalian Institute of Chemical Physics of the Chinese Academy of Sciences are given and a few selected application examples are listed. These include trace analysis by preconcentration and by direct analysis and the utilization of multidimensional gas chromatography with two columns, two detectors, a 12-port valve, and a catalytic conversion reactor.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 13
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 14 (1981), S. 277-278 
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; C1−C5 Hydrocarbons ; Dimethyl ether
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary An analytical GC method was developed which uses a single packed column consisting of three packings in series prepared with the following liquid phases: dimethyl sulfolane, propylene carbonate, and silver nitrate. This system provides satisfactory resolution of mixtures of C1−C5 hydrocarbons and dimethyl ether obtained when converting methanol to gasoline. Due to the high capacity of the column it is possible to inject larger sample amounts permitting trace analysis.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 14
    ISSN: 1612-1112
    Schlagwort(e): Phthalides ; Umbelliferae ; Liquid-solid chromatography ; Gas chromatography ; Ligustilide
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary A liquid-solid chromatographic pre-fractionation of naturally occurring phthalides has been developed. The LSC was carried out on a column of silica applying a 1–50% gradient elution of diethyl ether (containing 2% methanol) in pentane. The enrichment in the fractions led to better possibilities for a gas chromatographic separation and isolation allowing further studies by spectroscopic methods. Ligustilide may easily isomerize during GC as a result of ageing of the column.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 15
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 14 (1981), S. 19-22 
    ISSN: 1612-1112
    Schlagwort(e): Teflon columns ; Chemically modified teflon ; Gas chromatography ; Capillary columns
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary Wall-coated open tubular columns prepared from chemically modified teflon tubing have been developed for gas chromatography. Chemical reaction of the inner walls of teflon tubing allows bonding of an adhesive layer on which a variety of stationary phaes can be coated. Test mixtures of alkanes and alcohols were used to investigate the chromatographic properties of these columns and the stability and mixing of the adhesive and stationary phae layers. the results in dicate that mixing of the layers is negligible and that the column is stable for a long period of time.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 16
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 14 (1981), S. 55-66 
    ISSN: 1612-1112
    Schlagwort(e): Capillary columns, glass ; Gas chromatography ; Column preparation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Zusammenfassung Kapillar-Gas-Chromatographie ist heute das sich am stärksten entwickelnde Gebiet der Gas-Chromatographie. Es gibt viele komplexe, neue Fragestellungen in der Analytik, welche den Einsatz spezieller Kapillarsäulen erfordem. Glücklicherweise gibt es aber auch eine große Zahl von Herstellungsverfahren für Kapillarsäulen, welche — noch mehr als bei der Herstellung von gepackten Säulen — eine Anpassung an die gestellten Aufgaben ermöglichen. In diesem Artikel werden die Herstellungsverfahren für Kapillarsäulen zusammengestellt und Anregungen gegeben, wie aufgaben-orientierte Säulen erreicht werden.
    Notizen: Summary Glass capillary column chromatography is the most rapidly growing part of gas chromatography. There are many complex new analytical tasks and they require special capillary columns, Fortunately there is a wide range of column preparation methods available, and they make the preparation of glass capillary columns a more varied job than that of packed columns. In this paper these methods are reviewed and suggestions are given for making task-oriented columns.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 17
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 11-16 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; SCOT column ; Coating, liquid phase ; Single-step coating ; Phenols ; Phenolic acids ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A single-step coating method for the preparation of glass capillary SCOT columns is described. It is reproducible and less time-consuming than the well-known two-step coating procedures. Other methods attempted are discussed briefly. Both the flame ionization and electron capture detectors could be used in conjunction with temperature programming. The separations achieved with an “activity mixture”, phenols and phenolic acids, illustrate the resolution obtained. The columns are suitable for quantitative determinations and a comparison is made with a conventional packed column.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 18
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 38-39 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Fused silica capillary column ; Activity ; Hydroxylated surfaces ; Dehydroxylated surfaces ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 19
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 411-412 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, fused silica ; Chemical bonding - cross-linking ; Apolar columns ; Preparation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 20
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 523-524 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Split injection ; Injection time influence ; PAH ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 21
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 533-534 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; End-sealing method for static coating ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 22
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 421-422 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary columns ; Unstable flavor compound ; Comparison of fused silica, glass, and metal columns ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 23
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 49-53 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Glass capillary ; Routine analysis of C1-C6 carboxylic acids ; Animal wastes ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The C1 -C6 fatty acids present in various types of heterogeneous animal wastes were isolated by steam distillation and determined as benzyl esters by high resolution gas chromatography. Glass capillary columns, deactivated with barium carbonate and coated with UCON HB 5100, allowed the analysis of benzyl formate, acetate, propionate, isobutyrate, butyrate, isovalerate, valerate, and caproate in less than 20 minutes. Recovery tests, performed on more than 50 different samples, indicated a benzylation yield and an overall efficiency higher than 99%, with a standard deviation of 2.6% (C5) to 6.0% (C1). The absolute detection limit ranged from 0.3 picomole (caproic acid) to 1.0 picomole (formic acid).
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 24
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 495-499 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary column, fused silica ; Mass spectrometry ; Interface, direct coupling ; On-column injection ; Aflatoxin B1 ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A novel fused silica capillary GC/MS direct coupling is described which ensures quantitative transfer of sample from the point of injection to the ion source of a mass spectrometer without contacting any surfaces other than the column wall. This device permits GC analysis of highly labile substances. Aflatoxin B1, previously considered unassayable by GC, can now be determined by GC/MS.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 25
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 164-168 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Simultaneous detection with effluent splitter ; Element-specific detection ; Petroleum residues ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Two glass capillary gas chromatographic systems were equipped with inert effluent splitters which allowed simultaneous data acquisition using nonspecific and element-specific detectors. Simultaneous detection was achieved using the nonspecific flame ionization detector (FID) and the Hall® electrolytic conductivity detector (HECD) operated in either the sulfur-or the nitrogen-specific mode. Typical application of the simultaneous detection system as applied to analysis of petroleum residues is briefly described. The Hall electrolytic conductivity detector can be made element specific for halogen-, sulfur-, or nitrogen-containing compounds. Simultaneous detection enhances the information yield from a single sample injection and proves to be a powerful complementary technique when used with computerized gas chromatography/mass spectrometry.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 26
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 169-172 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Residue analysis ; Pirimiphos-methyl ; Malathion ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A gas chromatographic method developed for the simultaneous determination of residues of pirimiphos-methyl (O-[2-(dimethyl-amino)-6-methyl-4-pyrimidinyl] O,O-dimethyl phosphorothioate) and malathion (diethyl mercaptosuccinate S-ester with O,O-dimethyl phosphorodithioate), in whole peanuts, peanut hulls, peanut meats, and peanut oil gives good recoveries and has a limit of detection for pirimiphos-methyl and malathion of 0.04 ppm. Quantitative analysis for the two insecticides with electronic integration was reliable to 0.1 ppm.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 27
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 295-296 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; On-column injection ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 28
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 257-259 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Dihydro dimethyl ethers of vitamin K1 ; Separtion of diastereomers ; Characterization of source of vitamin K1 samples ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A method is described for the gas-chromatographic determination of the diastereomers of vitamin K1 (phylloquinone) in the form of their dihydro dimethyl ethers. The reported method of derivatization and chromatographic analysis in conjunction with optical rotation measurements are useful approaches for characterization of vitamin K1 samples with respect to their origin.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 29
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 333-336 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Rapid analysis ; On-line analysis ; Low molecular weight hydrocarbons ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Rapid analysis is important for on-line chromatography. Gaseous or vaporized samples have been injected via heated gas sampling valves of less than 500 μl dead volume. The critical sampling and split problems could be solved by temperature programming. The general analysis described could be successfully used inter alia in scouting reactions.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 30
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Dynamic headspace analysis ; Solid waste ; Fused silica capillary columns ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A dynamic headspace stripping technique for the extraction of volatile organic compounds has been applied to a variety of solid and semisolid waste materials. A simple glass apparatus accommodates a wide range of sample sizes and allows for the volatiles to be stripped at elevated temperatures. Concentration on Tenax, followed by thermal desorption and analysis by fused silica capillary gas chromatography provides detailed information on the volatile content of waste samples of widely differing matrix composition.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 31
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 527-529 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Thermodynamics ; Identification of analytes ; Olefins ; Squalane ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 32
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 612-615 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Porous layer open tubular fused silica columns ; Aluminum oxide ; C1-C5 hydrocarbons ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A method is described for the preparation of a Porous Layer Open Tubular (PLOT) fused silica column coated with submicron particles of aluminum oxide for the analysis of light hydrocarbons. The column is thermally stable and provides reproducible analytical data over a long period of time. The column can be operated at temperatures easily controlled by commercially available gas chromatographic apparatus. 1,3-Butadiene is retarded much more than its principal impurities: thus the polarity of aluminum oxide is extremely useful for butadiene analysis because none of the contaminants is obscured by the butadiene peak. The analysis of the 16 most common C1-C4 hydrocarbons is achieved within 5 min at 60°C with helium as the carrier gas. Conditioning of the carrier gas with water vapor from CuSO4.5H2O to decrease the activity of the aluminum oxide is described. Some applications of a 30 m × 0.32 mm aluminum oxide PLOT column are given.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 33
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 603-611 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, fused silica ; Gas chromatograph/mass spectrometer/data system ; Dynamic headspace analysis ; Focused cryogenic trapping ; Pyrolysis ; Polymers ; Adhesives ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Focused cryogenic trapping has been used to maximize the high resolution capabilities of fused silica capillary columns during dynamic headspace and pyrolytic polymer analyses. Mass spectrometric detection with data system recording/processing provide sensitive, selective, and rapid results. The techniques described herein demonstrate the power of both dynamic headspace and pyrolytic analyses for troubleshooting applications with complex industrial polymer products.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 34
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 188-190 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Helium ionization detector (HID) ; Vinyl chloride ; Sulfur gases ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 35
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 346-347 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; WCOT-glass capillary ; Organophosphorus insecticides ; Pesticides ; Metabolites ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: This article considers the separation of 23 organophosphorus insecticides to which two metabolites have been added. The high resolution of the column permits detection of the Z and E isomers of three of these insecticides.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 36
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 580-581 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Coal gasification tar ; Boiling point distribution ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 37
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 215-217 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary columns ; Direct method for flavor evaluation ; Aromatic herbs analysis ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A simple, quick method is described for GC head space evaluation of herbs and drugs. The proposed procedure consists of milling a weighed sample of a certain herb in a glass device like a Braun MXK coffee grinder, modified in such a way that a special gas-tight valve allows the direct sampling of the vapors. Glass capillary columns are used to analyze the head space volatiles. Some preliminary applications of the method are given.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 38
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 232-232 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Static coating ; Sealing method ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 39
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 323-327 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Deactivation by colloidal aqueous silica plus BTPPC plus Carbowax 1000 ; Use for adsorption-sensitive solutes fails with basic compounds ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Glass capillary columns have been prepared without acidic additive in the stationary phase, from which free organic acids elute as sharp and symmetrical peaks. The required surface in the borosilicate glass capillary was generated by a combination of leaching with aqueous HCl and deposition of colloidal silica particles; it can be coated with stationary phases have a broad range of polarity. Aqueous samples containing free organic acids can also be analyzed in such columns in an isothermal mode.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 40
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 122-123 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Fused silica ; Capillary columns ; Deactivation ; Pyrocarbon ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 41
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 156-163 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, fused silica ; Priority pollutants ; Volatile organics ; Extractable organics ; Pesticides ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Acrolein, acrylonitrile, volatile organics, base/neutral extractables, acid extractables, and pesticide fraction organics are analyzed in a single chromatographic run. This is accomplished by injecting the extractable organics, then applying a cryogenic focus to the front of the column, and desorbing the volatile components. The column utilized for this procedure is a fused silica open tubular (FSOT) column coated with the liquid phase SE-54. Minimum detection limits of this procedure by electron impact GC/MS are shown to be≤ 1 μg/liter in tests conducted on actual water samples.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 42
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 180-180 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary ; Injector to column connection ; TCDD ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 43
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 186-187 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Effluent splitter, preparation of ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 44
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 578-579 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Crosslinked silicones ; Peroxide-initiated vulcanization ; Trifluoropylsilicone ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 45
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 583-584 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; 10% CuCl in stationary phase greatly improves resolution of high-boiling olefins (up to 190°C) ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 46
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 641-643 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary column ; On-column injection ; Discrimination ; Criteria given for precise sampling ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 47
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, fused silica ; Split injection ; Splitless injection ; Polynuclear aromatic hydrocarbons, quantitation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 48
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 203-208 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary column ; Split injection, vaporizing ; Glass wool as evaporation aid in split injector ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: It has been reported that glass wool packed tightly into the glass liner of a vaporizing injector used in the splitting mode considerably reduces the standard deviation of the results obtained, because of improved evaporation of the sample prior to reaching the split point at the capillary column entrance. This finding could not be reproduced on using the same sample composition as reported in the literature, i.e. methanol/2-ethyl-1-hexanol (1:1).The standard deviations obtained were between 3 and 10% (depending on the conditions selected) and were not influenced significantly by the introduction of glass wool.The peak area ratio (methanol/2-ethyl-1-hexanol) was found to depend on a number of parameters, such as: injector temperature; glass liner internal diameter; syringe handling technique; the relative position of the syringe needle exit and capillary column entrance; the sample volume injected; and the packing of the glass liner. Generally, the area ratio deviated further from the correct one (determined by cold on-column sampling) when the glass liner was packed with glass wool.On the basis of the results, it is speculated that either a complete evaporation of the sample should be achieved (which appears to be impossible under the conditions we used) or, alternatively, the sample should be given the least possible opportunity to evaporate, thus allowing it to enter the column in the form of droplets. The results were worse in terms of precision and accuracy the greater the partition of sample components between the liquid (droplet) and vapor phase. It is concluded that the use of evaporation aids such as glass wool cannot be generally recommended.
    Zusätzliches Material: 5 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 49
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 297-299 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Quantitative mulicomponent analysis ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 50
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 647-648 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Direct injection of silicone fluids method of choice for determining trace organic contaminants ; ≥ 1 ppm toluene determined ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 51
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; On-column injection ; Triglycerides ; Separation according to degree of unsaturation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Triglycerides are separated according to their molecular weight and their degree of unsaturation on glass capillary columns by use of the on-column injection technique. The columns employed are silylated SE-30 columns of 4.5, 8, and 10m length with a film thickness of ca. 0.15 μm. The paper gives several examples of chromatograms of natural and hydrogenated triglycerides as well as of mixtures of pure, known triglycerides before and after interesterification.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 52
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 151-155 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; XAD-2 resin ; Fungicide residues, determination in wine and grape juice ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The fungicides Bupirimate, Fenarimol, and Vinclozolin were sprayed on Vines. The fruits were harvested 8 and 21 days after the final application and processed to juice and wine. The fungicide residues were determined by filtration of the samples throug XAD-2 after pH adjustment, elution with methylene chloride, and glass capillary gas chromatography with SE-30 as stationary phase. Residue values of the three compounds were reported before and after fermentation. The precision of the analytical method was established by spiking portuguese white wine and spanish grape juice with the three fungicides and Triadimefon. The recoveries were in the range 80%-100%, except for Vinclozolin.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 53
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 181-182 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Diatomaceous earth ; Deactivation ; Pyrocarbon ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 54
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 183-183 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; End-sealing technique for static coating ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 55
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 294-295 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, fused silica ; 2,3,7,8-TCDD ; Tetrachlorodibenzofurans ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 56
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 385-392 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary columns ; Theory of band broadening ; Regression methods in column evaluation abt concept ; Possible aid in assessing coating efficiency ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: In the approach to the developement of a practical procedure for the evaluation of band broadening properties of gas capillary columns, the expression for the variance of a solute band is cast in a dimensionless form. This expression supplies the basis for a valid bench mark for column evaluation. Experimental results demonstrate the applicability of the method.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 57
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 406-408 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary ; Effluent splitter, fused silica ; Efficient ; Inert ; Minimum dead volume ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 58
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 437-443 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Gas chromatographic profiles ; n-Butylboronates ; Alkyl-oximes ; Primary prostaglandins ; 6-Keto prostaglandin F1α ; Thromboxane B2 ; Isomers of prostaglandin F1α ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: This work describes the use of glass capillary columns (GCC) in the rapid concurrent analysis of primary prostaglandins (PGs) (e. g. PGE2, PGE2, PGF2α) and other functionally significant metabolites of arachidonic acid (AA) such as TXB2 and 6-keto PGF1α. The use of a new multistep mixed derivatization approach that generates the methyl esters of n-butylboronate, pentafluorobenzyloxime, trimethylsilyl ether derivatives of these compounds remarkably simplifies the GC profiling of the three main pathways of AA metabolism (PGs, thromboxane, and prostacyclin). Furthermore, isomeric species giving very similar or identical mass spectral patterns can be easily identified by their relative retention times on high efficiency capillary columns.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 59
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 86-89 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Packed columns ; Multidimensional switching, MDSS ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A multidimensional switching system with two packed columns has been used for the analysis of volatiles. Use of a high-boiling solvent and the backflush mode permitted total resolution of the mixture discussed in a short analysis time.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 60
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 102-108 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Series-coupled columns with different stationary phases ; Independent temperature control of columns ; Constant mass flow rate ; Retention time expressions ; Theory ; Selectivity control ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The technique of controlling chromatographic selectivity by the adjustment of column temperatures in systems of series-coupled columns is investigated by means of a general model incorporating the effects of temperature and mobile phase compressibility. In a previous article the performance of series-coupled columns was investigated under conditions of constant overall pressure drop. The present paper, on the other hand, considers systems in which a constant mass flow rate is maintained at all temperatures. The expressions derived for the effective partition coefficient and the retention time are compared with those of the previous paper. The numerical results for two-column systems exhibit the same major trends as those for constant pressure drop. It is shown that the effective partition coefficient is slightly dependent on the mass flow rate.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 61
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 549-552 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary column ; Optically active stationary phase ; Amino acids, enantiomeric derivatives ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: An enantiomeric mixture of amino acids is derivatized to give the respective N(O)-perfluoroacyl alkyl esters which can be resolved directly by gas chromatography on a Chirasil-Val capillary column. The retention times, resolution numbers, and elution order are reported.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 62
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 218-223 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Column preparation ; “Split” vs. “on-column” injection ; Amino acid analysis, quantitative 10 ng level ; Average relative standard deviation 1% ; Fish muscle protein analysis ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A carefully Standardized technique is described for the preparation of glass capillary columns which can be used successfully for routine quantitative amino acid analysis. Comparison is made between two different modes of sample injection. Preliminary quantitative results from “split” injection and “on-column” injection techniques are evaluated statistically and it is concluded that the “on-column” system is a prerequisite for quantitative amino acid analysis by glass capillary gas chromatography. An analysis of fish muscle protein hydrolyzate illustrates an application of this technique and results are compared with those from a packed column analysis.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 63
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 184-185 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, fused silica ; Alkene halohydrins ; Positional isomers ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The use of a fused silica capillary column for the gas chromatographic analysis of alkene halohydrin positional isomers is described. This method is illustrated with the complete resolution of the positional isomers for propylene bromohydrin, propylene iodohydrin, and allyl bromide bromohydrin. Comparison with the resolution obtained on a packed column is also provided.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 64
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 209-214 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, fused silica ; Capillary GC/MS ; PAH, M.W. 300-402 ; Airborne particulate matter ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Gas chromatography (GC), low-voltage mass spectrometry (LV MS), and gas chromatography/mass spectrometry (GC/MS) have been used for detecting polycyclic aromatic hydrocarbons (PAH) of molecular weight between 300 and 402 in airborne particulate matter. Nearly 200 high molecular PAH separated by fused silica capillary columns could be characterized by their El mass spectra. The lack of reference substances precluded further structure elucidation.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 65
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Cholesteric liquid crystal phase ; Film thickness and temperature study ; Separation of geometrical isomers ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Improved separations of the isomers of olefinic aliphatic insect pheromones were obtained on cholesteryl cinnamate glass capillary columns by operating in the supercooled temperature range of the liquid crystal. Capillary columns were prepared with varying film thickness of the stationary phase; choice of the correct film thickness ensured optimum retention for a wide range of compounds within the most effective temperature range of the liquid crystal. The deactivation procedures described made the liquid crystal columns suitable for separation of the geometric isomers of polar and nonpolar compounds.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 66
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 348-350 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Use for thermolabile, nonderivatized N-methylcarbamates tested ; Faster, better separation, higher sensitivity than with HPLC methods ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 67
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 409-410 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Micro-HPLC ; Capillary columns, preparation ; Optical monitor ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 68
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 433-436 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Persilylation ; Polar phases ; Ammonia etching ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Static ammonia etching has been used to effect regular surface roughening of glass capillaries. Following such treatment, polar phases could be coated after persilylation with varioussilylation agents such as hexamethyl-, tetramethyldiphenyl-, and tetra- phenyldimethyldisilazane, respectively. This method produces columns of high thermostability, which is limited only by the maximum applicable temperature for the phase itself.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 69
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 525-526 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Mass spectrometry ; Reactions of organomercurials interpreted ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 70
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 553-556 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass ; Carbohydrate enantiomer separation ; New chiral stationary phases ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: New chiral polymers have been prepared by conversion of cyano groups of polysiloxanes XE-60 and OV-225 into carboxylic groups and subsequent coupling to give the respective S-valine-R-α-phenyl-ethyl amide. In contrast to the corresponding stationary phases with S-α-phenylethyl amide groups, which have been used for the resoultion of trifluoroacetylated hexose derivatives, the new phase show high enantioselectivity for pentose and 6-deoxyhexose derivatives.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 71
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 644-646 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Wide-bore capillary columns ; On-column injector ; Prevention of sample discrimination ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 72
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 393-397 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, fused silica ; Simultaneous detection ; Splitting capillary effluent ; Detection limit of 1 ppm Archlor 1254 ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A state-of-the-art gas chromatographic system for automatic simultaneous detection of halogenated and normal hydrocarbons has been developed, which consists of a standard Hewlett-Packard 5880 with a fused silica capillary column, whose effluent is split between the standard flame ionization detector and a Tracor Hall electroconductivity detector. The system provedes excellent capillary chromatography results and high sensitivity for halogenated compounds (a detection limit of 1 ppm Archlor 1254 in fuel oil). Reliability has been provides in the daily analysis of complex environmental samples.Emergency response cleanup and the containment of hazardous chemical spills and chemical dump sites forces one to deal with samples that are very complex. The contain large numbers of naturally occurring organic compounds and varying types of organic pollutants. Capillary chromatographic techniques of gas chromatographic and gas chromatographic/mass spectrometric analyses are necessary to achieve the resolution required for the analysis of these samples.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 73
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 317-322 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Series-coupled columns with different stationary phases ; Independent temperature control of columns ; Constant mass flow and constant pressure drop ; Temperature dependence of viscosity coefficient ; Retention time expressions ; Theory ; Selectivity control ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A previously established model of a system of series-coupled columns, incorporating the effects of temperature and mobile phase compressibility, is generalized to take the temperature dependence of the mobile phase viscosity coefficient into account. Expressions are reported for the linear flow velocity, the effective partition coefficient, and the retention time for both the case of constant mass flow rate and that of constant overall pressure drop. Numerical results indicate that the temperature dependence of the viscosity coefficient affects the retention time and pressure drop while the effective mass distribution coefficient remains essentially unchanged.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 74
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 344-345 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Capillary, glass/fused silica ; Gas phase deactivation reaction ; Readily adjustable thickness of silicon layers for deactivation ; Wettability for any known stationary phase ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 75
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 6-10 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Retention index calculation by correlation techniques ; Use of n-dialkyl sulphides as standards ; Use of selective detectors ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Retention indices were determined for a homologous series of n-dialkyl sulphides on three stationary phases (SE-30, OV-17 and XE-60) under isothermal and linear temperature programming conditions. Under these two different GC conditions, equations were derived for each of the three stationary phases which showed the dependence of retention index on the number of carbon atoms and the boiling points for a homologous series of n-dialkyl sulphides. The equation for the correlation isothermal retention index was shown to be applicable to the identification of n-dialkyl sulphides using linear temperature programming. It was found that the GC behaviour of n-dialkyl sulphides makes these compounds suitable for use as a standard series instead of n-alkanes for the calculation of retention indices in GC analysis in which detectors insensitive to n-alkanes are employed. The use of the homologous series of n-dialkyl sulphides for the calculation of sulphide retention indices can be great practical importance in the microanalysis of natural compounds. We have used this method successfully in the analysis of pesticides containing S-atoms.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 76
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 79-80 
    ISSN: 0935-6304
    Schlagwort(e): Gas chromatography ; Glass capillary columns ; Barium carbonate ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 77
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 78
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 18-22 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A history dependent solubility model is generalized in accordance with the Dual Mode Sorption Theory to take into account a history dependency of effective water diffusion coefficients in epoxy resins, based on hypothesized microcavitational damage due to the combined effects of temperature and sorbed moisture. Sorption data presented in a different paper are analyzed in the light of a transport model in which part of diffusing molecules are completely immobilized in the formed microcavities. The nature of the hypothesized damaging process is in agreement with the diffusion coefficient depressions and solubility increases experimentally found and theoretically predicted by the model.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 79
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 23-31 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: An experimental study was made of single fibers rotating and bending in Couette flow of a Newtonian liquid. A previous result for critical fiber buckling was re-tested and found satisfactory, and the transition between ‘springy’ and ‘snake’ rotation was delineated. The minimum radius, of curvature achieved during rotation in the “snake orbit” regime was measured as a function of fiber aspect ratio, Young's modulus, and fluid shear stress. Two correlations are presented which are constrained to satisfy limiting conditions for very stiff and very flexible fibers. Together with a result from thin rod theory, these correlations may be used to predict breaking conditions for fibers of known Young's modulus and ultimate tensile strength. Predictions are tested in experiments where two types of glass fiber are broken in suspension and found satisfactory. Results show that several reinforcing materials will probably break within the range of conditions covered by our experiments, or in a region which can be treated by extrapolation from our results.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 80
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The oxidative degradation of cold drawn highly oriented high density polyethylene is studied by IR spectroscopy. Both gamma and ultraviolet radiation sources are used. It is found that under gamma radiation the oxidative degradation, as determined from carbonyl formation, is reduced very significantly but that the trans-vinylene unsaturation in the polymer increases with draw ratio. Similar results are obtained for samples irradiated in vacuum or when the polymer is stabilized with a radical quencher. Annealing (with free-ends) of the samples restores the rate of carbonyl formation over and above that of the undrawn polymer although restoration after annealing with fixed-ends is not complete. There, is further increase in trans-vinylene development after annealing. In stabilized samples, the effect of annealing on carbonyl and trans-vinylene development appears to depend on draw ratio.Under ultra-violet radiation, the oxidative degradation of drawn and unannealed samples is also reduced with increasing draw ratio. The same effect is observed in stabilized samples. Annealing, once again, restores the rate of oxidative degradation to that of the undrawn polymer. The main unsaturation product during ultraviolet irradiation is the vinyl end group and its development is suppressed with drawing. During ultraviolet irradiation of unannealed drawn samples, cracks, generally perpendicular to the draw direction (intrafibrillar cracks) appear on the sample and with further irradiation they penetrate into the sample. In the case of stabilized and unannealed drawn samples, cracks parallel to the draw direction (interfibrillar cracks) appear first and continued irradiation results in the appearance of intrafibrillar cracks. These observations may have significance in modelling the fibrous structures obtained by drawing semicrystalline polymers.
    Zusätzliches Material: 21 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 81
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 1-7 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The crystallization behavior of three IUPAC low density polyethylene samples has been characterized by thermal analysis. Their rates of crystallization only are directly correlatable with their film forming ability in film blowing technology. The IUPAC samples possessed essentially indistinguishable physical properties, including differential scanning calorimetry (DSC) melting curves and rheological characteristics, but their propensity for crystallization was found readily to parallel their film forming ability and other characteristics associated with end-use performance. The application of thermal analysis to assess crystallization is a unique diagnostic tool for measuring polymer film processability, which is well illustrated here using a few simple experiments made on the original polymer specimens and a polymer blend. Although all samples exhibit similar small-angle X-ray periodicities, the morphological differences assessed, particularly by microtomy-optical microscopy, correlate with, and complement, the results of phase transformation kinetics responsible for film properties. Fractography-scanning electron microscopy proves to be inferior to optical methods for revealing the morphology of these low density polyethylenes.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 82
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 47-52 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Mixtures of two compatible polymers, poly(vinyl chloride) and poly(acrylonitrile-co-butadiene) containing 40 percent acrylonitrile, can be compatible with poly(vinylidene chloride-co-vinyl chloride), which is incompatible and partially compatible respectively with these two polymers. The crystalline melting temperature and relative heat of fusion of poly(vinylidene chloride-co-vinyl chloride) in blends are higher than those in the pure component. This is attributed to greater ordering of the polymer chains in the crystalline phases of the blends. Replacing the rubber by poly(acrylonitrile-cobutadiene) containing 30 percent acrylonitrile, shows that these three polymers, in which each pair is incompatible or at most partially compatible, also form compatible ternary blends. The crystalline melting temperature is higher and relative heat of fusion lower than those in the pure component. This is attributed to dissolving of parts of the polymer chains originally located in the crystalline phases in the amorphous phases of the blends.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 83
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 32-38 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Films of low-density polyethylene, polypropylene, and rigid poly(vinyl chloride) were exposed for 1700 h to artificial aging in a Weather-O-Meter. Photochemical aging was characterized by tensile measurements. We noted that only ultimate properties are affected, whereas properties defined in the low strain range remain unchanged. The kinetics of strain and stress at break depend as much on the polymer's initial rheological characteristics as on the rate of the chemical degradation. The results show that aging results in localized chain breaking leading to defects at the supermolecular level. The average decrease of molecular weight does not seem to influence the mechanical behavior.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 84
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 53-56 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A study has been carried out on the properties of a fast-curing two-part polyurethane sealant, and on its blends with other polymers, such as poly(vinyl acetate), poly(vinyl chloride) and poly(vinyl alcohol). Different substrates, such as Portland cement mortar, wood, and aluminum in three different thermal conditions were used. Tension tests by Universal Testing machine Model 1175 have been made, and stress-strain curves have been devised and discussed. A two-component fastcuring polyurethane sealant demonstrates good adhesivity for the supports mentioned. The elasticity of polyurethane sealants may improve even at low temperatures if mixing with other polymers.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 85
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 39-46 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Thermoplastic interpenetrating polymer networks, IPN's, are defined as combinations of two physically crosslinked polymers. A styrene-b-ethylene-co-butylene-b-styrene (SEBS) triblock elastomer was combined with an ionomer prepared from a random copolymer of styrene, methacrylic acid, and isoprene (90/10/1 by volume), and subsequently neutralized. Two subclasses of the thermoplastic IPN's were identified. A sequential polymerization method yielded the chemically blended thermoplastic IPN's (CBT IPN's). Melt blending of the separately synthesized polymers produced the mechanically blended thermoplastic IPN's (MBT IPN's). Stress-strain and Rheovibron characterization revealed that the CBT IPN's exhibited greater tensile strength and higher elongation at break, but lower moduli than the MBT IPN materials of the same overall composition. Analysis of moduli data with the theories of Takayanagi, Davies, Budiansky, and Kerner disclosed more equal dual phase continuity for the MBT IPN's than the CBT IPN's at each composition. The low modulus of the more rubbery CBT IPN compositions was attributed to a decrease in the effective chain end-to-end distance between crosslinks in the elastomeric (EB) center block, brought about by the synthetic method.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 86
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 87
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 57-63 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A real-time computer system is described which minimizes the total analysis time in gel permeation chromatography by automatically acquiring the data, performing the necessary calculations and displaying the molecular weight distribution and molecular weight averages as soon as the polymer peak has eluted. The calculation method described here is valid for linear homopolymers only, and does not include corrections for instrumental peak broadening. The experimental results show good reproducibility and precision. On-line changes of the constants and other parameters may be implemented by means of an auxiliary program which runs in parallel with the data analysis program. A system such as that described here is suitable for utilization as a measurement technique in process control applications. The programs are written in CORAL 66 for a Ferranti Argus 700 E computer.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 88
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 65-68 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: An approximate analytical solution is obtained for the flow rate-pressure drop relation for adiabatic capillary flow of a fluid with a pressure- and temperature-dependent viscosity. Neglect of the pressure dependence can result in large errors in the usual range of injection molding practice. The approximate solution follows from an exact solution of capillary flow with a viscosity that depends only on pressure.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 89
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 76-79 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The properties and processing characteristics of open-celled foams produced by leaching small NaCl particles from high density polyethylene has been investigated. In a random dispersion of salt particles in the polymer matrix a minimum volume loading of 40 percent was required to produce an open-celled foam. The time required to remove this quantity of salt with 50°C water was 100 min. The maximum porosity of the foam is limited to the maximum packing fraction of the salt. For randomly dispersed isotropic particles the maximum packing fraction is approximately 0.64. Because the composite rapidly loses melt strength as the filler content nears the maximum packing fraction, the practical upper limit of extruded foam porosity is approximately 0.60.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 90
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 86-92 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: An experimental investigation into the performance in general and the melting behavior in particular of a single screw extruder running with a low density polyethylene power has been carried out and the results compared with those for a granular feedstock of low density polyethylene having similar melt properties. It was found that the tendency was for the output rate, pressure generated and specific power consumption to be lower for the powders, and that the removal of barrel heating near the feed hopper increased these parameters. Two melting mechanisms were observed in powder extrusion; one being the classic “Maddock” type, and the other such that the solid bed and melt pool were in reversed positions relative to the Maddock case. There was a trend for this latter mechanism to operate with low screw speeds, shallow channels and full heating. Melt initiation occurred nearer the feed end and melting was completed much more quickly with powders. An explanation of the mechanisms is proposed which is based on the observation of early melt initiation, and the industrial practices of feed zone cooling and increasing feed pressure generation to improve the performance of extruders running with powders are seen to be consistent with this proposition.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 91
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 80-85 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Several rheological aspects of thermoplastic foam extrusion are described by a phenomenological model of the flow in an extrusion die. The macroscopic effects of the phase change, from a homogeneous polymer melt that contains a blowing agent, to a foam, are described in terms of two dimensionless parameters. α is defined as the ratio of the pressure gradient in the melt phase to the average pressure gradient in the foam phase. Θ represents the ratio of the pressure drop in the melt phase to the pressure drop in the foam phase. The position at which the phase change initiates, the exit contribution to the Bagley ends pressure correction, and the true wall shear stress in the melt phase are related to α and Θ. The quality of the foam produced is discussed in terms of the extrusion conditions and their effect on the foaming position in the die. It is demonstrated that the ends pressure correction cannot be neglected on the basis of a long die alone. Asymptotic conditions for which the phase change has negligible effect on the melt flow rate are predicted. α is calculated from the data of Han and Villamizar, who measured the pressure distribution in the die and observed the phase change directly. The prediction of α from theory is complicated by the lack of suitable constitutive relations for the foam phase. Since Θ only requires knowledge of the pressure at which the phase change initiates, it is relatively easy to evaluate.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 92
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 69-75 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: An experimental and theoretical study was carried out to achieve a better understanding of bubble dynamics in foam extrusion through a converging die. For the experimental study, a number of converging channels were constructed of aluminum, with glass windows on both sides. Bubble dynamics in the flow channel were recorded on movie film as a gas-charged molten polymer was extruded. The dies had various converging angles (30, 45, 60, 90, and 150 degrees), and the polymer was polystyrene. As blowing agent, sodium bicarbonate (generating CO2) was used. It was found that the gas bubbles moving along the centerline of the channel grow initially at the upstream end of the die, and then start to collapse as the gas-charged molten polymer approaches the exit plane of the die. In order to help interpret the experimental results, a theoretical analysis was made of bubble dynamics in a converging channel, in which a thread-like bubble was assumed to flow along the centerline of the converging channel and the Coleman-Noll second-order fluid model was assumed to describe the rheological behavior of the polymer melt. Some mathematically convenient simplifying assumptions not-withstanding, the theoretical analysis corroborates the experimental observations. The practical significance of the present investigation is discussed in connection with controlling the cell structure in extruded foam products.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 93
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 93-99 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A method is given for selecting the “effective viscosity” for isothermal flow of non-Newtonian liquids in screw pumps or melt extruders. Effective viscosity is the Newtonian viscosity that would give the same screw-pump performance with non-Newtonian liquids at the same flow rate and speed. When effective viscosity is known, it can be inserted in performance equations for simple Newtonian flow. The analysis is restricted to shallow screw-pump channels with large aspect ratios and to shear stress/shear rate curves with modest curvatures when shown in a double logarithmic plot. The shear stress/shear rate curve is replaced by a power-law tangent to that curve in the domain of prevailing shear rates, but the analysis could be extended to more complex behavior. Curves are also included for calculating the efficiency of the screw-pump channel, which can be used to estimate the energy dissipated in screw-pumps. It is shown that efficiency decreases with decreasing power-law exponent.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 94
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 95
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 105-112 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A process of melting individual polymer granules and then combining them into a homogeneous molten mass is examined. The granules are introduced into a high temperature fluid bath, heated as they move due to the polymer-fluid density difference and finally coalesce under the action of surface and gravity forces into a uniform polymer melt which can be used for extrusion, injection molding or other melt processing techniques. Theoretical models and analyses are presented to predict the time required to melt a granule in a particular polymer-fluid system and to have the molten granule coalesce into the developing mass of molten polymer. This latter time includes the time for the continuous phase fluid to drain between the approaching granule and the molten polymer-fluid interface and the time for the granule, once in contact with the interface, to be deposited to some specified depth in the bulk molten polymer. Design parameters for a particular embodiment of the process are presented. Experimental results obtained with a prototype device using mercury as the heat transfer medium are discussed.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 96
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 100-104 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Finite element solutions are presented for developed, isothermal, power-law flow in an extruder channel, based on a variational formulation in helical co-ordinates. The success of the method in handling non-Newtonian flow in a deep, highly-curved channel is tested by comparison with experimental results. Operating characteristics were determired under virtually isothermal conditions for a screw with depth to diameter ratio 0.25 pumping an aqueous glucose solution containing high molecular weight hydroxyethyl cellulose. Shear stress and first normal stress differences of this solution were determined in a rheogoniometer. It was both highly shear-thinning and elastic. Computed and experimental screw operating characteristics agree well, except near closed discharge, where effects due to viscous heating and elasticity are tentatively suggested.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 97
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 121-123 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A simple model, based on an average elongational rate, correctly predicts qualitatively the effects of changes in all spinning parameters on the orientation of fibers spun from viscoelastic melts. The model may be extended to any extrusion process with an elongational character.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 98
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 113-118 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A new technique for the electrical monitoring of polymerization reactions such as resin cure is described. The technique is based on the charge-flow transistor, which resembles a conventional metal-oxide-semiconductor field-effect transistor (MOSFET), but with a portion of the metal gate replaced by the resin under study. Electrical signals obtained from several resins undergoing cure are presented, along with an electrical circuit model that can account for the principal features of these signals. The dramatic change in signal shape during cure can be related to corresponding changes in both the real and imaginary parts of the dielectric constant.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 99
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 124-128 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Methods of predicting and correlating thermal conductivity of polyethylene resins in solid and melt states are discussed herein. Dependence on crystallinity or density is estimated for the solid state by a form of Maxwell's equation for electrical conductivity. An equation is presented for predicting melt thermal conductivity based upon Bridgman's theory of energy transport and pressure-volume-temperature (PVT) data. The effect of pressure on melt thermal conductivity is calculated from the theory. The effect of pigmentation for near spherical particles up to approximately 2.5 volume percent is also correlated by a form of Maxwell's equation. Experimental thermal conductivities of unpigmented and pigmented polyethylene resins from 50 to 300°C are in good agreement with theoretical predictions and with literature data.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 100
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Torsional Braid Analysis (TBA), like many other sample-supported techniques, measures the transition temperatures of a polymer deposited on an elastic support. It is shown here that any polymer transition found by the location of the maximum in the log decrement Δ (or loss tangent tan δ) of a composite shifts to lower temperatures as the rigidity (or modulus) of the elastic support is increased. The magnitude of this temperature decrease is larger for transitions at which a composite has a larger support-to-polymer rigidity ratio. In general the above conclusions hold even with unsupported systems if the rigidity (or modulus) of the sample can be increased without interfering with the polymer domain under investigation, for example, by crosslinking one of two phases of microphase-separated co-polymers.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...