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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 83-87 (Jan. 1992), p. 1439-1444 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    BBA Section Nucleic Acids And Protein Synthesis 655 (1981), S. 335-341 
    ISSN: 0005-2787
    Keywords: Antibiotic structure ; Blasticidin S hydrochloride pentahydrate ; X-ray crystallography
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 1772-1774 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The electrical and photoluminescent properties of vanadium incorporated into GaAs epitaxial layers from a VO(OC2H5)3 source during organometallic vapor phase epitaxy were examined. The vanadium concentration in the GaAs was controllably varied from 1016 to 1018 atoms cm−3. Deep level transient spectroscopy showed the presence of an electron trap at Ec−0.15 eV which increased in concentration with vanadium content of the epitaxial layers. A maximum value of 8×1015 cm−3 for this trap was obtained. There were no midgap electron traps associated with vanadium. In intentionally Si-doped epitaxial layers, co-doping with vanadium was observed to have no effect in reducing the carrier density when the Si concentration was ≥4×1016 cm−3. The net carrier concentration profiles resulting from 29Si implantation into GaAs containing 1018 cm−3 of total V had sharper tails than for similar implantation into undoped material, indicating the presence of less than 1016 cm−3 V-related acceptors. Photoluminescent spectra exhibited the characteristic V+3 intracenter emission at 0.65–0.75 eV. No other deep level photoluminescence was detected. For a V concentration of 1016 cm−3 only 2.5×1013 cm−3 was electrically active. Over the entire V concentration investigated this impurity was predominantly (≥99%) inactive.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 4648-4654 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have investigated Be diffusion during molecular beam epitaxial growth of GaAs/AlGaAs graded index separate confinement heterostructure laser structures using secondary ion mass spectrometry (SIMS). For growth at 700 °C we find that Be from the p-type AlGaAs cladding layer diffuses into the quantum well and beyond. As a result, the p-n junction is displaced from the heterojunction. The extent of Be diffusion is found to depend on the dopants in the graded index (GRIN) regions adjoining the GaAs active layer. When the GRIN segments are left intentionally undoped, Be diffuses through the entire p-side GRIN, the quantum well active and a significant portion of the n-side GRIN. However, when the GRIN regions are doped, respectively, with Be and Si on the p and n sides, the displacement of the p-n junction caused by Be diffusion is significantly reduced. Assuming that Be diffuses from a constant source at the surface into a n-type layer as a singly charged interstitial donor, our analysis predicts that increasing the doping of the n layer retards the diffusion of Be while that of the p layer enhances it. Further, including the electric field of the p-n junction in the model leads to peaks and inflections resembling those observed in the experimental SIMS profiles. In view of Be-related oxygen contamination and Be diffusion on the p-side GRIN region, Be should be dispensed with on the p side, however, Si addition on the n side is beneficial as it minimizes Be diffusion and p-n junction displacement.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of hydrogenation on the low-temperature (5 K) photoluminescence properties of GaAs grown on InP substrate by metalorganic chemical vapor deposition are investigated. An emission band at ∼1.4 eV originating from the GaAs/InP interfacial region shows a 30-fold increase in intensity relative to the GaAs band-edge emission after exposure to hydrogen plasma for 30 min at 250 °C. This improvement in intensity is attributed to hydrogen passivation of defects at the heterointerface caused by the large (≈4%) lattice mismatch between GaAs and InP. Annealing the hydrogenated sample at 350 °C nullifies the passivation effect. Further, the 1.4-eV band shifts to higher energy on annealing the sample in the temperature range 150–450 °C with the hydrogenated sample exhibiting a larger shift than the untreated sample. It is suggested that the annealing-induced peak shift arises due to modification of the interface and that it is greater in the hydrogenated sample compared to the untreated sample.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 4116-4118 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We measured the forward current-voltage characteristics of self-electro-optic effect devices (SEED). These devices consist of p-i-n diodes where the i region is a GaAs/AlxGa1−xAs (x∼0.3) multiple-quantum-well structure. It is found that the diode current varies as exp(qV/2 kT) and that it also scales with the junction perimeter for diodes of different mesa sizes, indicating nonradiative surface recombination at the mesa sidewalls. We also measured minority-carrier lifetimes from photoluminescence decay experiments. They revealed that the recombination rate increases with decreasing mesa size, once again indicating that surface recombination at the mesa sidewalls limits carrier lifetime. A value of 6×105 cm s−1 for the surface recombination velocity for the sidewalls is determined. The implication of the nonradiative surface recombination at the mesa sidewalls is that it undermines the performance of the SEED as the mesa size decreases by reducing the photocurrent, thereby leading to higher bistability voltage threshold and hence higher switching energy.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 1993-1996 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The problem of hydrogenation of InP without surface degradation has been surmounted by exposure of the InP surface to a hydrogen plasma through a thin SiNx(H) cap layer. This layer is H permeable at the hydrogenation temperature of 250 °C, but P or PH3 impermeable thus minimizing PH3 loss and the attendant In droplet formation. In contrast to our results for this type of plasma exposure of GaAs, we find that shallow acceptors in InP are heavily passivated, whereas shallow donors are only very weakly affected. For example, p+-InP(Zn) of 3×1018 cm−3 has its residual hole concentration reduced to ≤3×1014 cm−3 over a depth of 1.3 μm by a 250 °C, 0.5 h deuteration. The presence of acceptors impedes H (or D) indiffusion, as indicated by D diffusion under the same conditions occurring to depths of 18 and 35 μm in p-InP (Zn, 2×1016 cm−3) and n-InP (S or Sn), respectively. Annealing for 1 min at 350 °C causes the acceptor passivation to be lost and the hole concentration to be returned to its prehydrogenation level, indicating that the passivation has similar thermal stability to that of acceptors in GaAs, but lower than that of donors.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 1849-1854 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report the results of the measurement of radius of curvature of 1.3 and 1.5 μm wavelength GaInAsP-InP channeled substrate buried heterostructure lasers. The objective of this investigation is to quantify the macroscopic stress present in the device and correlate it with device reliability. The change in dc threshold current (ΔIth) after an accelerated aging test was used as a measure to access device reliability, with high ΔIth indicating decreased reliability. Changes were made in the p-side metallization to bring about a change in either ΔIth or radius of curvature and they included two different contact widths and different thicknesses of the Au bonding pad. It is observed that no correlation between device curvature and ΔIth exists even though the modifications in the p metallization caused significant changes in both quantities. It is suggested that it is not the macroscopic device stress that is measured by the radius of curvature but localized stresses that may exist in the vicinity of the lasing active layer which would affect device reliability. It is surmised that the most important role of stress is its effect on the direction of defect migration with the principal driving force coming from the nonradiative electron-hole recombination occurring in the vicinity of the active layer.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 2164-2167 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We investigated the near-band-edge photoluminescence from semi-insulating GaAs crystals after they were annealed either in the wafer form or in the bulk form. Our results, with respect to the uniformity achieved after annealing, are in agreement with previous studies. The 1.360-eV emission band which is seen in annealed crystals and which has been taken to imply a VAs related rapid diffusion process as the mechanism responsible for the annealing-induced uniformity, is shown not to be connected with it. We also cite evidence which questions the involvement of VAs in the band. From data in the literature we estimate the diffusion coefficient of VAs and find it to be too low to bring about bulk equilibrium and uniformity via vacancy diffusion from the surface at the annealing temperatures. We conclude that the local rearrangement of defects is a viable mechanism for producing uniformity during post-growth annealing.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 372-375 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The photoluminescence characteristics of a 1.3-μm undoped n-type InGaAsP grown lattice matched by liquid-phase epitaxy in the V grooves of a channeled InP substrate are compared with that grown over a planar substrate. In the 5.5 K photoluminescence spectrum, for both types of growth the epitaxial layer exhibits two well-defined and sharp (FWHM∼7–8 meV) bands at 1.016 and 0.99 eV. Both peaks are assigned to band-edge luminescence arising from two different compositions in the epilayer, the 0.99-eV peak arising solely from a transient growth region present near the substrate–epi interface. It is found that the transient growth region can be enhanced in the V channels perhaps due to additional perturbations due to growth on nonplanar substrates.
    Type of Medium: Electronic Resource
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