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  • 2000-2004  (43)
  • 1955-1959
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  • 1930-1934  (426)
  • 2001  (43)
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  • ddc:000  (43)
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  • 2000-2004  (43)
  • 1955-1959
  • 1950-1954  (433)
  • 1930-1934  (426)
Year
Keywords
Language
  • 1
    Publication Date: 2014-11-10
    Description: An edge of a perfect graph $G$ is critical if $G-e$ is imperfect. We would like to decide whether $G - e$ is still {\sl almost perfect} or already {\sl very imperfect}. Via relaxations of the stable set polytope of a graph, we define two superclasses of perfect graphs: rank-perfect and weakly rank-perfect graphs. Membership in those two classes indicates how far an imperfect graph is away from being perfect. We study the cases, when a critical edge is removed from the line graph of a bipartite graph or from the complement of such a graph.
    Keywords: ddc:000
    Language: English
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  • 2
    Publication Date: 2020-03-06
    Description: Collection of abstracts of the first SIAM-EMS conference Applied Mathematics in our Changing World'' in Berlin, September 2-6, 2001.
    Keywords: ddc:000
    Language: English
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  • 3
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    Publication Date: 2020-02-11
    Description: {\sc Zimpl} is a little language to translate the mathematical model of a problem into a linear or (mixed-)integer mathematical program expressed in {\tt lp} or {\tt mps} file format which can be read by a LP or MIP solver.
    Keywords: ddc:000
    Language: English
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  • 4
    Publication Date: 2014-02-26
    Description: Im ersten Teil des folgenden Aufsatzes werden allgemeine Überlegungen zur Entwicklung von Bibliotheken hin zu Informationsvermittlungsstellen für sowohl elektronische wie auch gedruckte Medien angestellt. Basierend auf den Ergebnissen der Evaluation digitaler Bibliotheken und Informationsportale in Deutschland wird ein erster Kriterienkatalog für ein Verbund-Informationsportal für den Kooperativen Bibliotheksverbund Berlin-Brandenburg entwickelt. Im Anhang befindet sich der Statusbericht über Informationsportale und digitale Bibliotheken in Deutschland. Dazu wurden sieben digitale Bibliotheken auf Verbundebene und 21 Bibliotheken nach Bundesländern evaluiert.
    Keywords: ddc:000
    Language: German
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  • 5
    Publication Date: 2020-11-13
    Description: Given a set of service requests (events), a set of guided servers (units), and a set of unguided service contractors (conts), the vehicle dispatching problem {\sl vdp} is the task to find an assignment of events to units and conts as well as tours for all units starting at their current positions and ending at their home positions (dispatch) such that the total cost of the dispatch is minimized. The cost of a dispatch is the sum of unit costs, cont costs, and event costs. Unit costs consist of driving costs, service costs and overtime costs; cont costs consist of a fixed cost per service; event costs consist of late costs linear in the late time, which occur whenever the service of the event starts later than its deadline. The program \textsf{ZIBDIP} based on dynamic column generation and set partitioning yields solutions on heavy-load real-world instances (215 events, 95 units) in less than a minute that are no worse than 1\% from optimum on state-of-the-art personal computers.
    Keywords: ddc:000
    Language: English
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  • 6
    Publication Date: 2021-02-01
    Description: Scenario tree models of stochastic programs arise naturally under standard nonanticipativity assumptions. We demonstrate how tree-sparse programs cover the general case, with \emph{arbitrary} information constraints. Detailed examples and intuitive interpretations illuminate the basic thoughts behind the abstract but elementary construction.
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    Language: English
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  • 7
    Publication Date: 2020-03-09
    Description: In this paper we present an algorithm that accelerates 3D texture-based volume rendering of large and sparse data sets. A hierarchical data structure (known as AMR tree) consisting of nested uniform grids is employed in order to efficiently encode regions of interest. The hierarchies resulting from this kind of space partitioning yield a good balance between the amount of volume to render and the number of texture bricks -- a prerequisite for fast rendering. Comparing our approach to an octree based algorithm we show that our algorithm increases rendering performance significantly for sparse data. A further advantage is that less parameter tuning is necessary.
    Keywords: ddc:000
    Language: English
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  • 8
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    Publication Date: 2019-10-24
    Keywords: ddc:000
    Language: German
    Type: annualzib , doc-type:report
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  • 9
    Publication Date: 2021-02-01
    Description: Mathematical optimization techniques are on their way to becoming a standard tool in chemical process engineering. While such approaches are usually based on deterministic models, uncertainties such as external disturbances play a significant role in many real-life applications. The present article gives an introduction to practical issues of process operation and to basic mathematical concepts required for the explicit treatment of uncertainties by stochastic optimization.
    Keywords: ddc:000
    Language: English
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  • 10
    Publication Date: 2014-02-26
    Description: Uncoupling-coupling Monte Carlo (UCMC) combines uncoupling techniques for finite Markov chains with Markov chain Monte Carlo methodology. UCMC aims at avoiding the typical metastable or trapping behavior of Monte Carlo techniques. From the viewpoint of Monte Carlo, a slowly converging long-time Markov chain is replaced by a limited number of rapidly mixing short-time ones. Therefore, the state space of the chain has to be hierarchically decomposed into its metastable conformations. This is done by means of combining the technique of conformation analysis as recently introduced by the authors, and appropriate annealing strategies. We present a detailed examination of the uncoupling-coupling procedure which uncovers its theoretical background, and illustrates the hierarchical algorithmic approach. Furthermore, application of the UCMC algorithm to the $n$-pentane molecule allows us to discuss the effect of its crucial steps in a typical molecular scenario.
    Keywords: ddc:000
    Language: English
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  • 11
    Publication Date: 2021-02-01
    Description: Standard model predictive control for real-time operation of industrial production processes may be inefficient in the presence of substantial uncertainties. To avoid overly conservative disturbance corrections while ensuring safe operation, random influences should be taken into account explicitly. We propose a multistage stochastic programming approach within the model predictive control framework and apply it to a distillation process with a feed tank buffering external sources. A preliminary comparison to a probabilistic constraints approach is given and first computational results for the distillation process are presented.
    Keywords: ddc:000
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  • 12
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    Publication Date: 2021-02-01
    Description: Dynamic stochastic programs are prototypical for optimization problems with an inherent tree structure inducing characteristic sparsity patterns in the KKT systems of interior methods. We propose an integrated modeling and solution approach for such tree-sparse programs. Three closely related natural formulations are theoretically analyzed from a control-theoretic viewpoint and compared to each other. Associated KKT solution algorithms with linear complexity are developed and comparisons to other interior approaches and related problem formulations are discussed.
    Keywords: ddc:000
    Language: English
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  • 13
    Publication Date: 2020-11-13
    Description: We introduce a new problem that was motivated by a (more complicated) problem arising in a robotized assembly enviroment. The bin coloring problem is to pack unit size colored items into bins, such that the maximum number of different colors per bin is minimized. Each bin has size~$B\in\mathbb{N}$. The packing process is subject to the constraint that at any moment in time at most $q\in\mathbb{N}$ bins may be partially filled. Moreover, bins may only be closed if they are filled completely. An online algorithm must pack each item must be packed without knowledge of any future items. We investigate the existence of competitive online algorithms for the online uniform binpacking problem. We show upper bounds for the bin coloring problem. We prove an upper bound of $3q$ - 1 and a lower bound of $2q$ for the competitive ratio of a natural greedy-type algorithm, and show that surprisingly a trivial algorithm which uses only one open bin has a strictly better competitive ratio of $2q$ - 1. Morever, we show that any deterministic algorithm has a competitive ratio $\Omega (q)$ and that randomization does not improve this lower bound even when the adversary is oblivious.
    Keywords: ddc:000
    Language: English
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  • 14
    Publication Date: 2014-02-26
    Description: In circuit switching networks call streams are characterized by their mean and peakedness (two-moment method). The $GI/M/C/0$ system is used to model a single link, where the $GI$-stream is determined by fitting moments appropriately. For the moments of the overflow traffic of a $GI/M/C/0$ system there are efficient numerical algorithms available. However, for the moments of the freed carried traffic, defined as the moments of a virtual link of infinite capacity to which the process of calls accepted by the link (carried arrival process) is virtually directed and where the virtual calls get fresh exponential i.i.d.\ holding times, only complex numerical algorithms are available. This is the reason why the concept of the freed carried traffic is not used rigorously. The main result of this paper is an efficient algorithm for computing the moments of the freed carried traffic, in particular an explicit formula for its peakedness. This result offers a unified handling of both overflow and carried traffics in networks. Furthermore, some refined characteristics for the overflow and freed carried streams are derived.
    Keywords: ddc:000
    Language: English
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  • 15
    Publication Date: 2014-02-26
    Description: In this work we concentrate on developing methods which determine good lower bounds for set partitioning problems (SPP) in an appropriate amount of time. We found out that it makes sense to use the Lagrangian relaxation method for this task. The Lagrangian relaxed problem of SPP has a simple structure, which leads to algorithms and heuristics, whose total complexity per iteration depends linearly on the number of non-zeros of the problem matrix of SPP. In contrast, other methods like simplex methods or interior point methods have a complexity of higher order. Because the problem matrices of our tested instances are sparse, the linear dependence becomes an advantage for the algorithms and heuristics mentioned above. As a reference for the state-of-the-art we have applied the dual simplex method and the barrier function method, implemented in CPLEX. The methods, which we have developed and compared with those of CPLEX, are SBM, CAM, CCBM, and CBM. SBM is a subgradient bundle method derived from the basic subgradient method, which is a global convergent method for determining the maximum of concave functions. CAM is a coordinate ascent method, where the convex coordinate bundle method CCBM and the coordinate bundle method CBM are derivatives from CAM. We observed that the basic subgradient and the coordinate ascent method are improved if bundling techniques can be used. But the motivation for bundling differs for both approaches. In the former case bundling helps to approximate a minimum norm subgradient, which provides a steepest ascent direction, in order to speed up the performance. In the latter case bundling enables proceeding along directions, which are not restricted on the coordinate directions. By this the performance is accelerated. Among all used techniques stabilization is worth mentioning. Stabilization improves the performance especially at the beginning by avoiding too big steps during the proceeding. This leads to a more stabilized progression. Stabilization was successfully applied to SBM, CAM, CCBM, and CBM. As an overall result we conclude the following: \begin{enumerate} \item CPLEX computes the optimal objective values, whereas SBM and CBM has on average a gap of under $1.5\%$. \item In comparison to CPLEX baropt, SBM, CAM, and CBM the algorithm CCBM has a slow convergence because of the convex combination of ascent coordinate directions. An alternative is to relax the convex combination to a simple sum of the corresponding directions. This idea is realized in CBM. \item If we focus on the running time rather than on optimality then CBM is on average the fastest algorithm. \end{enumerate} Note that methods like SBM or CBM are applied on static SPP instances in order to determine a good lower bound. For solving SPP we need dynamical methods. Due to the complex topic of dynamical methods we will not discuss them, but a certain technique is worth mentioning. It is called column generation. We have indicated that this technique needs good Lagrangian multipliers of the corresponding SPP instances in order to generate further columns (in our case duties), which are added to the current SPP instance. Those multipliers are by-products of methods like our six considered methods. Due to the large number of such generation steps the running time depends on the computation time of these methods. Therefore, CBM fits more to this technique than CPLEX baropt or SBM. To sum it up it can be said that applications such as a duty scheduling can be described as set partitioning problems, whose lower bound can be solved by simplex, interior points, subgradient, or coordinate ascent methods. It turns out that the interior points method CPLEX baropt and the heuristic CBM have good performances. Furthermore, good Lagrangian multipliers, which are by-products of these methods, can be used by techniques like column generation. For this particular technique it also turns out that among our tested algorithms CBM is the most efficient one. In general we can state that real-world applications, which have to solve a large number of Lagrangian relaxed SPP instances can improve their performance by using CBM.
    Keywords: ddc:000
    Language: English
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  • 16
    Publication Date: 2014-02-26
    Description: The success of large-scale multi-national projects like the forthcoming analysis of the LHC particle collision data at CERN relies to a great extent on the ability to efficiently utilize computing a management software (Datagrid, Globus, etc.), while the effective integration of computing nodes has been largely neglected up to now. This is the focus of our work. We present a framework for a high-performance cluster that can be used as a reliable computing node in the Grid. We outline the cluster architecture, the management of distributed data and the seamless intergration of the cluster into the Grid environment.
    Keywords: ddc:000
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  • 17
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    Publication Date: 2020-11-13
    Description: Der Aufsatz ist die ausgearbeitete Fassung eines Vortrages, gehalten am 05.04.2001 auf dem 91. Deutschen Bibliothekartag in Bielefeld. Der Kooperative Bibliotheksverbund Berlin-Brandenburg (KOBV) ist im Rahmen eines wissenschaftlichen Projektes in den Jahren 1997 bis 2000 am Konrad-Zuse-Zentrum für Informationstechnik Berlin (ZIB) aufgebaut worden. Nachdem das Projekt erfolgreich abgeschlossen ist, wird der KOBV 2001 institutionalisiert. In dem Vortrag hat die Verfasserin einen Überblick über das bisher Erreichte, den derzeitigen Stand und die Perspektiven des neuen Verbundes gegeben. Der KOBV stellt eine neue Art von Bibliotheksverbund dar. Sein technisches Konzept und sein organisatorischer Aufbau basieren auf der {\sl Internetphilosophie}. Den informationstechnischen Kern bildet eine Suchmaschine, die die heterogenen lokalen Bibliothekssysteme miteinander verbindet. Die KOBV-Organisation ist dezentral. Sie wird getragen von der Kooperation der Bibliotheken in Berlin und Brandenburg. Eine kleine Verbundzentrale koordiniert dieses Geflecht vernetzter lokaler Einheiten, vertritt den KOBV nach außen und arbeitet - in Form von Projekten - an seiner Weiterentwicklung. Der Entwicklungsaspekt und die Nutzerorientierung sind zwei wesentliche Komponenten in der Verbundarbeit. Berlin und Brandenburg haben auf engem Raum zahlreiche Bibliotheken mit großen, reichhaltigen Medienbeständen. Mittel- bis langfristig sollen Bibliotheken aller Sparten und Größen in den KOBV integriert werden, seien es wissenschaftliche Universalbibliotheken, universitäre Bibliothekssysteme, Spezialbibliotheken, Behörden- und Parlamentsbibliotheken oder öffentliche Bibliotheken. Auch regionale Bibliotheksverbünde können als Subverbünde am KOBV teilnehmen. Mit der KOBV-Suchmaschine ist eine offene Plattform geschaffen worden, auf der weitere Entwicklungen aufsetzen können. Der Aufbau einer virtuellen Regionalbibliothek mit Bestell- und Lieferkomponenten ist eines der Ziele. Darüber hinaus ist es die Vision, in der Region ein virtuelles {\sl Wissensportal} aufzubauen, das dem Nutzer unter einer Adresse den umfassenden Zugang und die umfassende Bereitstellung von Informationen aller Art bietet.
    Keywords: ddc:000
    Language: German
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  • 18
    Publication Date: 2019-01-29
    Description: A new approach to the numerical solution of optimal control problems including control and state constraints is presented. Like hybrid methods, the approach aims at combining the advantages of direct and indirect methods. Unlike hybrid methods, however, our method is directly based on interior-point concepts in function space --- realized via an adaptive multilevel scheme applied to the complementarity formulation and numerical continuation along the central path. Existence of the central path and its continuation towards the solution point is analyzed in some theoretical detail. An adaptive stepsize control with respect to the duality gap parameter is worked out in the framework of affine invariant inexact Newton methods. Finally, the performance of a first version of our new type of algorithm is documented by the successful treatment of the well-known intricate windshear problem.
    Keywords: ddc:000
    Language: English
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  • 19
    Publication Date: 2014-02-26
    Description: Das \emph{Committee on Electronic Information and Communication} (CEIC) der \emph{International Mathematical Union} (IMU) hat die Aufgabe, sich über die langfristige Informationsversorgung in der Mathematik Gedanken zu machen und Lösungsvorschläge hierfür zu erarbeiten. Das Kernthema ist natürlich "`Elektronisches Publizieren"'. Dazu gehören auch Copyright-Regelungen. % Sie sind -- % neben einer Andeutung der weiteren CEIC-Pläne -- der Fokus dieses % kurzen Artikels. Er schließt mit einem von der IMU verabschiedeten % Aufruf zu vernünftigem Verhalten bei Copyright-Vereinbarungen. Eine % nachhaltige Befolgung dieses Aufrufs -- verbunden mit weiteren % Aktivitäten -- könnte die (derzeit kaum noch bezahlbare und % dadurch gefährdete) Literaturversorgung nachhaltig zum Positiven % verändern. Mit diesem Artikel beginnt eine kleine Serie von Aufsätzen, in denen ich (in meiner Funktion als eines von elf CEIC-Mitgliedern) die Empfehlungen des CEIC erläutern werde. % Das heutige Thema sind die % CEIC-Vorschläge zum Copyright
    Keywords: ddc:000
    Language: German
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  • 20
    Publication Date: 2019-05-10
    Description: By computed tomography data (CT), the individual geometry of the mandible is quite well reproduced, also the separation between cortical and trabecular bone. Using anatomical knowledge about the architecture and the functional potential of the masticatory muscles, realistic situations were approximated. The solution of the underlying partial differential equations describing linear elastic material behaviour is provided by an adaptive finite element method. Estimations of the discretization error, local grid refinement, and multilevel techniques guarantee the reliability and efficiency of the method.
    Keywords: ddc:000
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  • 21
    Publication Date: 2021-03-19
    Description: Optimization is the task of finding an optimum solution to a given problem. When the decision variables are discrete we speak of a combinatorial optimization problem. Such a problem is online when decisions have to be made before all data of the problem are known. And we speak of a real-time online problem when online decisions have to be computed within very tight time bounds. This paper surveys the are of combinatorial online and real-time optimization, it discusses, in particular, the concepts with which online and real-time algorithms can be analyzed.
    Keywords: ddc:000
    Language: English
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  • 22
    Publication Date: 2014-02-26
    Description: This paper describes a new simulation tool for the prediction of aerosol formation and behavior in gas--liquid contact devices such as absorbers, scrubbers, quench coolers, and condensers as well as multistage gas cleaning processes, respectively. Aerosol formation can impact severely the separation efficiency of gas cleaning processes. Aerosol or fog formation can arise by spontaneous condensation or desublimation in supersaturated gas phases. The rigorous description of the mass and energy transfer between the gas phase, the liquid phase, and the growing aerosol droplets leads to a system of partial differential and algebraic equations. For the solution of these systems we have developed the plant simulation tool AerCoDe. This program bases upon the linearly--implicit Euler discretisation, which in combination with extrapolation permits an adaptive step size and order control. Typical simulation results of a multistage industrial flue gas scrubbing process are presented. It is shown, that experimental data can be confirmed if the number concentration of condensation nuclei as an input parameter is roughly known.
    Keywords: ddc:000
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  • 23
    Publication Date: 2020-11-13
    Description: This paper discusses online optimization of real-world transportation systems. We concentrate on transportation problems arising in production and manufacturing processes, in particular in company internal logistics. We describe basic techniques to design online optimization algorithms for such systems, but our main focus is decision support for the planner: which online algorithm is the most appropriate one in a particular setting? We show by means of several examples that traditional methods for the evaluation of online algorithms often do not suffice to judge the strengths and weaknesses of online algorithms. We present modifications of well-known evaluation techniques and some new methods, and we argue that the selection of an online algorithm to be employed in practice should be based on a sound combination of several theoretical and practical evaluation criteria, including simulation.
    Keywords: ddc:000
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  • 24
    Publication Date: 2014-02-26
    Description: Wireless communication networks employ radio frequencies to establish communication links. The available radio spectrum is very limited. To meet today's radio communication demand, this resource has to be administered and reused carefully in order to control mutual interference. The reuse can be organized via separation in space, time, or frequency, for example. The problem, therefore, arises to distribute frequencies to links in a ``reasonable manner''. This is the basic form of the frequency assignment problem. What ``reasonable'' means, how to quantify this measure of quality, which technical side constraints to consider cannot be answered in general. The exact specification of this task and its mathematical model depend heavily on the particular application considered. In this paper we discuss this issue with respect to the GSM standard for mobile communication.
    Keywords: ddc:000
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  • 25
    Publication Date: 2014-02-26
    Description: This paper is a summary of the Round Table: ``The Impact of Mathematical Research on Industry and Vice Versa'' held at 3ecm in Barcelona on July 11, 2000. The round table started with contributions of the three panelists. Irene Fonseca, the panel chair, opened the discussion by stating six questions addressing the main issues of the round table topic. She presented the panel's answers to these questions, drawing on many examples from her own academic experience. In the following additional presentations, the other two panel members added further points of view based on their personal involvement with industry. The round table ended with a lively discussion with members from the audience. This written summary of the oral presentations follows the structure of the round table indicated above.
    Keywords: ddc:000
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  • 26
    Publication Date: 2020-03-09
    Description: This article is about \emph{adaptive column generation techniques} for the solution of duty scheduling problems in public transit. The current optimization status is exploited in an adaptive approach to guide the subroutines for duty generation, LP resolution, and schedule construction toward relevant parts of a large problem. Computational results for three European scenarios are reported.
    Keywords: ddc:000
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  • 27
    Publication Date: 2014-02-26
    Description: The recent spectral bundle method allows to compute, within reasonable time, approximate dual solutions of large scale semidefinite quadratic 0-1 programming relaxations. We show that it also generates a sequence of primal approximations that converge to a primal optimal solution. Separating with respect to these approximations gives rise to a cutting plane algorithm that converges to the optimal solution under reasonable assumptions on the separation oracle and the feasible set. We have implemented a practical variant of the cutting plane algorithm for improving semidefinite relaxations of constrained quadratic 0-1 programming problems by odd-cycle inequalities. We also consider separating odd-cycle inequalities with respect to a larger support than given by the cost matrix and present a heuristic for selecting this support. Our preliminary computational results for max-cut instances on toroidal grid graphs and balanced bisection instances indicate that warm start is highly efficient and that enlarging the support may sometimes improve the quality of relaxations considerably.
    Keywords: ddc:000
    Language: English
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  • 28
    Publication Date: 2014-02-26
    Description: Der Wissenschaftsrat hat in seiner Juli-Sitzung 2001 \glqq Empfehlungen zur digitalen Informationsversorgung durch Hochschulbibliotheken \grqq verabschiedet. Einige der Vorschläge des Wissenschaftsrates können, falls sie von den angesprochenen Institutionen aufgenommen werden, zu einer nachhaltigen Veränderung der wissenschaftlichen Informationslandschaft führen. In meinem kurzen Kommentar zu diesem Papier möchte ich auf einige dieser Anregungen hinweisen.
    Keywords: ddc:000
    Language: German
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  • 29
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    Publication Date: 2014-02-26
    Description: Von welcher "Informationsumwelt" träumt jemand, der für seine wissenschaftliche (und sonstige) Arbeit digitale Informationstechnologie intensiv einsetzt? In diesem Artikel beschreibe ich meinen "digitalen Traum". Er ist ganz einfach zu formulieren:"Ich will alles und zwar sofort, jederzeit, "überall" und kostenlos zur Verfügung haben." Ich schildere, was davon heute schon (fast) realisiert ist und was noch fehlt. Ich skizziere einige zentrale Schwierigkeiten der vollständigen Realisierung und skizziere mögliche Lösungen.
    Keywords: ddc:000
    Language: German
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  • 30
    Publication Date: 2019-01-24
    Description: Im Rahmen der biomechanischen Simulation knöcherner Organe ist die Frage nach einer befriedigenden Materialbeschreibung nach wie vor ungelöst. Computertomographische Datensätze liefern eine räumliche Verteilung der (Röntgen-)Dichte und ermöglichen damit eine gute Darstellung der individuellen Geometrie. Weiter können die verschiedenen Materialbestandteile des Knochens, Spongiosa und Kortikalis, voneinander getrennt werden. Aber die richtungsabängige Information der Materialanisotropie ist verloren. In dieser Arbeit wird ein Ansatz für eine anisotrope Materialbeschreibung vorgestellt, die es ermöglicht, den Einfluss der individuellen knöchernen Struktur auf das makroskopische Materialverhalten abzuschätzen.
    Keywords: ddc:000
    Language: German
    Type: reportzib , doc-type:preprint
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  • 31
    Publication Date: 2020-03-09
    Description: Many phenomena in nature and engineering happen simultaneously on rather diverse spatial and temporal scales, i.e.\ exhibit a multi-scale character. Therefore various hierarchical data structures and numerical schemes have been devised to represent quantitatively such phenomena. A special numerical multilevel technique, associated with a particular hierarchical data structure, is so-called Adaptive Mesh Refinement (AMR). This scheme achieves locally very high spatial and temporal resolutions. Due to its popularity, many scientists are in need of interactive visualization tools for AMR data. In this article we present a 3D texture-based volume rendering algorithm for AMR data, that directly utilizes the hierarchical structure. Thereby interactive rendering even for large data sets is achieved. In particular the problems of interpolation artifacts, opacity corrections, and texture memory limitations are addressed. The algorithm's value in practice is demonstrated with simulation and image data.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 32
    Publication Date: 2020-03-09
    Description: By combining techniques of preparation, histology, confocal microscopy, data visualization and data processing, we have created and recently published a standard brain model for drosophila and honey bee brains. This report describes the algorithms and implementation of the corresponding software modules. At the same time it serves as a user's guide for scientist who want to reproduce the results for differerent species or mutants.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 33
    Publication Date: 2014-02-26
    Description: Several classes of systems of evolution equations with one or two vector unknowns are considered. We investigate also systems with one vector and one scalar unknown. For these classes all equations having the simplest higher symmetry are listed.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 34
    Publication Date: 2014-02-26
    Description: Two traffic streams $\Phi_1$, $\Phi_2$ are offered a link. The calls of $\Phi_i$ require exponential holding times with parameter $\mu$ and are accepted if less than $C_i$ trunks are occupied. Approximating the $\Phi_i$ by appropriate renewal processes meeting their first two moments, defined as the moments of the numbers of calls in virtual links of infinite capacity to which the traffic streams as freed traffics are virtually directed and where the calls get fresh exponential i.i.d.\ holding times with parameter $\mu$, stable recursive algorithms of complexity $O(\max(C_1,C_2))$ are derived for the first two defined as above moments of the individual overflow and freed carried traffics. The results offer a unified handling of both overflow and carried traffics in circuit switching networks with trunk reservation, providing a basis for new two-moment network dimensioning algorithms.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 35
    Publication Date: 2014-02-26
    Description: We study the performance of QCD simulations with dynamical Wilson fermions by combining the Hybrid Monte Carlo algorithm with parallel tempering on $10^4$ and $12^4$ lattices. In order to compare tempered with standard simulations, covariance matrices between sub-ensembles have to be formulated and evaluated using the general properties of autocorrelations of the parallel tempering algorithm. We find that rendering the hopping parameter $\kappa$ dynamical does not lead to an essential improvement. We point out possible reasons for this observation and discuss more suitable ways of applying parallel tempering to QCD.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 36
    Publication Date: 2020-11-13
    Description: Dem vorliegenden Aufsatz liegt ein Vortrag zugrunde, den die Verfasserin auf der Ersten Gemeinsamen Fachtagung der DBV-Landesverbände Berlin und Brandenburg "Wir machen den Weg frei : Fusionen - Kooperationen in Berlin und Brandenburg" am 17. Oktober 2001 gehalten hat, in der Vortragsreihe "Möglichkeiten und Grenzen von Ausleih- und bibliographischen Verbünden - VÖB Berlin, VÖB Brandenburg, KOBV". Der Kooperative Bibliotheksverbund Berlin-Brandenburg (KOBV) ist angetreten, um auf der Basis neuer Technologien zeitgemäße, nutzerorientierte Dienstleistungen für den Informationsbereich zu entwickeln und die Informationsinfrastruktur in der Region Berlin-Brandenburg neu zu organisieren. Dabei setzt der KOBV insbesondere auf das Internet. Die Verfasserin beschreibt die einzelnen Stufen, in denen die Dienste des KOBV aufgebaut wurden und kontinuierlich weiter ausgebaut werden. Dabei zeigt sie Vorteile auf, die Nutzern und Bibliotheken durch den Verbund entstehen, und lotet gleichzeitig die Grenzen aus, die dem Verbund gesetzt sind.
    Keywords: ddc:000
    Language: German
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  • 37
    Publication Date: 2014-02-26
    Description: We report numerical results for SBmethod --- a publically available implementation of the spectral bundle method --- applied to the 7$^{th}$ DIMACS challenge test sets that are semidefinite relaxations of combinatorial optimization problems. The performance of the code is heavily influenced by parameters that control bundle update and eigenvalue computation. Unfortunately, no mathematically sound guidelines for setting them are known. Based on our experience with SBmethod, we propose heuristics for dynamically updating the parameters as well as a heuristc for improving the starting point. These are now the default settings of SBmethod Version 1.1. We compare their performance on the DIMACS instances to our previous best choices for Version 1.0. SBmethod Version 1.1 is also part of the independent DIMACS benchmark by H.~Mittelmann. Based on these results we try to analyze strengths and weaknesses of our approach in comparison to other codes for large scale semidefinite programming.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 38
    Publication Date: 2014-11-10
    Description: Many {\cal NP}-hard graph problems can be solved in polynomial time for graphs with bounded treewidth. Equivalent results are known for pathwidth and branchwidth. In recent years, several studies have shown that this result is not only of theoretical interest but can successfully be applied to find (almost) optimal solutions or lower bounds for diverse optimization problems. To apply a tree decomposition approach, the treewidth of the graph has to be determined, independently of the application at hand. Although for fixed $k$, linear time algorithms exist to solve the decision problem ``treewidth $\leq k$'', their practical use is very limited. The computational tractability of treewidth has been rarely studied so far. In this paper, we compare four heuristics and two lower bounds for instances from applications such as the frequency assignment problem and the vertex coloring problem. Three of the heuristics are based on well-known algorithms to recognize triangulated graphs. The fourth heuristic recursively improves a tree decomposition by the computation of minimal separating vertex sets in subgraphs. Lower bounds can be computed from maximal cliques and the minimum degree of induced subgraphs. A computational analysis shows that the treewidth of several graphs can be identified by these methods. For other graphs, however, more sophisticated techniques are necessary.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 39
    Publication Date: 2014-02-26
    Description: The currently most efficient algorithm for inference with a probabilistic network builds upon a triangulation of a network's graph. In this paper, we show that pre-processing can help in finding good triangulations for probabilistic networks, that is, triangulations with a minimal maximum clique size. We provide a set of rules for stepwise reducing a graph, without losing optimality. This reduction allows us to solve the triangulation problem on a smaller graph. From the smaller graph's triangulation, a triangulation of the original graph is obtained by reversing the reduction steps. Our experimental results show that the graphs of some well-known real-life probabilistic networks can be triangulated optimally just by preprocessing; for other networks, huge reductions in their graph's size are obtained.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 40
    Publication Date: 2014-11-11
    Description: {\begin{rawhtml} 〈a href="http://dx.doi.org/10.1007/s10479-007-0178-0"〉 Revised Version unter http://dx.doi.org/10.1007/s10479-007-0178-0〈/a〉 \end{rawhtml}} Wireless communication is used in many different situations such as mobile telephony, radio and TV broadcasting, satellite communication, and military operations. In each of these situations a frequency assignment problem arises with application specific characteristics. Researchers have developed different modelling ideas for each of the features of the problem, such as the handling of interference among radio signals, the availability of frequencies, and the optimization criterion. This survey gives an overview of the models and methods that the literature provides on the topic. We present a broad description of the practical settings in which frequency assignment is applied. We also present a classification of the different models and formulations described in the literature, such that the common features of the models are emphasized. The solution methods are divided in two parts. Optimization and lower bounding techniques on the one hand, and heuristic search techniques on the other hand. The literature is classified according to the used methods. Again, we emphasize the common features, used in the different papers. The quality of the solution methods is compared, whenever possible, on publicly available benchmark instances.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 41
    facet.materialart.
    Unknown
    Publication Date: 2014-02-26
    Description: Telota ist ein Kunstwort, das für alle Aktivitäten der Berlin-Brandenburgischen Akademie der Wissenschaften steht, die der Förderung von Forschung, Kommunikation und Präsentation durch elektronische Medien dienen. In diesem Artikel werden die Entstehung des Telota-Projektes geschildert und die Ziele diskutiert, die mit diesem Projekt erreicht werden sollen. Es geht darum, moderne Informationstechnik bewusst, geplant und nachhaltig für alle Belange der {\rm BBAW} einzusetzen. Informationstechnische Werkzeuge sollen für die wissenschaftliche Arbeit effizient genutzt werden; die Information nach innen und nach außen soll deutlich verbessert werden; eine bessere Kommunikationsinfrastuktur soll die Zusammenarbeit fördern.
    Keywords: ddc:000
    Language: German
    Type: reportzib , doc-type:preprint
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  • 42
    Publication Date: 2022-07-07
    Description: The pole condition is a general concept for the theoretical analysis and the numerical solution of a variety of wave propagation problems. It says that the Laplace transform of the physical solution in radial direction has no poles in the lower complex half-plane. In the present paper we show that for the Helmholtz equation with a radially symmetric potential the pole condition is equivalent to Sommerfeld's radiation condition. Moreover, a new representation formula based on the pole condition is derived and used to prove existence, uniqueness and asymptotic properties of solutions. This lays the foundations of a promising new algorithm to solve time-harmonic scattering problems numerically and provides a new approach for analyzing existing algorithms such as the Perfectly Matched Layer (PML) method and the Bayliss-Gunzburger-Turkel (BGT) algorithm.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 43
    Publication Date: 2022-07-07
    Description: In this paper we study the PML method for Helmholtz-type scattering problems with radially symmetric potential. The PML method consists in surrounding the computational domain by a \textbf{P}erfectly \textbf{M}atched sponge \textbf{L}ayer. We prove that the approximate solution obtained by the PML method converges exponentially fast to the true solution in the computational domain as the thickness of the sponge layer tends to infinity. This is a generalization of results by Lassas and Somersalo based on boundary integral eqaution techniques. Here we use techniques based on the pole condition instead. This makes it possible to treat problems without an explicitly known fundamental solution.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
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  • 44
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 6-17 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ausgehend vom α- und β-Mehtyl-D-galactosid-〈1,5〉 wurden jeweils auf zwei Wegen der α- und der β-Methyl-D-idomethylosid-〈1,5〉-3-methyläther bereitet. Das β-Derivat kristallisierte. Saure Hydrolyse der beiden Stoffe gab freien D-Idomethylose-3-methyläther als Sirup. Es liess sich ein krist. Osazon daraus gewinnen, womit alle vier theoretisch möglichen Osazone der Hexamethylose-3-methyläther der D-Reihe bekannt sind.
    Type of Medium: Electronic Resource
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  • 45
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 45-58 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Teilsynthese von 11-Epi-corticosteron und seinen Acetaten nach der Diazoketon-Methode, ausgehend vom 3β, 11α-Diacetoxyätiansäure-methylester wird beschrieben.
    Type of Medium: Electronic Resource
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  • 46
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 95-97 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Benzhydrazid schwächt die Wirkung von INH auf Tbc H37Rv deutlich ab. Zusatz von Cu‥ zu diesem System hebt diese Abschwächung wieder auf; darüber hinaus wird das nach dem 10. Tag mit INH allein zu beobachtende Wachstum stark zurückgedrängt. Ein ähnlicher Effekt ist auch durch Zusatz von Co‥ zu INH zu erreichen.
    Additional Material: 3 Tab.
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  • 47
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 97-103 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The use of cellulose as an adsorbent for the proteins of plasma in aqueous solution has been investigated.
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  • 48
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 1-6 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Herstellung von [3,3′-Dimethyl-diphenylen-(4,4′)]-bis-[N-(N′-phenyl)-formazyl-benzol],[3,3′-Dimethoxy-diphenylen-(4,4′)]-bis-[N-(N′-phenyl)-formazyl-benzol],[Diphenylen-(4,4′)]-bis-[N-(N′-phenyl)-formazyl-benzol], [Diphenyl-thioureyl-(4,4′)]-bis-[N(N′-phenyl)-formazyl-benzol], [Diphenyl-sulfoxydyl-(4,4′)]-bis-[N-(N′phenyl)-formazyl-benzol] und der entsprechenden Bis-tetrazoliumsalze beschrieben.
    Additional Material: 1 Ill.
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  • 49
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 35-41 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Abspaltung von 1 Mol Wasser aus Phenyl-osazonen und Phenyl-osotriazolen der Sorbose- und der Tagatose-Reihe führt zu-3, 6-Anhydro-Derivaten, deren Konstitution aufgeklärt werden konnte.
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  • 50
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Sarmutosid (I) und Musarosid (II) enthalten dasselbe Aglykon und unterscheiden sich nur im Zuckeranteil. Das Aglykon wird als Sarmutogenin (V) bezeichnet. Im Sarmutosid ist es β-glykosidisch mit D-Sarmentose (IV) verknüpft, im Musarosid analog mit D-Digitalose (VII).
    Additional Material: 2 Ill.
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  • 51
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 103-112 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Samen von Strophanthus caudatus (Burm. ex L.) Kurz gaben nach Einwirkung des wasserlöslichen Teils der darin enthaltenen Fermente ein Glykosidgemisch. Aus den äther- und chloroform löslichen Anteilen dieses Gemisches liess sich durch Adsorptionschromatographie als Hauptglykosid krist. Caudosid (0,246%) isolieren. Die Mutterlaugen gaben nach Trennung durch Verteilungschromatographie noch etwas krist. Divaricosid (0,031%). Neben diesen zwei Stoffen wurden noch kleine Mengen „Nebenprodukt H“ isoliert, das kein digitaloides Lacton darstellt, sowie Spuren „Kristallisat G“ und „Kristallisat J“. Die zwei letztgenannten Stoffe stellen wahrscheinlich digitaloide Lactone dar, doch ist ihre Reinheit unsicher.
    Additional Material: 8 Ill.
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  • 52
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 141-147 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Samen von Strophanthus mirabilis Gilg. wurden nach fermentativem Abbau Periplocymarin, Cymarin, Cymarol, Emi-cymarin und in sehr geringer Menge ein nicht identifizierter krist. Stoff vom Smp. 171-174° (Subst. A) isoliert. Im Chloroform-Alkohol-(2:1)-Extrakt wurden durch Papierchromatographie mindestens vier weitere Stoffe nachgewiesen.
    Additional Material: 5 Ill.
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  • 53
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 185-190 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: It is shown that LiAIH4 reduces cyclic imides, namely 3,3-disubstituted 2,5-dioxo-pyrrolidines and 2,6-dioxo-piperidines, primarily at the oxo-group not adjacent to the two substituents. Hydroxylactames are formed as the first reduction products. Similarly, the same oxygen atom is replaced by sulfur by reaction with P2S5. This behaviour is ascribed to steric hindrance.
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  • 54
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 216-221 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As an example of aminolysis of amides, the reaction between acetanilide and o-anisidine has been studied with special reference to the catalytic action of acids. In the case of a weak acid, the rate of aminolysis increases continuously as the concentration of the catalyzing acid is increased; on the other hand, in the case of a strong acid, the rate passes through a maximum value. A mechanism for aminolysis of amides, consistent with these facts, is suggested.
    Additional Material: 2 Ill.
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  • 55
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 225-233 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Kondensation von 2-Methyl-1,4-naphtohydrochinon mit synthetischem Isophytol wurde mittels Bortrifluoridätherat als Kondensationsmittel ein Vitamin K1 mit racemischer Seitenkette gewonnen. Dieses totalsynthetische racemische Vitamin K1 unterscheidet sich nur geringfügig vom Vitamin K1 mit optisch einheitlicher Phytylseitenkette. Die Verbindungen zeigen gleiche UV.- und IR.-Absorptionsspektren, und sie unterscheiden sich nicht im oxydativen Abbau. Sie besitzen am Vitamin-K-Mangelkücken und am Kaninchen mit Dicumarol-Hypoprothrombinämie die gleiche biologische Wirksamkeit.
    Additional Material: 3 Ill.
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  • 56
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 239-241 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden die in einem Dialysierschlauch erfolgenden Reaktionen 1. Verschiedener Komplexbildner mit Cu‥, 2. des Alanins mit verschiedenen Metallionen vergleichend durch Ermittlung der nach aussen diffundierenden Ionen untersucht.
    Additional Material: 3 Tab.
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  • 57
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 234-239 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird das Problem der Ähnlichkeit bei Komplexverbindungen erörtert und die aus Ni(CN)2 und β-(2-Thienyl)-äthylamin zu gewinnende Verbindung beschrieben.
    Additional Material: 2 Tab.
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  • 58
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 242-245 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A pressure-operated chromatographic device, fitted with a float valve which shuts off the pressure system when the reservoir of the eluant is empty, and a constant-volume automatic fraction collector are described.
    Additional Material: 6 Ill.
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  • 59
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 246-250 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: La phosphoglucomutase du muscle de lapin convertit l'acide α-galactose-1-phosphorique en une substance acidostable qui est vraisemblablement l'acide galactose-6-phosphorique.
    Additional Material: 4 Ill.
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  • 60
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 258-266 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Im Zusammenhang mit Untersuchungen über den sterischen Verlauf von Reaktionen an Steroid-epoxyden wurden die beiden Oxyde des Δ5-3 α-Oxy-cholestens („epi“-Cholesterin) hergestellt und ihre Konfiguration aufgeklärt.
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  • 61
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Oxydation von Δ7;22 β-Acetoxy-ergostadien (α-Dihydroergosterin-acetat (II)) mit Selendioxyd in Äther-Eisessig entsteht neben dem 8,14-ungesättigten-7 α-Oxy-Derivat Vb ein weiterer, isomerer Allylalkohol. Es konnten Anhaltspunkte dafür gewonnen werden, dass dieser Verbindung die Konstitution eines 7,8-ungesättigten 9-Oxy-ergostan-Derivates IV zukommt. Die beiden Oxydationsprodukte stellen Zwischenstufen bei der Dehydrierung von α-Dihydroergosterin-acetat (II) mit Selendioxyd zu Ergosterin B3 (III) und Ergosterin-D-acetat (I) dar.
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  • 62
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    Helvetica Chimica Acta 37 (1954), S. 266-271 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Zwei aliphatische Abbauprodukte des tricyclischen Sesquiterpens, Cedren, die α,α-Dimethyl-β-carboxy-adipinsäure (III) sowie die 2,2-Dimethyl-3-carboxy-6-keto-heptansäure (II) wurden synthetisiert; die racemische Verbindung II wurde in ihre optischen Antipoden gespalten.
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  • 63
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    Helvetica Chimica Acta 37 (1954), S. 271-281 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Konstitution einiger Azulen-carbonsäuren wurde durch ihre Überführung in die entsprechenden Isopropyl-azulene bestätigt.
    Additional Material: 7 Ill.
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  • 64
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dans le système quinaire Ca++—NH4+—H+—NO3-—PO4---—H2O, on peut obtenir des solutions qui sont simultanément saturées de phosphate monocalcique et d'un nitrate simple et double des ions Ca++ et NH4+. Nous avons déterminé la composition de solutions saturées à 25° de deux phases solides, soit de: .
    Additional Material: 11 Ill.
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  • 65
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nous décrivons un procédé d'interpolation permettant d'établir, dans le système quinaire Ca++—NH4+—H+—NO3-—PO4---—H2O, la composition de solutions simultanément saturées de phosphate monocalcique et d'un nitrate simple ou double des ions Ca++ et NH+. Cette méthode utilise le diagramme de solubilité du système quaternaire Ca++—NH4+—H+—NO3-—H2O et des diagrammes indiquant la solubilité du phosphate monocalcique dans des solutions aqueuses de Ca(NO3)2 + NH4NO3 + HNO3.
    Additional Material: 4 Ill.
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  • 66
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    Helvetica Chimica Acta 37 (1954), S. 314-320 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Isolierung von zwei neuen Alkaloiden aus Rauwolfia serpentina Benth. beschrieben. Die Bruttoformel C21H26O3N2 sowie physikalische und chemische Eigenschaften kennzeichnen sie als Isomere des Yohimbins, was durch die Bezeichnung Rauhimbin und Isorauhimbin zum Ausdruck gebracht wird.
    Additional Material: 5 Ill.
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  • 67
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    Helvetica Chimica Acta 37 (1954), S. 321-326 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Submerged cultures of several species of streptomyces under aerobic conditions converted cortexone into 16α-hydroxy-cortexone. The diacetate of this new compound is identical with a compound obtained by Hirschmann et al. in a chemical multistage synthesis.
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  • 68
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    Helvetica Chimica Acta 37 (1954), S. 327-332 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus einem gutartigen Hodentumor, der histologisch betrachtet an Nebennierenrindengewebe erinnerte und welcher beim Patienten deutliche Zeichen der Feminisierung (Gynaekomastie) erzeugte, wurde Östradiol als Dibenzoat isoliert. Die Konzentration an Östradiol in diesem Tumor ist mindestens 130 000mal grösser als der Gehalt normaler menschlicher Testes an demselben weiblichen Sexualhormon. Die in der Literatur vertretenen Ansichten über die hormonale Wirkungsweise solcher Tumoren werden unter Berücksichtigung dieser neuen experimentellen Befunde diskutiert.
    Additional Material: 1 Ill.
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  • 69
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Rats with a thoracic duct fistula absorb vitamin A and β-carotene very poorly in the total absence of bile from the intestine. Administration of taurocholic acid improves the degree of absorption but fails to raise it to its normal level. It was demonstrated in vitro that small quantities of bilirubin and biliverdin exert a stabilizing action towards vitamin A. Consequently, it may be assumed that the bile pigments play the same role in vivo, serving as natural antioxidants which protect easily oxidizable substances from destruction in the intestinal tract.
    Additional Material: 12 Tab.
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  • 70
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    Helvetica Chimica Acta 37 (1954), S. 333-344 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nous avons tout d' cherché à déterminer le potentiel normal de l'ion aurique en solution d'acide chloroaurique par la méthode des piles à électrodes de dissolution.
    Additional Material: 3 Ill.
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  • 71
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    Helvetica Chimica Acta 37 (1954), S. 378-381 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird eine neue Darstellung des 3-Desoxy-4, 6-benzyliden-α-methyl-D-glucopyranosids (II) durch Reduktion von 2,3-Ditosyl-4,6-benzyliden-α-methyl-D-glucopyranosid (I) durch Lithiumaluminium hydrid beschrieben.
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  • 72
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: En étudiant spectrographiquement l'autoxydation de l'aldéhyde benzoïque, nous avons mis en évidence une bande nouvelle, de fréquence 1270 cm-1, se repportant à un produit intermèdiaire, formé avant l'acide perbenzoïque.
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  • 73
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    Helvetica Chimica Acta 37 (1954), S. 360-374 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Für optisch weiche Kugeln wurden Streuung und Absorption elektromagnetischer Wellen in der Gegend einer Spektrallinie theoretisch untersucht. Die sich aus der Theorie ergebenden merkwürdigen Veränderungen der Transmissionskurven wurden an zahlreichen Beispielen diskutiert.
    Additional Material: 6 Ill.
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  • 74
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    Helvetica Chimica Acta 37 (1954), S. 375-377 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die in einer früheren vorläufigen Mitteilung erwähnte neue Pantethin-Synthese wird ausführlich beschrieben. Von dem Pantethin konnte ein cyclisch gebauter Phosphorsäureester dargestellt werden.
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  • 75
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    Helvetica Chimica Acta 37 (1954), S. 382-382 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 76
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    Helvetica Chimica Acta 37 (1954), S. 383-388 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird mit Hilfe von 15N gezeigt, dass bei der Bildung von Phenylazid aus Phenyldiazoniumperbromid und Wässeriger Ammonialklösung die Stickstoffatome streng nach dem Brutto-Schema aneinandergefügt werden. Nur die lineare Struktur ist verträglich mit den Analysenergebnissen, die zugleich einen Beweis für die Zuverlässigkeit der schon früher benutzten Abbaureaktionen des Phenylazids erbringen.
    Additional Material: 6 Ill.
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  • 77
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    Helvetica Chimica Acta 37 (1954), S. 388-393 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Teilsynthese von 11-Epi-cortiocosteron unter Verwendung von Trifluoressigsäure-estern als Zwischenprodukten wird beschrieben.
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  • 78
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    Helvetica Chimica Acta 37 (1954), S. 394-396 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 79
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    Helvetica Chimica Acta 37 (1954) 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 80
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    Helvetica Chimica Acta 37 (1954), S. 393-393 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 81
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    Helvetica Chimica Acta 37 (1954), S. 397-402 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus Di- und Trimethyl-glutarsäuren, die z. T. nach verbesserten bekannten Methoden gewonnen wurden, hat man die entsprechenden Di- und Trimethyl-glutarsäure-anhydride und -imide hergestellt und letztere mittels LiAlH, in folgende Piperidin-methyl-Homologen uber- geführt : 3,5-Dimethyl-piperidin, 4,4-Dimethyl-piperidin, 3,S-Dimethyl-piperidin, 3,3,5-Trimethyl-piperidin und 3,4,4-Trimethyl-piperidin.
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  • 82
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    Helvetica Chimica Acta 37 (1954), S. 403-427 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Isolierung der wichtigsten Glykoside der Samen von Acokanthera friesiorum Markgr. aus Kenya wird beschrieben. Die Samen enthielten als Hauptkomponente ca. 1,7 % des bekannten Acovenosid A. Daneben liessen sich aber auch etwa 0,l% Ouabain isolieren sowie kleine Mengen von Acolongiflorosid E, Acolongiflorosid G, Acolongiflorosid H, Acolongiflorosid-K-Acetat und ein Kristallisat, das als „Kristallisat Nr. 4“ bezeichnet wird und das ein Gemisch dar-stellt. Durch Verteilungschromatographie liess es sich in 3 Komponenten zerlegen, von denen eine rnit Acolongiflorosid E identisch war, während die zwei anderen neue Glykoside darstellten, die als Acofriosid L und Acofriosid M bezeichnet werden. - Fur einen Abbau war nicht genügend von diesen zwei Stoffen in reiner Form vorhanden, hingegen wurde die Spaltung von „Kristallisat Nr. 4“ mit HClin Aceton durchgeführt. Das in diesem Gemisch erhaltene Acolongiflorosid E blieb dabei weitgehend unverändert. Als Spaltprodukte wurden ein neuer krist. Zucker erhalten, den wir Acofriose (V) nennen, sowie 3,5-Dianhydro-periplogenin (VI), das sich zum Vergleich auch teilsynthetisch aus Periplogenin bereiten liess. Wir vermuten, dass diese zwei Spaltstücke aus Acofriosid L stammen, so dass sich fur dieses Glykosid eine Teilformel aufstellen liess.
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  • 83
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    Helvetica Chimica Acta 37 (1954), S. 427-435 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 84
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    Helvetica Chimica Acta 37 (1954), S. 435-436 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of 6-nitrocoumarone via 6-nitrocoumarilic acid has been described.
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  • 85
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The preparation of 6-amino-coumarone hydrochloride has been described. The antitubercular activity of some isonicotinoylhydrazones (somewhat more active against INH-resistent strains of Myc. tuberculosis than INH) and of different compounds liable to form metal complexes has been shown.
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  • 86
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Synthese von 3β,21-Diacetoxy-11β-oxy-allopregnanon-(20) und von Corticosteron-21-monoacetat, ausgehend von entsprechenden Ätiansäuren, wird beschrieben. Als Zwischenprodukte waren Stoffe, bei denen die 11β-Oxygruppe mit Ameisensäure oder mit Trifluor-essigsäure verestert war, geeignet.
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  • 87
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    Helvetica Chimica Acta 37 (1954), S. 451-454 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Zwiebeln von Bowiea volubilis Harvey wurde eine weitere, vorläufig Bowieasubstanz G genannte Substanz isoliert. Es wurde daraus das mit NaBH4 erhältliche Reduktionsprodukt und dessen Acetat hergestellt. Es wird vermutet, dass das Aglykon von Bovosid A vorliegt; der strenge Beweis dafür steht aber noch aus.
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  • 88
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    Helvetica Chimica Acta 37 (1954), S. 472-483 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Es wird die Darstellung von aminoalkylierten und aminoacylierten Derivaten des Iminodibenzyls (10, 11-Dihydro-5-dibenzo-[b, f]-azepin) beschrieben.
    Additional Material: 1 Ill.
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  • 89
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    Helvetica Chimica Acta 37 (1954), S. 484-494 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden Synthesen des 2,5-Dimethoxy-3-oxy-4-chlortetrahydro-furans (I), 2,3,5-Trimethoxy-tetrahydro-furans (IV), 2,3,4,5-Tetramethoxy-tetrahydro-furans (X), 6,7-Dimethoxy-tropinons (XIIIa,XIIIb), 6-Methoxy-tropinons (XIIa,XIIb), 1-Methoxymethyltropinons (XVIII, R = CH2OCH3), 1-Methoxymethyl-tropins (XIX, R=CH2OCH3, R′=H), 1-Methoxymethyl-pseudotropins (XX,R=CH2OCH3, R′=H), 1-Methoxymethyl-tropacocains (XX, R=CH2OCH3, R′=COC6H5), 1-Oxymethyl-tropinons (XVIII, R=CH2OH), 1-Oxymethyl-tropins (XIX, R=CH2OH, R′=H), 1-Acetoxy-methyl-tropinons (XVIII, R=CH2OCOCH3), 1-Acetoxy-methyl-tropins (XIX, R=CH2OCOCH3, R′=H), 1-Carboxy-tropinons (XVIII, R=COOH) und des 1-Carbomethoxy-tropinons (XXIII) beschrieben und die Konfiguration bzw. Konformation der erwähnten Tropinon- und Tropinderivate diskutiert.
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  • 90
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    Helvetica Chimica Acta 37 (1954), S. 455-461 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Diluted human saliva in an ammonia buffer solution and in presence of CoII gives three catalytic waves, whilst blood serum, under the same conditions, gives only two waves. Saliva presents the first two waves only in the presence of CoII, but the third wave appears in buffer solution with or without CoII. After denaturation with potassium hydroxyde under the given conditions the third wave disappears completely, whilst the first and the second waves augment. Saliva changes its properties when kept; the stability of the waves is diminished in regressive order from h, to h,. After simple dialysis the second and third waves disappear, whilst the first wave does not change. After electrodialysis during two and a half hours, the first wave disappears, but the third wave is hardly changed. The water used for the simple dialysis has also been examined under the polarograph; this gave only the second and the third waves, but the behaviour of the third wave with or without CoII is quite different from the behaviour of h, taken from a saliva which has not been dialysed. By addition of cystine or cysteine to the saliva, the third wave increases when CoII is present, but it decreases in the absence of this ion.
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  • 91
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Wurzeln von Carissa ovata (R. Br.) var. stolonifera F. M. Bailey aus Westqueensland (Australien) liessen sich nach wiederholter Chromatographie ca. 0,0007% eines krist. Glykosids gewinnen, das höchst wahrscheinlich mit Odorosid H identisch ist. Andere Glykoside liessen sich auch papierchromatographisch nicht nachweisen. - Zweige und Blätter wurden nur qualitativ geprüft und enthielten sicher nicht mehr als Spuren digitaloider Glykoside.
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  • 92
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    Helvetica Chimica Acta 37 (1954), S. 495-510 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Wir berichten über die Fortsetzung unserer Untersuchungen auf dem Gebiet der 6-Alkoxy-tropane, die sich auf den 2,5-Dialkoxy- bzw. 2,5-Diacyloxy-3-oxy-4halogen-tetrahydro-furanen und andern Furanderivaten als Schlüsselsubstanzen aufbauen. Letztere führten seinerzeit zu den entsprechenden O-Alkyl-äpfelsäure-dialdehyden. Durch Kondensation dieser Dialdehyde mit primären aliphatischen Aminen und Acetondicarbonsäure sind in der vorliegenden Arbeit eine grössere Zahl von 6-Alkoxy-tropinonen aufgebaut worden (siehe Tabelle 1).
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  • 93
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction of phenylhydrazine with maleic acid anhydride and with citraconic acid anhydride was studied. The cyclic phenylhydrazides (1-phenyl-3-hydroxy-6-pyridazones) obtained in this way served as starting materials for the preparation of substituted 1-phenyl-6-pyridazones. Some of them show analgesic and antipyretic activity.
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  • 94
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    Helvetica Chimica Acta 37 (1954), S. 523-533 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction between chloromaleic acid anhydride and phenylhydrazine is studied. The constitution of the two isomeric 1-phenyl-3-hydroxy-chloro-pyridazones-(6) is established. Starting with 1-phenyl-3-hydroxy-4-chloro-pyridazone-(6) some derivatives are prepared. Some of them show good analgesic activity.
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  • 95
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Destillation der Produkte der katalytischen Hydrierung von Δ1,7-Bicyclo-[0,3,5]-decen-8-on (I) konnten neben dem Kohlenwasserstoff cis-Bicyclo-[0,3,5]-decan (IV) und dem cis-Bicyclo-[0,3,5]-decan-8-on (II) die beiden stereoisomeren Alkohole cis-Bicyclo-[0,3,5]-decan-trans-8-ol (IIIa) und cis-Bicyclo-[0,3,5]-decan-cis-8-ol (IIIb) in reiner Form isoliert werden. Auf Grund von physikalischen und chemischen Eigenschaften wird die Stereochemie dieser Verbindungen diskutiert.
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    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 543-546 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Beim oxydativen Abbau von Manool (I) mit Kaliumpermanganat entsteht neben dem bereits beschriebenen Methyl-keton C18H30O (II) eine neutrale Verbindung C18H30O2, welche die Konstitution eines intramolekularen Acetals IV besitzt. Die Verbindung IV weist einen starken, dauerhaften und angenehmen Ambrageruch auf, der auf die intramolekulare Acetal-Gruppierung zurückzuführen ist.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 97
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In dieser Arbeit ist es gelungen, die Steroide mit Hilfe von direkten Umwandlungen mit den Monoterpenen konfigurativ zu verknüpfen. Daraus ergibt sich, dass die gebräuchlichen Projektionsformeln der Steroide Korrekt sind und ihre absolute Konfiguration wiedergeben.
    Type of Medium: Electronic Resource
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  • 98
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 565-574 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der konkurrierenden Hydrogenolyse von Aminen wird die α-Menaphtylgruppe etwas leichter abgespalten als die β-Menaphtyl-gruppe.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 553-565 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus dem Calebassen-alkaloid Fluorocurin C20H25O2N2⊕, einem Indoxylderivat, wurde durch Reduktion mit NaBH4 Hydro-fluorocurin C20H27O2N2⊕ erhalten, welches durch Säuren sehr leicht in das Indolderivat Mavacurin C20H25ON2⊕ übergeht. Mavacurin, ein Calebassen-alkaloid, haben wir auch in Rinde von Strychnos toxifera gefunden. Die Überführung von Fluorocurin in Mavacurin gelang auch direkt durch Reduktion ersterer Verbindung mit Zink und Schwefelsäure. Durch thermische Spaltung wurde Fluorocurin in Norfluorocurin C19H22O2N2 übergeführt; letzteres lässt sich durch Reduktion mit NaBH4 oder LiAlH4 in Norhydro-fluorocurin C19H24O2N2 verwandeln, das seinerseits durch Methylierung in Hydro-fluorocurin C20H27O2N2⊕ und durch H-Ionen in Normavacurin C19H22ON2 übergeht. Methylierung des Normavacurins liefert Mavacurin.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 100
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vier 3,6-Anhydro-hexose-phenylosotriazole, die aus Diels'schen Anhydro-hexose-phenylosazonen zugänglich sind, wurden mit Perjodsäure oxydiert. Als Oxydationsprodukte wurden optisch aktive Dialdehyd-hydrate in antipoden Formen und in kristallisiertem Zustand isoliert. Die Dialdehyd-hydrate, deren Konstitution durch Derivate und Abbauprodukte gesichert wurde, ermöglichten auf einfachstem Wege eine konfigurative Verknüpfung des asymmetrischen C-Atoms 3 der 3,6-Anhydro-triazole und bestätigten unsere früheren Konfigurationsbestimmungen. Acetylierung der Dialdehyd-hydrate führte unter Aufhebung der Asymmetrie ohne Verlust von C-Atomen zu einem für sämtliche 3,6-Anhydro-hexose-phenyloso-triazole gemeinsamen Monoacetyl-Derivat, für welches eine Acetoxy-1,4-dioxen-Struktur weitgehend bewiesen wurde.
    Type of Medium: Electronic Resource
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