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  • 1985-1989  (708)
  • 1925-1929
  • 1986  (708)
  • Chemical Engineering  (708)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1036-1038 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1049-1051 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1053-1054 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1088-1098 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A restricted diffusion model is developed to study the immobilization of enzyme in porous solid supports. Simulation studies have been carried out for various combinations of process variables and parameters of the immobilization system. The model has also been used to develop a method for estimating the intrinsic rate constant of immobilization when enzyme diffusion into the support is restricted. Results of experiments in which glucose oxidase was immobilized in porous glass supports are consistent with model simulations.
    Additional Material: 11 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1253-1262 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A universally valid formal expression for the composition dependence of solute and solvent fugacity coefficients in any dilute binary system far from criticality is derived in this paper. In the present context, dilution denotes the y1 → O limit, regardless of the mixture's molar density. The results are independent of the system under study and of the choice of equation of state. The solute fugacity coefficient is simply the product of a composition-independent term (the infinite dilution fugacity coefficient) and an exponential decay composition correction. These two parameters have important thermodynamic implications: their temperature and pressure derivatives are related to the solute's partial molar enthalpy and volume, respectively. When applied to activity coefficients, the same theoretical analysis yields universal relationships for the composition dependence of activity coefficients which can be used as consistency checks for empirical correlations. The relationship between infinite dilution activity and fugacity coefficients can be used to estimate relative solubilities of a given solute in different solvents. Excellent agreement is found when the theoretical expressions are tested with three different binary systems involving a nonvolatile solid solute and a supercritical fluid.
    Additional Material: 5 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1301-1311 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model is developed to simulate the drying of hygroscopic porous media and, in particular, of wood. Drying rate experiments were performed using wood specimens and a nonhygroscopic porous ceramic solid and were simulated using the appropriate version of the drying model. Calculated model predictions are in very satisfactory agreement with experimental results. An examination of the relative impacts on drying of the transport mechanisms that comprise the model leads to meaningful interpretations of observed drying behavior. Controlling rate factors can be identified and different types of drying behavior specific to a given material or drying condition can be explained and understood through model simulation studies. Such capability can provide important guidance for drying process design and control.
    Additional Material: 9 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1347-1359 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The technique of distillation with intermediate heat pumps and optimal sidestream return - IHOSR distillation - is presented. IHOSR distillation allows heat to be moved between points in a distillation column with greater efficiency than several other methods of using heat pumps for distillation.
    Additional Material: 15 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1546-1554 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Deterministic analyses applied to both velocity and concentration fluctuation data obtained in a region extremely close to air-water interface in a free-surface, unbaffled stirred tank allow estimation of the length and the velocity scales of individual eddies taking part in gas absorption. The mass transfer prediction by this method is superior to that by a statistical method using an integral length scale in the low-turbulence flow employed in this work. Eddy velocities are generally lower in the diffusion boundary layer zone compared with the bulk zone. Small eddies are generally associated with low velocity scales whereas large eddies occur at high velocity scales. Local mass transfer coefficients are high in regions where small eddies are dominant.
    Additional Material: 10 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1561-1566 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1567-1569 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1570-1573 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 13
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An approach to air-lift reactor analysis is presented that examines the three parts of the air-lift - the riser, downcomer, and gas-liquid separator - as three interconnected and interrelated elements. Downcomer flow configurations are described and characterized by either straight or oscillating bubble flow patterns. The downcomer gas flow rate is determined using a two-sparger system, and a correlation is presented relating the downcomer superficial gas velocity to the downcomer gas holdup. Gas recirculation is calculated and related to the geometric and operating conditions of the gas-liquid separator. It is shown that an increase in residence time in the gas-liquid separator decreases the gas recirculation rate. Correlations are presented relating gas holdup and liquid velocities to superficial gas velocity.A sparger was added near the entrance of the downcomer, in addition to the conventional placement near the entrance of the riser. Results of such a two-sparger system are discussed in relation to reactor stability and liquid velocities.
    Additional Material: 10 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1642-1654 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model for the variance σc2 of instantaneous plume concentrations, at a level corresponding to that of the Gaussian formulas for the mean field, is developed and tested against available data. Starting from the Eulerian species transport equation, theoretical and empirical information is used to estimate parameters and simplify the form of the transport equation for σc2 in a meandering frame of reference. Then, introduction of a localized production of fluctuations (LPF) scheme allows construction of analytical expressions for σc2 that provide a direct means for calculating the concentration variance inside the instantaneous boundaries of plumes resulting from continuous point emissions in turbulent flows with uniform mean velocity.
    Additional Material: 7 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1665-1676 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A procedure is presented for designing supercritical gas extraction processes using a pure solvent fluid to effect the separation. The necessary conditions for the procedure to be applicable are the existence of crossover behavior and separable crossover pressures in the fluid phase mixture. Data are presented to support the existence of such phenomena in ternary systems, and an actual separation process has been designed and operated based upon the data. For systems exhibiting this behavior, process synthesis principles are developed to illustrate the evolution of a process flowsheet for the separation of a mixture into its pure components.
    Additional Material: 15 Ill.
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  • 16
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1677-1689 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Multiple hydrodynamic states were observed during cocurrent down-flow of air and water under trickling flow conditions in a packed bed of rectangular cross section. Although the multiplicity was exhibited by both pressure gradient and liquid holdup, the pressure gradient showed the largest variations at identical conditions. The multiplicity is interpreted as being due to the liquid flowing in two different modes, namely, film flow and rivulet flow.The characteristics of pulsing flow in a packed bed of rectangular cross section were found to be appreciably different from those reported in the literature for flow in small-diameter cylindrical columns. The most significant observation in the packed bed of rectangular cross section was that the pulses did not always span the column cross section, unlike the case in small-diameter columns. The lower pressure drop and pulse velocity in the packed bed of rectangular cross section are believed to result from the bypassing of gas around the edge of the pulses. The location of the pulses was found to depend on the quality of gas and liquid distribution at the top of the column, and the shape of the top surface of the packing. A distributor configuration in which the gas was injected directly into the bed was found to be the most desirable, and is recommended in industrial practice.
    Additional Material: 19 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1971-1979 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bimolecular QRRK (Quantum Rice-Ramsperger-Kassel) analysis is a simple method for calculating rate constants of addition and recombination reactions, based on unimolecular quantum-RRK theory. Input parameters are readily derived, and rate constants and reaction branching can be predicted with remarkable accuracy. Such predictive power makes the method especially useful in developing mechanisms of elementary reactions. Furthermore, from the bimolecular QRRK equations, limiting forms of the rate constants in the limits of low and high pressure are developed. Addition/stabilization is pressure-dependent at low pressure but pressure-independent at high pressure, as is conventionally understood for simple decomposition, its reverse. In distinct contrast, addition with chemically activated decomposition has the opposite behavior: pressure independence at low pressure and pressure dependence [as (pressure)-1] at high pressure. The method is tested against data and illustrated by calculations for O + CO → CO2; for H + O2 → HO2 or O + OH; for H + C2H4 → C2H5 or C2H3 + H2; and for H + C2H3 → C2H4 or H2 + C2H2.
    Additional Material: 9 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 2020-2027 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model of multicomponent permeation systems with high-flux, asymmetric hollow-fiber membranes is presented. The model takes into account the permeate pressure variation inside the fiber. In the special case of negligible permeate pressure drop, the model yields a simple analytical solution for membrane area calculation that eliminates the numerical integration step required in existing methods. Laboratory multicomponent permeation experiments have verified the mathematical model and have demonstrated the technical feasibility of using the high-flux asymmetric cellulose acetate hollow fiber for H2, CO2, and H2S separation. It is shown that the selectivity of the cellulose acetate membrane is ideally suited to the recovery of hydrogen from the purge gas of reactor recycle loops. For the separation of high-concentration CO2 or H2S, the test data show that the permeabilities of the individual components in mixed gas permeation are significantly different from those of pure gases.
    Additional Material: 7 Ill.
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  • 19
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 2067-2078 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dew points of 40 multicomponent fluid mixtures including gas condensates, absorber oils, crude oils, synthetic aromatic heavy oils, and coal liquids were calculated using the method of continuous thermodynamics and the Patel-Teja cubic equation of state. These multicomponent mixtures were characterized by a log normal distribution function in two variables: the boiling point and specific gravity in this work. Comparisons were made with the case when a single variable distribution function is employed and also with the method of Cotterman et al. In general, the new method leads to excellent predictions of both phase equilibria and liquid densities.
    Additional Material: 2 Ill.
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  • 20
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 353-368 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The hydrodynamics of trickling flow in packed beds is modeled by representing the porous medium as an array of parallel conduits of circular cross section.First, a straight tube model is developed and analytical solutions are obtained for the relative permeabilities of the gas and liquid phases. Then a periodically constricted tube model is proposed and the equations of motion are solved numerically to determine the effect that surface tension forces have on the relative permeabilities. The constricted tube model predicts that the relative permeabilities of the phases are appreciably sensitive to surface tension forces, a prediction that seems at odds with experimental observations. This discrepancy may be caused by the assumption of fully wetted surface area of particles employed in the model.The straight tube model confirms experimental results indicating that the liquid phase relative permeability is, for practical purposes, insensitive to the gas flow rate and to the gas-to-liquid density and viscosity ratios. Both conduit models show that the gas phase relative permeability curves are strong functions of the gas phase Reynolds number when this parameter is small. For large gas Reynolds numbers, a single curve for the relative permeability as a function of saturation is obtained. These trends are observed in previous experimental studies.
    Additional Material: 15 Ill.
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  • 21
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 369-380 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The liquid holdup and the pressure drop for two-phase trickling flow in a packed bed were measured experimentally. Different values of those parameters were obtained as the liquid flow rate was increased and then decreased, indicating a multiplicity in hydrodynamic states. This behavior was observed even when the gas flow rate was zero in the bed. It was determined that the hysteresis exhibited by the process is due to imperfect wetting of the packing and to the difference between advancing and receding contact angles at the gas-liquid-solid contact lines. The reduced wetting conditions are also the cause of the increase in liquid holdup observed when the surface tension of the liquid is decreased. In this case, the amount of liquid retained in the bed is controlled by the extension of the wetted regions due to the more favorable contact angles as the surface tension decreases. The transition from the trickling to the pulsing flow regime was also dependent on the history of the process.A new correlation for predicting liquid holdups and pressure drops for trickling flow in packed beds is proposed for the decreasing liquid flow rate operating mode. This correlation is based on the experimental determination of the liquid phase relative permeability as a function of the the liquid phase reduced saturation and the determination of the gas phase relative permeability as a function of the gas phase saturation and the gas phase Reynolds number. The new data are analyzed in the light of the theory developed in the first part of this paper.
    Additional Material: 15 Ill.
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  • 22
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 444-454 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The electrolyte nonrandom two-liquid (NRTL) model proposed by Chen et al. (1982) is generalized to represent the excess Gibbs energy of aqueous multicomponent electrolyte systems. Using only binary parameters, the model correlates and predicts the deviation from ideality of aqueous multicomponent electrolyte systems over the entire range of temperature and concentration.
    Additional Material: 5 Ill.
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  • 23
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 751-764 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes reactive flow in permeable media based on a numerical model that assumes local thermodynamic equilibrium. The model simulates single-phase, one-dimensional flow with greater generality than any model in the current literature. The mathematical foundation for the formulation is discussed in some detail. Results for hypothetical examples demonstrate that ion exchange and precipitation/dissolution of solids can interact to produce wave behavior not possible with either phenomenon alone. An important application involving both ion exchange and precipitation/dissolution is alkaline flooding. Model predictions for several laboratory alkaline floods indicate that the assumption of equilibrium is justified for these experiments. Simple calculations based on the equilibrium theory provide estimates of pH loss and hydroxide penetration distance.
    Additional Material: 12 Ill.
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  • 24
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 782-788 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Lagrangian dispersion function in turbulent flow can be determined from measurements of the probability that a particle which is observed in a small volume is not observed in a similar size volume downstream. In this work a single-detector method is proposed to detect the particle arrivals in a multiple series of scattering volumes; the probability can be determined from the digital record over a long time compared to the turbulent integral time scale. The method is tested at locations downstream of a water spray nozzle and a submerged jet of dilute polymer solutions.
    Additional Material: 3 Ill.
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  • 25
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 809-819 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general theory is presented for the prediction of effective axial conductivity and overall radial heat transfer coefficient for fluid flow through packed beds, under either transient or steady state conditions. The parameters to be used in each case may be quite different, depending on the dominant phase for heat transfer. The theory unifies all previous results and explains conflicting conclusions arrived at by different workers. The ability of a pseudohomogeneous model to reproduce packedbed transients is shown to depend upon the choice of effective parameters.
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  • 26
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 829-843 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Upward cocurrent gas-liquid annular flow was investigated in a 50.8 mm ID cylindrical vertical pipe. The film flow was studied by measuring instantaneous local film thickness, wall shear stress, and pressure gradient. Analysis of these data revealed that at low gas flow rates the film motion is controlled by a switching mechanism, as speculated by Moalem-Maron and Dukler (1984). In the region of high gas flow rates the switching process is suppressed and traveling roll waves characterize the film motion.
    Additional Material: 33 Ill.
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  • 27
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1403-1403 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 28
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1403-1404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 29
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1558-1560 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 30
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 914-931 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new high-performance multivariable time delay compensator is presented that contains the Ogunnaike-Ray compensator as a special case, reduces to the Smith predictor for a single delay, and approaches the realizable part of the process inverse as a limit. The straightforward design procedure is illustrated with several distillation control examples.
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  • 31
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 971-980 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A separation theory in thermal diffusion columns with a permeable vertical barrier has been derived by making use of the orthogonal expansion method. It is shown that the undesirable remixing effect can be effectively reduced and controlled by introducing a permeable vertical barrier. Considerable improvement in separation was obtained when the position of the barrier was carefully chosen.
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  • 32
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 981-990 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: To identify conditions under which gas-liquid reaction systems exhibit natural oscillations, a model is formulated in which the time scales of the elementary processes play a leading role. The steady solutions of the model problem are investigated, with the finding that at most one solution may lie in each of five temperature ranges, each range corresponding to a dominant physicochemical process.
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  • 33
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1027-1035 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 34
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1015-1024 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The multiinput/multioutput pole-placement self-tuning controller (MIMO PPSTC) previously developed by McDermott and Mellichamp is used to control a fixed-bed autothermal reactor with internal countercurrent heat exchange. The performance of the controller is demonstrated using step changes in the set points and in the primary disturbance variables. It is shown that the complete temperature profile can be maintained by controlling two temperatures in the catalyst bed: one just before the hot spot and the other at the exit of the bed. Simulated results using a 36th-order nonlinear reactor model operating at both an open-loop upper stable steady state and an open-loop unstable steady state are presented. Experimental results for a fixed-bed autothermal reactor operating at an upper stable state are presented.
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  • 35
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    AIChE Journal 32 (1986), S. 1053-1053 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 36
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    AIChE Journal 32 (1986), S. 1055-1056 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 37
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    AIChE Journal 32 (1986), S. 1057-1066 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Various ways of building quasi-Newton matrix approximations that satisfy the special form of the Gibbs-Duhem equation are studied. Partition symmetry, the separability of the functions in γ and in φ, and the method of iterated projections are used in order to develop thermodynamically consistent matrix approximations with good secant information. Many examples are presented which show that exploiting the special form of the Gibbs-Duhem equation results in improved numerical performance. Ways of exploiting the Gibbs-Helmholtz equation in addition to the special form of Gibbs-Duhem equation, and thus the isobaric form of the Gibbs-Duhem equation, are also discussed.
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  • 38
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    AIChE Journal 32 (1986), S. 1099-1107 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A continuous, staged-feed column crystallizer was investigated to obtain enlarged product size distribution in precipitation from solution. Stage population balances, in moment form, were solved analytically for several single-feed configurations. It was found that internal staging permits control of the solids concentration profile, and if collision nucleation is unimportant then countercurrent operation yields the greatest product size enlargement. Nucleation kinetic parameters for a given salt indicate the potential product size improvement, compared to product from an MSMPR crystallizer of equal volume.
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  • 39
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    AIChE Journal 32 (1986), S. 1116-1124 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model that describes fractionation with condensation and evaporation in a plate-fin device has been formulated. It is capable of evaluating profiles of composition, temperature, and flow rate for both liquid and vapor streams in an extended surface device. The device may be adiabatic or nonadiabatic and the surface may be incompletely wetted. Compared to experimental measurements, the model predictions showed ± 1 number of transfer unit deviation along the length of the device. The predictions of the top and bottom flow rate ratio showed a 5-10% deviation for adiabatic and condensation runs and a 25% deviation for evaporation runs.
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  • 40
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    AIChE Journal 32 (1986), S. 1138-1145 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A recently developed error-in-variables method of calculating regression parameters was applied to the modeling of gas-solid adsorption equilibria. The method accounts for error in all experimental variables in the regression calculations. Regression coefficients from pure component data calculated by the new method were used to predict multicomponent equilibria. The multicomponent predictions using pure component parameters calculated by the error-in-variables method were more accurae than predictions using parameters calculated by conventional least-squares regression.
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  • 41
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    AIChE Journal 32 (1986), S. 1158-1168 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Nonlocal models for the surface transport of adsorbed gases on solids are proposed and compared to experimental data. These models take into account connectivity effects due to heterogeneous adsorption potential surfaces and introduce a more realistic calculation of the surface mean free path.
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  • 42
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The tendency for aggregation and disruption of aggregates of calcium oxalate dihydrate (CaOx) crystals in urinelike mother liquor was quantitatively studied in a two-stage mixed-suspension, mixed-productremoval crystallizer/Couette-flow aggregator operated in series. The degree of aggregation was obtained by comparing measured numbersize and volume-size crystal distributions in the crystallizer and aggregator outlets. Aggregation was a strong function of CaOx supersaturation and may have changed slightly with rotation speed in the Couette-flow aggregator. Rupture of the aggregates increased as the spindle rotation in the aggregator increased (presumably increasing turbulence). Average shear rates in these experiments were appreciably above estimated physiological levels.
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  • 43
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    AIChE Journal 32 (1986), S. 1205-1207 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 44
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    AIChE Journal 32 (1986), S. 1216-1220 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 45
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    AIChE Journal 32 (1986), S. 1227-1229 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 46
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    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 47
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    AIChE Journal 32 (1986), S. 1242-1252 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Multiresponse kinetic models are established for the low-temperature oxidation (LTO) reactions of Athabasca oil sands bitumen. The models provide adequate description of the overall rate of oxygen consumption and of the reactions of the liquid phase bitumen components. The LTO models are suitable for use in the in situ combustion numerical simulators of the oil sands.
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  • 48
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    AIChE Journal 32 (1986), S. 1277-1287 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Based on the concept of reactions in a continuum, a mathematical model has been developed to simulate coal liquefaction kinetics. In an excess hydrogen donor environment, the rate-limiting reactions are considered to be irreversible cracking reactions involving cleavage of carbon and oxygen linkages. Concurrent evolution of a wide spectrum of products, with an initial rapid formation of species of high carbon and oxygen contents, followed by progressively slower reactions leading to lower carbon and oxygen content species is predicted. Simple lumping functions are employed to obtain conventional lumped pseudocomponents (preasphaltenes, asphaltenes, and oils). Parameter analysis has been carried out.
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  • 49
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    AIChE Journal 32 (1986), S. 1312-1320 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The yield of a nonpremixed series-parallel reaction at complete conversion was measured in a turbulent, tubular-flow reactor with single and multijet feeds. The yield of the intermediate decreased as mixing was slowed relative to the chemical kinetics, either by decreasing the Reynolds number, or by using a less efficient mixing device, or by increasing the feed concentration.Four models, a modified slab model, a modified stretch model, the Harada mass transfer model, and a new closure model, adequately predict the yield when chemical and mixing kinetics are known from independent measurements of the conversion of acid-base reactions. Without modification, the original slab and stretch models are unable to account for the earlier observed invariance of conversion to Schmidt number of very rapid, single-step reactions or to satisfactorily predict the yield of the series-parallel reaction.
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  • 50
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    AIChE Journal 32 (1986), S. 1334-1346 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A receding interface model of the drying of single drops of slurries of sodium sulfate decahydrate has been developed to describe the drying characteristics of this material and to estimate the drying rates of particulate slurries. The simultaneous heat and mass transfer rate equations have been solved numerically, and the results obtained have been compared with those obtained experimentally by drying single drops suspended on the tip of a glass filament.Single drops of slurries, 1.0 to 1.5 × 10-3 m dia., were suspended on the tip of a flexible glass cantilever inserted in a vertical wind tunnel. A 50μm dia. nickel wire passed through the center of the glass beam and the outer surface was coated with a thin film of copper, thereby forming a thermocouple that measured the temperature of the core of the drop; the deflection of the beam gave the loss in weight during drying. In this way the instantaneous drying rate and drop temperature were determined and compared with those predicted by the receding interface model. In all cases the agreement between the predictions of the model and experimental results was good.
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    AIChE Journal 32 (1986), S. 1360-1366 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Methods are presented to determine structural identifiability and distinguishability of parametric models. Results are applied to transient isotope tracing of methanation over a nickel catalyst. More meaningful information is obtained in this way about fundamental parameters than is possible by empirical curve-fitting.
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    AIChE Journal 32 (1986), S. 1389-1392 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 53
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  • 54
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    AIChE Journal 32 (1986), S. 1402-1402 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 32 (1986), S. 1403-1403 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 56
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    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 57
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The overall nonideality of an aqueous mixed electrolyte solution is characterized in terms of a newly defined parameter Γ*, called the overall reduced ionic activity coefficient. It is shown that Γ* for the mixed solution is simply related to the properties of single-electrolyte solutions. Γ* is related to the vapor pressure of a mixed-electrolyte solution through well-known thermodynamic equations. This leads to a predictive equation for the vapor pressure of a mixed-electrolyte solution in terms of the vapor pressures of single-electrolyte solutions of the components. This equation is valid over the entire concentration range encountered in practice, without any empirical constants, and has a predictive accuracy of 2%. A predictive equation for the latent heat of vaporization is also developed and tested against experimental data.
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    AIChE Journal 32 (1986), S. 1450-1458 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Urea adsorbs on the ruthenium titanium oxide electrode, depressing the observed current. For artificial kidney dialysate concentrations of urea and NaCl (0.50 kg/m3 and 100 mol/m3, respectively), the major electrolysis products are N2, CO2, O2, and H2, and the reaction mechanism is solution oxidation of urea by anodically generated active chlorine. A nitrogen-yielding direct electrode reaction is observed at high urea concentration (30 kg/m3) and low NaCl concentration (10-100 mol/m3).
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  • 59
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    AIChE Journal 32 (1986), S. 1466-1482 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A rule of hydrodynamic similarity for a scale change of fluidized beds has been developed based on the governing equations of bubble and interstitial gas dynamics. When geometrically similar scale-up is to be carried out maintaining hydrodynamic similarity, the proposed similarity rule requires that two conditions be satisfied. The first condition assures a similarity in bubble coalescence. The second assures the similarities in bubble splitting and in the interstitial flow pattern. The present work proves theoretically that these two conditions are the necessary, and almost sufficient, conditions for hydrodynamic similarity. They consider not only bubble coalescence but also bubble splitting. The theory proposed was first tested by previous correlations for bubble diameter and grid zone structure, and second by experiment. It has been proved that as long as the present rule is satisfied, the longitudinal distribution of the average bubble diameter, stochastic variation around it, and the radial distribution of superficial bubble velocity can be maintained similar for a scale change.Application of the present rule to predict the bubbling and solid circulation characteristics in a large-scale unit by a small-scale experiment has thus proved promising, at least for Geldart group B particles. In order to further study the possibility of a similarity in mass transfer and chemical reactions, computation was carried out using the three-phase bubble assemblage model. If the effect of molecular diffusion is negligible, as in the case of fluidized bed combustion, even a chemical similarity is found to be possible.
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    AIChE Journal 32 (1986), S. 1491-1499 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The sulfation model of Simons and Rawlins (1980) is extended to include the effect of product deposits. The model includes: 1. the plugging of the smallest pores and the subsequent loss in the internal surface area, 2. the diffusion of the SO2 through the product deposits, and 3. the loss of intraparticle diffusion due to the complete plugging of the largest pores. It is shown that the plugging of the smallest pores is generally rate-controlling.
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    AIChE Journal 32 (1986), S. 1516-1525 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Kynch's theory of sedimentation is adopted to solve for the attainable steady state concentration in a vertical continuous sedimentation basin incorporating a thickener and a clarifier. The limiting flux solution corresponding to the local minimum at the flux concentration curve is proved to have a limited range of validity and is shown to apply only to the intermediate range of feed concentrations. This limit is replaced by a five-region diagram; the solution is determined by the feed coordinates in the flux concentration plane, with respect to the flux concentration curve. Each section exhibits different characteristic solutions for both the clarifier and the thickener.The analysis, which combines dispersion, dynamics, and stability considerations, reveals new possible ranges of operating conditions where the flux exceeds the limiting flux and solids are not entrained. The results, contradicting previous published work, are verified by a finite-difference dynamic simulator.
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    AIChE Journal 32 (1986), S. 1526-1531 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Using the zeolite ZSM-5, new technology has been developed for catalytically oligomerizing light olefins (C3 to C4) to gasoline (C5 to C10) and diesel (C10 to C20) range product. This reaction produces product constrained by both the shape selectivity of the zeolite catalyst and the thermodynamics governing the oligomerization reaction.
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    AIChE Journal 32 (1986), S. 1555-1557 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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    AIChE Journal 32 (1986), S. 1574-1578 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 32 (1986), S. 1597-1605 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical analysis has been performed to elucidate the relationship between two popular time delay compensation techniques, the Smith predictor and the analytical predictor. In general, use of these two techniques results in different closed-loop responses. It is only for the special case where the process model is perfect and set point changes occur, that the two techniques are equivalent. A modification of the analytical predictor has been proposed that allows the technique to be used with any feedback controller, instead of the special PI controller employed by Moore et al. (1970).
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    AIChE Journal 32 (1986), S. 1606-1611 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is proposed for calculating aerosol collection in the jet region of fluidized filters with sieve plate distributors. With the use of the model proposed earlier by Lefroy and Davidson and a new correlation for the single-collector efficiency, which was established as part of this study, a compartment-to-compartment procedure was developed for estimating aerosol collection. The results were compared with experimental data for model validation.
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    AIChE Journal 32 (1986), S. 1655-1664 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The electrolyte nonrandom two-liquid model proposed by Chen and Evans provides a thermodynamically consistent framework for representation of the phase equilibria of mixed-solvent electrolyte systems. Using only binary adjustable parameters, the model satisfactorily correlates the vapor-liquid equilibrium and liquid-liquid equilibrium of mixed-solvent electrolyte systems over the entire range of temperature and concentrations.
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    AIChE Journal 32 (1986), S. 1690-1701 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method is described for detecting and locating a leak in a gas transport pipeline lying between two pump stations by an indirect acoustic method. The basic concept is to treat the pipeline as an acoustic tube (similar to a wind instrument), and to estimate the impulse response of the acoustic wave in the pipeline solely from the acoustic signal detected at two terminal sites in the pipeline. The test signal introduced at the input site is only acoustic noise; pipeline operation need not be interrupted. If a leak occurs in the pipeline, the impulse response of the acoustic wave in the pipeline has a sharp pulse or a step at a certain time that can be directly related to the site of the leak. Using the mathematical model of the pipeline acoustics, i.e., the wave equation, a theoretical basis is developed to explain how and why the leak can be detected and located. Experiments carried out in the laboratory under conditions comparable to realistic field conditions demonstrate the validity of the proposed detection method.
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    AIChE Journal 32 (1986), S. 1716-1725 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The perturbed anisotropic chain theory (PACT) developed by Vimalchand and Donohue has been generalized to treat pure fluids that associate through hydrogen bonding, as well as mixtures of one associating component and several diluents. Using an approach similar to that of Heidemann and Prausnitz, a closed-form equation of state has been derived. It is applicable to simple as well as complex molecules at both gas and liquidlike densities and takes into account dipole and/or quadrupole moments. Molecular parameters were obtained by fitting the equation to experimental liquid density and vapor pressure data.
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    AIChE Journal 32 (1986), S. 1747-1749 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 32 (1986), S. 1754-1759 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 72
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    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 73
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The two-scale turbulence concept is recommended for modeling the turbulence in a baffled vessel equipped with a Rushton-type turbine impeller. A three-equation isotropic turbulence model is proposed that employs the balance equations for: the kinetic energy of the large scale vortices; the kinetic energy of the inertial subrange eddies; and the dissipation rate of the small-scale turbulence. The energy transfer rate from the large-scale vortices is prescribed algebraically. Flow patterns are modeled by solving the transport equations for vorticity, stream function, and tangential momentum. The Reynolds stresses are modeled by means of the effective viscosity, based on the three-equation model of turbulence. The calculated profiles of the mean velocity at the tank wall agree with experimental data obtained in the same system by means of a Pitot tube.
    Additional Material: 14 Ill.
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  • 74
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    AIChE Journal 32 (1986), S. 1813-1820 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A computer program designed to model the turbulent reacting flow in jet-stirred reactors has been developed. In solving the single-phase flow field, a two-equation turbulence closure was used to predict the turbulent eddy viscosity variation in the reactor. The model was used to predict the performance of a real reactor. The predicted results compared favorably with measurements in the field. It was found that the key to the reactor performance is the strength of the recirculating eddy caused by the jet entrainment.
    Additional Material: 7 Ill.
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  • 75
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    AIChE Journal 32 (1986), S. 1839-1847 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rates of hydration of isobutene were measured with Amberlyst-15 catalyst particles in a differential, liquid-full recycle reactor operating at atmospheric pressure and 303 to 333 K. Catalysts pretreated in two different ways were studied. Liquid-to-particle mass transfer had a small but measurable effect on the rate. Intraparticle diffusion was more significant, as indicated by effectiveness factors from 0.26 for the larger catalyst particles (dp = 1.04 × 10-3 m) at 333 K to 0.84 for the smaller particles (dp = 0.45 × 10-3 m) at 303 K. The intrinsic rate was first-order in isobutene concentration with an activation energy of 67 kJ/mol. The intraparticle diffusion resistance is due to the macropores surrounding the very small gel-type microparticles of which the particles were composed.Some data were obtained for reaction rates in trickle-bed operation. Global rates were somewhat lower in the trickle-bed operation than in the liquid-full runs. Using the previously determined intrinsic kinetics and effectiveness factors, the liquid-to-particle mass transfer coefficients could be approximated for the trickle-bed operation.
    Additional Material: 8 Ill.
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  • 76
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    AIChE Journal 32 (1986), S. 1864-1875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes a study of the possibility of using point efficiencies, measured in a small laboratory column, in the scale-up of distillation efficiencies. The conditions on a large rectangular tray were closely duplicated in a small glass Oldershaw column with one sieve tray having similar hole size and percent free area. Point efficiencies on the large rectangular sieve tray were deduced from the composition profiles and compared with the point efficiencies measured in the small column. A simple relationship between the two columns was found in terms of the froth heights and liquid holdups. The results demonstrate that the slightly lower point efficiencies measured in the Oldershaw column could be used in conjunction with a mathematical mass transfer model based on the eddy diffusion concept, to relate the point efficiencies to the tray efficiences, resulting in a conservative design provided either that allowance is made for other factors, such as nonuniform flow patterns and stagnant zones, or that these are eliminated. A wide range of composition was covered using the two systems MeOH-nPrOH and EtOH-nPrOH operating in the froth region.
    Additional Material: 20 Ill.
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  • 77
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    AIChE Journal 32 (1986), S. 1889-1901 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The separation of a He—CH4 mixture containing 9.95 mol% He in permeator modules that incorporate two different types of polymer membranes was studied theoretically and experimentally. The membranes were symmetric dense capillaries of silicone rubber and asymmetric hollow fibers of cellulose triacetate. These membranes exhibit reverse selectivities for He and CH4, silicone rubber being more permeable to CH4, and cellulose triacetate more permeable to He. The simultaneous use of these two types of membranes in a permeator enhances the enrichment and recovery of He compared to the levels obtained with a single-membrane permeator utilizing either membrane alone. The experimental results were found to confirm the theoretical predictions, the agreement being better at the lower stage cuts.
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  • 78
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    AIChE Journal 32 (1986), S. 1917-1919 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 79
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    AIChE Journal 32 (1986), S. 1928-1930 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 80
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    AIChE Journal 32 (1986), S. 1935-1935 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 81
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    AIChE Journal 32 (1986) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 82
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    AIChE Journal 32 (1986), S. 1948-1953 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Elution times determined from perturbation chromatography experiments are functions of all sorbing species isotherms through the concentration partial derivatives. Measurements at a sufficient number of appropriate compositions along with isotherm models and adjustable parameters allow reduction of the retention time data to VLE by a nonlinear parameter estimation procedure described in this paper. The method can be implemented for both empirical isotherm models, which can be used to minimize model deficiencies, and for theoretical thermodynamic models, which have extrapolation potential and may require fewer parameters.
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  • 83
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    AIChE Journal 32 (1986), S. 1963-1970 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: One hundred sets of R-11 two-phase pressure drop and boiling heat transfer data are reported for cocurrent down-flow over an in-line tube bundle. The pressure drop data agree with predicitions using the Diehl correlation. A new heat transfer correlation is reported, accounting for the observed convective and nucleate mechanisms.
    Additional Material: 11 Ill.
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  • 84
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    AIChE Journal 32 (1986), S. 1988-1993 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Infinite dilution activity coefficients of aroma compounds from various chemical series were measured in model food systems (water/carbohydrates, water/polyethylene-glycols) at concentrations of various solutes. These measurements were made with a specially designed equilibrium cell. Experimental results were used to determine the parameters of group contribution thermodynamic models. The predictive capacities of the equations obtained were shown to be quite precise (8% mean deviation).
    Additional Material: 3 Ill.
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  • 85
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    AIChE Journal 32 (1986), S. 1980-1987 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Three different pore size CoMo/Al2O3 catalysts, which had been deactivated to the same extent during bench-scale tests with an atmospheric resid, were examined for coke and metal deposits, diffusivity, and intrinsic activity for hydrodesulfurization, hydrogenation, and hydrodenitrogenation using model compounds. The aged catalysts had very low effective diffusivities and lower intrinsic activities than the fresh catalysts. Both metals and coke deposits were responsible for lowering diffusivity, but activity reduction appears to be predominantly due to metal deposits.
    Additional Material: 7 Ill.
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  • 86
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    AIChE Journal 32 (1986), S. 1994-2001 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Macroscopic behavior of solids circulation in a large jetting fluidized bed was surveyed with a force probe. Particles mixing was studied by pulse injection of tracer particles, and a simple mechanistic model was developed on the basis of the solids circulation pattern observed. The model compares favorably with experimental tracer concentration profiles.
    Additional Material: 14 Ill.
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  • 87
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ultrafine spherical titanium, silicon, and aluminium oxide particles were prepared by the thermal decomposition of their alkoxide vapors, produced by evaporation and subsequent heating. High-concentration ultrafine particles having geometric mean diameters ranging between 0.01 and 0.06 μm and a geometric standard deviation of about 1.4 were obtained by varying the temperatures of the evaporator containing the liquid alkoxides and the reactor furnace, and the flow rate of carrier gas. For furnace temperatures lower than 400°C for TiO2 and 1000°C for SiO2 and Al2O3, the particles obtained were found to be amorphous. The observed changes in the particle size distributions due to changes in operating conditions were compared with those predicted theoretically by solving the discrete-continuous aerosol general dynamic equation accounting for coagulation and generation of monomer by thermal decomposition. The effect of monomer number concentration on the size distribution of generated particles was found to be qualitatively explained.
    Additional Material: 17 Ill.
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  • 88
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    AIChE Journal 32 (1986), S. 2034-2046 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The different behavior of fluid density and viscosity in going from the dilute gas to the dense fluid state gives rise to kinematic viscosities which, in the near supercritical region, are lower than for liquid metals. As a consequence, the relative importance of natural convection (as measured by the ratio of buyoant to inertial forces) is two orders of magnitude higher in a supercritical fluid (at constant Reynolds number) than in normal liquids.Binary diffusion coefficients of nonvolatile solutes in supercritical fluids were measured with a technique that involved laminar flow and diffusion in a rectangular channel. The solution to this hydrodynamic problem is presented. By varying the inclination of the solute source plane with respect to the horizontal position, apparent diffusion coefficients were measured that were up to six times higher than the “true” coefficients.Experimental binary diffusion coefficients, including published literature data, were analyzed in the light of hydrodynamic (Stokes-Einstein) theory. The analysis suggests that under the high-density, low-viscosity conditions that characterize supercritical fluids, hydrodynamic behavior at the molecular level is approached, and can be used as a basis for data extrapolation.
    Additional Material: 15 Ill.
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  • 89
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pulse-response data for the hydrogenation of α-methyl styrene were obtained as a function of poisoning of the Pd/Al2O3 catalyst. The reaction is a first-order, reversible adsorption of hydrogen followed by a first-order, irreversible surface reaction. The experiments, at 298 to 323 K and atmospheric pressure, were carried out in a three-phase slurry reactor for which mass transport effects could be accurately accounted.Independent adsorption equilibrium data in cumene slurries showed that adsorption occurred to the same extent on both poisoned and unpoisoned sites with a heat of adsorption, ΔHc = -16.3 kJ/mol. Converted to styrene as the slurry liquid, ΔHs = -20.9 kJ/mol.The zero and first moments of the response curves indicated that the rate constant for the surface reaction was independent of the extent of poisoning. The analysis required developing a new theory for interpreting dynamic data where reactant adsorption occurred on both poisoned and unpoisoned sites. The rate constant (per unit mass of catalyst) for adsorption decreased continuously to zero as the extent of poisoning increased.The results are consistent with the concept that poisoning reduced the number of sites active for reaction, but that the activity per site for the surface reaction was constant. However, the activity per site for adsorption, while constant at poison levels up to 40%, appeared to decrease sharply at higher levels.
    Additional Material: 10 Ill.
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  • 90
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    AIChE Journal 32 (1986), S. 2083-2086 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 91
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    AIChE Journal 32 (1986), S. 2087-2090 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A detailed study has been made of the computing times for several common equations of state used by industry. The cubic equations are approximately equivalent to more complicated equations (e.g., perturbed hard chain and BWRS) for systems with eight or more components. Thus, it is not justified to choose cubic equations over other forms purely on the basis of computational advantage. Further, the study identifies mixing-rule summations as the dominant consumer of computing time.
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  • 92
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    AIChE Journal 32 (1986), S. 2095-2098 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 93
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    AIChE Journal 32 (1986), S. 1211-1215 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 94
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    AIChE Journal 32 (1986), S. 1224-1226 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 95
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    AIChE Journal 32 (1986), S. 1231-1232 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 96
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    AIChE Journal 32 (1986), S. 1233-1241 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper investigates the application of spatially adaptive numerical methods in the solution of one-dimensional premixed combustion problems. The selection of grid points by equidistribution of positive weight functions across consecutive mesh intervals is considered. The method is applied in the solution of a steady premixed laminar flame problem and a time-dependent freely propagating flame problem. The adaptive numerical results are compared with corresponding equispaced calculations.
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  • 97
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    AIChE Journal 32 (1986), S. 1372-1376 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study was designed to evaluate the effects of internal droplet convection on the extraction that occurs during generation of a dispersed phase. A photographic determination of dispersed-phase controlled mass transfer from liquid droplets in the formation stage demonstrates a strong dependence on formation time. Convection appears to control mass transfer during rapid drop formation, but an abrupt transition in transfer coefficient occurs as time of formation increases. Diffusion calculations overestimate total extraction for long formation times.
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  • 98
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    AIChE Journal 32 (1986), S. 1397-1400 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 99
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    AIChE Journal 32 (1986), S. 1401-1402 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 100
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    AIChE Journal 32 (1986), S. 1402-1403 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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