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  • 1
    Publikationsdatum: 2020-08-05
    Beschreibung: This article is about the optimal track allocation problem (OPTRA) to find, in a given railway network, a conflict free set of train routes of maximum value. We study two types of integer programming formulations: a standard formulation that models block conflicts in terms of packing constraints, and a new extended formulation that is based on additional configuration' variables. We show that the packing constraints in the standard formulation stem from an interval graph, and that they can be separated in polynomial time. It follows that the LP relaxation of a strong version of this model, including all clique inequalities from block conflicts, can be solved in polynomial time. We prove that the extended formulation produces the same LP bound, and that it can also be computed with this model in polynomial time. Albeit the two formulations are in this sense equivalent, the extended formulation has advantages from a computational point of view, because it features a constant number of rows and is therefore amenable to standard column generation techniques. Results of an empirical model comparison on mesoscopic data for the Hannover-Fulda-Kassel region of the German long distance railway network are reported.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 2
    Publikationsdatum: 2016-06-09
    Beschreibung: We study barrier methods for state constrained optimal control problems with PDEs. In the focus of our analysis is the path of minimizers of the barrier subproblems with the aim to provide a solid theoretical basis for function space oriented path-following algorithms. We establish results on existence, continuity and convergence of this path. Moreover, we consider the structure of barrier subdifferentials, which play the role of dual variables.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 3
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    Publikationsdatum: 2016-06-09
    Beschreibung: For the treatment of equilibrated molecular systems in a heat bath we propose a transition state theory that is based on conformation dynamics. In general, a set-based discretization of a Markov operator ${\cal P}^\tau$ does not preserve the Markov property. In this article, we propose a discretization method which is based on a Galerkin approach. This discretization method preserves the Markov property of the operator and can be interpreted as a decomposition of the state space into (fuzzy) sets. The conformation-based transition state theory presented here can be seen as a first step in conformation dynamics towards the computation of essential dynamical properties of molecular systems without time-consuming molecular dynamics simulations.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 4
    Publikationsdatum: 2021-01-22
    Beschreibung: We present a middleware to store multidimensional data sets on Internet-scale distributed systems and to efficiently perform range queries on them. Our structured overlay network \emph{SONAR (Structured Overlay Network with Arbitrary Range queries)} puts keys which are adjacent in the key space on logically adjacent nodes in the overlay and is thereby able to process multidimensional range queries with a single logarithmic data lookup and local forwarding. The specified ranges may have arbitrary shapes like rectangles, circles, spheres or polygons. Empirical results demonstrate the routing performance of SONAR on several data sets, ranging from real-world data to artificially constructed worst case distributions. We study the quality of SONAR's routing information which is based on local knowledge only and measure the indegree of the overlay nodes to find potential hot spots in the routing process. We show that SONAR's routing table is self-adjusting, even under extreme situations, keeping always a maximum of $\lceil \log N \rceil$ routing entries.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 5
    Publikationsdatum: 2016-06-09
    Beschreibung: \begin{abstract} In systems biology, the stochastic description of biochemical reaction kinetics is increasingly being employed to model gene regulatory networks and signalling pathways. Mathematically speaking, such models require the numerical solution of the underlying evolution equat ion, also known as the chemical master equation (CME). Up to now, the CME has almost exclusively been treated by Monte-Carlo techniques, the most prominent of which is the simulation algorithm suggest ed by Gillespie in 1976. Since this algorithm requires an update for each single reaction event, realizations can be computationally very costly. As an alternative, we here propose a novel approach, which focuses on the discrete partial differential equation (PDE) structure of the CME and thus allows to adopt ideas from adaptive discrete Galerkin methods (as designed by two of the present authors in 1989), which have proven to be highly efficient in the mathematical modelling of polyreaction kinetics. Among the two different options of discretizing the CME as a discrete PDE, the method of lines approach (first space, then time) and the Rothe method (first time, then space), we select the latter one for clear theoretical and algorithmic reasons. First numeric al experiments at a challenging model problem illustrate the promising features of the proposed method and, at the same time, indicate lines of necessary further research. \end{abstract}
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 6
    Publikationsdatum: 2014-02-26
    Beschreibung: Chvatal-Gomory cuts are among the most well-known classes of cutting planes for general integer linear programs (ILPs). In case the constraint multipliers are either 0 or $\frac{1}{2}$, such cuts are known as $\{0,\frac{1}{2}\}$-cuts. It has been proven by Caprara and Fischetti (1996) that separation of $\{0,\frac{1}{2}\}$-cuts is NP-hard. In this paper, we study ways to separate $\{0,\frac{1}{2}\}$-cuts effectively in practice. We propose a range of preprocessing rules to reduce the size of the separation problem. The core of the preprocessing builds a Gaussian elimination-like procedure. To separate the most violated $\{0,\frac{1}{2}\}$-cut, we formulate the (reduced) problem as integer linear program. Some simple heuristic separation routines complete the algorithmic framework. Computational experiments on benchmark instances show that the combination of preprocessing with exact and/or heuristic separation is a very vital idea to generate strong generic cutting planes for integer linear programs and to reduce the overall computation times of state-of-the-art ILP-solvers.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 7
    Publikationsdatum: 2014-02-26
    Beschreibung: In this paper a Godunov-type projection method for computing approximate solutions of the zero Froude number (incompressible) shallow water equations is presented. It is second-order accurate and locally conserves height (mass) and momentum. To enforce the underlying divergence constraint on the velocity field, the predicted numerical fluxes, computed with a standard second order method for hyperbolic conservation laws, are corrected in two steps. First, a MAC-type projection adjusts the advective velocity divergence. In a second projection step, additional momentum flux corrections are computed to obtain new time level cell-centered velocities, which satisfy another discrete version of the divergence constraint. The scheme features an exact and stable second projection. It is obtained by a Petrov-Galerkin finite element ansatz with piecewise bilinear trial functions for the unknown incompressible height and piecewise constant test functions. The stability of the projection is proved using the theory of generalized mixed finite elements, which goes back to Nicola{\"i}des (1982). In order to do so, the validity of three different inf-sup conditions has to be shown. Since the zero Froude number shallow water equations have the same mathematical structure as the incompressible Euler equations of isentropic gas dynamics, the method can be easily transfered to the computation of incompressible variable density flow problems.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 8
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    Publikationsdatum: 2019-10-24
    Schlagwort(e): ddc:000
    Sprache: Deutsch
    Materialart: annualzib , doc-type:report
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  • 9
    Publikationsdatum: 2020-12-15
    Beschreibung: We provide information on the Survivable Network Design Library (SNDlib), a data library for fixed telecommunication network design that can be accessed at http://sndlib.zib.de. In version 1.0, the library contains data related to 22 networks which, combined with a set of selected planning parameters, leads to 830 network planning problem instances. In this paper, we provide a mathematical model for each planning problem considered in the library and describe the data concepts of the SNDlib. Furthermore, we provide statistical information and details about the origin of the data sets.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 10
    Publikationsdatum: 2020-08-05
    Beschreibung: The \emph{optimal track allocation problem} (\textsc{OPTRA}), also known as the train routing problem or the train timetabling problem, is to find, in a given railway network, a conflict-free set of train routes of maximum value. We propose a novel integer programming formulation for this problem that is based on additional configuration' variables. Its LP-relaxation can be solved in polynomial time. These results are the theoretical basis for a column generation algorithm to solve large-scale track allocation problems. Computational results for the Hanover-Kassel-Fulda area of the German long distance railway network involving up to 570 trains are reported.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 11
    Publikationsdatum: 2020-12-15
    Beschreibung: We consider a multicommodity routing problem, where demands are released \emph{online} and have to be routed in a network during specified time windows. The objective is to minimize a time and load dependent convex cost function of the aggregate arc flow. First, we study the fractional routing variant. We present two online algorithms, called Seq and Seq$^2$. Our first main result states that, for cost functions defined by polynomial price functions with nonnegative coefficients and maximum degree~$d$, the competitive ratio of Seq and Seq$^2$ is at most $(d+1)^{d+1}$, which is tight. We also present lower bounds of $(0.265\,(d+1))^{d+1}$ for any online algorithm. In the case of a network with two nodes and parallel arcs, we prove a lower bound of $(2-\frac{1}{2} \sqrt{3})$ on the competitive ratio for Seq and Seq$^2$, even for affine linear price functions. Furthermore, we study resource augmentation, where the online algorithm has to route less demand than the offline adversary. Second, we consider unsplittable routings. For this setting, we present two online algorithms, called U-Seq and U-Seq$^2$. We prove that for polynomial price functions with nonnegative coefficients and maximum degree~$d$, the competitive ratio of U-Seq and U-Seq$^2$ is bounded by $O{1.77^d\,d^{d+1}}$. We present lower bounds of $(0.5307\,(d+1))^{d+1}$ for any online algorithm and $(d+1)^{d+1}$ for our algorithms. Third, we consider a special case of our framework: online load balancing in the $\ell_p$-norm. For the fractional and unsplittable variant of this problem, we show that our online algorithms are $p$ and $O{p}$ competitive, respectively. Such results where previously known only for scheduling jobs on restricted (un)related parallel machines.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 12
    Publikationsdatum: 2014-02-26
    Beschreibung: Die Zentrale des Kooperativen Bibliotheksverbunds Berlin-Brandenburg (KOBV) betreibt seit Januar 2004 das KOBV-Portal, in dem u.a. vielfältige Open-Linking-Dienste eingebunden sind. Dieser Beitrag erläutert Open-Linking allgemein und stellt die KOBV spezifischen Dienste im Detail vor. Dabei wird auch die Zugriffsentwicklung auf die KOBV-Open-Linking-Dienste evaluiert. Ein Ergebnis ist, dass signifikante Steigerungen der Nutzung erst dann bewirkt werden, wenn Maßnahmen durchgeführt werden, die erstens die Open-Linking-Dienste stärker ins Bewusstsein der NutzerInnen rücken und zweitens den Weg dorthin im KOBV-Portal verkürzen. Vor allem muss ein schneller Weg zu den Open-Linking-Diensten gewährleistet sein, um die Nutzung deutlich zu steigern. Um zusätzlich den Bekanntheitsgrad der Open-Linking-Dienste bundesweit zu erhöhen, regt die KOBV-Zentrale andere Bibliotheken und Verbünde dazu an, analoge Open-Linking-Dienste einzurichten. Auf diese Weise wird die Handhabung von Open-Linking selbstverständlicher.
    Schlagwort(e): ddc:000
    Sprache: Deutsch
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  • 13
    Publikationsdatum: 2014-02-26
    Beschreibung: Dieser Artikel berichtet über eine erfolgreiche Schüleraktivität, die seit Jahren am Zuse-Institut Berlin (ZIB) bei Besuchen von Schülergruppen erprobt und verfeinert worden ist. Das hier zusammengestellte Material ist gedacht als Basis für eine Unterrichtseinheit in Leistungskursen Mathematik an Gymnasien. Inhaltlich wird von einem zwar für Schüler (wie auch Lehrer) neuen, aber leicht fasslichen Gegenstand ausgegangen: der Drei-Term-Rekursion für Besselfunktionen. Die Struktur wird erklärt und in ein kleines Programm umgesetzt. Dazu teilen sich die Schüler selbstorganisierend in Gruppen ein, die mit unterschiedlichen Taschenrechnern "um die Wette" rechnen. Die Schüler und Schülerinnen erfahren unmittelbar die katastrophale Wirkung von an sich kleinen'' Rundungsfehlern, sie landen -- ebenso wie der Supercomputer des ZIB -- im Bessel'schen Irrgarten''. Die auftretenden Phänomene werden mathematisch elementar erklärt, wobei lediglich auf das Konzept der linearen Unabhängigkeit zurückgegriffen wird. Das dabei gewonnene vertiefte Verständnis fließt ein in die Konstruktion eines klassischen Algorithmus sowie eines wesentlich verbesserten Horner-artigen Algorithmus.
    Schlagwort(e): ddc:000
    Sprache: Deutsch
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  • 14
    Publikationsdatum: 2017-08-01
    Beschreibung: In this paper we study capacitated network design problems, differentiating directed, bidirected and undirected link capacity models. We complement existing polyhedral results for the three variants by new classes of facet-defining valid inequalities and unified lifting results. For this, we study the restriction of the problems to a cut of the network. First, we show that facets of the resulting cutset polyhedra translate into facets of the original network design polyhedra if the two subgraphs defined by the network cut are (strongly) connected. Second, we provide an analysis of the facial structure of cutset polyhedra, elaborating the differences caused by the three different types of capacity constraints. We present flow-cutset inequalities for all three models and show under which conditions these are facet-defining. We also state a new class of facets for the bidirected and undirected case and it is shown how to handle multiple capacity modules by Mixed Integer Rounding (MIR).
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    Sprache: Englisch
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  • 15
    Publikationsdatum: 2020-12-15
    Beschreibung: In this paper we study online multicommodity routing problems in networks, in which commodities have to be routed sequentially. The flow of each commodity can be split on several paths. Arcs are equipped with load dependent price functions defining routing costs, which have to be minimized. We discuss a greedy online algorithm that routes each commodity by minimizing a convex cost function that only depends on the demands previously routed. We present a competitive analysis of this algorithm showing that for affine linear price functions this algorithm is 4K2 (1+K)2 -competitive, where K is the number of commodities. For the single-source single-destination case, this algorithm is optimal. Without restrictions on the price functions and network, no algorithm is competitive. Finally, we investigate a variant in which the demands have to be routed unsplittably.
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    Sprache: Englisch
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  • 16
    Publikationsdatum: 2020-12-15
    Beschreibung: In this paper, we empirically investigate the NP-hard problem of finding sparse solutions to linear equation systems, i.e., solutions with as few nonzeros as possible. This problem has received considerable interest in the sparse approximation and signal processing literature, recently. We use a branch-and-cut approach via the maximum feasible subsystem problem to compute optimal solutions for small instances and investigate the uniqueness of the optimal solutions. We furthermore discuss five (modifications of) heuristics for this problem that appear in different parts of the literature. For small instances, the exact optimal solutions allow us to evaluate the quality of the heuristics, while for larger instances we compare their relative performance. One outcome is that the basis pursuit heuristic performs worse, compared to the other methods. Among the best heuristics are a method due to Mangasarian and a bilinear approach.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 17
    Publikationsdatum: 2014-02-26
    Beschreibung: The performance evaluation of W-CDMA networks is intricate as cells are strongly coupled through interference. Pole equations have been developed as a simple tool to analyze cell capacity. Numerous scientific contributions have been made on their basis. In the established forms, the pole equations rely on strong assumptions such as homogeneous traffic, uniform users, and constant downlink orthogonality factor. These assumptions are not met in realistic scenarios. Hence, the pole equations are typically used during initial network dimensioning only. Actual network (fine-) planning requires a more faithful analysis of each individual cell's capacity. Complex analytical analysis or Monte-Carlo simulations are used for this purposes. In this paper, we generalize the pole equations to include inhomogeneous data. We show how the equations can be parametrized in a cell-specific way provided the transmit powers are known. This allows to carry over prior results to realistic settings. This is illustrated with an example: Based on the pole equation, we investigate the accuracy of average snapshot'' approximations for downlink transmit powers used in state-of-the-art network optimization schemes. We confirm that the analytical insights apply to practice-relevant settings on the basis of results from detailed Monte-Carlo simulation on realistic datasets.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 18
    Publikationsdatum: 2017-08-01
    Beschreibung: This paper deals with directed, bidirected, and undirected capacitated network design problems. Using mixed integer rounding (MIR), we generalize flow-cutset inequalities to these three link types and to an arbitrary modular link capacity structure, and propose a generic separation algorithm. In an extensive computational study on 54 instances from the Survivable Network Design Library (SNDlib), we show that the performance of cplex can significantly be enhanced by this class of cutting planes. The computations reveal the particular importance of the subclass of cutset-inequalities.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 19
    Publikationsdatum: 2020-02-04
    Beschreibung: Wigner transformation provides a one-to-one correspondence between functions on position space (wave functions) and functions on phase space (Wigner functions). Weighted integrals of Wigner functions yield quadratic quantities of wave functions like position and momentum densities or expectation values. For molecular quantum systems, suitably modified classical transport of Wigner functions provides an asymptotic approximation of the dynamics in the high energy regime. The article addresses the computation of Wigner functions by Monte Carlo quadrature. An ad aption of the Metropolis algorithm for the approximation of signed measures with disconnected support is systematically tested in combination with a surface hopping algorithm for non-adiabatic quantum dynamics. The numerical experiments give expectation values and level populations with an error of two to three percent, which agrees with the theoretically expected accuracy.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 20
    Publikationsdatum: 2020-11-13
    Beschreibung: We study a planning problem arising in SDH/WDM multi-layer telecommunication network design. The goal is to find a minimum cost installation of link and node hardware of both network layers such that traffic demands can be realized via grooming and a survivable routing. We present a mixed-integer programming formulation that takes many practical side constraints into account, including node hardware, several bitrates, and survivability against single physical node or link failures. This model is solved using a branch-and-cut approach with problem-specific preprocessing and cutting planes based on either of the two layers. On several realistic two-layer planning scenarios, we show that these cutting planes are still useful in the multi-layer context, helping to increase the dual bound and to reduce the optimality gaps.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 21
    Publikationsdatum: 2020-08-05
    Beschreibung: In \emph{classical optimization} it is assumed that full information about the problem to be solved is given. This, in particular, includes that all data are at hand. The real world may not be so nice'' to optimizers. Some problem constraints may not be known, the data may be corrupted, or some data may not be available at the moments when decisions have to be made. The last issue is the subject of \emph{online optimization} which will be addressed here. We explain some theory that has been developed to cope with such situations and provide examples from practice where unavailable information is not the result of bad data handling but an inevitable phenomenon.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 22
    Publikationsdatum: 2020-12-11
    Beschreibung: Die Intention ist der kooperative Aufbau einer Infrastruktur durch die Bibliotheksverbünde, um den Nutzern Volltext-Angebote dauerhaft und komfortabel zur Verfügung zu stellen: Zeitschriftenartikel und elektronische Dokumente werden mittels Suchmaschinentechnologie indexiert und unter Berücksichtigung von Zugriffsrechten zugänglich gemacht. Realisiert ist dies bereits im KOBV-Volltextserver, der seit Ende 2005 im Routinebetrieb läuft. Vorstellbar ist ein überregionales Netz von Volltextservern der Verbünde, die mittels Suchmaschinentechnologie indiziert und nahtlos in das regionale und lokale Literaturangebot integriert werden. Bei den lizenzierten Materialien sind insbesondere auch die Rechte der Verlage zu wahren und entsprechende Rechtemanagement-Verfahren einzusetzen. Es gilt, transparente Verfahren zu konzipieren und umzusetzen, um für die Verlage die notwendige Vertrauensbasis zu schaffen und gleichzeitig den Einrichtungen ihren berechtigten Zugriff auf die Volltexte zu sichern. Der vorliegende Text ist die schriftliche Fassung eines Vortrages auf dem 3. Leipziger Kongress für Information und Bibliothek "Information und Ethik", der vom 19.-22. März 2007 im Congress Center Leipzig stattfand.
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    Sprache: Deutsch
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  • 23
    Publikationsdatum: 2020-12-11
    Beschreibung: Zur Unterstützung der Bibliotheken bei ihren Open-Access-Aktivitäten betreibt die KOBV-Zentrale seit Anfang 2005 den Service "Opus- und Archivierungsdienste". Die KOBV-Zentrale agiert als Application Service Provider (ASP) für sämtliche technischen Komponenten des Publikationsprozesses, indem sie die gesamte technische Infrastruktur bereitstellt und betreibt – angefangen bei den lokalen Publikationsservern bis hin zu lokalen Repositories zur Archivierung der elektronischen Dokumente. Der vorliegende Text ist die schriftliche Fassung eines gleichnamigen Vortrages auf der 31. ASpB-Tagung "Kooperation versus Eigenprofil?" der Arbeitsgemeinschaft der Spezialbibliotheken, die vom 25.-28. September 2007 in der Technischen Universität Berlin stattfand.
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    Sprache: Deutsch
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  • 24
    Publikationsdatum: 2022-07-07
    Beschreibung: A new approach to derive transparent boundary conditions (TBCs) for wave, Schrödinger, heat and drift-diffusion equations is presented. It relies on the pole condition and distinguishes between physical reasonable and unreasonable solutions by the location of the singularities of the spatial Laplace transform of the exterior solution. To obtain a numerical algorithm, a Möbius transform is applied to map the Laplace transform onto the unit disc. In the transformed coordinate the solution is expanded into a power series. Finally, equations for the coefficients of the power series are derived. These are coupled to the equation in the interior, and yield transparent boundary conditions. Numerical results are presented in the last section, showing that the error introduced by the new approximate TBCs decays exponentially in the number of coefficients.
    Schlagwort(e): ddc:000
    Sprache: Englisch
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  • 25
    Publikationsdatum: 2022-07-19
    Beschreibung: We present a unified approach for consistent remeshing of arbitrary non-manifold triangle meshes with additional user-defined feature lines, which together form a feature skeleton. Our method is based on local operations only and produces meshes of high regularity and triangle quality while preserving the geometry as well as topology of the feature skeleton and the input mesh.
    Schlagwort(e): ddc:000
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
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  • 26
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 134-138 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An analysis of the two-dimensional temperature field of a square column embedding a heating cylinder is presented. The analysis leads to a solution in finite series which gives rise to rapidly converging numerical results. The series coefficients computed for the extreme case of the cylinder being a line find a way of parametrization, which then furnishes the solutions for finite cylinders up to the case of the cylinder diameter being half of the column thickness. Results in five-digit accuracy are presented. The method is simple and direct. In addition, it retains the same concise formal solution for a variety of boundary conditions.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 27
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 147-148 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 28
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 151-153 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 29
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 249-254 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The hydrolysis of acetyl chloride was studied in a laboratory reactor designed to act as a chemical oscillator. The observed oscillating outputs are in fairly good agreement with the numerical solutions of the stirred tank reactor equations and the approximate analytical solutions published previously.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 30
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 233-240 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: It is shown that existing methods for design of optimal regulators by the Wiener-Hopf procedure must be modified in order to be applicable to unstable and/or nonminimum phase plant or disturbance transfer functions, such as are frequently encountered in the chemical industry. Solutions are developed for three cases: I. stable, but possibly nonminimum phase, plant and disturbance transfer functions; II. minimum phase, but possibly unstable, plant with no restrictions on the disturbance transfer functions; and III. prestabilized, with a proper modification to retain the original control effort inequality constraints, but possibly nonminimum phase plant and disturbance transfer functions. Case III gives the general solution for regulation of linear, time-invariant, lumped-parameter systems. When prestabilization is not necessary, it reduces to case I. Where applicable, solutions by the method of case II frequently involve less algebra than in case III.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 31
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 240-248 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The Wiener-Hopf procedure for synthesis of optimum constrained linear feedback regulators has been extended in part I to all linear time-invariant lumped parameter systems. The solution is here applied to the control of the output concentration of an exothermic, stirred tank reactor operating close to an unstable steady state, by constrained manipulation of a cooling water flow rate, in the presence of a randomly fluctuating inlet concentration.When the spectral density of disturbance is given (for example, white noise through a first-order time delay, or a series of randomly alternating steps), the optimum controller has three modes: proportional, derivative, and integral with minor feedback. The responses of the nonlinear reactor and the linearized reactor control systems to a series of alternating deterministic step inputs and Gaussian distributed inputs are simulated, and a sensitivity study of the linearized system with respect to variations in process, controller, and disturbance parameters is made in order to demonstrate the feasibility of the method.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 32
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 23-31 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In this paper, mathematical models for a single adsorbate component present in a gas phase have been developed for isothermal and adiabatic dynamic adsorption-desorption processes with special emphasis on adsorption drying by supported hygroscopic salts. The proposed generalized models are applicable to both an unsupported absorbent bed and a fixed bed of adsorbents impregnated on a supporter which may have nonlinear equilibrium relationships. The partial differential equations governing the dynamic adsorption-desorption processes and the nonlinear equilibrium relations were solved numerically on the digital computer.An experimental study was conducted to measure the adsorption and desorption rates of water vapor by lithium chloride impregnated on a solid supporter, Torvex.The proposed adiabatic adsorption-desorption model has been verified for unsupported adsorbent beds in the cases of water vapor adsorption from air by silica gel and of methane adsorption from a helium-methane mixture by activated carbon. The validity of the generalized adiabatic model for supported adsorbent beds with nonlinear equilibrium relationships was established by a direct comparison of experimental data obtained in this study with the predicted values.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
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  • 33
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 32-37 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Measurements of the effective self-diffusion coefficients for carbon dioxide and methane were performed in the transition pressure range. The experiments utilized carbon-14 tagged gases and semiconductor radiation detectors in a transient type of experiment. A detailed analysis of the errors associated with the experiments indicated that the accuracy of the measurements was near 5%. The results verify that the additive resistance law is valid for the representation in the transition range. The unknown effects of surface diffusion make the values to be employed in this law subject to review. As an example one surface diffusion model is considered.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 34
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 318-320 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 35
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 329-331 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 36
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 76-82 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental results have been obtained for heat transfer to melting ice spheres by measuring the rate of change of apparent weight. It is found that the traditional correlation format of Nusselt number against Rayleigh number is satisfactory only for bulk temperatures above 7°C. Average Nusselt numbers obtained from the sphere experiments are closely related to previous theoretical work with vertical flat plates.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 37
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 69-75 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An approach has been developed for predicting rates of interphase mass transfer under conditions of high flux and high concentration level. A rectangular channel device has been used to measure rates of evaporation of four solutes, carbon disulfide, n-pentane, cyclopentane, and ethyl ether, from n-tridecane into flowing nitrogen. The evaporation rate of carbon disulfide agreed with the prediction of the interphase theory up to a carbon disulfide mole fraction of 0.30 in the bulk liquid. For the other three systems, a concentration gradient induced, surface tension driven cellular convection served to increase liquid-phase coefficients substantially. A correlation was obtained for the effect of this cellular motion on the liquid-phase mass transfer coefficient.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 38
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 108-111 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Tray efficiencies were measured for desorbing ammonia from water by air in a small sieve-tray column operated in the cycling mode, that is, with alternate flow of vapor and liquid. The actual efficiency improvement obtained was compared with that theoretically possible assuming the liquid flows without mixing when dropped. A mixing model was proposed and the mixing parameter evaluated from the experimental data.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 39
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 120-130 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: As a step toward a unified treatment of particulately fluidized beds, a statistical-thermodynamic approach has been investigated, with the smoothed potential cell theory of pure liquids used to establish an equation of state and a collisional-viscosity relation. This treatment has correlated well with experimental data on liquid-fluidized beds, and the same method gives reasonable predictions for gas-fluidized beds. A parameter equivalent to thermodynamic temperature has been identified for fluidized beds, which depends solely upon fluid properties and includes the three-halves power of superficial velocity. This approach should be of value for interpreting other liquidlike properties of fluidized systems.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 40
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 41
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 150-150 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 42
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 43
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 177-184 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The efficiency of process optimization by mathematical programming can be increased by tearing, that is, rearranging the design equations so as to reduce the number of equality constraints. The structure of a system of equations may be depicted as an undirected bipartite graph; algorithm I-T utilizes this graph to determine an order of solution for the equations which requires no tears. If this is impossible, then algorithm II-T uses indexing in conjunction with algorithm I-T to produce an order which minimizes the number of torn equations. This procedure is extended to the problem of minimum recycle parameters, and the two-way interaction between tearing and algebraic simplification is illustrated.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 44
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 499-501 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 45
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 501-501 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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  • 46
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 512-702 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 47
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 513-519 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental gas absorption studies for bubbles transported in turbulent pipe flow of water strongly indicate that liquid phase controlled mass transfer is due to surface renewal by turbulent eddies. Predictions of transport behavior from the conditions of turbulent flow cannot be made in support of this mechanism because no satisfactory theory of turbulent transport near a gas-liquid interface is available. This work considers a model of the hydrodynamic behavior near the surface which provides a link between the observed mass transfer behavior and the state of the turbulent field.In this model, the very small scales of turbulent motion are considered to be controlling. These motions are idealized, and their flow and mass transfer behavior are solved analytically. The overall result for eddies of various sizes is related to the turbulent energy spectrum by using only the easily accessible parameter ∊, the energy dissipation rate. This model gives quantitative agreement to within a factor of 2 for three widely different experimental situations including gas-liquid and liquid-solid interfaces. However, the predicted Reynolds number dependence is somewhat higher than the experimental result.The model attempts to clearly define the basic physical process at the interface. Therefore, it indicates the direction for further experimentation needed to clarify the basic relationship between the mass transfer rates in the liquid phase and the hydrodynamic behavior of the turbulent liquid.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 48
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 553-559 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An experimental study of the photochlorination of propane was undertaken to assess the significance of heterogeneous termination steps (wall reactions). Data were obtained in 2- and 10-mm. I.D. tubular flow reactors with varying oxygen concentrations. The results indicated that homogeneous terminations were dominant in the large reactor, and heterogeneous ones were dominant in the small unit. A kinetic scheme which explained the data was proposed. It included two parallel termination steps: a second-order homogeneous reaction between C3H7. and oxygen and a first-order heterogeneous reaction between C3H7. and the reactor wall.Even though the data were taken in the laminar flow regime, the rate of reaction was a function of Reynolds number for the 10-mm. reactor. Kinetic factors may explain these results, but the reasons are not clear. More research in this area is needed.Data taken in the 10-mm. reactor packed with quartz cylinders gave results similar to those for the 2-mm. reactor. This provided confirming evidence for the proposed scheme of parallel, heterogeneous and homogeneous termination steps.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 49
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 588-594 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The heat and mass transfer processes in a binary mixture flowing in a parallel plate channel with mass addition at the bounding surfaces are investigated analytically. The rate of mass addition, the temperature, and the mass fraction are arbitrarily prescribed at each of the bounding walls. Similarity solutions are evaluated numerically to yield pressure gradient, Nusselt number, and Sherwood number results for a wide range of each of three governing parameters. It is found that increasingly strong surface mass addition markedly increases the magnitude of the axial pressure gradient. Mass addition decreases the Nusselt and Sherwood numbers at the channel wall at which the injection is strongest but may actually increase these moduli at the opposite wall. A generalizing analysis is performed to accommodate phase change processes as well as to accommodate the specification of plenum conditions rather than wall surface conditions. Application is made to the evaporation of liquid water by an air stream. It is shown that the rate of evaporation is augmented as the rate of air injection increases, but the extent of the augmentation is less than the causative increase in the air flow rate.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 50
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 633-638 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A previous report (1) has presented the derivation of new filter cake washing equations. This report presents the procedure for their application and contains an example of application to a specific batch washing system. It also presents the adaption of the equations to permit their use in predicting the performance of a continuous rotary-drum filter.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 51
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970) 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 52
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 528-535 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A theoretical analysis of the laminar-turbulent transition phenomenon is presented for the case of steady, isothermal, fully developed flow of Newtonian fluids in straight ducts of constant isosceles triangular cross section. As a result of this analysis, the simultaneous existence of macroscopically large stable regions of laminar and turbulent flow are predicted to occur during the transition phenomenon. The existence of this special type of flow field, which has not been previously predicted theoretically, is shown to be a consequence of the presence of an asymmetric shear stress distribution. The results of an experimental study are also presented. These data verify the predictions made by the theoretical analysis.
    Zusätzliches Material: 19 Ill.
    Materialart: Digitale Medien
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  • 53
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 762-766 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Pressure drops were measured for the high velocity isothermal viscous flow of steam in circular tubes. For the velocities tested, up to 0.48 times the isothermal sonic velocity, these flows obeyed the following equation with an average deviation of 2.4%. \documentclass{article}\pagestyle{empty}\begin{document}$$ P_1 2 - P_2 2 = \frac{{8\mu RTG}}{{DM}}\left[{\frac{{8L}}{D} + \frac{{N_{{\mathop{\rm Re}\nolimits} } }}{3}In\left({\frac{{P_1 }}{{P_2 }}} \right)} \right] $$\end{document}This equation differs from the Poiseuille-Meyer equation commonly used to correlate isothermal viscous flow in that it includes the term (NRe/3) In (P1/P2) which accounts for the change in momentum caused by expansion. In deriving this equation, the mean velocity, mean squared velocity, and wall shear stress were obtained from the parabolic velocity distribution for normal viscous flow. The velocity profile should flatten as the isothermal Mach number increases, and it is therefore anticipated that somewhere above the range tested the equation will no longer prove applicable. Variants of the equation, which take into account the flattening of the velocity profile in the range tested, did not fit the experimental data quite as well.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 54
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 766-770 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Information about the transition state of a chemical reaction is quite useful for the determination of mechanisms and for design of solvents for the reaction. High pressure kinetic studies, if sufficiently accurate, provide the required data. This work reports a new technique developed for measuring rates of chemical reactions in solution at high pressure. This method involves in situ mixing of reactants under pressure and direct sampling for analysis, eliminating large errors of temperature equilibration and time measurement inherent in existing techniques, and thus yielding more accurate results. Experimental results for the Diels-Alder reaction of isoprene and maleic anhydride are reported at pressures up to more than 6,000 atm.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 55
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 793-802 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The problem of mass transfer with nonequilibrium at, and significant convection across, the interface has been studied by the method of matched asymptotic expansions. The inner solution for small values of t or z/Um was found in terms of fk functions which were obtained in closed analytical form. The outer solution for large values of t or z/Um was found in terms of gk functions which had to be determined numerically. With these solutions, calculation of concentratration distributions or instantaneous rates of mass transfer is straightforward, but determination of the total amount of mass transfer as a function of time is complicated by the lack of an intersection wherein the inner and outer solutions overlap and converge. To avoid the need for graphical interpolation and integration of the interfacial concentration as a function of time to obtain the total mass transferred, the constant of integration M1 is found to be (-kγ\documentclass{article}\pagestyle{empty}\begin{document}$ \sqrt \pi $\end{document}/2h) by assuming that the ratio of mass transferred with an equilibrium interface to that with a nonequilibrium interface is independent of whether or not Vy convection is negligible in the system as t → ∞.The effect of a nonequilibrium interface is greatest for small t in unsteady systems and z/Um in steady state systems. This occurs because the departure from their equilibrium values of the interfacial concentrations of the phases in contact is greatest when they are first brought into contact. The larger the interfacial mass transfer coefficient α, the smaller is the time required for the interfacial concentrations to achieve their equilibrium values.Other things being equal, the rate of mass transfer is greatest when the driving force xA*-xA0 is greatest. Since the departure from equilibrium at the interface is greatest for small values of time, it follows that nonequilibrium interfacial phenomena can be observed most easily in systems where the rate of mass transfer is high. This is also the case when one cannot neglect the effect of finite velocity at the interface which is shown in the present work to be a significant effect.The method of analysis can be used to study a variety of problems in addition to the specific system considered here. In particular, both batch and flow reverse osmosis problems can be attacked by the present approach.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 56
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 832-837 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Ternary diffusion coefficients at 25°C. of the system 0.5 g./cc. d-tartaric acid - 0.5 g./cc. l-tartaric acid-water are reported. The results allow experimental verification of the theory for the diffusion of two indistinguishable solutes and clearly illustrate the difference between mutual and tracer diffusion. Moreover, the results allow calculation of ternary mass transfer coefficients and ternary tray efficiencies for the case of two similar species dissolved in a third.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 57
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 876-877 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 58
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 882-884 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 59
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970) 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 60
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1117-1117 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 61
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 999-1004 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The mechanism of diffusion in an absorbent pore was studied by applying adsorption rate data to the Damköhler equation. Most of the data were taken in the multimolecular region of the nitrogen-silica gel adsorption isotherm. Vapor-phase and adsorbed-phase contributions to the total transport were separated. Vapor-phase transport increased with temperature and was most dominant at relative pressures of 0.4 to 0.6. Adsorbed-phase diffusivities were of the order of 10-2  -  10-3 sq. cm./sec. and showed some dependence on the amount adsorbed at surface coverages greater than 1.5 molecular layers.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 62
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1047-1054 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A Burnett type of apparatus was built for 12,000 lb./sq.in. pressure and temperatures of 25° to 100°C. Isothermal expansions were run on methane, ethylene, and four binary mixtures at 25°, 50°, and 75°C., and compressibility factors were derived from the pressure ratio observations.From the experimental data, second and third virial coefficients were derived by two techniques, that is, the slope-intercept and the multiple regressions curve-fit of the data by the density-series virial equation. A comparison of these virial coefficients with those from the different empirical equations of state indicates areas of needed improvements in these equations. Second virial cross coefficients were also obtained.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 63
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 787-792 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: By expressing the meniscus height and the sine of the angle between the horizontal and a tangent to the meniscus curve as simple exponential functions of radial position, a new calculational procedure for determining surface tensions from menisci has been developed. These simple functions, when combined with the Laplace-Young equation, generated three useful equations for calculating surface tensions as a function of radial positions. The overall procedure by using the three equations and five smoothing methods was tested on both experimental and calculated menisci. The results from the procedure for the calculated menisci agreed within 1.5% with the original surface tensions used to generate the meniscus. The agreement of values generated with the method and the comparison method previously reported for experimental menisci was within ±8% in general and within ±2% for the best formed menisci.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 64
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 817-823 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A gradientless reactor has been tested by measurement of the chemical reaction rate in the synthesis of methanol from carbon monoxide and hydrogen. The reactor behaves as a well-stirred tank, and data have been obtained at 3,000 lb./sq.in.abs. over the temperature range 300° to 400°C.Rate data have been obtained for commercial zinc chromite catalyst in particle form and for the commercial ¼-in. pellets. The effectiveness factors derived from these experiments have been used to estimate the tortuosity of the pellets; it is found to agree qualitatively with the value measured from experiments on pure diffusion in a catalyst pellet.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 65
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1055-1063 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A theoretical and experimental investigation of the separation achieved in a column crystallizer which utilizes a spiral conveyor was conducted to determine the effect of variables associated with continuous flow operation. A system that exhibits negligible solid solubility was used. Several feed mixtures containing less than 31,000 p.p.m. weight cyclohexane in benzene were employed. The principal variables evaluated in this study in a column of constant length were the feed position, internal crystal rate, and flow rates of terminal streams. A mathematical model is developed which considers axial dispersion and mass transfer between the liquid adhering to the crystals and the bulk liquid. The model satisfactorily explains the effect of the variables associated with continuous flow operation and shows that axial dispersion is more dominant in continuous flow than in total reflux operation. It is shown that multiple pass or cascade operation is necessary to produce material of purity higher than a critical level which is related to the feed composition. This occurs because of impurities in the crystal phase which are likely caused by volumetric inclusions.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 66
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1088-1091 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 67
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 979-984 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The effect of catalyst fouling on the stability and operation of adiabatic packed bed reactors was investigated for two poisoning mechanisms. The effect of fouling was found to be most predominant for packed beds in which nonunique pseudo steady states can exist. Fouling may cause the reactor to misbehave suddenly, with a violent temperature rise, after a long period of pacific operation.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
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  • 68
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1010-1015 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Laminar flow in helically coiled tubes is treated numerically. Fully developed axial and secondary velocities are calculated for both circular and elliptical cross sections. Only closely wrapped helices, that is, helices with modest pitch, are considered. Ten solutions with Deans numbers up to 200 have good accuracy. Two additional solutions with Deans numbers up to 280 are approximate.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 69
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1005-1010 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Free convection between two vertical coaxial cylinders was studied by solving the governing transport equations as an initial-value problem. The coupled, nonlinear, partial differential equations were converted into a set of difference equations by use of an alternating-direction implicit finite-difference numerical scheme. Twenty-four different combinations of Prandtl and Grashof numbers, and height to annular spacing ratios were used to characterize the problem. The results are presented primarily in the form of contour maps for the steady-state isotherms and streamlines.For Rayleigh numbers greater than 5 × 103, a fully developed boundary-layer flow was found to exist in the cavity. The interior region of the annulus was found to be thermally stratified and to possess a nearly uniform vertical temperature gradient, with a unicellular flow pattern being generated.With Rayleigh numbers of 5 × 104 and greater, it was found that the flow patterns could not be properly described with a grid spacing of 1/10. The variation of the steady-state mean Nusselt number with Prandtl and Rayleigh numbers and with geometric ratios was also investigated.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 70
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1030-1033 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental concentration profiles throughout a fourteen plate column approaching steady state at total reflux were obtained for mixtures of benzene, toluene, and ethylbenzene. The concentration profiles are characterized by a large movement of the middle component, toluene, through the column so that its maximum concentration shifts from plate to plate until steady state is reached.Computer runs were made in which the column variables were specified to be, as nearly as possible, those observed or calculated for the experimental runs. The computer results indicated the same behavior as the experimental runs, and the concentration profiles were in fair agreement. Thus, the computer model and calculation procedure used could replace the real column for many purposes. Inaccuracies in the computer simulation are due more to inadequate information about the characteristics of the real column than to deficiencies of the computer model.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 71
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1064-1071 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The photodecomposition of aqueous solutions of formic acid was studied as a model reaction for removing organic pollutants from water. The process was carried out in a tubular-flow reactor, operated continuously. The cylindrical reactor was irradiated from the outside by placing the cylindrical lamp and the reactor at the foci of an elliptical reflector. Measurements made at differential operating conditions permitted calculation of rates of reaction as a function of formic acid concentration and light intensity for the temperature range 25° to 60°C. Carbon dioxide and carbon monoxide were the only observed products of the decomposition.The rate was first order in absorbed light intensity and between zero and first order in formic acid. These results correspond to a combination of chain and non-chain kinetics occurring simultaneously. Rate constant ratios and quantum yields were calculated from the data and the kinetics model.A few measurements were made by adding ferric chloride and ferrous chloride to the feed to the reactor. An order of magnitude increase in rate was observed with these sensitizers.
    Zusätzliches Material: 7 Ill.
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  • 72
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970) 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 73
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 2-156 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 74
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 18-22 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Numerical integration of the coexistence equation for isothermal P-x data can be carried out by standard techniques. Two questions are considered with respect to this procedure: (a) Do continuous, analytic P-x relations exist which fail to provide thermodynamically acceptable results? (b) Does it matter from what point one starts the numerical integration? It is the purpose of this paper to demonstrate in each case that the answer is affirmative.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 75
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 44-48 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: This report describes a simple and reliable method of constructing small platinum film thermometers on Pyrex glass. The thermometers were used to measure surface temperature during nucleate boiling of water at pressures between 1 and 4 lb./sq.in. abs. The thermometers showed that as superheated microlayers of water evaporated beneath vapor bubbles, the surface temperature often dropped 40° to 75°F. before ultimately reaching the saturation temperature. The thermometers proved to be accurate (±1°F.) and capable of fast response (145°F./msec.).
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 76
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 64-69 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Normal pentane and isopentane were evaporated into nitrogen in laminar, concurrent flow in a rectangular channel. Composition profiles within the gas phase were measured, and the evaporation rates were compared with theoretical predictions with satisfactory agreement. The interfacial mole fraction of the evaporating species in the gas phase ranged as high as 0.74. A solution is reported for the Leveque problem under high flux conditions.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 77
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 90-96 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Exact solutions of the boundary layer equations were used to calculate the local mass transfer coefficients for an impinging jet with a parabolic velocity distribution. Boundary conditions were obtained from an inviscid flow solution and also from experimental pressure distributions. Experimental data for the air/naphthalene system were in good agreement with theoretical results. Mass transfer from the impingement surface was independent of nozzle height in the range 0.5 to 12 nozzle radii. For lower nozzle heights the effect of the constriction of flow between the nozzle and the surface led to increased transfer rates near the nozzle wall; data followed the predicted behavior.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 78
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 112-119 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A modified Redlich-Kwong equation has been applied to the calculation of phase equilibria in multicomponent systems. The two parameters of the Redlich-Kwong equation are treated as temperature functions. They are obtained for each pure component from experimental vapor pressures and liquid densities with the help of a generalized fugacity coefficient correlation for saturated vapors. The need to submit coefficients for pure components is thus eliminated. At least one experimental vapor-liquid equilibrium point is required to establish an interaction constant for each binary system. Applications have been made to binary and multicomponent systems containing hydrocarbons, hydrogen, carbon dioxide, and hydrogen sulfide.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 79
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 130-133 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The two-dimensional motion of two circular bubbles moving in train up through a fluidized bed is considered. By using continuum equations of motion for this two-phase flow situation, neutral coalescence curves are obtained which indicate, for given bubble radii and distance apart, whether or not the bubbles will coalesce. The conclusions are in agreement with the available experimental results.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 80
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 144-146 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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  • 81
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 149-149 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 82
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 153-155 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 83
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 173-177 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A general means is proposed for predicting transitional velocity patterns in concentric annuli and between parallel plates from behavior in tubes. As in laminar and turbulent flow, transformations of space coordinates yield identical profiles under specific conditions of comparison. Predictions are confirmed by published data and can be related to recent theoretical proposals.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 84
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 169-172 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The differential equation for diffusion of a solute in a quasi-homogeneous, spherical, ion exchange particle, previously solved for time-dependent boundary conditions, is applied to an activated carbon adsorption system. This solution differs from the infinite volume solution which assumes constant boundary conditions. The result is applied to experimental data and yields effective adsorbent-phase diffusion coefficients. Equilibrium and rate studies were performed by using the aqueous phenol solution - activated carbon system. The rigorous solution to the diffusion equation is compared with a recently published frequency domain solution. Excellent agreement is obtained for values of the effective diffusion coefficient computed from the two rate equations.It is recommended that the rigorous model be used for mechanism and diffusion coefficient determination. After the mass transfer parameters have been obtained, the simplified rate equation may be used for either lumped parameter or distributed parameter models for prediction of fixed-bed adsorber response. Further studies are required to determine if the simplified model adequately describes fixed-bed behavior.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 85
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 194-198 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An investigation of the mass and heat transfer equations describing radial and axial profiles for tubular reactors in laminar and plug flow is reported. Reactor conditions evaluated were isothermal, constant wall temperature, and adiabatic. Both diffusion and nondiffusion were considered. The reaction investigated was the demethylation of toluene in the presence of hydrogen.It was found that diffusion plays only a minor role in laminar flow for the conditions investigated. It was also found that isothermal and constant wall temperature reactor operation affected the temperature and concentration profiles very little when r/R was less than 0.6.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 86
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 224-229 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Hill's extremum principles are not directly applicable to an Ellis model fluid. A method of adapting Hill's principles to the Ellis model was developed and used to calculate upper and lower bounds on the drag coefficient for a sphere moving slowly through such a fluid. Available experimental data were compared with the average of the upper and lower bounds. Agreement was poor with Slattery's data and good with Turian's data. Some reasons to suspect Slattery's data have been pointed out.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 87
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 268-273 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Expressions are derived for the heat and mass transfer coefficients for laminar free convection driven by simultaneous differences in temperature and composition for the asymptotic cases of equal Schmidt and Prandtl numbers approaching zero, equal Schmidt and Prandtl numbers approaching infinity, Schmidt number approaching infinity and Prandtl number approaching zero, and Schmidt number larger than Prandtl number and Prandtl number approaching infinity.The results are applicable for horizontal cylinders or vertical axisymmetric bodies with arbitrary body contours insofar as the approximations of boundary-layer theory are valid. The results compare favorably with existing solutions and experimental results for particular conditions.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 88
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 286-292 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An experimental investigation was made of the absorption and scattering of thermal radiation by a cloud of small, spherical, micronsized, aluminum oxide particles in a plane-parallel enclosure. By using carbon tetrachloride and carbon disulphide as suspendign media, transmission measurements were made with collimated and diffuse sources for wavelengths from 2 to 11μ. By employing a two-flux diffuse model, the data were correlated to obtain absorption and back-scattering cross sections. From the diffuse and collimated data, a backscattering coefficient was found which varied linearly with relative refractive index. With the developed coefficients, the absorptivities of the cloud of particles were determined.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 89
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 305-314 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The oxidation of carbon monoxide with Hopcalite catalyst was studied in an isothermal recycling reactor with special attention paid to the changes of gas phase compositions with time.Conversion-time data exhibit significant departures from first-order behavior often ascribed to this reaction. In early stages the reaction rate declines more rapidly than would a first-order reaction; later the reverse is true. A mechanism, based on careful analyses of the literature and of our observations, is proposed. A kinetic model based on this mechanism is shown to reproduce the data of any run satisfactorily, but there is a considerable variation in values of the constants from run to run.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 90
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 321-324 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 91
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 332-334 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 92
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 339-344 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The present state of the theory of nonisothermal tube flow is inadequate to predict the behavior of polymer melts. In addition, relatively few experimental measurements on radial temperature profiles of polymer melts in the tube flow have been reported. For non-Newtonian systems, the separation of viscous losses due to frictional heat generation and those due to the effect of shear rate is a formidable problem which has hampered progress. This paper will describe a method of measuring shear induced heating and present experimental data on radial temperature profiles in tube flow. A novel method of estimating the velocity profile is also described.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 93
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 369-374 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The classical emulsion is made up of drops of one liquid dispersed in a containing liquid. Under certain circumstances, however, some of the containing phase may form drops within the drops of the dispersed liquid, giving rise to a structure known as a double-multiple emulsion. This study was an investigation of the hydrodynamic formation of these structures.Double-multiple emulsions were produced by using both transient and steady state liquid injection, with a cylindrical jet configuration. Analysis of the spray was by means of high-speed photography.The distribution of the large drops and that of the included drops were both found to be represented satisfactorily by a log-normal probability function. A simplified model based on the use of nozzle parameters satisfactorily correlated percent included area and volume as a function of Reynolds number and Weber number. Large dispersed phase drops contained proportionally many more inclusions than did the smaller sizes.The mechanism of inclusion formation was found to involve the drawing out of a ligament or sheet from the flowing jet, followed by the recoalescence of the free end of this ligament or sheet with the main jet body, entraining in the process a portion of the containing phase. Thus, the inclusions predate the formation of the drops of the dispersed phase from the jet disruption.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 94
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 405-410 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Facilitated transport is a process in which permeation through a liquid film is chemically augmented. Because of the scientific and engineering interest in this phenomenon, the purpose of this work was to carry out a detailed mathematical and experimental investigation of facilitated transport. The differential equations describing facilitated transport are presented, and a generally applicable numerical solution recently developed by G. M. Roe for this type of boundary value problem is summarized. The experimental investigation consisted of measuring the steady state rate of transport of nitric oxide through thin films of ferrous chloride solution and of determining independently the values of the system parameters of which the nitric oxide flux was a function. The experimental results were accurately predicted by using the model developed by Roe. This is the first demonstration of a general quantitative understanding of facilitated transport.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 95
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 436-441 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A model for the rheological behavior of thixotropic systems is presented. The model is intended for systems exhibiting no elastic or anisotropic effects. It is shown how the constants of the model can be determined by a systematic program of experimentation. It is also shown how the model can be tested and amended, if necessary, by the same program of experiments. The model is advanced for suspensions of rigid, solid particles in liquids; it is not expected to be valid for materials of polymeric constitution or for suspensions of elastic, deformable particles in liquids.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 96
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 464-471 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Heat transfer coefficients were measured for glass particles at the same wall surface of a fluidized bed for which glass particle residence times were measured in a previous study. The data compared well with theoretical predictions of the dependence of heat transfer coefficients on particle residence times. Heat transfer coefficients for metal particle systems, for which direct measurements of residence times were not available, were predicted with fair accuracy by estimating residence times from a dimensionless correlation proposed in a previous study. The ability of the particle surface renewal models to accurately predict heat transfer coefficients is strong evidence of their physical validity.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 97
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 483-489 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A flow visualization study was made with an optically birefringent solution of milling yellow dye in water flowing through a transparent duct of isoceles triangular cross section. The present data confirm a number of theoretical predictions concerning transitional phenomena in triangular ducts. One of the most interesting of these phenomena is the existence of a region of simultaneous laminar and turbulent flow in the duct. The present results, which agree with the theory, indicate an order of laminar and turbulent flow which is inverse to previous observations made with smoke filament tracings.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 98
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 499-499 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 99
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 505-506 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 100
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 536-538 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The inversion of sucrose by partially deactivated ion exchange resin catalysts has been studied in a fixed bed reactor under conditions where intraparticle diffusion of sucrose is slow. Results show that the reaction remains apparently first order for deactivated catalyst. Activity is directly related to hydrogen content of the resin and is also dependent on the nature of the ion used to poison the catalyst.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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