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  • 1995-1999
  • 1985-1989  (729)
  • 1988  (729)
  • Chemical Engineering  (691)
  • Magnetic resonance imaging
  • Nuclear reactions
  • Theoretical, Physical and Computational Chemistry
Material
Years
  • 1995-1999
  • 1985-1989  (729)
Year
  • 1
    ISSN: 1432-2161
    Keywords: Magnetic resonance imaging ; Trauma ; Spine ; Cervicothoracic
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract From 1984 to 1987 magnetic resonance (MR) imaging was performed on 100 patients suffering acute spinal trauma. MR demonstrated one or more injuries to the cervicothoracic region in 31 patients. It displayed a spectrum of spinal cord injury ranging from mild compression and swelling to complete transection. MR was also useful in evaluating alignment at the cervicothoracic junction, in depicting ligamentous injury, in establishing the presence of disc herniation, and in identifying unsuspected levels of injury. We present a diagnostic algorithm that incorporates the role of MR in evaluating acute cervicothoracic spinal trauma and emphasizes the replacement of myelography by MR in the initial assessment of neurologic deficit.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-2161
    Keywords: Magnetic resonance imaging ; Threedimensional, gradient-echo sequence ; Chondromalacia ; Knee joint ; FLASH ; FISP
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Diagnosis of chondromalacia of the patellofemoral joint using three-dimensional gradient-echo sequences was investigated in 41 patients, with arthroscopic verification in 25 patients. In vitro examinations in human caderveric patellae were performed in order to determine optimal imaging parameters. FLASH (TR=40 ms, TE=10 ms, flip angle=30°) and FISP (TR=40 ms, TE=10 ms, flip angle=40°) were used in clinical studies. Advanced stages of chrondromalacia could be visualized with high sensitivity. The therapeutically relevant differentiation of major and minor degrees of chondromalacia seems to be possible. 30° FLASH-images in the axial plane proved to be the most efficacious technique for the diagnosis of chondromalacia.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Skeletal radiology 17 (1988), S. 190-193 
    ISSN: 1432-2161
    Keywords: Pyomyositis ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Pyomyositis is a relatively rare entity in temperate climates. Because of its rarity and its nonspecific clinical and radiographic findings, pyomyositis may be misdiagnosed and may cause severe morbidity and mortality. We present magnetic resonance imaging findings in two cases of pyomyositis. Magnetic resonance imaging was helpful in differentiating other pathological processes from pyomyositis, outlining the extent of involvement, and localizing the fluid collection.
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  • 4
    ISSN: 1432-2161
    Keywords: Gadolinium-DTPA ; Magnetic resonance imaging ; Soft tissue tumor
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract In a preliminary report of a clinical trial of gadolinium-DTPA (Gd-DTPA) for enhancement of soft tissue tumors in magnetic resonance imaging (MRI), experience of the first five cases is presented. Enhancement was found to give better delineation of the tumor in richly vascularized parts of the tumors, compressed tissue immediately surrounding the tumor, and in atrophic, but richly vascularized, muscle.
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  • 5
    ISSN: 1432-2161
    Keywords: Synchronous multicentric aggressive fibromatosis ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Synchronous multicentric aggressive fibromatosis does not appear to have been previously reported. Two such cases are described. The tumors were identified by magnetic resonance (MR) imaging. The incidence of synchronous multicentric aggressive fibromatosis is not known. It is anticipated that increased use of coronal MR imaging will reveal more tumors of this type, both synchronous and metachronous. In a patient with known or suspected aggressive fibromatosis, every other soft tissue nodule or mass in the same limb has to be regarded as an additional tumor of the same histology.
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  • 6
    ISSN: 1432-2161
    Keywords: Magnetic resonance imaging ; Chronic patellar tendinitis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Chronic patellar tendinitis can be a frustrating diagnostic and therapeutic problem. This report evaluates seven tendons in five patients with chronic patellar tendinitis. The etiologies included “jumper's knee” and Osgood-Schlatter disease. In all cases magnetic resonance images (MRI) showed thickening of the tendon. Some of the tendons had focal areas of thickening which helped establish the etiology. All cases had intratendinous areas of increased signal which, in four cases, proved to be chronic tendon tears. MRI is useful in evaluating chronic patellar tendinitis because it establishes the diagnosis, detects associated chronic tears, and may help determine appropriate rehabilitation.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Neuroradiology 30 (1988), S. 81-83 
    ISSN: 1432-1920
    Keywords: Computed tomography ; Magnetic resonance imaging ; Ecchordosis physaliphora ; Spinal cord
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary The authors report a rare case of ecchordosis physaliphora arising from C2, manifested with clinical symptoms, with the findings of CT scans and MRI.
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  • 8
    ISSN: 1432-1920
    Keywords: Magnetic resonance imaging ; Gadolinium-DTPA ; Intracranial disease
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary One hundred patients with CT-proven intracranial disease have been studied by magnetic resonance imaging (MRI) before and after intravenous injection with Gadolinium-DTPA (Gd-DTPA), in order to assess the role and clinical efficacy of Gd-DTPA. T2-weighted spin echo sequences, although sensitive to the detection of intracranial disease, in general fail to differentiate macroscopic tumour from oedema. Following Gd-DTPA, T1-weighted spin echo sequences in primary tumours demonstrated a variable degree of contrast enhancement unrelated to histological type. Small tumours, especially acoustic neuromas and meningiomas in the posterior fossa, were rendered more conspicuous. Optimum time for scanning was between five and 25 min following injection for all lesions except those adjacent to normal enhancing structures such as nasal/sinus mucosa and pituitary gland when delayed scans up to 45 min were necessary. No differences were observed between the 0.1 and 0.2 mmol/kg Gd-DTPA concentrations used and no complications attributable to Gd-DTPA were detected. Clinical advantages of Gd-DTPA include shorter scan times, macroscopic tumour/oedema separation and improved detection of certain tumours, particularly acoustic neuromas.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1432-1920
    Keywords: Ankylosing spondylitis ; Cauda equina syndrome ; Vertebral scalloping ; Dural ectasia ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Three cases of cauda equina syndrome in long-standing ankylosing spondylitis are reported. In all, vertebral scalloping and dural ectasia were confirmed by magnetic resonance imaging and computed tomography. MRI showed widening of the dural sac with signal intensity corresponding to cerebrospinal fluid. CT demonstrated asymmetrical lesions of the posterior elements of the lumbar spine. Myelography was not felt necessary to confirm the findings.
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  • 10
    ISSN: 1432-1920
    Keywords: Magnetic resonance imaging ; Intraspinal tumor ; Meningioma ; Schwannoma
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Magnetic resonance (MR) images of 29 consecutive patients with intraspinal neoplasms (9 intramedullary tumors, 20 extramedullary tumors) were reviewed to evaluated the utility of MR imaging in distinguishing the intraspinal compartmental localisation and signal characteristics of each lesion. Compartment and histology of all neoplasms were surgically proven. MR correctly assigned one of three compartments to all lesions, 9 intramedullary, 14 intradural extramedullary (6 schwannomas, 3 neurofibromas, 5 meningiomas), and 6 extradural (3 schwannomas, 1 meningioma, 1 cavernous hemangioma, 1 metastatic renal cell carcinoma). All intramedullary tumors showed swelling of the spinal cord itself. In all five extradural tumors a low intensity band was visualized between the spinal cord and tumor. On the other hand, a low intensity band was demonstrated in no cases with intradural tumors. Visualization of this low intensity band is important in differentiating extradural from intradural-extramedullary lesions. We call this low intensity band, “the extradural sign”. Signal intensity of intradural tumors varied with histology. In extramedullary tumors, signal intensity of schwannomas was similar to that of the cerebrospinal fluid (CSF) both on T1 weighted (inversion recovery) and T2 weighted spin echo (SE) images. On the other hand, meningiomas tended to be isointense to the spinal cord on both T1 and T2 weighted SE images. We found relatively reliable signal characteristics to discriminate meningioma from schwannoma.
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  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Neuroradiology 30 (1988), S. 385-389 
    ISSN: 1432-1920
    Keywords: Alcohol ; Magnetic resonance imaging ; Brain shrinking
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Magnetic resonance imaging of the intracranial CSF volume was compared before and after 5 weeks of confirmed abstinence in 9 alcohol-dependent patients. All patients showed a highly significant reduction in CSF volume in accordance with reexpansion of the brain after alcohol abstinence. T2 values for white matter, estimated by linear regression from 16 echoes of a CPGM sequence, however, showed no significant increase such as occurs in rehydration. This indicates, that alcohol-induced reversible brain atrophy cannot be attributed to fluctuation of free water in the brain only.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Neuroradiology 30 (1988), S. 65-68 
    ISSN: 1432-1920
    Keywords: Hypothalamic hamartoma ; Precocious puberty ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Hypothalamic hamartoma is the most common detectable cerebral lesion causing precocious puberty. Two histologically confirmed cases were studied by computerized tomography (CT) and magnetic resonance (MR) imaging. T2 weighted, sagittal MR images were superior to CT in delineating the tumor from surrounding grey matter. The lesion was isointense to grey matter on T1 weighted images allowing exclusion of other hypothalamic tumors. MR will undoubtedly become the imaging modality of choice in the detection of hypothalamic hamartoma.
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Neuroradiology 30 (1988), S. 219-223 
    ISSN: 1432-1920
    Keywords: Multiple sclerosis ; Computed tomography ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Magnetic resonance imaging (MRI) findings of 20 patients with clinically definite multiple sclerosis (MS) are presented. The studies were performed on a 0.5 Tesla magnet using spin-echo technique. Analysis of the MRI findings included detailed linear measurements of the ventricular and the subarachnoid spaces and reading of the intensity of the grey and white matter and intensity of the MS plaques. The plaques were sorted according to their number and size. The younger patients (20–40 years) had overall more plaques than the older ones (over 40 years). The small plaques were the most numerous and the large ones were the least common. Statistically significant association was found between the number of plaques and the cella media width. The intensity ratios between the nonplaque white matter/grey matter showed a significant correlation with the ventricular score. A significant negative correlation was found between the antero-posterior diameter of the spinal cord and the number of MS plaques in the brain. The plaque/white matter ratio had a significantly negative correlation with the cervical cord's width.
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  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Neuroradiology 30 (1988), S. 399-407 
    ISSN: 1432-1920
    Keywords: Magnetic resonance imaging ; Sodium imaging ; Brain tumors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Twelve patients with different diseases of the brain were examined with sodium and proton MRI at 1.5 Tesla and the results of both studies compared. Due to the 1500-fold lower concentration in the body, the decreased sensitivity and the shorter relaxation times of sodium compared with hydrogen a sequence with gradient reversal and a volume imaging method was applied to achieve a short echo time (4.5 ms). As a result of the mainly extracellular distribution of sodium the CSF spaces are depicted by their high signal intensity while the normal parenchyma is not visible. Changes induced by encephalitis, ischemic infarction and tumors can also be detected by their increased sodium content. Different tumors provided different signal intensities, not always permitting a distinction between tumor, surrounding edema and CSF. The diagnostic impact of these findings is discussed.
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  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Neuroradiology 30 (1988), S. 310-314 
    ISSN: 1432-1920
    Keywords: Hydrocephalus ; Spinal cord tumours ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary In six young patients presenting with raised intracranial pressure during the period of a year, CT revealed the presence of hydrocephalus, but not the cause. Magnetic Resonance Imaging not only shwed the site and nature of the obstructing lesion, but also detected additional clinically silent spinal cord tumors in five of the patients. The place of MRI in the diagnosis of diseases involving the region of the cranio-cervical junction and in the elucidation of “unexplained hydrocephalus” is considered.
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  • 16
    ISSN: 1432-1920
    Keywords: Magnetic resonance imaging ; Intracerebral haematoma ; Low field MRI
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Results of MRI at 0.15T in twelve successive patients with intracerebral haematoma are reviewed. Using T2 weighted spin echo (SE) and partial saturation (PS without a refocussing 180° pulse) sequences, low intensity areas were seen in eleven of the twelve cases. These included central regions (three cases), a peripheral rim (seven cases) and more diffuse patterns involving the brainstem and cerebral hemispheres (two cases). One case initially displayed a peripheral rim and later a central low intensity region. Central low intensity regions were seen in acute, subacute, and chronic cases. Follow up in five cases displayed an increase in signal within the haematoma in three cases and a decrease in signal intensity in two cases. Low signal intensity areas can be seen within and around intracerebral haematomas imaged with T2 weighted sequences at low field strength.
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  • 17
    ISSN: 1432-1971
    Keywords: Cor triatriatum ; Magnetic resonance imaging ; Phase display
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Magnetic resonance imaging utilizing spin echo sequences was used to demonstrate cor triatriatum in an 18-year-old boy. Phase map images aided the diagnosis by demonstrating the presence of slowly flowing blood in the accessory atrial chamber. Magnetic resonance is an excellent modality for the noninvasive diagnosis of cor triatriatum.
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  • 18
    ISSN: 1432-198X
    Keywords: Acquired cystic kidney disease ; Magnetic resonance imaging ; Ultrasonography ; Children ; Peritoneal dialysis ; Hemodialysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Acquired cystic kidney disease (ACKD) occurs in adult patients undergoing long-term dialysis. Early detection is important because clinically significant hematuria and malignancies are associated with ACKD. We evaluated by magnetic resonance imaging (MRI) and ultrasonography (US) the incidence of ACKD in 15 patients aged 7.3–21.6 years (mean 15.9 years) with non-cystic primary renal disease. Nine patients had been treated with peritoneal dialysis only, and 6 with both hemodialysis and peritoneal dialysis for 24–73 months (mean 37 months). Three patients (20%) had no cysts. In 5 patients (33%) with bilateral multiple cysts, the diagnosis of ACKD was made by MRI and US. In another 5 patients, solitary cysts were localized to one kidney by MRI, and in 2 patients solitary cysts were seen in both kidneys. This study documents that ACKD is not limited to older patients with end-stage renal disease. Early detection of these cysts can be accomplished by MRI and is warranted since 1 patient developed neoplastic tubular changes which can precede tumor formation.
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  • 19
    Electronic Resource
    Electronic Resource
    Springer
    Neuroradiology 30 (1988), S. 261-264 
    ISSN: 1432-1920
    Keywords: Cavernous hemangiorna ; Spinal cord ; Thoracic spine ; Computed tomography ; Metrizamide myelogram ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary A 25-year-old woman presented with a four-year history of progressive right-lower-extremity weakness and atrophy and a left hemisensory deficit was found. Metrizamide-enhanced spinal CT scan showed an intramedullary lesion at the level of T1-T2; this had expanded the cord in fusiform fashion but showed no evidence of a cystic component. Surgical resection was performed and the pathological diagnosis was cavernous hemangioma. Two and one-half years later, her left hemisensory deficit was worsening and a spinal MRI showed high signal intensity mass in the region of the previous surgery consistent with chronic hematoma which was re-evacuated with some improvement in the patient's neurological condition.
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  • 20
    ISSN: 1432-1920
    Keywords: Magnetic resonance imaging ; Quantification ; Multiple sclerosis ; Treatment ; Evaluation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Magnetic resonance scans of 74 patients with multiple sclerosis participating in a controlled trial were compared 6 months before and at the end of a 24–32 months-treatment period with either Cyclosporin A (n=31) or Azathioprine (n=43). Both qualitative rating and computation of lesion volume showed deterioration in more than 40% of the patients, while by clinical criteria only 10–30% were worse. No significant difference was noted when the two treatment groups were compared. If careful repositioning and standardized image parameters are used, MRI is an indispensable tool for the objective determination of disease progression in MS although it cannot replace clinical examination.
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  • 21
    ISSN: 1432-1920
    Keywords: Arteriovenous malformation ; Magnetic resonance imaging ; Cavernous sinus ; Dura mater
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Four patients with dural arteriovenous malformation (AVMs) draining into the cavernous sinus, who presented ophthalmic manifestations, were studied by magnetic resonance (MR) imaging. In all patients signal decrease in the involved cavernous sinus was demonstrated in coronal spinecho (SE) imaging. It is attributable to rapid venous flow in the sinus, and this “high velocity signal loss” is a fairly pathognomonic finding in this condition. We stress the validity of MR imaging in the primary diagnosis of dural AVMs with ophthalmic symptoms.
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  • 22
    Electronic Resource
    Electronic Resource
    Springer
    Neuroradiology 30 (1988), S. 571-573 
    ISSN: 1432-1920
    Keywords: Magnetic resonance imaging ; Ossification of ligamentum flavum ; Thoracic myelopathy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary A case of thoracic myelopathy due to ossification of the ligamentum flavum is presented. A fifty-five year old female complained of sensory and motor disturbance of lower limbs. Neuroradiologically, in addition to ossification of the posterior longitudinal ligament throughout the spines, ossified ligamenta flava were found at the Th10–11 level and magnetic resonance imaging (MRI) clearly showed the spinal cord compressed at the same level by a low-intensity-signal lesion. Laminectomy and removal of the ossfied ligamenta flava improved her neurological dysfunction. The usefulness of the MRI in the neuroradiological diagnosis was confirmed.
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  • 23
    ISSN: 1432-1920
    Keywords: Multiple sclerosis ; Magnetic resonance imaging ; Corpus callosum atrophy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Among 110 patients (45 men, 65 women), aged 15 to 66, with clinical and/or biological diagnosis of multiple sclerosis (MS), severe to moderate corpus callosum (CC) atrophy was observed in 67 (60%) patients. Correlation between CC atrophy, brain atrophy, duration and severity of clinical symptoms, and high signal white matter areas, was carried out in 90 patients. Mean age was 46 years for those with severe CC atrophy, and 33 years for those without atrophy. Mean duration of the disease was 14 years in patients with severe atrophy, and 5 years in patients without atrophy. Severity of clinical symptoms is more pronounced in patients with severe CC atrophy. Numerous or large white matter high signal areas are observed in patients with severe CC atrophy on T2-weighted images. CC atrophy appears earlier than brain atrophy in the course of MS.
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  • 24
    ISSN: 1432-1920
    Keywords: Multiple sclerosis ; Respiratory arrest ; Magnetic resonance imaging ; Dual respiratory pathways
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary A 66-year-old MS patient who suffered respiratory arrest followed by complete remission is reported. Magnetic resonance imaging (MRI) revealed a medullary lesion. Clinicoradiological relationships are discussed.
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  • 25
    ISSN: 1432-1076
    Keywords: Tuberous sclerosis ; Echocardiography ; Magnetic resonance imaging ; Neonate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract In a neonate with tuberous sclerosis, cardiac tumours were diagnosed by two-dimensional echocardiography and evaluated by electrocardiogram-gated magnetic resonance imaging (MRI). The tumour size, shape and mobility in the ventricular cavities were more precisely determined by two-dimensional echocardiography than electrocardiogramgated MRI, while the extent of tumour mass at the apex was more clearly delineated by MRI. As two-dimensional echocardiography provides real-time imaging of cardiac anatomy without sedation, it is useful for initial evaluation of cardiac masses in neonates with genetic predisposition to tuberous sclerosis.
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  • 26
    ISSN: 1437-2320
    Keywords: Magnetic resonance imaging ; orbital neoplasms ; radiography ; surgical therapy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract During the last two and a half years 60 patients with orbital space occupying neoplasms were treated surgically at the Department of Maxillo-facial Surgery of the University Clinic of Essen. With modern imaging techniques exact information on the location and extent of space occupation was available before the operation. Therefore the surgical approach could be optimized. Despite the various and sometimes inaccessible tumor locations, transcranial operation was only necessary in six patients. In the remaining 54 patients anterior orbitotomy allowed either a definitive tumor therapy or histological verification of the diagnosis.
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  • 27
    ISSN: 1432-1459
    Keywords: Evoked potentials ; Magnetic resonance imaging ; Somatosensory evoked potentials ; Brain-stem auditory evoked potentials
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary There is still a need to prove that even static magnetic fields up to 1.5 T used in magnetic resonance imaging (MRI) are biologically safe and harmless for humans. Recordings of median and ulnar nerves and brain-stem auditory evoked potentials in 20 patients were completed prior to and after MRI investigation of the central nervous system. Neither the somatosensory nor the auditory evoked potentials exhibited any significant change of latencies, interpeak latencies or amplitudes. Since these electrophysiological parameters are highly dependent on the quality of nerve conduction and integrity of information processing in various nuclei, it may be assumed that MRI causes no lasting changes in either respect.
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  • 28
    ISSN: 1432-1459
    Keywords: Multiple sclerosis ; Interferon ; Cerebrospinal fluid ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary A preliminary study is reported of clinical response and CSF/MRI findings in nine patients with multiple sclerosis receiving intravenous infusions of natural beta-interferon. The mean patient follow-up was for 1.2 years. Neither exacerbation rates nor CSF-IgG synthesis nor plaque formation as revealed by MRI showed a significant reduction during therapy. One patient developed a severe exacerbation of multiple sclerosis shortly after interferon infusion.
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  • 29
    ISSN: 1432-1459
    Keywords: Multiple sclerosis ; Neuropsychology ; Memory functions ; Dementia ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Progressive decline of anterograde memory functions has been increasingly recognized as a frequent symptom in chronic multiple sclerosis. In order to investigate the brain structures involved, magnetic resonance imaging was performed in 20 patients. Neuropsychological assessment included the WAIS and WMS subtests information, picture completion, similarities, digit span, logical memory, and paired associate learning. All patients with severely impaired memory functions (n=5) showed bilateral lesions in the medial temporal lobe, whereas in those patients with moderate (n=10) or no measurable impairment of memory testing (n=5) either no lesions were seen in the medial temporal lobes or these lesions were restricted to one side. A post hoc cluster analysis strikingly confirmed these results. The differences could not be related to the age of the patients, the disease duration, or the level of education. Extensive lesions in the white matter of the frontal lobes, thinning and lining of the corpus callosum, and bilateral involvement of the anterior cingulate gyrus had no bearing on the neuropsychological results. These findings indicate that bilateral demyelination in the hippocampal regions is the most likely explanation for the impairment of anterograde memory in such patients.
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  • 30
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    Journal of neurology 235 (1988), S. 379-381 
    ISSN: 1432-1459
    Keywords: Central pontine myelinolysis ; Cerebellar ataxia ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Development of severe ataxia and mild pyramidal signs without mental deterioration, tetraparesis or pseudobulbar palsy during recovery from withdrawal delirium and initial hyponatraemia are unusual clinical features consistent with central pontine myelinolysis. This diagnosis was confirmed by magnetic resonance imaging (MRI) in an alcoholic man. Clinical and electrodiagnostic improvement occurred, whereas the MRI findings remained unchanged in a follow-up study.
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  • 31
    ISSN: 1432-1459
    Keywords: Lymphomatoid granulomatosis ; Spinal cord syndrome ; Magnetic resonance imaging ; Histopathology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary An unusual mode of presentation of lymphomatoid granulomatosis is reported. A 19-year-old man developed spinal cord symptoms, and magnetic resonance imaging of the spinal cord disclosed a compatible lesion. Despite medical therapy the outcome was fatal.
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  • 32
    ISSN: 1432-1459
    Keywords: Mycoplasma pneumoniae ; Encephalomyelitis ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Two patients are reported with Mycoplasma pneumoniae-related cervical myelitis. Magnetic resonance imaging in each case demonstrated clinically silent lesions suggesting more extensive neurological involvement. This supports the concept of widespread immunologically mediated disease occurring as a remote effect of initial M. pneumoniae respiratory infection. Differences from the MRI appearances of a patient with mycoplasma-related Guillian-Barré syndrome imply that more than one antigenic determinant is involved.
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  • 33
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    Journal of neurology 235 (1988), S. 193-206 
    ISSN: 1432-1459
    Keywords: Magnetic resonance imaging ; Comparative studies ; Central nervous system ; Brain diseases ; Spine diseases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary The efficacy of magnetic resonance imaging (MRI) in the diagnosis of diseases of the central nervous system is reviewed. MRI, computed tomography (CT) and certain radionuclide studies are compared in the evaluation of intracranial tumours, cerebral vascular disease, multiple sclerosis and other white matter diseases, dementia, head injury, infection, epilepsy, spinal lesions and in paediatric central nervous system disorders. The measurement of cerebrospinal fluid volumes and dynamics by MRI is discussed. MRI most clearly has advantages where CT is degraded by bone hardening and streak artefacts (spine, skull base, posterior and temporal fossa, sella and parasellar regions) and in diseases in which the X-ray attenuation of the suspected lesion differs little from normal parenchyma (paediatric brain disorders, demyelination and dysmyelination, early oedema associated with infarction, infection or low-grade infiltrating neoplasm, subacute and chronic haemorrhage and lesions in the spinal subarachnoid space and cord). Elsewhere MRI and CT should be seen as complementary rather than competitive methods of imaging. In spite of an absence of information about the contribution of MRI to management decisions and a lack of rigorous, prospective controlled trials, MRI will play an increasing role in the diagnosis of diseases of the central nervous system.
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  • 34
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    European archives of psychiatry and clinical neuroscience 237 (1988), S. 139-143 
    ISSN: 1433-8491
    Keywords: Cyanide poisoning ; Basal ganglia ; Computerized tomography ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary A 29-year-old chemistry student took 50 ml of a 1% potassium cyanide solution (500 mg) in an attempted suicide. He became comatose, mydriatic, and was admitted to hospital in an apneic state. He woke up after 7 h and developed Parkinsonism in the following weeks. This regressed slowly during the 2 months after the poisoning apart from dysarthria, bradykinesia of the upper limbs, and very brisk monosynaptic reflexes. At 3 weeks after the intoxication, computerized tomography was largely normal, and there was CSF-dense hypodensity in both putamina after 5 months. Sharply delimited signal elevation in T2 corresponding to the two putamina was detected by magnetic resonance imaging 8 weeks and 5 months after ingestion of the poison.
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  • 35
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    European journal of nuclear medicine 13 (1988), S. 653-660 
    ISSN: 1619-7089
    Keywords: Magnetic resonance imaging ; Cardiac imaging ; Cardiac function ; Fast NMR imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract NMR imaging is a noninvasive technique that has been shown to provide high-quality images of the heart. Due to the signal characteristics of flowing blood, inherent contrast between blood pool and myocardium is achieved without the use of contrast media. This paper briefly describes technical aspects of NMR imaging of the heart, normal cardiovascular anatomy, applications of the technique in patients with ischemic heart disease, and the potential of NMR imaging for functional studies in various forms of heart disease.
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  • 36
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 13-19 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of crystallization during anioiiic polymerization of ∊-caprolactam was studied by the adiabatic temperature rise method, A new kinetic model for the non-isothermal crystallization was derived and the possibility of its application was Investigated. By evaluating the parameters in the model for the given adiabatic system, the crystallization behavior during the; polymerization process was analyzed. The experimental and calculated temperature rise showed a very good agreement, which indicated that the model equation was appropriate to describe the non-isothermal reaction-induced crystallization kinetics in this study. The melting temperature of the reaction mixture increased steadily due to the change of the crystal structure with conversion. The equilibrium crystallinity was higher when the crystallization started in the presence of unreacted monomer than when the crystallization occurred after polymerization was completed. At lower conversion, the reaction mixture was less viscous, a condition that made transport to the liquid-crystal interlace easier, and thus the activation energy for transport decreased. On the other hand, the increasing mobility resulted in difficulty in forming stable nuclei arid the free energy of nucleation increased.
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  • 37
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 38
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Investigations of instability of phase morphology of blends of nylons with polyethylenes and polystyrenes and the effects of “compatibilizing” additives or “agents” are described. Annealing coarsens the phase morphology of blends of nylons with polyethylenes and polystyrenes. Phase growth is observed for various periods of annealing time. The addition of compatibilizing agents, specifically maleic anhydride grafted polyolefins to polyethylene-nylon blends and syrene-maleic anhydride copolymers to polystyrene-nylon blends, stabilize the phase dimensions. Styene-maleic anhydride copolymer is found more effective than styrene acrylonitrile copolymer as a compatibilizing agent. The mechanisms of this behavior are critically discussed.
    Additional Material: 14 Ill.
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  • 39
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 40
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    Polymer Engineering and Science 28 (1988), S. 147-156 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper discusses a computer control system for ram velocity of an injection molding machine using optimal state feedback based on the linear quadratic control theory. A new approach for the selection of appropriate weighting matrices is presented in this context. The simulation results reveal that the optimal controller has improved performance over the conventional PID controller presently used, having faster speed of response, significantly better tracking performance, and better noise filtering properties. The execution speed and the core storage requirements would allow implementation even on a small online computer.
    Additional Material: 9 Ill.
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  • 41
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    Polymer Engineering and Science 28 (1988), S. 165-169 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Film embossing is a mechanical process in which a flat film is transformed into an embossed product. During the process, thermal and stress fields are applied Lo the polymer, causing changes in the microstructure and physical dimensions of the material. The engineering analysis of the process requires the study of various aspects relating to the characterization of the microstructure before and after embossing, A variety of techniques were employed to characterize the properties and microstructure of the embossed film in relation to: crystallinity, orientation, mechanical properties, and dimensions of the embossed films. The thermal treatment of the polymer film was shown to be the most significant factor in the process. By controlling the thermal treatment of the film, it is possible to manipulate the properties and dimensions of the embossed film. The important aspects: influencing thermal treatment include the radiation heater temperature, preheat roll temperature, line velocity, and film thickness. The initial film orientation and embossing pressure have a minor effect on the final properties of the embossed film. The main effect of the embossing pressure is on the bulk thickness of the embossed film.
    Additional Material: 11 Ill.
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  • 42
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 43
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    Polymer Engineering and Science 28 (1988), S. 257-274 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A detailed model for emulsion polymerization is compared with extensive data from continuous stirred tank reactors. Model predictions are compared with both steady-state and dynamic data, for polymerization of styrene, methyl methacrylate, and vinyl acetate. Good agreement between model and experiment is achieved with one set of parameters and without any data fitting. The results show that the model is capable of predicting all of the experimentally observed phenomena including steady-state multiplicity, sustained oscillations, ignition and extinction dynamics, and overshoot during start-up.
    Additional Material: 47 Ill.
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  • 44
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    Polymer Engineering and Science 28 (1988), S. 321-332 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A mathematical model is developed for simulating the pultrusion process of unsaturated polyester resin, using a mechanistic kinetic model based on free radical polymerization. In their previous publications (Refs. 1 and 7), Han and Lee used the mechanistic model to simulate the curing behavior of unsaturated polyester resins under isothermal conditions, employing the differential scanning calorimetry data obtained for a range of single initiators and multiple initiator systems. For the sake of mathematical convenience, a pultrusion die of cylindrical geometry was considered. The mathematical model developed permits one to choose any number of initiators when predicting the distributions of the degree of cure and temperature in both the radial and axial directions of the die. The effects of material variables (e.g., the type and concentration of mixed initiators) and processing conditions (e.g., pulling speed and die temperature distribution) on the performance of the pultrusion are evaluated.
    Additional Material: 22 Ill.
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  • 45
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    Polymer Engineering and Science 28 (1988), S. 189-199 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Post mold thermal processing of epoxy encapsulated semiconductor devices is accomplished in order to optimize the properties of the encapsulating material. Traditionally, such processes were believed to alter solely the state of cure in such systems. We have examined the effects of aging at temperatures close to, but below the molding temperature via dynamic mechanical spectroscopy, Fourier transform infrared spectroscopy, and differential scanning calorimetry as a function of molding temperature. The large property changes observed during aging for samples molded at the lowest temperatures studied were attributed to physical aging phenomena in the presence of low levels of chemical reaction. As the molding temperature was increased chemical aging, phenomena began to precede the volume recovery associated with physical aging, and the overall property shift was altered. It is the intent of this paper to examine in detail the microstructural basis for such observations, as well as the time dependence of the overall property shifts.
    Additional Material: 19 Ill.
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  • 46
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    Polymer Engineering and Science 28 (1988), S. 275-290 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In many operations in polymer processing, such as polymer blending, devolatilization, or incorporation of fillers in a polymeric matrix, continuous mixers are used; e.g., corotating twin-screw extruders (ZSK), Buss Cokneaders and Farrel Continuous Mixers. Theoretical analysis of these machines tends to emphasize the flow in complex geometries rather than generate results that can be directly used (1-5). In this paper, a simple model is developed for the hot melt closely intermeshing corotating twin-screw extruder, analogous to the analysis of the single-screw extruder carried out in 1922 and 1928 (6, 7). With this model, and more specifically with its extension to the complete nonisothermal, non-Newtonian situation, it is possible to understand the extrusion process and to calculate the energy, specific energy, and temperature rise during the process with respect not only to the viscosity of the melt, but also to the screw geometry (location and number of transport elements, kneading sections and blisters, pitch, positive or negative, screw clearance, and flight width) and screw speed. To support the theoretical analysis, model experiments with a Plexiglas-walled twin-screw extruder were performed, in addition to practical experiments with melts on small- and large-scale extruders, with very reasonable results, In Part 2, the Buss Cokneader will be analyzed analogously.
    Additional Material: 15 Ill.
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  • 47
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    Polymer Engineering and Science 28 (1988), S. 434-443 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The radial flow of a chemically reactive fluid between two parallel circular disks during the process of Reactive Injection Molding (RIM) has been simulated in a decelerative, non-isothermal, transient flow environment. The effects of key operating and system parameters (feed temperature, volumetric flow rate, reaction rate, and cavity thickness) on velocity, conversion, and temperature profiles which occur in this decelerative flow environment were determined. A catalyzed, unfilled polyurethane RIM system was modeled by a linear step polymerization scheme using average literature values for the reaction rate, and thermodynamic and constitutive parameters. The numerical solution was achieved using the method of lines and upwind approximations of the spatial derivatives. The geometry studied (two parallel, center gated circular disks) models flow patterns in commercial RIM processes more realistically than the rectangular flow between two parallel surfaces (studied by previous workers) in which the average velocity is constant along the length of the mold. This simulation predicts the accumulation of high polymer near the entrance to the mold and near the outer edge of the cavity in fast reactive systems. The accumulation of material near the gate results in viscous heat generation and a maximum in temperature in the region immediately downstream from the restriction.
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  • 48
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    Polymer Engineering and Science 28 (1988), S. 469-476 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An analysis of a drawing plate test for easily monitoring the low-pressure frictional characteristics of powders is presented. The test is performed by measuring the force required to withdraw a plate from a cylindrical bed of dry powder. The characteristics of the drawing force profile are analyzed using Janssen's classical differential element approach to relate the product μK of powders as a function of packing of powder medium, where μ is the coefficient of friction of the powders against the solid drawing plate, and K is Janssen's constant, an anisotropic pressure distribution factor of a powder bed. The packing arrangement, expressed as the external void fraction, due to tapping, significantly alters the μK value and the effective sustaining strength of a powder bed. Experimental results on spherical glass beads having mono- and bimodal size distributions, and on three different poly (vinyl chloride) (PVC) powders are discussed. A spherical, high bulk density PVC powder has the combination of low μK and high, bulk density desirable for rigid powder compounding applications.
    Additional Material: 11 Ill.
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  • 49
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    Polymer Engineering and Science 28 (1988) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 50
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    Polymer Engineering and Science 28 (1988), S. 413-420 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper presents the development of the boundary element equations for the compression molding process of isothermal Newtonian fluids. It shows the numerical implementation of the boundary element equations and presents a simple method of carrying out the domain integral present in the governing equations. The results and accuracy of a boundary element simulation are discussed, and the numerical results compared to experimental values.
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  • 51
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    Polymer Engineering and Science 28 (1988), S. 444-452 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A numerical method has been developed for simulating fully developed multilayer shear flows of non-Newtonian fluids with arbitrary viscosity functions. Poiseuille and combined Poiseuille/Couette flows in both slits arid annuli may be modeled. The method employs a finite difference system where grid points lie on streamlines and move to their correct positions as the solution procedure converges. Interfaces are easily handled as particular stream lines with the equation of motion replaced by a boundary condition. The method is stable for high interface viscosity ratios and readily handles a large number of layers. Many authors have employed power law models to model multi-layer non-Newtonian flows. We find that the power law is sufficient to predict pressure gradients and interface positions in most cases, but gives unrealistically flat velocity profiles, even when truncated at finite viscosity. Results are presented for the Carreau fluid and for the rubber-like liquid with shear thinning via Wagner's strain functional.
    Additional Material: 9 Ill.
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  • 52
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    Polymer Engineering and Science 28 (1988), S. 477-484 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A computer simulation model was established to analyze the reaction injection molding process of nylon 6. A numerical calculation was carried out to predict the temperature, conversion, and crystallinity profile within a disc type mold. The effects of the feed temperature, wall temperature, and overall reaction constant on the eject time were discussed for searching the optimum processing conditions.
    Additional Material: 14 Ill.
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  • 53
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    Polymer Engineering and Science 28 (1988), S. 497-505 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: With respect to molecular masses, polymers are polydispersive. Since many of their properties depend on the distribution of molecular masses, to study this correlation it is necessary to have samples of narrow molecular mass distribution or samples with accurately defined distribution. In spite of the developmental progress of fast instrumental methods (analytical and preparative gel chromatography) used to determine the molecular mass distribution curve and to obtain higher amounts of fractions of narrow molecular mass distributions, there still exists an interest in classical methods of fractionation. On the basis of a survey of monographs on polymer fractionation, numerous publications and personal experience, this review describes primarily what is an efficient fractionation. Afterwards, factors that affect fractionation efficiency according to the type of effects arc given and causes of their action are described. Conditions under which efficient fractional precipitation and fractional solution methods are applied are considered separately. At the end of the review, criteria on the basis of which fractionation efficiency is evaluated are considered in detail.
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  • 54
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    Polymer Engineering and Science 28 (1988), S. 538-543 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The relationship between the relaxation time spectrum H(τ) in the terminal zone and the volume-fraction differential molecular-weight-distribution function P(M) is derived by considering binary chain contacts for stress transmission, where β and λ are constants for a given chemical type. This is used to determine the molecular-weight-distribution curves from the stress relaxation modulus spectrum (above the crystal melting point) at 370°C for a number of commercial and experimental poly(tetrafluoroethylenes) (PTFEs). It is found that PTFEs typically have bimodal molecular-weight distributions. The lower-molecular-weight peak conforms essentially to the “most-probable” distribution, and the higher-molecular-weight peak to the binary coupling distribution. The entanglement molecular weight Me is 5490, and the number of main-chain atoms between entanglement points is 110, consistent with a flexible chain. The zero-shear melt viscosity at 370°C is η0 = 1.79 × 10-13 Mw2.94±0.13, where η0 is in Pa.s and Mw/Me = 2,000 to 12,000. The monomeric friction coefficient is also determined.
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  • 55
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    Polymer Engineering and Science 28 (1988), S. 81-89 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A method to obtain the tenacity and Young's modulus of nonwoven webs without direct measurement of web thickness is proposed. This has been tested with several series of samples with different basis weight. It was found that these properties were nearly Independent of the sample gage length, and both tenacity and modulus generally decreased with increase in the die temperature, the air pressure at the die, or the die to collector distance [DCD]. The web stiffness as measured by bending rigidity followed similar trends. The elongation Lo break also decreased as die temperature and air pressure at The die increased, but it increased with increasing DCD. The average filament diameter in the web decreased with increasing die temperature or air pressure at the die. The single filament strength was measured and compared with strength properties of web and of high-speed melt spun filament prepared from the same resins. The strength of single filaments in the web lie in between those of the web and high-speed spun filaments. The mechanical properties of melt blown web were interpreted in terms of the changes in Fiber diameter, the level of interfilament bonding, the molecular orientation developed in the filament, the diameter uniformity along the individual filaments in the web, and the presence of voids in the filament.
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  • 56
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    Polymer Engineering and Science 28 (1988), S. 113-119 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A computer simulation model for the latent skin growth inside a hollow fiber polymeric membrane Is developed. The evaporation step is studied using a solvent evaporation Law and a concentration-dependent diffusion coefficient, both derived from data. The solvent concentration profiles inside the fiber are obtained as a function of the evaporation time for different sets of the parameters governing the internal diffusion and the surface evaporation of the solvent. The computer model enables estimation of the role of the parameters in the growth of the asymmetric latent skin.
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  • 57
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    Polymer Engineering and Science 28 (1988), S. 136-142 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A series of thermotropic liquid crystalline polyesters based on p-acetoxybenzoic acid, naphthalene dicarboxylic acid, hydroquinone diacetate, and poly(ethylene terephthalate) were prepared via melt polycondensation. The anisotropic melts were studied by means of thermal optical testing, differential scanning calorimetry, scanning electron microscopy. X-ray diffraction, and rheological methods. It was found that the copolyesters in the mesomorphic state exhibit drastic shear-thinning and the experimental results indicate that the non-Newtonian Index n is in the range of 0.17 to 0.50, the flow-activation energies ΔEη are 297.1 to 182.0 KJ/mol over the shear rate of 10 to 1000 S-1 at temperature 225 to 270°C; and the mesomorphic copolymers are readily oriented during processing, resulting in highly oriented as-spun fibers.
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  • 58
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    Polymer Engineering and Science 28 (1988), S. 170-180 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Results of experimental and modeling studies of the peroxide promoted degradation of polypropylene (PP) are presented. Experiments were carried out, in glass ampoules and in a plasticating extruder. The initiator, 2.5-dimethyl-2,5-bis(tert-butylperoxy)hexane was used as a radical generator. The extruder used had a 38 mm diameter and 24:1 L/D single-screw. In these experiments, the effect of peroxide concentration and screw speed on the molecular weight distribution (MWD) of the polypropylene resin was studied. Samples collected from the experimental runs were analyzed for melt flow index (MFI), flow curve, extrudate swell, and MWD. The measured data are presented and correlations among various parameters are considered. Generally, it can be concluded that controlled-rheology (CR) resins with lower molecular weight, narrower MWD, and reduced viscosity and elasticity, can be produced, A kinetic model for the peroxide Initiated degradation of PP is proposed. Simulations based on this model are compared with experimental data for the production of CR resins. The experimental data were obtained from three sources: (i) industry, (ii) literature, and (iii) present experimental work. The comparison was done in terms of average molecular weights of the resin. Agreement between model predictions and experimental results is quite satisfactory suggesting that this model should find use in commercial practice.
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  • 59
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    Polymer Engineering and Science 28 (1988), S. 181-187 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This study examines the effects of crystallinity and temperature on the mechanical properties of PEEK. Crystallinity in PEEK Increases with annealing temperature up to a maximum of 28 percent with a melting point at 335°C. A minor melting peak also occurs about 10°C above the annealing temperature. In cold drawing the samples exhibited a yield stress and necking followed by homogeneous drawing. The yield stress increases with crystallinity, but there is no change in the modulus. The extension in the necking process also increases with crystallinity, however there is only a slight increase in extension-to-break since necking is compensated by the final amount of homogeneous drawing. The yield stress of PEEK when drawn at Tg (145°C) is significantly lower than at room temperature indicating a reduction in mechanical properties at temperatures approaching Tg. After mechanical drawing the minor melting peak disappears and on heating the material undergoes cold crystallization near the onset of Tg. There is evidence that this minor crystalline component might contribute to the yield stress changes with annealing history. Cold drawing induces crystallization of amorphous PEEK but decreases crystallinity and generates microscopic voids in crystalline PEEK, The various effects of crystallinity on mechanical properties could be important in determining the stress response of PEEK as the matrix in composites.
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  • 60
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 61
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 367-371 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A negative-acting dry-film photoresist was examined via both photocalorimetry and conventional calorimetry. The photo reaction of the resist was investigated as a function of temperature, and two distinct regimes with different activation energies have been identified. Possible reaction mechanisms were discussed in terms of termination reactions of the polymerization as well as effects of vitrification. The thermal reactivity of this particular resist was studied as well. It was possible to use Kissinger's equations to predict thermal aging effects. Finally, the utility of photocalorimetry as a tool to examine quickly the reactivity of monomers and initiator systems was demonstrated.
    Additional Material: 7 Ill.
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  • 62
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 381-384 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The applicable range of the regression equation proposed by Yamada, et al. expressing oligomer melting point by oligomer characteristics and relations derivable from the equation correlating each oligomer characteristic and melting point were studied. It was confirmed that the equation is applicable not only to poly(ethylene terephthalate) (PET) oligomer but also to the extent of polymerization. As number-average degree of polymerization (Pn) increases, the influence of end groups on melting point becomes weak, and when Pn exceeds 50, the influence of end groups becomes negligibly small. On the other hand, when Pn is below 2, It was confirmed that the influence of end groups on melting point is very strong.
    Additional Material: 5 Ill.
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  • 63
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 405-412 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Means of improving the deep drawability of thermoplastic sheets were explored by introducing temperature gradients in the deforming material during deep drawing of initially flat sheets. The specific experimental procedure consisted of either limiting the heating to the flange section of the deforming sheet or exposing the entire material to higher temperatures. At the same time, the initial blank size and the clamping force at the flange section were varied systematically. Both polypropylene and polypropylene with 40 percent calcium carbonate in the form of sheet were tested up to 130°C. It is demonstrated that the draw-ability increases markedly with increasing temperature gradient between the flange and punch sections. The results of measured strain distribution in the deformed part indicate that the magnitude of temperature difference between the flange and punch sections determines the relative amount of deep drawing and stretching in the wall of the formed part, which in turn dictates the drawability of the material.
    Additional Material: 8 Ill.
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  • 64
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 333-339 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Injection molding can be used to fabricate fiber-reinforced polymer composites by impregnating a continuous fabric mat preplaced in a mold cavity with a polymer resin. The mold-filling time is dependent on the flow and heat transfer behavior in the mold. A model is proposed that considers the non-Newtonian How through the porous fabric mat and the heat transfer between mold, fabric mat, and flowing fluid. The model was simulated for the mold filling of a carbon fiber mat with a pseudoplastic polymer solution. The results from the simulation provide Information for optimizing mold-filling parameters through proper selection of inlet fluid pressure, heat source temperature, and type of polymer-solvent system.
    Additional Material: 8 Ill.
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  • 65
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 291-310 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The wire-coating process was analyzed numerically making use of a particular die design employed in highspeed industrial operations. Both the lubrication approximation theory and a fully two-dimensional finite element analysis were applied under isothermal and nonisothermal conditions, respectively. Particular emphasis has been given to the heat transfer effects between the melt arid the solid and free boundaries. A variety of thermal boundary conditions was studied, ranging from adiabatic to constant temperature walls. The influence of dimension less groups such as Peclet, Nahme, and Biot numbers is examined. Oscillation-free solutions are obtained for the temperature field by using a standard finite element Streamline-Upwind/Petrov-Galerkin technique. Rheological data for a wire-coating low-density polyethylene (LDPE) resin (Alathon-3535) were used in the analysis. The predictions include pressure and temperature distributions, shear stresses and shear rates both at the die wall and the wire, and wire tension for different wire speeds. The numerical results are compared with a set of experimental data for LDPE in a typical die used by Du Pont Co. It is found that the isothermal lubrication approximation for power-law fluids overestimates pressure distributions when applied at die operating temperature. The nonisothermal finite element analysis gives better predictions, especially when realistic thermal boundary conditions are imposed, with the experimental results lying between those found from simulations assuming isothermal walls (upper limit) and adiabatic walls (lower limit).
    Additional Material: 26 Ill.
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  • 66
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 393-402 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Using three series of sodium carboxymethylcellulose (NaCMC) in the range of the degree of substitution (the average number of carboxymethyl groups/glucose unit) from 0.5 to 1.3, weight-average molecular weight Mw was determined by light scattering in solution of triethylenediamine cadmium hydroxide (cadoxene). It was found that the relation between Mw and the limiting viscosity number [η] in 0.1 N sodium chloride (NaCl) aqueous solution can be represented by Staudinger's equation. Dynamic viscoelasticity of aqueous disperse systems of NaCMC with various added salts was measured by means of a cone-and-plate rheometer. If the concentration of added salt is less than the concentration at which polymer begins to salt out, frequency dependence curves of the dynamic modulus, which is measured at various salt concentrations, can be superposed into a master curve by horizontal shift only. The shift factor depends on the salt concentration and the kind of salt.
    Additional Material: 11 Ill.
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  • 67
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 385-392 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: To study the effect of potassium titanium oxyoxalate on the esterification reaction of terephthalic acid (TPA) and ethylene glycol (EG) in the first tank reactor of TPA/EG continuous esterification, experiments at various addition rates of potassium titanium oxyoxalate were made in the pilot plant. Potassium titanium oxyoxalate accelerated the esterification reaction of TPA and EG. Also, reaction rate constants of the reaction scheme reported in a previous report were fitted with the experimental results, and the calculated values of physical properties of oligomers obtained from these reaction rate constants showed relatively good agreement with experimentally obtained physical properties of the oligomers. The effect of potassium titanium oxyoxalate on the reaction rate constants was expressed by a set of seven equations: Using the resultant reaction rate constants, the esterification reaction at various addition rates of potassium titanium oxyoxalate were stimulated and the following conclusions drawn: 1Under low pressure close to atmospheric, when the amount of water in the reaction mixture is very low, the decomposition of potassium titanium oxyoxalate proceeds slowly and decomposition can be practically neglected.2Potassium titanium oxyoxalate accelerates the esterification reaction.2Potassium titanium oxyoxalate mainly accelerates the main reactions and its effects on side reactions are rather weak. As a result, the higher the addition rate of potassium titanium oxyoxalate, the lower the values of AV and DEG, as is preferable.
    Additional Material: 12 Ill.
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  • 68
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 69
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 1-5 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Physical aging of a thermoset system based on bisphenol-A epoxy (DERTrademark of The Dow Chemical Company. 383) and tetrabromobisphenol-A cured with sulfanilamide and diaminodiphenylsulfone was studied as a function of cure history. Changes in the dynamic mechanical spectra for the thermoset system were correlated to changes in relative toughness associated with physical aging as determined by plane-strain biaxial tension-compression yield measurements. It was found that master curves, generated by using tan δ data obtained in the β relaxation temperature regime, are well related to the corresponding changes in mechanical properties and, hence, have predictive value. Relative toughness decreases and compressive yield increases with decreasing tan 5 because of decreased molecular segmental mobility. The relative extent of physical aging for the as-cast thermosets was shown to be linearly related to the cure time.
    Additional Material: 9 Ill.
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  • 70
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    Polymer Engineering and Science 28 (1988), S. 6-12 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Strain-induced crystallization of poly(ether ether ketone) (PEEK) was studied by the use of a parallel plate rheometer. The experimental variables included preheating time, crystallization temperature, and shear rate. The crystallization kinetics were characterized by means of an induction time defined as the time elapsed from the start of shearing to the onset of crystallization. The experimental results showed that the induction time for strain-induced crystallization of PEEK was significantly shorter than that for crystallization under quiescent condition, and that strain-induced crystallization was much less temperature dependent than quiescent crystallization. The activation energy for strain-induced crystallization was found to be 0.035kcal/mole, which was considerably smaller than the reported activation energy for quiescent crystallization. Photomicrographs of the sheared specimens indicated that PEEK crystallites orient along the flow direction.
    Additional Material: 12 Ill.
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  • 71
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    Polymer Engineering and Science 28 (1988), S. 52-57 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A lap shear joint method was used to study strength development during welding of polystyrene surfaces- The surfaces previously had not been in contact and care was taken to insure rapid wetting of the interface. The shear stress at failure, τf was measured at room temperature as a function of contact time, t, at constant welding temperatures up no 20°C above the glass transition temperature, Tg. The time dependence of welding could be well described by τfαt1/4. This result is in agreement with predictions of the reptation molecular dynamics model applied to inter-diffusion at a symmetric amorphous polymer-polymer interface. The activation energy for the thermally activated increase in strength development was determined as E = 96 kcal/mol at T = 113.5°C, which compares with E = 93,2 kcal/mole as predicted by the W-L-F theory using C1 = 13.7, C2 = 50 and Tg = 100°C. The polystyrene samples had molecular weights, Mn = 143,000 and Mw = 262.000. The time to achieve complete healing, t∞ ≍ 256 min at 118°C, was found to be of the same order of magnitude as the viscoelastic relaxation time and also with the time required for a polymer chain to diffuse a distance equal to its root mean square end-to-end vector.
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  • 72
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    Polymer Engineering and Science 28 (1988), S. 90-95 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Rheological data have been collected in isothermal elongational flow for three different types of blends, made from one low density polyethylene and three linear low density samples. In addition to the transient curves, elongation at break data are also reported. The influence of the composition and of the molecular weight of the linear low density polyethylene is discussed.
    Additional Material: 7 Ill.
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  • 73
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 104-112 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The morphology of polycarbonate (PC)-poly(butylene terephthalate) (PBT) blends prepared by melt-processing in an extruder or a Brabender Plastograph was studied by Transmission Electron Microscopy. Transesterification during blending was avoided by the use of di-n-octadecyl phosphite, an efficient transesterification inhibitor. Ruthenium tetraoxide was used to selectively stain the PC fraction. Observation of ultrathin sections revealed the biphasic nature of the blends and the partial compatibility of the polymers in the molten state. The most striking consequence of this Is the presence, of PBT crystalline lamellae growing inside the PC-rich phase for samples annealed in the proper temperature range. A preliminary study of the morphology as a function of composition and thermal annealing was undertaken. The RuO4 staining technique was also applied to the commercial blend Xenoy CL 100 from General Electric, which was shown to contain an MBS impact modifier (a methylmethacrylate butadiene-styrene copolymer) exclusively located In the PC-rich phase.
    Additional Material: 14 Ill.
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  • 74
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    Polymer Engineering and Science 28 (1988), S. 121-135 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The control of polymerization reactors is particularly arduous for several reasons; (a) difficulty in specification of the control objectives; (b) high exothermicities and viscosities involved: (c) complicated process dynamics: and (d) problems with measurement of the polymer structure. Computer control has now simplified many tasks such as sequential operations of batch reactors; but no less important, it has made feasible the implementation of elaborate state estimation and control algorithms. The tendency in the polymerization industry and in current research centers is centered on producing ‘tailor-made’ polymers from the view of its microscopic and/or macroscopic structures. To this end, several solutions have been proposed. For example, in the ‘chemical approach’, open loop methods have been developed based on the detailed dynamic models of the processes. Any control technique requires a knowledge of the process to be controlled through mathematical models. These models may be developed either from detailed mass and energy balances, or through empirical input-output or “black-box” techniques. The most promising control techniques are probably optimal control, adaptive control, and their combinations. Optimal control is powerful because it utilizes directly the detailed non-linear plant model. Adaptive control developed for linear plants has already proven satisfactory, in spite of the highly nonlinear nature of the polymerizations. Undoubtedly, improved solutions will be obtained when this technique is extended to non-linear systems.
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  • 75
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    Polymer Engineering and Science 28 (1988), S. 230-236 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A comparison of the prediction of the theory of rubber elasticity with the experimentally observed variation of the shear storage modulus, G, as a function of crosslink concentration shows that deviations occur when the network strand concentration in diepoxide-diamine polymers exceeds approximately 1.5 mole kg-1. The rapid rise in G above this level is accounted for in terms of the increasing importance of non-Gaussian chain statistics and steric interactions. It is also established that the contribution from entanglements is significant and the behavior over the entire crosslink density range can be described by the following equation\documentclass{article}\pagestyle{empty}\begin{document}$$ G = \frac{{\phi \nu \rho RT}}{{1 - \psi \nu ^2}} + \varepsilon T_e \rho RT $$\end{document}where v and ∊Te are the concentrations of elastically active strands which orginate from fixed points and entanglements respectively, ψ is an empirical constant related to the importance of the non-ideal behavior, and φ is the so-called “front factor”. This latter constant is found to depend on the functionality of the network junctions, varying from 0.9, for a system with tetrafunctional junctions, to an average of 0.53 for those networks with trifunctional junctions.
    Additional Material: 3 Ill.
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  • 76
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    Polymer Engineering and Science 28 (1988), S. 237-256 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A detailed model for the prediction of the behavior of batch or continuous emulsion polymerization reactors has been formulated, and an efficient numerical scheme for simulation developed. The model makes use of population balance equations and detailed mechanisms for chemical and physical rate processes. The numerical procedure chosen for its solution is orthogonal collocation on finite elements. In this paper, a few comparisons with experimental data are presented to demonstrate the model validity. Finally, a parametric sensitivity study is carried out to identify the most important kinetic and physical parameters. In the sequel, a comprehensive comparison of model predictions with a wide variety of experimental data will be presented.
    Additional Material: 16 Ill.
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  • 77
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Accelerated aging of an Initial formulation of a nylon 6,6/poly(phenylene oxide) (PA/PPO) blend resulted in a significant loss in impact strength after a relatively short aging period. Fourier transform infrared (FTIR) spectroscopy showed considerable surface oxidation in air-aged samples. Scanning electron micrographs (SEM) of fracture surfaces showed evidence of embrittlement (glassy skin formation). This brittle skin apparently influenced crack propagation throughout the entire cross section of the test specimens. It was determined by nuclear magnetic resonance (NMR) analysis that the PPO phase of the blend contained a poly(styrene-butadiene) copolymer, probably added as an impact modifier. The susceptibility of the polybutadiene to oxidation, especially at elevated temperature, is believed to have caused the oxidation and surface embrittlement. However, the surface oxidation also resulted in a large loss in molecular weight of the nylon phase (m-cresol-soluble portion) and considerable cross-linking of the PPO phase (chloroform-soluble portion). Samples aged in inert atmosphere showed no skin formation nor loss in impact properties, thus confirming that oxidative degradation caused the embrittlement.
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  • 78
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    Polymer Engineering and Science 28 (1988), S. 341-359 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A technique has been developed to prepare crosslinked, porous/asymmetric membranes from poly(styrene-co-divinylbenzene). Mixtures of styrene monomer, divinylbenzene, benzoin (a photo-initiator), and some dead polystyrene are dissolved in a cosolvent and cast on a flat, transparent substrate. The coating is then irradiated with a UV lamp and subsequently phase separated by exposure to a nonsolvent bath. Pores are generated by phase separation induced by nonsolvent ingression. Crosslinking is achieved via the photo-initiated incorporation of divinylbenzene with styrene, while the membrane morphology evolves. A mechanism for the formation of crosslinked membranes prepared by this technique has been proposed. Experimental results systematically examine the effects of crosslinking and nonsolvent/solvent combinations on pore size and overall membrane structure. Temperature and solvent treatments on the finished membrane structure are also studied.
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  • 79
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    Polymer Engineering and Science 28 (1988), S. 377-380 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The melting points (Tm) were measured for oligomers obtained by a direct continuous esterification process between terephthalic acid and ethylene glycol. Multiple regression analyses of data were carried out, and an equation was obtained for predicting melting points with correlation coefficient of ∼0.99.
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  • 80
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    Polymer Engineering and Science 28 (1988), S. 37-41 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The amount of diethylene glycol (DEG) formed as a result of the dehydration reaction of ethylene glycol (EG) in the presence of terephthalic acid (TPA) was measured. It became clear that the amount of DEG formed at the boiling point of EG can be expressed by a regression equation. It was confirmed that by this equation, the amount of DEG formed under the carboxylic end group concentration of 0.0 to 0.6 Eq/kg and the reaction time of 0 to 20 h can be estimated with high accuracy.
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  • 81
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyamidethioethers were synthesized and evaluated as positive electron beam (EB) resists, The polyamidethioethers decomposed easily with EB exposure. At high doses (indicating low sensitivity), crosslinking reactions occurred for polyamidethioethers having C-S bonds produced by Michael addition, but the other polyamidethioethers did not crosslink. The C-S bonds produced by Michael addition may influence crosslinking rather than decomposition. The sensitivity of oxidized polyamidethioether was higher than that of the nonoxidized polymer with no change in resolution. The oxidized polyamidethioether had a high sensitivity and a high resolution, and is adaptable as a positive EB resist.
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  • 82
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    Polymer Engineering and Science 28 (1988), S. 58-63 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Changes in volume resistivity with temperature of carbon-black-filled polymers and a random copolymer of styrene and butyl methacrylate were measured. For polystyrene containing 20 wt % carbon black, of surface area 24 m2/g, the resistivity changes abruptly from 1013 to 106 ohm-cm above 150°C. Poly(butyl methacrylate) did not show well-defined changes in resistivity on heating. The random copolymer containing 16.7 or 28.6 wt % carbon black, of surface area 24 m2/g, showed a resistivity exceeding 1013 ohm-cm, that decreased to about 107 ohm-cm on heating above 120°C. This Copolymer containing 16.7 wt % carbon black, of surface area 625 m2/g, shows a resistivity of about 108 ohm-cm that decreases sharply to 103 ohm-cm by 150°C. Decreases in resistivity on increasing the temperature in the quiescent state are correlated with the observation of a yield stress at low shear rates in rheological studies. It is suggested that carbon black agglomerates at elevated temperature and forms an independent conductive network that prevents flow.
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  • 83
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    Polymer Engineering and Science 28 (1988), S. 200-206 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hydrolysis of a polycarbonate/polybutylene terephthalate (PBT) blend (50/50) was investigated by immersing molded samples in water baths between 21 and 98°C. Samples were also placed in a 100°C air circulating oven (dry environment). Changes in impact properties, dynamic mechanical properties, molecular weight, and thermal properties were followed. In 80°C water bath the material was found to embrittle in five to six days, and in circulating air oven at 100°C in less than 90 days. A sharp decline in molecular weight and changes in thermal and mechanical properties were observed. The activation energy for the embrittlement process in water was found to be 22 kcal/ mole. This value is between the activation energy for the hydrolysis of PC and that of PBT.
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  • 84
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 221-229 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effects of systematically varying the crosslink density on the mechanical relaxations in the glassy region of typical highly crosslinked diepoxide-diamine polymers are reported. Activation enthalpies and intensities for the β relaxation have been measured using a torsion pendulum at 1 Hz. The glyceryl groups, which are thought to be responsible for this process, are divided into a number of categories defined by the structure of the surrounding matrix. Concentrations of these units are calculated using probability theory, and a correlation is obtained with three measures of the relaxation Intensity, In the case of non-stoichiometric networks, variations in the intensity of the β relaxation are interpreted in terms of the simultaneous motion of each class of glyceryl group. The manner in which these processes combine to produce a composite peak appears to be unimportant. For the γ relaxation (-140°C), it is shown that at least four methylene units are needed in the diamine component before the process is observable, whereas only two consecutive methylene units in the center of the diepoxide molecule produce the relaxation.
    Additional Material: 13 Ill.
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  • 85
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 491-495 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Williams-Landel-Ferry (W-L-F) equation was shown to describe the temperature dependence of the viscosity of a sulfonium accelerated, amine cured epoxy resin that had been formulated for pultrusion. The reference temperature and the viscosity at the reference temperature of the W-L-F equation were found to be simple functions of the resin advancement as determined by isothermal differential scanning calorimetry, A method is described of constructing the baseline for temperature-programmed differential scanning calorimetry analyses in which the heat capacity is changing due to reaction.
    Additional Material: 12 Ill.
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  • 86
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 522-528 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A method for predicting the stress-strain and volumetric behavior of particulate composites from constituent properties has been developed for large values of strain. This approach allows a simple model for systems in which damage occurs without resorting to complicated constitutive equations. An energy balance derived from the first law of thermodynamics and the equations of linear elasticity calculates critical strain values at which filler particles will dewet when subjected to uniaxial tension and superimposed pressure. Calculations of critical strains over the entire strain history using reevaluated material properties accounting for the damage yield highly nonlinear stress-strain and volumetric curves. Experimentally observed dependences on particle size, filler concentration, matrix and filler properties, and superimposed pressure are correctly predicted. The method has no adjustable parameters, and allows several idealized models of the dewetting process to be examined. Comparisons of model predictions to experimental data show good agreement.
    Additional Material: 8 Ill.
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  • 87
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 534-537 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A model solvent technique is presented according to which polystyrene (PS) foam scrap is recovered in the form of small grains. The process mainly comprises dissolution of the waste into benzene or toluene, filtering, dispersion of the solution into water, and subsequent distillation. The alternative solvent/non-solvent systems have been studied on the basis of solution rheology, operating conditions during the recycling procedure, and extents of recovery of PS and solvent. Eventually, the toluene/water system has been chosen for a larger scale experiment (LSE), the product of which was used for characterization work. No influence on critical properties was detected due to the solvent technique followed.
    Additional Material: 3 Ill.
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  • 88
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 553-553 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 89
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 554-561 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper discusses the cost of high technology and its benefits to commercial air transportation. The manufacturer's dilemma today is that, while one could pay a 16 percent price premium to obtain a 10 percent reduction in fuel cost in the late 1970s, in 1985 that price premium has diminished to only 2-1/2 percent to achieve a 10 percent fuel saving. Consequently, we must obtain the benefits of high technology at an extremely low cost. Four areas are discussed in some depth: Aerodynamics, including the effects of computational fluid dynamics, wing design, and laminar flow; structures, including the effects of new materials, both metallic and nonmetallic, and the automated tools necessary to build the nonmetallic structure; avionics, including both fly-by-wire and fly-by-light, and the improvements due to high-speed digital computers as well as flat panel flight deck displays; and propulsion systems, including the effects of high-bypass ratio, high-pressure ratio turbofan engines, and single and counter rotation turbopropellers. The final result is an integration of these four areas of technology into a composition transport aircraft and the resulting performance.
    Additional Material: 28 Ill.
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  • 90
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 562-567 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An epoxy resin and a sized carbon fiber have been used to produce a light-weight filament wound case for the Space Shuttle. The sizing facilitates fiber handling during winding but may affect the amount of resin absorbed by the fiber during impregnation and the final mechanical properties of the composite. Naval Ordnance Lab rings were wound to study the effect of the sizing content on the resin absorption by the fiber bundles, the final tensile properties of the composite, and the type of failure observed at burst. The resin content of the rings studied was between 20 to 40 percent, and the sizing content, 0 to 1.6 percent by weight. Results showed that the sizing content was a critical parameter which determined the amount of resin absorbed by the fibers. The final tensile strength was dependent on the amount of sizing present. The tensile strength decreased by as much, as 60 percent when a low resin and high sizing content were present. The type of failure at burst was a function of resin content rather than size content.
    Additional Material: 8 Ill.
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  • 91
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 92
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1-8 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Results of a computer study are reported applying data reconciliation and interpretation techniques to a single-stage flash operation. Measured errors in the process variables are significantly reduced. The techniques are successfully extended to estimate flash efficiency. The flash efficiency is estimated using two methods: (1) a statistically rigorous simultaneous data reconciliation and efficiency estimation procedure, and (2), a faster, nonrigorous sequential procedure. It is found that the simultaneous procedure provides better measured variable and flash efficiency estimates.
    Additional Material: 8 Ill.
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  • 93
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 9-16 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of supercritical ethane on the high-pressure phase behavior of the polystyrene-toluene system is experimentally investigated. Adding 17.8 wt. % ethane to the polystyrene-toluene solution lowers the temperature of the lower critical solution temperature (LCST) curve by 162°C, 22.5 wt. % lowers the temperature of the curve by 231°C, and with 24.9 wt. % the curve is shifted to such low temperatures that it merges with the upper critical solution temperature curve. In practice this means that polymer solutions can be separated at lower temperatures where thermal degradation of the polymer is less. Also, more than 99 wt. % of the polystyrene is recovered in the polymer-rich phase after the solution phase splits. Patterson's corresponding states treatment is used to model the LCST data.
    Additional Material: 7 Ill.
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  • 94
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 17-24 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Reaction schemes for the thermal cracking of paraffins, naphthenes, olefins, and aromatics, and the associated rate equations, are generated by an algorithm based upon Boolean relation matrices. In order to reduce calculation times for the heavier components, a self-learning system is introduced. This self-learning system avoids repetition of identical calculations by recognizing intermediate species, for which the reaction schemes have already been generated. The software includes routines for standardizing the representation of the species, an information retrieval system, and libraries containing the necessary information for recognition of the species and the reaction schemes for these species.
    Additional Material: 7 Ill.
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  • 95
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 37-44 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady states with different flow rates and temperature profiles may exist in a monolith or multitube packed-bed reactor operating under a prescribed pressure drop, due to the coupling among the species, energy, and momentum balances, and the change of physical properties with temperature and pressure. Criteria are derived predicting the conditions under which thermoflow multiplicity can occur for a gaseous reaction involving a change in the number of moles. In general, a reaction-induced volume increase enables thermoflow multiplicity to occur for reactions with a lower adiabatic temperature rise. A surprising finding is that thermoflow multiplicity may be found for an isothermal reaction involving a volume decrease. This point emphasizes the difference in the feedback mechanism leading to thermoflow and thermokinetic multiplicity.
    Additional Material: 8 Ill.
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  • 96
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 25-36 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of diagnosing faults in chemical plants can be efficiently addressed by a hierarchical procedure involving successive narrowing of the space in which the fault search is conducted. A technique is presented for narrowing diagnostic focus useful in the first stages of a diagnostic search. Based on a decomposition of the process according to function, the technique assesses the functionality of process systems based on measurements of controlled and manipulated variables. A procedure for identification of possibly faulty systems and units from the system states is outlined. Detailed diagnosis, not treated in this paper, would be applied after candidate systems or units are located. An example is presented using a hypothetical chemical reaction process.
    Additional Material: 6 Ill.
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  • 97
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 55-68 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass transfer coefficients for the solution, without reaction, of oxygen in cyclohexane over a wide range of temperature and pressure have been measured in a flat interface reactor (FIR) and a gas sparged stirred-tank reactor (STR). Solubilities have also been measured and it is suggested that a modified Henry's law coefficient of 1.09 × 10-2 kmol/m3 · bar can be regarded as constant over the temperature range 293-435 K. The physical mass transfer coefficient in the STR shows very little variation over this temperature range and a value of 3.5 × 10-4 m/s can be assumed for 423-435 K. However, coefficients in the FIR increase with agitation rate as expected. The difference is ascribed to interference by neighboring bubbles in the transfer process, when diffusivities are high, and also to the lowering of surface tension at high temperatures. A model proposed by Gal-Or and Resnick is reviewed in its application to the present system.
    Additional Material: 11 Ill.
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  • 98
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 45-54 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical and experimental study on the dissolution of porous media by flowing acid has been carried out. Dissolution of the media results in an evolution of the pore geometry and the formation of random flow channels. The goal is to predict the range of conditions under which channels will form, and the effects of various parameters on the structure of the channels and on their rate of propagation through the media. A random network model is used to describe the behavior of the stochastic, rootlike channels that form during flow and dissolution in carbonate rock and in other systems. The structure of the flow channels that form as a result of acid attack are characterized and studied using a Wood's metal casting technique. A comparison of model results shows that the rates of channel formation and growth are intimately related to the developing structure of the channels (size of branches and degree of branching), which in turn is controlled by factors such as the fluid velocity and the rate of reaction. Depending on the experimental conditions, the channels range from a single conduit with a minimum of branching to a highly branched, spongy network of channels. The dependence of permeability increase and channel branchedness on injection rates and acid diffusion rates is described by the Damkohler number for flow and reaction.
    Additional Material: 18 Ill.
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  • 99
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 69-80 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid phase oxidation of hydrocarbons is a major source of organic chemicals. This paper concerns itself with the oxidation of cyclohexane. The process is one in which gas absorption is accompanied by chemical reaction, but little information has been reported. A major factor has been safety considerations, the Flixborough explosion being a constant reminder. In this paper attention is given to the kinetics and to the interaction of kinetics and mass transfer, showing that in this autocatalytic system the dissolved oxygen level rises to saturation and falls as the rate of reaction increases. Initially zero order in oxygen, the reaction becomes first order at low oxygen levels. Oscillations and enhancement due to reaction within the boundary layer are noted. A kinetic model is developed based on simplification of the accepted free radical scheme and it is reasonably successful in accounting for the results reported. Experiments at temperatures up to 170°C and 70 bar using uncatalyzed reaction are reported from three different reactors: a homogenous batch reactor, a flat interface reactor, and a sparged agitated bubbling reactor.
    Additional Material: 15 Ill.
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  • 100
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1634-1648 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rigorous analytical methods for consistent modeling of control structures for multivariable processes are presented. The continuous distillation process is used to illustrate the methods, but the basic ideas, and more specifically the transformations and consistency relations derived, are valid in general.If steady-state operating data and the process gains of an arbitrary control structure are known, it is possible to calculate the process gains of any feasible control structure. A general expression relating the process gaisn of different control structures is derived. In general, the process gains must also satisfy certain consistency relationships which can be derived from first principles, e.g., steady-state material balances.The usefulness of the results is illustrated by control structure transformations and reconciliation of process gains, by an application to process dynamics, by synthesis of noninteracting control loops, and by derivation of analytical relationships useful in relative gain analysis.
    Additional Material: 1 Ill.
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