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  • 1
    Publication Date: 2020-08-05
    Description: Das heutige Leben ist durchdrungen von komplexen Technologien. Ohne Kommunikationsnetze, Internet, Mobilfunk, Logistik, Verkehrstechnik, medizinische Apparate, etc. könnte die moderne Gesellschaft nicht funktionieren. Fast alle dieser Technologien haben einen hohen Mathematikanteil. Der "normale Bürger"' weiss davon nichts, der Schulunterricht könnte dem ein wenig abhelfen. Einige mathematische Aspekte dieser Technologien sind einfach und sogar spielerisch intuitiv zugänglich. Solche Anwendungen, die zusätzlich noch der Lebensumwelt der Schüler zugehören, können dazu genutzt werden, die mathematische Modellierung, also die mathematische Herangehensweise an die Lösung praktischer Fragen, anschaulich zu erläutern. Gerade in der diskreten Mathematik können hier, quasi "nebenbei" mathematische Theorien erarbeitet und Teilaspekte (Definitionen, Fragestellungen, einfache Sachverhalte) durch eigenständiges Entdecken der Schüler entwickelt werden. Wir beginnen mit einigen Beispielen.
    Keywords: ddc:510
    Language: German
    Type: reportzib , doc-type:preprint
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  • 2
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    Publication Date: 2020-08-05
    Description: Den kürzesten Weg in einem Graphen zu finden ist ein klassisches Problem der Graphentheorie. Über einen Vortrag zu diesem Thema beim Tag der Mathematik 2007 von R. Borndörfer kam ich in Kontakt mit dem Konrad-Zuse-Zentrum (ZIB), das sich u.a. mit Wegeoptimierung beschäftigt. Ein Forschungsschwerpunkt dort ist im Rahmen eines Projekts zur Chipverifikation das Zählen von Lösungen, das, wie wir sehen werden, eng mit dem Zählen von Wegen zusammenhängt. Anhand von zwei Fragen aus der Graphentheorie soll diese Facharbeit unterschiedliche Lösungsmethoden untersuchen. Wie bestimmt man den kürzesten Weg zwischen zwei Knoten in einem Graphen und wie findet man alle möglichen Wege? Nach einer Einführung in die Graphentheorie und einer Konkretisierung der Probleme wird zunächst für beide eine Lösung mit auf Graphen basierenden Algorithmen vorgestellt. Während der Algorithmus von Dijkstra sehr bekannt ist, habe ich für das Zählen von Wegen einen eigenen Algorithmus auf der Basis der Tiefensuche entwickelt. Im zweiten Teil der Arbeit wird das Konzept der ganzzahligen Programmierung vorgestellt und die Lösungsmöglichkeiten für Wegeprobleme, die sich darüber ergeben. Schließlich wurden die vorgestellten Algorithmen am Beispiel des S- und U-Bahnnetzes von Berlin implementiert und mit Programmen, die die gleichen Fragen über ganzzahlige Programmierung lösen, verglichen.
    Keywords: ddc:510
    Language: German
    Type: reportzib , doc-type:preprint
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  • 3
    Publication Date: 2016-06-09
    Description: This paper is intended to be a first step towards the continuous dependence of dynamical contact problems on the initial data as well as the uniqueness of a solution. Moreover, it provides the basis for a proof of the convergence of popular time integration schemes as the Newmark method. We study a frictionless dynamical contact problem between both linearly elastic and viscoelastic bodies which is formulated via the Signorini contact conditions. For viscoelastic materials fulfilling the Kelvin-Voigt constitutive law, we find a characterization of the class of problems which satisfy a perturbation result in a non-trivial mix of norms in function space. This characterization is given in the form of a stability condition on the contact stresses at the contact boundaries. Furthermore, we present perturbation results for two well-established approximations of the classical Signorini condition: The Signorini condition formulated in velocities and the model of normal compliance, both satisfying even a sharper version of our stability condition.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 4
    Publication Date: 2020-08-05
    Description: Most data networks nowadays use shortest path protocols to route the traffic. Given administrative routing lengths for the links of the network, all data packets are sent along shortest paths with respect to these lengths from their source to their destination. In this paper, we present an integer programming algorithm for the minimum congestion unsplittable shortest path routing problem, which arises in the operational planning of such networks. Given a capacitated directed graph and a set of communication demands, the goal is to find routing lengths that define a unique shortest path for each demand and minimize the maximum congestion over all links in the resulting routing. We illustrate the general decomposition approach our algorithm is based on, present the integer and linear programming models used to solve the master and the client problem, and discuss the most important implementational aspects. Finally, we report computational results for various benchmark problems, which demonstrate the efficiency of our algorithm.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 5
    Publication Date: 2020-12-15
    Description: This paper introduces the "line connectivity problem", a generalization of the Steiner tree problem and a special case of the line planning problem. We study its complexity and give an IP formulation in terms of an exponential number of constraints associated with "line cut constraints". These inequalities can be separated in polynomial time. We also generalize the Steiner partition inequalities.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 6
    Publication Date: 2020-08-05
    Description: Testing is the process of stimulating a system with inputs in order to reveal hidden parts of the system state. In the case of non-deterministic systems, the difficulty arises that an input pattern can generate several possible outcomes. Some of these outcomes allow to distinguish between different hypotheses about the system state, while others do~not. In this paper, we present a novel approach to find, for non-deterministic systems modeled as constraints over variables, tests that allow to distinguish among the hypotheses as good as possible. The idea is to assess the quality of a test by determining the ratio of distinguishing (good) and not distinguishing (bad) outcomes. This measure refines previous notions proposed in the literature on model-based testing and can be computed using model counting techniques. We propose and analyze a greedy-type algorithm to solve this test optimization problem, using existing model counters as a building block. We give preliminary experimental results of our method, and discuss possible improvements.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 7
    Publication Date: 2021-08-05
    Description: Starting with the description of the Traveling Salesmen Problem formulation as given by van Vyve and Wolsey in the article Approximate extended formulations'', we investigate the effects of small variations onto the performance of contemporary mixed integer programming solvers. We will show that even minor changes in the formulation of the model can result in performance difference of more than a factor of 1000. As the results show it is not obvious which changes will result in performance improvements and which not.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 8
    Publication Date: 2022-03-14
    Description: Orbitopes can be used to handle symmetries which arise in integer programming formulations with an inherent assignment structure. We investigate the detection of symmetries appearing in this approach. We show that detecting so-called orbitopal symmetries is graph-isomorphism hard in general, but can be performed in linear time if the assignment structure is known.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 9
    Publication Date: 2019-01-29
    Description: Regional hyperthermia is a cancer therapy aiming at heating tumors using phased array applicators. This article provides an overview over current mathematical challenges of delivering individually optimal treatments. The focus is on therapy planning and identification of technical as well as physiological quantities from MR thermometry measurements.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 10
    Publication Date: 2019-05-10
    Description: Reasons for the failure of adaptive methods to deliver improved efficiency when integrating monodomain models for myocardiac excitation are discussed. Two closely related techniques for reducing the computational complexity of linearly implicit integrators, deliberate sparsing and splitting, are investigated with respect to their impact on computing time and accuracy.
    Keywords: ddc:510
    Language: English
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  • 11
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    Publication Date: 2020-08-05
    Description: We investigate the computation of periodic timetables for public transport by mixed integer programming. After introducing the problem, we describe two mathematical models for periodic timetabling, the PERIODIC EVENT SCHEDULING PROBLEM (PESP) and the QUADRATIC SEMI-ASSIGNMENT PROBLEM. Specifically, we give an overview of existing integer programming (IP) formulations for both models. An important contribution of our work are new IP formulations for the PESP based on time discretization. We provide an analytical comparison of these formulations and describe different techniques that allow a more efficient solution by mixed integer programming. In a preliminary computational study, on the basis of standard IP solvers, we compare different formulations for computing periodic timetables. Our results justify a further investigation of the time discretization approach. Typically the timetable is optimized for the current traffic situation. The main difficulty with this approach is that after introducing the new timetable the passengers’ travel behavior may differ from that assumed for the computation. Motivated by this problem, we examine an iterative timetabling procedure that is a combination of timetable computation and passenger routing. We discuss the algorithmic issues of the passenger routing and study properties of the computed timetables. Finally, we confirm our theoretical results on the basis of an own implementation.
    Description: Wir untersuchen die Berechnung von Taktfahrplänen für den öffentlichen Verkehr mit gemischt-ganzzahliger Programmierung (MIP). Im Anschluss an die Problembeschreibung, stellen wir zwei mathematische Modellierungen vor, das PERIODIC EVENT SCHEDULING PROBLEM (PESP) und das QUADRATIC SEMI-ASSIGNMENT PROBLEM. Wichtiger Bestandteil ist ein Überblick über existierende ganzzahlige Formulierungen beider Modelle. Wir entwickeln neue ganzzahlige Formulierungen für das PESP auf der Basis von Zeitdiskretisierung. Diese werden analytisch miteinander verglichen und wir beschreiben verschiedene Techniken, die eine effizientere Lösung der Formulierungen mit gemischt-ganzzahliger Programmierung ermöglichen. In einer ersten Rechenstudie, unter Verwendung gängiger MIP-Löser, vergleichen wir verschiedene ganzzahlige Formulierungen zur Berechnung von Taktfahrplänen. Unsere Ergebnisse rechtfertigen eine weitere Untersuchung des Zeitdiskretisierungsansatzes. In der Regel werden Fahrpläne mit Bezug auf die gegenwärtige Verkehrssituation optimiert. Dies birgt jedoch folgendes Problem. Wenn der neue Fahrplan eingeführt wird, ist es möglich, dass die Passagiere ein anderes Fahrverhalten zu Tage legen, als für die Berechnung des Fahrplans angenommen wurde. Vor diesem Hintergrund behandeln wir ein iteratives Verfahren zur Berechnung von Taktfahrplänen. Dieses ist eine Kombination aus Fahrplanberechnung und Passagierrouting. Neben den algorithmischen Details des Passagierroutings untersuchen wir Eigenschaften der berechneten Fahrpläne. Abschließend bestätigen wir unsere theoretischen Ergebnisse auf Grundlage einer eigenen Implementierung des Verfahrens.
    Keywords: ddc:510
    Language: English
    Type: masterthesis , doc-type:masterThesis
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  • 12
    Publication Date: 2020-08-05
    Description: This paper describes several experiments to explore the options for solving a class of mixed integer nonlinear programming problems that stem from a real-world mine production planning project. The only type of nonlinear constraints in these problems are bilinear equalities involving continuous variables, which enforce the ratios between elements in mixed material streams. A branch-and-bound algorithm to handle the integer variables has been tried in another project. However, this branch-and-bound algorithm is not effective for handling the nonlinear constraints. Therefore state-of-the-art nonlinear solvers are utilized to solve the resulting nonlinear subproblems in this work. The experiments were carried out using the NEOS server for optimization. After finding that current nonlinear programming solvers seem to lack suitable preprocessing capabilities, we preprocess the instances beforehand and use an heuristic approach to solve the nonlinear subproblems. In the appendix, we explain how to add a polynomial constraint handler that uses IPOPT as embedded nonlinear programming solver for the constraint programming framework SCIP. This is one of the crucial steps for implementing our algorithm in SCIP. We briefly described our approach and give an idea of the work involved.
    Keywords: ddc:510
    Language: English
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  • 13
    Publication Date: 2020-08-05
    Description: Dieser kurze Aufsatz zur Algorithmengeschichte ist Eberhard Knobloch, meinem Lieblings-Mathematikhistoriker, zum 65. Geburtstag gewidmet. Eberhard Knobloch hat immer, wenn ich ihm eine historische Frage zur Mathematik stellte, eine Antwort gewusst – fast immer auch sofort. Erst als ich mich selbst ein wenig und dazu amateurhaft mit Mathematikgeschichte beschäftigte, wurde mir bewusst, wie schwierig dieses „Geschäft“ ist. Man muss nicht nur mehrere (alte) Sprachen beherrschen, sondern auch die wissenschaftliche Bedeutung von Begriffen und Symbolen in früheren Zeiten kennen. Man muss zusätzlich herausfinden, was zur Zeit der Entstehung der Texte „allgemeines Wissen“ war, insbesondere, was seinerzeit gültige Beweisideen und -schritte waren, und daher damals keiner präzisen Definition oder Einführung bedurfte. Es gibt aber noch eine Steigerung des historischen Schwierigkeitsgrades: Algorithmengeschichte. Dies möchte ich in diesem Artikel kurz darlegen in der Hoffnung, dass sich Wissenschaftshistoriker dieses Themas noch intensiver annehmen, als sie das bisher tun. Der Grund ist, dass heute Algorithmen viele Bereiche unserer Alltagswelt steuern und unser tägliches Leben oft von funktionierenden Algorithmen abhängt. Daher wäre eine bessere Kenntnis der Algorithmengeschichte von großem Interesse.
    Keywords: ddc:510
    Language: German
    Type: reportzib , doc-type:preprint
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  • 14
    Publication Date: 2016-06-09
    Description: We consider first order optimality conditions for state constrained optimal control problems. In particular we study the case where the state equation has not enough regularity to admit existence of a Slater point in function space. We overcome this difficulty by a special transformation. Under a density condition we show existence of Lagrange multipliers, which have a representation via measures and additional regularity properties.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 15
    Publication Date: 2016-06-09
    Description: The enormous time lag between fast atomic motion and complex pro- tein folding events makes it almost impossible to compute molecular dy- namics on a high resolution. A common way to tackle this problem is to model the system dynamics as a Markov process. Yet for large molec- ular systems the resulting Markov chains can hardly be handled due to the curse of dimensionality. Coarse graining methods can be used to re- duce the dimension of a Markov chain, but it is still unclear how far the coarse grained Markov chain resembles the original system. In order to answer this question, two different coarse-graining methods were analysed and compared: a classical set-based reduction method and an alternative subspace-based approach, which is based on membership vectors instead of sets. On the basis of a small toy system, it could be shown, that in con- trast to the subset-based approach, the subspace-based reduction method preserves the Markov property as well as the essential dynamics of the original system.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 16
    Publication Date: 2021-02-19
    Description: Line planning is an important step in the strategic planning process of a public transportation system. In this paper, we discuss an optimization model for this problem in order to minimize operation costs while guaranteeing a certain level of quality of service, in terms of available transport capacity. We analyze the problem for path and tree network topologies as well as several categories of line operation that are important for the Quito Trolebus system. It turns out that, from a computational complexity worst case point of view, the problem is hard in all but the most simple variants. In practice, however, instances based on real data from the Trolebus System in Quito can be solved quite well, and significant optimization potentials can be demonstrated.
    Keywords: ddc:510
    Language: English
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  • 17
    Publication Date: 2020-08-05
    Description: It is well known that competitive analysis yields too pessimistic results when applied to the paging problem and it also cannot make a distinction between many paging strategies. Many deterministic paging algorithms achieve the same competitive ratio, ranging from inefficient strategies as flush-when-full to the good performing least-recently-used (LRU). In this paper, we study this fundamental online problem from the viewpoint of stochastic dominance. We show that when sequences are drawn from distributions modelling locality of reference, LRU is stochastically better than any other online paging algorithm.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 18
    Publication Date: 2020-12-15
    Description: Die Angebotsplanung im öffentlichen Nahverkehr umfasst die Aufgaben der Netz-, Linien-,Fahr- und Preisplanung. Wir stellen zwei mathematische Optimierungsmodelle zur Linien- und Preisplanung vor. Wir zeigen anhand von Berechnungen für die Verkehrsbetriebe in Potsdam(ViP), dass sich damit komplexe Zusammenhänge quantitativ analysieren lassen. Auf diese Weise untersuchen wir die Auswirkungen von Freiheitsgraden auf die Konstruktion von Linien und die Wahl von Reisewegen der Passagiere, Abhängigkeiten zwischen Kosten und Reisezeiten sowie den Einfluss verschiedener Preissysteme auf Nachfrage und Kostendeckung.
    Keywords: ddc:510
    Language: German
    Type: reportzib , doc-type:preprint
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  • 19
    Publication Date: 2022-03-14
    Description: This article introduces constraint integer programming (CIP), which is a novel way to combine constraint programming (CP) and mixed integer programming (MIP) methodologies. CIP is a generalization of MIP that supports the notion of general constraints as in CP. This approach is supported by the CIP framework SCIP, which also integrates techniques from SAT solving. SCIP is available in source code and free for non-commercial use. We demonstrate the usefulness of CIP on two tasks. First, we apply the constraint integer programming approach to pure mixed integer programs. Computational experiments show that SCIP is almost competitive to current state-of-the-art commercial MIP solvers. Second, we employ the CIP framework to solve chip design verification problems, which involve some highly non-linear constraint types that are very hard to handle by pure MIP solvers. The CIP approach is very effective here: it can apply the full sophisticated MIP machinery to the linear part of the problem, while dealing with the non-linear constraints by employing constraint programming techniques.
    Keywords: ddc:510
    Language: English
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  • 20
    Publication Date: 2016-06-09
    Description: An extended mathematical framework for barrier methods for state constrained optimal control compared to [Schiela, ZIB-Report 07-07] is considered. This allows to apply the results derived there to more general classes of optimal control problems, in particular to boundary control and finite dimensional control.
    Keywords: ddc:510
    Language: English
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  • 21
    Publication Date: 2021-08-05
    Description: In the recent years there has been tremendous progress in the development of algorithms to find optimal solutions for integer programs. In many applications it is, however, desirable (or even necessary) to generate all feasible solutions. Examples arise in the areas of hardware and software verification and discrete geometry. In this paper, we investigate how to extend branch-and-cut integer programming frameworks to support the generation of all solutions. We propose a method to detect so-called unrestricted subtrees, which allows us to prune the integer program search tree and to collect several solutions simultaneously. We present computational results of this branch-and-count paradigm which show the potential of the unrestricted subtree detection.
    Keywords: ddc:510
    Language: English
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  • 22
    Publication Date: 2020-08-05
    Description: Edmonds showed that the so-called rank inequalities and the nonnegativity constraints provide a complete linear description of the matroid polytope. By essentially adding Grötschel's cardinality forcing inequalities, we obtain a complete linear description of the cardinality constrained matroid polytope which is the convex hull of the incidence vectors of those independent sets that have a feasible cardinality. Moreover, we show how the separation problem for the cardinality forcing inequalities can be reduced to that for the rank inequalities. We also give necessary and sufficient conditions for a cardinality forcing inequality to be facet defining.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 23
    Publication Date: 2020-08-05
    Description: The paper describes a method for solution of very large overdetermined algebraic polynomial systems on an example that appears from a classification of all integrable 3-dimensional scalar discrete quasilinear equations $Q_3=0$ on an elementary cubic cell of the lattice ${\mathbb Z}^3$. The overdetermined polynomial algebraic system that has to be solved is far too large to be formulated. A probing' technique which replaces independent variables by random integers or zero allows to formulate subsets of this system. An automatic alteration of equation formulating steps and equation solving steps leads to an iteration process that solves the computational problem.
    Keywords: ddc:510
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  • 24
    Publication Date: 2020-08-05
    Description: An algorithmic method using conservation law multipliers is introduced that yields necessary and sufficient conditions to find invertible mappings of a given nonlinear PDE to some linear PDE and to construct such a mapping when it exists. Previous methods yielded such conditions from admitted point or contact symmetries of the nonlinear PDE. Through examples, these two linearization approaches are contrasted.
    Keywords: ddc:510
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  • 25
    Publication Date: 2021-02-26
    Description: We classify all integrable 3-dimensional scalar discrete affine linear equations $Q_3=0$ on an elementary cubic cell of the lattice ${\mathbb Z}^3$. An equation $Q_3=0$ %of such form is called integrable if it may be consistently imposed on all $3$-dimensional elementary faces of the lattice ${\mathbb Z}^4$. Under the natural requirement of invariance of the equation under the action of the complete group of symmetries of the cube we prove that the only ontrivial(non-linearizable) integrable equation from this class is the well-known dBKP-system.
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  • 26
    Publication Date: 2020-12-11
    Description: The article describes the online mathematics test {\tt http://lie.math.brocku.ca/mathtest}, its typical applications and experiences gathered.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 27
    Publication Date: 2020-08-05
    Description: We introduce (TTPlib), a data library for train timetabling problems that can be accessed at http://ttplib.zib.de. In version 1.0, the library contains data related to 50 scenarios. Most instances result from the combination of macroscopic railway networks and several train request sets for the German long distance area containing Hannover, Kassel and Fulda, short denoted by Ha-Ka-Fu. In this paper, we introduce the data concepts of TTPlib, describe the scenarios included in the library and provide a free visualization tool TraVis.
    Keywords: ddc:510
    Language: English
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  • 28
    Publication Date: 2020-08-05
    Description: The purpose of this paper is twofold. An immediate practical use of the presented algorithm is its applicability to the parametric solution of underdetermined linear ordinary differential equations (ODEs) with coefficients that are arbitrary analytic functions in the independent variable. A second conceptual aim is to present an algorithm that is in some sense dual to the fundamental Euclids algorithm, and thus an alternative to the special case of a Gr\"{o}bner basis algorithm as it is used for solving linear ODE-systems. In the paper Euclids algorithm and the new dual version' are compared and their complementary strengths are analysed on the task of solving underdetermined ODEs. An implementation of the described algorithm is interactively accessible at http://lie.math.brocku.ca/crack/uode.
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  • 29
    Publication Date: 2020-08-05
    Description: This paper proposes a new method for probabilistic analysis of online algorithms that is based on the notion of stochastic dominance. We develop the method for the Online Bin Coloring problem introduced by Krumke et al. Using methods for the stochastic comparison of Markov chains we establish the strong result that the performance of the online algorithm GreedyFit is stochastically dominated by the performance of the algorithm OneBin for any number of items processed. This result gives a more realistic picture than competitive analysis and explains the behavior observed in simulations.
    Keywords: ddc:510
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  • 30
    Publication Date: 2020-12-15
    Description: The optimization of fare systems in public transit allows to pursue objectives such as the maximization of demand, revenue, profit, or social welfare. We propose a non-linear optimization approach to fare planning that is based on a detailed discrete choice model of user behavior. The approach allows to analyze different fare structures, optimization objectives, and operational scenarios involving, e.g., subsidies. We use the resulting models to compute optimized fare systems for the city of Potsdam, Germany.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 31
    Publication Date: 2022-03-14
    Description: Pseudo-Boolean problems generalize SAT problems by allowing linear constraints and a linear objective function. Different solvers, mainly having their roots in the SAT domain, have been proposed and compared,for instance, in Pseudo-Boolean evaluations. One can also formulate Pseudo-Boolean models as integer programming models. That is,Pseudo-Boolean problems lie on the border between the SAT domain and the integer programming field. In this paper, we approach Pseudo-Boolean problems from the integer programming side. We introduce the framework SCIP that implements constraint integer programming techniques. It integrates methods from constraint programming, integer programming, and SAT-solving: the solution of linear programming relaxations, propagation of linear as well as nonlinear constraints, and conflict analysis. We argue that this approach is suitable for Pseudo-Boolean instances containing general linear constraints, while it is less efficient for pure SAT problems. We present extensive computational experiments on the test set used for the Pseudo-Boolean evaluation 2007. We show that our approach is very efficient for optimization instances and competitive for feasibility problems. For the nonlinear parts, we also investigate the influence of linear programming relaxations and propagation methods on the performance. It turns out that both techniques are helpful for obtaining an efficient solution method.
    Keywords: ddc:510
    Language: English
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  • 32
    Publication Date: 2020-08-05
    Description: Millionen von Menschen werden allein in Deutschland täglich von Bussen, Bahnen und Flugzeugen transportiert. Der öffentliche Personenverkehr (ÖV) ist von großer Bedeutung für die Lebensqualität einzelner aber auch für die Leistungsfähigkeit ganzer Regionen. Qualität und Effizienz von ÖV-Systemen hängen ab von politischen Rahmenbedingungen (staatlich geplant, wettbewerblich organisiert) und der Eignung der Infrastruktur (Schienensysteme, Flughafenstandorte), vom vorhandenen Verkehrsangebot (Fahr- und Flugplan), von der Verwendung angemessener Technologien (Informations-, Kontroll- und Buchungssysteme) und dem bestmöglichen Einsatz der Betriebsmittel (Energie, Fahrzeuge und Personal). Die hierbei auftretenden Entscheidungs-, Planungs- und Optimierungsprobleme sind z.T. gigantisch und "schreien" aufgrund ihrer hohen Komplexität nach Unterstützung durch Mathematik. Dieser Artikel skizziert den Stand und die Bedeutung des Einsatzes von Mathematik bei der Planung und Durchführung von öffentlichem Personenverkehr, beschreibt die bestehenden Herausforderungen und regt zukunftsweisende Maßnahmen an.
    Keywords: ddc:510
    Language: German
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  • 33
    Publication Date: 2019-05-10
    Description: Pulse thermography of concrete structures is used in civil engineering for detecting voids, honeycombing and delamination. The physical situation is readily modeled by Fourier's law. Despite the simplicity of the PDE structure, quantitatively realistic numerical 3D simulation faces two major obstacles. First, the short heating pulse induces a thin boundary layer at the heated surface which encapsulates all information and therefore has to be resolved faithfully. Even with adaptive mesh refinement techniques, obtaining useful accuracies requires an unsatisfactorily fine discretization. Second, bulk material parameters and boundary conditions are barely known exactly. We address both issues by a semi-analytic reformulation of the heat transport problem and by parameter identification. Numerical results are compared with measurements of test specimens.
    Keywords: ddc:510
    Language: English
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  • 34
    Publication Date: 2016-06-09
    Description: In this paper we are concerned with the application of interior point methods in function space to gradient constrained optimal control problems, governed by partial differential equations. We will derive existence of solutions together with first order optimality conditions. Afterwards we show continuity of the central path, together with convergence rates depending on the interior point parameter.
    Keywords: ddc:510
    Language: English
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  • 35
    Publication Date: 2016-06-09
    Description: We consider an interior point method in function space for PDE constrained optimal control problems with state constraints. Our emphasis is on the construction and analysis of an algorithm that integrates a Newton path-following method with adaptive grid refinement. This is done in the framework of inexact Newton methods in function space, where the discretization error of each Newton step is controlled by adaptive grid refinement in the innermost loop. This allows to perform most of the required Newton steps on coarse grids, such that the overall computational time is dominated by the last few steps. For this purpose we propose an a-posteriori error estimator for a problem suited norm.
    Keywords: ddc:510
    Language: English
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  • 36
    Publication Date: 2020-08-05
    Description: Ticket pricing in public transport usually takes a welfare or mnemonics maximization point of view. These approaches do not consider fairness in the sense that users of a shared infrastructure should pay for the costs that they generate. We propose an ansatz to determine fair ticket prices that combines concepts from cooperative game theory and integer programming. An application to pricing railway tickets for the intercity network of the Netherlands demonstrates that, in this sense, prices that are much fairer than standard ones can be computed in this way.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 37
    Publication Date: 2014-02-26
    Description: We present a second order sharp interface finite volume method for the solution of the three-dimensional poisson equation with variable coefficients on Cartesian grids. In particular, we focus on interface problems with discontinuities in the coefficient, the source term, the solution, and the fluxes across the interface. The method uses standard piecewiese trilinear finite elements for normal cells and a double piecewise trilinear ansatz for the solution on cells intersected by the interface resulting always in a compact 27-point stencil. Singularities associated with vanishing partial volumes of intersected grid cells are removed by a two-term asymptotic approach. In contrast to the 2D method presented by two of the authors in [M.~Oevermann, R.~Klein: A Cartesian grid finite volume method for elliptic equations with variable coefficients and embedded interfaces, J.~Comp.~Phys.~219 (2006)] we use a minimization technique to determine the unknown coefficients of the double trilinear ansatz. This simplifies the treatment of the different cut-cell types and avoids additional special operations for degenerated interface topologies. The resulting set of linear equations has been solved with a BiCGSTAB solver preconditioned with an algebraic multigrid. In various testcases -- including large coefficient ratios and non-smooth interfaces -- the method achieves second order of accuracy in the L_inf and L_2 norm.
    Keywords: ddc:510
    Language: English
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  • 38
    Publication Date: 2020-08-05
    Description: Given a combinatorial optimization problem and a subset $N$ of natural numbers, we obtain a cardinality constrained version of this problem by permitting only those feasible solutions whose cardinalities are elements of $N$. In this paper we briefly touch on questions that addresses common grounds and differences of the complexity of a combinatorial optimization problem and its cardinality constrained version. Afterwards we focus on polytopes associated with cardinality constrained combinatorial optimization problems. Given an integer programming formulation for a combinatorial optimization problem, by essentially adding Grötschel's cardinality forcing inequalities, we obtain an integer programming formulation for its cardinality restricted version. Since the cardinality forcing inequalities in their original form are mostly not facet defining for the associated polyhedra, we discuss possibilities to strengthen them.
    Keywords: ddc:510
    Language: English
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  • 39
    Publication Date: 2020-08-05
    Description: This survey concerns optimization problems arising in the design of survivable communication networks. It turns out that such problems can be modeled in a natural way as non-compact linear programming formulations based on multicommodity flow network models. These non-compact formulations involve an exponential number of path flow variables, and therefore require column generation to be solved to optimality. We consider several path-based survivability mechanisms and present results, both known and new, on the complexity of the corresponding column generation problems (called the pricing problems). We discuss results for the case of the single link (or node) failures scenarios, and extend the considerations to multiple link failures. Further, we classify the design problems corresponding to different survivability mechanisms according to the structure of their pricing problem. Finally, we show that almost all encountered pricing problems are hard to solve for scenarios admitting multiple failures.
    Keywords: ddc:510
    Language: English
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  • 40
    Publication Date: 2021-02-19
    Description: We introduce an optimization model for the line planning problem in a public transportation system that aims at minimizing operational costs while ensuring a given level of quality of service in terms of available transport capacity. We discuss the computational complexity of the model for tree network topologies and line structures that arise in a real-world application at the Trolebus Integrated System in Quito. Computational results for this system are reported.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
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  • 41
    Publication Date: 2021-02-19
    Description: Line planning is an important step in the strategic planning process of a public transportation system. In this paper, we discuss an optimization model for this problem in order to minimize operation costs while guaranteeing a certain level of quality of service, in terms of available transport capacity. We analyze the problem for path and tree network topologies as well as several categories of line operation that are important for the Quito Trolebus system. It turns out that, from a computational complexity worst case point of view, the problem is hard in all but the most simple variants. In practice, however, instances based on real data from the Trolebus System in Quito can be solved quite well, and significant optimization potentials can be demonstrated.
    Keywords: ddc:510
    Language: English
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  • 42
    Publication Date: 2016-06-09
    Keywords: ddc:510
    Language: English
    Type: doctoralthesis , doc-type:doctoralThesis
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  • 43
    Publication Date: 2020-08-05
    Description: wird nachgereicht
    Keywords: ddc:510
    Language: English
    Type: doctoralthesis , doc-type:doctoralThesis
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  • 44
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 1-13 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Einwirkung von Zink auf unverdünnten Methylchlormethyläther wurden Äthylen, Propylen, Cyclopropan, Methychloride, Dimethyläther, Formaldehyd, Methylal, Methyl-β-chloräthyläther, Methyl-γ-chloropropyläther, Zinkchlorid und Chlorzinkmethylat als Reaktionsprodukte erhalten. In Diäthyläther als Lösungsmittel bildeten sich neben einem harzigen Reaktionsanteil noch zusätzlich Methyläthyläther und Methyläthylformal. Das komplexe Reaktionsgeschehen wird an Hand der einzelnen Reaktionsprodukte unter dem Aspekt des intermediären Auftretens einer zinkorganischen Verbindung, deren Zerfall und ätherspaltenden Eigenschaften diskutiert. Verbunden mit einer quantitativen Auswertung wird ein umfassendes Reaktionsschema vorgeschlagen.
    Additional Material: 3 Tab.
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  • 45
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 21-27 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper deals with the separation of microcrystalline wax (ceresin) from the Soviet Tuimasa heavy oil, using an ABT mixture. Structure investigation was performed using different methods of analysis such as fractional crystallisation, n-d-method, Grodde analysis, elementary analysis, urea adduction and adsorption analysis. It was concluded, that this wax was mostly composed of di- and tricyclic paraffinic compounds.
    Additional Material: 1 Ill.
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  • 46
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 81-90 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Einwirkung von gasförmigem Ammoniak auf ein Gemisch aus 3-Mercaptobutyraldehyd und Aldehyden bzw. Ketonen bilden sich in 4-Stellung unsubstituierte Dihydrometathiazine-Δ3. Herstellung und Eigenschaften des 3-Mercaptobutyraldehyds werden beschrieben.
    Additional Material: 2 Tab.
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  • 47
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 29-41 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das Interesse an den α-Hydrazinocarbonsäuren hat sich durch die Entdeckung der Möglichkeit, sie in den Peptidverband an Stelle einer α-Aminosäure einzubauen, erheblich vergrößert. Es wird deshalb ein umfassender Überblick über die zur Zeit bekannten Synthesemethoden gegeben. Insbesondere wird die Methode von Bailey und Thiele zur Synthese von α-Carbamidhydrazinoalkylnitrilen und deren Verseifung und Spaltung zu α-Hydrazinosäuren untersucht.Eine Reihe neuer α-Hydrazinosäuren wird beschrieben.
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  • 48
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    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 82-85 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ω-Diazofettsäureester lagern sich an die Doppelbindungen von Di-(α-naphthyl)-carbodiimid, Phenylisothiocyanat, Benzoylisothiocyanat und Azodicarbonsäureester unter Bildung der entsprechend substituierten Triazole, Thiadiazole und Oxadiazoline an.
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  • 49
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 108-112 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Synthese von 1-Acyl-4-allyl-thiosemicarbaziden und daraus die Darstellung von 2-Allylamino-5-R-1,3,4-thiadiazolen (R=p-Nitrophenyl-, Benzyl-, p-Chlorophenoximethyl-, o-Hydroxiphenyl-, o-Chlorophenyl-, m-Chlorophenyl-, p-Chlorophenyl-, (3′:5′)- Dinitrophenyl-, (3′)-Pyridil-, (4′)-Pyridil-) wird beschrieben.
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  • 50
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 148-152 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Während Azidosteroide von Natriumborhydrid nicht angegriffen werden, erfolgt die Reduktion sehr glatt durch das System Natriumborhydrid/Kobalt-II-tris-α,α′-dipyridyl-bromid. Der Vorteil dieses Verfahrens gegenüber einer Anzahl anderer Reduktionsmittel besteht darin, daß verschiedene im Molekül vorhandene funktionelle Gruppen wie Epoxyde oder Ester unter den Reaktionsbedingungen nicht verändert werden.
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  • 51
    Electronic Resource
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 52
    Electronic Resource
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 197-204 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Umsatz von N-Methyl-β-aminopropionsäureäthylester mit vernetztem Chlormethylpolystyrol wird ein mechanisch stabiles, einheitlich aufgebautes amphoteres Ionenaustauscherharz hergestellt. Die Bindungsmöglichkeiten von Kationen werden an Hand des Elutionsverhaltens von Kupfer- und Kobaltionen diskutiert. Kapazitätsmessungen zei gen, daß zweiwertige Kationen infolge schwacher Komplexbildung fast nicht und mehrwertige nur als Hydroxoverbindungen unbestimmter Zusammensetzung gebunden werden. Ursache dafür sind die ausgeprägten Anionenaustauschereigenschaften der Ankergruppen und die geringe Stabilität des aliphatischen Chelatsechsringes im hochmolekularen Harzgerüst.
    Additional Material: 3 Ill.
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  • 53
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 294-301 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Für die präparative Synthese von Phenyl-isotrithion (I) aus Phenylacetylen-Na, Schwefel und Schwefelkohlenstoff ist ein Protonenüberträger erforderlich, wie am Beispiel des Deutero-I (III) mit Aceton-d6 gezeigt wird. Stärkere acide Zusätze bewirken eine Dimerisierung des Mercaptids II zu Benzyliden-phenyl-1,3-dithiol (IV). Die Struktur dieses bildungsbegünstigten Heterocyclus, der u. a. auch bei der Einwirkung von Schwefel auf Enamine des Typs VI also Konkurrenzprodukt des Thioamids VII entsteht, wird durch unabhängige Synthese gesichert. Sekundäre Amine addieren bei Raumtemperatur an II unter Bildung von VII.
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  • 54
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    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 326-332 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das bei der Addition von Nitrylchlorid an Olefine entstehende Reaktionsgemisch wurde gaschromatographisch analysiert. Die Reaktion verläuft in wenig polaren Lösungsmitteln radikalisch, in stark polaren bzw. protonenhaltigen Solventien erfolgt der Primärangriff im wesentlichen durch das Cl⊕-Kation.
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  • 55
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    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 149-158 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ferrocencarbonylhydrazide wurden durch Umsetzung von Ferrocencarbonsäureestern order -chloriden mit Hydrazin oder Säurehydraziden hergestellt und durch Cyclodehydratisierung in die entsprechenden 1,3,4-Oxadiazole übergeführt. Ferrocenyl-1,3,4-Oxadiazole konnten auch durch direkte Synthese aus Ferrocencarbonsäurechloriden und substituierten Tetrazolen gewonnen werden. Nach analogen Methoden wurden Poly-ferrocenylen-hydrazide und Poly-ferrocenylen-1,3,4-oxadiazole hergestellt. Die thermische Beständigkeit der Poly-ferrocenylen-1,3,4-oxadiazole wurde untersucht.
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  • 56
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 177-185 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Chlorierung von Schwefelkohlenstoff in Gegenwart von 〉 5% Jod oder durch Umsetzung mit Jodchloriden entsteht neben Trichlormethansulfenylchlorid, Schwefelchloriden, Tetrachlorkohlenstoff und Hexachlordimethyltrisulfid Trichlormethanthiosulfenylchlorid (TMTS), CCl3—S—S—Cl. TMTS, aus dem sich unter Einwirkung von Chlor Trichlormethansulfenylchlorid und Tetrachlorkohlenstoff bilden, erhält man ebenfalls durch Addition von Schwefeldichlorid an Thiophosgen sowie durch chlorierende Spaltung aus Hexachlordimethyltrisulfid. Es setzt sich mit Kaliumjodid zum kristallinen Hexachlordimethyltetrasulfid um und lagert sich an Thiophosgen zum Hexachlordimethyltrisulfid an. An Hand eines Reaktionsschemas wird der Reaktionsablauf bei der Chlorierung des Schwefelkohlenstoffs diskutiert.
    Additional Material: 2 Ill.
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  • 57
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 213-224 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch schrittweisen Aufbau vom Carboxylende her wurden nach verschiedenen Synthese-Methoden, unter Verwendung der BOC- und Z-Schutzgruppen, Peptide der Struktur Lys—X—Y—Phe hergestellt. Die Verseifung der Ester erfolgte chymotryptisch.
    Additional Material: 2 Tab.
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  • 58
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 262-270 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Reaktionsfähigkeit von α-Hydroxy-carbonsäuren bzw. deren Ester sowie der Hydrate von Carbonylverbindungen gegenüber Azulen beschrieben.
    Additional Material: 3 Tab.
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  • 59
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 288-293 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es werden vergleichende Untersuchungen an Wofatit KPS und dessen nach dem DWP 43983 hergestellten Aufhellungsprodukt beschrieben. Die Quellungsuntersuchungen erfolgen mit der Apparatur nach Enslin, wobei die absolute Quellung des Austauscherharzes bestimmt wird. Aus dem ermittelten Quellungsvermögen wird auf den Vernetzungsgrad aufgehellten Austauscherharzes geschlossen. Die Bestimmung der Quellbarkeit wird in Wasser, Alkohol und Eisessig vorgenommen.
    Additional Material: 3 Ill.
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  • 60
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 61
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 28-35 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eine neue Synthese von 2-Alkyl-1, 3-diketonen, insbesondere von 2-Alkyl-cyclopentandionen-(1-3), durch Bisacylierung von Enolecetaten mit Carbonsäureanhydriden order-chloriden wird beschrieben.
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  • 62
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 59-67 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurde eine photometrische Bestimmungsmethode ausgearbeitet, mit deren Hilfe noch 5.10-5 mMol Hyponitrit mit einem mittleren Fehler von ±1,5% bestimmt werden kann. Die Oxydation in alkalischer Lösung wurde eingehend untersucht. Dabei wurde fest-gestellt, daß die Reaktion \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm N}_2 {\rm O}_2^{2 -} + 4\ {\rm MnO}_4^ - + 4\ {\rm OH}^ - \to 4\ {\rm MnO}_4^{2 -} + 2\ {\rm NO}_2^ - + 2\ {\rm H}_2 {\rm O} $$\end{document} nur in Gegenwart von Silber(I)- und Kupfer(II)-Ionen quantitative verläuft. Das dabei entstandene Nitrit wurde nach C. A. Parker mit α-Naphthylamin phtometrisch bestimmt.Gleichzeitig wurde eine Methode zur Reindarstellung von verdünnten Natriumhypo-nitritlösungen beschrieben.
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  • 63
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 73-80 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch spektroskopische Untersuchungen und Diplomessungen wurde die Konfiguration und Konformation der α,α′-Dichlor-, Dibrom- und Chlor-brom-cycloheptanone sowie der entsprechenden Cyclooctanone bestimmt. Während vom 2,7-Dichlor-cycloheptanon das cis- und trans-Isomere isoliert werden konnte, ist von allen anderen vermessenen Verbindungen nur eine Form, die trans-Konfiguration, bekannt. In den α,α′-Chlor-brom-cyclo-alkanonen nimmt Brom die quasi-axiale, Chlor die quasi-äquatoriale Konformation ein.
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  • 64
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 105-109 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ω-Diazofettsäureester lagern sich an die Dreifachbindungen von Acetylendicarbonester, Propiolsäureester, Phenylpropiolsäureester und Phenylpropargylaldehyddimethylacetal unter Bildung der entsprechend substituierten Pyrazole an.
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  • 65
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 142-148 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus 7α-Brom-cholestan-3β-ol-6-on-acetat entsteht bei der Umsetzung mit Natriumazid 7β-Azido-cholestan-3β-ol-6-on-acetat. Dieses wird durch Hydrazinhydrat/Raney-Nickel zum Aminoketon und durch Natriumborhydrid zum Azidoalkohol reduziert. Der Azidoalkohol kann durch Hydrazinhydrat/Raney-Nickel weiter reduziert werden zum Aminoalkohol. Die funktionellen Gruppen an C6 and C7 haben β-Konfiguration.
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  • 66
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 166-174 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch säurekatalysierte Kondensation von β-Ketoaldehyden und β-Diketonen mit o-Phenylendiamin werden 2,3- und 2,3,4-substituierte 1,5-Benzodiazepine hergestellt. Die Umsetzung versagt bei β-Ketoaldehyden, deren Ketogruppe mit einem Benzolkern konjugiert ist. Es werden dann lediglich Monokondensationsprodukte isoliert, die im Gegensatz zu den aus alkyl- oder benzylsubstituierten β-Ketoaldehyden und o-Phenylendiamin in neutraler Lösung gebildeten analogen Kondensationsprodukten nicht cyclisiert werden können.
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  • 67
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 68
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 225-235 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden die Absorptionsspektren einiger Derivate des Chinazolins, des Chinazolin-3-oxids und des an verschiedenen Stellen substituierten 1,2-Dihydrochinazolin-3-oxids im UV untersucht. Die Maxima wurden ausgemessen und die zugehörigen Hauptpolarisationsrichtungen angegeben. Für die 2-phenylsubstituierten Chinazolin-3-oxide wurde das Vorhandensein einer sterischen Hinderung zwischen der N→O-Gruppe und dem Benzolring des Substituenten bewiesen.
    Additional Material: 11 Ill.
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  • 69
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 271-283 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An monomeren Glyceriden, den Grundbausteinen nichtlinearer und ölmodifizierter Polyester mit ein, zwei und mehr Hydroxyl-bzw. Carboxylgruppen wurde das Assoziationsverhalten in den Lösungsmitteln Toluol und Diäthylketon in Abhängigkeit von der Anzahl der funktionellen Endgruppen und der Konzentration ebullioskopisch untersucht. Bei allen verwandten Glyceriden konnte eine lineare Abhängigkeit von Mgem. zu c festgestellt werden. Gleiche Verhältnisse ergaben sich bei der Messung des Assoziationsgrades für lineare und verzweigte Polester. Die Temperaturgenauigkeit der Messung betrug 1,5 · 10-5 °C.
    Additional Material: 4 Ill.
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  • 70
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 319-325 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Kondensation von Rutin, Formaldehyd oder anderen Aldehyden mit primären oder sekundären Basen bilden sich wasserlösliche Rutinderivate, denen die Konstitution von [8-Bis-(6-dialkylaminoalkyl-rutin)]-methanen zugeschrieben wird.
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  • 71
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 5-18 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: o-Aminobenzhydrole setzen sich bei Gegenwart von Mineralsäuren mit Mercapto-alkylsäuren zu Dihydrobenzothiazepinonen um. Es wird eine Reihe von Derivaten dieser neuen Körperklasse beschrieben.
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  • 72
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 42-49 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: PAP-amin erfährt durch Ansäuern eine Farbvertiefung von gelb nach rot. Die sauren Lösungen absorbieren bei 500 nm maximal. Bei den Aminosäure-PAP-amiden erfolgt der gleiche Übergang durch Ansäuern in wäßriger Lösung nur schwer, in schwächer polaren Lösungsmitteln dagegen leichter. Das Absorptionsmaximum im sauren Bereich liegt hier bei 470 nm. Die Rotfärbung der Aminosäure-PAP-amide in saurer Lösung sowie die ebenfalls rote Farbe der Aminosäure-PAP-amid-hydrobromide wird auf eine durch Protonisierung an der Azogruppe stabilisierte chinoide Struktur zurückgeführt.
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  • 73
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 86-91 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Anlagerung von Isocyanaten an die NH-Gruppe von Oxaziridinen werden Aminoformyl-oxaziridine hergestellt. Amine greifen den Ringstickstoff dieser Oxaziridine an und geben in guten Ausbeuten Semicarbazide. Entsprechend reagiert Piperidin mit 2-p-Nitrobenzoyl-3-phenyl-oxaziridin unter N—N-Knüpfung zu einem Säurehydrazid. 2-Anilinoformyl-3-phenyl-oxaziridin lagert sich beim Erwärmen in Phenylaminoformyl-benzaldoxim um.
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  • 74
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 113-125 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In dieser Arbeit wird die Synthese der in 1-Stellung durch funktionelle Gruppen substituierten 7-Amino-, 7-Hydroxy- und 7-Mercapto-benzimidazole beschrieben. Es konnten Darstellungsmethoden gefunden werden, die es gestatten, vom 7-Aminobenzimidazol ausgehend, das 7-Hydroxybenzimidazol und das bisher nicht bekannte 7-Mercaptobenzimidazol aus den gleichen Grundsubstanzen zu erhalten.Außerdem konnten im Verlauf der Untersuchungen drei neue heterocyclische Ringsysteme erhalten werden, welche als Piperazino-(hi),-benzimidazol, Hexahydro-1,4-diazepino-(hi)-benzimidazol und Thiamorpholino-(hi)-benzimidazol zu bezeichnen sind3).
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  • 75
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 153-159 
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Synthese des Menthonsemicarbazons und dessen säurekatalytische Spaltung ist von Isomerisierungserscheinungen begleitet, die durch Dünnschicht-Chromatographie festgestellt werden können.
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  • 76
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 180-196 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: β-Nitrosoäther fragmentieren bei Einwirkung starker Säuren unter Bildung von Carbonylverbindungen und Oximen. Die Fragmentierung geht von den monomeren Nitrosoäthern, die in einigen Fällen daneben ablaufende Eliminierung geht von den Bisnitrosoäthern aus. Auch β-Nitrosoamine, β-Chlornitrosoverbindungen und β-alkylierte Nitrosoverbindungen können unter Fragmentierung reagieren.
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  • 77
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 230-237 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Investigations were carried out to ó-hydroxylate the monohydroxy azo types (I) and (II) respectively in different solvents, under varied conditions. A new continuous procedure for ó-hydroxylation is described.The influence of introduction of ó-hydroxyl group and annullation in compounds (I-IV) on the wave length at maximum absorptions is also described.
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  • 78
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 256-259 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Seventeen new condensation products of 2-amino dibenzothiophene with several alkyl and aryl isothiocyanates and eight new substituted amidines with 2-dibenzothiophenyl and 2-dibenzothiophenyl-5-dioxide substituents have been prepared with a view to study their antiviral and tuberculostatic activity.
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  • 79
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 280-286 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Synthese einiger N-Allyliminodialkylnitrile bzw. deren Halogenderivate beschrieben.N-Allyliminodialkylnitrile wurden bei der Umsetzung von Allylamin und Chloracetonitril bzw. β-Chlorpropionitril in Gegenwart von BaCO3 bzw. K2CO3 als HCl-Acceptoren erhalten.Durch Einleiten gasförmiger Halogenwasserstoffe in N-Allyliminodialkylnitrile dargestellt.Die Verseifung von N-Allyliminodiacetonitril führte zur N-Allyliminodiessigsäure.
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  • 80
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 311-313 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Synthese von α-Methyl-[theophyllinyl-(7)]-alanin von 7-Acetonyl-theophyllin aus über das 5-Methyl-5-[theophyllinyl-(7)]-methyl-hydantoin beschrieben.
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  • 81
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 36-40 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of some hittherto unknown chromone and flavone-7-carboxylic acids is reported.
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  • 82
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 236-248 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die relativen Autoxydationsgeschwindigkeiten der cis/trans-Isomeren von Decalin, 1,2-Dimethylcyclohexan und 1,3-Dimethylcyclohexan wurden durch Konkurrenzreaktion mit Sauerstoff bei 105-130° bestimmt. Tertiäre C—H-Bindungen in äquatorialer Stellung werden leichter angegriffen als solche in axialer Stellung; ke: ka liegt zwischen 2,0 und 2,5.Für 34 repräsentative Kohlenwasserstoffe wurden die relativen Reaktionsgeschwindigkeiten nach der Methode der Konkurrenzreaktion ermittelt.
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  • 83
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 41-48 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1,2-Diketone I werden bei der basenkatalysierten Einwirkung von H2S unter schonenden Bedingungen spezifisch zu α-Hydroxyketonen II bzw. Monoketonen III reduziert. Der für das Benzil (Ia) gültige Reduktionsmechanismus ist nicht verallgemeinerungsfähig. α-Oxo-caronsäureester unterliegen ebenfalls der Reduktion, während Carbonsäurean-hydride in Thiocarbonsäureanhydride übergehen. Das bisher unbekannte Thiomaleinsäureanhydrid ist auch auf diesem Wege nicht synthetisierbar.
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  • 84
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Isotherme Flüssigkeit-Dampf-Gleichgewichte der binären flüssigen Systeme Benzol-Dioxan, Benzol-Diäthylformamid und Dioxan-Diäthylformamid wurden im Temperaturbereich zwischen 30 und 60°C nach der dynamischen Methode gemessen. Die Auswertung der Meßdaten erfolgte bis zu den korrigierten Aktivitätskoeffizienten bzw. molaren freien Zusatzenthalpien. Thermodynamische Konsistenz der Ergebnisse konnte nachgewiesen werden.
    Additional Material: 3 Ill.
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  • 85
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 70-72 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Im Zusammenhang mit unseren Arbeiten auf dem Gebiet der anorganischen Stickstoffverbindungen wurde eine Methode zur Bestimmung von Hyponitrit, Nitrit, Nitrat und Nitrohydroxylaminat nebeneinander ausgearbeitet. Die einzelnen Anionen können dabei im Gemisch in einem Konzentrationsbereich von 2-20 mg vorliegen. Die Methode liefert reproduzierbare Werte, die im Bereich von 4-20 mg einem mittleren Fehler von ±1.5% behaftet sind. Außerdem wird eine modifizierte chromatometrische Methode zur quantitativen Bestimmung von Nitrat beschrieben.
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  • 86
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 110-112 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2,4,6-Trimethoxyanilin (II) kann bequem durch katalytische Hydrierung von 2,4,6-Trimethoxy-nitrobenzol (I) gewonnen werden. Diese bisher schwer zugängliche Nitroverbindung ist in sehr guter Ausbeute durch Methylierung von Nitrophloroglucin mit Dimethylsulfat-Natronlauge unter kontrollierten Bedingungen (pH 8-9) zugänglich.
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  • 87
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 122-130 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis, some dyeing, and fastness properties of several new dispersed, acid, and direct dyes derived from the aminobenzotriazoles (I-IV) and 5-hydroxybenzotriazole (V) are described. The suitability of the amino derivatives (I-IV) as bases for azoic dyeing has also been studied. Several interesting observations between the properties of some synthesized dyes and the corresponding benzene or naphthalene analoges are cited.
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  • 88
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    Journal für Praktische Chemie/Chemiker-Zeitung 35 (1967), S. 113-117 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden Trennversuche der Halogenidionen am stark basischen Anionenaustauscher WOFATIT SBW durchgeführt. Für die Harzbelegung und Elution dienten Nitrat-, Nitrit-und Oxalat-Lösungen. Die Auswahl dieser Anionen erfolgte auf Grund ihrer für die Elutionschromatographie der Halogenide günstigen relativen Affinitätswerte innerhalb der von uns aufgestellten Anionen-Affinitätsreihe zum verwendeten Austauscher1). Die quantitative Trennung aller vier Halogenide gelingt in einem Arbeitsgang mit einer 1 n Natrium-nitratlösung bei einer Säulenfüllung von 150 cm Höhe, wobei die Anionen Fluorid, Chlorid, Bromid und Jodid in der angegebenen Reihenfolge im Eluat erscheinen. Der Trenneffekt bei den Ionenpaaren Fluorid-Chlorid bzw. Chlorid-Bromid kann mit Hilfe von Oxalat-bzw. Nitrit-Lösungen noch wesentlich gesteigert werden.
    Additional Material: 4 Ill.
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  • 89
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 92-100 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mit Hilfe einer speziell ausgearbeiteten Methodik der gaschromatographischen Analyse für Gemische von isomeren aromatischen Kohlenwasserstoffen wurde das Verhalten der Karbeniumionen bei der schwefelsauren Alkylierung von Benzol mit allen vierzehn Propyl-, Butyl-, Pentylalkoholen und einigen Hexylalkoholen untersucht. Unter den Bedingungen der schwefelsauren Alkylierung des Benzols (80proz. Schwefelsäure, 80°C) werden alle primären Karbeniumionen C3H7+ bis C5H11+ praktisch vollständig isomerisiert. Die Skelettisomerisierung ist unter den Bedingungen der schwefelsauren Alkylierung sehr verbreitet und kann sowohl zu einer Verzweigung als auch zu einem Ausrichten der Kohlenstoffkette führen. Parallel mit der Isomerisierung sind alle verzweigten Karbeniumionen C5H11+—C6H13+ einer bemerkenswerten Fragmentierung unterworfen.
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  • 90
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 126-137 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A detailed study on the composition, stability and analytical applications of Rare Earth chelates with Aluminon, Chrome Azurol S, Thoron, Chromotrope 2B and Alizarin Red S have been described. The composition have been ascertained spectrophotometrically using the Method of Continuous Variations, Mole Ratio Method and the Slope Ratio Method. The range for adherence to BEER'S law, sensitivity and other optimum conditions required in the analytical applications have been described.
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  • 91
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    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 160-164 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung der Pyridin-3-sulfosäure, ihres Säurechlorids und des Pyridin-3-thiols mittels neuer bzw. überarbeiteter Methoden wird beschrieben.
    Type of Medium: Electronic Resource
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  • 92
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 197-201 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Zehn Azoxyalkane wurden durch selektive Hydrierung der entsprechenden Bisnitrosoverbindungen, teilweise auch durch Oxydation der Azoalkane mit Benzopersäure hergestellt. Die Zersetzung der sekundären Azoxyalkane mit Salzsäure lieferte Ketazine, die primären Azoxyalkane wurden zu Acyl-alkylhydrazinen umgelagert. Die Methanolyseprodukte wurden identifiziert und quantitativ bestimmt.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
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  • 93
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 238-245 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eine von C. K. Bradsher et al. ausgearbeitete Methode zur Darstellung kurzkettiger 9,10-Dialkylphenanthrene wurde auf den Molekulargewichtsbereich 400-600 ausgedehnt und 9,10-Dinonylphenanthren, 9-Nonyl-10-tetradecylphenanthren sowie 9,10-Ditetradecylphenanthren dargestellt. Von diesen Substanzen sowie deren Vorstufen, den α-Alkyl-α-(o-xenyl)-acetonitrilen und den α-(o-xenyl)-Ketonen sind Ausbeuten, Schmelzpunkte, Dichten, Viskositäten und die Ergebnisse der Elementaranalyse angegeben. Die IR-Spektren der genannten Verbindungen werden interpretiert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 94
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: With a view to study their antiviral and antitubercular activity, ten new 4-aryl substituted thiosemicarbazones of 2-formyl benzofuran and 4-methoxy naphthaldehyde have been prepared. The preparation of sixteen new hydrazones of 3-aryl, thiazolidine-2,4-dione and 5-carboxymethyl-3-aryl, thiazolidine-2,4-dione and ten new substituted guanidines has also been accomplished from these thiosemicarbazones.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 95
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 36 (1967), S. 287-303 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die UV-S-Absorptionsspektren von 36 2H-1,3-Dithiol-2-thionen wurden in einem Bereich von 215-500 mμ in verschiedenen Lösungsmitteln gemessen. Einige Banden sind zur Identifizierung dieser Verbindungsklasse brauchbar. Der Einfluß von Substituenten auf die Absorptionen wurde diskutiert und die längstwelligen intensiven Absorptionen wurden HMO-Indices gegenübergestellt.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 96
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The adducts of benzoyl chlorides p-substituted by CH3O—, CH3—, and H— with the electronic acceptors SbCl5 and TiCl4 have been prepared, and the IR. absorption spectra of the solid products studied.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 97
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Extracts from the seeds of Strophanthus gratus showed the presence of 30 cardenolides after being subjected mainly to techniques of preparative separation and partly through acetylation of these concentrates. These 30 cardenolides have been differentiated from one another by paper chromatography in five solvent systems. Among the identified cardenolides were most of the compounds isolated earlier by Jäger et al. [1]. In accordance with the results of these authors, ouabain (ca. 7%) was by far the predominant constituent, followed by acolongifloroside K (ca. 0.4%) and strogoside (0.4%). These three compounds have been isolated in crystalline form. Strogoside (structure elucidation see following paper) is a new name for the compound K described by JÄGER et al. Of the compounds present in trace amounts, only sarmentoside E was isolated in crystalline form directly, and the new compound λ after acetylation, which yielded O-acetyl-λ. The compound λ seems to be a dilactone with a structure similar to that of strogoside but containing rhamnose as the sugar and an aglycone probably different from strogogenin.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 98
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of the 7α-methyl homologues of estrone, estradiol, 17α-methyl- and 17α-ethinyl-estradiol, and of the respective 3-methyl ethers is described. Their estrogenic activity is compared with that of the corresponding unmethylated compounds.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 50 (1967), S. 319-321 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: On treatment of styrolene between 30 and 40°C with performic acid, phenylglycol monoformate is produced.
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 50 (1967), S. 347-347 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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