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  • Electronic Resource  (674)
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  • 1990-1994  (674)
  • 1990  (674)
  • Chemical Engineering  (674)
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 22-29 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polymer blends of nylon 66 and thermotropic polyester with long flexible spacers in the main chains were prepared by melt mixing. The samples were made as single filaments by passing the polymer blend through a small and round die of a capillary rheometer. Mechanical properties of blends showed that the modulus and strength of nylon 66 could be improved without reduction of extensibility. The morphology of fractured surfaces was observed by a scanning electron microscope (SEM). It showed that the microfibrillar structure of a thermotropic polyester was formed by extensional flow while the spherical and ellipsoidal particles in the nylon 66 (matrix polymer) were produced by shear flow. The polyester particles were occasionally covered with adhering matrix polymer because of good adhesion between these two polymers. They were highly elongated by tensile stress without loss of elongational characteristics of blends. This fact was explained by very good adhesion between the two phases.
    Additional Material: 8 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 83-89 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The physical behavior of the diglycidyl ether of bisphenol A, cured with different concentrations of 2-ethyl-4-methylimidazole, was examined with dynamic mechanical and dielectric analyses, differential scanning calorimetry, and solvent extraction studies, ‘The network formation process was shown to depend strongly on the imidazole concentration’. At high imidazole concentrations, the gel point was characterized by a decrease in sol fraction, the crossover of the dynamic moduli and a rapid increase in viscosity. At low imidazole concentrations, the viscosity remained low until the sol fraction approached zero. For this system, the gel point, which occurred prior to the dynamic moduli crossover, was characterized by comparing the thermal properties of the network with the viscosity and dielectric behavior of the resin system during cure.
    Additional Material: 12 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 108-117 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We examine several practically important problems, related to the mechanical behavior of dual coated optical fibers: low temperature microbending, evaluation of spring constant due to coating layers, strength of the end portions of fibers clamped in terminal fixtures, and prediction of stresses caused by the misalignment of the openings in the frame and in the terminal fixture. The developed formulas are simple, easy-to-use, and clearly indicate the role of the major factors affecting the mechanical behavior of the fibers. The obtained results can be of help in physical design of dual coated fibers and optical interconnections.
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 129-133 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The “Efficiency of Energy Absorption” (or “Efficiency”) and “Ideality” parameters were evaluated for several plastic foams and were found to be very useful in choosing an appropriate cushion for the protection of a specific product. The maxima in these parameters were found to be in the same range of stresses, when derived from dynamic measurements or from predicted stress-strain curves based on previously proposed “Reference” and “Modified Boltzman Superposition” Models. For the rate independent foams the maxima in these parameters do not change with strain rate and can therefore be derived from slow, constant rate (“static”) experiments. For rate dependent foams however, the maxima from “static” measurements were found to be in a lower range of stresses than those derived from dynamic ones. As a result, slow rate compressive measurements do not predict well the behavior of the foams during impact and the use of the “Reference” and “Modified Boltzman Superposition” Models is required for good predictions. It was found that the suffer PS and PE foams attain maximum Efficiency and Ideality at higher stresses than the more flexible PUR foams.
    Additional Material: 11 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 96-107 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Sudden changes of compressive strain-rate on glassy poly(methyl methacrylate) lead to the conclusion that the post-yield state under a constant stress is a state of steady flow in the polymer. Non-linearity between the stress divided by temperature and the logarithm of strain rate for this steady plastic flow can successfully be analyzed using the Eyring equation with structural factors variable depending on stress and temperature. This analysis gives a unique functional relationship between the activation entropy and the activation enthalpy, which agrees fairly well with that for the melt derived from the WLF equation. This agreement provides a direct evidence verifying structural change of the glass into liquid-like structure and enables us to recognize the conformational arrangement as an essential structural parameter controlling molecular mobility. Another experimental relation between the Eyring factors - the activation volume and the activation enthalpy - permits us to estimate the magnitude of an elementary volume for the molecular movement in the melt as a function of temperature. Moreover, the experimental finding of the steady flow in the glassy polymer motivated us to propose a transition mechanism from elastic deformation to plastic flow in which the internal viscosity or the activation volume is introduced as a single parameter representing the transient state of the structure.
    Additional Material: 16 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 118-123 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An apparatus was designed and assembled to study the solvent removal from solution-cast thin polymer films. The computer interfacing of a thermogravimetric analyzer, spectrophotometer, electronic flowmeters, and control valves for the apparatus enabled the preprogramming of the carrier gas velocity, carrier gas solvent content, and temperature profiles to simulate the environment experienced in large parallel flow industrial driers. The apparatus has also been designed and operated to enable the visual observation of the drying film with an optical microscope. Initial experimental studies conducted with the apparatus involved the effect of temperature on solvent removal. The results indicate that high dryer gas temperatures can apparently cause skinning of the film surface resulting in slower solvent removal rates. The skin formation can be suppressed by higher solvent concentration in the carrier gas. The visual observations revealed the formation of standing waves in the film surface during drying at high gas velocities (〉2OO cm/min). The wave formation at least partially overcomes the effect of skinning by increasing the surface area of the film, and may be the manifestation of flow instabilities involving circulation within the film.
    Additional Material: 9 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 147-152 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ultrasonically induced bubble formation for the production of thermoplastic foam was investigated experimentally and theoretically as a basic study. A general purpose polystyrene and blends of low density polyethylene and polyethylene wax were saturated with nitrogen gas under various pressures and the ultrasonic excitation was applied to the polymer system upon release of gas pressure. The ultrasonic nucleation of bubbles in the polymer matrix was modeled by utilizing the classical nucleation theory. The negative pressure generated by the ultrasonic excitation was considered as the environmental pressure at the moment of nucleation. The experimental results showed that the heterogeneous nucleation must be used for ultrasonic foaming of the viscous fluid and the homogeneous nucleation for the low viscosity fluid. The theoretical analysis also indicated that the ultrasonic nucleation can be applied to the production of thermoplastic foam if the ultrasonic excitation generates large enough negative pressure.
    Additional Material: 10 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 7-12 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Extrusion measurements have been carried out on blends of nylon 6 and a liquid-crystalline copolyesteramide (LCP). The flow curves at low temperature show a behavior similar to that of pure LCP with a rapid rise of the viscosity at low shear rates. At high shear rates the viscosity is lower than that for each of the two components. This minimum has been attributed to the lack of interactions between the two phases and to the formation of fibrils of the LCP phase. The SEM analysis shows, indeed, that fibrils of the LCP phase are produced in the convergent flow at the inlet of the capillary at high shear rates. These fibrils are lost during the flow in the long capillary.
    Additional Material: 12 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 124-128 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Rheological studies of an experimental liquid crystalline (LC) copolyester were carried out using a capillary rheometer and a cone and plate rheometer. Rheological characteristics of the polymer in the nematic state were observed. The nematic melt was found to be pseudoplastic and the degree of pseudoplasticity varied with shear rate. Melt viscosity was found to decrease with shear rate. Negative die swelling was observed at the exit of the capillary rheometer at temperatures marginally above the solid-nematic transition temperature of the polymer and was also found to be a function of shear rate. The dynamic mechanical properties of the polymer were studied as a function of temperature. The activation energies of flow and of dynamic mechanical deformation were calculated.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 137-141 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ion beam mixing was used to improve the adhesion between deposited Cu film (400 Å) and polyimide (PI) substrate. Ar+ ion with the energy levels between 180 and 200 keV, and the dose between 1014 to 4 × 1016 ions/cm2 were used. The surface analyses were carried out by Rutherford Backscattering Spectroscopy (SEM). RBS analysis, using 2 MeV He+ ions, showed mixing of Cu and FI and the mixing depended on the Ar+ energy and dose. The X-ray study showed a very broad halo for deposited Cu film but the (111) peak appeared after the Ar+ implantation and the peak increased with Ar+ ion dose. Optical micrographs showed that Cu film formed circular bubbles after many thermal cycles when adhesion was poor and fracture cracks when adhesion was good.
    Additional Material: 7 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 153-161 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The general domain in which this work resides is that of mixing in creeping flows. Mixing, in this context, refers to the stretch of an interfacial line, or area in a strain field. The advancement of mixing technology is applied to the design of continuous mixers used in polymer processing. The geometric designs included single screw extruders, static motionless mixers, and co- and counter-rotating twin screw extruders. The co-rotating twin screw extruder was chosen to be studied in detail since it enjoys wide applications and, for which, little understanding of the contribution to mixing in the different screw geometries is known. In order to evaluate the rate of mixing for the non-uniform strain history flows, the method for measuring mixing had to be reexamined and broadened. An automated method has been developed which incorporates a digital camera and a computer to analyze the cross-sections of interest. Two measures of mixing - the correlation function and the distribution function - are developed to describe mixing in these regimes. These measures are applied successfully to the mixer geometries revealing subtle differences as to the nature of mixing in each.
    Additional Material: 14 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 175-186 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper describes the shear imposed interfacial segregation of release systems for the facilitated attenuation of polyurethane (PU) adhesion to metal coun-terfaces using a RI-RIM system. It is shown that the migration rate of the dispersed release additives due to a shear imposed stress in the resin fluid is much greater than that arising from Fickian diffusion, thereby removing a vital constraint from conventional practice. The novel rotary injection RIM system is presented to simulate the on-line injection and shear induced interfacial segregation in model PU/abherent systems. A wide range of recipes comprising single (liquids or solids) and multicomponent (liquid-liquid and solid-liquid) release materials were injected into the polymerizing resin mixture to provide cohesively weak and friable “particle” boundary layer assemblies at the PU/metal interface. An instrumented Blister Test was employed to evaluate the quality of the molded interfaces in terms of adhesion and the concentration distribution of the injected species in the final cured moldings was determined through high pressure liquid chromatography (HPLC). A comparison of the results on the shear modified and the compounded interfaces confirm an accentuated lateral migration of the additives to the interface resulting in an appreciable diminution in the adhesion of the system. Finally, transport models are suggested to account for the observed augmented transport.
    Additional Material: 12 Ill.
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  • 13
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 197-201 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It is the purpose of the present publication to show that most of the phenomenological viscoelastic theories developed for bulk polymers can be readily adapted to plastic foams in order to evaluate their mechanical properties. In addition it will be demonstrated how the mechanical properties of open cell plastic foams can be predicted from a few simple compression and relaxation experiments.
    Additional Material: 7 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 211-218 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We have extended the essential work of fracture technique to allow for the determination of the plane-strain essential work of fracture. The new technique is to measure the specific work of fracture as a function of ligament length in deeply double edge notched samples. This type of data is then experimentally corrected to remove the plastic work of fracture and leave only the essential work of fracture as a function of ligament length. By extrapolating the essential work of fracture to zero-ligament length, we claim to be measuring the plane-strain essential work of fracture. This new technique was applied to two rubber toughened nylons and to a series of polyethylenes. The plane-strain essential work of fracture was found to be independent of thickness. Where comparison can be made to J-integral testing, the plane-strain essential work of fracture was similar to the critical J-integral, JIc.
    Additional Material: 9 Ill.
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  • 16
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 228-234 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The objective of this work has been to study composite systems in which carbon fibers are dispersed in a liquid crystal polymer matrix. The fundamental point of interest here has been the interfacial response that fiber surfaces can potentially induce in self-ordering polymers. The matrix material used was a thermotropic liquid crystal polyester synthesized in our laboratory from the monomers p-acetoxybenzoic acid, diacetoxyhydroquinone, and pimelic acid. The aromatic-aliphatic polymer was characterized by NMR as a chemically disordered polymer of the three structural units which exhibits a nematic phase at temperatures above 150°C. Breadline proton NMR above the solid to liquid crystal transition was used to measure the rate of magnetic alignment of molecules in the matrix and polarized optical microscopy was used to analyze interfacial zones in composite samples. Fiber surfaces were found to influence the orientation and orientational dynamics of a liquid crystal polymer matrix. This was revealed by enhanced rates of magnetic orientation in the polymer melt when carbon fibers are dispersed in the medium. Fiber surfaces were also found to stabilize nematic ordering of the polymer as the melt was heated towards complete isotropization. The phenomena discovered here may originate in the development of zones around fibers with a common molecular orientation anchored by the carbon surface.
    Additional Material: 10 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 241-248 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A series of impact tests are described in which the plane strain fracture toughness, Kc1, of five different polymers is measured using a three point bend specimen at striker speeds up to 5m/s. At low speeds Kc1 is determined using the maximum load and a static analysis, but at speeds greater than 1 m/s the dynamic effects render the load signal unusable. For the higher speeds the fracture is timed using contact and crack propagation gages and the analysis is performed using the striker displacement at fracture. A dynamic analysis is used to convert this measurement to the true specimen displacement and Kc1 is determined from this. The apparent downward trends in the Kc1 results obtained, especially at speeds above 3m/s, are discussed.
    Additional Material: 14 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 385-393 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We have developed a new method to measure the true temperature of the polymer melt and its three-dimensional distribution of a shot stored in the reservoir during injection. By means of this method, it is demonstrated that the temperature distribution of the polymer melt stored in the reservoir is strongly dependent on the setup molding conditions, the polymer investigated, and the geometry of the screw used. Further, it is noted qualitatively that there are two major effects of screw geometry on the temperature distribution of polymer melts. One, which governs strongly the temperature in the high temperature zone, is shear heat generated within the polymer itself in the metering zone of the screw during the transporting process. The second is the ability to preheat and plasticate the polymer in the compression zone, which is indispensable for uniform plastication.
    Additional Material: 17 Ill.
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  • 20
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The breaking strength, strain at break, and work to rupture of perfect fibers prepared with polymers of finite molecular weight are calculated by treating the perfect fiber as a stressed crystal undergoing a crystal-melt phase transition. In this view, a tensile load destabilizes the crystal and depresses its melting point. When the load is sufficient to lower the melting temperature to the ambient condition the fiber melts - i.e., fails. The theoretical equations (extremely simple) are applied to several common polymer fibers. The maximum tensile strength of polyethylene, for example, is calculated to be 7 to 9 GPa, in good agreement with current experimental results.
    Additional Material: 2 Ill.
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  • 21
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Vinyl polymers containing pendant acetal groups were synthesized using (2,2-dimethyl-l,3-dioxolan-4-yl)methyl acrylate (DMA) and (2,2-dimethyl-l,3-dioxo-lan-4-yl)methyl methacrylate (DMM), and were evaluated as negative electron beam (EB) resists. It was found that the EB sensitivity of polymers containing acetal groups in the side chain was higher than that of polymers containing acetal groups in the main chain. A high sensitivity of 3.6 × 10-8 C/cm2 was observed. Copolymers of DMA or DMM with styrene were also synthesized in order to improve the durability for dry etching process. It was found that the copolymers had an excellent dry etching durability and were adaptable to EB lithography.
    Additional Material: 5 Ill.
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  • 22
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 453-458 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The thermal behavior of poly(etheretherketone)(PEEK) film heated in an open differential scanning calorimetry (DSC) pan at 20°C/min is distorted by relaxation of the strained film. PEEK film in a closed pan or quenched PEEK in open or closed pans shows a glass-transition temperature (Tg) around 144°C, cold crystallization (∼22 J/g) at 177°C, melt-temperature (Tm) peaking at 335-340°C, with an enthalpy of fusion of 32-34 J/g, and recrystallization on cooling at 285°C, with a crystallization exotherm of about 40 J/g. The enthalpy of fusion decreases with increasing heating rate from 2-100°C/min and approaches the enthalpy of cold crystallization. With increasing heating rate, further crystallization of PEEK during the DSC scan is suppressed. With increasing cooling rate, PEEK melt crystallizes at larger supercoolings to a lesser extent. Crystallization on cooling the melt was more complete than cold crystallization and annealing on heating.
    Additional Material: 4 Ill.
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  • 23
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 459-468 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The electrical and dielectric properties of compression-molded segregated polyethylene-carbon black mixtures are described in the frequency range between 10 and 8000 kHz as a function of frequency, temperature, and carbon black loading. The segregated systems investigated exhibit insulator-conductor transitions in the range 0.25-0.65% (volume/volume) carbon black. The dielectric constant and the dissipation factor of the conductive samples are relatively very high in the frequency range studied. The dielectric constant increased sharply with the carbon black concentration, and then increased moderately beyond the insulator-conductor transition. The dissipation factor-concentration curves for different carbon blacks show maximum values in the vicinity of the critical concentration values. The dielectric properties of these systems are discussed in terms of interfacial Maxwell-Wagner polarization effects.
    Additional Material: 9 Ill.
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  • 24
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 476-479 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The heat capacities of isotactic polypropylene and its composite with glass fiber have been measured at high pressure, up to 7 MPa, in the melt state by high pressure differential scanning calorimetry (HPDSC). The values also have been calculated from the data of specific volume (V) measured by dilatometry and thermal conductivity (κ) and thermal diffusivity (α) measured by a compensating hot wire method. The values of the heat capacity measured from HPDSC are consistent with those from the calculation method. The heat capacities of molten polypropylene and its composite increase linearly with temperature at a constant pressure and decrease with pressure at a constant temperature. It was found that the heat capacity of polypropylene is insensitive to molecular weight. The heat capacities of molten polypropylene composites are found to be predicted by an additive rule from the weight fractions of heat capacities of polypropylene and glass fiber.
    Additional Material: 7 Ill.
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  • 25
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 480-484 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mutual diffusion coefficients for styrene-butadiene rubber (SBR)-ethylbenzene systems were measured using a sorption apparatus with a quartz spring at 100 and 130°C for mass fractions of ethylbenzene ranging from 0 to 0.17. The mutual diffusion coefficients were correlated with good agreement by the free-volume theory.
    Additional Material: 7 Ill.
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  • 26
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 27
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 485-489 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polymers were prepared from saturated (HMDS) and unsaturated (AN) monomers in a radio frequency discharge (plasma). The effect of selected parameters such as electrode type (such as Cu, Zn, Ni, Al), reactor type, and substrate temperature (other parameters constant) on chemical structure and the rate of polymer deposition was examined by Fourier transform infrared (FTIR) spectroscopy. Differences in the nature of electrodes and reactor types were found to yield similar plasma products with similar rates of deposition for two monomers. In the tubular reactor used, deposition rates were observed to decrease with increasing substrate temperatures showing different dependencies on temperature for the monomers tested.
    Additional Material: 10 Ill.
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  • 28
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 469-475 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dielectric and magnetic properties of polystyrene composites containing barium or nickel-zinc ferrites were studied as function of the ferrite concentration and field frequency. The composites were prepared by methods yielding a random distribution of the ferrite particles or segregated structures. Barium ferrite-poly-styrene composites exhibited a typical insulator behavior, and only above 60% ferrite were high values of the dielectric properties noted at the lower frequencies, decreasing gradually with frequency to the low values typical of the higher frequencies. The mode of barium ferrite particle distribution did not affect the dielectric properties. The nickel-zinc ferrite systems demonstrated a conductor type behavior. An apparent insulator-conductor transition was observed, having lower values for segregated than for random distributions. The magnetic permability of barium ferrite-polystyrene composites above 10% ferrite increases with the ferrite concentration, whereas the magnetic dissipation factor steeply increases with concentration above 40% ferrite.
    Additional Material: 6 Ill.
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  • 29
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 493-510 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Morphology and properties of polymer alloys can be controlled by thermody-namlcally reversible (structure freeze-in) or irreversible (structure lock-in) processes by simultaneously manipulating miscibility, mechanisms of phase separation, glass transition temperature (structural relaxation), and cure kinetics of polymer systems. Using phase diagrams consisting of binodal and spinodal curves, the morphology of epoxy/CTBN (carboxyl-terminated butadiene acryloni-trile copolymer) systems can be controlled by the mechanism of nucleation and growth or by spinodal decomposition via simultaneously manipulating the kinetic processes of phase separation and curing reactions. We have found that the particle size of the rubber reinforcement in epoxies is affected by the mechanisms of phase separation. Phase separation by nucleation and growth gives larger rubber particles than the corresponding phase separation by spinodal decomposition. This contrast in the morphology development is the consequence of controlling phase separation through chemorheological behavior. Medication of the phase separation kinetics in epoxy/CTBN systems was extremely effective at altering both morphology and properties of these alloys. This technique offers a means to shift the glass transition temperature of the rubber-rich phase drastically without reducing the glass transition temperature of the epoxy-rich phase significantly. Such control over morphology is the key to ultimately controlling material properties. This morphology manipulation allows us to tailor the mechanical properties of alloy systems.
    Additional Material: 16 Ill.
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  • 30
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 511-518 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends of polypropylene (PP) and ethylene-propylene rubber (EPR) and blends of polystyrene (PS) and styrene-butadiene rubber (SBR) were prepared in a laboratory-scale internal mixer at various blend compositions and rotor rates. Blend morphology was studied by means of electron microscopy. For each blend pair under the given processing conditions, the phase inversion process occurred progressively with respect to the variation in blend composition; it is within this composition range of phase inversion that dual-phase continuity was observed. In addition, Characteristic torque values of blends were found to deviate negatively from a linear additivity rule; the composition range of maximum deviation from linear additivity corresponded approximately to the composition range where dual-phase continuity was observed. Sperling's predictive scheme was found to yield acceptable (although not completely satisfactory) estimates for compositions of dual-phase continuity in the present systems. It was also observed that partial cross-linking of SBR during the mechanical blending process, as suggested by the appearance of a cure peak in the torque curve and supported by infrared spectroscopic evidence, resulted in morphological features drastically different from those of the uncured blends.
    Additional Material: 10 Ill.
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  • 31
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 519-526 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends of an engineering thermoplastic, poly(ethylene terephthalate) (PET), and two liquid crystalline polymers (LCPs) viz., copolyesters of PET and parahydrox-ybenzoic acid (PHB) in 40/60 mole percent (LCP60) and in 20/80 mole percent (LCP80) were prepared. A blend of LCP60 and LCP80 in 50/50 weight percent (LCP60-80) was blended with PET. Both flat films and rods were extruded and their properties examined. The morphology of the films investigated using Scanning Electron Microscopy (SEM) revealed that the LCP phase remained as dispersed droplets in the PET matrix. In spite of the lack of fibrillation in these films, the mechanical properties were enhanced to some extent with a maximum at 10 weight percent of the LCP phase. However, in the case of the rods thin fibrils of the LCP phase of the order of 1 μm in diameter were observed provided the composition of the LCP was 20 weight percent or greater. This success In achieving fibrillation is through to be due to the extensional flow fields present at the entrance of the capillary die and the fact that a short L/D ratio die was used. Differential Scanning Calorimetry (DSC) thermograms of the extruded films indicated that the LCP phase may act as a nucleating agent for the crystallization of PET. Rheology of the blends revealed that the complex viscosity of the blends is not much different from that of pure PET. This is attributed to the partial miscibility of the two components. Based on the DSC results and residence times in the extruder, it is concluded that no significant transesterification reactions appear to have: taken place in the blends. The rheology is studied further with respect to the cooling behavior of the pure components and factors important to the fibrillation of the LCP phase and the formation of in-situ reinforced composites are discussed.
    Additional Material: 7 Ill.
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  • 32
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 618-618 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 33
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Eight commercial semiconductor grade epoxy compounds that are used to encapsulate 1C (integrated circuit) devices have been evaluated for their ability to minimize the development of thermal stresses which can cause failure during device temperature cycling. Thermal expansion, dynamic modulus and adhesion studies are used to describe the mechanical interaction between the plastic package and the silicon device it surrounds. A “figure of merit” is defined for the development of stress on the 1C device as it is cooled after the packaging process. The stress is shown to be proportional to the product of three terms: (αp-αs) Ep (Tanch-T) where αp and αs are the expansion coefficients for the plastic and silicon, respectively, Ep is the modulus of the epoxy and Tanch is the temperature at which the epoxy becomes anchored to the silicon device during transfer molding. In addition, the importance of good adhesion between the epoxy encapsulant and the silicon device to prevent package cracking has been demonstrated by finite element analysis and a novel adhesion test.
    Additional Material: 16 Ill.
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  • 34
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 603-608 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Covalent grafting of mesogenic chains on carbon fiber surfaces was attempted as part of a study on composite materials containing liquid crystal polymer matrices. Grafting in these composite systems is viewed not only as a mechanism to achieve interfacial bonding but also as an approach to modify the interphase physical structure. The synthetic approach to grafting involved the in-situ polymerization of monomers in the presence of functionalized fibers in order to grow chains covalently attached to the fibers. The chemical mechanism may be viewed as the “transesterification of car boxy lated fibers” with acetylated monomers. The monomers used were pimelic acid, p-acetoxybenzoic acid and diacetoxy hydroquinone which are known to yield upon condensation a chemically aperiodic nematic polymer. Evidence for grafting was obtained from X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) analysis on fibers retrieved from composite samples. Interestingly, SEM micrographs of fractured composite specimens containing the mesogen-grafted fibers reveal excellent wetting and interfacial bonding of a liquid crystalline matrix on the carbon surfaces. Based on theoretical considerations for end-adsorbed macromolecules and the nematogenic nature of the grafted chains we infer that dense layers of adsorbed polymer may form at the interfaces studied. From a materials point of view the in situ growth of liquid crystal polymer chains on fibers may offer mechanisms to control composite properties through both bonding and molecular orientation in interfacial regions.
    Additional Material: 9 Ill.
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  • 35
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We present chain structure, phase morphology, and toughness relationships in thermoplastic polymers and polymer/rubber blends. In neat polymers, molecular aspects of craze/yield behavior are controlled by two chain parameters: entanglement density νe and characteristic ratio C∞. The crazing stress is proportional to νe1/2, and the yield stress is proportional to C∞. The dispersed rubber toughens a polymer/rubber blend mainly by promoting energy dissipation of the matrix. The toughening efficiency correlates with the rubber phase morphology and the chain structure of the matrix.
    Additional Material: 7 Ill.
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  • 36
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 762-768 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The positron annihilation lifetime spectroscopy (PALS) technique is used to measure volume relaxation in physically aged glassy polycarbonate. The relaxation times and activation energy calculated for the isothermal relaxations in the aged polycarbonate are greater than those parameters calculated for unaged polycarbonate. The activation energy of 8.2 kcal/mol in the aged polycarbonate is used to identify the phenyl group motion or the cooperative carbonate-phenyl interaction as the molecular features responsible for the thermally induced open volume relaxations. It is postulated that the open volume relaxation kinetics as measured by PALS can be used as a nondestructive indication of property differences between aged and unaged polycarbonate.
    Additional Material: 6 Ill.
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  • 37
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 769-775 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of added silica on the spherulite radial growth rates of isotactic poly(propylene oxide) (i-PPrO) has been investigated by optical photomicroscopy. Two different i-PPrO samples were used of different molecular weights and isotacticity, 87 and 100% as determined by 13C NMR. The addition of fine particle silica, an effective nucleating agent, depresses the spherulite growth rates throughout the entire temperature range, but the effect is more dramatic for the i-PPrO of lower isotacticity. For a given sample, the retardation increases as the quantity of filler increases. The growth rate-temperature behavior is analyzed in terms of the classical Hoffman-Lauritzen equation, modified to take into account the polymer-filler interaction.
    Additional Material: 4 Ill.
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  • 38
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 835-840 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effects of different cure procedures on the structure and properties of epoxy samples made from diglycidyl ether of bisphenol A (DGEBA) and mixtures of two linear aliphatic diamines were studied. The elastic modulus, fracture toughness, impact resistance, and glass transition temperature were determined for various cure schemes. The morphologies of the cured resins were characterized with small angle X-ray scattering. The results show that samples with the same average morphology (molecular network structure) have similar elastic moduli and glass transition temperatures. If some heterogeneity is introduced in the molecular network structure without changing the average structure, however, the experiments indicate that the toughness can be increased without significantly sacrificing other properties.
    Additional Material: 6 Ill.
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  • 39
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 841-847 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Viscoelastic properties of polypropylene melts filled with small (0.15 μm) and large (4.0 μm) CaCO3 particles have been measured. The effects of particle size, loading, and rheological history on the dispersion of particles have been investigated. The dispersion of particles was found to decisively influence the viscoelastic properties of these filled polymers. The systems filled with large particles exhibit a relatively stable viscoelastic behavior. The small particle-filled polymers with low loading are stable similarly to the large particle-filled system. For the system filled with 30 wt% small particles, there appears a “second plateau” in the storage modulus G′ curve in low frequency region and the height of the second plateau depends strongly on the rheological history. The results are interpreted in terms of the formation of an internal structure of particles. It was found that the internal structure of particles is broken up by a steady shear flow and the dispersion of particles is changed.
    Additional Material: 10 Ill.
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  • 40
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 829-834 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Three copolymeric perfluoroethers with the structure CF3[(OCF2CF2)p(OCF2)q] OCF3, having different p/q ratios, have been fractionated. The fractions obtained have been characterized by Gel Permeation Chromatography and 19F-NMR. The viscosity η the specific volume v and the glass transition temperature, Tg have been measured by standard techniques for all the above samples as well as for some other perfluorinated polyethers.The temperature dependence of viscosity of the unfractionated samples is described by the W.L.F. equation. The values of fg (fractional free-volume at Tg) and of af (free-volume expansion coefficient) are independent of composition, for p/q ratios from 0.53 to 1.15. The critical molecular weight, Mc, is of the order of 8-9,000. From the molecular weight dependence of specific volume, the contribution to the molar volume of the in-chain CF2 group and the excess molar free volume of the chain ends have been determined. The limiting value of Tg for an infinite molecular weight polymer was found to depend linearly on the compositional ratio O/C and the extrapolated values for polytetrafluoroethylene and for the homopolymer (CF2O)n were found to be respectively 200 K and 120 K.
    Additional Material: 7 Ill.
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  • 41
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1146-1150 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Divalent metal (I.e.) Ba(2+), Ca(2+i), Mg(2+), Mn(2+), Cd(2+), Zn(2+), Pb(2+), and Sn(2+) salts of monovalent organic acids (i.e. p-methoxycinnamic, cinnamic, p-methoxybenzoic, and 4-n-butoxybenzoic) were synthesized via the double decomposition reaction from aqueous solution. Optical microscopy and differential scanning calorimetry (DSC) analysis showed that this series of salts formed nematic liquid crystals. DSC thermograms were characterized by broad nematic-to-isotropic transitions indicative of biphasic regions in which the nematic and isotropic phases coexist. These liquid crystalline salts were polymeric when melted due to ionic crosslinking which took place through the coordination of the divalent metal ion. Except Sn (2+) and Pb(2+), all the liquid crystalline halato-polymers were spun into fibers.
    Additional Material: 2 Ill.
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  • 42
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1158-1164 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The steady shear viscosity and dynamic moduli, at 180 and 200°C, of polystyrene composites, containing cross-linked monodisperse polystyrene beads varying in diameter from 0.2 to 0.8 μm, are independent of bead size and cross-link density, but increase with the volume fraction of beads. Steady shear viscosities exhibit power-law regions up to 40% concentration of beads, but no yield stress. Storage and loss moduli are initially linear with frequency, on double logarithmic plots, with limiting slopes of 1.3 and 0.9, respectively. Uncross-linked beads and beads cross-linked with 0.1% divinylbenzene are destroyed by thermomechanical dispersion in the melt.
    Additional Material: 10 Ill.
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  • 43
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1140-1145 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Room temperature mechanical properties, such as flexural strength and impact resistance, of epoxies and graphite/epoxy composites go through a maximum as a function of epoxy conversion. For tetraglycidyl 4,4′-diaminodiphenylmethane (TGDDM)-4,4′-diamlnodiphenylsulfone (DDS) formulations, the recommended cure cycle prescribes a maximum temperature close to 177°C. The maximum extent of reaction that may be obtained at this temperature is determined from the vitrification curve. At this maximum conversion, balanced mechanical and physical properties are attained in the partially cured specimen. However, if the standard cycle is used to cure thick parts, the maximum temperature inside the sample increases beyond 177°C. This leads to a complete conversion in most of the part and a consequent impairment of resulting physical and mechanical properties. It is shown how numerical solutions of differential energy and mass balances may be used to propose alternative cure cycles such that the maximum conversion at every point remains bounded by the vitrification curve. An illustration for a particular thickness is provided.
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  • 44
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1165-1170 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal lithography on poly(ethylene terephthalate) (PET) is carried out by inducing crystallization through selective exposure of amorphous films to Infrared radiation. The obtained images can be smaller than the wavelength of the CO2 laser light. This circumvention of the diffraction limit is accomplished by taking advantage of the non-linear temperature dependence of the crystallization rate. The optical marking process is reversible through simple melting of the crystalline images. The complementary process, selective melting of an initially crystalline film, can also be accomplished. The use as a heat sink of a mask which forms the image pattern is demonstrated.
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  • 45
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1182-1182 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 46
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Tab.
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  • 47
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1171-1174 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new approach involving dynamic melt rheology i.e. dynamic mechanical analysis in a molten inert matrix, is presented for studying the cure of thermoset resins. The degree of cure by dynamic melt rheology has been correlated with that from differential scanning calorimetry, DSC (correlation coefficient = 0.87) and the lack of an excellent correlation is attributed to the uncertainties with the DSC method at higher cure levels. A kinetic expression with appropriate constants, “E, A, and n” from our new approach is presented for predicting the time-temperature dependence of the degree of cure. Advantages of dynamic melt rheology are discussed in relationship to conventional dynamic mechanical and DSC methods.
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  • 48
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    Polymer Engineering and Science 30 (1990), S. 1175-1179 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The time for brittle failure by slow crack growth for 22 polyethylene copolymers was measured in Igepal and air. The notched tensile tests were conducted in Igepal and air at 50°C and 4.2 MPa and in air at 80°C and 2.4 MPa. For failure times less than 103 min, the difference between the Igepal and air environments was not measurable. As the failure time increased beyond 103 min, the ratio of failure in air compared to that in Igepal increased so that for the very highest failure times of 5 × 105 to 108 min in air, the failure time in Igepal was reduced by 25 - 50 times. The correlation between the Igepal and air tests was generally good with respect to all types of polyethylene. However, a separation of the polyethylenes with respect to their comonomer, butene, hexene, or octene improved the correlation. The resistance to slow crack growth of all the current commercial polyethylene copolymers can be assessed by a notched tensile test in Igepal in about a week or less.
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  • 49
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    Polymer Engineering and Science 30 (1990), S. 1183-1183 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 50
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 51
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1200-1204 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study of melting a polymer pellet immersed in a hot silicone oil bath was conducted. The temperature rise at the center of the pellet was recorded. This experiment simulates the conduction melting mechanism of polymer solid pieces mixed in the hot melt inside an extruder screw channel. The pellets immersed in the silicone oil melted quite slowly, taking around one minute to melt a spherical pellet of about 4.5 mm diameter. The heating time could be greatly decreased by stirring the silicone oil to increase the heat transfer from the silicone oil to the pellet. Analysis of the conduction melting mechanism showed that the size reduction of the solid would be most effective in decreasing the heating time.
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  • 52
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1205-1208 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The extrusion of blown film polyethylene is a complex process characterized by a large number of interdependent process variables. In order to derive the set of process conditions necessary for a desired film solid state property, the processor normally utilizes a laborious trial-and-error method. In this work, a technique is described to establish more directly the set of extruder settings for producing film with an optimum value of a given property. Biaxial toughness was optimized in the present work, but the technique is applicable to any quantifiable film property.
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  • 53
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1185-1199 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The conventional sheet metal forming technique known as Deep Drawing was used to investigate the formability of self-reinforced thermoplastic sheets. The materials studied included uniaxially roll-drawn oriented polypropylene (OPP), cross-rolled biaxially oriented polypropylene (BOPP), and cross-ply laminated OPP (LOPP). OPP exhibits poor room temperature formability as determined by its Limiting Drawing Ratio (LDR). Its formability is improved at elevated temperatures, but samples suffer from non-uniform material flow, temperature sensitivity during forming, and a loss of mechanical properties due to the relaxation of orientation caused by the need for forming temperatures above the normal melting point. Although BOPP attains only moderate Improvements in mechanical properties compared to the machine direction of OPP, it exhibits much better room temperature formability. This difference in drawability between uniaxial and biaxial orientation states is a consequence of the difference in planar anisotropy between these two materials. LOPP has the potential of producing a material with superior performance compared to BOPP while still possessing the desirable formability of BOPP. The formed parts, however, undergo cracking in the outer ply parallel to the orientation direction as a consequence of the OPP small elongation to break in the transverse direction. In addition to forming problems, ordered polypropylene exhibits large shrinkage stresses at elevated temperatures. This may preclude its use in applications requiring a high level of dimensional stability. Classical plasticity theory for metals was appropriately modified to model the radial drawing stress for planar isotropic thermoplastic sheet materials.
    Additional Material: 23 Ill.
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  • 54
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    Polymer Engineering and Science 30 (1990), S. 1209-1219 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The theory of optimal control is used to analyze the performance of a batch PMMA (poly(methylmethacrylate)) polymerization reactor. Optimal dynamic profiles of temperature, initiator feed rate, and initiator concentration in the reactor are generated in order for specified conversion of monomer, number molecular weight, and polydispersity of the final product to be obtained. Based on tae physical limitations of the system, some restrictions are imposed to the control variable variations. The application of Pontryagin's Minimum Principle leads to a mixed initial/final value problem, which is solved by discretizing the control law in the state-space, with the usage of a first order holder. A gradient method is used to minimize the Hamiltonian. The simulation results show that the gel-effect equation and restrictions imposed on the system are of primary importance to the analysis of the reactor performance.
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  • 55
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    Polymer Engineering and Science 30 (1990), S. 1220-1227 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effects of cavity shapes, particularly the expansion and contraction angles, and the Theological properties of polymeric liquids on vortex formation in the cuter cavity of a dual-cavity coat-hanger die have been examined. For power-law fluids, a vortex may appear in the expansion side of the outer cavity, and the size of the vortex is influenced by the expansion angle, the power-law index, and the Reynolds number. Two viscoelastic fluids were used in the flow visualization experiment; for an aqueous polyacrylamide solution, a vortex may appear in the contraction side of the outer cavity and this vortex is influenced by the contraction angle and the fluid elasticity, but no vortex was observed for a Boger fluid.
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  • 56
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    Polymer Engineering and Science 30 (1990), S. 1228-1236 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A double bubble tubular film process to produce biaxially oriented poly(p-phenylene sulfide) (PPS) film is described. Operating windows were developed for stable operation of both the first and second bubbles. Films produced from single bubble tubular film extrusion were largely amorphous having only seven to nine percent crystallinity. Double bubble PPS tubular film had up to 20 percent crystallinity which was increased to 30 percent by further annealing. The first and second bubble films had surface roughness standard deviation heights of 0.01 to 0.04 μm. Orientation was characterized by birefringence and wide angle X-ray diffraction pole figures of the 110 and 112 reflections. Biaxial orientation factors were computed. The double bubble films had higher Young's modulus and tensile strength but lower elongation to break than the single bubble films. Annealing further increases Young's modulus and tensile strength but decreases elongation to break. Double bubble and annealed films with roughly equal second bubble drawdown ratio and second blow up ratio tend to have balanced properties in the plane of the film.
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  • 57
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    Polymer Engineering and Science 30 (1990), S. 1237-1251 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper presents an experimentally-based analysis of the continuous filament regime of the melt-blowing process. The experiments were performed with a versatile air-polymer die, several die operating temperatures, and three different polymer feed resins. The measurements discern the effects upon the final fiber diameter of the following input parameters: die dimensions, die temperature, polymer feed resin, and both the air and polymer mass flow rates. An empirical model equation is developed which relates these input parameters to the final fiber diameter. In addition, the conditions which result in a transition of the filament from continuous (or stable) to discontinuous (or unstable) are quantified. The model equation and the transition or stability information are then used to predict the behavior of the melt-blowing process for a wide range of case studies involving the input parameters noted above. The data and empirical model are of considerable utility for developing new die designs, for comparison with theoretical models, for predicting fiber stability, and for explaining the behavior of current industrial melt-blowing processes.
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  • 58
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    Polymer Engineering and Science 30 (1990), S. 1323-1329 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A novel process to produce microcellular thermoplastic parts is described. This is achieved by integrating the deformation process in the foaming cycle in such a way that the cell nucleation and growth processes are effectively uncoupled from deformation. The nitrogen-polystyrene system is studied and the relationships between the essential process parameters are established. It is experimentally shown that the pressures associated with deformation do not reduce the number of bubbles nucleated. The process synthesized is demonstrated by making a microcellular polystyrene container.
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  • 59
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 60
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    Polymer Engineering and Science 30 (1990), S. 1345-1345 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 61
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    Polymer Engineering and Science 30 (1990), S. 1341-1344 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In (1), Narisawa and Takemori examined the physical interpretations and some experimental techniques of the J-Integral (ASTM E813-81) as applied to toughened polymers. Their results and conclusions are reexamined and discussed in terms of recent developments in J testing.
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  • 62
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    Polymer Engineering and Science 30 (1990), S. 1330-1337 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The bubble size distribution created by the expanding foam plays a key role in controlling the load-bearing and other mechanical properties of the manufactured structural foam part. A numerical method to study the bubble growth and predict the bubble size distribution in polymeric foams is presented. On the microscopic scale, a cell model has been used. A cell is a system composed of a hypothetical spherical gas bubble and an envelope of polymer with constant mass surrounding the bubble. On the macroscopic scale, the foam has been modeled as a compressible medium consisting of a number of cells growing in close proximity to each other. The coupled system of the bubble growth equations for a cell and the field equations for the polymeric fluid are solved numerically to predict the spatial bubble size distribution and the flow front movement during the expansion process. The influence of different dimensionless parameters on the growth of spatially distributed bubbles and on the relative reduction in the transient bulk foam density, under isothermal condition; has been predicted. The existence of an axial pressure gradient in the mold due to the spatial variation of bubble growth is demonstrated through numerical experiments.
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  • 63
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    Polymer Engineering and Science 30 (1990), S. 1346-1351 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A negative deep UV resist, XP 8843 (Shipley Co.),Since this paper was written the name of this resist has been changed from XP 8843 to SNR 248-10. has been made positive by the addition of 1,2,4-triazole. This is achieved by exposing the resist in the presence of the additive thereby inhibiting the crosslinking reaction. After exposure the additive is removed by heating under a vacuum. Unexposed areas of the resist may then be exposed and the resist crosslinked under normal processing conditions.
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  • 64
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    Polymer Engineering and Science 30 (1990), S. 1352-1360 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An easy to use, spreadsheet based, mathematical model for drying of strand cut polymer pellets has been developed and experimentally verified. This particle-scale model is based on internal mass-transfer controlled diffusion in the pellet. Examples of its usage in correlation and prediction of the effects of the drying-gas temperature, humidity, and pellet dimensions are presented. Application of the particle-scale model to the design of a countercurrent hopper drier is discussed. Even though examples are limited to water removal from poly(bisphenol-A)carbonate pellets, the model is general and may be used for the removal of other non-solvating low-concentration molecules from polymers with isotropic morphology.
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  • 65
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    Polymer Engineering and Science 30 (1990), S. 1373-1381 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Monodisperse methyl methacrylate grafted latex rubber (MMA-g) particles (0.12-0.13 µm) have been used for the impact toughening of a series of styrene-acrylonitrile (SAN) copolymers of varied AN content. It was found that the MMA-g particles are most effective in toughening SANs containing about 25 to 34% AN. Mechanical properties, interphase adhesion, mechanical dilatometry, and phase morphology by transmission electron microscopy were determined on blends containing 20-30% rubber. Also, the miscibility range of SANs and poly(methyl methacrylate) (PMMA) graft was considered in attempting to analyze the relationships between the mechanical properties and the characteristic features of the blends. Issues relating the impact strength and deformation mechanisms, interphase adhesion, and particle morphology are discussed. It appears that the high impact strength of some of the blends may be caused primarily by certain morphological features such as particle clustering or small interparticle distances. Thus, craze initiation, shear yielding, and significant matrix deformation may all contribute to the overall ductility of the blend.
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  • 66
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    Polymer Engineering and Science 30 (1990), S. 1382-1398 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow pattern within a partially intermeshing co-rotating twin-screw extruder is three dimensional and extremely complex. In order to simplify the problem, a slice perpendicular to the axis of the twin-screw extruder has been considered for flow analysis as a two-dimensional or a quasi-three-dimensional problem. The flow in this slice may be considered to consist of a nip region (located between the two screws) and a translation region in which the movement of the material is very similar to the one found in single-screw extruders. The flow in these two regions have been studied separately. This paper presents the numerical and experimental results of the nip region study. The flow division in the nip region has been quantified and results are presented in terms of a flow division ratio Xf. The flow field patterns have also been obtained. Newtonian as well as non-Newtonian behavior has been investigated. The influences of such factors as (i) the geometry (the radius of the barrel, radius of the screw, distance between the two screws), (ii) the material properties (the power-law index for shear rate dependent viscosity), and (iii) processing conditions (the screw speed), have also been studied.
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  • 67
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    Polymer Engineering and Science 30 (1990), S. 1399-1406 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Crack healing in poly(methyl methacrylate) (PMMA) by methanol treatment at 40°C-60°C has been investigated. It is found that the methanol treatment reduces the glass transition temperature in PMMA. Crack healing only occurs at an operating temperature higher than the effective glass transition temperature. There are two distinctive stages for crack healing based on the recovery of mechanical strength. The first stage corresponds to the progressive healing due to wetting, which has a constant crack closure rate at a given temperature. Immediately following the first stage, the second stage corresponding to diffusion enhances the quality of healing behavior. The surface morphologies obtained during healing and after fracture tests confirm these two stages. By comparing the fracture stress with the fractography, the fracture surface for stage I of crack healing is coplanar to the original crack surface. On the other hand, the original crack surface is destroyed in stage II of crack healing. It occurs in the region incorporating the original healed surface and appears to be like the Virgin fracture surface. It is also found that the tensile fracture stress of PMMA treated by methanol can recover to that of the virgin material. In addition, it is interesting to find that after sustained methanol treatment, the “snake bone” phenomenon on the fracture surface emerges.
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  • 68
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    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 69
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    Polymer Engineering and Science 30 (1990), S. 1407-1412 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This is a study on the rheological properties and packing efficiency of a fluid suspension, composed of a mixture of two dissimilar particulate species. A generalized analytic expression for the viscosity of the blend is first developed, and then utilized to derive quantitative ways of maximizing the fluidity and optimizing the filling capacity of the composite system. These, results are compared with earlier experimental and theoretical findings, and with the rheological measurements performed in the course of this work on a series of calcium carbonate-carbon black suspensions in poly-dimethylsiloxane.
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  • 70
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    Polymer Engineering and Science 30 (1990), S. 1413-1419 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polypropylene melt blown webs have been studied in terms of the relationships among the processing conditions, structure, and filtration efficiency. The effects of the processing conditions on filtration efficiency to aerosolized latex particles, pore size, fiber diameter, and air permeability have been investigated. The melt blowing process conditions investigated in this study were die and air temperatures, die-to-collector distance, and attenuation air flow rate at the die. The filtration efficiency has been found to increase linearly as mean pore size decreased. The degree of fiber-entanglement increased, therefore, the pore size and air permeability decreased with increasing processing temperature, increasing air flow rate at the die, or decreasing die-to-collector distance. Average fiber diameter appeared to change little with die-to-collector distance, but decreased with increasing die temperature or with increasing air flow rate.
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  • 71
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    Polymer Engineering and Science 30 (1990), S. 1420-1430 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: ‘Enriched’ element, Q1+Po, and ‘standard’ element, Q1Po, are compared for the simulation of 3-dimensional flow of non-Newtonian fluids. Several 3-dimensional polymer flow problems are analyzed. The pressure field obtained by using Q1Po elements suffers from spurious pressure modes. For complex flows, depending upon the flow geometry and the boundary conditions used, Q1+Po elements may fall to simulate even the velocity field. Q1Po elements, which satisfy the Babuska-Brezzi condition, give accurate velocity and pressure distributions for all the problems analyzed here.
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  • 72
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    Polymer Engineering and Science 30 (1990), S. 1431-1441 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Igepal assisted environmental stress cracking (ESC) of LDPE has shown three characteristic regions with increasing crack driving force: Region I-crack speed and craze length increased. Region II-crack speed and duplex plastic zone length were constant, and Region Ill-crack speed decreased while the deformation zone length increased. The activation energies for the three regions were 100, 23, 20 kJ/mole, respectively. The proposed rate controlling processes of ESC for the LDPE/Igepal system are: Region 1 is controlled by a;-relaxation, and Region II and III are controlled by lamellar orientation. The Igepal plasticizes the amorphous phase and facilitates the stress induced orientation of the lamellar.
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  • 73
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    Polymer Engineering and Science 30 (1990), S. 1442-1453 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Three different polymer blends consisting of an isotropic matrix and a ther-motropic liquid crystalline polymer (LCP) as the reinforcement were extruded. Polycarbonate (PC) and polyetherimide (PEI) were the two matrices, and the LCPs used were Vectraw A950 of Hoechst-Celanese, a copolyester of hydroxybenzoic and 2,6 hydroxynaphthoic acids and an LCP of Granmont Inc., a condensation polymer of terephthalic acid, (l-phenylethyl)hydroquinone, and phenylhydroqui-none. These extrudates were characterized by a quantitative morphological technique to determine the percentage of LCP present as fibrils and the average domain diameter. These experimental observations were then coupled with the component Theological behavior and a simple heat transfer analysis to explain the morphology and property differences between the blends. Blends with the Granmont LCP showed no appreciable increase In the quantity of fibrils with draw ratio, for example, whereas the amount of fibrils in Vectra® blends tended to increase to a plateau with draw. The tensile modulus of the blends agreed well with composite theory, with average fibril moduli of 24.6 GPa and 23,3 GPa for Vectra® and the Granmont LCP, respectively. These differences can be explained in terms of the cooling behavior of the LCPs.
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  • 74
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The characterization of network segment density of elastomers is discussed. Normally equilibrium solvent swelling is used as long as the polymer-solvent interaction parameter χ is available. However, χ is often not known or may be a function of the network segment density, or composition for a polymer whose structure is changed upon aging. The technique of measuring the modulus in tension or compression on solvent-swollen samples allows the network segment density to be calculated from the theory of rubber elasticity. This circumvents the problems associated with the solvent swelling technique. The modification of a commercially available thermomechanical analyzer is described, to enable compression modulus measurements on solvent swollen elastomers to be performed.
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  • 75
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    Polymer Engineering and Science 30 (1990), S. 1595-1598 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Oven aged tensile bars of heat stabilized, glass reinforced nylon 66 material were studied by Fourier transform infrared (FTIR) spectroscopy using a photoacoustic detector. Flat weighed scrapings were removed from tensile bars whose tensile strength, elongation, impact, molecular weight, and thermal properties had previously been measured. Using the amide I band of nylon 66 as an internal standard, the thermal oxidation of nylon was followed using a commercially available photoacoustic detector. The infrared absorbance spectra demonstrate the formation of carbonyl stretching vibrations due to the thermal oxidation of nylon with a band center at 1713 cm-1 whose width at half height is 40 cm-1. The difference infrared spectra support reaction mechanisms dealing with an Initial increase in the degree of polymerization followed by transamidation reactions with subsequent formation of an α, β unsaturated carbonyl species and chain scissioning. By using data related to the percent retention of certain physical properties which had also been measured on these tensile bars, subtractive infrared spectroscopy yielded additional fundamental information regarding nylon 66 degradation. Consequently, nylon products being used in underhood automotive applications are currently being investigated for thermal oxidative degradation using this rapid and relatively non-destructive photoacoustic FTIR technique for durability considerations.
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    Polymer Engineering and Science 30 (1990), S. 1615-1619 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A crystallization rate coefficient (CRC) parameter is introduced which has allowed a direct comparison of the crystallization rates of various polymers on a single scale for the first time. Basically, CRC represents a change in cooling rate required to bring about 1°C change in the supercooling of the polymer melt. For the polymers studied, this value varies between 35 h-1 (polyethylene terephthalate) and 155 h-1 (poly(tetrafluoroethylene)) and jumps to 295 h-1 for indium metal; the precision being better than ±5 percent. The reliability of CRC has been tested against the established trends e.g., (i) a large decrease in the crystallization rate of polyethylene terephthalate with increase in molecular weight, (ii) a lower crystallization rate of the “virgin” nylon 6 as compared to the processed nylon 6 resin, (iii) an increase in the crystallization rate of nylon 6 in the presence of nucleating agents, and (iv) a dramatic increase in crystallization rate as we go from poly(ethylene terephthalate) to poly(tetrafluoroethylene) and then from poly(tetrafluoroethylene) to the metals. The significance of the CRC barometer is discussed in the light of prior difficulties in directly comparing the crystallization rates of polymers.
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  • 77
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1628-1632 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this paper it is shown that a core-shell impact modifier which is predispersed in one phase of a complex blend may migrate to another phase during melt compounding. The migration process appears to be driven by differences in the spreading behavior of the individual blend components. The details of the migration are analyzed by electron microscopy studies of partially compounded samples which were quenched, extracted, and separated from the extruder screw.
    Additional Material: 7 Ill.
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  • 78
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1620-1627 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The microstructure and fracture behavior of Injection molded samples of unfilled and filled grades of liquid crystalline polymers (Vectra® and Ultrax®) containing cold and warm knit lines have been studied by scanning electron microscopy, X-ray scattering, and Instron tensile tests. Four process parameters - melt temperature, mold temperature, injection time, and holding pressure - have been varied in accordance with a 24 factorial design experiment. In cold knit lines a 200 µm thick region with transverse orientation with Hermans orientation function f ≈ 0.12-0.18 is formed on both sides on the weld area. The strength of the cold knit lines is very low, 9.0-19.8 MPa corresponding to 15-20% of the full strength of the material. The strength of the warm knit lines increases markedly with increasing distance from the insert and is generally significantly greater (40-45 MPa, 48 mm from the insert) than in the cold welds. Annealing at 260-300°C of samples containing cold knit lines causes first a partial healing of the knit line and later extensive chemical degradation of the polymer.
    Additional Material: 14 Ill.
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  • 79
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 13-21 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A thermotropic liquid crystalline polyester (LCP) with a long flexible spacer group in the main chain was prepared by melt polymerization and mixed with poly(ethylene terephthalate) (PET). Differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) studies revealed that the crystallization of PET was accelerated by the addition of LCP in the matrix. Interfacial adhesion between PET and LCP was much improved by introduction of a long flexible spacer in the main chain. Fibers of the blend with 30 wt percent of LCP had fine microfibrillar structure with a large aspect ratio formed in the matrix. Initial modulus and ultimate strength were highly elevated by the addition of LCP due to good interfacial adhesion and microfibrillar structure of LCP in the blend.
    Additional Material: 12 Ill.
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  • 80
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 81
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Tensile, cyclic, and tear properties were compared for several styrene-butadiene-styrene (SBS) triblock copolymers, KRATON D2104, D1101 and D1102, and blends of D2104 with monodisperse polystyrene of various molecular weights. D2104 is expected to have a morphology of polystyrene spheres in a polybutadiene continuous matrix. The mechanical properties of D2104 were compared to the properties of SBS materials which have higher styrene contents and exhibit cylindrical or lamellar morphologies. Blending the D2104 with polystyrene (molecular weights ranging from 2000 to 51,000) to 24 and 28 wt % total styrene content showed that the tensile strength obtained for a blend was dependent on the molecular weight of the polystyrene added. Cycle testing of the D2104-polystyrene blends showed that with increasing polystyrene content the softening effect increases with increasing strain. This indicates that the degree of phase continuity of the polystyrene domains may be changing from a spherical morphology to a cylindrical morphology similar to that of pure SBS with 28 wt % styrene content. Tear test results for the blends were also observed to be similar to the results for pure SBS of the same total polystyrene content.
    Additional Material: 11 Ill.
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  • 82
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 90-95 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Rapid freezing of a polymethylpentene (PMP)/cyclohexane solution to -80°C gives a tough, flexible foam, in marked contrast to the weak, friable foams obtained by phase-separation of PMP from other solvents. X-ray diffraction and differential scanning calorimetry (DSC) data indicate that the isotactic PMP is in an amorphous state. The production of a flexible, robust foam tube from PMP/cyclohexane implies that this material could find applications as replacement parts for arteries and veins or as filter devices. In sheet form, this material seems ideally suited for use as light-weight insulation for clothing because its open, microcellular structure permits moisture to escape as vapors, but retards air flow. This study demonstrates that process parameters, such as solvent composition, play an important role in determining the various microstructures and physical properties that can be obtained from a single polymer.
    Additional Material: 9 Ill.
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  • 83
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 84
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 142-146 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Some design strategies for structural reaction injection molding (S-RIM) and resin transfer molding (RTM) are presented. Our approach makes use of moldability diagrams to define the parameters necessary to meet the process requirements. Moldability diagrams are presented for the filling and curing steps. The criterion for selecting the amount of fiber reinforcement, injection time, catalyst level, and process temperatures in order to optimize properties and demold time is described.
    Additional Material: 6 Ill.
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  • 85
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 263-269 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dispersion of variously surface-treated CaCo3 fillers in linear low density polyethylene has been studied, along with mechanical properties of the filled compounds. Microwave plasma discharges were used to modify the filler surfaces. Inverse gas chromatographic analyses showed that plasma treatments could change the dispersive and non-dispersive components of filler surface characteristics. A reduction in these surface energies facilitated the dispersion of the filler in the non-polar polyethylene. Mechanical properties, particularly those at high deformation of the filled plastic, also responded to filler surface treatments, the ductility at failure increasing with a decrease in the filler's surface polarity. For any given elongation at failure, it was found that the amount of filler accommodated by the host polymer was raised by the appropriate surface modification procedure. The work illustrates the important contribution made by interfacial phenomena to various performance aspects of complex polymer systems.
    Additional Material: 8 Ill.
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  • 86
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    Polymer Engineering and Science 30 (1990), S. 303-307 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The tensile properties: Young's modulus, ultimate tensile strength, ultimate elongation, the glass transition temperature, and the dynamic mechanical properties (dynamic shear modulus (G'), loss tangent (Tan δ)), of three epoxy resins (Epon 828, Epon 836, Epon HPT 1071) cured with the disulfide-containing crosslinking agent - 4.4-dithiodianilme (DTDA) have been characterized. The results show that DTDA is a satisfactory crosslinking agent for the epoxide resins that have been studied as compared to the well-known curing agent methylene dianiline (MDA). There are no significant differences between the properties of Epon 828 cured with DTDA at stoichiometric ratio (2:1) and Epon 828 cured with DTDA at small amine excess ratio (1.75:1). The glass transition temperature of the cured tetrafunctional epoxy resin Epon HPT 1971 (235°C) is significantly higher than that of difunctional epoxy resins such as Epon 828 (Tg-175°C), but the product is too brittle to be used without plasticizer.
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  • 87
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 88
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 291-302 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Based on previous works, a simple model is built to simulate the vinyl chloride monomer (VCM) polymerization in continuous suspension and bulk reactors. The branches of steady-state solutions are computed and their dynamic behavior is analyzed. It is observed that these systems present multiple steady-state solutions for some ranges of parameter values and that non-adiabatic reactors can also present ISOLAs. These reactors can also experience self-sustained oscillations in a very wide region of operation conditions.
    Additional Material: 24 Ill.
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  • 89
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    Polymer Engineering and Science 30 (1990), S. 321-325 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: DGEBA-DDM (diglycicyl ether of bisphenol-A-diamino diphenyl methane) networks of various epoxide/amine molar ratios ranging from 0.7 to 1.4, were studied by density, quasi static (10-4 s-1), and ultrasonic (5 106 s-1) modulus, and thermostimulated creep measurements. Any step aside stoichiometry leads to an antiplasticization, e.g. an increase of the quasi static modulus, whereas Tg decreases. The previous interpretations (based on volumetric property considerations), of this phenomenon are questionable. The only common feature of all the antiplasticized systems is an unexplained decrease of the population of macro-molecular segments involved in beta motions.
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  • 90
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    Polymer Engineering and Science 30 (1990), S. 314-320 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dynamic-mechanical and dielectric characterization of the cold crystallization of PEEK has been performed in order to develop a non-destructive evaluation method of crystallinity in thermoplastic matrices. The Avrami approach is applied here to describe the Poly(ether ether ketone) (PEEK) crystallization kinetics after an appropriate reduction of dynamic-mechanical and dielectric parameters. Avrami exponents obtained from dielectric characterization are comparable with those obtained with DSC measurements reported in literature, while the exponents obtained from the dynamic-mechanical characterization are higher, reflecting also changes in the aspect ratio of the growing crystals. Variations in the glass transition temperature detected during cold crystallization are analyzed and analogies between PEEK and PET are discussed.
    Additional Material: 9 Ill.
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  • 91
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 424-430 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A theoretical analysis of the diffusion-controlled, essentially bubble-free, mass transfer regime of polymer solution devolatilization has been performed for a counterrotating, nonintermeshing twin-screw extruder (1). The commonly used penetration diffusion approach is applied specifically to this geometry. Mass transfer from the recirculating pool and barrel film in the closed channel and the pool only in the open channel is taken into account. Use is made in this study of the recently determined pumping characteristics of this geometry (2), which allow the estimation of the length of the extraction section. Mass transfer rate measurements have been taken on a 20-mm extruder using the model system polystyrene/ethylbenzene. The agreement between the mass transfer calculations and the experimental results is very good.
    Additional Material: 6 Ill.
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  • 92
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    Polymer Engineering and Science 30 (1990), S. 431-435 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Isothermal aging after a quench from above the glass-transition temperature (Tg) to below it was studied as a function of cross-link density for model epoxy networks using small deformation stress relaxation experiments. We found that time-aging time and time-cross-link density superposition principles described the changes observed in the Viscoelastic behavior of the epoxy networks. The aging response in the nonlinear Viscoelastic regime was also studied using creep experiments for one of the networks. It was found that upon aging near to the conventional glass-transition temperature, the time required for the glass to age into structural equilibrium was independent of the magnitude of the applied stress. This result suggests that large stresses do not erase physical aging (or cause rejuvenation of the glasses).
    Additional Material: 6 Ill.
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  • 93
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    Polymer Engineering and Science 30 (1990), S. 553-565 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends of polyethylene (PE) and polyamide (PA) were prepared by a melt mixing process. The dependence of the number average size An of the dispersed phase on hydrodynamic conditions not only of shear rate but also temperature, inter-facial tension, viscosity of the blends (WU's treatment), and dispersed phase concentration were studied. The analysis of PE-PA blend morphology shows An to be the result of a balance between coalescence and disruption of the particles in the melt, and to display a strong increase in particle size when the minor component concentration is enhanced. These observations can be explained by a change in the rheology of the system. These assumptions are confirmed by the insertion in the blend of an ethylenemaleic anhydride (EMA) copolymer that yields EMA-g-PA graft copolymer during mechanical processing. Formation of this graft copolymer has been indicated by a strong particle size reduction and its concentration was measured by infrared experiments. The EMA-g-PA copolymer seems to decrease the blend interfacial tension and to deter the coalescence process.
    Additional Material: 15 Ill.
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  • 94
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    Polymer Engineering and Science 30 (1990), S. 665-676 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The performance of plasticating single-screw extruders is analyzed by combining three functional sections: (a) solids-conveying section, (b) melting section, and (c) melt-conveying section. In the analysis of the melting section, we have incorporated a new concept of solid-bed deformation (i.e., the rheology of the solid bed) into Lindt-Elbirli's analysis and included convective heat transfer in the energy equation. Specifically, we have computed stresses on the surfaces of the solid bed, which is surrounded by thin melt films and a melt pool, and, also, computed the apparent modulus of the solid bed in the bulk state as a function of temperature and position within the solid bed, along the extruder axis. From this information, we were able to compute the extent of solid-bed deformation, by assuming a linear stress-strain relationship as the constitutive equation of the solid bed. In this approach, we do not assume a priori whether the solid bed is rigid or freely deformable. The solution of the system equations gives us the following information: (a) whether or not the solid bed deforms and if it does, then, how much; (b) the solid-bed velocity along the extruder axis; (c) pressure profiles along the extruder axis; (d) solid-bed profiles in the melting zone along the extruder axis; (e) temperature profiles along the extruder axis; (f) velocity and temperature distributions in the melt pool along the extruder axis; and (g) thicknesses of thin melt films surrounding the solid bed. Theoretically predicted solid bed and pressure profiles along the extruder axis are compared with experimental results reported in the literature. We have pointed out an urgent need for measurements of the apparent modulus of the solid bed in the bulk state as a function of temperature and pressure, under a combined shear/drag flow field.
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  • 95
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    Polymer Engineering and Science 30 (1990), S. 734-740 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The behavior of epoxy mortar was studied under various curing conditions, temperature and strain rate. The effect of aggregate size and distribution on the mechanical properties of epoxy mortar was also studied. Epoxy mortar with a uniform fine sand was cured at various temperatures to determine the optimum curing condition. The strain rate was varied between 0.01 to 6 percent strain per minute and the testing temperature between 22°C and 80°C. The strength, modulus, and compressive strain-strain relationship of polymer mortar are influenced by the curing method, testing temperature, and strain rate to varying degrees. The influence of test variables on the mechanical properties of epoxy mortar are quantified. Compared to the uniformly graded fine aggregate fillers the gap-graded aggregates produced polymer mortar with better mechanical properties. The compressive modulus and splitting tensile strength of epoxy mortar are related to their compressive strength. A new nonlinear constitutive model is proposed to predict the complete compressive stress-strain behavior of epoxy mortar. The constitutive relationship parameters are also related to the testing temperature and logarithmic strain rate.
    Additional Material: 12 Ill.
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  • 96
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In theories of the minor phase (domain) formation in polyblends rendered as emulsions it is usually assumed that the size and shape of the domains are the result of melt viscosity effects (Taylor, Wu) or viscoelasticity effects (VanOene, Elmendorp) being balanced by interfacial tension. This assumption would predict a monotonic decrease of the domain size to a final limiting size with increasing energy of mixing. However, a systematic study of the dependence of domain morphology on industrial mixing processes which was carried out on a “model” LDPE/PS (2/1) mixture and the related polyalloy (i.e., the same mixture with a corresponding block copolymer as compatibilizer) does not support this expectation. Doirain size was found to go through a minimum as mixing energy was increased. A similar minimum was seen in data on specific volume of the melt vs. mixing energy, which indicates a correlation between melt specific volume and domain size. Calculation of the approximate surface area of the domains using a simple model of domain shape indicated that total interfacial energy in the polyblend and/or polyalloy is a trivial part of the mixing energy introduced. These calculations also indicated that if compatibilizer was located entirely at the interface, the surface layer would have a thickness of about 90 nm. Some micrographs seem to show such a surface layer. We propose that an abrasion mechanism is responsible for the early stage of the dispersion process, and that the final domain size may be controlled by a dispersion-coalescence equilibrium. This is compared with the theories of final particle size proposed by VanOene and Wu.
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  • 97
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 98
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of viscous dissipation on solidification onto the inner surface of a straight circular tube of a liquid flowing laminarly with a specified volumetric rate is analytically determined. Steady conditions and a constant tube wall temperature below the solidification temperature of the liquid are assumed. Solutions for the thickness of the solidified shell and for the pressure drop are obtained. The pressure gradient versus volumetric flow rate curve exhibits a minimum, suggesting that it might be possible to design runners for injection molding machines to have a minimum pressure drop if the volumetric flow rate is specified.
    Additional Material: 4 Ill.
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  • 99
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 813-820 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The birefringence distributions in injection-molded Compact Discs (CD) are determined in radial and tangential cross-sections and interpreted in terms of the process. The influence of processing conditions is discussed in several examples. It is shown that despite the high birefringence level the retardation of a beam of normal incidence is almost zero due to several compensation mechanisms. One optical axis is almost perpendicular to the surface. The medium, however, is biaxial with the preferential directions depending on the distance from the surface and the radial position. In contrast to a parallel beam, zero retardation cannot be achieved with a convergent beam in injection-molded polycarbonate disks for that reason.
    Additional Material: 8 Ill.
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  • 100
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dimensional stability of sample cylinders cured with sheet molding compound pastes was investigated. A significant amount of dimensional change was found for these samples when they were annealed. Furthermore, the amount of change varied with location from the center to the wall along the radial direction of the sample cylinder to form a strain gradient. A series of experiments were then carried out to determine property gradients along the same direction in search of the source of the dimensional instability. It was found that the sample also had a gradient in cure and a gradient in dynamic mechanical properties. But these gradients are not in full agreement. In particular, the gradient of cure appears to be opposite to the direction of the strain gradient, while the gradient of the dynamic mechanical properties coincides with it. These results, therefore, suggest that the dimensional stability may be predominantly governed by the viscoelastic behavior of the material.
    Additional Material: 8 Ill.
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