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  • 1970-1974  (362)
  • 1971  (362)
  • Analytical Chemistry and Spectroscopy  (300)
  • Engineering General  (62)
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Erscheinungszeitraum
  • 1970-1974  (362)
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 3-3 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 5-11 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: It has long been recognized that permeability, compressibility and viscosity vary during the consolidation of soil. However, the introduction of these variations into consolidation theory leads to formidable difficulties due to their rendering the equations highly non-linear. Numerical methods are given herein which enable the governing equation to be solved for a variety of different non-linear laws.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 13-24 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The simultaneous iteration method of obtaining eigenvalues and eigenvectors is employed for the solution of undamped vibration problems. This method is of significance when a few of the dominant eigenvalues and eigenvectors are required from a large matrix, and hence is particularly suitable for vibration problems involving a large number of degrees of freedom. It is shown that advantage may be taken of both the symmetry and the band form of the mass and stiffness matrices, thus making it feasible to process on a computer larger order vibration problems than can be processed using transformation methods. A method of allowing for body freedom is given and some numerical tests are discussed.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 25-33 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The general eigenvalue problem Ax = λBx as arising from vibration problems tackled by the finite element method is often solved by the economization method in which the two matrices are reduced to a more manageable size and approximate answers are obtained.This paper analyses the method in a more mathematical way than previous accounts and leads to a definition of the optimum set of variables to be retained during the reduction. An extension to the method is suggested which allows the approximate eigenvalue to be improved and bounds are obtained on the eigenvalues of the full problem before reduction.An estimate is made of the calculation involved in the method and it is concluded, by reference to examples, that the extended method leads to a more efficient algorithm.
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 35-43 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A technique is described for solving the compressible flow equations in subsonic flow. The general quasi-linear equation ∇.g∇v = 0 is considered with g a function of ∇v. ∇v, and iterations of the form ∇.gn∇vn+1 = 0 are analysed, where g0 is suitably chosen and gn defined from vn for n≥1. This approach is applied to the compressible flow equations in terms of a velocity potential ø: monotonic convergence is predicted and at each iteration the error is multiplied by a factor less than the square of the greatest Mach number in the solution.Reliable convergence has been obtained in practice solving the linear equation for øn+1 by a finite difference method. The alternative of working in terms of the stream function ψ is discussed, and also discretization by the finite element method.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 103-117 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The application of the finite element rank force method for the dynamic analysis of redundant structures is presented. The applied loading consists of discrete and distributed loads. Both forced and free vibrations are considered, the latter yielding latent vectors corresponding to dynamic redundancies.It is shown that the dynamic properties of an element are given by a static flexibility matrix, an inverse mass matrix, a damping parameter and a displacement vector representing the effect of the applied distributed loading.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 119-129 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A stiffness matrix for a finite element having the planform of an annular segment is derived using the displacement approach. Numerical problems involved in the derivation are discussed and rapid convergence to exact solutions is demonstrated on three sample problems. It is concluded that the new element will be of great value to engineers concerned with the analysis of slabs of bridge decks curved in plan.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971) 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 151-151 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 154-154 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 11
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 155-160 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The conventional central finite difference equations for the plane stress extension of flat plates are derived as a localized Ritz process. A dual differential-variational discretization of this type enables common classification of the finite difference and finite element methods. Also, it provides alternative methods of establishing sufficiency conditions and relative rates of convergence for discrete systems derived from a localized Ritz process, and the existence of solution bounds for discrete systems derived using difference procedures.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 12
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 161-179 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper is concerned with the development of consistent discrete models, via the concept of finite elements, of linear and non-linear electrothermomechanical behaviour of continuous bodies. In the development, general energy balances are utilized to derive equations governing electromagnetic fields over an element and coupled equations of motion and heat conduction of a typical element of the continuum. These equations make it possible to study a general class of field problems involving arbitrary geometries and boundary conditions. Sample problems are included.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 13
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 181-198 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The dynamic finite element technique, which is referred to in the literature as ‘computer-analysis’, is applied to wave propagation problems occurring in finite and semi-infinite linearly elastic membranes of revolution. Both semi-infinite and finite versions of cylindrical and conical membranes are considered, and a finite membrane having a meridional curve which is parabolic is solved. The source of excitation is generally a constant velocity motion of one end of the membranes, but the results for a stress-pulse input at one end of a semi-infinite cylindrical membrane are also given. The results for the finite membranes are new, and the results for the semi-infinite problems are discussed with respect to previously published results. The two-dimensional state of stress in the membrane requires careful ordering of the calculations, and the boundary conditions for finite membranes are shown to follow logically from this ordering of the calculations. The difference in the solutions resulting from prescribing an axial or a tangential velocity excitation at the end of a conical membrane is presented, and the mesh size necessary for convergence to the solution is indicated. The graphs of the results clearly indicate regions in space and time where the membrane model should be replaced by the shell formulation to represent a realistic structure. The technique is shown to be self-contained and independent of any formal method such as the method of characteristics.
    Zusätzliches Material: 18 Ill.
    Materialart: Digitale Medien
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  • 14
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 199-213 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The numerical solution of the biharmonic equation in a rectangular domain is presented in the context of continuous dynamic programming techniques. The equations are specialized to the solution of elastic rectangular plates. A suitable approximate expression of a certain functional equation containing derivatives only in one direction is used to derive equations for the stiffness and flexibility matrices of the plate. It is shown that those matrices satisfy matrix Riccati equations subject to suitable initial conditions. It is also shown that the condition of optimality in the Hamilton-Jacobi-Bellman equation directly expresses a classical variational principle, i.e. the principle of complementary energy. Some numerical examples are finally presented.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 15
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 293-294 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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  • 16
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 291-292 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 17
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 275-290 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The solution of plate and shell problems by an independent specification of slopes and middle surface displacements is attractive due to its simplicity and ability of reproducing shear deformation. Unfortunately elements of this type are much too stiff when thickness is reduced.In an earlier paper a derivation of such an element was presented1 which proved very successful in ‘thick’ situations. Here a very simple extension is made which allows the element to be economically used in all situations.The improved flexibility is achieved simply by reducing the order of numerical integration applied to certain terms without sacrificing convergence properties. The process is of very wide applicability in improvement of element properties.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 18
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971) 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 19
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 389-403 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: An important limitation of finite element analysis, namely, the need for a large number of small elements in regions of finite or infinite stress concentrations and the difficulties of convergence in such cases, is well known. Rao1 suggested a possibility of overcoming this by developing hybrid techniques combining continuum and finite element concepts. In such techniques, each region of stress concentration is covered by one large ‘primary element’ whose description includes term(s) identifying the type and order of concentration, while the remaining structure is split into a few ‘secondary elements’ which are conventional finite elements. In this paper a procedure incorporating this concept is developed and its effectiveness is clearly demonstrated by successful application to two important examples, one of them with stress singularities. The concept, in fact, can be applied equally well to other two- and three-dimensional problems of continua with discontinuities and concentrations.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 20
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 443-444 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 21
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 446-446 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 22
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 444-445 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 23
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 447-448 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 24
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971) 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 25
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 451-462 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Using the finite element method, a detailed study of the deformations and stresses produced in an elastic-perfectly plastic half-space indented by a rigid sphere was done. The analysis covers the transition region from the maximum elastic contact load to a state where this load has been increased one hundredfold. Experimental results available in the literature are in good agreement with the analysis. In solving repeatedly the large number of linear equations involved in the solution of the problem, it was found profitable, in order to save computer time, to modify the direct elimination method. This technique is described in some details in the paper.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 26
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 463-483 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Dynamic relaxation, an iterative method for use with digital computers, is described and is shown to be suitable for the solution of a system of linear equations and in particular for such problems derived from structural frame analysis. It is further shown that the method may be modified to include non-linear equations relating to these problems.Some specific examples of linear and non-linear solutions are given and comparisons are made with another computer method which performs the same tasks.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 27
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 485-493 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The convergence of nodal displacements obtained by the finite element method is investigated for special element patterns in plane elasticity with the aid of the differential equation derived from the equilibrium condition at each node. The convergence of strains is also discussed. It is shown that averaging is an effective tool for obtaining approximations to strain for some kinds of mesh arrangement. It is also shown that the approach becomes inaccurate along force boundaries.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 28
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 89-101 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The point matching numerical method and its generalization, the method of boundary point least squares, have been successfully applied to numerous boundary value and eigenvalue problems. The present paper demonstrates the application of these techniques to problems in the micromechanics of fibrous composite materials, i.e. determination of elastic moduli and stress concentrations for parallel-fibre materials which are loaded transversely with respect to the fibres. The solution technique utilizes exact solutions of the governing equations of plane elasticity for each component fibre and its surrounding matrix material in a typical repeating section of the composite material. The continuity conditions for stresses and displacements between fibre and matrix and the repeatability conditions at the boundary of the repeating section are satisfied approximately in a pointwise manner. Some special numerical techniques which were found to be particularly useful in applying the point matching method to these problems are delineated. The method is demonstrated for composite materials having circular, elliptical and square fibres in regular, staggered arrays. Numerical results are given which show the accuracy of the method as well as stress concentration and composite elastic moduli data.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 29
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 131-144 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper discusses the mathematical foundations of a technique that has been used extensively in structural optimization.1-6 Two basic problems are considered. The first of these is the concave programming problem which consists of finding the global minimum of ‘piece-wise concave functions’ on ‘piece-wise concave sets’. Since any function can be approximated by a piece-wise concave function, this method could in principle be used to find the global minimum in non-convex optimization problems. The second one is the piece-wise linear programming problem in which the objective function is convex and piece-wise linear. The iterative method outlined for handling this problem is shown to be much more efficient than the standard simplex method of linear programming.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 30
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 327-347 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Many of the known finite elements are based on a variational procedure in a functional basis of monomials. The present paper attempts to formulate completely a finite element procedure which is non-variational on a functional basis which is left to the choice of the user.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 31
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 379-388 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A very simple equation solver of very large capacity is developed. The method described here does not require a very large in-core memory; however, a fast random access device like a magnetic disk drive is required.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 32
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 361-377 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The equations governing the axisymmetric dynamic deformation of an elastic solid are considered as a symmetric hyperbolic system of linear first-order partial differential equations. The characteristic properties of the system are determined and a numerical method for obtaining the solution of mixed initial and boundary value problems in elastodynamics is presented. Two examples are considered.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 33
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 349-360 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A computer program is described for the analysis of plates in extension using the equivalent plane-framework idealization. The conjugate gradient method is adopted to solve the resulting large number of simultaneous equations. Performance figures are quoted for the program when used on an ICL KDF9 machine with a restriction of 18K on the available core store. The method is generally shown to provide a satisfactory solution to a heavy computational task and thus permits the solution of very large structural systems on a small computer.
    Zusätzliches Material: 1 Ill.
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  • 34
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 575-586 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A quadratic thick shell element derived from a three-dimensional isoparametric element was first introduced by Ahmad and co-workers in 1968. This element was noted, however, to be relatively inefficient in representing bending deformations in thin shell or thin plate applications. The present paper outlines a selective integration scheme for evaluating the stiffness matrix of the element, in which each component of the strain energy is evaluated separately using a different Gaussian integration grid for each contribution. By this procedure, the excessive bending stiffness of the element, which results from the use of me quadratic interpolation functions, is avoided.The improved performance of this element, as compared with the original thick shell element, is demonstrated by analyses of a variety of thin and thick shell problems. Editors' note: A similar development was outlined by O. C. Zienkiewicz and co-workers in lnt. J. num. Meth. Engng, 3, 275-290 (1971). Some important details differ between the two papers which are thus complementary.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 35
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 587-588 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
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  • 36
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 591-591 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 37
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 588-591 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 38
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 591-592 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 39
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971) 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 40
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 1-2 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 41
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 45-51 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A method of analysis is presented for two structures which have connections with clearance. It is assumed that the behaviour of the structures is described, by the movement of discrete nodes and that as the load on the structure changes, clearances open or close between corresponding nodes on the structures; each time this occurs the stiffness of the combined structure changes because its configuration has changed. Between these changes, the structure will behave linearly and the overall behaviour can be described as piecewise linear. Applications include diesel engine crankshafts with bearing clearances and the wrap-around problem in pin-and-eye connections.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 42
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 63-87 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The finite element method is applied to the stability analysis of structural systems subject to non-conservative forces. The development of the method is general, but the specific application considered here is the stability of thin-walled members subject to follower forces. The method predicts the type of instability, whether it be buckling or flutter. Example problems, for which exact solutions are known, illustrate the accuracy and convergence characteristic of the finite element formulation.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 43
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 53-61 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A solution is presented for the computation of the transient thermoelastic stresses in a hollow cylinder with temperature boundary conditions given as a circumferential variation of surface heat transfer coefficient. The temperature distribution is solved explicitly. The problem is set up using the Airy stress function which leads to the biharmonic equation. This approach requires the satisfaction of three Michell integrals at the inner boundary in order to ensure single-valued displacements and rotation. An iterative method is described in which these integrals are all simultaneously satisfied and thus provide the necessary non-zero boundary conditions for the solution of the biharmonic equation which is rapidly solved by Gaussian elimination. Results are presented for the general case where the temperature is a function of r and θ. The computer program is checked by assuming a constant value of the surface heat transfer coefficients. In this case a closed form solution is obtained.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 44
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 215-232 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The paper presents an analysis of the response of plastic spherical and cylindrical shells subjected to loads applied through a rigid boss. Special emphasis is placed on following the load-deflection behaviour of these structures after the application of the yield-point load in order to predict the appearance of any snapping action.The method of analysis assumes that upper bound calculations are applicable and that the associated velocity fields can be represented by a series of piecewise continuous polynomials. The internal dissipation of energy for the structures are then written in terms of the coefficients of these polynomials and the values appropriate to the solution are found by using a non-linear programming routine.The results of this analysis are correlated with a non-dimensional boss size parameter p and compared with the results of experimental investigations. Mention is also made of the possible effects of initial imperfections.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 45
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 261-273 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A study of bending of plates for small deformations by applying the finite element method is presented in this paper.A new class of displacement functions has been developed for rectangular bending elements. For the first time a method is proposed for the derivation of displacement functions in which trigonometric expressions that had apparently failed to yield satisfactory results in earlier attempts can be used along with polynomial terms.The derivation leads to conforming type of displacement functions which satisfy the convergence criterion. The approach also demonstrates how many more new displacement functions can be found.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 46
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 249-259 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper describes a search procedure for finding the unconstrained maximum or minimum of a function of many independent variables. If this function represents the volume, cost, stiffness, etc. of a structure and each of the independent variables is associated with a parameter governing the geometry of the structure then designs of optimum geometry may be made in certain cases with the assistance of this search procedure. The procedure consists of steepest gradient calculations used in conjunction with a reverse Fibonacci location process. A ridge-following technique is included to speed convergence in addition to localized exploration in the region of an optimum.The search procedure has been programmed for computer use and an outline of its structural design applications is presented together with an example of its efficiency in a specific case.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 47
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 233-248 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A finite element technique is used to determine the natural frequencies and the mode shapes of a cantilever plate mounted on the periphery of a rotating disc. The plane of the plate is assumed to make any arbitrary angle with the plane of rotation of the disc. The distributed centrifugal force is resolved into two components - one acting in the plane of the plate and the other normal to the plate. The stresses produced in the middle surface of the plate due to the in-plane forces are first determined. The increase in the bending stiffness of the plate elements due to these in-plane stresses is obtained in a manner similar to that used in the stability analysis of plates. The component of the distributed centrifugal force normal to the plate surface is added to the inertia force.From the results of computations carried out for various values of the aspect ratio, the speed of rotation, the disc radius and the setting angle, empirical formulae are derived giving the effect of these parameters on the natural frequencies. These empirical formulae are observed to be in agreement with the corresponding known formulae for rotating cantilever beams, when the aspect ratio is high.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 48
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 317-325 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The theory of conjugate approximations1 is used to obtain consistent approximations of stress fields in finite element approximations based on displacement assumptions. These consistent stresses are continuous across interelement boundaries and involve less mean error than those computed by the conventional approach.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 49
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 425-441 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A unified network-topological approach to the formulation and solution of the analysis and minimum weight design of rigid-plastic structural systems is presented. It is shown that both analysis and design can be formulated using network concepts, but that, in contrast to elastic networks, the formulation results in a mathematical programming problem. Formulations based both on the static and kinematic theorems of plasticity are presented, and it is shown that duality guarantees that the two types of formulation yield identical results. The problem is first formulated on the basis of a simple definition of yielding, and is then generalized to the case where yielding is defined in terms of a yield surface.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 50
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 445-446 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 51
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 495-508 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A refined axisymmetric curved finite element for the analysis of thin elastic-plastic shells of revolution is described in the paper. The improved element is obtained by employing cubic polynomials in terms of local Cartesian co-ordinates for the assumed in-plane and out-of-plane displacements. This introduces into the solution two internal degrees of freedom in the cord direction of each element. These internal degrees of freedom are removed by static condensation before assembling the individual element stiffness matrices, and are subsequently recovered after the nodal displacements are obtained. On comparison with the previous formulation, this procedure greatly improves the accuracy of the solution especially with regards to in-plane stress-resultants at discontinuities in the meridional curvature and interelement equilibrium of forces. The latter fact makes it possible to analyse shells with a discontinuous meridional slope. In using this element, improvement in the convergence of the elastic-plastic solutions has also been observed.Several examples illustrate the quality of solutions. The reported study is limited to axisymmetric loadings cum boundary conditions.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 52
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 509-517 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper considers methods of solution of the relevant equations based on the Newton-Raphson process. Expressions are derived for calculation with both good and very poor initial guesses and for calculation of pressure, volume and temperature during an equilibrium process. A method of programming the calculations is outlined. Variations and modifications to suit specific situations are discussed.
    Zusätzliches Material: 1 Ill.
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  • 53
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 149-149 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 54
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 145-147 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The Dynamic Relaxation (DR) method of solving a set of simultaneous linear equations requires an estimate of the spectral radius of the matrix. Dividing each equation by the corresponding row sum of moduli of the elements of the matrix gives a convenient upper bound of unity to this. This note shows that the DR method then gives a faster asymptotic rate of the convergence than the degenerate Chebyshev method which it closely resembles.
    Materialart: Digitale Medien
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  • 55
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 295-296 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 56
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 299-315 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A system of finite element shell analysis codes, called SABOR/DRASTIC, is used to analyse a complex two-layered shell of revolution under static and dynamic asymmetric loads. The dynamic analysis is compared with experimentally measured response. In this linear elastic analysis, emphasis is placed on the inherent flexibility of the finite element method in modelling the complex structural geometry of a given test specimen. Static studies, which involve variations in important shell parameters, and dynamic studies, which provide a successful correlation with experiment, are used to illustrate both the detail and the generality with which shell analyses may now be performed with confidence.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 57
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 415-423 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The analysis is aimed at determination of displacements in elastic-perfectly plastic frames, in the case of monotonically increasing loads. Spread of partial plasticity from hinges and change of geometry on the conditions of equilibrium are not included. Extremum energy principles and linear programming methods are employed to solve the problem. Both the kinematic and the static formulations of the problem are presented. The mathematical models of the formulations constitute a dual pair of linear programming problems.
    Zusätzliches Material: 2 Ill.
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  • 58
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 405-413 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: In convection heat transfer problems, it is convenient to solve the governing differential equations by using straightforward marching techniques for numerical integration. However, the boundary layer equations in these heat transfer problems are not of the initial value type even though they are parabolic equations. Consequently marching techniques are not successful until correct initial values are known. A means of determining these initial values is presented herein. Selected optimization methods are utilized in conjunction with marching integration techniques to solve third- and fourth-order ordinary differential equations which have three unknown initial boundary conditions. Two optimization methods, one deterministic and the other non-deterministic in nature, are used both independently and in combination as determined by the particular circumstances. Two applications are used to demonstrate the technique and comparison is made with existing solutions.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 59
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 519-528 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: A computer orientated method is presented which generates meshes of triangular elements in plane and curved surfaces. Depending on geometrical and material variations, the region to be discretized is divided into a number of four sided zones. By using curvi-linear co-ordinate systems, nodes within and on the boundary of each zone are automatically positioned and referenced to a global Cartesian co-ordinate system. Elements are automatically assembled from these nodes. Input data is required to specify the positions and material properties of each zone and how they are connected. Examples are given which illustrate the range of meshes that can be generated. Extension of the method to generate three-dimensional tetrahedral elements is indicated.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 60
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 529-552 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The discrete element displacement method is used to analyse the finite-deflection behaviour of shallow arches. The arches are idealized as assemblies of shallow curved elements and the necessary properties of the displacement patterns in these elements are discussed. Numerical solutions of the geometrically non-linear problem are obtained by directly minimizing the total potential energy of the system.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 61
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 565-574 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: Finite element procedures usually require more degrees of freedom for a specified accuracy than does a classical Ritz procedure if suitable coordinate functions are available. This paper develops a combined global and local dependent variable representation which couples the conventional and finite element Ritz methods. This hybrid method preserves much of the flexibility of the finite element method while increasing the solution accuracy for a specified system order. The method is illustrated by examination of a beam and a plate vibration problem.
    Zusätzliches Material: 5 Ill.
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  • 62
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 3 (1971), S. 553-563 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: For a hierarchy of polynomials on the triangle there is derived an algorithm for computing the stiffness matrix of the plate bending element. The algorithm is easy to program and means a considerable saving of the computing time. The same approach can be used for any elliptic equation with constant coefficients.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 63
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 99-101 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
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  • 64
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The electron-impact induced fragmentation of twenty 3-alkyl-1-phenyl-Δ2-1,2,4-triazolin-5-ones, three 1-phenyl-1,2,4-triazolin-3,5-diones and ten 2-alkyl-4-phenyloxadiazolin-5-ones has been studied by conventional mass spectrometry. The major cleavages take place in the 1-phenyl-Δ2-1,2,4-triazolin-5-one nucleus, producing three major fragment ions. 4-Phenyloxadiazolin-5-ones exhibit a similar fragmentation pattern to 1-phenyl-Δ2-1,2,4-triazolin-5-ones. Furthermore, several additional fragmentation processes are observed in the case of specific 1,2,4-triasolines.
    Zusätzliches Material: 1 Tab.
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  • 65
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 187-195 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Some of the fragmentation modes operating in a few furanosesquiterpenes have been established from accurate mass measurements and metastable data.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 66
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 235-236 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 67
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 237-248 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The ionic fragmentation of twelve partially fluorinated β-diketones, RCOCH2COCF3 was studied with a medium resolution mass spectrometer. In addition to the anticipated fragmentation by β-cleavage, a number of interesting rearrangements are observed. [CF3COCH2CO]+., an ion common to all of the compounds investigated, decomposes predominantly by elimination of HF. When R is an alkyl group containing hydrogen γ to the adgacent carbonyl, the McLafferty rearrangement occurs. The [RCOCH2CO]+.ion eliminates neutral RH when R is phenyl, thienyl, or cyclopropyl. An intense metastable peak, absent when R is an alkyl substituent, accompanies the rearrangement in these three compounds. A number of fragments characteristic of the R substituent are also observed in many cases. This is interpreted as indicating a considerable degree of charge localization on the R moiety.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 68
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 297-301 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Three bicyclic thioketones were examined by combined gas chromatography-mass spectrometry. Deuterium labelling was employed in the interpretation of the fragmentation processes in thiocamphor. Compared with the oxygen analogues, the thiones yielded on electron-impact a higher proportion of characteristic fragment ions containing the hetero-atom.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 69
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: High resolution mass spectrometry, metastable defocusing and deuterium labeling of trimethylsilyl (TMS) ethers have been used to study the electron-impact induced fragmentations of o-, m- and p-hydroxyalkylphenones and their TMS ether derivatives. These derivatives have proven useful in contrasting the fragmentation patterns of singly- and doubly-charged ions because of the competing fragmentations: α-cleavage and a McLafferty rearrangement from the ketone moiety and methyl cleavage from the TMS group. A proximity effect was responsible for a markedly increased methyl radical loss from the o-TMS ether. This fragmentation was minor with the m- and p-isomers. Significantly intense doubly-charged ions were formed from ketonic cleavage and by the loss of a TMS methyl radical. The sequence of fragmentation depended on the size of the alkyl group attached to the ketone carbonyl. There was no evidence found for a McLafferty rearrangement occurring from the doubly-charged molecular ion of the TMS ethers of the hydroxyalkylphenones but the rearrangement occurred from the doubly-charge molecular ion of bis-3-(1-oxopentyl)-4-hydroxy-phenyl-methane and, of course, from the singly charged [M]+. The bis-p-hydroxyphenylmethane derivatives were studied in an effort to increase the intensity of the doubly-charged ions as it was expected that the charges would be separated by a longer distance.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 70
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 599-604 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The vapor phase reactions of various metal alkyl and alkoxy ions are discussed. Ions produced from suitable precursors can react with neutral molecules which contain an electronegative site. It appears that ions containing a positively charged silicon, tin, germanium or mercury center are more reactive than corresponding carbonium ions.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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  • 71
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 565-572 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: High resolution mass spectrometry has been employed to establish the structural formulae of the unique carotenoid pigment siphonaxanthin, its natural ester, siphonein and several derivatives. Siphonaxanthin exhibits a fragmentation reaction that is unusual among carotenoid pigments, namely, the elimination of carbon dioxide, observed as [M - CO2] and [M - (CO2 + H2O)]. This reaction involves the migration of an oxygen atom. Siphonaxanthol, a partially hydrogenated siphonaxanthin, exhibits a similar reaction involving the elimination of carbon monoxide and formaldehyde. From the fragmentation of derivatives of siphonaxanthin, such as the triacetate, the dimethyl ether and siphonaxanthol, and also from the fragmentation of related pigments, such as loroxanthin and fucoxanthin, the unique structural units responsible for the elimination of the carbon dioxide and carbon monoxide have been identified.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 72
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A study on the behavior of a large number of monomeric and dimeric coumarins in the mass spectrometer is reported and discussed. The results illustrate that the observed characteristic fragmentation patterns are of considerable utility in the application of mass spectrometry to structure elucidation in this series.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 73
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 289-295 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of 1,2-dichloro-3,4-bis(dichloromethylene)cyclobutene (IV) and of hexachloropentafulvene (II) have been studied. Compound IV cannot be an intermediate in the formation of II from octachloro-1,2-dimethylenecyclobutane (III) under electron-impact, as previously suggested. In the mass spectra of II and IV the species [C6]+ and [C5]+ occur, obviously through cleavage of the semicyclic C-C bond.The mass spectrum of pentachlorofulvalene (VI) shows strikingly that successive elimination of an even number of CI atoms is preferred over that of an odd number of CI atoms; probably corresponding C-CI bonds in the two rings are broken simultaneously. Amongst the fragments, the species [C10]+ and [C7]+ and possibly also [C8]+ and [C9]+ have been observed.
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
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  • 74
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 317-324 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The low resolution mass spectra of a number of homologous 5-alkylthio-1,3,4-thiadiazolyl-2-amines have been determined. With the methylthio compound the only significant loss from the molecular ion is the sulphydryl radical. As the homologous series is ascended this reaction becomes less important and is insignificant with the butylthio isomers. The ethylthio compound suffers extensive loss of ethylene and when the alkyl group contains three or more carbon atoms the main reaction is always loss of the olefin coresponding to the alkyl group.All of the n-alkylthio compounds showed in addition loss of methylthio radical from the molecular ion. A mechanism is proposed and comparisons made with alkyl phenyl thioethers and alkylthio substituted heterocycles.
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
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  • 75
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: From the mass spectra of site-specifically deuterated analogues of isonicotinic acid it appears that the molecular ion eliminates hydroxyl and water after an exchange between the hydroxylic and β-hydrogens. The percentage of exchange in these reactions depends on the internal energy of the molecular ion and is shown to be 53 to 57% in the ion source, 92 to 97% in the first and ∽ 100% in the second field free regions.Furthermore, the isotope effect i, operative in the loss of water, increases with decreasing internal energy of the molecular ion, being 1.6, 2.0 and 2.3 in the ion source, first- and second field free regions, respectively.In the molecular ions, losing successively hydroxyl and carbon monoxide as deduced from diffuse peaks in the first-and second field free regions, a substantially lower percentage of exchange (ca. 20%) is found, which is due to the higher internal energy of these molecular ions.In the molecular ion of nicotinic acid only one of the ortho hydrogens (α) is involved in the exchange of hydrogen. The percentage of exchange for loss of hydroxyl in the ion source is 66%. Molecular ions, which successively eliminate hydroxyl and carbon monoxide, show a 45% exchange of hydrogen as calculated from diffuse peaks in the first- and second field free regions.
    Zusätzliches Material: 7 Tab.
    Materialart: Digitale Medien
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  • 76
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 573-597 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The electron impact (EI) and field ionization (FI) mass spectra of some representative underivatized cardenolides have been studied together for the first time, with the objective of assessing the structural and in particular the sequence information afforded by this promising analytical method. Two series of cardenolides have been examined, each consisting of a mono-, di- and trisaccharide glycoside. The first was based on the aglycone digitoxigenin and comprised neriifolin, thevebioside and cerberoside; the second was based on the genin strophantidin and included cymarin, K-strophantin-β and K-strophantoside. Other cardiac glycosides investigated and discussed include digitoxin and helveticoside. Important and structurally diagnostic fragmentations have been uncovered, especially in FI mode. In addition, the EI and FI spectra of individual components of the cardenolides have been recorded, e.g. the genins digitoxigenin and strophantidin, and the mono-saccharides L-thevetose, D-cymarose and D-glucose.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 77
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971) 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 78
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 633-649 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of the Al(III), Cr(III), Fe(III) and Co(III) complexes of the anions of hexafluoroacetylacetone (hfac) trifluoroacetylacetone (ttac), benzoyltrifluoroacetone (btac) and thenoyltrifluoroacetone (ttac) have been determined and are discussed here. Emphasis is placed on discerning which of the observed reactions may properly be attributed to the influence of the metal in the complex and those which may be thought of as arising from the nature of the ligand. The most important influence of the coordinated metal is related to its ability to be reduced2; however, the presence of the metal serves to prohibit or facilitate certain rearrangement reactions relative to the free protonated ligand. Since essentially all fragmentation occurs within or by loss of a ligand, the nature of the ligand determines the nature of the observed fragments. Where intramolecular com-petition of fragment types is possible (tfac, btac and ttac complexes), the most probable fragment of a given class, odd electron or even electron, is easily determined. The most commonly eliminated fragments are CF3and CF2. Certain metastable peaks are associated with consecutive decomposition in the field free region. Such a phenomenon appears to be common for molecules of the type studied here.
    Zusätzliches Material: 4 Tab.
    Materialart: Digitale Medien
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  • 79
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1132-1132 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 80
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The molecular ions of the title compounds appear to lose a molecule of benzaldehyde or a benzyl radical. The first reaction is followed by the elimination of a second molecule of benzaldehyde, the second reaction by either the expulsion of a molecule of benzaldehyde or a molecule of benzylalcohol. These degradations can be readily explained by assuming charge localization in the purine or pyrimidine part of the molecular ions. For the successive loss of a benzyl radical and of a molecule of benzaldehyde from the molecular ions, however, charge localization at one of the ether oxygen atoms may also be responsible to some extent, as demonstrated by the mass spectrum of 1,3-dibenzyloxy-2-ethylpropane.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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  • 81
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The formation of [CH2OH]+. by fragmentation of [C3H7O]+. ions in the electron-impact mass spectra of 2-methyl-2-propanol and 2-propanol has been investigated using 13C labeling, deuterium labeling and metastable studies. The similar fragmentation reaction in the chemical ionization mass spectrum of acetone has been studied. It is concluded that the fragmentation reaction does not involve complete randomization of the carbon atoms and therefore does not proceed through formation of a hydroxylated cyclopropane intermediate. Alternative mechanisms are discussed.
    Zusätzliches Material: 4 Tab.
    Materialart: Digitale Medien
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  • 82
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971) 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 83
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 939-944 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of the tris(dimethylamino)arsine metal carbonyl complexes [(CH3)2N]3-AsM(CO)5 (M = Cr, Mo and W), trans-[(CH3)2N]3AsCr(CO)4As[N(CH3)2]3 and [(CH3)2N]3-AsFe(CO)4 were examined and compared with those of the corresponding tris(dimethylamino)-phosphine complexes. The molecular ions in the mass spectra of the tris(dimethylamino)arsine complexes have a greater tendency to eliminate a (CH3)2N fragment than the molecular ions in the mass spectra of the corresponding tris(dimethylamino)phosphine complexes. The mass spectrum of the tungsten derivative [(CH3)2N]3AsW(CO)5 exhibits not only the usual series of ions [(CH3)2N]3-AsW(CO)n+ and [(CH3)2N]2AsW(CO)n[+ but also the series of ions (CH3)2NAsW(CO)n]+ (n = 5, 4, 3, 2, 1 and 0) and even the nitrogen-free ions [AsW(CO)n]+ (n = 2, 1 and 0). Metastable ion evidence was obtained for arsine (AsH3) elimination from the [(CH3)2N]2AsFeH+ ion in the mass spectrum of [(CH3)2N]3AsFe(CO)4.
    Zusätzliches Material: 4 Tab.
    Materialart: Digitale Medien
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  • 84
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 967-975 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A series of alkylphenylketones has been examined. Whenever the alkyl chain is three or more carbon atoms long, the well-known McLafferty rearrangement occurs with elimination of the elements of a neutral olefin. The further fragmentation of the ion formed in this rearrangement reaction has been studied using the technique of ion kinetic energy (IKE) spectroscopy. The measured release of kinetic energy has been used to show that the rearrangement ion has an enolic type structure.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 85
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1027-1027 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 86
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1029-1041 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of quinuclidone-3, benzquinuclidone-3, 2-azaquinuclidone-3, 2-azabenzquinuclidone-3 and some of their functional substituted derivatives have been investigated. Fragmentation of the compounds investigated has been shown to proceed through the open form of the molecular ion with cleavage of a bridgehead bond containing the carbonyl group and subsequent elimination of carbon monoxide.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 87
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1081-1084 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A complex rearrangement on electron-impact for β-aroyl-α-methylpropionic acids, involving both hydrogen and hydroxy migration followed by loss of carbon monoxide and allyl radical, is described and discussed. The rearrangement process, resulting in an ion [ArCOOH2]+, is favoured by electron-withdrawing substituents in the aromatic ring.
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
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  • 88
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 89
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1345-1346 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Elimination of CO gives rise to prominent peaks in the mass spectra of cis-1,2,3,6-tetrahydrophthalic anhydride (Ia) and its 4,5-dimethyl analogue which are almost absent in the corresponding trans-isomers. The striking difference in the fragmentation of the isomers shows that practically no rearrangement in the molecular ion occurs prior to this fragmentation. In this case a high degree of stereospecificity is observed, although hydrogen migration is apparently not involved in the process.
    Materialart: Digitale Medien
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  • 90
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1349-1362 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of norbornene, nortricyclene and deuterium labeled derivatives thereof have been studied. The appearance potentials of the ions [C7H10]+·, [C7H9]+, [C6H7]+ and [C5H6]+· have been determined for both compounds and heats of formation of the hydrocarbons have been estimated. Detailed fragmentation schemes are proposed for the molecular ions and it is concluded that they dissociate by essentially different mechanisms which do not involve common intermediates. The structures and energy contents of the primary fragment ions are discussed in detail by comparing energetics, labeling experiments and metastable ion abundances.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 91
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1391-1397 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Experimental evidence demonstrating reversible hydrogen transfer between specific positions in the molecular ions of anisole and o-toluic acid suggests stepwise mechanisms for the loss of CH2O and H2O, respectively. Added support for a stepwise mechanism for the loss of CH2O is found in the mass spectra of pyridine and quinoline analogues.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 92
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1429-1453 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of methyl, n-butyl, t-butyl, phenyl and cyclohexyl boronates of various classes of steroid are reported and discussed. Steroid types represented are 17α, 21-dihydroxy-20-ketones, 17α, 20, 21-triols, 17α, 20-diols, 20, 21-ketols. Each gives rise to characteristic fragmentation modes, although derivatives of the 20α- and 20β-hydroxy compounds have similar spectra.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 93
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1189-1196 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The mass spectra of a series of substituted indolosteroids have been obtained. With one or two exceptions these are some value in structural analysis; the N-benzyl compounds are exceptional in this. One interesting observation is that substituents such as the oximino- or nitro-groups only have a marginal effect upon the fragmentation-pattern except on the masses of the various fragment ions.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 94
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1-13 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The major decomposition pathway involved in the fragmentation of derivatives of the title ring systems was the loss of RCN from the five-membered ring, except when this ring had a 3-amino,3-hydroxyl or 3-mercapto substituent. In these cases, the exocyclic substituent and at least one nitrogen atom from the five-membered ring were lost.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 95
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 53-59 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: In contrast to adducts I of bi-1-cycloalken-1-yls and p-benzoquinone, their reduction products II do not exhibit a double hydrogen migration from δ positions accompanying a ‘retro-Diels-Alder’ type fragmentation. An ordinary retro-Diels-Alder fragmentation was found to take place, with charge retention in the diene portion of the molecule. A double hydrogen migration has been detected in II leading to m/e 112 ion c2, which differed, however, from that in I in charge retention and in the origin of the migrating hydrogen atoms. Adducts III of di-1-cycloalken-1-yls and naphthoquinone behave similarly to II. They exhibit relatively low abundance ions a, however, due to a double hydrogen migration from δ positions, similarly to I. The origin of the migrating hydrogen atoms have been determined by deuterium labelling. Mechanistic suggestions are presented to explain the observed facts.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 96
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 79-81 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A classification of alkylbenzenes is proposed based on the relative intensities of pairs of ions, of which one is formed from the other by loss of a hydrogen molecule.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 97
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 103-104 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 98
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 545-550 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Mass spectra of 2-methyl-5-chloro-3-N-ethyl-benzothiazolium iodide and labeled counter-parts are discussed with particular emphasis on the loss of ethylene from the moiety produced by thermal elimination of HI from this salt. This process demonstrates the stepwise nature of a McLafferty rearrangement involving a hydrogen transfer to an olefinic carbon.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 99
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 3 (1971) 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 100
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 3 (1971), S. 1-5 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The configuration of the insecticidal and medicinal lipid ‘affinin,’ N-isobutyldeca-trans-2, cis-6, trans-8-trienamide, may be assigned in an unequivocal manner by NMR spectroscopy. The spectral data and the advantages of the multiple irradiation methods are presented and discussed.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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