Bibliothek

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • 2005-2009  (31)
  • 1985-1989
  • 1965-1969  (578)
  • 2009  (31)
  • 1969  (268)
  • 1966  (310)
  • Chemical Engineering  (578)
  • ddc:510  (31)
Materialart
Erscheinungszeitraum
  • 2005-2009  (31)
  • 1985-1989
  • 1965-1969  (578)
Jahr
Sprache
  • 1
    Publikationsdatum: 2019-01-29
    Beschreibung: We consider an optimal control problem from hyperthermia treatment planning and its barrier regularization. We derive basic results, which lay the groundwork for the computation of optimal solutions via an interior point path-following method. Further, we report on a numerical implementation of such a method and its performance at an example problem.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Publikationsdatum: 2016-06-09
    Beschreibung: Optical technologies are ubiquitously used in hi-tech devices. As a common feature of such devices one finds structures with dimensions in the order of the wavelength of the used light. To design and produce such devices, the wave nature of light must be taken into account. Accordingly, robust simulation tools are required which are based on rigorously solving Maxwell's equations, the governing equations of light propagation within macroscopic media. This thesis contributes to the modeling and the numerical computation of light scattering problems: Light scattering problems are typically posed on the entire space. The Perfectly-Matched -Layer method (PML) is widely used to restrict the simulation problem onto a bounded computational domain. We propose an adaptive PML method which exhibits a good convergence even for critical problems where standard PML implementations fail. Besides the computation of the near field, that is the electromagnetic field within the computational domain, it is of major interest to evaluate the electromagnetic field in the exterior domain and to compute the far field. So far, this was numerically only possible for simple geometries such as homogeneous exterior domains or layered media. To deal with more complicated devices, for example with waveguide inhomogeneities, we develop an evaluation formula based on the PML solution which allows for an exterior domain field evaluation in a half space above the device. Finally, we generalize the PML method to problems with multiply structured exterior domains. The term “multiply structured exterior domain” is defined in this thesis and means that the exterior domain exhibits several half-infinite structures. Mathematically, this gives rise to various complications. For example, no analytical solutions to Maxwell's equations for standard light sources are available in the exterior domain, which are needed to describe the incoming field in a light scattering problem. To tackle this we propose a new light scattering problem formulation which fits well into the PML method framework and which may be regarded as an extension of classical contributions by Sommerfeld, Wiener and Hopf. An exterior domain evaluation formula for multiply structured exterior domains with an extended illumination is derived as well.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: doctoralthesis , doc-type:doctoralThesis
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Publikationsdatum: 2020-08-05
    Beschreibung: We introduce the coolest path problem, which is a mixture of two well-known problems from distinct mathematical fields. One of them is the shortest path problem from combinatorial optimization. The other is the heat conduction problem from the field of partial differential equations. Together, they make up a control problem, where some geometrical object traverses a digraph in an optimal way, with constraints on intermediate or the final state. We discuss some properties of the problem and present numerical solution techniques. We demonstrate that the problem can be formulated as a linear mixed-integer program. Numerical solutions can thus be achieved within one hour for instances with up to 70 nodes in the graph.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/zip
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Publikationsdatum: 2021-08-05
    Beschreibung: Given a general mixed integer program (MIP), we automatically detect block structures in the constraint matrix together with the coupling by capacity constraints arising from multi-commodity-flow formulations. We identify the underlying graph and generate cutting planes based on cuts in the detected network. Our implementation adds a separator to the branch-and-cut libraries of SCIP and CPLEX. We make use of the complemented mixed integer rounding framework (cMIR) but provide a special purpose aggregation heuristic that exploits the network structure. Our separation scheme speeds-up the computation for a large set of MIPs coming from network design problems by a factor of two on average.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    Publikationsdatum: 2022-03-14
    Beschreibung: Pseudo-Boolean problems lie on the border between satisfiability problems, constraint programming, and integer programming. In particular, nonlinear constraints in pseudo-Boolean optimization can be handled by methods arising in these different fields: One can either linearize them and work on a linear programming relaxation or one can treat them directly by propagation. In this paper, we investigate the individual strengths of these approaches and compare their computational performance. Furthermore, we integrate these techniques into a branch-and-cut-and-propagate framework, resulting in an efficient nonlinear pseudo-Boolean solver.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 6
    Publikationsdatum: 2020-08-05
    Beschreibung: Every day, millions of people are transported by buses, trains, and airplanes in Germany. Public transit (PT) is of major importance for the quality of life of individuals as well as the productivity of entire regions. Quality and efficiency of PT systems depend on the political framework (state-run, market oriented) and the suitability of the infrastructure (railway tracks, airport locations), the existing level of service (timetable, flight schedule), the use of adequate technologies (information, control, and booking systems), and the best possible deployment of equipment and resources (energy, vehicles, crews). The decision, planning, and optimization problems arising in this context are often gigantic and “scream” for mathematical support because of their complexity. This article sketches the state and the relevance of mathematics in planning and operating public transit, describes today’s challenges, and suggests a number of innovative actions. The current contribution of mathematics to public transit is — depending on the transportation mode — of varying depth. Air traffic is already well supported by mathematics. Bus traffic made significant advances in recent years, while rail traffic still bears significant opportunities for improvements. In all areas of public transit, the existing potentials are far from being exhausted. For some PT problems, such as vehicle and crew scheduling in bus and air traffic, excellent mathematical tools are not only available, but used in many places. In other areas, such as rolling stock rostering in rail traffic, the performance of the existing mathematical algorithms is not yet sufficient. Some topics are essentially untouched from a mathematical point of view; e.g., there are (except for air traffic) no network design or fare planning models of practical relevance. PT infrastructure construction is essentially devoid of mathematics, even though enormous capital investments are made in this area. These problems lead to questions that can only be tackled by engineers, economists, politicians, and mathematicians in a joint effort. Among other things, the authors propose to investigate two specific topics, which can be addressed at short notice, are of fundamental importance not only for the area of traffic planning, should lead to a significant improvement in the collaboration of all involved parties, and, if successful, will be of real value for companies and customers: • discrete optimal control: real-time re-planning of traffic systems in case of disruptions, • model integration: service design in bus and rail traffic. Work on these topics in interdisciplinary research projects could be funded by the German ministry of research and education (BMBF), the German ministry of economics (BMWi), or the German science foundation (DFG).
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 7
    Publikationsdatum: 2020-08-05
    Beschreibung: The steel mill slab design problem from the CSPLib is a binpacking problem that is motivated by an application of the steel industry and that has been widely studied in the constraint programming community. Recently, several people proposed new models and methods to solve this problem. A steel mill slab library was created which contains 380 instances. A closely related binpacking problem called multiple knapsack problem with color constraints, originated from the same industrial problem, were discussed in the integer programming community. In particular, a simple integer programming for this problem has been given by Forrest et al. [3]. The aim of this paper is to bring these different studies together. Moreover, we adopt the model of [3] for the steel mill slab problem. Using a state of the art integer program solver, this model is capable to solve all instances of the steel mill slab library, mostly in less than one second, to optimality. We improved, thereby, the solution value of 76 instances.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 8
    Publikationsdatum: 2020-08-05
    Beschreibung: Nowadays most data networks use shortest path protocols such as OSPF or IS-IS to route traffic. Given administrative routing lengths for the links of a network, all data packets are sent along shortest paths with respect to these lengths from their source to their destination. One of the most fundamental problems in planning shortest path networks is to decide whether a given set of routing paths forms a valid routing and, if this is not the case, to find a small subset of the given paths that cannot be shortest paths simultaneously for any routing lengths. In this paper we show that it is NP-hard to approximate the size of the smallest shortest path conflict by a factor less than 7/6.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 9
    Publikationsdatum: 2020-08-05
    Beschreibung: The Vehicle Positioning Problem (VPP) consists of the assignment of vehicles (buses, trams or trains) of a public transport or railway company to parking positions in a depot and to timetabled trips. Such companies have many different types of vehicles, and each trip can be performed only by vehicles of some of these types. These assignments are non-trivial due to the topology of depots. The parking positions are organized in tracks, which work as one- or two-sided stacks or queues. If a required type of vehicle is not available in the front of any track, shunting movements must be performed in order to change vehicles' positions, which is undesirable and should be avoided. In this text we present integer linear and non-linear programming formulations for some versions of the problem and compare them from a theoretical and a computational point of view.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/pdf
    Format: application/postscript
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 10
    Publikationsdatum: 2020-03-11
    Beschreibung: The understanding of geometric structures and dynamical properties of molecular conformations gives insight into molecular long-term behavior. The identification of metastable conformations together with their life times and transition patterns is the intention of conformation dynamics. Conformation dynamics is a multi-scale approach that leads to a reduced description of the dynamical system in terms of a stochastic transition probability matrix. The present thesis deals with the error analysis of computed matrices and the resulting matrix functions. Since conformational membership vectors, as they are computed by the Robust Perron Cluster Analysis (PCCA+), form an invariant subspace of the transition matrix, subspace-based error estimators are of particular interest. The decomposition of the state space into basis functions and the approximation of integrals by Monte-Carlo quadrature give rise to row-wise correlated random matrices, for which stochastic norms are computed. Together with an appropriate statistical model for the distribution of matrix rows, this allows for the calculation of error bounds and error distributions of the invariant subspace and other variables of interest. Equilibration of errors among the basis functions can be achieved by enhanced sampling in regions where the trajectories are mixing slowly. Hierarchical refinement of such basis functions systematically improves the clustering into metastable conformations by reducing the error in the corresponding invariant subspace. These techniques allow for an evaluation of simulation results and pave the way for the analysis of larger molecules. Moreover, the extension of PCCA+ to non-reversible Markov chains, verified by the corresponding perturbation theory, and the modification of the objective function for the case of soft membership vectors represent a further generalization of the clustering method, thus continuing the development from PCCA over PCCA+ to PCCA++. The methods developed in this thesis are useful for but not limited to conformation dynamics. In fact, they are applicable to a broader class of problems which combine domain decomposition with Monte-Carlo quadrature. Possible application areas may include the chemical master equation or quantum dynamical systems.
    Beschreibung: Das Verständnis von geometrischen Strukturen und dynamischen Eigenschaften molekularer Konformationen ist essentiell für die Vorhersage des Langzeitverhaltens von Molekülen. Die Identifikation metastabiler Konformationen sowie die Bestimmung von Übergangswahrscheinlichkeiten und Haltezeiten sind Bestandteil der Konformationdynamik. Dabei handelt es sich um eine Mehrskalenmethode, die auf eine reduzierte Beschreibung des Systems mittels einer stochastischen Übergangsmatrix führt. In der vorliegenden Dissertation wurde untersucht, wie man die Genauigkeit der Matrizen sowie der daraus berechneten Größen quantifizieren kann. Im Mittelpunkt stehen dabei Fehlerschätzer für den invarianten Unterraum, da die rechten Eigenvektoren als Grundlage der Robusten Perron Cluster Analyse (PCCA+) zur Identifizierung der metastabilen Konformationen dienen. Die Zerlegung des Zustandsraumes in Basisfunktionen sowie die Approximation der Matrixeinträge mittels Monte-Carlo-Quadratur führen zu zeilenweise korrelierten Zufallsmatrizen. Mit Hilfe einer stochastischen Norm sowie einem geeigneten statistischen Modell für die Verteilung der Matrixzeilen können u.a. Fehlerschranken und -verteilungen für den invarianten Unterraum brechnet werden. Eine Equilibrierung des Fehlers zwischen den Basisfunktionen kann durch erweitertes Sampling in solchen Regionen erreicht werden, in denen die Trajektorien nur langsam mischen.Eine hierarchische Zerlegung dieser Basisfunktionen verbessert systematisch die Zerlegung in metastabile Konformationen, indem sie den Fehler im invarianten Unterraum reduziert. Diese Techniken gestatten eine Evaluierung der Simulationsergebnisse und ebnen den Weg zur Behandlung komplexerer Moleküle. Desweiteren wurden Verallgemeinerungen der PCCA+ untersucht. Die Erweiterung der PCCA+ auf nicht-reversible Markov-Ketten sowie die Modifizierung der Zielfunktion für den Fall der weichen Clusterung setzen die Entwicklung von der PCCA über PCCA+ zu PCCA++ fort. Somit können neue Anwendungsfelder für dieses Cluster-Verfahren erschlossen werden. Die Methoden wurden zwar in Rahmen der Konformationsdynamik entwickelt, jedoch lassen sie sich auf eine weite Problemklasse anwenden, in der Gebietszerlegungsverfahren mit Monte-Carlo-Quadratur kombiniert werden. Mögliche Anwendungsgebiete umfassen die chemische Master-Gleichung oder quantenchemische Systeme.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: doctoralthesis , doc-type:doctoralThesis
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 11
    Publikationsdatum: 2020-08-05
    Beschreibung: The Vehicle Positioning Problem (VPP) is a classical combinatorial optimization problem in public transport planning. A number of models and approaches have been suggested in the literature, which work for small problems, but not for large ones. We propose in this article a novel set partitioning model and an associated column generation solution approach for the VPP. The model provides a tight linear description of the problem. The pricing problem, and hence the LP relaxation itself, can be solved in polynomial resp. pseudo-polynomial time for some versions of the problems.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 12
    Publikationsdatum: 2020-08-05
    Beschreibung: Since the initial application of mathematical optimisation methods to mine planning in 1965, the Lerchs-Grossmann algorithm for computing the ultimate pit limit, operations researchers have worked on a variety of challenging problems in the area of open pit mining. This thesis focuses on the open pit mining production scheduling problem: Given the discretisation of an orebody as a block model, determine the sequence in which the blocks should be removed from the pit, over the lifespan of the mine, such that the net present value of the mining operation is maximised. In practise, when some material has been removed from the pit, it must be processed further in order to extract the valuable elements contained therein. If the concentration of valuable elements is not sufficiently high, the material is discarded as waste or stockpiled. Realistically-sized block models can contain hundreds of thousands of blocks. A common approach to render these problem instances computationally tractable is the aggregation of blocks to larger scheduling units. The thrust of this thesis is the investigation of a new mixed-integer programming formulation for the open pit mining production scheduling problem, which allows for processing decisions to be made at block level, while the actual mining schedule is still computed at aggregate level. A drawback of this model in its full form is the large number of additional variables needed to model the processing decisions. One main result of this thesis shows how these processing variables can be aggregated efficiently to reduce the problem size significantly, while practically incurring no loss in net present value. The second focus is on the application of lagrangean relaxation to the resource constraints. Using a result of Möhring et al. (2003) for project scheduling, the lagrangean relaxation can be solved efficiently via minimum cut computations in a weighted digraph. Experiments with a bundle algorithm implementation by Helmberg showed how the lagrangean dual can be solved within a small fraction of the time required by standard linear programming algorithms, while yielding practically the same dual bound. Finally, several problem-specific heuristics are presented together with computational results: two greedy sub-MIP start heuristics and a large neighbourhood search heuristic. A combination of a lagrangean-based start heuristic followed by a large neighbourhood search proved to be effective in generating solutions with objective values within a 0.05% gap of the optimum.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: masterthesis , doc-type:masterThesis
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 13
    Publikationsdatum: 2019-01-29
    Beschreibung: In dieser Arbeit wird ein neuer Ansatz zur Modellierung von thermal signifikanten Gefäßsträngen im Hyperthermie-Kontext betrachtet. Ausgehend von einer Konvektions-Diffusions-Gleichung wird durch Reskalierung des Massenflussterms eine Reduktion des Adergebietes auf eine 1D-Struktur erreicht. Nach numerischen Vorbetrachtungen wird die Grenzgleichung innerhalb einer verallgemeinerten Sobolev-Algebra formuliert. Die Untersuchung der Lösungsfamilie in klassischen Funktionenräumen zeigt, dass deren schwacher Grenzwert die Lösung der korrespondierenden Diffusions-Gleichung ist. Die Diskretisierung einer formalen Grenzgleichung mit Linienstromanteil stellt jedoch eine gute Approximation an die Diskretisierung des ursprünglichen Problems dar, wenn man die lokale Maschenweite an die Gefäßradien koppelt und bei erhöhtem Genauigkeitsbedarf auf ein vollständiges 3D-Modell umschaltet.
    Schlagwort(e): ddc:510
    Sprache: Deutsch
    Materialart: masterthesis , doc-type:masterThesis
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 14
    Publikationsdatum: 2022-03-14
    Beschreibung: We present Undercover, a primal heuristic for mixed-integer nonlinear programming (MINLP). The heuristic constructs a mixed-integer linear subproblem (sub-MIP) of a given MINLP by fixing a subset of the variables. We solve a set covering problem to identify a minimal set of variables which need to be fixed in order to linearise each constraint. Subsequently, these variables are fixed to approximate values, e.g. obtained from a linear outer approximation. The resulting sub-MIP is solved by a mixed-integer linear programming solver. Each feasible solution of the sub-MIP corresponds to a feasible solution of the original problem. Although general in nature, the heuristic seems most promising for mixed-integer quadratically constrained programmes (MIQCPs). We present computational results on a general test set of MIQCPs selected from the MINLPLib.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/pdf
    Format: application/postscript
    Format: application/postscript
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 15
    Publikationsdatum: 2020-08-05
    Beschreibung: We consider a system with Poisson arrivals and i.i.d. service times. The requests are served according to the state-dependent processor sharing discipline, where each request receives a service capacity which depends on the actual number of requests in the system. The linear systems of PDEs describing the residual and attained sojourn times coincide for this system, which provides time reversibility including sojourn times for this system, and their minimal non negative solution gives the LST of the sojourn time $V(\tau)$ of a request with required service time $\tau$. For the case that the service time distribution is exponential in a neighborhood of zero, we derive a linear system of ODEs, whose minimal non negative solution gives the LST of $V(\tau)$, and which yields linear systems of ODEs for the moments of $V(\tau)$ in the considered neighborhood of zero. Numerical results are presented for the variance of $V(\tau)$. In case of an M/GI/2-PS system, the LST of $V(\tau)$ is given in terms of the solution of a convolution equation in the considered neighborhood of zero. For bounded from below service times, surprisingly simple expressions for the LST and variance of $V(\tau)$ in this neighborhood of zero are derived, which yield in particular the LST and variance of $V(\tau)$ in M/D/2-PS.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 16
    Publikationsdatum: 2020-12-11
    Beschreibung: Eigentlich war der erste Autor nur zu einem Grußwort zur Tagung „GML² 2009 - Grundfragen Multi¬medialen Lehrens und Lernens“ eingeladen. Daraus wurde ein E-Learning-bezogener Vortrag, der – basierend auf Erfahrungen im Fach Mathematik – einen kritischen Blick auf die E-Learning-Szene in Deutschland wirft und diese mit entsprechenden Aktivitäten weltweit vergleicht. Dies ist die in seinen mathematischen Teilen gekürzte, in den E-Learning-Anteilen ein wenig erweiterte schriftliche Fassung des Vortrags. Der Artikel stammt nicht von E-Learning-Spezialisten sondern von Personen, die sich seit fast zwanzig Jahren mit elektronischer Information und Kommunikation (kurz: IuK) – insbesondere in der Mathematik – beschäftigen. Nach einer Definition von Michael Kerres kennzeichnet der Begriff E-Learning (electronic learning – elektronisch unterstütztes Lernen) alle Formen von Lernen, bei denen digitale Medien für die Präsentation und Distribution von Lernmaterialien und/oder zur Unterstützung zwischenmenschlicher Kommunikation zum Einsatz kommen, siehe z.B. http://de.wikipedia.org/wiki/E-Learning. IuK und E-Learning haben nach dieser Begriffsbildung viele Berührungspunkte. Deswegen wagen wir es, unsere positiven und negativen Erfahrungen im Bereich IuK in diesem Eröffnungsvortrag zu berichten, einige Entwicklungslinien zu vergleichen und eine eigene Kurzversion der Definition von E-Learning (besser E-Teaching and -Learning) voranzustellen: „Lehren und Lernen mit Unterstützung elektronischer Hilfsmittel“.
    Schlagwort(e): ddc:510
    Sprache: Deutsch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 17
    Publikationsdatum: 2020-08-05
    Beschreibung: Telecommunication transport networks consist of a stack of technologically different subnetworks, so-called layers, which are strongly interdependent. For example, one layer may correspond to an Internet (IP) backbone network whose links are realized by lightpath connections in an underlying optical fiber layer. To ensure that the network can fulfill its task of routing all communication requests, the inter-layer dependencies have to be taken into account already in the planning phase of the network. This is particularly important with survivability constraints, where connections in one layer have to be protected against cable cuts or equipment failures in another layer. The traditional sequential planning approach where one layer is optimized after the other cannot properly take care of the inter-layer dependencies; this can only be achieved with an integrated planning of several network layers at the same time. This thesis provides mathematical models and algorithmic techniques for the integrated optimization of two network layers with survivability constraints. We describe a multi-layer network design problem which occurs in various technologies, and model it mathematically using mixed-integer programming (MIP) formulations. The presented models cover many important practical side constraints from different technological contexts. In contrast to previous models from the literature, they can be used to design large two-layer networks with survivability requirements. We discuss modeling alternatives for various aspects of a multi-layer network and compare different routing formulations under multi-layer survivability constraints. We solve our models using a branch-and-cut-and-price approach with various problemspecific enhancements. This includes a presolving technique based on linear programming to reduce the problem size, combinatorial and sub-MIP-based primal heuristics to compute feasible network configurations, cutting planes which take the multi-layer survivability constraints into account to improve the lower bound on the optimal network cost, and column generation to generate flow variables dynamically during the algorithm. We develop techniques to speed up computations in a Benders decomposition approach and compare this approach to the standard formulation with a single MIP. We use the developed techniques to design large survivable two-layer networks by means of linear and integer programming methods. On realistic test instances with up to 67 network nodes and survivability constraints, we investigate the algorithmic impact of our techniques and show how to use them to compute good network configurations with quality guarantees. Most of the smaller test instances with up to 17 nodes can be solved to near-optimality. Moreover, we can compute feasible solutions and dual bounds even for large networks with survivability constraints, which has not been possible before.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: doctoralthesis , doc-type:doctoralThesis
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 18
    Publikationsdatum: 2020-08-05
    Beschreibung: In the simplex algorithm, solving linear systems with the basis matrix and its transpose accounts for a large part of the total computation time. We investigate various methods from modern numerical linear algebra to improve the computation speed of the basis updates arising in LPs. The experiments are executed on a large real-world test set. The most widely used solution technique is sparse LU factorization, paired with an updating scheme that allows to use the factors over several iterations. Clearly, small number of fill-in elements in the LU factors is critical for the overall performance. Using a wide range of LPs we show numerically that after a simple permutation the non-triangular part of the basis matrix is so small, that the whole matrix can be factorized with (relative) fill-in close to the optimum. This permutation has been exploited by simplex practitioners for many years. But to our knowledge no systematic numerical study has been published that demonstrates the effective reduction to a surprisingly small non-triangular problem, even for large scale LPs. For the factorization of the non-triangular part most existing simplex codes use some variant of dynamic Markowitz pivoting, which originated in the late 1950s. We also show numerically that, in terms of fill-in and in the simplex context, dynamic Markowitz is quite consistently superior to other, more recently developed techniques.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 19
    Publikationsdatum: 2020-03-11
    Beschreibung: We compute expectation values for the solution of the nuclear Schrödinger equation. The proposed particle method consists of three steps: sampling of the initial Wigner function, classical transport of the sampling points, weighted phase space summation for the final computation of the expectation values. The Egorov theorem guarantees that the algorithm is second order accurate with respect to the semiclassical parameter. We present numerical experiments for a two-dimensional torsional potential with three different sets of initial data and for a six-dimensional Henon-Heiles potential. By construction, the computing times scale linearly with the number of initial sampling points and range between three seconds and one hour.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 20
    Publikationsdatum: 2022-03-14
    Beschreibung: This paper discusses how to build a solver for mixed integer quadratically constrained programs (MIQCPs) by extending a framework for constraint integer programming (CIP). The advantage of this approach is that we can utilize the full power of advanced MIP and CP technologies. In particular, this addresses the linear relaxation and the discrete components of the problem. For relaxation, we use an outer approximation generated by linearization of convex constraints and linear underestimation of nonconvex constraints. Further, we give an overview of the reformulation, separation, and propagation techniques that are used to handle the quadratic constraints efficiently. We implemented these methods in the branch-cut-and-price framework SCIP. Computational experiments indicates the potential of the approach.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/pdf
    Format: application/postscript
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 21
    Publikationsdatum: 2016-06-09
    Beschreibung: Supercomputers can simulate complex molecular systems. However, there is a very large gap between the fastest oscillations of covalent bonds of a molecule and the time-scale of the dominant processes. In order to extract the dominant time-scales and to identify the dominant processes, a clustering of information is needed. This thesis shows that only the subspace-based Robust Perron Cluster Analysis (PCCA+) can solve this problem correctly by the construction of a Markov State Model. PCCA+ allows for time-extrapolation in molecular kinetics. This thesis shows the difference between molecular dynamics and molecular kinetics. Only in the molecular kinetics framework a definition of transition rates is possible. In this context, the existence of an infinitesimal generator of the dynamical processes is discussed. If the existence is assumed, the Theorem of Gauß can be applied in order to compute transition rates efficiently. Molecular dynamics, however, is not able to provide a suitable statistical basis for the determination of the transition pattern.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 22
    Publikationsdatum: 2020-08-05
    Beschreibung: We consider a system with Poisson arrivals and general service times, where the requests are served according to the State-Dependent Processor Sharing (SDPS) discipline (Cohen's generalized processor sharing discipline), where each request receives a service capacity which depends on the actual number of requests in the system. For this system, denoted by $M/GI/SDPS$, we derive approximations for the squared coefficients of variation of the conditional sojourn time of a request given its service time and of the unconditional sojourn time by means of two-moment fittings of the service times. The approximations are given in terms of the squared coefficients of variation of the conditional and unconditional sojourn time in related $M/D/SDPS$ and $M/M/SDPS$ systems, respectively. The numerical results presented for $M/GI/m-PS$ systems illustrate that the proposed approximations work well.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 23
    Publikationsdatum: 2020-08-05
    Beschreibung: We consider a system with Poisson arrivals and i.i.d. service times and where the requests are served according to the state-dependent (Cohen's generalized) processor sharing discipline, where each request in the system receives a service capacity which depends on the actual number of requests in the system. For this system we derive asymptotically tight upper bounds for the moments of the conditional sojourn time of a request with given required service time. The bounds generalize corresponding results, recently given for the single-server processor sharing system by Cheung et al. and for the state-dependent processor sharing system with exponential service times by the authors. Analogous results hold for the waiting times.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 24
    Publikationsdatum: 2020-11-13
    Beschreibung: The Dynamic Multi-Period Routing Problem DMPRP introduced by Angelelli et al. gives a model for a two-stage online-offline routing problem. At the beginning of each time period a set of customers becomes known. The customers need to be served either in the current time period or in the following. Postponed customers have to be served in the next time period. The decision whether to postpone a customer has to be done online. At the end of each time period, an optimal tour for the customers assigned to this period has to be computed and this computation can be done offline. The objective of the problem is to minimize the distance traveled over all planning periods assuming optimal routes for the customers selected in each period. We provide the first randomized online algorithms for the DMPRP which beat the known lower bounds for deterministic algorithms. For the special case of two planning periods we provide lower bounds on the competitive ratio of any randomized online algorithm against the oblivious adversary. We identify a randomized algorithm that achieves the optimal competitive ratio of $\frac{1+\sqrt{2}}{2}$ for two time periods on the real line. For three time periods, we give a randomized algorithm that is strictly better than any deterministic algorithm.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 25
    facet.materialart.
    Unbekannt
    Publikationsdatum: 2021-08-05
    Beschreibung: This thesis introduces the novel paradigm of "constraint integer programming" (CIP), which integrates constraint programming (CP) and mixed integer programming (MIP) modeling and solving techniques. It is supplemented by the software SCIP, which is a solver and framework for constraint integer programming that also features SAT solving techniques. SCIP is freely available in source code for academic and non-commercial purposes. Our constraint integer programming approach is a generalization of MIP that allows for the inclusion of arbitrary constraints, as long as they turn into linear constraints on the continuous variables after all integer variables have been fixed. The constraints, may they be linear or more complex, are treated by any combination of CP and MIP techniques: the propagation of the domains by constraint specific algorithms, the generation of a linear relaxation and its solving by LP methods, and the strengthening of the LP by cutting plane separation. The current version of SCIP comes with all of the necessary components to solve mixed integer programs. In the thesis, we cover most of these ingredients and present extensive computational results to compare different variants for the individual building blocks of a MIP solver. We focus on the algorithms and their impact on the overall performance of the solver. In addition to mixed integer programming, the thesis deals with chip design verification, which is an important topic of electronic design automation. Chip manufacturers have to make sure that the logic design of a circuit conforms to the specification of the chip. Otherwise, the chip would show an erroneous behavior that may cause failures in the device where it is employed. An important subproblem of chip design verification is the property checking problem, which is to verify whether a circuit satisfies a specified property. We show how this problem can be modeled as constraint integer program and provide a number of problem-specific algorithms that exploit the structure of the individual constraints and the circuit as a whole. Another set of extensive computational benchmarks compares our CIP approach to the current state-of-the-art SAT methodology and documents the success of our method.
    Beschreibung: Diese Arbeit stellt einen integrierten Ansatz aus "Constraint Programming" (CP) und Gemischt-Ganzzahliger Programmierung ("Mixed Integer Programming", MIP) vor, den wir "Constraint Integer Programming" (CIP) nennen. Sowohl Modellierungs- als auch Lösungstechniken beider Felder fließen in den neuen integrierten Ansatz ein, um die unterschiedlichen Stärken der beiden Gebiete zu kombinieren. Als weiteren Beitrag stellen wir der wissenschaftlichen Gemeinschaft die Software SCIP zur Verfügung, die ein Framework für Constraint Integer Programming darstellt und zusätzlich Techniken des SAT-Lösens beinhaltet. SCIP ist im Source Code für akademische und nicht-kommerzielle Zwecke frei erhältlich. Unser Ansatz des Constraint Integer Programming ist eine Verallgemeinerung von MIP, die zusätzlich die Verwendung beliebiger Constraints erlaubt, solange sich diese durch lineare Bedingungen ausdrücken lassen falls alle ganzzahligen Variablen auf feste Werte eingestellt sind. Die Constraints werden von einer beliebigen Kombination aus CP- und MIP-Techniken behandelt. Dies beinhaltet insbesondere die "Domain Propagation", die Relaxierung der Constraints durch lineare Ungleichungen, sowie die Verstärkung der Relaxierung durch dynamisch generierte Schnittebenen. Die derzeitige Version von SCIP enthält alle Komponenten, die für das effiziente Lösen von Gemischt-Ganzzahligen Programmen benötigt werden. Die vorliegende Arbeit liefert eine ausführliche Beschreibung dieser Komponenten und bewertet verschiedene Varianten in Hinblick auf ihren Einfluß auf das Gesamt-Lösungsverhalten anhand von aufwendigen praktischen Experimenten. Dabei wird besonders auf die algorithmischen Aspekte eingegangen. Ein weiterer Hauptteil der Arbeit befasst sich mit der Chip-Design-Verifikation, die ein wichtiges Thema innerhalb des Fachgebiets der "Electronic Design Automation" darstellt. Chip-Hersteller müssen sicherstellen, dass der logische Entwurf einer Schaltung der gegebenen Spezifikation entspricht. Andernfalls würde der Chip fehlerhaftes Verhalten aufweisen, dass zu Fehlfunktionen innerhalb des Gerätes führen kann, in dem der Chip verwendet wird. Ein wichtiges Teilproblem in diesem Feld ist das Eigenschafts-Verifikations-Problem, bei dem geprüft wird, ob der gegebene Schaltkreisentwurf eine gewünschte Eigenschaft aufweist. Wir zeigen, wie dieses Problem als Constraint Integer Program modelliert werden kann und geben eine Reihe von problemspezifischen Algorithmen an, die die Struktur der einzelnen Constraints und der Gesamtschaltung ausnutzen. Testrechnungen auf Industrie-Beispielen vergleichen unseren Ansatz mit den bisher verwendeten SAT-Techniken und belegen den Erfolg unserer Methode.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: doctoralthesis , doc-type:doctoralThesis
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 26
    facet.materialart.
    Unbekannt
    Publikationsdatum: 2020-08-05
    Beschreibung: In this paper we investigate the fare planning model for public transport, which consists in designing a system of fares maximizing the revenue. We discuss a discrete choice model in which passengers choose between different travel alternatives to express the demand as a function of fares. Furthermore, we give a computational example for the city of Potsdam and discuss some theoretical aspects.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 27
    Publikationsdatum: 2020-08-05
    Beschreibung: This extended abstract is about algorithms for controlling elevator systems employing destination hall calls, i.e. the passenger provides his destination floor when calling an elevator. We present the first exact algorithm for controlling a group of elevators and report on simulation results indicating that destination hall call systems outperform conventional systems.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 28
    Publikationsdatum: 2019-01-29
    Beschreibung: The paper proposes goal-oriented error estimation and mesh refinement for optimal control problems with elliptic PDE constraints using the value of the reduced cost functional as quantity of interest. Error representation, hierarchical error estimators, and greedy-style error indicators are derived and compared to their counterparts when using the all-at-once cost functional as quantity of interest. Finally, the efficiency of the error estimator and generated meshes are demonstrated on numerical examples.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 29
    Publikationsdatum: 2016-06-09
    Beschreibung: The paper considers the time integration of frictionless dynamical contact problems between viscoelastic bodies in the frame of the Signorini condition. Among the numerical integrators, interest focuses on the contact-stabilized Newmark method recently suggested by Deuflhard et al., which is compared to the classical Newmark method and an improved energy dissipative version due to Kane et al. In the absence of contact, any such variant is equivalent to the Störmer-Verlet scheme, which is well-known to have consistency order 2. In the presence of contact, however, the classical approach to discretization errors would not show consistency at all because of the discontinuity at the contact. Surprisingly, the question of consistency in the constrained situation has not been solved yet. The present paper fills this gap by means of a novel proof technique using specific norms based on earlier perturbation results due to the authors. The corresponding estimation of the local discretization error requires the bounded total variation of the solution. The results have consequences for the construction of an adaptive timestep control, which will be worked out subsequently in a forthcoming paper.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 30
    facet.materialart.
    Unbekannt
    Publikationsdatum: 2020-08-05
    Beschreibung: The mathematical treatment of planning problems in public transit has made significant advances in the last decade. Among others, the classical problems of vehicle and crew scheduling can nowadays be solved on a routine basis using combinatorial optimization methods. This is not yet the case for problems that pertain to the design of public transit networks, and for the problems of operations control that address the implementation of a schedule in the presence of disturbances. The article gives a sketch of the state and important developments in these areas, and it addresses important challenges. The vision is that mathematical tools of computer aided scheduling (CAS) will soon play a similar role in the design and operation of public transport systems as CAD systems in manufacturing.
    Beschreibung: Die mathematische Behandlung von Planungsproblemen im öffentlichen Verkehr hat im letzten Jahrzehnt große Fortschritte gemacht. Klassische Probleme wie die Umlauf- und die Dienstplanung können heutzutage routinemäßig mit kombinatorischen Optimierungsmethoden gelöst werden. Die Behandlung von Problemen der Angebotsplanung und der Betriebssteuerung sind dagegen noch nicht ganz auf diesem Stand. Dieser Artikel gibt einen Überblick über den Stand der Forschung, über wichtige Entwicklungen und einige Herausforderungen in diesem Gebiet. Die Vision ist, dass mathematische Planungswerkzeuge im öffentlichen Verkehr (Computer Aided Scheduling, CAS) in Zukunft eine ähnliche Rolle spielen werden wie CAD-Systeme in der industriellen Fertigung.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 31
    Publikationsdatum: 2022-07-19
    Beschreibung: The reconstruction of geometric shapes plays an important role in many biomedical applications. One example is the patient-specific, computer-aided planning of complex interventions, which requires the generation of explicitly represented geometric models of anatomical structures from medical image data. Only solutions that require minimal interaction by medical personnel are likely to enter clinical routine. Another example is the planning of surgical corrections of deformities where the target shape is unknown. Surgeons are often forced to resort to subjective criteria. These applications still pose highly challenging reconstruction problems, which are addressed in this thesis. The fundamental hypothesis, pursued in this thesis, is that the problems can be solved by incorporating a-priori knowledge about shape and other application-specific characteristics. Here, we focus mainly on the aspect of geometric shape analysis. The basic idea is to capture the most essential variations of a certain class of geometric objects via statistical shape models, which model typical features contained in a given population, and restrict the outcome of a reconstruction algorithm (more or less) to the space spanned by such models. A fundamental prerequisite for performing statistical shape analysis on a set of different objects is the identification of corresponding points on their associated surfaces. This problem is particularly difficult to solve if the shapes stem from different individuals. The reason lies in the basic difficulty of defining suitable measures of similarity. In this thesis, we divide the correspondence problem into feature and non-feature matching. The feature part depends on the application, while the non-feature part can be characterized by a purely geometric description. We propose two different approaches. The first approach has proved useful in many applications. Yet, it suffers from some practical limitations and does not yield a measure of similarity. Our second, variational, approach is designed to overcome these limitations. In it, we propose to minimize an invariant stretching measure, constrained by previously computed features. An important property, which sets our method apart from previous work, is that it does not require the computation of a global surface parameterization.
    Schlagwort(e): ddc:510
    Sprache: Englisch
    Materialart: doctoralthesis , doc-type:doctoralThesis
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 32
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 155-156 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 33
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 18-24 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Effects of pore diffusion in the catalytic oxidation of ethylene on copper oxide-alumina have been studied by varying the catalyst size and maintaining constant the ratio of the tube to the pellet diameter. Hydrocarbon analysis was determined with a flame ionization detector; infrared analyzers were used to determine carbon monoxide and carbon dioxide concentrations. Other reaction products were analyzed with a gas chromatograph. Curvature of the Arrhenius plots and increase in reaction order with temperature indicated a transition region between kinetic control at lower temperatures and pore diffusion control at higher temperatures. A calculation procedure which was developed to predict the conversion considering pore diffusion effects provided satisfactorily agreement between calculated and experimental results.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 34
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 35-39 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The rate of attrition of a catalyst sample, of a single particle size, can be expressed by a simple function of initial diameter and time. The initial rate is a function of initial diameter, whereas the decrease in attrition rate of a catalyst of a given size as it ages depends only on time.The attrition equation for a single size of particles is introduced into the particle size distribution function and, through mathematical analyses, yields a relationship for the attrition of a full size-range catalyst. The form of this relationship, which includes terms for attritability and severity of attrition conditions, is verified by laboratory and commercial attrition data on two full-range catalysts. The size distribution of an attrited sample is not expressible in simple analytical form, but is readily obtained by numerical analysis.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 35
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 94-100 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Process design computations are represented by directed graphs whose edges correspond to streams of information flow between computational units. Algorithm I-R extends existing algorithms for finding the minimal sized blocks of units between which no recycle exists. Algorithm II-R orders the sequence of unit computations within a block to minimize the number of recycle parameters. Algorithm III-R uses the concept of indexing to order computations which evade algorithm II-R. This work is directed toward the evolution of efficient programs for computer-aided process design.
    Zusätzliches Material: 17 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 36
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 64-73 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The permeation of carbon dioxide through polyethylene membranes has been studied at pressures up to 54.4 atm. and at temperatures above and below the critical temperature of the gas (31.0°C.). The permeability coefficient is independent of pressure at the highest experimental temperature (61.0°C.), but becomes increasingly pressure-dependent as the temperature is lowered. The principle of corresponding states can be used to correlate the solubility of both gases and vapors in polyethylene over a wide range of temperatures. This principle can also be invoked to obtain an upper limit for the penetrant pressure above which the permeability coefficient becomes pressure-dependent. The effect of pressure on the permeability, solubility, and diffusivity of gases and vapors in polyethylene is discussed in some detail.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 37
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 3-3 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 38
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 146-149 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 39
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 214-219 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Differently shaped bubbles were observed growing during nucleate boiling of water at atomspheric pressure. The surface temperature beneath the bubbles was measured simultaneously with a fast response surface thermocouple. The evaporation from the base necessary to account for the observed cooling was calculated. A comparison of the ratio of vapor volume formed at the base to the total volume of the bubble shows a dependency on bubble shape. The ratio is smallest for spherical bubbles, largest for hemispherical and intermediate for oblate bubbles.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 40
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Solubilities and diffusivities of various gases (helium, nitrogen, carbon dioxide, argon, neon, krypton, and monochlorodifluoromethane) in molten or thermally softened polymers (polyethylene, polypropylene, polyisobutylene, polystyrene, and polymethylmethacrylate) have been correlated with structural characteristics, temperature, and pressure. Temperature dependence of both Henry's Law constants and diffusivities were of the Arrhenius equation form. No appreciable effect of pressure was found for either Henry's Law constants or diffusivities up to 300 atm. Earlier correlations for Henry's Law constants in solid polymer systems were found to be inapplicable for molten and thermally softened polymers. New correlations were developed individually for the latter systems. The correlating factor used was the gas Lennard-Jones force constant. Existing correlations for diffusivities were also found not to apply to molten and thermally softened systems. New correlations were again developed on an individual polymer basis. These related diffusivity to gas Lennard-Jones collision diameter or molecular diameter. Generalized correlations were also developed that held for a number of polymers. These were for both Henry's Law constants and diffusivities.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 41
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 303-305 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 42
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969) 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 43
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 276-281 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: This paper describes a numerical procedure for optimizing a large set of interconnected systems with respect to a given index of performance. The method automatically constructs the vector differential equation of the complete system from (a) the vector differential equations describing the behavior of the components of the system and (b) the manner of their interconnection. A hill-climbing method is then used to select optimum values of the system's parameters to maximize a given index of performance. An example of the procedure applied to a high order system is included.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 44
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 442-449 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An absolute rate theory based on a plausible model of the activated state, was developed for the interfacial kinetics of crystal growth from the melt. Except for liquid metals the theory predicts the growth rates of pure materials within about an order of magnitude. A microinterferometric technique was employed to observe liquid compositions near the faces of crystals growing from binary melts. For the simple eutectic system composed of salol and thymol, the theory represents the composition and temperature dependence of the growth rate.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 45
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 308-311 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 46
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 327-333 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The laminar boundary layers on a moving continuous flat surface in non-Newtonian fluids characterized by the power law model are investigated using exact and approximate methods. Both pseudoplastic and dilatant fluids are considered. Numerical solutions of the boundary-layer equations are obtained for values of the parameter n in the power law model ranging from 0.1 to 2.0. An integral solution of the momentum equation, which can be used to obtain values of the dimensionless shearing stress that are in good agreement with the exact values, is developed. An integral solution to the energy equation is also presented.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 47
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 357-362 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Forced convection heat transfer from vertical cylinders normal to an air-water spray flow stream was measured over an air velocity range from 60 to 140 ft./sec. and a water spray density range from 0.03 to 0.50 lb.m/(min.) (sq. in.). Local heat transfer coefficients were determined at 15 deg. intervals around the circumference of both a 1.5 and a 1.0 in. diam. cylinder. It was found that the addition of 0.426 lb.m/(min.) (sq. in.) of water spray to a 133 ft./sec. air stream raised the stagnation point heat transfer coefficient from 45 to 1,650 B.t.u./(hr.) (sq. ft.) (°F.). Similar intensification was found for other angles around the cylinder circumference; however, the magnitude decreased with increasing distance from the stagnation point. Local heat transfer coefficients were normalized with respect to their corresponding stognation point values and plotted parametrically as a function of angle and air velocity. These profiles showed that the normalized heat transfer coefficients decreased with increasing air velocity at angles other than the stagnation point. Average cylinder heat transfer coefficients were calculated from the air-water data and two correlations were obtained relating these coefficients to the air and the water spray Reynolds number.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 48
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 387-392 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A study was made of the radiolytic oxidation of cyclohexane in aqueous solution by using cobalt 60 gamma radiation. In the presence of dissolved oxygen gas the reaction proceeds irreversibly with the formation of a number of oxidation products. Those identified were cyclohexanol, cyclohexanone, and hydrogen peroxide. Trace quantities of carbon dioxide were also detected in the liquid phase. Using a constant dose rate of 15 × 104 rad./hr. in all runs, radiation yields were G(C6H11OH) = 0.49, and G(C6H10O) = 1.08. When molecular oxygen was excluded from the system, neither cyclohexanol nor cyclohexanone was formed on irradiation. A simplified kinetic model based on competition by the various solutes in the system for a single primary radical species produced by radiolysis of the solvent molecules is developed. Results generated using the mathematical model are compared with the experimental data. Excellent agreement between the observed and computed trends is noted at radiation doses up to 50 × 104 rad.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 49
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 414-418 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The optimal unsteady control of a jacketed tubular reactor with and without heat generation due to chemical reaction in response to a step disturbance in the feed stream concentration is computed. More rigorous control action was found to be necessary for the case with heat generation than without heat generation. Convergence of the method was also investigated with fixed and free final time.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 50
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 434-441 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An analysis is performed of the strongly coupled heat and mass transfer processes which result from sublimation of mass from the walls of a duct into a flowing gas, the latent heat being provided solely by convective transfer from the gas. The flow is assumed to be laminar and hydrodynamically developed. Results are given for the streamward variations of the bulk and wall temperatures and mass fractions, of the heat and mass transfer rates, and of the local heat transfer coefficient. Representative temperature and mass fraction profiles are also presented. Entrance lengths characterizing the near approach to fully developed conditions are tabulated. Comparisons are made of the present results (based on a parabolic velocity profile) with those based on a slug flow velocity profile. A subsidiary analysis using the Lévěque model is also performed and the results compared with those of the principal solution.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 51
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 712-715 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The liquid that moves along the duct walls in the annular regime observed in gas-liquid flows often consists of a series of flow surges (roll waves) moving over a thin liquid film (base film). At a given gas velocity there is a critical flow rate of the liquid below which roll waves are not present. Measurements of the height and wall stress are presented to support the notion that the conditions in the base film are close to those which exist at the critical liquid flow rate.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 52
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 727-733 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Data are reported for heat transfer from water to melting ice spheres and for mass transfer in the case of dissolving spheres of pivalic acid suspended in water agitated in a stirred vessel. The transport coefficients are found to depend on agitator power input but not on agitator design, in agreement with the Kolmogoroff theory. These experimental results are used with others in the literature to develop a correlation involving Nusselt and Prandtl or Schmidt numbers together with a dimensionless group involving agitation power. The correlation is essentially independent of solid-liquid density ratio in the range 0.8 to 1.25, and in this range the gravity group also appears to be unimportant.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 53
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 592-596 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Heat transfer and pressure drop data were taken on commercial plate heat exchange equipment. Nusselt and Euler correlations were determined for each of the six commercial heat exchangers investigated. These correlations were combined to establish a single heat transfer-pressure drop relationship for any plate type of heat exchanger channel.The results of this investigation were tested by using the correlations developed in Part I of this series to predict pressure drop data for the commercial unit based on their channel geometries. These predicted pressure drops were then used with the results of this part of the series to predict and compare heat transfer data.The correlations developed in this work allow one to determine the heat transfer characteristics in a ribbed rectangular channel from the pressure drop characteristics of the channel in question.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 54
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 615-617 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 55
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 829-836 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A generalized approach to reverse osmosis process design is presented for solution-membrane-operating systems characterized by the dimensionless parameters γ, θ, and λ defined in terms of the pure water permeability constant A, solute transport parameter (DAM/Kδ), mass transfer coefficient k on the high pressure side of the membrane, and the properties of the solution. Analytical expressions are derived, in terms of dimensionless quantities, for the change of volume of solution, concentration of the bulk solution and that of the concentrated boundary solution on the high pressure side of the membrane, the change in the permeating velocity of solvent water through the membrane, solute separation, and the other related quantities, at any instance, as a function of concentration of the product solution on the atmospheric pressure side of the membrane, or time from the start of the operation for reverse osmosis systems specified by γ, θ, and λ. The equations are applicable to membranes for which (DAM/Kδ) is independent of solute concentration and feed flow rate, and for aqueous feed solutions whose molar density can be assumed constant and whose osmatic pressure is proportional to mole fraction. The equations are developed first for the case of batch-by-batch operation, and their applicability to the flow case is then indicated.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 56
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 861-865 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The final stages of condensation polymerization are characterized by a rapid rise in molecular weight, as the condensation product is formed and diffuses out of the polymer. The process occurring is one of desorption accompanied by a chemical reaction. The penetration theory equations for a generalized condensation polymerization reaction have been solved and some solutions are presented. The penetration theory solution, obtained by finite-difference computations, is compared with an analytical solution for the special case of no diffusional resistance.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 57
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 933-935 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: No Abstracts.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 58
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 815-822 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Equations were developed for evaluating the laminar flow behavior of high-solids suspensions from the physical properties of the liquid and solid components. A technique was developed for calculating suspension flow rates as a function of pressure drop. The technique is applicable to the design of pipe lines. Flow measurements were made in pipe-line viscometers of a unique design that minimized entrance and exit effects. Experimental flow data were obtained for suspensions consisting of nickel, alumina, copper, or glass solids in sodium, xylene, or glycerine vehicles with solids concentrations of 28 to 55 vol. %. The basis for the correlation of the data was an analytical investigation of the flow behavior that considered the particle-particle interaction that takes place in a settled suspension. The correlation equations fit all systems investigated. They take into account the effects of liquid viscosity, liquid and solid densities, particle size, size distribution, particle surface area, volume fraction of solids in the suspension, and volume fraction of solids at maximum settled conditions.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 59
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 853-860 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A realistic CSTR model was developed and verified experimentally. The reaction studied was the exothermic, base sodium hydroxide catalyzed decomposition of hydrogen peroxide. The model was used to evaluate the usefulness of the following stability analyses: steady state analysis, local linearization and Liapunov's direct method through Krasovskii's theorem. The effect of control valve hysteresis on the system was also investigated.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 60
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 866-872 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The local volume average of the equation of motion is taken for an incompressible fluid flowing through a porous structure under conditions such that inertial effects may be neglected. The result has two terms beyond a pressure gradient: g, the force per unit volume which a flowing fluid exerts on a porous structure, and the divergence of the local volume-averaged extra stress tensor (viscous portion of the stress tensor).Constitutive equations for g are examined with the aid of the principle of material indifference. When g is assumed to be a function of the velocity of the fluid relative to the solid as well as various scalars, the usual results for a nonoriented (isotropic) porous structure are obtained. When g is assumed to be a function of the local porosity gradient as well, we derive a new expression for g applicable to oriented (anisotropic) porous structures.For a Newtonian fluid with a constant viscosity, the divergence of the local volume-averaged extra stress tensor is proportional to the Laplacian of the averaged velocity vector. Boundary conditions for the averaged velocity vector are discussed. Three problems are solved for the flow of an incompressible Newtonian fluid in a nonoriented permeable medium. These solutions, as well as an order-of-magnitude analysis, suggest that we may often neglect both the Laplacian of average velocity and the boundary conditions for the tangential components of averaged velocity at an impermeable wall.Two specific constitutive equations for g are proposed for the flow of incompressible Noll simple fluids in nonoriented porous structures. Flow through a porous medium bounded by an impermeable cylindrical surface is solved for these two constitutive equations, and the results are compared with previously available experimental data.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 61
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 3-155 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 62
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 4-10 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A dye tracer technique was utilized to measure the residence time distribution of the drops in a spray column, operating with a dispersed or a dense packing of drops, for a wide range of flow rates, in a 15 cm.in diameter, 150 to 160 cm. long column proper.For dispersed packing of drops and for flow rates below the onset of coalescence, the flow of the drops was approximately plug flow, with a variance of the residence time distribution of 0.095. For flow rates above the onset of coalescence within the column, the variance increased sharply to 0.55 and decreased at higher flow rates.For dense packing of drops the variance of the residence time distribution was in the range of 0.1 to 0.5. This variance is attributed to the effect of bypassing water and kerosene near the wall of the column. A mathematical model based on this effect showed reasonable fit with the experimental results. This model predicts an approach to plug flow of the drops for large diameter columns.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 63
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 57-63 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A sensitivity matrix is defined as a measure of trajectory deviations to small parameter variations of both open and closed loop controlled nonlinear parabolic and first-order hyperbolic systems. In general the parameters may enter through the system equations or the boundary conditions and may be time or spatially dependent. The introduction of a positive measure of the sensitivity, the norm of the sensitivity matrix, into the performance index is shown to be effective in limiting the trajectory deviations due to the parameter variations. The open and closed loop control of a double pipe heat exchanger is analyzed with the open loop problem solved by an approximate procedure. The sensitivity reformulation is successful in reducing trajectory sensitivity, however at the cost of decreased overall performance.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 64
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 81-85 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Axial dispersion was studied experimentally for turbulent flow through a 1 1/4-in. piping system containing 90 deg. elbows. The Reynolds number range was 15,400 to 96,555. The imperfect pulse tracer technique was used with the axial dispersion numbers being obtained from the difference in variances of concentration-time curves observed at two points in the system.Elbows interconnected by short lengths of pipe with each succeeding one reversed so as to cause a change in the direction of flow, increased axial dispersion by 35 to 61% over that expected for straight pipe, while the same elbows turned so as to form a helix decreased the dispersion substantially; however, the amount of axial dispersion was still 8 to 22% greater than that observed for straight pipe.The equivalent lengths of the elbows depend upon both their arrangement and the Reynolds number. Closely placed, helically arranged elbows required equivalent lengths of from 2.9 to 5.1 diam., while a reversed arrangement required 6.9 to 11.6 diam. Elbows separated by a developing length and randomly arranged yielded an equivalent length range of 3.6 to 10.6 diam. The geometical l/d ratio of the elbows used was 2.05.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 65
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 100-105 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A region into which particles arrive in a random manner, remain a random amount of time, and then leave is considered. This model is used in penetration theories of heat and mass transfer. From observations of the number of particles present at any time, it is desired to estimate arrival and exit statistics, residence time statistics, and average rates of transfer across the region. Assuming arrival is a Poisson process, equations governing the above statistics are derived. Some problems in spectral analysis arising from the use of nondifferentiable stochastic processes are solved. Estimators for important parameters are discussed, and it is shown that generally they are biased. A derivation linking the rate of transfer across the region with the rates of transfer of particles is obtained and compared with other such results.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 66
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 126-127 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 67
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 116-123 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Differential equations were derived to describe the system characterized by a rapid, irreversible reaction of a fluid species in a flowing fluid with a fixed bed of solids in which the reaction rate was controlled by mass transfer of the reacting fluid from the bulk fluid to the reaction site in the solid. Two kinds of mass transfer resistances were assumed, external or film diffusion resistance, and internal pore diffusion resistance. The set of differential equations were solved by a finite-difference method for both the generalized case and for the specific case of reaction of hydrogen in a stream of helium with fixed beds of copper oxide pellets.The hydrogen-copper oxide reaction is one step in a proposed method for removal of hydrogen as a contaminant in the helium coolant of nuclear reactors. This reaction was experimentally investigated in tests with both differential and deep beds of copper oxide in the temperature range of 400 to 600°C., at pressures of 10.2 to 30.0 atm., with gas mass flow rates of 0.0050 to 0.050 g./sq.cm.-sec, and with inlet hydrogen concentrations of 0.0008 to 1.21 vol. %. These tests showed that the system could be described by the two rate-limiting steps: film and pore diffusion of hydrogen. Differential-bed tests were used to establish hydrogen transport properties within the porous copper oxide pellets, and tests with deep beds were used to establish external mass transport properties.Generalized breakthrough curves were determined by a computer solution of the mathematical model. These curves can be the basis for design of fixed-bed copper oxide oxidizers for gas-cooled, nuclear reactor purification systems and for design of any fixed-bed system which follows the assumed reaction mechanism.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 68
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 133-135 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 69
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 136-137 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 70
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 144-146 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 71
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969) 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 72
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 73
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 171-177 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Liapunov's direct method is used to establish a finite region of asymptotic stability for nonlinear systems with an arbitrary number of state variables. The procedure is a geometric one in multidimensional space which uses the Fletcher-Powell minimization technique to find the maximum time derivative of the Liapunov function on the closed Liapunov hypersurface. Three detailed examples are presented, the first being the classical 2-variable CSTR with heat transfer and the third being a 32-variable 16-stage model of an adiabatic tubular reactor with axial diffusion.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 74
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 194-199 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A shell progressive kinetic model is used to determine the temperature rise in a spherical pellet for a gas-solid diffusion controlled reaction. The effects of heat and mass transfer resistances in the gas film as well as inside the pellet are investigated. The predicted temperature rise may be severe enough to cause sintering to catalyst pellets in which reactions such as combustion of coke occur.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 75
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 220-226 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 76
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 208-214 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experiments have been carried out to measure the permeation of tritium-labeled toluene through polyethylene films fully swollen with chlorobenzene, mesitylene, cumene, toluene, ethylbenzene, cyclohexane, tetrahydronaphthalene, and decahydronaphthalene. The results show characteristic Arrhenius temperature dependence over the range 25 to 40°C. The permeation of toluene through the films appears to be enhanced by increased solubility of the swelling agent (estimated from the work of others) in the film and there also appears to be a rough correlation between permeability of toluene and the boiling points and vapor pressures of the swelling agents. The range of permeabilities measured at 25°C. is 2.09 × 10-7 to 0.51 × 10-7 sq.cm./sec., the extremes of measured permeation activation energy, Ep, are 11.41 to 16.68 kcal./mole, and the pre-exponential factor, Po, falls within the interval 36.59 to 1.29 × 105 sq.cm./sec. A very definite linear relationship or compensation effect is evident between Po and Ep. Except as mentioned above, none of these quantities appears to correlate uniformly with the following properties of swelling solvent: molecular weight, dipole moment, specific gravity, vapor pressure, boiling point, heat of vaporization, critical temperature, viscosity, surface tension, molar volume, molecular area or other molecular dimensions.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 77
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 245-249 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Oxidation-reduction rates have been determined in stirred liquid-liquid systems wherein tetravalent cerium ions in a continuous aqueous phase were reduced by tetrachlorohydroquinone contained in dispersed organic droplets. Kinetic data obtained (using low volume fractions (〈0.06) of dispersed organic phase) indicate that the rate of reduction of ceric cerium is proportional to the extent of the interfacial area of the stirred liquid-liquid system. Two possible rate-limiting mechanisms are discussed to explain the observed kinetic behavior.This liquid-liquid electron exchange system might find potential use as a chemical tool for measuring changes in interfacial area as influenced by various mixing parameters.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 78
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 256-263 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Pressure-temperature data were obtained along isenthalps for nitrogen, methane, and three ternary nitrogen-methane-ethane mixtures. These data were differentiated to obtain Joule-Thomson coefficients over the temperature range from ambient to 200°K. and at pressures from 165 atm. to about 5 atm. Data for nitrogen was obtained down to 140°K.The resulting Joule-Thomson coefficients were compared with predictions based on the Beattie-Bridgeman and Benedict-Webb-Rubin equations of state and on the virial equation of state truncated after the third virial coefficient. These comparisons show that the Benedict-Webb-Rubin equation could predict the data with a deviation averaging 1.7%. The Beattie-Bridgeman predictions were highly dependent upon the mixture rules used, with the best set of mixture rules giving an absolute average deviation of 4.8%. Predictions using the virial equation with virial constants obtained from the Lennard-Jones potential energy function using a geometric mean minimum potential energy deviated from the experimental data by 5%.In all of these comparisons, the virial coefficients of ethane appear to be in greatest uncertainty, and the predictions of mixture data high in ethane least satisfactory. Thus it appears that improved data on the pure components, particularly ethane, are vital to any satisfactory evaluation of mixture properties.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 79
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 281-288 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The effects of ultrasonic vibrations on heat transfer to water and methanol by natural convection and by boiling were measured at three ultrasonic energy levels with frequency ranging from 20.6 to 306 kcycles/sec., using electrically heated platinum wires of diameters 0.007 and 0.010 in. Up to an eight-fold increase in heat transfer coefficient was obtained in natural convection, but the effects diminished with increased temperature difference and became negligible in the well-developed nucleate boiling region. High-speed photographs showed that the increase was due to the motion of cavitation bubbles on the wire surface. The heat transfer results were correlated by local cavitation activity values measured by a technique developed for this work.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 80
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 301-303 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 81
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 475-476 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 82
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 323-327 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A laser doppler flowmeter is used to obtain velocity profiles in circular glass tubes downstream from a plug composed of brass screens. The apparatus for measuring point velocities of particles suspended in a fluid is described. Measurements were made very close to the plug at Reynolds numbers of 16.5, 47, and 274, and the flow development followed down the tube. The results show that the entrance flow development is dependent on the inlet profile shape and the Reynolds number for Reynolds numbers below 300.The flow development at Reynolds numbers less than 300 was considerably slower than that predicted by the boundary-layer solution of the equations of motion starting with a flat profile.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 83
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 339-350 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: When a porous solid is penetrated by a reactive fluid which changes the pore geometry, the macroscopic properties of that porous material may be greatly changed. A model is proposed in which the matrix is visualized as being a number of short cylindrical pores dispersed randomly throughout the solid. The change in the distribution of these cylindrical pores is then represented by a integrodifferential equation which is solved for two special cases.The evolution of the pore size distribution is determined by the particular way in which the solid-liquid boundary takes place. The case considered here is that of a surface reaction which dissolves the solid thus continuously enlarging the pores. The rate of reaction is calculated theoretically using a laminar flow diffusion model and this growth rate expression is then taken as the basis for numerical calculations relating to the action of dilute hydrochloric acid on limestone.A comparison is made with experimental results and it is found that the model behaves in much the same way as the real system although the observed rate of pore growth was two to three times that predicted by the diffusion model. Several possible explanations for this discrepancy are being tested.An exact solution of the integrodifferential equation for highly retarded reaction rates has been found with the change in permeability being given in terms of the change in porosity. This result will permit a prediction of the stimulation that can be achieved in acidizing oil wells with retarded acids.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 84
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 379-383 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The stability of high speed laminar Newtonian jets is studied as a function of ambient air pressure. For Weber numbers less than 5.3 (based on air density) air pressure has no effect on stability. Ambient viscosity, through the effect of shear stresses acting on the jet surface, gives rise to the maximum in the breakup curve. For large Weber numbers ambient pressure effects can alter, and eventually control, the appearance of the maximum.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 85
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 393-400 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The gradient technique and Lagrange multiplier are used to obtain the optimum of complex chemical plants. The advantage of this approach is its ability to handle nearly all types of complex stages in a natural way. This approach is used to solve a heterogeneous complex chemical process with recycle. It is shown that although there are many different iteration loops, the convergence rate is fast even with rough starting values and only 0.3 minute is needed to obtain the optimum operating conditions.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 86
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 410-414 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The necessary conditions for optimization of a system governed by a nonlinear vector first-order partial differential equation with two (space and time) independent variables, such as governs the unsteady behavior of tubular flow reactors, are derived. Rather general objective functionals and boundary conditions, such as the recycle of unconverted reactant with an appropriate time delay for separation and a free choice of final time, are allowed. A gradient technique in control space is formulated, and it is shown that distinct computational advantages can accrue from the use of the method of characteristics.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 87
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 426-434 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An analysis based on the Townsend-Bakewell model of the eddies in the wall regions of turbulent shear flows shows that viscoelastic fluid properties must lead to significant reductions in the rate of production of turbulent energy. This analysis in turn leads to the proper form of the similarity laws for drag reducing fluids, heretofore deduced empirically.Measurements of the axial and radial turbulence intensities for flow through smooth round tubes are reported, as are measurements of the time-averaged velocity profiles and the drag coefficients. These indicate that for solutions exhibiting drag reduction at all Reynolds numbers the flow may be transitional to Reynolds numbers of the order of 105. This transitional flow consists of alternating patches of laminar and turbulent fluid, within each of which the flow characteristics are approximately similar to those of Newtonian fluids. At high Reynolds number conditions with the turbulent field fully developed the velocity profile in the core is flatter under drag-reducing conditions than for turbulent Newtonian fluids, a change dependent on the increased isotropy of the turbulent field of the drag-reducing fluid. These effects appear to be a result of increases in the time scales of the radial fluctuations caused by the fluid properties.Design calculations based upon the present results suggest that in large diameter pipelines, or in boundary layers on large objects, drag reduction may not be attainable under conditions of practical interest until fluids having relaxation times an order of magnitude larger than those presently available, but with comparable viscosity levels, are developed or, alternately, until fluids exhibiting Weissenberg numbers which do not change with deformation rate, can be found.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 88
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 460-460 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 89
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 482-636 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 90
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 483-489 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: This study concerns rates of evaporation and mass transfer of water vapor from a heated salt solution through a water repellent porous membrane to a cooled water condensate. This transfer is a result of temperature differences and corresponding vapor pressure differences across the membrane. Three groups of experiments were carried out which indicate that the major factor influencing the rates of transfer is diffusion through a stagnant gas in the membrane pores. However, an equation considering film heat transfer coefficients, membrane thermal conductivity, and an empiricial correction based on temperature driving force appears to be necessary for representing all the data. The empirical correction appears to be related to internal condensation and possibly diffusion along surfaces.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 91
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 515-520 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental results for the adsorption of the binary gas mixtures oxygen-nitrogen, oxygen-carbon monoxide and nitrogen-carbon monoxide on two synthetic zeolites are reported. In all of these experiments the temperature was -200°F. and the total pressure was 1 atm. Also reported are the isotherms for the three pure gases on the two zeolites at -200°F. The results indicate that these zeolites have a surface selectivity which is independent of any sieving effect based on the size of the adsorbed molecules. It does not appear that the strong separations obtained can be explained in terms of the van der Waals forces which are generally believed to be dominant in physical adsorption. The available methods of predicting binary adsorption data from the pure gas isotherms have been examined.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 92
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 533-547 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The effects of a trace quantity of a surface-active agent on creeping flow past a bubble or droplet are investigated. The equations describing mass and momentum transfer are simultaneously solved by a perturbation technique, consistent with the jump mass and momentum balances at the phase interface. The stream function for the velocity distribution is evaluated as an infinite series of spherical harmonics. Galerkin's method, which reduces the partial differential equation of continuity to a set of ordinary differential equations, is used to evaluate the concentration distribution of surfactant.A sample calculation is carried out for relative motion between an air bubble and an infinite body of water which contains a trace of isoamyl alcohol. The relative velocity of the water at an infinite distance from the bubble is found to be highly sensitive to small changes in surfactant concentration from zero, although the bubble varies imperceptibly from a spherical shape.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 93
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 560-564 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Partial removal of dissolved or absorbed solvent from polymers can be accomplished during the process of screw extrusion. This paper shows how two simple transport models based either on an effective diffusivity or on an empirical mass transfer coefficient can be combined with the fluid mechanical equations which describe polymer flow during screw extrusion. In this way, the drying of solvent from a polymer during extrusion can be correlated in terms of the design and operating parameters of the extruder screw and a mass-transfer coefficient or an effective diffusivity. This approach is illustrated employing data obtained by using two extruders of different size and two different solvent-polymer systems. Furthermore, it is pointed out how the results can be used to predict the extent of drying during screw extrusion as well as how modifications in extruder-screw design can permit more extensive drying of polymers during the extrusion process.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 94
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 585-592 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Plexiglas models of rectangular channels were fabricated with various rib shapes to determine the effects of rib and channel geometry on the pressure drop. Pressure drops in twenty-four individual variations of channel geometry were investigated using plexiglas models.From this investigation, an empirical correlation for the pressure drop across the ribbed section of the channel was determined as a function of the linear fluid velocity and the geometric characteristics of the channels. This empirical correlation involves functions of seven geometric parameters of rib pattern and channel geometry.Ribbed section pressure drops for commercial plate heat exchanger channels were predicted using the geometric characteristics of the commercial plates with the empirical correlations developed from the plexiglas channel studies. The total pressure drop for commercial channels was predicted by adding an average entrance and exit pressure drop to the predicted ribbed section pressure drop.The correlations developed in this work allow one to determine the pressure drop in a ribbed rectangular channel from the geometric characteristics of the ribs and the channel in question.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 95
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 612-614 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 96
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 624-624 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 97
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 631-634 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 98
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 643-653 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Shear stress and first normal stress difference data are presented for several polymer solutions undergoing steady shear rates from 1.0 to 100,000 sec.-1. The steady shear response is divided into three regions as a function of increasing shear rate. These are the diffusion controlled linear region, a moderate shear rate region where shear controls the entanglement-disentanglement process, and a high shear rate region where aggregation of polymer molecules occurs. The transitions between the three regions are clearly illustrated by using a group designated as the rotation rate function.A molecular model is derived for the shear controlled region that allows prediction of the first normal stress difference from the viscosity function and one additional constant that depends only on the molecular species. The White-Metzner equation is found to adequately describe the aggregation region at high shear rates.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 99
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 670-679 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Steady state multiplicity in an adiabatic loop reactor was studied in experiments employing the reaction between sodium thiosulfate and hydrogen peroxide in aqueous solution. The steady state characteristics of the loop reactor were predicted by a method which utilized batch reactor data of temperature vs. time directly. The method was based on the assumption of plug flow with negligible axial dispersion and on a single-step chemical kinetic model. Experimental results verify the existence of multiple steady states on ranges of feed flow rates and recycle ratios and demonstrate the capability of the simple model for predicting the qualitative and quantitative features of the reactor steady state.Some observations were made of the effect of large disturbances on the stability of the reactor while operating in a multiple state region. Results for such cases illustrate reactor instability in the sense that a transition to a new steady state takes place provided the disturbance is sufficiently large.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 100
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 707-711 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Red blood cell damage and destruction are important problems in the use of artificial valves, heart-lung machines, and other devices which pump or process blood. An experimental study has been made on the mechanism of cell damage. Damage was defined by three types of observations on blood which had been subjected to trauma: (a) release of hemoglobin from cells (hemolysis), (b) morphological changes observed microscopically, and (c) red cell life span studies in rabbits using a Cr51 tagging technique.Three types of physical forces which might be injurious to red cells were studied; shearing stress (of known, constant magnitudes from a concentric cylinder viscometer), pressure variations (from studies in a static pressure cell), and direct impact of solid surfaces (from studies in a device which simulates the seating action of artificial heart valves).The study shows that high shearing stress may be primarily responsible for mechanical cell damage under certain important circumstances. There is a critical shearing stress above which cell damage increases markedly. Much of the cell damage does not appear as an immediate release of hemoglobin. Many cells undergo morphological changes and exhibit shortened average life span in vivo. The morphological changes due to shearing stress are very similar to the changes observed in patients who have hemolytic anemia associated with artificial valves.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...