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  • 1965-1969  (3,407)
  • 1925-1929  (1,634)
  • Organic Chemistry  (4,763)
  • Atomic, Molecular and Optical Physics  (246)
  • Engineering General
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  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 3-28 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Finite element methods can be formulated from the variational principles in solid mechanics by relaxing the continuity requirements along the interelement boundaries. The combination of different variational principles and different boundary continuity conditions yields numerous types of approximate methods. This paper reviews and reinterprets the existing finite element methods and indicates other alternative schemes. Plate bending problems are used to compare the relative merits of the various methods.
    Additional Material: 10 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 1-2 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 47-66 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Three methods for finding natural frequencies and modes of complex structures composed of beam elements are described and compared. The analysis is extended to include hysteretic damping for the determination of response and transmissibility without a modal analysis. Experimental comparison is given for the response of a simple engineering structure.
    Additional Material: 10 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 101-122 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The derivation of the stiffness matrix for a refined, fully compatible triangular plate bending finite element is presented. The Kirchhoff plate bending theory is assumed. Six parameters or degrees of freedom are introduced at each of the three corner nodes resulting in an 18 degree of freedom element. This refined element is found to give better results for displacements and particularly for internal moments than any plate bending element, regardless of shape, previously reported in the literature.
    Additional Material: 9 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 67-73 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Finite difference treatment of two-dimensional problems in elastostatics is usually based on the differential equations for the displacement vector or the Airy stress function, depending on whether boundary conditions are on displacement or stress. In either case, determination of stresses requires numerical differentiation and therefore use of a rather fine grid. Moreover, neither method is suited to the treatment of mixed boundary conditions. The alternative method developed in this paper uses the first derivatives of the displacement components at the grid points as basic variables and hence does not require numerical differentiation in the evaluation of stresses. Appropriate finite difference equations are established, and their use is discussed in connection with a specific example with known explicit solution.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 29-45 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The theory, function generator routine and testing procedures are given for a six-node 18 degree of freedom triangular element. At corner nodes the variables are the displacement and the two slopes. At midside nodes the variables are the displacement, the slope normal to the side, and the rate of change of this along the side - i.e., the rate of torsion. Of two options, one divides the triangle into three and takes different quartic displacements in the three regions, and the other uses displacement functions with singularities at the vertices. According to a test which compares the energies of the two formulations by eigenvalues, the second is the better if the integration is accurate. The same test, together with others based on finite differences and on nodal values, etc. checks the correctness of the routine decisively.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 123-133 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The large deflection problem of a rectangular plate is analysed by using the finite element method and employing the iteration technique. In the present study, the stiffness matrix of a rectangular plate element for bending proposed by Greene is employed, and results of numerical examples duly justifies applicability of the present method.
    Additional Material: 9 Ill.
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  • 9
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    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 75-100 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper presents first a general formulation of the elasto-plastic matrix for evaluating stress increments from those of stresses for any yield surface with an associated flow rule. A new ‘initial stress’ computational process is proposed which is shown (1) to yield more rapid convergence than alternative approaches (2) to permit large load increments without violating the yield criteria and thus simply to establish lower bound solutions. Several solutions showing stress distribution, strain development and growth of plastic enclaves are given both for the von Mises and for Coulomb (Drucker) type yield surfaces. Load reversal and thermoplastic behaviour are dealt with.
    Additional Material: 18 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 11
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 151-162 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The direct Finite Element Analysis which was successfully employed in the solution of dynamic flexural traveling wave problems is extended herein to provide the transient behaviour of finite beams and plates in which shear deformation and rotatory inertia are considered. The particle and angular velocities are exponentially damped so that the static solutions for these problems are obtained with the same analysis which provided the dynamic and transient cases. Three special cases are chosen as examples. In the first, a sinusoidally varying shear force is applied at the tip of a cantilever beam. The resonant characteristics of this beam for both the undamped and damped cases are studied. In the second, a step shear loading is applied to a cantilever beam and its damped dynamic history is studied. Finally, a circular plate whose outer edge is simply supported is impacted at its inner edge by a step moment and its damped transient behaviour is determined. The idea of the methods is potentially applicable to dynamic problems in general.
    Additional Material: 8 Ill.
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  • 12
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 135-149 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The assumed stress distribution approach is used to derive the stiffness matrix of a plate-bending element of general polygonal shape having any number of nodes. The effect of assuming various numbers of unknown coefficients in the stress distributions is examined and the convergence properties of the resulting elements compared with others derived form assumed displacements.
    Additional Material: 13 Ill.
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  • 13
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 169-175 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical method for obtaining the Green's functions for Laplace's, Poisson's, and the transient heat diffusion equations is presented. The Green's functions thus obtained are then employed to rapidly obtain numerical solutions of the above equations by matrix multiplication, with subsequent considerable savings in machine time.
    Additional Material: 3 Tab.
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  • 14
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 177-180 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The solution of the large numbers of non-linear algebraic equations occurring in analyses of non-linear structural systems using finite differences or finite elements is time consuming even for the fastest computers. This paper presents a method of solution based on a Taylor's expansion technique which is an aid in the solution of such systems of equations.Examples presented show that in the finite element analysis of moderately non-linear structural systems the technique provides sufficiently accurate solutions. For more non-linear systems the technique provides excellent starting values for the Newton-Raphson method.
    Additional Material: 1 Ill.
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  • 15
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 163-167 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Deformation functions which, in addition to satisfying the continuity conditions at nodes. Also satisfy. Approximately, the governing differential equation within the element allow system eigenvalues to be found more accurately, with a given number of elements, than is possible with previously published deformation functions. This is illustrated for the case of beams.
    Additional Material: 2 Ill.
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  • 16
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 201-203 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 17
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 205-221 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper presents a general theory of finite elements. The concept of finite elements is cast in a general topological framework valid for spaces of finite dimension. It is shown that the idea of finite element models can be developed in higher-dimensional spaces, independent of specific co-ordinate systems, for any type of continuous abstract function defined on the space. Generalizations of the familiar Lagrange and Hermite interpolation functions are presented as well as a general statement of the notion of generalized variables and conjugate fields. It is also shown that admissible finite elements can be developed for non-Euclidean spaces of finite dimension. Topological properties of finite element models are examined in Part I of the paper. Part II is devoted to certain applications.
    Additional Material: 4 Ill.
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  • 18
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 224-224 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 20
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 225-245 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A method is presented based on matrix algebra for the dynamic analysis of a mixed rotating and non-rotating vibration system. Such systems occur in practice when turbo-alternator sets are mounted on flexible steel foundations.The mathematical model considered consists of a rotating non-uniform, bi-symmetric shaft connected via three or more flexible-film bearings to a flexible structure throughout which mass is distributed. The shaft, which is assumed to rotate at constant speed, is heavy, flexible and carries several rigid axi-symmetric discs. Viscous damping is assumed to act in all parts of the system and gravitational effects are ignored.
    Additional Material: 8 Ill.
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  • 21
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 181-200 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Surface displacements at the end of a semi-infinite, circular cylinder due to an axisymmetric ring of forces on the end are examined. The solution which has been found may then be used to find surface displacements for general axisymmetric loadings by convolution. The solution, in tabular form, is given as corrections to the counter-part half-space solution.The method of solution involves a three step superposition process. First, the displacement due to a ring of forces on a half-space is found by using the Boussinesq solution. Then, the excess tractions on the half-space, over that of the cylinder, are removed. This is done in two parts. The problem of an infinite cylinder with linearly varying pressure and shear over a short length of the lateral surface is solved by using Fourier integrals. This is used for the removal of the pressure and shear on the lateral surface of the cylinder by convolution. Next, the stresses at the mid-section of the infinite cylinder are removed. This is done by finding a set of boundary conditions for the end which yields zero tractions on the lateral surface. Then a series of these boundary conditions is used to approximate the tractions which must be removed.With the solution thus obtained, two sample problems are shown: 1. an elastic cylinder in contact with a half-space; 2. a rigid punch in contact with an elastic cylinder.
    Additional Material: 10 Ill.
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  • 22
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 247-259 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In Part I of the this paper, topological properties of finite element models of functions defined on spaces of finite dimension were examined. In this part, a number of applications of the general theory are presented. These include the generation of finite element models in the time domain and certain problems in wave propagation, kinetic theory of gases, non-linear partial differential equations, non-linear continuum mechanics, and fluid dynamics.
    Additional Material: 2 Ill.
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  • 23
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 275-277 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Additional Material: 1 Tab.
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  • 24
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 261-274 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A presentation is made of a rectangular plate bending element, the use of which corresponds to the finite difference method. The element stiffness matrix is arrived at by approximation of the strain energy of the element by suitably selected finite difference expressions which contain not only values in respect of the deflection, but also values of its first derivatives. On the basis of the connection found between the two methods, some changes are suggested in the finite difference method, which involve a more realistic way of considering the detailed distribution of the loading. The effect of these modifications is illustrated in two applications.
    Additional Material: 5 Ill.
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  • 25
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 279-299 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: When calculating complex interconnected systems (electrical, power, water supply, gas systems, etc.) by digital computer, a number of common problems arise, connected both with the mathematically correct formulation of the problem under investigation, and with the algorithms of the solution, the programming of which makes it possible to reduce the computing time, the store capacity and the volume of input data required. The present article is devoted to the solution of these problems. The procedure is illustrated by formulating and manipulating the equations relating to complex interconnected mine ventilation networks.
    Additional Material: 2 Ill.
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  • 26
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 27
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 301-310 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Solution of plane elastic problems by piecewise linear approximation is outlined. This method is based upon Galerkin error distribution technique, which leads to simultaneous algebraic equations identical to those associated with the Finite Element Method. In addition, this method permits definition of the discretization error, which can be computed once the displacement components are known. Properties of the interpolation functions are discussed, and a sequence of internally compatible plane elastic elements is defined.
    Additional Material: 1 Ill.
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  • 28
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 311-331 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A review is given of some mathematical programming methods suitable for optimization of structures needing matrix methods for analysis. An application is presented for elastic flat grillages made of straight orthogonal beams normally loaded. Empirical relationships are used to relate beam section properties so that each beam element has only one design variable. Optimization results are obtained by methods of stress-ratio, linear programming-cutting plane and usable-feasible gradient directions. A comparison of the efficiency of these methods is given for the grillage designs which are shown to have non-convex stress constraints and numerous relative optima. Instances are given of non-fully stressed global optima and fully stressed designs which are not local optima for cases with only stress constraints. Discussions include locating the global optima for grillage designs and extensions of the methods presented to other structural design problems.
    Additional Material: 5 Ill.
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  • 29
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 333-349 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper presents a method for reducing the size of a vibration analysis by generating an inertia matrix referred to a limited set of ‘master’ vibrational freedoms. In designing a computer program to perform this mass condensation process, the emphasis has been on providing a two way interface between structural analysis and vibration analysis programs. The transformation from the full set of degrees of freedom to the master set makes extensive vibration calculations economically feasible giving solutions in terms of the amplitudes of the master freedoms. However, by reversing the transformation after completion of a vibration analysis, it is possible to restore the full set of freedoms, allowing automatic plotting of mode shapes in full detail, and re-entry to the structural analysis program for the purpose of computing dynamic stresses.A worked example is given. This is a realistic machine tool structure rather than the simple plates or beams which are usually used for illustration purposes. Natural frequencies and mode shapes, calculated with various degrees of condensation, are compared with those obtained by using all possible freedoms. A comparison is also made with an intuitive selection of ‘lumped masses’.
    Additional Material: 9 Ill.
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  • 30
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 351-378 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The application of non-linear programming methods for the optimum design of statically indeterminate structures is discussed, with special emphasis on the design of elastic grillages loaded laterally and in plane. Some features of SUMT (sequential unconstrained minimization technique) are demonstrated by means of numerous examples of varying complexity. The Variable Metric method of search is discussed and compared to Powell's Direct Method. It is shown that non-convex sets of design variables are often encountered in structural problems of the grillage type. SUMT may still be used, but the choice of starting value and initial response factor decisively influences the chance of finding the global optimum.It is demonstrated that a fully stressed design may not necessarily correspond to the minimum weight design. Optimum design of grillages which are simultaneously subjected to lateral and in-plane loads may be performed efficiently by means of non-linear programming.
    Additional Material: 12 Ill.
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  • 31
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 379-394 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A completely numerical method for steady state linear viscoelastic stress analysis is presented by means of the finite element approach. Numerical representations of the measured viscoelastic constitutive relations are used. This method is developed to obtain steady state solutions to mixed boundary value problems in which the character of the boundary conditions at a point changes with time. Such problems cannot be handled by direct application of the correspondence theorem. A numerical example of viscoelastic sheet rolling is presented along with an experimental verification of the solution by photo-viscoelastic observations.
    Additional Material: 11 Ill.
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  • 32
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 1 (1969), S. 395-395 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 33
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 402-407 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyclohexanon und -heptanon reagieren basenkatalysiert mit Schwefel und Cyanacethydrazid bzw. N-Acetylcyanacethydrazid zu Thieno[2,3-d]pyrimidon-Derivaten, die sich zu 2-Amino-thiophencarbonsäure-(3)-hydraziden hydrolysieren lassen, während das aus Cyclopentanon, Acetylcyanacethydrazid und Schwefel erhältliche substituierte Aminothiophencarbonsäurehydrazid leicht zu einem 3-Amino-thieno[2,3-d]pyrimidon cyclisiert.
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  • 34
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 408-419 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Läßt man auf N-(β-Haloalkyl)-imidhalogenide, die bei der Reaktion von Olefinen mit Halogenen in Gegenwart von Nitrilen neben den vic-Dihalogenalkanen entstehen, Wasser, Schwefelwasserstoff, Ammoniak oder primäre Amine in alkalischem Medium einwirken, so erhält man in praktisch einstufiger Synthese Δ2-Oxazoline, Δ2-Thiazoline oder Δ2-Imidazoline. Die Reaktionsschritte verlaufen stereospezifisch. Bei Verwendung von Δ1-Olefinen ist in den Δ2 -Azolinen neben dem 4-substituierten Hauptprodukt (Markownikow-Addition) auch die 5-substituierte Verbindung (anti-Markownikow-Addition) zu 5-10% enthalten.
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  • 35
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 429-437 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In einer modifizierten Umlaufapparatur nach GILLESPIE wurden Flüssigkeit-Dampf-Gleichgewichte der Systeme n-Butanol/sek.-Butanol und n-Butanol/tert.-Butanol isobar bei 100, 300, 500 und 700 Torr im gesamten Molenbruchbereich gemessen.Aus den Experimentaldaten wurden unkorrigierte Aktivitätskoeffizienten berechnet und mit Hilfe der Beziehungen von LI und COULL approximativ dargestellt. Für beide Systeme konnten geringe aber eindeutig nachweisbare negative Abweichungen vom idealen Mischungszustand festgestellt werden. Die Meßwerte erfüllten die thermodynamische Konsistenzbedingung nach HERINGTON befriedigend. Die thermodynamischen Zusatzeigenschaften deuten die Bildung von Mischassoziaten in beiden Systemen an.
    Additional Material: 4 Ill.
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  • 36
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 438-444 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus 1-Methyl-7-amino-6-azalumazinen werden substituierte 3,5-Diamino-as-triazin-carbonsäuren-6 dargestellt. Durch Erhitzen über den Schmelzpunkt entstehen daraus substituierte Diamino-as-triazine. Die alkalische Verseifung von 1-Methyl-7-äthylmercapto-6-azalumazin ergab 1-Methyl-7-hydroxy-6-azalumazin.
    Additional Material: 2 Tab.
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  • 37
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei 25°C wurden an den binären Systemen Methanol/Dimethylformamid, Aceton/Dimethylformamid, Äthanol/Diäthylformamid und Aceton/Diäthylformamid mittlere molare Zusatzenthalpien und mittlere molare Zusatzvolumina bestimmt. Die kalorimetrischen Messungen erfolgten vorwiegend im mittleren, die pyknometrischen im gesamten Molenbruchgebiet. Die experimentell gefundenen Zusatzeffekte ergaben sich bei äquimolarer Zusammensetzung in der genannten Reihenfolge der Systeme wie folgt: -26,5; +8,8; +72,5; +10,2 cal/Mol bzw. -0,385; -0,26; -0,095 und +0,036 cm3/Mol. Ihre Konzentrationsabhängigkeiten zeigten schwache bis mäßige Asymmetrie.Diese Ergebnisse führten zusammen mit früher ermittelten molaren freien Zusatzenthalpien zu qualitativen Modellvorstellungen über molekularstrukturell bedingte Nahordnungszustände in den vier Mischphasen.
    Additional Material: 4 Ill.
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  • 38
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 445-454 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Synthese von 6-Azido- und 6-Amino-17 α-acetoxy-progesteron und von 6-Azido- und 6-Amino-testosteronacetat beschrieben. Die Einführung der Stickstoffunktion kann durch Aufspaltung des entsprechenden Epoxides mit Natriumazid erfolgen. Die Aminoverbindungen werden aus den Azidoverbindungen durch Reduktion mit Hydrazinhydrat/Raney-Nickel erhalten.
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  • 39
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 455-462 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung von Caprolactam mit Sulfurylchlorid in CCl4 wird ein bicyclisches, chlorhaltiges Amidin (1-[3,3-Dichlor-azacyclohepten-(1)-yl (2)]-2-oxo-3,3-dichlorazacycloheptan) 2 gebildet, dessen Struktur durch NMR-Spektroskopie aufgeklärt wurde. Die Bildungsweise von 2 aus Caprolactam, α, α-Dichlor-caprolactam und dem bisher als Dicaprolactimäther bezeichneten 1-[Azacyclohepten-(1)-yl-(2)]-2-oxo-azacycloheptan 5 wurde untersucht.
    Additional Material: 4 Ill.
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  • 40
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 463-471 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über die Reaktionen von Bi- und Cyclopoly-phosphinen mit P-substituierten Lithiumphosphiden berichtet. Die Umsetzung von Tetraphenylbiphosphin mit LiPR2 (R = C2H5; c-C6H11) und Li2PR′ (R′ = C6H5) führt zunächst zu unsymmetrischen Biphosphinen R′2P-PR2 bzw. R′(Li)P-PR′2, die mit weiterem LiPR2(Li2PR′) die symmetrischen Biphosphine R2P-PR2 bzw. R′(Li)P-P(Li)R′ bilden. Aus „Phenylphosphor“ und Li2PC6H5 entstehen Verbindungen des Typs Li-(PC6H5)x-Li (x = 2, 3, 4). Versuche, Lithium-phosphide der Zusammensetzung Li-(PC6H5)x-P(C6H5)2 (x 〉 1) aus „Phenylphosphor“ und Lithium-diphenylphosphid herzustellen, blieben ohne Erfolg. Es gelang nur, ihre Zerfalls- bzw. Abbauprodukte 1.4-Dilithium-1.2.3.4-tetraphenyl-tetraphosphin, Tetraphenylbiphosphin und 1-Lithium-1.2.2-triphenylbiphosphin zu isolieren.
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  • 41
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 472-476 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Anwendbarkeit der jodometrischen Titration zur Bestimmung von Enthiolgehalten einiger Thiocarbonylverbindungen wird geprüft. Verläßliche Ergebnisse lassen sich nur bei völlig wasserfreier Arbeitsweise erzielen, anderenfalls wird ein Enthiolgehalt nur vorgetäuscht. Die Endpunktsanzeige kann optisch oder besser potentiometrisch erfolgen. Rücktitrationsverfahren mit wäßrigen Lösungen sind ungeeignet. Beim potentiometrischen Verfahren vermögen einige CH-acide Thion- und Dithioester mit basischen Leitsalzen Enthiolate zu bilden, die wie freie Enthiole reagieren, weshalb die Methode bei diesen Verbindungen nicht brauchbar ist.
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  • 42
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 614-620 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend vom 1-Chlor-2-formyl-acenaphthylen 1 wurden Acenaphtho-(1,2-b)-thiophen 2g und 1-Methyl-acenaphtho-(1,2-b)-pyrrol 3c dargestellt. An beiden Verbindungen wurde versucht, durch Substitutionsreaktionen die Ergebnisse quantenchemischer Berechnungen experimentell zu überprüfen. Die Festlegung des Substitutionsortes erfolgte mit Hilfe der NMR-Spektroskopie.
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  • 43
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 630-634 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Addition von Diisopropyl- und Dicyclohexylcarbodiimid an einige Hydroxy-steroide beschrieben, die in Gegenwart von Kupfer(II)-bromid in glatter Reaktion zu den entsprechenden Guanyloxysteroiden führt.
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  • 44
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 621-629 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsetzung von N-Sulfinyl-arylaminen mit stark basischen Anionen (Alkoholat, Amid, Hydrid) werden in hohen Ausbeuten Diarylschwefeldiimide erhalten. Die Reaktion ist auf eine Vielfalt von substituierten N-Sulfinyl-arylaminen anwendbar, wobei die Substituenten sowohl Gruppen mit Elektronendonatorwirkung als auch solche mit Elektronen-akzeptorwirkung sein können.
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  • 45
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 635-642 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polarographic investigations on complexes of cadmium and lead with adipic acid have been carried out. The present study includes the effects of various parameters such as mercury pressure, temperature, concentration of metal ion, concentration of ligand, pH, surface active substances and viscosity on the waves. The plot of  -  E1/2 vs SCE and  -  log Cx is a curve (Fig. 2) showing the formation of more than one complex. The value of F3(X) is found to be constant (Table 1) which proves that three complexes are formed. Their overall stability constants have been calculated by using DEFORD and HUME'S method [2] and the values habe been found to be β1 = 16.5, β2 = 48.5, β3 = 116 ± 2.Along with this, effect of pH on pK1 (4.43) and pK2 (5.28) of adipic acid has also been investigated. The present work is also an attempt to describe the mechanism of the electrode process involved therein.
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  • 46
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 694-696 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 47
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 697-700 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 48
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 49
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 701-704 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 50
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 705-711 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus 2-Chloräthyl-trimethylammoniumchlorid 1 wird eine Reihe von Salzen hergestellt, die das gleiche kation enthalten. Weiterhin werden einige nucleophile Substitutionsreaktionen am 2-Chloräthyl-trimethylammoniumkation untersucht. β-Eliminierungen sind sowohl zum Vinyl-trimethylammoniumkation als auch zum Vinylchlorid möglich. Bei der Oxydation von 2-Chloräthyltrimethylammoniumchlorid entsteht Glykokollbetain, bei der Pyrolyse Methylchlorid.
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  • 51
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 712-720 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die katalytische Aktivität von metallcarbonylen wird durch die Elektrophilie der entsprechenden Metallcarbonylwasserstoffe bestimmt, welche auf Grund ihrer Sauren Eigenschaften eingeschätzt wurde.Bei steigender Acidität des Metallcarbonylwasserstoffes wird seine elektrophile Wirkung gegenüber dem Ausgangsprodukt (z.B. einem Olefin) beschleunigt und die Reaktionsfreudigkeit des als Zwischenprodukt entstehenden Acylmetallcarbonyls verstärkt.Die sauren Eigenschaften von als Katalysator wirkenden Metallcarbonylwasserstoffen können durch Einfügung elektronenabgebender bzw. -anziehender Liganden in das Molekül geändert werden. Gleichzeitig verändern sich die katalytische Aktivität sowie der Anteil der nach der Markownikow-Regel bei Umsetzung von Olefinen gebildeten Reaktionsprodukte.
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  • 52
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 731-736 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umlagerung von N-(β-Haloalkyl)-carbonsäureamiden zu Δ2-Oxazolin-hydrohalogeniden wurde durch mercurimetrische Titration der gebildeten Halogenidionen kinetisch verfolgt. Es liegt ein temperatur- und lösungsmittelabhängiges Gleichgewicht vor. Die Geschwindigkeit der Hinreaktion ist stark vom Halogen und von den Substituenten am Amid abhängig.
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  • 53
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 737-745 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Reaktion von Olefinen mit Nitrilen und Quecksilber(II)-nitrat werden 1-Chlormercuri-2-acylaminoalkane (2) dargestellt. Die Reduktion dieser Verbindungen mit Natriumamalgam oder Natriumborhydrid führt zu 2-Acylaminoalkanen (4); Lithiumalanat reduziert zu 2-Alkylaminoalkanen (5). Halogenierende Spaltung der Chlormercuriverbindungen ergibt 1-Halogen-2-acylaminoalkane (6). Die Umsetzung mit Hg(NO3)2 und die halogenierende Spaltung der quecksilberorganischen Verbindungen erfolgen stereospezifisch. Die Addition des HgNO3⊕ erfolgt vorwiegend im MARKOWNIKOW-Sinne.
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  • 54
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 746-759 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Einwirkung von Nitrosylhydrogensulfat (NOHSO4) auf Δ2-Olefine oder unsubstituierte cyclische Olefine in Gegenwart aliphatischer Nitrile entstehen aus primär gebildeten α-Sulfatooximen und Imidazol-3-oxiden 1-(β-Oximinoalkyl)-imidazol-3-oxide 4. Die Strukturaufklärung der Imidazolderivate wird mit Hilfe chemischer und spektroskopischer Methoden sowie durch Vergleich mit auf unabhängigem Wege gewonnenen Substanzen vorgenommen.
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  • 55
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 775-785 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Kombination von kinetischen Messungen und Konkurrenzreaktionen wird nachgewiesen, daß die sehr schnelle Substitution des Halogens in α-Halogenhydroxamsäuren durch basische Nucleophile nach einem Eliminierungs-Additions-Mechanismus verläuft. Bei der Umsetzung von α-Chlorhydroxamsäurechloriden mit Methanol in Gegenwart von CaCO3 werden nicht α-Chlorhydroxamsäuremethylester, sondern α-Methoxyhydroxamsäurechloride gebildet.
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  • 56
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 786-799 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aminofumarsäuredialkylester und 2-Amino-3-acetyl-acrylsäureäthylester reagieren mit p-Benzochinon in Eisessig zu 3-Amino-6-hydroxy-4-alkoxycarbonyl- (bzw. -4-acetyl-) cumarin 1 bzw. 15. N-monosubstituierte Aminofumarsäuredialkylester liefern unter sonst gleichen Bedingungen meist ebenfalls das N-unsubstituierte 3-Amino-6-hydroxy-4-alkoxy-carbonyl-cumarin 1 bzw. das 3,6-Dihydroxy-4-alkoxycarbonyl-cumarin 12. In Abhängigkeit von den Ausgangsprodukten findet man darüber hinaus Benzofurane, Benzo[1.2-b; 4.5-b′]difurane und Benzo[1.2-b; 4,5-b′]dipyrone. Aus 2-Amino-3-benzoyl-acrylsäureäthylester entsteht mit p-Benzochinon in guten Ausbeuten 5-Hydroxy-3-benzoyl-2-äthoxycarbonyl-indol 19.
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  • 57
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aminofumarsäurediäthylester reagiert mit p-Benzochinon in Gegenwart äquimolarer Mengen Bortrifluorid unter thermodynamischer Kontrolle zum 3-Amino-6-hydroxy-4-äthoxycarbonyl-cumarin 2; die kinetisch kontrollierte Reaktion liefert das 3,6-Dihydroxy-4-äthoxycarbonyl-cumarin 3a. N,N-disubstituierte Aminomaleinsäuredimethylester bilden mit p-Benzochinon sowohl in Eisessiglösung ohne Katalysator als auch mit Bortrifluoridätherat in Diäthyläther das 2,3,6,7-Tetramethoxycarbonyl-benzo[1.2-b; 4.5-b′]difuran 5, bei den bortrifluoridkatalysierten Umsetzungen lassen sich Zwischenprodukte der Reaktion isolieren.
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  • 58
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 878-880 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 59
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 889-892 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Zinkdicyanimid reagiert mit Methanol unter Bildung von Zink-bis-(imino-bis-carbimidsäuremethylester). Durch Behandeln mit Schwefelwasserstoff läßt sich hieraus der freie Ester gewinnen. Beide Verbindungen liefern mit Carbonsäureanhydriden oder Carbonsäurechloriden substituierte Dialkoxy-s-triazine.
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  • 60
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 884-888 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Hexa-coordinated complexes of nickel(II) bis(methylacetoacetate) with pyridine, β-picoline and β-picoline have been prepared and characterised. Conductance measurements in methanol indicate non-electrolytic nature of the complexes. The complexes are all pale blue in color and are paramagnetic (μeff. = 3.0-3.1 B.M.). Electronic spectra and magnetic moment identify the complexes as octahedral ones. The d-d spectra of the complexes are discussed in the light of the structure of the complexes. The spectrophotometric data for the adducts have been used to calculate the values for the parameters, Δ, B′, β and λ.
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  • 61
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 893-896 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the hydrolysis of n-amyl bromide and iso-amyl bromide have been studied in alkaline and neutral media at different temperatures in varying ethanol-water mixtures. The substitution and elimination reactions occur simultaneously in alkaline medium, while in neutral medium only substitution reaction occurs. They have been analysed kinetically and given separate rate constants.
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  • 62
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 936-941 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1-Acylsemicarbazide reagieren in Dimethylsulfoxid/Kaliumhydroxid mit molekularem Sauerstoff unter Abspaltung von Stickstoff, Kohlenmonoxid und Wasser zu N-substituierten Carbonsäureamiden. Die Umsetzung verläuft wahrscheinlich über die Zwischenstufe der instabilen Azoverbindungen. Durch ein Kreuzungsexperiment wurde festgestellt, daß die Carbonsäureamidbildung zumindest teilweise intermolekular über Bruchstücke erfolgt.
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  • 63
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 993-996 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In den Massenspektren der 2-Methylencycloalkanonäthylenketale mit den Ringgrößen C4 bis C6 zeigen sich charakteristische Fragmentierungsvorgänge. Neben der dirigierenden Wirkung der Ketalgruppierung übt die exo-Methylengruppe einen charakteristischen Einfluß auf die Spaltungsvorgänge aus. Er ist dem einer Methylgruppe entgegengesetzt.
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  • 64
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 1013-1017 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Uranium tetraacetate is always the end product when uranium tetrachloride is treated with excess of tertiary butyl acetate, even in cold. However, when uranium tetrachloride is made to react with other esters, the replacement of chloride groups by acetate groups was found to be in the order normal 〈 secondary 〈 tertiary, resulting in the formation of acetate derivatives.
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  • 65
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 997-1012 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Alkalisalzen des Benzimidazolthions bildet sich bei der Reaktion mit Acetobromglucose in Äthanol oder in Aceton - Wasser sehr bevorzugt das S-Glucosid 2. Vom Benzimidazolthion werden drei Quecksilber-Verbindungen hergestellt; ihre Umsetzungen mit Acetobromglucose in siedendem Xylol oder siedendem Benzol führen zum N,N′-Diglucosid 5, daneben entsteht etwas N-Glucosid 4. Die beiden Verbindungen bilden sich dabei zumindest teilweise aus dem S-Glucosid 2 durch Umglucosidierung und durch Transglucosidierung. In Dimethylformamid liefert die Glucosidierung des Bis-(benzimidazolthionyl)-quecksilbers mit Acetobromglucose bevorzugt das S-Glucosid 2. Dieses läßt sich am besten durch Glucosidieren des N,N′-Bis-(trimethylsilyl)-benzimidazolthions in der Schmelze, das N,N′-Diglucosid 5 durch Umsetzung der Silyl-Verbindung mit Acetobromglucose in siedendem Benzol bei Gegenwart von Quecksilber(II)-bromid und Quecksilberoxid darstellen. Die beiden N-Glucoside 4 und 5 können durch Kochen mit RANEY-Nickel in Äthanol entschwefelt werden, man erhält dabei das Benzimidazol-N-glucosid 6 bzw. das 2,3-Dihydro-benzimidazol-N,N′-diglucosid 7.
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  • 66
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 1018-1028 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Synthese einiger vom Lysin abgeleiteten schwefelhaltigen Aminosäuren, darunter Sulfoxide und Sulfone, wird beschrieben. Die Isolierung wurde mittels Ionenaustauscher-Verfahren durchgeführt.
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  • 67
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 1-2 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 68
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 3-8 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Synthese des geschützten Pentapeptids Boc - Orn(MOA)-Thr - Orn(Z) - Thr - Orn(Z) - OMe [3] beschrieben. Dazu wurden die beiden Dipeptide Boc - Thr - Orn(Z) - OH und Thr - Orn(Z) - OMe nach der Carbodiimid- und Azid-Methode zum Tetrapeptid gekuppelt und dieses mit Boc - Orn(MOA) - ONP zum Pentapeptid umgesetzt.
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  • 69
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 70
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 9-14 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die aus 4-Amino-1,2,4-triazol bzw. 3,5-Dimethyl-4-amino-1,2,4-triazol erhältlichen 1-Al-kyl-4-amino- bzw. 1-Alkyl-3,5-dimethyl-4-amino-triazolium-Salze gehen beim Erhitzen mit verdünnter Natronlauge durch Ringspaltung, Wanderung der gebildeten Acylgruppe und erneuten Ringschluß in die entsprechenden 4-Alkylamino-1,2,4-triazole über, deren Struktur bewiesen wird.Die Acylwanderung verläuft intermolekular, wie sich aus dem Kreuzungsexperiment ergibt.
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  • 71
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 15-35 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der elektrophilen Halogenierung von Olefinen in Gegenwart organischer Cyanverbindungen, wie RCN, RSCN, R2NCN, CICN und ROCN werden neben den 1,2-Dihalogenalkanen N-(β-Haloalkyl)-imidhalogenide erhalten, die bei Hydrolyse die entsprechenden Amide ergeben. So sind N-(β-Haloalkyl)-amide, N-(β-Haloalkyl)-thiolurethane, N-(β-Haloalkyl)-N′,N′-dialkylharnstoffe und N-(β-Haloalkyl)-urethane zugänglich.Die primär entstehenden Verbindungen mit Imidhalogenidstruktur sind teils zersetzliche, teils in Substanz isolierbare Verbindungen.
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  • 72
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 40-44 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2-Amino-3-halogen-pyrazine werden mit Brom in Bromwasserstoffsäure leicht bromiert. Der Eintritt des Broms erfolgt in 5-Stellung. Die Darstellung von 2,3,5-Trihalogen- sowie 2,5-Dihalogen-3-hydroxy-pyrazinen aus 2-Amino-3,5-dihalogen-pyrazinen wird beschrieben.
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  • 73
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 61-70 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 4,6-Diphenyl-2H-thiopyranthion-(2) 1, ist am Thionschwefel zu Thiopyryliumsalzen des Typs 2, alkylierbar und acylierbar. Bei der Umsetzung von Oxalylhalogeniden mit 1, oder 4,6-Diphenyl-2H-thiopyranon-(2) 4 fragmentiert das Acylierungsprodukt A zu den reaktiven 2-Halogen-thiopyryliumsalzen 3.Die Hydrolyse der 3, führt zu Gemischen von 1, und 4,6-Diphenyl-2H-thiopyranon-(2) 4, die Sulfhydrolyse zu reinem 1.1 und 2 sind zu 4 hydrolysierbar, mit primären Aminen bilden 1,2 und 3 die Azomethine 5. Am Stickstoff aliphatisch substituierte 5 werden durch Methyljodid zu 2-Dialkylamino-thiopyrylium-jodiden 6 alkyliert. Aliphatische Amine bewirken bei 4 einen Austausch des Ringschwefels gegen Stickstoff unter Bildung von 4,6-Diphenyl-pyridonen-(2) 9. Kupferbronze reagiert mit 1 unter Bildung von 4,4′,6,6′-Tetraphenyl-2,2′-dithiodipyrylen 10.
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  • 74
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 36-39 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Am cis-4-Phenyl-4-hydroxy-cycloheptanol, cis-1,4-Dimethyl- und cis-1,4-Dibutylcycloheptandiol-(1,4) können infrarotspektroskopisch transanulare H-Brücken nachgewiesen werden. In den entsprechenden trans-Verbindungen findet keine transanulare Assoziation statt.
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  • 75
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 71-77 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2-Hydrazino-pyridin- bzw. -chinolin-hydrochlorid (1 bzw. 2) reagiert mit 2-Amino-5-aryl-1.3.4-oxdiazolen 3 in Äthanol-Pyridin unter Abspaltung von Ammoniak zu Produkten, denen die Struktur von 3-(Nβ-Aroyl-hydrazino)-s-triazolo[4,3-a]pyridinen 4 bzw. 1-(Nβ-Aroyl-hydrazino)-s-triazolo[4,3-a]chinolinen 5 zugesprochen wird, da die Verbindungen 4 in einer für dieses Ringsystem typischen Oxydationsreaktion 1.2.4-Triazol ergeben.
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  • 76
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 78-81 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung von o-[p-Tosylamino]-benzoylchlorid mit ätherischer Diazomethan-lösung entsteht o-[p-Tosylamino]-ω-diazoacetophenon 5 in guter Ausbeute, aus dem über N-Tosyl-indoxyl 6 Indigo gewonnen werden kann.
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  • 77
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 91-96 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In Lösungsmitteln unterschiedlicher Polarität wird die Umsetzung des trans-1-Phenyl-2-cyclohexyl-äthylens mit Brom und Chlor sowie komplexen Halogenierungsmitteln untersucht. Aus der IR-spektroskopischen Produktanalyse der Diastereomerenbildung ergeben sich Schlußfolgerungen über die Natur des Zwischenzustandes bei der elektrophilen Halogenaddition.
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  • 78
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 97-101 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von 2,5-Methylen-1,2,5,6-tetrahydrobenzaldehyd 1 bzw. 2,5-Methylenhexahydrobenzaldehyd 2 mit Acetophenonen liefert Chalkone, während Aceton vornehmlich zum Aldol-Additionsprodukt führt. KNOEVENAGEL-Kondensationen mit Malonsäure und ihren Derivaten verlaufen in der bicyclischen Reihe im allgemeinen glatt.
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  • 79
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 45-60 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die charakteristischen UV-S-Absorptionen einiger Aryldithiocarbonsäureester werden mitgeteilt. Die längstwelligen Banden werden auf der Basis der HMO - SC-Übergangsenergien diskutiert. Die ersten intensiven Absorptionsmaxima von Dithiobenzoesäureestern, die in p-Stellung mit Elektronendonatoren substituiert sind, dienen zur Ableitung spektroskopischer Substituentenkonstanten. Diese sind auch für andere Serien brauchbar.Schon die einfache HÜCKELsche MO - LCAO - (kurz HMO-) Methode erlaubt eine Beschreibung der Anregungsenergien der längstwelligen Absorptionsbanden heterocyclischer Schwefelverbindungen im ultravioletten und sichtbaren Spektrabereich [1-5].Diese quantenchemische Methode geht von sinnvollen Annahmen über die Eigenschaften der einzelnen Atome μ und Bindungen μν in den π-Elektronensystemen aus, die als empirische Parameter αμ = αC + hμβCC (COULOMB-Integral) und βμν = kμνβCC (Resonanzintegral) in die Rechnung eingehen (vgl. [6]).In welchem Umfang die bisher verwendeten Schwefelparameter auch für die Berechnung acyclischer Schwefelverbindungen geeignet sind, ist bisher nicht eingehend geprüft worden. Ein anderes offenes Problem ist das Verhältnis der Schwefelparameter zu denen anderer Heteroatome. Dithiocarbonsäureester, deren Präparation und Reduktion Gegenstand einer früheren Veröffentlichung war [7], bieten eine Möglichkeit, diesen Fragenkomplex in Angriff zu nehmen und das experimentelle spektroskopische Material zu systematisieren.
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  • 80
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 102-104 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Interaction of uranyl nitrate with potassium-molybdocyanide has been investigated spectrophotometrically. The reaction occurs in the molar ratio of 1:1. This is further supported by conductometric titrations performed in aqueous and aqueous-alcoholic media. Formation constant and free energy of formation has been calculated.
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  • 81
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 105-117 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mit einem anisothermen Mischungskalorimeter, das auf dem Prinzip der thermometrischen Titration beruht, und einem Verdampfungskalorimeter, das nach der Inertgas-Durchströmungsmethode arbeitet und die isotherme differentielle Verdampfungswärme zu bestimmen gestattet, wurde das Enthalpie-Konzentrations-Diagramm (MOLLIER-PONCHON-Diagramm) des Systems Nitromethan/Wasser für 50° in einer für technische Zwecke ausreichenden Güte bestimmt. Die experimentellen Ergebnisse konnten mit theoretischen Voraussagen von SCHUBERTH [2] unter Verwendung des zweiseitigen PORTERschen Ansatzes, der für die Beschreibung des Phasengleichgewichtsverhaltens des genannten Systems eine gute Näherung darstellt [3], verglichen werden; die Übereinstimmung war im Rahmen des zu Erwartenden zufriedenstellend.
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  • 82
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 130-134 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurde die Nitrierung von 2,3-diarylsubstituierten Indonen 1 mit einer Methyl- bzw. Methoxylgruppe am 3-Phenylrest untersucht. Die anfallenden Nitroprodukte wurden durch Säulenchromatographie an Aluminiumoxid gereinigt und ihre Struktur durch IR-Spektroskopie und oxydativen Abbau ermittelt.
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  • 83
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 82-90 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die N2O4-Oxydation von Thioäthern R1 - S - R2 in Tetrachlorkohlenstoff als Lösungsmittel wurde nach der Methode der Konkurrenzreaktion kinetisch verfolgt. Die relativen RG-Konstanten von 6 kernsubstituierten Thioanisolen genügen der Hammett-Gleichung mit ϱ = -2,71; die relativen RG-Konstanten von 30 aliphatischen Sulfiden genügen der Taft-Gleichung mit ϱ* = -1,68 und δ = 0,85. Zwischen den RG-Konstanten der N2O4-Oxydation und denen der H2O2-Oxydation besteht eine lineare Freie-Energie-Beziehung. Alle Befunde deuten darauf hin, daß bei der untersuchten Reaktion ein nucleophiler Angriff des Sulfid-S-Atoms auf ein O-Atom des N2O4 stattfindet. Da die N2O4-Oxydation nach einem Geschwindigkeitsgesetz \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm RG = k}_{\rm 3} \left[{{\rm Thio}\mathop {\rm a}\limits^{..} {\rm ther}} \right]\left[{{\rm N}_{\rm 2} {\rm O}_{\rm 4} } \right]^2 $$\end{document} verläuft, muß ein cyclischer Übergangszustand angenommen werden, der zwei Moleküle N2O4 und ein Molekül Thioäther enthält.
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  • 84
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 135-140 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Hydrierungsgeschwindigkeit unverzweigter Δ1-Olefine des Kettenlängenbereiches C6—C17 in Äthanol in Gegenwart von Pt, Pd- und Rh-haltigen Trägerkontakten sinkt mit steigender Kettenlänge des Olefins. Geschwindigkeitsbestimmend ist die Reaktion an der Katalysatoroberfläche an Pt-haltigen Trägerkonstanten.
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  • 85
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 141-146 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurde gezeigt, daß eine Reinigung des bei der Perjodatoxydation des Dextrans gebildeten Oxydextrans vom Jodat in einfacher Weise mittels Ionenaustauschern auch im präparativen Maßstab erfolgen kann. An Stelle des in der Literatur für analytische Arbeiten zur Abtrennung von Perjodat beschriebenen Austauschers Amberlite IRA - 400 (Acetatform) konnten mit Erfolg Austauscher der DDR-Produktion eingesetzt werden (Wofatit SBW und Wofatit L 150 des VEB Farbenfabrik Wolfen). Wofatit L 150 ist wegen seiner höheren Kapazität und seines universelleren Anwendungsbereiches (pH 1 - 14) dem Wofatit SBW vorzuziehen. Die Abtrennung des Oxydextrans vom Jodat gelingt quantitativ bei einer Rückgewinnung des Jodats von 99,0 ± 0,7%. Ist in der zu reinigenden Oxydextranlösung neben Jodat noch Natriumsulfat in größeren Mengen vorhanden, wie es für die Regeneration des Jodats zu Perjodat durch anodische Oxydation erforderlich ist, muß zweistufig adsorbiert/eluiert werden.
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 118-129 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Benzonitriloxid-Addition an die semicyclische CC-Doppelbindung der 2-Methylen-cycloalkanone-(1), der benzokondensierten und bicyclischen α-Methylenketone sowie der α,α′-Dimethylen-cycloalkanone beschrieben. Die erhaltenen Spiro-isoxazoline wurden NMR-spektroskopisch untersucht und daraus die Additionsrichtung festgelegt. Die LiAlH4-Reduktion vom Benzonitriloxid-Addukt des 2-Methylen-cycloheptanons-(1) liefert 1,2-Dihydroxy-2-(β-amino-β-phenyl-äthyl)-cycloheptan.
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 153-158 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Als Testsubstanzen zur Untersuchung der Abbauprodukte von Diacetylen-MANNICH-Basen-methojodiden mit wäßriger Kalilauge wurden die isomeren Octendiine und Nonendiine 1-3 synthetisiert und deren gaschromatographische Identifizierung untersucht.
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 159-161 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 165-167 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 168-170 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 162-164 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Peroxygenierungsgeschwindigkeiten bei Alkoholen, Essigsäureestern und Methyläthern mit olefinischen und aromatischen Gruppen werden verglichen. Die substituierten Essigsäureester und Methyläther bilden Hydroperoxide, deren Struktur bewiesen wurde. C—H-Bindungen mit benachbarten sauerstoffhaltigen funktionellen Gruppen und olefinischen oder aromatischen Resten reagieren leicht mit molekularem Sauerstoff. Enthält die funktionelle Gruppe Carbonylsauerstoff, so verläuft die Reaktion nach dem α-Methylen-Mechanismus; ist der Sauerstoff Brückenatom, so tritt keine Wanderung der Doppelbindung ein.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 93
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 171-171 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 172-173 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 95
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 174-177 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 96
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 183-186 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 97
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 178-182 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 98
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 187-189 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 99
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    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 100
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    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 190-192 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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