ZIB

101

Electronic Resource

Semiempirical approach to the problem of the radiative lifetime of the excited F-color center (1969)

Berezin, A. A.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 485-487

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: It is emphasized that for the theoretical consideration of many problems of defect centers in crystals (especially of problems which need the correct asymptotic behavior of the wave functions) the semiempirical approach can be effective. As an example the spontaneous radiative time decay of the excited F-center in alkali halides is calculated by using the experimental energies of absorption and emission bands.

Additional Material: 1 Tab.

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URL: http://dx.doi.org/10.1002/qua.560030406

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102

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The calculation of matrix elements for valence bond functionsThis work has been supported in part by grants from the National Science Foundation and the AF Office of Scientific Research to Indiana University. (1969)

Shull, Harrison

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 523-534

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Pauling's formulas for the calculation of matrix elements for valence bond functions are derived using a simple substitutional process. The results generalize and simplify the formulas. In particular, the formulas do not depend upon orthogonality of atomic orbitals nor upon the nature of the choice of bond structures (canonical or not). The results are particularly adaptable to automatic computation.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030411

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103

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Théorie quantique du pouvoir rotatoire magnétique des molécules diamagnétiques. II. Applications (1969)

Smet, P.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 593-610

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The general formalism of the variational theory of the Faraday effect established in the first part of this paper is now applied to the actual computation of the Verdet constant of the hydrogen molecule, of water and of some saturated hydrocarbons. The numerical results have a correct order of magnitude and even, for hydrogen, are rather close to the experimental value.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030507

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104

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Expansion of r12 and r12-1 in terms of analytical functionsWork was performed at the Ames Laboratory of the U.S. Atomic Energy Commission. Contribution No. 1932. (1969)

Cressy, Norman ; Ruedenberg, Klaus

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 493-501

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Expansions in terms of the spherical coordinates of two particles are given for the interparticle distance and its inverse. The expansions are characterized in that each term is a product of analytical one-variable functions. While it is possible to find acceptable expansions for r12, those obtained for r12-1 exhibit extremely slow convergence, unacceptable for practical use. The same objections must be raised against related expansions of multi-centered molecular integrals.

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030408

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105

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Masthead (1969)

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969)

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030501

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106

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Bounds for eigenfunctions of one-electron molecular systemsThis work has been supported in part by the NATO Research Grants Program under the number SA5-2-05(170)1757PS and in part by the Aerospace Research Laboratories, Office of Aerospace Research, United States Air Force, Contract numbers AS-7-283 and AS-8-0001. (1969)

Bazley, Norman W. ; Fox, David W.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 581-586

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: This article gives pointwise bounds for the wave functions of one-electron molecular systems.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030505

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107

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Wellenmechanische absolutrechnung am HeHHe+ (1969)

Swanstrøm, P. ; Janoschek, R. ; Preuss, H.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 115-121

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The wave function of the HeHHe+ molecule has been calculated by means of the GENERAL SCF-MO-LC(LCGO) PROGRAM SYSTEM, taking all four electrons into account. The calculations were carried out for a number of linear equidistant, linear non-equidistant, and bent nuclear arrangements. The minimum energy of -5.7930 a.u. was found for a linear equidistant configuration with a He—H distance of 0.939 Å. The corresponding ionization energy was 37.9 eV. An estimation of the energy of formation of HeHHe+ from HeH+ and He based on SCF-calculations on HeH+ and He gave 7.9 kcal/mole. The frequencies of the normal vibrations were calculated.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030115

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108

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Announcments (1969)

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 145-145

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030119

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109

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On the least squares procedure for atomic calculations (1969)

Lloyd, M. H. ; Delves, L. M.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 169-184

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: We discuss the properties of one version of the least squares (LS) method for the solution of the Schrödinger equation. These properties are exemplified by a number of calculations on the n1S and n3S states of helium, up to principal quantum number three, which are very much more accurate than previous LS calculations on helium. Particular attention is paid to the convergence properties of the LS procedure and we compare it with the simpler Rayleigh-Ritz (RR) procedure in the case when the RR matrix elements are evaluated numerically over the same quadrature mesh as used in the LS procedure. We conclude that although the LS procedure is capable of high accuracy it has no advantages which would justify its sole use in place of the RR procedure. However, it does have some advantages when used in conjunction with RR, in that it gives an estimate of the numerical accuracy of the RR energies.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030203

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110

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Theory of biorbitals. Study of conjugated systems in their ground and excited electronic states (1969)

Bessis, G. ; Espagnet, P. ; Bratož, S.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 205-218

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The biorbital theory called also “identical geminals theory” is applied to the study of a number of conjugated molecules. All basic integrals are determined by means of the Pariser-Parr-Pople procedure. The biorbital theory reproduces about 40 per cent of the correlation energy of the ground state of the molecule; this number is raised to about 70 per cent for the lowest triplet state. The low lying excited states are well represented from the point of view of transition energy as well as from the point of view of symmetry. The occupation number matrix and the charge-bond order matrix are defined and discussed. The overall chemical description of conjugated molecules produced by the biorbital theory is similar to that produced by other theories of electronic structure of molecules. It is concluded that the biorbital theory provides a description the quality of which is, roughly speaking, about half way between those provided by the SCF-MO and complete CI theories, respectively.

Additional Material: 10 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030206

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111

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Applied group theory. Author: G. G. Hall. Published by: Longmans, Green and Co, London, 1967. Price: 25s. (paperback). No. of pages: 135 (1969)

Calais, Jean-Louis

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 246-247

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030212

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112

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LCAO-MO studies on hydrogen bonding: The interaction between carbonyl and hydroxyl groups (1969)

Schuster, Peter

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 851-871

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Potential curves that show the energy dependence of hydrogen bonds between carbonyl and hydroxyl groups on the O—H bond length, on the distance between the molecules, and on the angle between the functional groups have been calculated with the CNDO/2 method. The results are presented for a small model system-formaldehyde/water - and for the dimer of formic acid. Good agreement is obtained with the available experimental data. The influence of the molecular geometry on the calculated results is discussed.

Additional Material: 14 Ill.

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URL: http://dx.doi.org/10.1002/qua.560030608

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113

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Wellenmechanische untersuchungen am 2-buten unter berücksichtigung aller elektronen (1969)

Janoschek, R. ; Preuss, H.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 889-891

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: 2-butene has been investigated for different nuclear positions taking all 32 electrons into account, using the SCF-MO-LC(LCGO) method. The calculations show that the energy of the trans-form is 1.1 kcal/mol lower than that of the cis-form. The potential curve between these two forms is shown graphically. The ionization energy was estimated to be 9.0 eV.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030611

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114

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Fermi surfaces and electron-impurity interactions in simple metals (1969)

Foster, Howard J.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 969-981

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A review is given of the current status of our work on electron transport properties and Fermi surfaces in simple metals. A simple classical model is proposed to extend existing theory to account for the effects of electron-impurity interactions on the behavior of magnetoacoustic absorption and the size and shape of the Fermi surface in the alkali metal potassium. The theoretical prediction is compared with measurements of the magnetoacoustic absorptionand Fermi surface diameters in potassium crystals of different impurity levels. An attempt is made to explain, on the basis of the theory of electron-impurity interactions, the decrease by 9% in the Fermi diameter and the departure by 53% in the phase factors of the impure potassium crystal. The results are compared with observations on a zone refined potassium crystal which satisfies the nearly-free-electron model.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030617

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115

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Long-range interactions in the ground and two excited states of the HeH+ molecule (1969)

Piela, Lucjan

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 945-968

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The long-range interaction energies for different dissociation products of the HeH+ molecule have been calculated using the Rayleigh-Schrödinger perturbation theory up to the third order in the energy. The calculations were carried out for the ground state (He(ls2) + H+), the first excited state (H(ls) + He+(ls)) and the second excited state Π(H(2pπ) + He+(ls)). The unperturbed states correspond to the dissociation products denoted in parentheses. Assuming the overlap to be zero, expanding the interaction potential in the inverse powers of the internuclear distance R and using the familiarly known perturbation-variational technique, the coefficients of various powers of R-1 in the energy expansion were evaluated. They correspond to different multipole-multipole interactions. The potential energy curves of all three states under consideration were calculated for large values of R. Also calculated were the multipole polarizabilities of the hydrogen atom in the is and 2pπ states and of the helium atom in the ground state.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030616

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116

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Laplace transform wave functions (1969)

Farmer, Christine M.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 1027-1043

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The wave function defining a quantum-mechanical system is considered as the Laplace transform of some distribution and the consequent form of the Variational Principle derived; an integral equation defines the eigenfunctions of a certain subclass. The model of the hydrogen-like atom is used to test the theory; the eigenfunctions and associated energy levels of the ground and excited states are obtained for arbitrary values of the orbital quantum number.

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URL: http://dx.doi.org/10.1002/qua.560030621

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117

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Vibronic absorption spectrum of the ethylene dimer (1969)

Sadlej, Andrzej J.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 569-580

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Vibronic coupling theory is used to construct the vibronic absorption spectrum of the ethylene dimer. It is shown that in this case an extended four-parameter form of the vibronic Hamiltonian should be considered. In addition to the commonly used three vibronic parameters, the difference between the ground and excited state force constants of the monomer is taken into account.Numerical calculations were performed for the dimer geometry resembling that of norbornadiene. Some comments on the interpretation of the absorption spectrum of norbornadiene are made.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030504

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118

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Free-electron model for electronic spectra of benzene (1969)

Sen, Purnendranath ; Basu, Sadhan

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 611-619

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Using a three dimensional free-electron model for the π-electron system the energies of the various singly and doubly excited configurations of benzene have been calculated. It has been found that the energies of the various singly excited configurations are in good agreement with the values obtained by Craig; whereas the energies of the doubly excited configurations are higher than those obtained by Craig. Therefore the configurational mixing for the doubly excited configurations is not necessary in this kind of model.

Additional Material: 4 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030508

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119

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The hydrogen atom in a cubic field of electric dipoles (1969)

Blokker, Esko

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 663-681

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The full rotational symmetry of the hydrogen atom is lowered to that of the double group of Oh. This is done by a cubic field of electric dipoles. Symmetry-adapted spin orbitals have been calculated and with them the energies of the lowest states as functions of the distance from the dipoles to the atom, the dipole moment, and the size of the atoms forming the dipoles. The Hamiltonian used is obtained by starting with the Dirac equations and then making some simplifications and approximations.

Additional Material: 10 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030512

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120

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Many-Electron problems. II. Energy expansions and internal fields (1969)

Gáspár, R.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 723-730

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Energy relations are derived for neutral atoms and isoelectronic sequences. It is shown that the field of the electrons at the position of the nucleus follows a very simple law and the diamagnetic shielding constant may be given in simple analytic form as a function of the atomic number.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030516

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121

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Valence configuration interaction calculations for atomic scattering (1969)

Michels, H. H. ; Harris, F. E.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 751-751

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030520

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122

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On uncoupled approximation with approximate form of the Hartree-Fock operator (1969)

Malinowski, S.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 763-766

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: It is shown that the uncoupled approximation of Dalgarno with the approximate form of the Hartree-Fock operator gives no bound for the second order energy.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030603

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123

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The distribution of electronic charge in the ground state of cubic boron nitride (1969)

Doggett, G.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 753-762

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The distribution of electronic charge in cubic boron nitride is investigated using the bond orbital wave functions recently calculated by Coulson and Doggett. Plots of the one-electron density function, in the (110) plane, are found to be insensitive to the choice of atomic basis functions, in contradistinction to the previously calculated effective atomic charges. A number of structure amplitudes are also calculated for each of the bond orbital wave functions.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030602

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124

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Energy levels of paramagnetic ions: Algebra. II (1969)

Kibler, Maurice

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 795-822

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The correspondence rules between the algebra of coupling coefficients of the special unitary group SU(2) and the associated algebra of a subgroup G of SU(2) are presented. The matrix elements of the irreducible representations of G are written in a convenient quantization scheme and different relations between these matrix elements and the Clebsch-Gordan coefficients of G are derived. Such a formalism is appropriate for numerous spectroscopic problems. As an example, it is applied to crystal field theory and electron paramagnetic resonance. General formulas from which a large number of results are rederived and generalized in a straightforward fashion are given. Numerical values of coupling coefficients for the tetragonal and cubic groups are listed in the Appendix.

Additional Material: 8 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030606

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125

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Theory of two shells of atomic electrons using non-orthogonal radial orbitals (1969)

Jucys, A. P. ; Bandzaitis, A. A. ; Grudzinskas, J. J.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 913-930

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Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A theory for handling non-orthogonal radial orbitals of two shells of atomic electrons based on the mathematical apparatus of irreducible tensor operators is presented. The general expressions for one- and two-electron operator matrix elements are given.

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URL: http://dx.doi.org/10.1002/qua.560030614

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126

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Nature of the chemisorption bond on semiconductor surfaces (1969)

Tomášek, M. ; Koutecký, J.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 249-267

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Results obtained by various quantum-mechanical approaches in studying localized states on crystal surfaces are summarized and discussed. The one- and many-electron aspects of the problem are compared and shown to lead to similar results. Emphasis is laid upon localized chemisorption states on intrinsic semiconductors. The problem of the calculation of chemisorption heat on solid surfaces is also mentioned.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030302

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127

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Wellenmechanische behandlung der protonisierung des äthylens unter berücksichtigung aller elektronen (1969)

Fratev, F. ; Janoschek, R. ; Preuss, H.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 873-879

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The system C2H5+ has been investigated as ethyl cation and as protonated ethylene using the SCF-MO-LC(LCGO) method. Equilibrium distances and angles have been estimated by different potential curves. No difference in total energy was found between the π- and the σ-complex.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560030609

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128

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The asymptotic Casimir-Polder potential from second-order perturbation theory and its generalization for anisotropic polarizabilities (1969)

Craig, D. P. ; Power, E. A.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 3 (1969), S. 903-911

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

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Topics: Chemistry and Pharmacology

Notes: It is shown how the leading term for very large R of the Casimir-Polder potential, that is the term varying as R-7, arises in second-order perturbation theory applied to the interaction Hamiltonian - \documentclass{article}\pagestyle{empty}\begin{document}$ - \sum\limits_\sigma {\frac{1}{2}\alpha (\sigma){\rm E}^{ \bot ^2 } (\sigma)} $\end{document}. The generalization to anisotropic molecules is calculated and the angular dependence of the long range intermolecular potential in this case is given explicitly in terms of the principal polarizabilities and their corresponding directions of the two molecules.

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URL: http://dx.doi.org/10.1002/qua.560030613

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Zur katalatischen und peroxidatischen Aktivität von Cu2+-Komplexen (1969)

Sigel, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 161-171

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Notes: Der Zusammenhang zwischen der Struktur von Cu2+-Komplexen und ihrer katalytischen Aktivität beim H2O2-Zerfall läßt sich als „molekulare Sonde“ verwenden, indem er es erlaubt, aus der katalytischen Aktivität eines Cu2+-Komplexes unbekannter Struktur die Zahl der koordinierten Ligandgruppen abzuleiten. Da außerdem nur koordinierte Ligandgruppen durch H2O2 oxidiert werden, lassen sich aus der spektrophotometrisch verfolgbaren Oxidation bestimmter Teile eines Liganden weitere Hinweise auf die Beschaffenheit der Koordinationssphäre des Metallions gewinnen. Dies gelang am Beispiel der Cu2+-Komplexe von Amiden, Polyaminosäuren, Nucleotiden, RNS und nativer sowie denaturierter DNS. Kinetische Untersuchungen gestatten Einblicke in die Mechanismen katalatischer und peroxidatischer Reaktionen.

Additional Material: 12 Ill.

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URL: http://dx.doi.org/10.1002/ange.19690810502

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trans-2-Methylcyclopropanol aus 1-Methylcyclopropen (1969)

Köster, R. ; Arora, S. ; Binger, P.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 185-186

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URL: http://dx.doi.org/10.1002/ange.19690810507

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131

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Synthese des trans/syn- und trans/anti-dimeren Uracils (1969)

Richter, P. ; Fahr, E.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 188-189

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URL: http://dx.doi.org/10.1002/ange.19690810510

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132

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Tetrakis(cyclopentadienyl)protactinium(IV) (1969)

Baumgärtner, F. ; Fischer, E. O. ; Kanellakopulos, B. ; [et al.]

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 182-182

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URL: http://dx.doi.org/10.1002/ange.19690810504

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133

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Ein salzartiger organischer Komplex mit molekularem Stickstoff (1969)

Ellermann, J. ; Poersch, F. ; Kunstmann, R. ; [et al.]

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 183-185

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URL: http://dx.doi.org/10.1002/ange.19690810506

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Darstellung und Reaktionen des 1,2-Diäthylidencyclobutans (1969)

Heimbach, P. ; Schimpf, R.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 186-188

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Additional Material: 1 Tab.

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URL: http://dx.doi.org/10.1002/ange.19690810509

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135

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Kalium-nitrosobissulfat als spezifisches Oxidationsmittel in der organischen Chemie (1969)

Teuber, H.-J.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 190-190

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URL: http://dx.doi.org/10.1002/ange.19690810512

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Rundschau (1969)

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 191-192

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URL: http://dx.doi.org/10.1002/ange.19690810515

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Reallexikon der Medizin und ihrer Grenzgebiete, Bd. II: Cargile Membran bis E-Zelle. Herausgeg. von G. Thiele und H. Walter. Urban & Schwarzenberg, München 1968. 1. Aufl., 805 S., Lose-Blatt-Heftung mit Kunststoffdecke, DM 140.- (1969)

Grünewald, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 194-194

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URL: http://dx.doi.org/10.1002/ange.19690810521

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138

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Elektrochromie - Solvatochromie (1969)

Liptay, W.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 195-206

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Notes: Die Lage und die Intensität von Elektronenbanden werden durch ein elektrisches Feld beeinflußt. Eine stärkere Veränderung der Lage von Absorptionsbanden wird hauptsächlich durch das Dipolmoment des Moleküls im Grundzustand und durch die Dipolmomentänderung beim Anregungsprozeß bestimmt, eine stärkere Veränderung der Intensität durch die direkte Feldabhängigkeit des Übergangsmoments, die durch die Übergangspolarisierbarkeit beschrieben werden kann. Aus der Beeinflussung der optischen Absorption durch ein äußeres elektrisches Feld (Elektrochromie) können an geeigneten Molekülen das Dipolmoment im Grundzustand, die Dipolmomentänderung beim Anregungsprozeß, die Übergangsmomentrichtung der Elektronenbande sowie bestimmte Komponenten des Tensors der Übergangspolarisierbarkeit ermittelt werden. Diese Daten bestimmen im wesentlichen die starke Solvatochromie (Lösungsmittelabhängigkeit der Lage und der Intensität von Elektronenbanden), die besonders bei Molekülen mit großem Dipolmoment beobachtet werden kann. Kleinere Beiträge zur Solvatochromie werden durch Dispersionswechselwirkungen verursacht, die im Falle nichtpolarer Moleküle überwiegen. Die Kombination von elektrooptischen Absorptionsmessungen (Beeinflussung der Absorption durch ein äußeres elektrisches Feld) mit der Untersuchung der Lösungsmittelabhängigkeit der Elektronenbanden ließ eine experimentelle Überprüfung und Bestätigung der entwickelten Modelle zu.

Additional Material: 5 Ill.

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URL: http://dx.doi.org/10.1002/ange.19690810602

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Intramolekulare Photocycloaddition von N,N′-AlkylendimaleinimidenDiese Arbeit wurde vom Center of High Polymer Research, von Gevaert-Agfa und von der National Science Foundation unterstützt. (1969)

De Schryver, F. C. ; Bhardwaj, I. ; Put, J.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 224-225

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URL: http://dx.doi.org/10.1002/ange.19690810607

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140

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Konformationsabhängige Thermooxidation N-vicinaler Methylengruppen in Polyamiden (1969)

Krüßmann, H. ; Valk, G. ; Heidemann, G. ; [et al.]

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 226-227

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Additional Material: 1 Tab.

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URL: http://dx.doi.org/10.1002/ange.19690810609

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Molecular orbital theories of bonding in organic molecules. Von R. L. Flurry jr., Marcel Dekker, Inc., New York 1968. 1. Aufl., X, 334 S., zahlr. Abb. und Tab. geh. $ 17.75 (1969)

Kutzelnigg, W.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 232-232

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URL: http://dx.doi.org/10.1002/ange.19690810618

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142

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Zur Biosynthese von Flechtenstoffen, Produkten einer symbiotischen Lebensgemeinschaft (1969)

Mosbach, K.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 233-244

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Notes: Flechten setzen sich aus Algen und Pilzen zusammen, die miteinander in Symbiose leben. Sie bilden charakteristische, oft polycyclische Flechtenstoffe, welche nur in wenigen Fällen auch in anderen Organismen nachgewiesen werden konnten. Die biosynthetischen Fähigkeiten der Flechten setzen sich nicht additiv aus denen ihrer Bestandteile zusammen. Die in diesem Aufsatz besprochenen Erkenntnisse über die Biosynthese der Flechtenstoffe wurden meistens an 14C-markierten Verbindungen gewonnen.

Additional Material: 3 Ill.

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URL: http://dx.doi.org/10.1002/ange.19690810702

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Organometallsubstitutuierte Sulfide als Liganden in Pentacarbonylchrom(0)-KomplexenDiese Arbeit wurde von der Deutschen Forschungsgemeinschaft und dem Fonds der Chemischen Industrie unterstützt. (1969)

Schumann, H. ; Stelzer, O. ; Gick, W.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 256-257

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URL: http://dx.doi.org/10.1002/ange.19690810704

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Synthese des dl-Juvenilhormons des Riesenseidenspinners Hyalophora cecropia (L.) (1969)

Schulz, H. ; Sprung, I.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 258-258

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URL: http://dx.doi.org/10.1002/ange.19690810706

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145

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Synthese substituierter Cyclopentadienone durch Ringverengung (1969)

Ried, W. ; Kunkel, W. ; Olschewski, P. B.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 260-261

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URL: http://dx.doi.org/10.1002/ange.19690810709

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Koordinationschemie (1969)

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 262-265

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The organic compounds of zinc and cadmium. Von N. I. Sheverdina und K. A. Kocheshkov. Aus der Reihe methods of elemento-organic chemistry. Herausgeg. von A. N. Nesmeyanov und K. A. Kocheshkov. Vol. 3. North-Holland Publishing Company, Amsterdam 1967. 1. Aufl., X, 252 S., zahlr. Abb., Hfl. 36. - (1969)

Neumann, W. P.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 266-267

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URL: http://dx.doi.org/10.1002/ange.19690810714

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Atlas of electron microscopy. Biological applications. Herausgeg. von F. Scanga. Elsevier Publishing Corporation, Amsterdam 1964. 1. Aufl., XXVI, 331 S., 496 Abb., geb. ca. DM 115, - (1969)

Grünewald, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 268-268

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URL: http://dx.doi.org/10.1002/ange.19690810717

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Framework molecular models. Baukasten mit 24 S. Gebrauchsanleitung. Prentice-Hall, Englewood Cliffs, N. J., USA., ca. DM 33. - (1969)

Grünewald, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 268-268

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URL: http://dx.doi.org/10.1002/ange.19690810719

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150

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Synthese eines 6-Thia-2-phosphonia-1,3,5,8-tetraazabicyclo[2.2.2]oct-4(5)-enchlorid-Derivats (1969)

Latscha, H. P. ; Klein, W.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 291-291

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URL: http://dx.doi.org/10.1002/ange.19690810805

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151

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1,1,3-Trimethylisopropylindenium-tetrachloroaluminat (1969)

Strohmeyer, M. ; Hiller, K. H. ; Witte, K.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 292-293

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Additional Material: 1 Tab.

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URL: http://dx.doi.org/10.1002/ange.19690810807

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Die Umwandlung von Arzneimitteln gegen Malaria im Stoffwechsel als Grundlage für die Entwicklung neuer Wirksubstanzen (1969)

Nickel, P.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 295-296

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Röntgenstrukturanalyse von Alkylthiostannonsäuren (Monoalkylsesquisulfiden) (1969)

Dörfelt, C. ; Paulus, E. F. ; Scherer, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 297-297

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URL: http://dx.doi.org/10.1002/ange.19690810816

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Siebenwertiges Plutonium (1969)

Keller, C. ; Seiffert, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 294-294

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Reversible Redoxsysteme mit stabilem Radikal-Kation (1969)

Hünig, S.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 295-295

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Übertragungsmechanismen in isolierten Neuronen (1969)

Giacobini, E.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 296-296

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157

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Halb- und vollsynthetische Makromoleküle in der immunchemischen Forschung (1969)

Rüde, E. ; Himmelspach, K. ; Sorg, C.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 338-338

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URL: http://dx.doi.org/10.1002/ange.19690810926

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158

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Dibenzo[a,e]cycloocten-Komplexe des Chroms und Molybdäns (1969)

Müller, J. ; Göser, P. ; Elian, M.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 331-332

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Synthesen mit Kohlenmonoxid. Von J. Falbe. Aus der Reihe Organische Chemie in Einzeldarstellungen, Bd. 10. Springer-Verlag, Berlin-Heidelberg-New York 1967, 1. Aufl., VII, 212 S., 20 Tab., DM 48. - (1969)

Kröper, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 342-342

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URL: http://dx.doi.org/10.1002/ange.19690810937

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160

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Über die Bildung von Makro-Zwitterionen bei ionischen Polymerisationen (1969)

Boehlke, K. ; Han, M. J. ; Jaacks, V. ; [et al.]

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 336-336

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URL: http://dx.doi.org/10.1002/ange.19690810920

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161

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Polymerisation von Äthylen mit Methyltitantrichlorid und Methyltitandichlorid (1969)

Kühlein, K. ; Clauss, K.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 337-337

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URL: http://dx.doi.org/10.1002/ange.19690810923

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162

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Untersuchungen zur Strukturaufklärung von Seidenfibroin (1969)

Schade, W.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 338-338

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URL: http://dx.doi.org/10.1002/ange.19690810927

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163

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Neue Umlagerungen bei der Umsetzung von Pyryliumsalzen mit NitromethanHerrn Professor H. Bredereck zum 65. Geburtstag gewidmet (1969)

Dimroth, K. ; Laubert, G.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 392-393

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164

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Röntgenspektroskopische Untersuchung der chemischen Bindung in Oxiden (1969)

Chun, H.-U.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 400-401

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Gruppentheorie für Chemiker, Physiko-Chemiker, Mineralogen ab 5. Sem. Von K. Mathiak und P. Stingl. Aus der Reihe Hochschul-Studienbuch. Friedr. Vieweg und Sohn, Braunschweig, Akad. Verlagsgesellschaft, Frankfurt/M. 1968. 1. Aufl., 199 S., brosch. DM 9.80 (1969)

Wilhelm, K.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 406-406

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URL: http://dx.doi.org/10.1002/ange.19690811029

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166

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Selektive oxidative Kupplung von Phenolen mit Silbercarbonat/Celite (1969)

Balogh, V. ; Fetizon, M. ; Golfier, M.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 423-424

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URL: http://dx.doi.org/10.1002/ange.19690811105

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167

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Eine neue Benzo-cyclopropen-Synthese[1] (1969)

Dürr, H. ; Schrader, L.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 426-427

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URL: http://dx.doi.org/10.1002/ange.19690811109

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168

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Kristallstruktur von PCl4(NCH3)2CCl - ein viergliedriges Ringsystem mit sechsbindigem Phosphor (1969)

Ziegler, M. L. ; Weiss, J.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 430-430

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Phosphorisocyanate (1969)

Derkatsch, G. I.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 407-415

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Notes: Verbindungen mit der PNCO-Gruppierung sind z. B. aus Phosphorhalogeniden und Silbercyanat oder N-Chloriminokohlensäureestern sowie durch thermische Zersetzung von Alkoxycarbonyliminophosphoranen zu erhalten. In ihren chemischen Eigenschaften ähneln die Phosphor(V)-isocyanate den „Kohlenstoff“-isocyanaten, die Phosphor(III)-isocyanate dagegen den Phosphor(III)-chloriden. Einige der besprochenen Verbindungen haben insektizide oder cytostatische Wirkung.

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URL: http://dx.doi.org/10.1002/ange.19690811102

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170

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Neuere Untersuchungen zur Biosynthese der Flavonoide (1969)

Grisebach, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 403-403

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171

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5,6-Didehydro-11,12-dihydrodibenzo[a,e]cycloocten (1969)

Seitz, G. ; Pohl, L. ; Pohlke, R.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 427-428

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URL: http://dx.doi.org/10.1002/ange.19690811110

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Rundschau (1969)

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 434-435

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URL: http://dx.doi.org/10.1002/ange.19690811119

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173

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Zur Möglichkeit kernresonanzspektroskopischer Untersuchungen an paramagnetischen Verbindungen (1969)

Schwarzhans, K. E.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 433-433

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URL: http://dx.doi.org/10.1002/ange.19690811117

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174

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Synthesen seltener Zucker (1969)

Brimacombe, J. S.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 415-423

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Notes: Sekundäre Hydroxygruppen geeignet geschützter Zucker lassen sich mit Oxidationsmitteln wie Dimethylsulfoxid-Carbodiimid (Pfitzner-Moffatt-Reagens), Dimethylsulf-oxid-Säureanhydrid-Gemischen oder Rutheniumtetroxid zur Carbonylstufe oxidieren. Die entstehenden Ketone sind wertvolle Zwischenprodukte für die Darstellung von Amino- und Desoxyzuckern und auch von verzweigten und anderen seltenen Zuckern, wie an einigen repräsentativen Synthesen gezeigt werden soll.

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175

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Neue Zweistufensynthese des Yohimban-Ringsystems (1969)

Meise, W. ; Zymalkowski, F.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 425-426

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URL: http://dx.doi.org/10.1002/ange.19690811107

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176

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Ein Diaziridinimin (1969)

Quast, H. ; Schmitt, Edeltraud

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 428-429

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URL: http://dx.doi.org/10.1002/ange.19690811111

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177

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Alkyl- und Aryl-α-chlorenamine (1969)

Ghosez, L. ; Haveaux, B. ; Viehe, H. G.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 468-469

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URL: http://dx.doi.org/10.1002/ange.19690811209

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Rundschau (1969)

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 471-472

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URL: http://dx.doi.org/10.1002/ange.19690811213

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Masthead (1969)

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969)

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Stereospezifische Synthese des cis-2-Hydroxy-4-methyl-1,3,2-dioxaphosphorv-inan-2-thionsGeometrische Isomerie bei cyclischen Monothiophosphorsäuren, 2. Mitteilung. - 1. Mitteilung: [1]. (1969)

Mikołajczyk, M.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 495-495

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URL: http://dx.doi.org/10.1002/ange.19690811307

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181

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Polyoxymethylene (1969)

Cherdron, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 502-502

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URL: http://dx.doi.org/10.1002/ange.19690811314

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182

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Extrusion reactions. Von B. P. Stark, A. J. Duke. Pergamon Press, Oxford 1967, 1 Aufl., X, 190 S., zahlr. Abb. s 63.- (1969)

Regitz, M.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 505-505

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URL: http://dx.doi.org/10.1002/ange.19690811318

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183

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Intramolekulare Bewegungen von Enaminen und Hydrazonen. Trennung von Rotationsisomeren (1969)

Mannschreck, A. ; Kölle, U.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 540-540

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Kunststoff-Handbuch. Herausgeg. von R. Vieweg und E. Becker. Band X: Duroplaste. Herstellung, Eigenschaften, Verarbeitung und Anwendung. Carl Hanser Verlag, München 1968. 1. Aufl., XXII, 749 S., 473 Abb., 110 Tab., LN DM 210,- bei Subskr. auf das Gesamtwerk (12 Bde.) DM 168,- (1969)

Horn, O.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 542-542

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URL: http://dx.doi.org/10.1002/ange.19690811421

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185

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Hydratstruktur und zwischenmolekulare Wechselwirkung in Polyelektrolyten (1969)

Zundel, G.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 507-518

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Notes: Bei der Hydratation ist die zwischenmolekulare Wechselwirkung von entscheidender Bedeutung, denn die Ionen verändern die Eigenschaften ihrer Hydratwassermoleküle, und umgekehrt nehmen die Wassermoleküle wesentlichen Einfluß auf die Wechselwirkung zwischen den Ionen. Mit Hilfe der IR-Spektroskopie können diese Vorgänge im Detail studiert werden; sie gibt darüberhinaus ein Bild der Hydratstruktur. Die IR-Spektroskopie zeigt auch, daß die Überschuß-Protonen in Energiebändern vorliegen und ermöglicht den Nachweis der zwischen tunnelnden Protonen wirkenden Protonen-Dispersionskräfte. Die Ergebnisse IR-spektroskopischer Untersuchungen von Polyelektrolyten sind ein Beitrag zum Verständnis der vielen biologischen Vorgänge, die durch das Verhalten von Ionen bestimmt werden.

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Zur Existenz des Oxalyldikations [C2O2]2+ (1969)

Adelhelm, M.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 530-531

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Hydrido- und Alkyl(aryl)hydrido-Komplexe des Nickels (1969)

Jonas, K. ; Wilke, G.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 534-534

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Das Bis(chloroschwefel)stickstoff-Kation in [NS2Cl2]+[BCl4]- (1969)

Glemser, O. ; Krebs, B. ; Wegerner, J. ; [et al.]

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 568-568

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Magnetische Nichtäquivalenz von Methylen-Protonen und gem-Methyl-Gruppen in asymmetrischen Eisenkomplexen (1969)

Brunner, H. ; Schmidt, E.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 570-571

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190

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Katalytische Oxidation von Olefinen über ein Allyl-RadikalDiese Arbeit wurde von Eli Lilly and Company unterstützt. (1969)

Baldwin, J. E. ; Swallow, J. C.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 571-572

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191

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Isolierung und Zerfall der Zwischenstufe einer ElcB-Eliminierung (1969)

Berndt, A.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 567-567

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192

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Reaktionen in chiralen Kristallen: Eine absolute asymmetrische Synthese (1969)

Penzien, K. ; Schmidt, G. M. J.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 628-628

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URL: http://dx.doi.org/10.1002/ange.19690811615

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Masthead (1969)

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969)

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URL: http://dx.doi.org/10.1002/ange.19690811901

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Malondithioamid aus Dimethylaminomalondinitril und SchwefelwasserstoffHerrn Professor B. Timm zum 60. Geburtstag gewidmet (1969)

Eilingsfeld, H. ; Patsch, M.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 741-742

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Moderne AnalytikHerrn Professor B. Timm zum 60. Geburtstag gewidmet (1969)

Kienitz, H.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 723-741

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Notes: An den wichtigsten Fortschritten der sich rasch entwickelnden modernen analytischen Methoden wird der gründliche Wandel aufgezeigt, den die „analytische Chemie“ in Theorie und Praxis erfährt. Die „Informationsoptimierung“ bedarf des Umdenkens in Lehre und Forschung, sie braucht die Integration der Chemie mit anderen naturwissenschaftlichen und technischen Disziplinen.

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Bis(diphenylboryl)diimin (1969)

Wiberg, N. ; Schwenk, G.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 745-745

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URL: http://dx.doi.org/10.1002/ange.19690811909

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Elektrochemische Oxidation von Aldehyden, Ameisensäure und Kohlenmonoxid an Wolframcarbid-Elektroden in 2 N Schwefelsäure (1969)

Binder, H. ; Köhling, A. ; Kuhn, W. ; [et al.]

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 748-748

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ISSN: 0044-8249

Keywords: Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/ange.19690811912

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Hexakalium-μ-thio-bis(hexacyanomolybdat(IV)), ein neuartiger Molybdänkomplex (1969)

Müller, A. ; Christophliemk, P.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 752-752

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ISSN: 0044-8249

Keywords: Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/ange.19690811917

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Statische Elektrizität als Gefahr. Von K. Haase. Verlag Chemie GmbH., Weinheim/Bergstr. 1967. 1. Aufl., 124 S., 21 Abb., kart. DM 14,- (1969)

Euler, K. J.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 755-756

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ISSN: 0044-8249

Keywords: Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/ange.19690811922

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Sorptionsvermittler in der Biopharmazie (1969)

Ritschel, W. A.

Weinheim : Wiley-Blackwell

Zeitschrift für die chemische Industrie 81 (1969), S. 757-769

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ISSN: 0044-8249

Keywords: Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Die Absorption von Arzneistoffen hängt von den chemisch-physikalischen Eigenschaften der Substanzen ab. Mit Hilfe von „Sorptionsvermittlern“ gelingt es, Arzneistoffe, die schwer, überhaupt nicht oder nur langsam absorbierbar sind, in die Haut und in die Schleimhaut eindringen (penetrieren) oder durch diese hindurchdringen (permeieren) zu lassen. Die Suche nach derartigen Hilfsstoffen sowie die Aufklärung ihrer Wirkungsprinzipien gehören in den Bereich der Biopharmazie.

Additional Material: 9 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/ange.19690812002

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