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  • Organic Chemistry  (8,058)
  • ddc:080
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  • 1
    facet.materialart.
    Unknown
    Publication Date: 2019-10-24
    Keywords: ddc:080
    Language: German
    Type: annualzib , doc-type:report
    Format: application/pdf
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  • 2
    facet.materialart.
    Unknown
    Publication Date: 2019-10-24
    Keywords: ddc:080
    Language: German
    Type: annualzib , doc-type:report
    Format: application/pdf
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  • 3
    Publication Date: 2016-06-09
    Description: Im Rahmen dieser Arbeit wurde ein individuell anpassungsfähiges Modell entwickelt und implementiert, das die Perfusion in menschlichen soliden Tumoren beschreibt und für verschiedene Zeitpunkte w¨ahrend regionaler Hyperthermie ein lokal abhängiges Temperaturprofil berechnet. Da vor jeder Simulation alle wichtigen Parameter anhand von Ultraschall-, MRT- oder Angiogrammbildern individuell bestimmt werden können, wird eine patientenspezifische Aussage ¨uber das intratumorale Antwortverhalten bereits vor der eigentlichen Behandlung möglich. In Abh¨angigkeit von der Qualität der zur Verfügung stehenden anatomischen Daten über das zu simulierende Gebiet kann das Modell beliebig verfeinert oder bei Mangel an detaillierten Informationen auch mit Minimaldaten und reduzierter räumlicher Genauigkeit benutzt werden. Die für eine Simulation benötigten 2- oder 3- dimensionalen Geometrien können leicht mit der am ZIB entwickelten Software Amira erstellt und zur Berechnung in KARDOS, einem ebenfalls am ZIB implementierten Löser für nichtlineare partielle Differentialgleichungen, eingelesen werden. Mit Hilfe dieses Modells wird eine einfache, aber realistische und aussagekräftige Simulation für die Therapieplanung einer klinischen Hyperthermieanwendung ermöglicht, die innerhalb kurzer Zeit vorbereitet und durchgeführt werden kann.
    Keywords: ddc:080
    Language: German
    Type: masterthesis , doc-type:masterThesis
    Format: application/pdf
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  • 4
    Publication Date: 2016-06-30
    Description: In dieser Arbeit werden effiziente Co-Reservierungs-Algorithmen vorgestellt, mit denen Rechenressourcen mehrerer Cluster im Grid reserviert werden können. Es werden fünf Algorithmen vorgestellt, die flexible Co-Reservierungsanfragen ermöglichen. In einer Co-Reservierungsanfrage müssen die angeforderten CPUs der Teilreservierungen exakt festgelegt werden. Die Cluster und die Startzeiten, bei denen die Teilreservierungen durchgeführt werden, ermittelt ein Co-Reservierungs-Algorithmus erst bei der Anfragebearbeitung. Die Benutzer können die Startzeit in der Anfrage eingrenzen, in dem sie eine früheste Startzeit und eine Deadline angeben. In den bisher entwickelten Reservierungsverfahren können Benutzer nur starre Co-Reservierungsanfragen stellen, in denen sie für alle Attribute der Teilreservierungen exakte Werte angeben müssen. Eine flexible Co-Reservierungsanfrage erlaubt einem Grid-Reservierungsdienst optimierte Reservierungsvarianten durchzuführen, da er aus vielen Reservierungsvarianten auswählen kann. Die Anwendungen von lokalen Benutzern können durch die Grid-Reservierungen verzögert werden. Bei der Auswahl der Reservierungsvarianten kann ein Grid-Reservierungsdienst dies berücksichtigen und den negativen Einfluß der Grid-Reservierungen verringern. Bei zwei Co-Reservierungs-Algorithmen werden auch zusätzliche Sortiervorgaben des Klienten bei der Auswahl der Reservierungsvarianten beachtet. Die Algorithmen wurden durch Simulationen mit dem Workload eines realen großen Supercomputers ausgewertet. Die Untersuchungen zeigen, daß sowohl die lokalen als auch die Grid-Benutzer von den flexiblen Anfragen profitieren können. Den lokalen Benutzern wurden die Ressourcen weniger oft durch zu früh gestellte Reservierungsanfragen entzogen. Die Grid- Benutzer können ihrerseits komfortabel eine optimierte Reservierungsvariante durchführen lassen.
    Keywords: ddc:080
    Language: German
    Type: masterthesis , doc-type:masterThesis
    Format: application/pdf
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  • 5
    Publication Date: 2016-06-30
    Keywords: ddc:080
    Language: German
    Type: masterthesis , doc-type:masterThesis
    Format: application/pdf
    Format: application/pdf
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  • 6
    Publication Date: 2020-08-05
    Keywords: ddc:080
    Language: English
    Type: masterthesis , doc-type:masterThesis
    Format: application/pdf
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  • 7
    Publication Date: 2020-08-05
    Description: In dieser Diplomarbeit werden grundlegende Probleme der kostenoptimalen Dimensionierung von Telekommunikationsnetzwerken untersucht. Diese werden als lineare gemischt ganzzahlige Programme formuliert, wobei sich in der Modellierung auf die Konzepte Routing und Kapazitätszuweisung beschränkt wird. Es werden parallel drei übliche, aus der Praxis motivierte Möglichkeiten behandelt, die auf gerichteten oder ungerichteten Kanten eines Netzwerkes installierte Kapazität zu nutzen. Diese unterscheiden wir als DIrected, BIdirected und UNdirected. Die studierten Probleme treten als Relaxierungen vieler realistischer Fragestellungen der Netzwerkoptimierung auf. Sie enthalten elementare Strukturen, deren Studium ausschlaggebend ist für das Verständnis komplexerer Modelle. Letztere können zusätzliche Erfordernisse berücksichtigen, wie zum Beispiel die Ausfallsicherheit von Netzwerken. Zur Lösung solcher NP-schweren Optimierungsprobleme werden erfolgreich Branch & Bound und Schnittebenenverfahren kombiniert (Branch & Cut). Für die Wirksamkeit dieser Algorithmen ist es sehr nützlich, möglichst genaue Kenntnisse der Struktur der Seitenflächen der zugrundeliegenden Polyeder zu haben, welche die konvexe Hülle der Lösungsmenge beschreiben. Es sind starke gültige Ungleichungen zu finden, welche hochdimensionale Seitenflächen oder sogar Facetten definieren. Diese sollten zudem schnell separiert werden können und die numerische Stabilität der Algorithmen möglichst nicht beeinflussen. Diese Arbeit beschäftigt sich im Wesentlichen mit der sehr allgemeinen Rundungstechnik Mixed- Integer Rounding (MIR) zur Verstärkung gültiger Ungleichungen unter Verwendung der Ganzzahligkeitsnebenbedingungen. Es wird eine MIR-Prozedur motiviert, bestehend aus den Schritten Aggregieren, Substituieren, Komplementieren und Skalieren, welche durch Ausnutzung der Struktur der gegebenen Parameter zu einer gültigen Basisungleichung führt, die dann durch MIR eine starke und oft facetten-induzierende Ungleichung gibt. Es werden verschieden Klassen solcher Ungleichungen untersucht und auf ihre Praxistauglichkeit beim Einsatz in Branch & Cut-Verfahren getestet. Nach einer kurzen Einführung werden in Kapitel 2 die für uns in dieser Diplomarbeit relevanten Probleme definiert. Kapitel 3 gibt eine ausführliche Übersicht über die Technik MIR.Wir beschäftigen uns vor allen Dingen mit den Begriffen Superadditivität und Lifting und behandeln Aspekte wie Numerik und beschränkte Variablen. Kapitel 4 und Kapitel 5 umfassen Untersuchungen zu so genannten cut sets. Diese Polyeder werden durch Schnitte in Netzwerken definiert und relaxieren die von uns behandelten Probleme. Hauptsächlich durch MIR entwickeln wir sowohl neue als auch bekannte Klassen von facetten-definierenden Ungleichungen für cut sets, wobei strukturelle Unterschiede herausgearbeitet werden, die durch die drei verschiedenen Typen der Kapzitätsbereitstellung und durch beschränkte Variablen entstehen. Als ein zentrales Resultat wird bewiesen unter welchen Bedingungen facetten-induzierende Ungleichungen für cut sets auch Facetten der zugehörigen relaxierten Polyeder sind. Im Kapitel 6 geben wir weitere Typen von MIR-Ungleichungen an, die auf anderen Netzwerkstrukturen basieren und weisen ferner auf offene Fragen sowie interessante Ideen hin. Das Kapitel 7 widmet sich schließlich der Entwicklung und Implementation von Separationsalgorithmen. Wir testen einige der entwickelten Ungleichungsklassen mit Hinblick auf Ihre Wirksamkeit zur Lösung von realistischen Problemen der Netzwerkdimensionierung aus der Telekommunikation und diskutieren die Ergebnisse.
    Keywords: ddc:080
    Language: German
    Type: masterthesis , doc-type:masterThesis
    Format: application/pdf
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  • 8
    Publication Date: 2016-06-30
    Description: Diese Arbeit dokumentiert den Entwurf und die Implementierung einer NFS-Schnittstelle zum ZIBDMS. Das ZIBDMS, welches derzeit am Zuse-Institut Berlin entwickelt wird, ist ein Managementsystem für verteilte Daten in heterogenen Umgebungen [10]. Es soll die einfache Benutzung von Mechanismen zur Replikation sowie neue Möglichkeiten des Zugriffs und der Verwaltung von Metadaten und Datenobjekten ermöglichen. Dem Nutzer bietet das System verschiedene Sichten: Neben der klassischen, hierarchischen Sicht mit Verzeichnissen und Dateien wird auch eine attributbasierte Zugriffsmethode angeboten, in der Datenobjekte ausschließlich über Attribut/Wert-Paare referenziert werden. Für den Benutzer transparent, soll sich das System im Hinblick auf die Verfügbarkeit von Daten und Metadaten selbsttätig optimieren. Um Skalierbarkeit gew¨ahrleisten zu können, werden intern Peer-to-Peer- Techniken entwickelt und benutzt. Die NFS-Schnittstelle erhöht die Nutzbarkeit des Systems, da Client- Implementierungen für nahezu alle Betriebssysteme zur Verfügung stehen. Der Benutzer kann so über das gewohnte Dateisystem Daten und Metadaten pflegen, ohne spezifisches Vorwissen zu benötigen. In dieser Arbeit wird untersucht, inwiefern sich die Semantik des ZIBDMS auf jene des NFS-Protokolls übertragen läßt. Weiterhin wird das Konzept von Pseudodateien beschrieben und diskutiert, inwiefern es eine brauchbare Lösung darstellt, den im Vergleich zur NFS-Semantik wesentlich größeren Funktionsumfang des ZIBDMS für den Anwender nutzbar zu machen. Pseudodateien sind nicht-persistente Objekte, welche für den Benutzer als reguläre Datei sichtbar werden und die erweiterte Funktionalitäten wie die Bearbeitung von Metadaten oder die Platzierung von Replikaten über die Dateisystem-Sicht des NFS zur Verfügung stellen sollen. Schließlich werden Leistungsmessungen an den benutzten Komponenten des ZIBDMS vorgenommen und vergleichbaren Systemen gegen übergestellt. Die Aufmerksamkeit liegt hier auf der zugrundeliegenden Katalog-Technologie sowie dem durch das NFS-Protokoll verursachten Overhead.
    Keywords: ddc:080
    Language: German
    Type: masterthesis , doc-type:masterThesis
    Format: application/pdf
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  • 9
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Analysis of Technical Diphenylolpropane (Bisphenol A) by High-performance Liquid ChromatographyA method for the investigation of technical 2,2-bis-(4′-hydroxyphenyl)-propane (bisphenol A) by high-performance liquid chromatography is described. Microspherical silicagel in unmodified (adsorption) and C16-modified form (reversed phase) was used as support. It has been found that supports with small particle sizes (5 μm) achieve their optimum efficiency only when they possess an adequately narrow optimum particle size distribution.The investigations were carried out using a self-made apparatus. Details concerning an UV-cell being insensitive to gas bubbles as well as a differential refractometer, which can be disassembled, are presented.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 65-70 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Sterische Effekte in der STOBBE-Kondensation von 3,4-disubstituierten Acetophenonen mit Dimethyl-methylsuccinatDie Kondensation von 3,4-Dimethyl-, 3,4-Dimethoxy- und 3,4-Dichloracetophenon mit Dimethylsuccinat in Gegenwart von Kalium-t-butylat lieferte in jedem Fall ölige Gemische der stereoisomeren Halbester 1 und 2. Während die (E)-Halbester 1 zu den entsprechenden 1-Acetoxy-3-nahpthoesäureestern 5 cyclisiert werden konnten, ergaben die (Z)-Halbester 2 unter den gleichen Bedingungen die entsprechenden 3-Oxo-inden-2-(α-subst.)-essigsäuren 7.Das Isomerenverhältnis wird mit sterischen Wechselwirkungen in den γ-Lacton-Zwischenprodukten 8 erklärt.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 11
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 93-101 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Reaction of α,β-Dihalogeno-propionitriles with Monosubstituted Hydrazines  -  A Simple Synthesis of 1-Substituted 3- or 5-Amino-pyrazolesIn methanol hydrazines 3, and α,β-dihalogeno-propionitriles 1, 2 even at 0°C irreversibly yield 3 · HX, and α-halogenoacrylonitriles 4, 5 (A1). Fast addition of alkyl- and aralkyl- hydrazines 3 to 4, 5 (C) gives 1-substituted 1-(2′-halogeno-2′-cyan-ethyl)-hydrazines 6, the addition of arylhydrazines 3 to 4, 5 (D) 1-aryl-2-(2′-halogeno-2′-cyan-ethyl)-hydrazines 8. In methanol 6 spontaneously cyclise (E) to hydrogen halides 7 · HX of 1-alkyl- and 1-aralkyl-3-amino-pyrazoles, 8 with 2 moles of acids (F) to salts 10 · 2HY of 1-aryl-4-halogeno-5-imino-pyrazolidines, and the free 10 spontaneously (G) to hydrogen halides 9 · HX of 1-aryl-5-amino-pyrazoles. Mechanisms (A1), (C), (D), (E), (F), and (G) are proved by t.l.c., 1H-n.m.r., and isolation of intermediates, the structures of 7 resp. 9, using the significant 1H-n.m.r.-parameter ΔHMPTCDCl3. Simple general syntheses are described for 3-amino-pyrazoles 7 (R = H, alkyl, aralkyl) or 5-amino-pyrazoles 9 (R = aryl) starting with α,β-dihalogeno-propionitriles 1, 2, and for α-bromo-acrylonitrile 5.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 137-140 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Identification and Determination of Byproducts of the Acrylonitrile Synthesis
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 141-150 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthese von hexakoordinierten Ketiminderivaten des Germanium(IV)
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 175-176 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Verbesserte Synthese von 4,6-Diamino-2-nitro-m-xylen durch Reduktion von 2,4,6-trinitro-m-xylen
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 186-196 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quantum Chemical Investigation of the Cycloaddition of Phenol to Phenylcyanate as an Example for the Study of M.O. Correlation Diagrams of Systems without Symmetry Elements in the Transition State.There is experimental evidence, that the N-monomethylaniline-catalyzed addition of phenol to phenylcyanate proceeds via a six-membered, cyclic transition state, in which N-mono-methylaniline is involved, whose presence as a catalyst is necessary. In the present work is investigated by quantumchemical considerations, whether an analogy can be found between this reaction and a symmetry-allowed [2 + 4]cycloaddition of π-systems. Using the CNDO/2-method an energy curve has been calculated, having only a small activation barrier. The wavefunctions at some points of the reaction coordinate have been localized to bond orbitals, which are then taken into some linear combinations. These do not show any change of their nodal behaviour at points belonging to the starting resp. to the final state of the reaction. This shows, that the above mentioned analogy is valid. For the [2 + 2]cycloaddition in absence of the catalyst, on the contrary, the energy curve shows a very high activation energy, and the nodal behaviour of the combined localized orbitals is changed on passing from the starting to the final state.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 243-248 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass Spectroscopy of Natural Compounds. I.Comparative Investigation of Anion-Cation Mass Spectra of 2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl EstersThe electron attachment mass spectra (anion mass spectra) of 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl esters with different structures of the acids are discussed and compared with the corresponding electron impact spectra. In contrast to the cation mass spectra the molecular ion peak appears in all the anion mass spectra.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 267-273 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Acids HOOCCH(SX)CH(SX)COOH (X = CH2COOH, C6H5) and their Methyl EstersThe acids HOOCCH(SX)CH(SX)COOH with X = CH2COOH and C6H5 and their methyl esters have been prepared by addition of thiols to acetylene dicarboxylic acid as salt and methyl ester. The structures and configurations have been discussed.
    Additional Material: 1 Tab.
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  • 18
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 308-314 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of 3 Shortened, Repeatedly by Ala Substituted Analogues of the Insulin B Chain in Protected FormStarting from the previously described fragments of the insulin B chain with native or partielly modified amino acid sequence, the 3 terminal shortened, additionally in several positions by Ala respectively in position 6 by Val substituted analogues B1-27(Ala9, Ala10, Ala27), B4-27-(Ala4, Ala9, Ala10, Ala27) (1) and B4-27(Ala4, Val6, Ala9, Ala10, Ala27) were prepared in protected form.
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  • 19
    Electronic Resource
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 323-326 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Concerning the Extractive Behaviour of Long-chain Alkanesulphonates
    Additional Material: 3 Tab.
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  • 20
    Electronic Resource
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 341-344 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Potentiell psychopharmakologische Verbindungen. II. Synthese einiger neuer fluorhaltiger Pyrazolo[1,5-a]pyrimidine
    Additional Material: 1 Tab.
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  • 21
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 22
    Electronic Resource
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 370-378 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of Triorgano-amido-arsenic-, -antimony- and -bismuthhalidesThe preparation of some triorgano-amido-metalhalides by addition of various N-haloamides to organometallic compounds of the type R3M (M = As, Sb, Bi) in polar aprotic solvents under mild conditions is described. The properties of these derivatives are studied. In solution equilibriums of triorgano-amido-antimonyhalides, the corresponding dihalides, and diamido compounds are existing, as we proved by 1H-n.m.r.
    Additional Material: 2 Tab.
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  • 23
    Electronic Resource
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 404-406 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Photochromism of the o-Nitrobenzylpyridines in Supercooled Melts2-(2′, 4′-dinitrobenzyl)-pyridines 1 a-g and 4-(2′,4′-dinitrobenzyl)-pyridine 2 form supercooled melts which are photochromic on u.v.-irradiation. The photochromism and the kinetic stability of the coloured form in supercooled melts are quite different from the behaviour in ethanolic solution. The differences are explained on the basis of a polymethin constitution of the coloured form.
    Additional Material: 1 Tab.
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  • 24
    Electronic Resource
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 429-436 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyclization Reactions of 1-[2-amino-1-cyano-2-thio-]ethenepyridinium Ylides1-[2-Amino-1-cyano-2-thio-]ethene-pyridinium ylides 1 can be alkylated with methyliodide or α-haloesters and α-haloketones, respectively, to form 1-[2-alkyl(aryl)amino-1-cyano-2-methylthio-ethene-1]pyridinium iodides 2a--e or 1-[2-alkyl(aryl)-amino-1-cyano-2-alkoxy(aryl)-carbonylmethylthio-ethene-1] pyridinium salts 3a-f. With the exception of 3a-b the compounds 3 or 1 react with haloketones to yield 1-[4-amino-2-alkyl-(aryl)amino-5-benzoyl-thiene-3]pyridinium salts 4a-m or 3-alkyl-4-aryl-2-(1-cyano-1-pyridinium)methylene-Δ4-thiazoline salts 5a-f.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 25
    Electronic Resource
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 420-428 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Deactivation Behaviour of Arenes and Heteroarenes. XVII. Fluorescence Quenching of Cations by AnionsFluorescence quenching, caused by cation-anion interaction in the excited state, was investigated for the combinations of 13 acridinium and acridizinium ions (fluorophors) and chloride, bromide and iodide (quenchers). The obtained dependence of rate constants of dynamic quenching process on the acceptor properties of cations in the case of chloride is interpreted by the model of electron transfer in the encounter state. The resulting limit-rate constants of quenching are greater than those of diffusion of neutral molecules, caused by the Coulomb-interaction between cation and anion.
    Additional Material: 2 Ill.
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  • 26
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 437-442 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Propellane. I. 3,6,10,13-Tetrathia(4,5,11,12-trans-dicyclohexano)-(6,6,1)propellanDurch Reaktion des 1,1,2,2-Tetrabrommethylcyclopropans mit trans-1,2-Dimercaptocyclohexan wurde die tricyclische Verbindung 1 mit Propellan-Struktur erhalten. Die Struktur dieser Verbindung wurde mit Hilfe spektroskopischer Daten und der Fragmentierung der Massenspektren ermittelt. Für die beiden achtgliedrigen Ringe wird eine “twist-crown” Konformation vorgeschlagen. Die Oxidation des (6,6,1)Propellans 1 führt zu dem entsprechenden Tetrasulfon, in dem der Cyclopropan-Ring erhalten bleibt.
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  • 27
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 449-465 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: MO-LCAO Calculations on Polymethines. XI. Local Spectral Excitations in Polynuclear Cyanine DyesVarious branched-conjugated cyanine dyes display long-wavelength absorption bands similar in position to those of their straight-chain substructures. According to the analysis of results of PPP-type calculations this close similarity results from a partial localization of the electronic transitions, whereas the participating electronic states are highly delocalized. The long-wavelength absorptions of symmetrically-branched trinuclear cyanine dyes have an entire molecular chromophore origin resulting from twofold degenerate electronic transitions. Lowering of the symmetry brings about a splitting of the colour-band.In contrast to the branched-conjugated cyanine dyes various tetranuclear cyanine dyes can be considered as being composed of two subchromophores either directly linked or joined through a conjugative bridge. In accordance with PPP configuration analyses and LHM-type calculations the splitting of the colour band is best understood by composite-molecule approaches. In this context the applicability of the simple molecular exciton theory is discussed.
    Additional Material: 5 Ill.
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  • 28
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Umwandlung von 4-Hydroxy-5-nitro-4,5-dihydrothymin unter alkalischen Bedingungen
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  • 29
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 519-521 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Untersuchungen an Yliden: Reaktion von N-Phenacylpyridiniumbromiden mit aromatischen Diazoniumsalzen
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  • 30
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 541-543 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Isosteric Heat of Adsorption of n-Ethane on Zeolites NaX and NaYUsing a volumetric method isotherms of adsorption of ethane on zeolites NaX and NaY were measured. The Clausius-Clapeyron equation was used to calculate the isosteric heat of adsorption of the paraffin on both molecular-sieves. These enthalpies show a linear dependence of the amount of adsorbed molecules. The zeolite with the higher charge density shows a larger heat of adsorption. The difference in the heat of adsorption is explained by adsorption on different centers in the cavity of both zeolites.
    Additional Material: 1 Ill.
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  • 31
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 555-564 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Reaction of E-ß-Nitro-styrenes with 3-Pyrazolidone-azomethinimines - a Non-cisoid 1,3-Dipolar CycloadditionNormal flipping at both ring-N-atoms postulated, the thermal addition of E-β-nitro-5a or E-(4-chloro-β-nitro)-styrene 5b to 3-pyrazolidone-azomethinimine-1,3-dipoles 4a or 4b formally can yield 8 isomeric pairs of enantiomers, 4 of which are “permitted”(cisoid) and 4 of which are “forbidden” according to the concerted [π4s + π2s]-mechanism. If the addition of 5 to 4 is regiospecific, 2 “permitted”(cisoid) (1 and 6) and 2 “forbidden”(3 and 10) isomers are conceivable. From pure 5a and 4a we regiospecifically got 1ref,3trans-diphenyl-2cis-nitro-6a (75%) and 1ref,3trans-diphenyl-2trans-nitro-5-oxo-perhydropyrazolo[1,2-a]pyrazol 10a (25%), from 5b and 4b the corresponding bis(4-chloro-phenyl)-isomers 6b and 10b. The sodium salts 8a, b, gained from 6a, b and 10a, b, are identical. With H⊕ (D⊕) in water (D2O) 8a, b give 6a, b (2-deutero-6a, b = 7a, b). The 1H-n.m.r. spectra of 6a, b, 7a, b, 8a, b, 10a, b, and of the 2-amino-isomers 11a/12a, corresponding to 6a/10a, are discussed.For the first time products of a non-cisoid 1,3-dipolar cycloaddition (10a, b) were isolated. In the discussion (E ⇌ Z)-isomerization of 5a, and conceivable mechanisms of isomerizations 6a → 10a are excluded. Theoretical consequences are suggested.
    Additional Material: 2 Ill.
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  • 32
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Characterization of the Radiationless Deactivation of the Lowest Excited Singlet State of N-Methylacridone by Means of the Triplet Sensitized (E) → (Z) Photoisomerization of (E)-StilbeneThe (E) → (Z) isomerization of (E)-stilbene photosensitized by N-methylacridone (A) has been studied under anaerobic conditions at 298 K in dependence on the solvent as well as the concentration of iodoethane as heavy atomquencher. For the experimental conditions the quantum yield of the triplet-triplet energy transfer 3A* → 3E* is unity and the photoreaction is homogenous.The ISC quantum yield of the sensitizer N-methylacridone was determined from the initial slopes of the plotted concentration-time functions in the solvents methanol, N-methylformamide, acetonitrile, dichloromethane, tetrahydrofuran, benzene and tetrachloromethane, respectively. The comparison of the ISC quantum yields ψisc and the quantum yields of fluorescence ψf indicate that ψf + ψisc = 1 is true for the used solvents; the IC process is negligible.
    Additional Material: 9 Ill.
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  • 33
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 643-654 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Liquid Crystal ThiazolesThe synthesis of 2,4- and 2,5-disubstituted thiazoles is described and their melting and clearing points are investigated. The influence of the thiazole ring system on the formation of crystalline-liquid phases is discussed.
    Additional Material: 5 Ill.
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  • 34
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Model Calculations on the Counterion Effect in the Cationic Polymerization; Geometry Optimization and Behaviour of the Mixed Halogenoantimonates SbClnBr-n-6.The CNDO/2 method including geometry optimization with respect to the energy has been applied to calculate the structure and the electronic properties of the complex anions SbClnBr-6-n. Independently on the composition of the anions the bond lengths Sb-X (X = Cl, Br) remain those of the pure antimonates.The HOMOs are delocalized over the ligand sphere. They mainly contain components of Br and are lifted by increasing Br amount. The LUMOs have central atom character and are lowered by Br. Charge distribution and Wiberg bond indices indicate extra easy cleavage of the Sb-Br bond if Cl holds a trans position to Br. The computed data agree with spectral properties, the acceptor behaviour and the decay trend of the antimonates SbClnBr-6-n.
    Additional Material: 2 Ill.
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  • 35
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 699-703 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reactions of Open Chain and Cyclic Ketene-S,S-acetales with Amines
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  • 36
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 37
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 775-786 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Halogenolipids. III. Alkyl Glyceryl Ether AnaloguesSynthesis of the halogeno analogues of alkyl glycerol ether, 3-fluoro-1-O-hexadecyl-(octadecyl)-propane-1, 2-diol, 2-fluoro-1-O-hexadecyl(octadecyl)-propane-1, 3-diol, 2-chloro-1-O-hexadecyl-propane-1,3-diol and 3-fluoro-2-O-hexadecyl-propane-1,2-diol, which are of interest as potential cytostatic agents, is described.
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  • 38
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 804-812 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthese von N-(Formylphenyl)- und N-(Acetophenyl) Derivaten des Harnstoffs und der CarbaminsäureAminobenzaldehyde und Aminoacetophenone reagieren in Gegenwart von tertiären Aminen, z. B. Pyridin oder Triethylamin, mit Alkylchloroformiaten und Alkylisocyanaten zu den entsprechenden N-(Formylphenyl)- und N-(Acetophenyl)-Derivaten des Harnstoffs 2a-p bzw. der Carbaminsäure 1a-u. Aminobenzaldehyde und Aminoacetophenone reagieren nicht mit N,N-Dialkylcarbamoylchloriden.
    Additional Material: 2 Tab.
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  • 39
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 859-864 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Application of Relaxation Reagents in the 13C-NMR Quantitative AnalysisIn 13C-PFT-n.m.r. spectrum, the intensities of different signals become almost equal on adding Cr(acac)3 as a relaxation reagent. An intensity ratio precisely corresponding to the number of the adjacent carbon atoms can be reached only with infinitely high concentrations of Cr(acac)3. By means of a linearized function, it is possible to give an extrapolation to this infinitely high concentration. In this way, a quantitative 13C-n.m.r. analysis can be obtained routinely. The method does not require calibration, the standard deviation amounts to about 10% (rel.).
    Additional Material: 6 Ill.
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  • 40
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 878-878 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 41
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 881-898 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: General Syntheses and Rational Parameters for Structural Assignment of Isomeric Derivatives of [3,4]-fused Pyrazoles4 isomeric 1- or 2-methyl-, and 1- or 2-benzyl-pyrazolo[3,4-b]pyridones, i.e. the 4-oxo-types 17a, b or 11a, b and the 6-oxo-types 16a, b or 10a, b, are synthesized unambiguously. Cyclisation of 1-substituted 3- or 5-(1-methyl-2-ethoxycarbonyl-vinylamino)-pyrazoles 9a, b or. 15a, b, which were synthesized from 1-substituted 3- or 5-amino-pyrazoles and ethyl acetoacetate yields 11a, b or 17a, b in downtherm, but 10a, b or 16a, b in presence of acidic catalysts. The acidic cyclisation is preceded by a new rearrangement of 9 or 15 into 1- substituted 3- 27 or 5-amino-4-(1-methyl-2-ethoxycarbonyl-vinyl)-pyrazoles 30; mechanism and concurring reactions are explained. Because of their higher electron densities at C-4 it is easier to cyclise derivatives of 5-amino-pyrazoles compared to 3-amino-pyrazoles. All isomeric 1- or 2-substituted 4(6)-chloro-6(4)-methyl-pyrazolo-[3,4-b]pyridines are formed with POCl3 from the corresponding oxo-compounds.The position of a substituent at N-1 or N-2 of [3,4]-fused pyrazoles can be assigned using the significant 1H-n.m.r.-parameter ΔHMPTCDCL3 = δCDCl3  -  - δHMPT (conc. HC - 3). If solvent influences are considered, δ(C = O) is a useful 13C-n.m.r.-parameter to distinguish the 4-oxo-types (11a, b; 17a, b) from the 6-oxo-types (10a, b; 16a, b) of pyrazolo[3,4-b]pyridones. Further own and lit. dates conc. structural assignment (n.m.r., i.r., u.v.) are discussed critically.
    Additional Material: 3 Ill.
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  • 42
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 921-927 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Neue Möglichkeiten zur Verwendung von 1,1,1-Trichlor-2,2-bis(4-chlorophenyl)ethan für die Darstellung von selbstlöschenden und wärmebeständigen Polyurethan- und PolyharnstoffharzenEs werden Reaktionen zur Darstellung von 1,1,1-Trichlor-2,2-bis(4-chlor-3-aminophenyl)ethan, 1,1-Dichlor-2,2-bis(4-chlor-3-isocyanatophenyl)ethylen und 1,1,1-Trichlor-2,2-bis(4-chlor-3,5-diaminophenyl)ethan aus 1,1,1-Trichlor-2,2-bis(4-chlorphenyl)ethan beschrieben. Die Polyadditionsprodukte der Diisocyanate mit Diolen und Diaminen werden durch Derivatographie charakterisiert.
    Additional Material: 2 Tab.
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  • 43
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 953-958 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass Spectra of Alicyclic Compounds. VI. Mass Spectrometric Fragmentation of Chloroacetic Esters of the trans-1,4-CyclohexanediolThe electron impact mass spectra of some chloroacetic esters of trans-1,4-cyclo-hexanediol and of cyclohexanol are discussed.It was found that the fragmentation process in these compounds is determined by the number of chlorine atoms in the acid and the interactions between the two functional groups.
    Additional Material: 2 Ill.
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  • 44
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 987-999 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Chemical Synthesis of the Oligonucleotides dpG-A-T-A-T-C, dpG-A-T-C-T-T-T-T and dpT-T-T-C-A-T-C-A-TFor studies of some sequence dependent structural factors the oligonucleotides dpG-A-T-A-T-C, dpG-A-T-C-T-T-T-T and dpT-T-T-C-A-T-C-A-T were required. Their chemical synthesis is reported according to the diester method.
    Additional Material: 11 Ill.
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  • 45
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 1021-1028 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of o-Halobenzyl Cyanides with Carbon Disulfide and Phenyl IsothiocyanateStarting from o-halobenzyl cyanides 1 and carbon disulfide in the presence of sodium hydride dithiolates 3 are prepared, which are not isolated. Alkylation under cooling gives ketene S, S-acetals 4, while on heating at 100°C benzo[b]thiophenes 6 are obtained. Nitrile cyclisation yields thieno[2, 3-b]benzothiophene 7. Reaction of 1 with phenyl isothiocyanate/sodium hydride and subsequent alkylation leads to the ketene S, N-acetals 13 und to the thiazolidines 15.
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  • 46
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 1047-1052 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaktionen mit Acetondicarbonsäure-Dianiliden. I. Reaktionen an der Carbonylgruppe
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  • 47
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979) 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 48
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 8-12 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaktion von Grignardverbindungen mit gemischten DiimidenN-Phthalimidosukzinimid 1 und N-Phthalimidomaleinsäureimid 2 entstehen aus N-Aminophthalimid und Succzinsäure- bzw. Maleinsäureanhydrid. 1 reagiert mit Grignardverbindungen zu den 3, 3-disubstituierten Phthaliden 3 und N-Aminosucczinimid. 2 reagiert mit Grignardverbindungen ebenfalls zu den Phthaliden 3 und einem schwer zu reinigenden Verbindungsgemisch. N-Phthalimidomaleinsäureimid 2 reagiert leicht mit Diazoalkanen und Stickstoffwasserstoffsäure.
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  • 49
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 112-116 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: On the Use of Nitrosomesitylene as a Spin Trap2, 4, 6-Trimethylnitrosobenzene (nitrosomesitylene) has been tested for spin trapping of radicals. The rate constant for trapping of tert. butyl radicals by nitrosomesitylene has been estimated to be (1.2 ± 0.3) · 108 mole-1 dm3 s-1.
    Additional Material: 2 Ill.
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  • 50
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 107-111 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Studies on Sulphochlorination of Paraffins. IV. On the Sulphochlorination of IsobutaneIn the sulphochlorination of isobutane at -20 to -10°C a mixture of 20-25% tert.-butyl and 75-80% of isobutyl sulphochlorides is formed. The mixture has been analyzed by 1H- and by 13C-n.m.r.-spectroscopy. It is possible to transform the mixture of sulphochlorides into mixtures of the corresponding sulphonates, sulphonic acid methyl esters or sulphonic acid demithylamides. During the work-up of the sulphochlorination mixtures it is necessary to keep the temperature low, because tertiary butyl sulphochloride is desulphonated at a noticeable rate already at temperatures above 35°C.
    Additional Material: 3 Tab.
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  • 51
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 205-214 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis and Reactions of 2-[Bis-(alkylthio)-methyliden]-indan-1,3-dionesThe 2-[bis-(alkylthio)-methyliden]-indan-1,3-diones 3 and especially the methyl-compound 3a react with nucleophiles by substitution of the CH3—S—group. The reaction with amines are yields the S,N— or N,N-acetales 7 and 8, respectively. Diamines, amino hydroxy- or amino-mercapto compounds as dinucleophiles give the cyclic compounds 9 or the condensed heterocycles 12 and 16, where the carbonyl group has been integrated in the cyclisation. Also carbanions react with 3a under substitution. The structures of the final products are determined with ir-, 1H-n.m.r.- and ms-spectra.
    Additional Material: 5 Tab.
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  • 52
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 231-242 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Control of Synthesis and Characterization of Higher-Molecular Peptides by Means of 13C n.m.r. SpectroscopyThe 13C n.m.r. spectra of the C-terminal bovine insulin decapeptide derivative Boc-Glu(OBzl)-Arg(H+)-Gly-Phe-Phe-Tyr(Bzl)-Thr(Bzl)-Pro-Lys(Z)-Ala-OBzl as well as the amino acid and peptide intermediates used in its synthesis, have been measured and assigned as extensively as possible. The use of 13C n.m.r. spectroscopy as a method for controlling the synthesis and for the characterization of higher-molecular peptides is discussed.
    Additional Material: 8 Ill.
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  • 53
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Photocatalytic Systems. XVI. Photo-oxidation of Octacyano Molybdate (IV) by Excitation in the Long-Wave Range
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  • 54
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 197-204 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Phase Transitions of Liquid Crystalline Modifications by Photochemical IsomerisationOn irradiating of liquid crystalline phases of aromatic azo- and azoxy-compounds, stilbenes or of derivatives of cinnamic acid by light of appropriate wave lengths the liquid crystalline phase will be converted into the isotropic liquid. In case of the azo- and azoxy-compounds studied this process is reversible, in case of the stilbene and cinnamic acid derivatives partially irreversible. The experimental results indicate that the photoinduced phase transition is caused by a trans-cis-isomerisation. For azo-compounds with more liquid crystalline phases also photoinduced transitions are possible between different liquid crystalline phases.
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  • 55
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 226-230 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of 1-(2-Benzoxazolon-3-yl)-2-propanones with Hydrazinhydrate. The reaction of 1-(2-benzoxazolon-3-yl)-2-propanones 1a-g with hydrazinhydrate is studied. It is shown that according to the reactional conditions are obtained hydrazones 2a-b, azines 4a-b and 6-Methyl-4-(2-hydroxyphenyl)-2,3,4,5-tetrahydro-1,2,4-triazine-3-ones 6a-g. The structure of the products is discussed on the base of i.r. and n.m.r.-spectras.
    Additional Material: 1 Tab.
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  • 56
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 127-130 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Darstellung und Reaktionen einiger 5-Chlorpyrazole
    Additional Material: 2 Tab.
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  • 57
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 161-163 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Preparation of Aliphatic Diisocyanates without Using of PhosgeneDas Hauptausgangsmaterial für die Synthese des modernen Typs von Polyurethanlacken, die gegen das Licht widerstandsfähig sind, bilden die aliphatischen Diisocyanate [1-4]. Diese Verbindungen werden im größeren Maßstab durch Phosgenierung entsprechender Diamine gewonnen. Die Methode ist aber für Mensch und Umgebung gefährlich [5].
    Additional Material: 3 Tab.
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  • 58
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 349-349 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 59
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α-Substituted Phosphonates. XXXIV. Esterification and N-Formylation of α-Aminomethane-bisphosphonic Acids with TriethylorthoformateIn contrast to simple mono- and bisphosphonic acids esterification of dialkylaminomethanebisphosphonic acids with orthoformate (OAE) proceeds very slowly. Monoalkyl and monoarylaminomethanebisphosphonic acids, respectively react with OAE in constrast to analogous hydroxy compounds more readily primarily by formylating the N-atom and then esterification to formyl aminomethane bisphosphonictetraesters 10. Acetaminomethanephosphonic acid (12) reacts without N-formylation, while the aminomethanebisphosphonic acid (14) reacted to give a mixture of mono- and bis-formylated products 15 and 16. By acidic hydrolysis of 10 the ester- and formylgroups are splitt off, while the ester group can selectively be removed by reaction with Me3SiBr/H2O. - As shown by 1H-, 13C- and 31P-n.m.r. spectroscopy the phosphorylated formamides 10 exists in two rotameres, the ratio depending on the solvent. The n.m.r. signals could be correlated to E-resp. Z-form undoubtedly by using shift-agents or the benzene-diluting technique. A rotational barrier of 22,8 kcal for 10c could be calculated.
    Additional Material: 4 Tab.
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  • 60
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 379-386 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyanic Acid Esters. 27. Triazino-benzimidazoles from 2-Amino-benzimidazole-1-imid-esters and Carbonyl Analogic CompoundsThe Cyclocondensation of 2-amino-benzimidazole-1-imid-esters with aldehydes, carbonic acid anhydrides and isocyanates has been investigated. With aldehydes in the presence of piperidine 4-aryloxy-1,2-dihydro-1,3,5-triazino[1,2-a]benzimidazoles 3 and with carbonic acid anhydrides 4-aryloxy-1,3,5-triazino[1,2-a]benzimidazoles 5 are formed. Isocyanates react with the imid esters to the corresponding 3-substituted ureas 8 which on heating undergo acyl migration of the carbamoyl group followed by cyclocondensation to 4-imino-2-oxo-1,2,3,4-tetrahydro-1,3,5-triazino[1,2-a]benzimidazoles 12.
    Additional Material: 1 Ill.
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  • 61
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 62
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 415-419 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Short-Time Spectroscopic Investigations of Photochromic N-Substituted DinitrobenzylpyridinesBy means of nanosecond laser absorption spectroscopy of N-substituted photochromic dinitrobenzylpyridines is shown that in polar solvents the long wave absorbing polymethin coloured form forms independently on the electronic properties of the substituents at the pyridine nitrogen. The polymethin is formed either directly or via the nitronic acid immediately after irradiation by the laser impulse (20 ns). In nonpolar solvents, on the other hand, the polymethin is only produced if the substituent (e.g. in N-oxide 6) is able to bind the hydrogen splitted from the methylen group by photoreaction. If this is impossible (e.g. N-Methyl-compound 5) only absorption of nitronic acid occur.
    Additional Material: 2 Ill.
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  • 63
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 443-448 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cathodic Reduction of Ketene S,S-acetalsKetene S,S-acetals are reduced in protic media by the cleavage of one S-alkyl group. The resulting carbanion either may be protonated or reacts with the starting material to yield dimers. The effects of different substituents on the half-wave potentials and the rate constants of amination have been investigated.
    Additional Material: 3 Ill.
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  • 64
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Photocatalytic Systems. XXI. On the Mechanism of the Photoreduction of Potassium Chromate in AlcoholsThe photolysis of crown ether complexes of potassium chromate in several alcohols has been investigated by e.s.r.-spectroscopy. Two different relatively long-lived Cr(V) intermediates formed by different reaction pathways have been observed. Radicalic oxidation products of the alcohols (alkoxy and hydroxyalkyl radicals as well as fragmentation products) and of the crown ether have been detected by spin trapping.
    Additional Material: 4 Tab.
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  • 65
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 671-674 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vilsmeier-Reaction on Dimedone.The Vilsmeier-reaction has been studied in detail for a special cyclic β-diketone, dimedone. It was shown, that the first step in this reaction is the formation of the corresponding β-chlorovinylketone. 3-Chloro-5,5-dimethyl-cyclohex-2-en-one-(1) 2, 2,4-dichloro-6,6-dimethyl-1-formyl-cyclohexa-1,3-diene 3 und 2,4-dichloro-1,5-diformyl-6,6-dimethyl-cyclohexa-1,4-diene 4 were isolated in equal parts. The symmetrical enolether 6 was identified as condensation-product of the diformylated compound 5.
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  • 66
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 683-690 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Koordinationsverbindungen des vierwertigen Siliziums mit stickstoff-, schwefel- und sauerstoffhaltigen Schiffschen Basen
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  • 67
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 704-704 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 68
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 741-746 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Stobbe-Kondensation von aromatischen Aldehyden mit DiethyldiglycollatPiperonal, p-Tolylaldehyd und p-Chlorbenzaldehyd kondensieren mit Diethyldiglycollat in Gegenwart von Natriumhydrid zu den entsprechenden Z-Halbestern 1 und den Diarylidendicarbonsäuren 2 und 3. Strukturen und Konfigurationen der Produkte wurden durch chemische und spektroskopische Methoden untersucht.
    Notes: Piperonal, p-tolualdehyde, and p-chlorobenzaldehyde condense with diethyl diglycollate in the presence of sodium hydride to give predominantly the corresponding (Z)-half-esters 1. together with smaller yields of the diarylidene diacids 2 and 3. The structure and configuration of the products was established by chemical and spectroscopic evidence.
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  • 69
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 721-740 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of Substance P and of Acylated Partial SequencesSubstance P undecapeptide has been synthesized by the stepwise procedure and via condensation of the fragments 1-4 and 5-11. Formation of pyrrolidone carboxylic acid- and S-tert. butyl peptides was observed. Gln(Mbh)-containing sequences have been synthesized but were not useful for fragment condensation due to there low solubility. Additionally, some derivatives have been prepared by acylation of the C-terminal pentapeptide. Reaction with trifluoracetic acid anhydride resulted in the formation of substituted 5-amino-oxazole derivatives as detected by mass spectrometric investigation.
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  • 70
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 769-774 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Halogenolipids. II. Problems of Synthesis and Mass Spectrometric Characterization of 2-O-acyl-3-halogeno-propane-1,2-diols3-Fluoro- and 3-chloro-2-O-palmitoyl-propane-1, 2-diol 2a, b were prepared by acylation of 3-fluoro- and 3-chloro-1-O-trityl-propane-1, 2-diol with palmitoyl chloride in pyridine and subsequent detritylation of the resulting 3-fluoro- and 3-chloro-2-O-palmitoyl-3-O-trityl-propane-1, 2-diol.3-chloro-1, 2-di-O-palmitoyl-propane-1, 2-diol was deacylated enzymatically using pancreas lipase to give 3-chloro-2-O-acylpropan-1, 2-diol 2b.2a and b both were unstable compounds which slightly isomerize  -  so under conditions of mass spectrometry  -  to give mixtures of 1- and 2-O-acyl-derivatives.
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  • 71
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 827-834 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of 2-Heterocyclidenamino-1, 3-diaza-trimethincyaninesThe synthesis of 2-[3-methyl-benzthiazol-(1, 3)-inylidene-(2)-amino]- and of substituted 2-[1, 3-dithiolyliden-(2)-amino]-1, 3-diaza-trimethincyanines is described. The heterocyclic imines 1 react with phosgene or thiophosgene to the corresponding ureas 2 and thiureas 3, respectively. Alkylation of 3 to the 2-alkylmercapto-1, 3-diaza-trimethincyanines 4 and subsequent condensation with imine 1 yields the dyes 5. The chemical and spectroscopical data of cyanines 5 are described.
    Additional Material: 2 Ill.
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  • 72
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 870-875 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthese von Heterocyelischen Spiroverbindungen
    Additional Material: 3 Tab.
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  • 73
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 876-877 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A Simple Procedure to Prepare tert.-Butyllithium in High, Reproducible Yields
    Additional Material: 1 Tab.
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  • 74
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    Topics: Chemistry and Pharmacology
    Notes: Komplexe der o-(N-α-Pyrrolylimino)benzolsulfonsäure und 2-(N-α-Pyrrolylimino)ethansulfonsäure mit Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Pd(II), Cd(II), UO22+ und VO2+
    Additional Material: 1 Tab.
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  • 75
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 712-720 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Heterocycles from Acrylonitrile. I. Reactions of 2-Cyano-aziridin with Ketones2-Cyano-aziridine 2 is stable towards water at room temperature, but yields aziridine-2-carbonamide 6 on addition of cyclohexanone. Hemiaminal 8 is shown by 13C-spectroscopy to be an intermediate in this reaction.In the absence of water the aminal-like compounds 10 and 11 are formed from 2-cyano-aziridin 2 and ketones.Above 100° 2 as well as 6 form the imidazolinone 12 on action of cyclohexanone by opening of the aziridine ring and formation of a methyl group.
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  • 76
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 131-133 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Substituenteneinflüsse auf Reaktionsgeschwindigkeiten. VI. Kinetik der Kondensation substituierter Benzaldehyde mit Acetophenon und 2-Hydroxy-4-methoxy-propiophenon
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  • 77
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 327-330 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Solvent Dependence of the Barriers to Rotation about the C=C-Double Bond in Substituted Acrylates
    Additional Material: 1 Ill.
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  • 78
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 345-348 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kinetik der Epoxidierung von Allylbromid durch Wasserstoffperoxid in Gegenwart von Molybdänsäure
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  • 79
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  • 80
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979) 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 81
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quantum Chemical Study on Colour and Stereodynamics of Acyclic Azines. II. Influence of Twisted S0 Molecular Geometries on the Spectral Behaviour and the Photochromic Effect of Benz- and AnthraldazineOn the basis of quantum chemical calculations the influence of twisted molecular geometries on the spectral behaviour of (1E,3E)- and (1E,3Z)-isomers of benz- and anthraldazine has been investigated. It is possible to point out structural peculiarities in the S0 state and to explain the photochromic effect of the arylsubstituted acyclic azines.
    Additional Material: 6 Ill.
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  • 82
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 475-487 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetrathiafulvalenes. VIII. Ethylene-bridged Polymer TetrathiafulvalenesSyntheses and properties of ethylene-bridged polymer tetrathiafulvalenes are described. These polymers react with bromine, iodine or tetracyanoquinodimethane to form the radical cation salts, whose electrical conductivity are estimated by means of powder compactions. The polymer radical cation salts have a higher conductivity than the polymer TTF (σRT max. 10-5 Ω-1cm-1). The differences in the conductivity between polymer TTF-cationhalides and polymer TTF-TCNQ-salts are small.
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  • 83
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 516-518 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 5-Oxo-2-pyrroline aus Δβ,γ-Butenoliden
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  • 84
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Oxidative Coupling of CH-acid Compounds with p-Phenylene Diamines. III. Reactivity of 4-Substituted 3-Methyl-1-phenyl-pyrazolin-5-ones with N,N-Diethyl-quinone-(1,4)-diimineSubstitution products 2-28 of 3-methyl-1-phenyl-pyrazolin-5-one 1, with a wide variety of substituents in the 4-position, were synthesized. Most of these compounds react with N,N-diethyl-quinone-(1,4)-diimine by elimination of the substituent giving the same azomethine dye as that formed by oxidative coupling of the 4-unsubstituted compound. A study of the influence of side reactions by measurement of dye yields has been undertaken.
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 522-528 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Tab.
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 544-548 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cationic Grafting of Isobutene onto Chlorinated PolycyclopentadieneThe effect of reaction conditions on the cationic grafting of isobutene onto chlorinated polycyclopentadiene has been investigated, varying particularly temperature, solvent and coinitiator. The coinitiators used were Et3Al, Et2AlCl, Et3Al2Cl3, EtAlCl2, AlCl3 and SnCl4. The solvents used were methylenchloride and dichloroethane. The graft copolymers were characterized by conversion, extraction with n-pentane and GPC. Only Et3Al2Cl3, EtAlCl2 and AlCl3 let to a higher grafting efficiency.
    Additional Material: 1 Ill.
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  • 87
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 570-578 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Gas Adsorption Chromatography of Higher Hydrocarbons. Determination of Normal Paraffins by Temperature-Programmed Segregation Gas Chromatography on 5A Molecular SieveA fast temperature program makes it possible to determine the normal paraffins up to C 20 in the concentration range between 0.1 and 99.9 percent (molecule type analysis). From the group peak of the normal paraffins we can obtain on line the distribution of the carbon numbers.As the normal paraffin selectivity of the molecular sieve S ≈ 1 can be assumed. Isoparaffin memory could not be detected.The new method makes it possible to perform analysis with great accuracy within three minutes or less. Connected to a computer it is excellently suitable for large series of samples.Under the standard conditions of this method only a little paraffin cracking has been found. Type and quantity of the cracked products proved to be independent of the chain length of the individual normal paraffin.
    Additional Material: 7 Ill.
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 353-360 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Furanderivatives. VII. O,O-Diethyl-2-[furyl-(2)- and 5-nitro-furyl-(2)] vinylphosphonatesSyntheses and spectroscopic properties (i.r., u.v., 1H-, and 13C-n.m.r.) of the title compounds existing as E-isomers with the general structure 1-8 (R5 = H, NO2; R = CN, COOEt, H, NMe2) are represented. According to spectroscopic data the compound 8 (R5 = NO2; R = NMe2) differs in its electronic structure.
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    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979) 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 90
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 537-540 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Isosteric Heat of Adsorption of n-Butane on Zeolites NaX and NaYUsing the technique of measuring isosteres the equilibria of adsorption of n-butane on zeolites NaX and NaY were investigated. From the isosteres the heats of adsorption were calculated. Although the differences between the enthalpies are small the zeolithe with higher electrostatic field in the cavity always shows larger heats of adsorption. These differences are explained assuming an adsorption of the n-butane molecules at (or near) Na+-cations in SIII position (which are found only in NaX-zeolites).
    Notes: No abstract.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 91
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Structures and Isomerisation of the 1,3-Dipolar Cycloadducts of Dimethyl Maleate and Fumarate to 3-Pyrazolidone-azomethiniminesThe 1,3-dipolar cycloaddition of dimethyl maleate 1b and fumarate 5b to the 3-pyrazolidone-azomethinimine 2 is a stereospecific cisoid reaction yielding the perhydropyrazolo[1,2-a] pyrazoles 3b/4b in the molar ratio of 2:1, and 6b/7b in the molar ratio 1:1. Starting with each of the 4 stereoisomers, epimerization, catalysed by alcoholate, results in all 4 of them 3b, 4b, 6b and 7b with 7b as sterically favoured main product. During the addition reaction no epimerization is occurring. 1H- and 13C-n.m.r. data are discussed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 92
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 601-604 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: On the Reaction of Bis-(dimethylglyoximato)-nickel(II) with HexamethyldisilazaneThe reaction of bis-(dimethylglyoximato)-nickel(II) with hexamethyldisilazane was investigated. Some reactions of the formed nickel(II) dimethylglyoximate are described.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 93
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Liquid Crystalline State as a Criterion in Determination of Structure. I. Crystalline Liquid Benzoic Acid and Thiobenzoic Acid Pyrimidinyl-(2)-estersThe acylation of subst. 1H-pyrimidinethiones-(2) 3 and 4, as well as of subst. 1H-pyrimidinones-(2) 7 is investigated. Due to the tautomeric equilibrium in the starting materials the reactions may lead to N-, S-, or O-esters. The liquid crystalline properties of the reaction products formed prove that S- and O-acylated esters 5, 6, and 8 had been formed only. Spectroscopic data confirm this.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 94
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Oxidative Coupling of CH-acid Compounds with p-Phenylenediamines. IV. Mass Spectrometric Investigations of 4-Substituted 1-Hydroxy-2-naphthoic-acid Derivatives.Mass spectrometric fragmentations of 4-substituted 1-hydroxy-N-3′, 5′-(dimethoxy-carbonyl)phenyl-2-naphthalene carboxamides and derivatives of 1-hydroxy-2-naphthoic acid and 4-bromo-1-hydroxy-2-naphthoic acid have been determined. All compounds undergo a characteristic fragmentation. The most important primary process is amide cleavage and hydrogen rearrangement. The relation of the primary fragments which compete for the charge depends on the substituents of the active methylene group and of the amide. The mass spectra permit determination of structure, purity and stability of the substituted colour couplers.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 95
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 797-803 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of 2,3-Dichloromaleimides with Ethoxycarbonylmethylenetriphenylphosphorane and Secondary Reactions2, 3-Dichloromaleimide 1a reacts with ethoxycarbonylmethylenetriphenylphosphorane under alkenylation to give 3, 4-dichlor-5-ethoxycarbonylmethylidene-3-pyrrolin-2-one 2. With N-substituted 2, 3-Dichloromaleimides 1b-1f one chloroatom is substituted to give 2-(ethoxycarbonyltriphenylphosphoranyl)-methylene-3-chloro-maleinimides 3. The reactions of 2 and 3a with various nucleophiles are investigated.
    Type of Medium: Electronic Resource
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  • 96
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: On the Acylation of the Phosphoryl Oxygen. I. Acyloxyphosphonium Salts from HMPT and Carboxylic Acid DerivatesAcylation equilibria with participation of acyloxyphosphonium ions exist in solutions of HMPT and carboxylic chlorides, or anhydrides, respectively, as can be shown by 31P-n.m.r. after trapping the counter ion with SbCl5. Moderately stable acyloxyphosphonium salts have been isolated for the first time by acylation of HMPT. In the alternative reaction of (Me2N)3P with CCl4 and carboxylic acids, acyloxyphosphonium salts are formed only after prolonged reaction times, due to the stability of the intermediate chlorotris-(dimethylamino)-phosphonium ion.
    Additional Material: 4 Tab.
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  • 97
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 1-7 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Spectroscopical Investigations on N,N′-Disubstituted Dithiomalonamides and their Co(II)-ComplexesThe Co(II)-complexes of N,N′-disubstituted dithiomalonamides have been synthesized and characterized. Comparative uv/vis-, ir-, epr-, x-ray-, and n.m.r.-spectral studies of this complexes and of the dithiomalonamides suggest that their Co(II)-compounds are S4-coordinated square planar inner complexes (CoL2). The orbital splitting parameters Δ of these complexes have been calculated in the order of less than 20000 cm-1.For compounds CoL2 by this way the following spectrochemical series of the ligands results: dmma 〈 d clmma 〈 dnma 〈 d clpma 〈 dpma. All dithiomalonamides investigated in this work exist nearly complete in the dithion-form.
    Notes: Die spektrometrischen Untersuchungen in Lösungen belegen eindeutig die dominie-rende Rolle der Dithionform bei den Dithiomalonamiden, fur die Enthiol-thion-Form gibt es nur geringfügige, nicht eindeutige Hinweise bei einigen IR-Festkörperspektren.
    Additional Material: 6 Tab.
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  • 98
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 23-42 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: About Some Correlations between Electron-Impact-Induced Fragmentations and Properties of Organic MoleculesThe most important theoretical conceptions in organic mass-spectrometry are discussed and compared. By consideration of special cases of single, competitive and consecutive reaction models and their graphical presentation it is possible to demonstrate some consequences of the QET useful for the qualitative interpretation and the understanding of the formation process of a mass-spectrum. The validity and the limits of the physical-organic theory of mass-spectra is examined from the point of view of the QET. A method to estimate the relative strength of chemical bonds in ions from fragmentation behaviour, including rearrangement, is proposed.
    Additional Material: 12 Tab.
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  • 99
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 75-85 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fe(III)-Complexes with Mixed Ligands Consisting of Oxalate and Phenolate LigandsThe formation of mixed-ligand complexes between iron(III) ion, potassium oxalate and potassium salts of salicylic acid, sulfosalicylic acid, catechol, sodium 3,5-sulfocatechol („tiron“) and tetrachlorocatechol, respectively, has been investigated. There were obtained solid products with the approximate composition K3[Fe(C2O4)3-xLx] · n H2O (L = phenolat; x = 1; 2). For the synthesis of the above compounds ligand exchange reactions as well as addition-technique of oxalic acid followed by potassium phenolat to Fe2O3 · aq has been used. Through spectroscopic examination of the obtained products was found, that Fe3+-ion is simultaneously coordinated by oxalat and phenolat. Probably the products consist of at least two components as Fe(III) was found in two different bond states.
    Additional Material: 2 Ill.
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  • 100
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 134-136 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Darstellung von Mercaptoacetamiden und Bestimmung der pK-Werte
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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