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  • 1985-1989  (889)
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  • 1986  (889)
  • Chemical Engineering  (708)
  • Rat  (181)
  • 201
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 369-380 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The liquid holdup and the pressure drop for two-phase trickling flow in a packed bed were measured experimentally. Different values of those parameters were obtained as the liquid flow rate was increased and then decreased, indicating a multiplicity in hydrodynamic states. This behavior was observed even when the gas flow rate was zero in the bed. It was determined that the hysteresis exhibited by the process is due to imperfect wetting of the packing and to the difference between advancing and receding contact angles at the gas-liquid-solid contact lines. The reduced wetting conditions are also the cause of the increase in liquid holdup observed when the surface tension of the liquid is decreased. In this case, the amount of liquid retained in the bed is controlled by the extension of the wetted regions due to the more favorable contact angles as the surface tension decreases. The transition from the trickling to the pulsing flow regime was also dependent on the history of the process.A new correlation for predicting liquid holdups and pressure drops for trickling flow in packed beds is proposed for the decreasing liquid flow rate operating mode. This correlation is based on the experimental determination of the liquid phase relative permeability as a function of the the liquid phase reduced saturation and the determination of the gas phase relative permeability as a function of the gas phase saturation and the gas phase Reynolds number. The new data are analyzed in the light of the theory developed in the first part of this paper.
    Additional Material: 15 Ill.
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  • 202
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 444-454 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The electrolyte nonrandom two-liquid (NRTL) model proposed by Chen et al. (1982) is generalized to represent the excess Gibbs energy of aqueous multicomponent electrolyte systems. Using only binary parameters, the model correlates and predicts the deviation from ideality of aqueous multicomponent electrolyte systems over the entire range of temperature and concentration.
    Additional Material: 5 Ill.
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  • 203
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 751-764 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes reactive flow in permeable media based on a numerical model that assumes local thermodynamic equilibrium. The model simulates single-phase, one-dimensional flow with greater generality than any model in the current literature. The mathematical foundation for the formulation is discussed in some detail. Results for hypothetical examples demonstrate that ion exchange and precipitation/dissolution of solids can interact to produce wave behavior not possible with either phenomenon alone. An important application involving both ion exchange and precipitation/dissolution is alkaline flooding. Model predictions for several laboratory alkaline floods indicate that the assumption of equilibrium is justified for these experiments. Simple calculations based on the equilibrium theory provide estimates of pH loss and hydroxide penetration distance.
    Additional Material: 12 Ill.
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  • 204
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 782-788 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Lagrangian dispersion function in turbulent flow can be determined from measurements of the probability that a particle which is observed in a small volume is not observed in a similar size volume downstream. In this work a single-detector method is proposed to detect the particle arrivals in a multiple series of scattering volumes; the probability can be determined from the digital record over a long time compared to the turbulent integral time scale. The method is tested at locations downstream of a water spray nozzle and a submerged jet of dilute polymer solutions.
    Additional Material: 3 Ill.
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  • 205
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 809-819 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general theory is presented for the prediction of effective axial conductivity and overall radial heat transfer coefficient for fluid flow through packed beds, under either transient or steady state conditions. The parameters to be used in each case may be quite different, depending on the dominant phase for heat transfer. The theory unifies all previous results and explains conflicting conclusions arrived at by different workers. The ability of a pseudohomogeneous model to reproduce packedbed transients is shown to depend upon the choice of effective parameters.
    Additional Material: 6 Ill.
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  • 206
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 829-843 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Upward cocurrent gas-liquid annular flow was investigated in a 50.8 mm ID cylindrical vertical pipe. The film flow was studied by measuring instantaneous local film thickness, wall shear stress, and pressure gradient. Analysis of these data revealed that at low gas flow rates the film motion is controlled by a switching mechanism, as speculated by Moalem-Maron and Dukler (1984). In the region of high gas flow rates the switching process is suppressed and traveling roll waves characterize the film motion.
    Additional Material: 33 Ill.
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  • 207
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1403-1403 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 208
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1403-1404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 209
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1558-1560 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 210
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 914-931 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new high-performance multivariable time delay compensator is presented that contains the Ogunnaike-Ray compensator as a special case, reduces to the Smith predictor for a single delay, and approaches the realizable part of the process inverse as a limit. The straightforward design procedure is illustrated with several distillation control examples.
    Additional Material: 10 Ill.
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  • 211
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 971-980 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A separation theory in thermal diffusion columns with a permeable vertical barrier has been derived by making use of the orthogonal expansion method. It is shown that the undesirable remixing effect can be effectively reduced and controlled by introducing a permeable vertical barrier. Considerable improvement in separation was obtained when the position of the barrier was carefully chosen.
    Additional Material: 5 Ill.
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  • 212
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 981-990 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: To identify conditions under which gas-liquid reaction systems exhibit natural oscillations, a model is formulated in which the time scales of the elementary processes play a leading role. The steady solutions of the model problem are investigated, with the finding that at most one solution may lie in each of five temperature ranges, each range corresponding to a dominant physicochemical process.
    Additional Material: 8 Ill.
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  • 213
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1027-1035 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 214
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1015-1024 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The multiinput/multioutput pole-placement self-tuning controller (MIMO PPSTC) previously developed by McDermott and Mellichamp is used to control a fixed-bed autothermal reactor with internal countercurrent heat exchange. The performance of the controller is demonstrated using step changes in the set points and in the primary disturbance variables. It is shown that the complete temperature profile can be maintained by controlling two temperatures in the catalyst bed: one just before the hot spot and the other at the exit of the bed. Simulated results using a 36th-order nonlinear reactor model operating at both an open-loop upper stable steady state and an open-loop unstable steady state are presented. Experimental results for a fixed-bed autothermal reactor operating at an upper stable state are presented.
    Additional Material: 12 Ill.
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  • 215
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1053-1053 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 216
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1055-1056 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 217
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1057-1066 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Various ways of building quasi-Newton matrix approximations that satisfy the special form of the Gibbs-Duhem equation are studied. Partition symmetry, the separability of the functions in γ and in φ, and the method of iterated projections are used in order to develop thermodynamically consistent matrix approximations with good secant information. Many examples are presented which show that exploiting the special form of the Gibbs-Duhem equation results in improved numerical performance. Ways of exploiting the Gibbs-Helmholtz equation in addition to the special form of Gibbs-Duhem equation, and thus the isobaric form of the Gibbs-Duhem equation, are also discussed.
    Additional Material: 3 Ill.
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  • 218
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1099-1107 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A continuous, staged-feed column crystallizer was investigated to obtain enlarged product size distribution in precipitation from solution. Stage population balances, in moment form, were solved analytically for several single-feed configurations. It was found that internal staging permits control of the solids concentration profile, and if collision nucleation is unimportant then countercurrent operation yields the greatest product size enlargement. Nucleation kinetic parameters for a given salt indicate the potential product size improvement, compared to product from an MSMPR crystallizer of equal volume.
    Additional Material: 9 Ill.
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  • 219
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1116-1124 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model that describes fractionation with condensation and evaporation in a plate-fin device has been formulated. It is capable of evaluating profiles of composition, temperature, and flow rate for both liquid and vapor streams in an extended surface device. The device may be adiabatic or nonadiabatic and the surface may be incompletely wetted. Compared to experimental measurements, the model predictions showed ± 1 number of transfer unit deviation along the length of the device. The predictions of the top and bottom flow rate ratio showed a 5-10% deviation for adiabatic and condensation runs and a 25% deviation for evaporation runs.
    Additional Material: 8 Ill.
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  • 220
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1138-1145 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A recently developed error-in-variables method of calculating regression parameters was applied to the modeling of gas-solid adsorption equilibria. The method accounts for error in all experimental variables in the regression calculations. Regression coefficients from pure component data calculated by the new method were used to predict multicomponent equilibria. The multicomponent predictions using pure component parameters calculated by the error-in-variables method were more accurae than predictions using parameters calculated by conventional least-squares regression.
    Additional Material: 11 Ill.
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  • 221
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1158-1168 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Nonlocal models for the surface transport of adsorbed gases on solids are proposed and compared to experimental data. These models take into account connectivity effects due to heterogeneous adsorption potential surfaces and introduce a more realistic calculation of the surface mean free path.
    Additional Material: 8 Ill.
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  • 222
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The tendency for aggregation and disruption of aggregates of calcium oxalate dihydrate (CaOx) crystals in urinelike mother liquor was quantitatively studied in a two-stage mixed-suspension, mixed-productremoval crystallizer/Couette-flow aggregator operated in series. The degree of aggregation was obtained by comparing measured numbersize and volume-size crystal distributions in the crystallizer and aggregator outlets. Aggregation was a strong function of CaOx supersaturation and may have changed slightly with rotation speed in the Couette-flow aggregator. Rupture of the aggregates increased as the spindle rotation in the aggregator increased (presumably increasing turbulence). Average shear rates in these experiments were appreciably above estimated physiological levels.
    Additional Material: 15 Ill.
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  • 223
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1205-1207 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 224
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    AIChE Journal 32 (1986), S. 1216-1220 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 225
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1227-1229 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 226
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 227
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1242-1252 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Multiresponse kinetic models are established for the low-temperature oxidation (LTO) reactions of Athabasca oil sands bitumen. The models provide adequate description of the overall rate of oxygen consumption and of the reactions of the liquid phase bitumen components. The LTO models are suitable for use in the in situ combustion numerical simulators of the oil sands.
    Additional Material: 10 Ill.
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  • 228
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    AIChE Journal 32 (1986), S. 1277-1287 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Based on the concept of reactions in a continuum, a mathematical model has been developed to simulate coal liquefaction kinetics. In an excess hydrogen donor environment, the rate-limiting reactions are considered to be irreversible cracking reactions involving cleavage of carbon and oxygen linkages. Concurrent evolution of a wide spectrum of products, with an initial rapid formation of species of high carbon and oxygen contents, followed by progressively slower reactions leading to lower carbon and oxygen content species is predicted. Simple lumping functions are employed to obtain conventional lumped pseudocomponents (preasphaltenes, asphaltenes, and oils). Parameter analysis has been carried out.
    Additional Material: 8 Ill.
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  • 229
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    AIChE Journal 32 (1986), S. 1312-1320 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The yield of a nonpremixed series-parallel reaction at complete conversion was measured in a turbulent, tubular-flow reactor with single and multijet feeds. The yield of the intermediate decreased as mixing was slowed relative to the chemical kinetics, either by decreasing the Reynolds number, or by using a less efficient mixing device, or by increasing the feed concentration.Four models, a modified slab model, a modified stretch model, the Harada mass transfer model, and a new closure model, adequately predict the yield when chemical and mixing kinetics are known from independent measurements of the conversion of acid-base reactions. Without modification, the original slab and stretch models are unable to account for the earlier observed invariance of conversion to Schmidt number of very rapid, single-step reactions or to satisfactorily predict the yield of the series-parallel reaction.
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  • 230
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    AIChE Journal 32 (1986), S. 1334-1346 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A receding interface model of the drying of single drops of slurries of sodium sulfate decahydrate has been developed to describe the drying characteristics of this material and to estimate the drying rates of particulate slurries. The simultaneous heat and mass transfer rate equations have been solved numerically, and the results obtained have been compared with those obtained experimentally by drying single drops suspended on the tip of a glass filament.Single drops of slurries, 1.0 to 1.5 × 10-3 m dia., were suspended on the tip of a flexible glass cantilever inserted in a vertical wind tunnel. A 50μm dia. nickel wire passed through the center of the glass beam and the outer surface was coated with a thin film of copper, thereby forming a thermocouple that measured the temperature of the core of the drop; the deflection of the beam gave the loss in weight during drying. In this way the instantaneous drying rate and drop temperature were determined and compared with those predicted by the receding interface model. In all cases the agreement between the predictions of the model and experimental results was good.
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  • 231
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    AIChE Journal 32 (1986), S. 1360-1366 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Methods are presented to determine structural identifiability and distinguishability of parametric models. Results are applied to transient isotope tracing of methanation over a nickel catalyst. More meaningful information is obtained in this way about fundamental parameters than is possible by empirical curve-fitting.
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  • 232
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    AIChE Journal 32 (1986), S. 1389-1392 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 233
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 234
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    AIChE Journal 32 (1986), S. 1402-1402 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 235
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    AIChE Journal 32 (1986), S. 1403-1403 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 236
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    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 237
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The overall nonideality of an aqueous mixed electrolyte solution is characterized in terms of a newly defined parameter Γ*, called the overall reduced ionic activity coefficient. It is shown that Γ* for the mixed solution is simply related to the properties of single-electrolyte solutions. Γ* is related to the vapor pressure of a mixed-electrolyte solution through well-known thermodynamic equations. This leads to a predictive equation for the vapor pressure of a mixed-electrolyte solution in terms of the vapor pressures of single-electrolyte solutions of the components. This equation is valid over the entire concentration range encountered in practice, without any empirical constants, and has a predictive accuracy of 2%. A predictive equation for the latent heat of vaporization is also developed and tested against experimental data.
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  • 238
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    AIChE Journal 32 (1986), S. 1450-1458 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Urea adsorbs on the ruthenium titanium oxide electrode, depressing the observed current. For artificial kidney dialysate concentrations of urea and NaCl (0.50 kg/m3 and 100 mol/m3, respectively), the major electrolysis products are N2, CO2, O2, and H2, and the reaction mechanism is solution oxidation of urea by anodically generated active chlorine. A nitrogen-yielding direct electrode reaction is observed at high urea concentration (30 kg/m3) and low NaCl concentration (10-100 mol/m3).
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  • 239
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1466-1482 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A rule of hydrodynamic similarity for a scale change of fluidized beds has been developed based on the governing equations of bubble and interstitial gas dynamics. When geometrically similar scale-up is to be carried out maintaining hydrodynamic similarity, the proposed similarity rule requires that two conditions be satisfied. The first condition assures a similarity in bubble coalescence. The second assures the similarities in bubble splitting and in the interstitial flow pattern. The present work proves theoretically that these two conditions are the necessary, and almost sufficient, conditions for hydrodynamic similarity. They consider not only bubble coalescence but also bubble splitting. The theory proposed was first tested by previous correlations for bubble diameter and grid zone structure, and second by experiment. It has been proved that as long as the present rule is satisfied, the longitudinal distribution of the average bubble diameter, stochastic variation around it, and the radial distribution of superficial bubble velocity can be maintained similar for a scale change.Application of the present rule to predict the bubbling and solid circulation characteristics in a large-scale unit by a small-scale experiment has thus proved promising, at least for Geldart group B particles. In order to further study the possibility of a similarity in mass transfer and chemical reactions, computation was carried out using the three-phase bubble assemblage model. If the effect of molecular diffusion is negligible, as in the case of fluidized bed combustion, even a chemical similarity is found to be possible.
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    AIChE Journal 32 (1986), S. 1491-1499 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The sulfation model of Simons and Rawlins (1980) is extended to include the effect of product deposits. The model includes: 1. the plugging of the smallest pores and the subsequent loss in the internal surface area, 2. the diffusion of the SO2 through the product deposits, and 3. the loss of intraparticle diffusion due to the complete plugging of the largest pores. It is shown that the plugging of the smallest pores is generally rate-controlling.
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  • 241
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    AIChE Journal 32 (1986), S. 1516-1525 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Kynch's theory of sedimentation is adopted to solve for the attainable steady state concentration in a vertical continuous sedimentation basin incorporating a thickener and a clarifier. The limiting flux solution corresponding to the local minimum at the flux concentration curve is proved to have a limited range of validity and is shown to apply only to the intermediate range of feed concentrations. This limit is replaced by a five-region diagram; the solution is determined by the feed coordinates in the flux concentration plane, with respect to the flux concentration curve. Each section exhibits different characteristic solutions for both the clarifier and the thickener.The analysis, which combines dispersion, dynamics, and stability considerations, reveals new possible ranges of operating conditions where the flux exceeds the limiting flux and solids are not entrained. The results, contradicting previous published work, are verified by a finite-difference dynamic simulator.
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  • 242
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    AIChE Journal 32 (1986), S. 1526-1531 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Using the zeolite ZSM-5, new technology has been developed for catalytically oligomerizing light olefins (C3 to C4) to gasoline (C5 to C10) and diesel (C10 to C20) range product. This reaction produces product constrained by both the shape selectivity of the zeolite catalyst and the thermodynamics governing the oligomerization reaction.
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  • 243
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    AIChE Journal 32 (1986), S. 1555-1557 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 244
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    AIChE Journal 32 (1986), S. 1574-1578 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 245
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    AIChE Journal 32 (1986), S. 1597-1605 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical analysis has been performed to elucidate the relationship between two popular time delay compensation techniques, the Smith predictor and the analytical predictor. In general, use of these two techniques results in different closed-loop responses. It is only for the special case where the process model is perfect and set point changes occur, that the two techniques are equivalent. A modification of the analytical predictor has been proposed that allows the technique to be used with any feedback controller, instead of the special PI controller employed by Moore et al. (1970).
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  • 246
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    AIChE Journal 32 (1986), S. 1606-1611 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is proposed for calculating aerosol collection in the jet region of fluidized filters with sieve plate distributors. With the use of the model proposed earlier by Lefroy and Davidson and a new correlation for the single-collector efficiency, which was established as part of this study, a compartment-to-compartment procedure was developed for estimating aerosol collection. The results were compared with experimental data for model validation.
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  • 247
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    AIChE Journal 32 (1986), S. 1655-1664 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The electrolyte nonrandom two-liquid model proposed by Chen and Evans provides a thermodynamically consistent framework for representation of the phase equilibria of mixed-solvent electrolyte systems. Using only binary adjustable parameters, the model satisfactorily correlates the vapor-liquid equilibrium and liquid-liquid equilibrium of mixed-solvent electrolyte systems over the entire range of temperature and concentrations.
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  • 248
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    AIChE Journal 32 (1986), S. 1690-1701 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method is described for detecting and locating a leak in a gas transport pipeline lying between two pump stations by an indirect acoustic method. The basic concept is to treat the pipeline as an acoustic tube (similar to a wind instrument), and to estimate the impulse response of the acoustic wave in the pipeline solely from the acoustic signal detected at two terminal sites in the pipeline. The test signal introduced at the input site is only acoustic noise; pipeline operation need not be interrupted. If a leak occurs in the pipeline, the impulse response of the acoustic wave in the pipeline has a sharp pulse or a step at a certain time that can be directly related to the site of the leak. Using the mathematical model of the pipeline acoustics, i.e., the wave equation, a theoretical basis is developed to explain how and why the leak can be detected and located. Experiments carried out in the laboratory under conditions comparable to realistic field conditions demonstrate the validity of the proposed detection method.
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  • 249
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    AIChE Journal 32 (1986), S. 1716-1725 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The perturbed anisotropic chain theory (PACT) developed by Vimalchand and Donohue has been generalized to treat pure fluids that associate through hydrogen bonding, as well as mixtures of one associating component and several diluents. Using an approach similar to that of Heidemann and Prausnitz, a closed-form equation of state has been derived. It is applicable to simple as well as complex molecules at both gas and liquidlike densities and takes into account dipole and/or quadrupole moments. Molecular parameters were obtained by fitting the equation to experimental liquid density and vapor pressure data.
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    AIChE Journal 32 (1986), S. 1747-1749 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 251
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    AIChE Journal 32 (1986), S. 1754-1759 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 252
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    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 253
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The two-scale turbulence concept is recommended for modeling the turbulence in a baffled vessel equipped with a Rushton-type turbine impeller. A three-equation isotropic turbulence model is proposed that employs the balance equations for: the kinetic energy of the large scale vortices; the kinetic energy of the inertial subrange eddies; and the dissipation rate of the small-scale turbulence. The energy transfer rate from the large-scale vortices is prescribed algebraically. Flow patterns are modeled by solving the transport equations for vorticity, stream function, and tangential momentum. The Reynolds stresses are modeled by means of the effective viscosity, based on the three-equation model of turbulence. The calculated profiles of the mean velocity at the tank wall agree with experimental data obtained in the same system by means of a Pitot tube.
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  • 254
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    AIChE Journal 32 (1986), S. 1813-1820 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A computer program designed to model the turbulent reacting flow in jet-stirred reactors has been developed. In solving the single-phase flow field, a two-equation turbulence closure was used to predict the turbulent eddy viscosity variation in the reactor. The model was used to predict the performance of a real reactor. The predicted results compared favorably with measurements in the field. It was found that the key to the reactor performance is the strength of the recirculating eddy caused by the jet entrainment.
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  • 255
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    AIChE Journal 32 (1986), S. 1839-1847 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rates of hydration of isobutene were measured with Amberlyst-15 catalyst particles in a differential, liquid-full recycle reactor operating at atmospheric pressure and 303 to 333 K. Catalysts pretreated in two different ways were studied. Liquid-to-particle mass transfer had a small but measurable effect on the rate. Intraparticle diffusion was more significant, as indicated by effectiveness factors from 0.26 for the larger catalyst particles (dp = 1.04 × 10-3 m) at 333 K to 0.84 for the smaller particles (dp = 0.45 × 10-3 m) at 303 K. The intrinsic rate was first-order in isobutene concentration with an activation energy of 67 kJ/mol. The intraparticle diffusion resistance is due to the macropores surrounding the very small gel-type microparticles of which the particles were composed.Some data were obtained for reaction rates in trickle-bed operation. Global rates were somewhat lower in the trickle-bed operation than in the liquid-full runs. Using the previously determined intrinsic kinetics and effectiveness factors, the liquid-to-particle mass transfer coefficients could be approximated for the trickle-bed operation.
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  • 256
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    AIChE Journal 32 (1986), S. 1864-1875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes a study of the possibility of using point efficiencies, measured in a small laboratory column, in the scale-up of distillation efficiencies. The conditions on a large rectangular tray were closely duplicated in a small glass Oldershaw column with one sieve tray having similar hole size and percent free area. Point efficiencies on the large rectangular sieve tray were deduced from the composition profiles and compared with the point efficiencies measured in the small column. A simple relationship between the two columns was found in terms of the froth heights and liquid holdups. The results demonstrate that the slightly lower point efficiencies measured in the Oldershaw column could be used in conjunction with a mathematical mass transfer model based on the eddy diffusion concept, to relate the point efficiencies to the tray efficiences, resulting in a conservative design provided either that allowance is made for other factors, such as nonuniform flow patterns and stagnant zones, or that these are eliminated. A wide range of composition was covered using the two systems MeOH-nPrOH and EtOH-nPrOH operating in the froth region.
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  • 257
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    AIChE Journal 32 (1986), S. 1889-1901 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The separation of a He—CH4 mixture containing 9.95 mol% He in permeator modules that incorporate two different types of polymer membranes was studied theoretically and experimentally. The membranes were symmetric dense capillaries of silicone rubber and asymmetric hollow fibers of cellulose triacetate. These membranes exhibit reverse selectivities for He and CH4, silicone rubber being more permeable to CH4, and cellulose triacetate more permeable to He. The simultaneous use of these two types of membranes in a permeator enhances the enrichment and recovery of He compared to the levels obtained with a single-membrane permeator utilizing either membrane alone. The experimental results were found to confirm the theoretical predictions, the agreement being better at the lower stage cuts.
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    AIChE Journal 32 (1986), S. 1917-1919 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 259
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    AIChE Journal 32 (1986), S. 1928-1930 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 260
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    AIChE Journal 32 (1986), S. 1935-1935 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 261
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    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 262
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    AIChE Journal 32 (1986), S. 1948-1953 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Elution times determined from perturbation chromatography experiments are functions of all sorbing species isotherms through the concentration partial derivatives. Measurements at a sufficient number of appropriate compositions along with isotherm models and adjustable parameters allow reduction of the retention time data to VLE by a nonlinear parameter estimation procedure described in this paper. The method can be implemented for both empirical isotherm models, which can be used to minimize model deficiencies, and for theoretical thermodynamic models, which have extrapolation potential and may require fewer parameters.
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    AIChE Journal 32 (1986), S. 1963-1970 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: One hundred sets of R-11 two-phase pressure drop and boiling heat transfer data are reported for cocurrent down-flow over an in-line tube bundle. The pressure drop data agree with predicitions using the Diehl correlation. A new heat transfer correlation is reported, accounting for the observed convective and nucleate mechanisms.
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  • 264
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    AIChE Journal 32 (1986), S. 1988-1993 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Infinite dilution activity coefficients of aroma compounds from various chemical series were measured in model food systems (water/carbohydrates, water/polyethylene-glycols) at concentrations of various solutes. These measurements were made with a specially designed equilibrium cell. Experimental results were used to determine the parameters of group contribution thermodynamic models. The predictive capacities of the equations obtained were shown to be quite precise (8% mean deviation).
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  • 265
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    AIChE Journal 32 (1986), S. 1980-1987 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Three different pore size CoMo/Al2O3 catalysts, which had been deactivated to the same extent during bench-scale tests with an atmospheric resid, were examined for coke and metal deposits, diffusivity, and intrinsic activity for hydrodesulfurization, hydrogenation, and hydrodenitrogenation using model compounds. The aged catalysts had very low effective diffusivities and lower intrinsic activities than the fresh catalysts. Both metals and coke deposits were responsible for lowering diffusivity, but activity reduction appears to be predominantly due to metal deposits.
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  • 266
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    AIChE Journal 32 (1986), S. 1994-2001 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Macroscopic behavior of solids circulation in a large jetting fluidized bed was surveyed with a force probe. Particles mixing was studied by pulse injection of tracer particles, and a simple mechanistic model was developed on the basis of the solids circulation pattern observed. The model compares favorably with experimental tracer concentration profiles.
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  • 267
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ultrafine spherical titanium, silicon, and aluminium oxide particles were prepared by the thermal decomposition of their alkoxide vapors, produced by evaporation and subsequent heating. High-concentration ultrafine particles having geometric mean diameters ranging between 0.01 and 0.06 μm and a geometric standard deviation of about 1.4 were obtained by varying the temperatures of the evaporator containing the liquid alkoxides and the reactor furnace, and the flow rate of carrier gas. For furnace temperatures lower than 400°C for TiO2 and 1000°C for SiO2 and Al2O3, the particles obtained were found to be amorphous. The observed changes in the particle size distributions due to changes in operating conditions were compared with those predicted theoretically by solving the discrete-continuous aerosol general dynamic equation accounting for coagulation and generation of monomer by thermal decomposition. The effect of monomer number concentration on the size distribution of generated particles was found to be qualitatively explained.
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  • 268
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    AIChE Journal 32 (1986), S. 2034-2046 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The different behavior of fluid density and viscosity in going from the dilute gas to the dense fluid state gives rise to kinematic viscosities which, in the near supercritical region, are lower than for liquid metals. As a consequence, the relative importance of natural convection (as measured by the ratio of buyoant to inertial forces) is two orders of magnitude higher in a supercritical fluid (at constant Reynolds number) than in normal liquids.Binary diffusion coefficients of nonvolatile solutes in supercritical fluids were measured with a technique that involved laminar flow and diffusion in a rectangular channel. The solution to this hydrodynamic problem is presented. By varying the inclination of the solute source plane with respect to the horizontal position, apparent diffusion coefficients were measured that were up to six times higher than the “true” coefficients.Experimental binary diffusion coefficients, including published literature data, were analyzed in the light of hydrodynamic (Stokes-Einstein) theory. The analysis suggests that under the high-density, low-viscosity conditions that characterize supercritical fluids, hydrodynamic behavior at the molecular level is approached, and can be used as a basis for data extrapolation.
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  • 269
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pulse-response data for the hydrogenation of α-methyl styrene were obtained as a function of poisoning of the Pd/Al2O3 catalyst. The reaction is a first-order, reversible adsorption of hydrogen followed by a first-order, irreversible surface reaction. The experiments, at 298 to 323 K and atmospheric pressure, were carried out in a three-phase slurry reactor for which mass transport effects could be accurately accounted.Independent adsorption equilibrium data in cumene slurries showed that adsorption occurred to the same extent on both poisoned and unpoisoned sites with a heat of adsorption, ΔHc = -16.3 kJ/mol. Converted to styrene as the slurry liquid, ΔHs = -20.9 kJ/mol.The zero and first moments of the response curves indicated that the rate constant for the surface reaction was independent of the extent of poisoning. The analysis required developing a new theory for interpreting dynamic data where reactant adsorption occurred on both poisoned and unpoisoned sites. The rate constant (per unit mass of catalyst) for adsorption decreased continuously to zero as the extent of poisoning increased.The results are consistent with the concept that poisoning reduced the number of sites active for reaction, but that the activity per site for the surface reaction was constant. However, the activity per site for adsorption, while constant at poison levels up to 40%, appeared to decrease sharply at higher levels.
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  • 270
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    AIChE Journal 32 (1986), S. 2083-2086 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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    AIChE Journal 32 (1986), S. 2087-2090 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A detailed study has been made of the computing times for several common equations of state used by industry. The cubic equations are approximately equivalent to more complicated equations (e.g., perturbed hard chain and BWRS) for systems with eight or more components. Thus, it is not justified to choose cubic equations over other forms purely on the basis of computational advantage. Further, the study identifies mixing-rule summations as the dominant consumer of computing time.
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    AIChE Journal 32 (1986), S. 2095-2098 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 273
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    AIChE Journal 32 (1986), S. 1211-1215 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 274
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    AIChE Journal 32 (1986), S. 1224-1226 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 275
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    AIChE Journal 32 (1986), S. 1231-1232 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 276
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    AIChE Journal 32 (1986), S. 1233-1241 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper investigates the application of spatially adaptive numerical methods in the solution of one-dimensional premixed combustion problems. The selection of grid points by equidistribution of positive weight functions across consecutive mesh intervals is considered. The method is applied in the solution of a steady premixed laminar flame problem and a time-dependent freely propagating flame problem. The adaptive numerical results are compared with corresponding equispaced calculations.
    Additional Material: 10 Ill.
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  • 277
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    AIChE Journal 32 (1986), S. 1372-1376 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study was designed to evaluate the effects of internal droplet convection on the extraction that occurs during generation of a dispersed phase. A photographic determination of dispersed-phase controlled mass transfer from liquid droplets in the formation stage demonstrates a strong dependence on formation time. Convection appears to control mass transfer during rapid drop formation, but an abrupt transition in transfer coefficient occurs as time of formation increases. Diffusion calculations overestimate total extraction for long formation times.
    Additional Material: 5 Ill.
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  • 278
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    AIChE Journal 32 (1986), S. 1397-1400 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 279
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    AIChE Journal 32 (1986), S. 1401-1402 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 280
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    AIChE Journal 32 (1986), S. 1402-1403 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 281
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    AIChE Journal 32 (1986), S. 1404-1404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 282
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    AIChE Journal 32 (1986), S. 2047-2055 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental and theoretical study was conducted to identify the flow behavior of gas and particulates in the freeboard of a gas-fluidized bed. The axial velocity and turbulence intensity distributions were measured along the centerline and across the freeboard. A laser Doppler velocimeter (LDV) was used for the experiments. A technique based on fluorescence emission was developed to discriminate between gas-phase and particle-phase velocity information. The gas phase measurements revealed a strong influence of bubble induced turbulence on gas velocity distribution. The axial particle velocity indicated a two-stage decay with height. Models were developed to predict centerline gas velocity and transport disengagement height.
    Additional Material: 12 Ill.
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  • 283
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    AIChE Journal 32 (1986), S. 2079-2082 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 284
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    AIChE Journal 32 (1986), S. 2091-2094 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 285
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    AIChE Journal 32 (1986), S. 497-500 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 286
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    AIChE Journal 32 (1986), S. 513-516 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 287
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    AIChE Journal 32 (1986), S. 517-519 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 288
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    AIChE Journal 32 (1986), S. 520-522 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 289
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    AIChE Journal 32 (1986), S. 537-546 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analytical solution of thermally coupled system (TCS) optimization was found. Energy requirements of the TCS were minimized provided that the ternary solution being separated is ideal. The TCS is energetically profitable in comparison with other sequences of distillation columns. The solution method can be used for the synthesis of separation systems and for screening calculations, due to the great simplicity of the result.
    Additional Material: 10 Ill.
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  • 290
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    AIChE Journal 32 (1986), S. 557-565 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A finite-element method is used to solve the full Navier-Stokes and energy equations for the problem of laminar combined convection from two horizontal cylinders in tandem arrangement. From comparisons with the previous theoretical and experimental results of a single-cylinder situation, it is found that the behaviors flow and heat transfer in the upstream cylinder are close to those in a single-cylinder, but this is not the case for the downstream cylinder.
    Additional Material: 9 Ill.
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  • 291
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    AIChE Journal 32 (1986), S. 592-606 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of synthesizing processing systems via simultaneous structural and parameter optimization is addressed in this paper. Based on a superstructure representation for embedding alternative configurations, a general mixed-integer nonlinear programming (MINLP) framework is presented for the synthesis problem. An efficient outer-approximation algorithm is described for the solution of the underlying optimization problem, which is characterized by linear binary variables and continuous variables that appear in nonlinear functions. The proposed algorithm is based on a bounding sequence that requires the analysis of few system configurations, and the solution of a master problem that identifies new candidate structures. Application of the proposed algorithm is illustrated with the optimal synthesis of gas pipelines.
    Additional Material: 11 Ill.
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  • 292
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    AIChE Journal 32 (1986), S. 616-623 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Flow rate and concentration measurements in a steady state process are reconciled by weighted least squares so that the conservation laws and other constraints are obeyed. Two projection matrices are constructed in turn, in order to decompose the problem into three subproblems to be solved in sequence. The first matrix eliminates all unmeasured component flow rates and concentrations from the equations; the second then removes the unmeasured total flow rates. The adjustments to component flow rates are iteratively determined, starting with guessed values of unmeasured total flow rates.Chi-square and normal test statistics are derived by linearizing the equations, to allow detection of gross errors in imbalances and adjustments of measurements.
    Additional Material: 2 Ill.
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  • 293
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    AIChE Journal 32 (1986), S. 640-649 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A fluorimetric technique was used to determine detailed residence time and velocity distribution on commercial sieve trays installed in a five-tray, 1.22 m dia. air/water simulator. Results show a strong effect of the gas rate on the residence time distribution. At low air rates, isochron lines of high residence time are found at the column wall, and the variance distributions suggest the existence of zones of different degrees of mixing. The velocity profiles at Fs (vapor velocity load) factors less than 0.65 show severe flow nonuniformities characterized by a high velocity at the centerline and stagnant zone close to the wall. At higher Fs factors the velocity maldistribution seems to be relatively mild. Correlations are presented to estimate the velocity distribution on the tray as a function of the gas rate.
    Additional Material: 11 Ill.
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  • 294
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    AIChE Journal 32 (1986), S. 650-656 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dimensionless group [(mRT/ΔG) ln(P/P°)] is a universal function of θ (fractional filling of micropores) for different vapors adsorbed on a heterogeneous adsorbent. Adsorptive parameters are the saturation capacity (m) and the free energy of immersion of the solid in bulk liquid adsorbate (ΔG). The heat of immersion of the adsorbent determines the temperature dependence of ΔG according to the Gibbs-Helmholtz equation ΔH = ∂(ΔG/T)/∂(1/T).
    Additional Material: 4 Ill.
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  • 295
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    AIChE Journal 32 (1986), S. 677-681 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 296
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    AIChE Journal 32 (1986), S. 1053-1053 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 297
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    AIChE Journal 32 (1986), S. 1067-1078 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A low-order modeling technique for separation processes is developed by considering a staged column as a compartment system in which a number of stage are lumped to form an equivalent stage. This method leads to low-order models of separation processes directly and without linearization. Moreover, the resulting models have state variables and parameters that are physically significant. In contrast to alternative model reduction methods, compartmental analysis guarantees preservation of both material balances and steady states for arbitrary changes in the input variables.A comparison of compartmental analysis to a recently proposed technique based on orthogonal collocation, both methods incorporating an equimolal overflow assumption, shows the efficiency and robustness of the compartmental method.
    Additional Material: 12 Ill.
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  • 298
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    AIChE Journal 32 (1986), S. 1079-1087 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A scheme for rapidly computing the chemical equilibrium composition of hydrocarbon combustion products is derived. A set of ten governing equations is reduced to a single equation that is solved by the Newton iteration method. Computation speeds are approximately 80 times faster than the often used free-energy minimization method. The general approach also has application to many other chemical systems.
    Additional Material: 6 Ill.
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  • 299
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    AIChE Journal 32 (1986), S. 1125-1131 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The composition and temperature dependence of the mutual diffusion coefficient near the liquid-liquid critical point of methanol-n-hexane mixtures has been determined by Gouy interferometry. The critical exponent was found to be 0.685. Constant-temperature extrapolation to zero diffusivity located the spinodal curve. Spinodal loci calculated from the NRTL model are inconsistent with the experimentally determined values.
    Additional Material: 5 Ill.
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  • 300
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    AIChE Journal 32 (1986), S. 1132-1137 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The mechanism of potassium-catalyzed C/CO2 reaction is studied by a temperature and concentration programmed reaction (TCPR) technique. The proposed redox mechanism contains three surface complexes: -CO2K, -COK, and -CK. The oxide groups are the intermediates during C/CO2 gasification. The completely reduced form, -CK, is the end product of catalyst reduction and is the precursor for K loss. The stoichiometries of these surface groups are confirmed by oxygen and potassium balances.
    Additional Material: 6 Ill.
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