Library

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • 2005-2009  (43)
  • 2000-2004  (2)
  • 1960-1964
  • 1955-1959  (515)
  • 1950-1954
  • 1935-1939
  • 1900-1904
  • 1890-1899  (197)
  • 1830-1839  (593)
  • 2008  (41)
  • 2006  (2)
  • 2004  (1)
  • 2003  (1)
  • 1957  (515)
  • 1907
  • 1905
  • 1895  (197)
  • 1836  (593)
  • Organic Chemistry  (1,305)
  • ddc:510  (45)
Material
Years
  • 2005-2009  (43)
  • 2000-2004  (2)
  • 1960-1964
  • 1955-1959  (515)
  • 1950-1954
  • +
Year
Language
  • 1
    Publication Date: 2020-08-05
    Description: Das heutige Leben ist durchdrungen von komplexen Technologien. Ohne Kommunikationsnetze, Internet, Mobilfunk, Logistik, Verkehrstechnik, medizinische Apparate, etc. könnte die moderne Gesellschaft nicht funktionieren. Fast alle dieser Technologien haben einen hohen Mathematikanteil. Der "normale Bürger"' weiss davon nichts, der Schulunterricht könnte dem ein wenig abhelfen. Einige mathematische Aspekte dieser Technologien sind einfach und sogar spielerisch intuitiv zugänglich. Solche Anwendungen, die zusätzlich noch der Lebensumwelt der Schüler zugehören, können dazu genutzt werden, die mathematische Modellierung, also die mathematische Herangehensweise an die Lösung praktischer Fragen, anschaulich zu erläutern. Gerade in der diskreten Mathematik können hier, quasi "nebenbei" mathematische Theorien erarbeitet und Teilaspekte (Definitionen, Fragestellungen, einfache Sachverhalte) durch eigenständiges Entdecken der Schüler entwickelt werden. Wir beginnen mit einigen Beispielen.
    Keywords: ddc:510
    Language: German
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    facet.materialart.
    Unknown
    Publication Date: 2020-08-05
    Description: Den kürzesten Weg in einem Graphen zu finden ist ein klassisches Problem der Graphentheorie. Über einen Vortrag zu diesem Thema beim Tag der Mathematik 2007 von R. Borndörfer kam ich in Kontakt mit dem Konrad-Zuse-Zentrum (ZIB), das sich u.a. mit Wegeoptimierung beschäftigt. Ein Forschungsschwerpunkt dort ist im Rahmen eines Projekts zur Chipverifikation das Zählen von Lösungen, das, wie wir sehen werden, eng mit dem Zählen von Wegen zusammenhängt. Anhand von zwei Fragen aus der Graphentheorie soll diese Facharbeit unterschiedliche Lösungsmethoden untersuchen. Wie bestimmt man den kürzesten Weg zwischen zwei Knoten in einem Graphen und wie findet man alle möglichen Wege? Nach einer Einführung in die Graphentheorie und einer Konkretisierung der Probleme wird zunächst für beide eine Lösung mit auf Graphen basierenden Algorithmen vorgestellt. Während der Algorithmus von Dijkstra sehr bekannt ist, habe ich für das Zählen von Wegen einen eigenen Algorithmus auf der Basis der Tiefensuche entwickelt. Im zweiten Teil der Arbeit wird das Konzept der ganzzahligen Programmierung vorgestellt und die Lösungsmöglichkeiten für Wegeprobleme, die sich darüber ergeben. Schließlich wurden die vorgestellten Algorithmen am Beispiel des S- und U-Bahnnetzes von Berlin implementiert und mit Programmen, die die gleichen Fragen über ganzzahlige Programmierung lösen, verglichen.
    Keywords: ddc:510
    Language: German
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2016-06-09
    Description: This paper is intended to be a first step towards the continuous dependence of dynamical contact problems on the initial data as well as the uniqueness of a solution. Moreover, it provides the basis for a proof of the convergence of popular time integration schemes as the Newmark method. We study a frictionless dynamical contact problem between both linearly elastic and viscoelastic bodies which is formulated via the Signorini contact conditions. For viscoelastic materials fulfilling the Kelvin-Voigt constitutive law, we find a characterization of the class of problems which satisfy a perturbation result in a non-trivial mix of norms in function space. This characterization is given in the form of a stability condition on the contact stresses at the contact boundaries. Furthermore, we present perturbation results for two well-established approximations of the classical Signorini condition: The Signorini condition formulated in velocities and the model of normal compliance, both satisfying even a sharper version of our stability condition.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 2020-08-05
    Description: Most data networks nowadays use shortest path protocols to route the traffic. Given administrative routing lengths for the links of the network, all data packets are sent along shortest paths with respect to these lengths from their source to their destination. In this paper, we present an integer programming algorithm for the minimum congestion unsplittable shortest path routing problem, which arises in the operational planning of such networks. Given a capacitated directed graph and a set of communication demands, the goal is to find routing lengths that define a unique shortest path for each demand and minimize the maximum congestion over all links in the resulting routing. We illustrate the general decomposition approach our algorithm is based on, present the integer and linear programming models used to solve the master and the client problem, and discuss the most important implementational aspects. Finally, we report computational results for various benchmark problems, which demonstrate the efficiency of our algorithm.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2020-12-15
    Description: This paper introduces the "line connectivity problem", a generalization of the Steiner tree problem and a special case of the line planning problem. We study its complexity and give an IP formulation in terms of an exponential number of constraints associated with "line cut constraints". These inequalities can be separated in polynomial time. We also generalize the Steiner partition inequalities.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2020-08-05
    Description: Testing is the process of stimulating a system with inputs in order to reveal hidden parts of the system state. In the case of non-deterministic systems, the difficulty arises that an input pattern can generate several possible outcomes. Some of these outcomes allow to distinguish between different hypotheses about the system state, while others do~not. In this paper, we present a novel approach to find, for non-deterministic systems modeled as constraints over variables, tests that allow to distinguish among the hypotheses as good as possible. The idea is to assess the quality of a test by determining the ratio of distinguishing (good) and not distinguishing (bad) outcomes. This measure refines previous notions proposed in the literature on model-based testing and can be computed using model counting techniques. We propose and analyze a greedy-type algorithm to solve this test optimization problem, using existing model counters as a building block. We give preliminary experimental results of our method, and discuss possible improvements.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 7
    Publication Date: 2021-08-05
    Description: Starting with the description of the Traveling Salesmen Problem formulation as given by van Vyve and Wolsey in the article Approximate extended formulations'', we investigate the effects of small variations onto the performance of contemporary mixed integer programming solvers. We will show that even minor changes in the formulation of the model can result in performance difference of more than a factor of 1000. As the results show it is not obvious which changes will result in performance improvements and which not.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2022-03-14
    Description: Orbitopes can be used to handle symmetries which arise in integer programming formulations with an inherent assignment structure. We investigate the detection of symmetries appearing in this approach. We show that detecting so-called orbitopal symmetries is graph-isomorphism hard in general, but can be performed in linear time if the assignment structure is known.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 9
    Publication Date: 2019-01-29
    Description: Regional hyperthermia is a cancer therapy aiming at heating tumors using phased array applicators. This article provides an overview over current mathematical challenges of delivering individually optimal treatments. The focus is on therapy planning and identification of technical as well as physiological quantities from MR thermometry measurements.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2019-05-10
    Description: Reasons for the failure of adaptive methods to deliver improved efficiency when integrating monodomain models for myocardiac excitation are discussed. Two closely related techniques for reducing the computational complexity of linearly implicit integrators, deliberate sparsing and splitting, are investigated with respect to their impact on computing time and accuracy.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 11
    facet.materialart.
    Unknown
    Publication Date: 2020-08-05
    Description: We investigate the computation of periodic timetables for public transport by mixed integer programming. After introducing the problem, we describe two mathematical models for periodic timetabling, the PERIODIC EVENT SCHEDULING PROBLEM (PESP) and the QUADRATIC SEMI-ASSIGNMENT PROBLEM. Specifically, we give an overview of existing integer programming (IP) formulations for both models. An important contribution of our work are new IP formulations for the PESP based on time discretization. We provide an analytical comparison of these formulations and describe different techniques that allow a more efficient solution by mixed integer programming. In a preliminary computational study, on the basis of standard IP solvers, we compare different formulations for computing periodic timetables. Our results justify a further investigation of the time discretization approach. Typically the timetable is optimized for the current traffic situation. The main difficulty with this approach is that after introducing the new timetable the passengers’ travel behavior may differ from that assumed for the computation. Motivated by this problem, we examine an iterative timetabling procedure that is a combination of timetable computation and passenger routing. We discuss the algorithmic issues of the passenger routing and study properties of the computed timetables. Finally, we confirm our theoretical results on the basis of an own implementation.
    Description: Wir untersuchen die Berechnung von Taktfahrplänen für den öffentlichen Verkehr mit gemischt-ganzzahliger Programmierung (MIP). Im Anschluss an die Problembeschreibung, stellen wir zwei mathematische Modellierungen vor, das PERIODIC EVENT SCHEDULING PROBLEM (PESP) und das QUADRATIC SEMI-ASSIGNMENT PROBLEM. Wichtiger Bestandteil ist ein Überblick über existierende ganzzahlige Formulierungen beider Modelle. Wir entwickeln neue ganzzahlige Formulierungen für das PESP auf der Basis von Zeitdiskretisierung. Diese werden analytisch miteinander verglichen und wir beschreiben verschiedene Techniken, die eine effizientere Lösung der Formulierungen mit gemischt-ganzzahliger Programmierung ermöglichen. In einer ersten Rechenstudie, unter Verwendung gängiger MIP-Löser, vergleichen wir verschiedene ganzzahlige Formulierungen zur Berechnung von Taktfahrplänen. Unsere Ergebnisse rechtfertigen eine weitere Untersuchung des Zeitdiskretisierungsansatzes. In der Regel werden Fahrpläne mit Bezug auf die gegenwärtige Verkehrssituation optimiert. Dies birgt jedoch folgendes Problem. Wenn der neue Fahrplan eingeführt wird, ist es möglich, dass die Passagiere ein anderes Fahrverhalten zu Tage legen, als für die Berechnung des Fahrplans angenommen wurde. Vor diesem Hintergrund behandeln wir ein iteratives Verfahren zur Berechnung von Taktfahrplänen. Dieses ist eine Kombination aus Fahrplanberechnung und Passagierrouting. Neben den algorithmischen Details des Passagierroutings untersuchen wir Eigenschaften der berechneten Fahrpläne. Abschließend bestätigen wir unsere theoretischen Ergebnisse auf Grundlage einer eigenen Implementierung des Verfahrens.
    Keywords: ddc:510
    Language: English
    Type: masterthesis , doc-type:masterThesis
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 12
    Publication Date: 2020-08-05
    Description: This paper describes several experiments to explore the options for solving a class of mixed integer nonlinear programming problems that stem from a real-world mine production planning project. The only type of nonlinear constraints in these problems are bilinear equalities involving continuous variables, which enforce the ratios between elements in mixed material streams. A branch-and-bound algorithm to handle the integer variables has been tried in another project. However, this branch-and-bound algorithm is not effective for handling the nonlinear constraints. Therefore state-of-the-art nonlinear solvers are utilized to solve the resulting nonlinear subproblems in this work. The experiments were carried out using the NEOS server for optimization. After finding that current nonlinear programming solvers seem to lack suitable preprocessing capabilities, we preprocess the instances beforehand and use an heuristic approach to solve the nonlinear subproblems. In the appendix, we explain how to add a polynomial constraint handler that uses IPOPT as embedded nonlinear programming solver for the constraint programming framework SCIP. This is one of the crucial steps for implementing our algorithm in SCIP. We briefly described our approach and give an idea of the work involved.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 13
    Publication Date: 2020-08-05
    Description: Dieser kurze Aufsatz zur Algorithmengeschichte ist Eberhard Knobloch, meinem Lieblings-Mathematikhistoriker, zum 65. Geburtstag gewidmet. Eberhard Knobloch hat immer, wenn ich ihm eine historische Frage zur Mathematik stellte, eine Antwort gewusst – fast immer auch sofort. Erst als ich mich selbst ein wenig und dazu amateurhaft mit Mathematikgeschichte beschäftigte, wurde mir bewusst, wie schwierig dieses „Geschäft“ ist. Man muss nicht nur mehrere (alte) Sprachen beherrschen, sondern auch die wissenschaftliche Bedeutung von Begriffen und Symbolen in früheren Zeiten kennen. Man muss zusätzlich herausfinden, was zur Zeit der Entstehung der Texte „allgemeines Wissen“ war, insbesondere, was seinerzeit gültige Beweisideen und -schritte waren, und daher damals keiner präzisen Definition oder Einführung bedurfte. Es gibt aber noch eine Steigerung des historischen Schwierigkeitsgrades: Algorithmengeschichte. Dies möchte ich in diesem Artikel kurz darlegen in der Hoffnung, dass sich Wissenschaftshistoriker dieses Themas noch intensiver annehmen, als sie das bisher tun. Der Grund ist, dass heute Algorithmen viele Bereiche unserer Alltagswelt steuern und unser tägliches Leben oft von funktionierenden Algorithmen abhängt. Daher wäre eine bessere Kenntnis der Algorithmengeschichte von großem Interesse.
    Keywords: ddc:510
    Language: German
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 14
    Publication Date: 2016-06-09
    Description: We consider first order optimality conditions for state constrained optimal control problems. In particular we study the case where the state equation has not enough regularity to admit existence of a Slater point in function space. We overcome this difficulty by a special transformation. Under a density condition we show existence of Lagrange multipliers, which have a representation via measures and additional regularity properties.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 15
    Publication Date: 2016-06-09
    Description: The enormous time lag between fast atomic motion and complex pro- tein folding events makes it almost impossible to compute molecular dy- namics on a high resolution. A common way to tackle this problem is to model the system dynamics as a Markov process. Yet for large molec- ular systems the resulting Markov chains can hardly be handled due to the curse of dimensionality. Coarse graining methods can be used to re- duce the dimension of a Markov chain, but it is still unclear how far the coarse grained Markov chain resembles the original system. In order to answer this question, two different coarse-graining methods were analysed and compared: a classical set-based reduction method and an alternative subspace-based approach, which is based on membership vectors instead of sets. On the basis of a small toy system, it could be shown, that in con- trast to the subset-based approach, the subspace-based reduction method preserves the Markov property as well as the essential dynamics of the original system.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 16
    Publication Date: 2021-02-19
    Description: Line planning is an important step in the strategic planning process of a public transportation system. In this paper, we discuss an optimization model for this problem in order to minimize operation costs while guaranteeing a certain level of quality of service, in terms of available transport capacity. We analyze the problem for path and tree network topologies as well as several categories of line operation that are important for the Quito Trolebus system. It turns out that, from a computational complexity worst case point of view, the problem is hard in all but the most simple variants. In practice, however, instances based on real data from the Trolebus System in Quito can be solved quite well, and significant optimization potentials can be demonstrated.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 17
    Publication Date: 2020-08-05
    Description: It is well known that competitive analysis yields too pessimistic results when applied to the paging problem and it also cannot make a distinction between many paging strategies. Many deterministic paging algorithms achieve the same competitive ratio, ranging from inefficient strategies as flush-when-full to the good performing least-recently-used (LRU). In this paper, we study this fundamental online problem from the viewpoint of stochastic dominance. We show that when sequences are drawn from distributions modelling locality of reference, LRU is stochastically better than any other online paging algorithm.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 18
    Publication Date: 2020-12-15
    Description: Die Angebotsplanung im öffentlichen Nahverkehr umfasst die Aufgaben der Netz-, Linien-,Fahr- und Preisplanung. Wir stellen zwei mathematische Optimierungsmodelle zur Linien- und Preisplanung vor. Wir zeigen anhand von Berechnungen für die Verkehrsbetriebe in Potsdam(ViP), dass sich damit komplexe Zusammenhänge quantitativ analysieren lassen. Auf diese Weise untersuchen wir die Auswirkungen von Freiheitsgraden auf die Konstruktion von Linien und die Wahl von Reisewegen der Passagiere, Abhängigkeiten zwischen Kosten und Reisezeiten sowie den Einfluss verschiedener Preissysteme auf Nachfrage und Kostendeckung.
    Keywords: ddc:510
    Language: German
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 19
    Publication Date: 2022-03-14
    Description: This article introduces constraint integer programming (CIP), which is a novel way to combine constraint programming (CP) and mixed integer programming (MIP) methodologies. CIP is a generalization of MIP that supports the notion of general constraints as in CP. This approach is supported by the CIP framework SCIP, which also integrates techniques from SAT solving. SCIP is available in source code and free for non-commercial use. We demonstrate the usefulness of CIP on two tasks. First, we apply the constraint integer programming approach to pure mixed integer programs. Computational experiments show that SCIP is almost competitive to current state-of-the-art commercial MIP solvers. Second, we employ the CIP framework to solve chip design verification problems, which involve some highly non-linear constraint types that are very hard to handle by pure MIP solvers. The CIP approach is very effective here: it can apply the full sophisticated MIP machinery to the linear part of the problem, while dealing with the non-linear constraints by employing constraint programming techniques.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 20
    Publication Date: 2016-06-09
    Description: An extended mathematical framework for barrier methods for state constrained optimal control compared to [Schiela, ZIB-Report 07-07] is considered. This allows to apply the results derived there to more general classes of optimal control problems, in particular to boundary control and finite dimensional control.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 21
    Publication Date: 2021-08-05
    Description: In the recent years there has been tremendous progress in the development of algorithms to find optimal solutions for integer programs. In many applications it is, however, desirable (or even necessary) to generate all feasible solutions. Examples arise in the areas of hardware and software verification and discrete geometry. In this paper, we investigate how to extend branch-and-cut integer programming frameworks to support the generation of all solutions. We propose a method to detect so-called unrestricted subtrees, which allows us to prune the integer program search tree and to collect several solutions simultaneously. We present computational results of this branch-and-count paradigm which show the potential of the unrestricted subtree detection.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 22
    Publication Date: 2020-08-05
    Description: Edmonds showed that the so-called rank inequalities and the nonnegativity constraints provide a complete linear description of the matroid polytope. By essentially adding Grötschel's cardinality forcing inequalities, we obtain a complete linear description of the cardinality constrained matroid polytope which is the convex hull of the incidence vectors of those independent sets that have a feasible cardinality. Moreover, we show how the separation problem for the cardinality forcing inequalities can be reduced to that for the rank inequalities. We also give necessary and sufficient conditions for a cardinality forcing inequality to be facet defining.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 23
    Publication Date: 2020-08-05
    Description: The paper describes a method for solution of very large overdetermined algebraic polynomial systems on an example that appears from a classification of all integrable 3-dimensional scalar discrete quasilinear equations $Q_3=0$ on an elementary cubic cell of the lattice ${\mathbb Z}^3$. The overdetermined polynomial algebraic system that has to be solved is far too large to be formulated. A probing' technique which replaces independent variables by random integers or zero allows to formulate subsets of this system. An automatic alteration of equation formulating steps and equation solving steps leads to an iteration process that solves the computational problem.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 24
    Publication Date: 2020-08-05
    Description: An algorithmic method using conservation law multipliers is introduced that yields necessary and sufficient conditions to find invertible mappings of a given nonlinear PDE to some linear PDE and to construct such a mapping when it exists. Previous methods yielded such conditions from admitted point or contact symmetries of the nonlinear PDE. Through examples, these two linearization approaches are contrasted.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 25
    Publication Date: 2021-02-26
    Description: We classify all integrable 3-dimensional scalar discrete affine linear equations $Q_3=0$ on an elementary cubic cell of the lattice ${\mathbb Z}^3$. An equation $Q_3=0$ %of such form is called integrable if it may be consistently imposed on all $3$-dimensional elementary faces of the lattice ${\mathbb Z}^4$. Under the natural requirement of invariance of the equation under the action of the complete group of symmetries of the cube we prove that the only ontrivial(non-linearizable) integrable equation from this class is the well-known dBKP-system.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 26
    Publication Date: 2020-12-11
    Description: The article describes the online mathematics test {\tt http://lie.math.brocku.ca/mathtest}, its typical applications and experiences gathered.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 27
    Publication Date: 2020-08-05
    Description: We introduce (TTPlib), a data library for train timetabling problems that can be accessed at http://ttplib.zib.de. In version 1.0, the library contains data related to 50 scenarios. Most instances result from the combination of macroscopic railway networks and several train request sets for the German long distance area containing Hannover, Kassel and Fulda, short denoted by Ha-Ka-Fu. In this paper, we introduce the data concepts of TTPlib, describe the scenarios included in the library and provide a free visualization tool TraVis.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 28
    Publication Date: 2020-08-05
    Description: The purpose of this paper is twofold. An immediate practical use of the presented algorithm is its applicability to the parametric solution of underdetermined linear ordinary differential equations (ODEs) with coefficients that are arbitrary analytic functions in the independent variable. A second conceptual aim is to present an algorithm that is in some sense dual to the fundamental Euclids algorithm, and thus an alternative to the special case of a Gr\"{o}bner basis algorithm as it is used for solving linear ODE-systems. In the paper Euclids algorithm and the new dual version' are compared and their complementary strengths are analysed on the task of solving underdetermined ODEs. An implementation of the described algorithm is interactively accessible at http://lie.math.brocku.ca/crack/uode.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 29
    Publication Date: 2020-08-05
    Description: This paper proposes a new method for probabilistic analysis of online algorithms that is based on the notion of stochastic dominance. We develop the method for the Online Bin Coloring problem introduced by Krumke et al. Using methods for the stochastic comparison of Markov chains we establish the strong result that the performance of the online algorithm GreedyFit is stochastically dominated by the performance of the algorithm OneBin for any number of items processed. This result gives a more realistic picture than competitive analysis and explains the behavior observed in simulations.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 30
    Publication Date: 2020-12-15
    Description: The optimization of fare systems in public transit allows to pursue objectives such as the maximization of demand, revenue, profit, or social welfare. We propose a non-linear optimization approach to fare planning that is based on a detailed discrete choice model of user behavior. The approach allows to analyze different fare structures, optimization objectives, and operational scenarios involving, e.g., subsidies. We use the resulting models to compute optimized fare systems for the city of Potsdam, Germany.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 31
    Publication Date: 2022-03-14
    Description: Pseudo-Boolean problems generalize SAT problems by allowing linear constraints and a linear objective function. Different solvers, mainly having their roots in the SAT domain, have been proposed and compared,for instance, in Pseudo-Boolean evaluations. One can also formulate Pseudo-Boolean models as integer programming models. That is,Pseudo-Boolean problems lie on the border between the SAT domain and the integer programming field. In this paper, we approach Pseudo-Boolean problems from the integer programming side. We introduce the framework SCIP that implements constraint integer programming techniques. It integrates methods from constraint programming, integer programming, and SAT-solving: the solution of linear programming relaxations, propagation of linear as well as nonlinear constraints, and conflict analysis. We argue that this approach is suitable for Pseudo-Boolean instances containing general linear constraints, while it is less efficient for pure SAT problems. We present extensive computational experiments on the test set used for the Pseudo-Boolean evaluation 2007. We show that our approach is very efficient for optimization instances and competitive for feasibility problems. For the nonlinear parts, we also investigate the influence of linear programming relaxations and propagation methods on the performance. It turns out that both techniques are helpful for obtaining an efficient solution method.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/pdf
    Format: application/postscript
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 32
    Publication Date: 2020-08-05
    Description: Millionen von Menschen werden allein in Deutschland täglich von Bussen, Bahnen und Flugzeugen transportiert. Der öffentliche Personenverkehr (ÖV) ist von großer Bedeutung für die Lebensqualität einzelner aber auch für die Leistungsfähigkeit ganzer Regionen. Qualität und Effizienz von ÖV-Systemen hängen ab von politischen Rahmenbedingungen (staatlich geplant, wettbewerblich organisiert) und der Eignung der Infrastruktur (Schienensysteme, Flughafenstandorte), vom vorhandenen Verkehrsangebot (Fahr- und Flugplan), von der Verwendung angemessener Technologien (Informations-, Kontroll- und Buchungssysteme) und dem bestmöglichen Einsatz der Betriebsmittel (Energie, Fahrzeuge und Personal). Die hierbei auftretenden Entscheidungs-, Planungs- und Optimierungsprobleme sind z.T. gigantisch und "schreien" aufgrund ihrer hohen Komplexität nach Unterstützung durch Mathematik. Dieser Artikel skizziert den Stand und die Bedeutung des Einsatzes von Mathematik bei der Planung und Durchführung von öffentlichem Personenverkehr, beschreibt die bestehenden Herausforderungen und regt zukunftsweisende Maßnahmen an.
    Keywords: ddc:510
    Language: German
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 33
    Publication Date: 2019-05-10
    Description: Pulse thermography of concrete structures is used in civil engineering for detecting voids, honeycombing and delamination. The physical situation is readily modeled by Fourier's law. Despite the simplicity of the PDE structure, quantitatively realistic numerical 3D simulation faces two major obstacles. First, the short heating pulse induces a thin boundary layer at the heated surface which encapsulates all information and therefore has to be resolved faithfully. Even with adaptive mesh refinement techniques, obtaining useful accuracies requires an unsatisfactorily fine discretization. Second, bulk material parameters and boundary conditions are barely known exactly. We address both issues by a semi-analytic reformulation of the heat transport problem and by parameter identification. Numerical results are compared with measurements of test specimens.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 34
    Publication Date: 2016-06-09
    Description: In this paper we are concerned with the application of interior point methods in function space to gradient constrained optimal control problems, governed by partial differential equations. We will derive existence of solutions together with first order optimality conditions. Afterwards we show continuity of the central path, together with convergence rates depending on the interior point parameter.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 35
    Publication Date: 2016-06-09
    Description: We consider an interior point method in function space for PDE constrained optimal control problems with state constraints. Our emphasis is on the construction and analysis of an algorithm that integrates a Newton path-following method with adaptive grid refinement. This is done in the framework of inexact Newton methods in function space, where the discretization error of each Newton step is controlled by adaptive grid refinement in the innermost loop. This allows to perform most of the required Newton steps on coarse grids, such that the overall computational time is dominated by the last few steps. For this purpose we propose an a-posteriori error estimator for a problem suited norm.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 36
    Publication Date: 2020-08-05
    Description: Ticket pricing in public transport usually takes a welfare or mnemonics maximization point of view. These approaches do not consider fairness in the sense that users of a shared infrastructure should pay for the costs that they generate. We propose an ansatz to determine fair ticket prices that combines concepts from cooperative game theory and integer programming. An application to pricing railway tickets for the intercity network of the Netherlands demonstrates that, in this sense, prices that are much fairer than standard ones can be computed in this way.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 37
    Publication Date: 2014-02-26
    Description: We present a second order sharp interface finite volume method for the solution of the three-dimensional poisson equation with variable coefficients on Cartesian grids. In particular, we focus on interface problems with discontinuities in the coefficient, the source term, the solution, and the fluxes across the interface. The method uses standard piecewiese trilinear finite elements for normal cells and a double piecewise trilinear ansatz for the solution on cells intersected by the interface resulting always in a compact 27-point stencil. Singularities associated with vanishing partial volumes of intersected grid cells are removed by a two-term asymptotic approach. In contrast to the 2D method presented by two of the authors in [M.~Oevermann, R.~Klein: A Cartesian grid finite volume method for elliptic equations with variable coefficients and embedded interfaces, J.~Comp.~Phys.~219 (2006)] we use a minimization technique to determine the unknown coefficients of the double trilinear ansatz. This simplifies the treatment of the different cut-cell types and avoids additional special operations for degenerated interface topologies. The resulting set of linear equations has been solved with a BiCGSTAB solver preconditioned with an algebraic multigrid. In various testcases -- including large coefficient ratios and non-smooth interfaces -- the method achieves second order of accuracy in the L_inf and L_2 norm.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 38
    Publication Date: 2020-08-05
    Description: Given a combinatorial optimization problem and a subset $N$ of natural numbers, we obtain a cardinality constrained version of this problem by permitting only those feasible solutions whose cardinalities are elements of $N$. In this paper we briefly touch on questions that addresses common grounds and differences of the complexity of a combinatorial optimization problem and its cardinality constrained version. Afterwards we focus on polytopes associated with cardinality constrained combinatorial optimization problems. Given an integer programming formulation for a combinatorial optimization problem, by essentially adding Grötschel's cardinality forcing inequalities, we obtain an integer programming formulation for its cardinality restricted version. Since the cardinality forcing inequalities in their original form are mostly not facet defining for the associated polyhedra, we discuss possibilities to strengthen them.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 39
    Publication Date: 2020-08-05
    Description: This survey concerns optimization problems arising in the design of survivable communication networks. It turns out that such problems can be modeled in a natural way as non-compact linear programming formulations based on multicommodity flow network models. These non-compact formulations involve an exponential number of path flow variables, and therefore require column generation to be solved to optimality. We consider several path-based survivability mechanisms and present results, both known and new, on the complexity of the corresponding column generation problems (called the pricing problems). We discuss results for the case of the single link (or node) failures scenarios, and extend the considerations to multiple link failures. Further, we classify the design problems corresponding to different survivability mechanisms according to the structure of their pricing problem. Finally, we show that almost all encountered pricing problems are hard to solve for scenarios admitting multiple failures.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 40
    Publication Date: 2021-02-19
    Description: We introduce an optimization model for the line planning problem in a public transportation system that aims at minimizing operational costs while ensuring a given level of quality of service in terms of available transport capacity. We discuss the computational complexity of the model for tree network topologies and line structures that arise in a real-world application at the Trolebus Integrated System in Quito. Computational results for this system are reported.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 41
    Publication Date: 2021-02-19
    Description: Line planning is an important step in the strategic planning process of a public transportation system. In this paper, we discuss an optimization model for this problem in order to minimize operation costs while guaranteeing a certain level of quality of service, in terms of available transport capacity. We analyze the problem for path and tree network topologies as well as several categories of line operation that are important for the Quito Trolebus system. It turns out that, from a computational complexity worst case point of view, the problem is hard in all but the most simple variants. In practice, however, instances based on real data from the Trolebus System in Quito can be solved quite well, and significant optimization potentials can be demonstrated.
    Keywords: ddc:510
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/pdf
    Format: application/postscript
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 42
    Publication Date: 2016-06-09
    Keywords: ddc:510
    Language: English
    Type: doctoralthesis , doc-type:doctoralThesis
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 43
    Publication Date: 2020-08-05
    Description: wird nachgereicht
    Keywords: ddc:510
    Language: English
    Type: doctoralthesis , doc-type:doctoralThesis
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 44
    Publication Date: 2020-08-05
    Description: This thesis deals with a Dial-a-Ride problem on trees and considers both offline and online versions of this problem. We study the behavior of certain algorithms on random instances, i.e. we do probabilistic analysis. The focus is on results describing the typical behavior of the algorithms, i.e. results holding with (asymptotically) high probability. For the offline version, we present a simplified proof of a result of Coja-Oghlan, Krumke und Nierhoff. The results states that some heuristic using a minimum spanning tree to approximate a Steiner tree gives optimal results with high probability. This explains why this heuristic produces optimal solutions quite often. In the second part, probabilistic online versions of the problem are introduced. We study the online strategies REPLAN and IGNORE. Regarding the IGNORE strategy we can show that it works almost optimal under high load with high probability.
    Keywords: ddc:510
    Language: English
    Type: masterthesis , doc-type:masterThesis
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 45
    Publication Date: 2020-08-05
    Description: All-optical telecommunication networks allow for switching connections by lightpaths which can pass several network links without any opto-electronic conversion. Upon arrival of a connection request, it must be decided online, i.e., without knowledge of future requests, if it is accepted and in that case on which lightpaths the connection is routed. This online problem with the goal of maximizing the total profit gained by accepted requests is called Dynamic Singleclass Call Admission Problem (DSCA). We present existing and new algorithms for the DSCA as well as their theoretical and practical evaluation.
    Keywords: ddc:510
    Language: English
    Type: masterthesis , doc-type:masterThesis
    Format: application/pdf
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 46
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 47
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 190-200 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird der Einfluß der Temperatur der reduzierenden Zersetzung von Nickel-Magnesiumformiat-Mischkristallen und Nickel-Magnesiumoxalat-Mischkristallen auf die Oberflächengröße und die katalytische Aktivität der so hergestellten Nickel-Magnesiumoxydkatalysatoren untersucht.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 48
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 177-178 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 49
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 179-189 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden Nachweisreaktionen für Pyrrole erprobt, die es ermöglichen, diese Körper auch in biologischem Material zu finden und zu trennen. Dabei erwiesen sich Isatin- und HgCl2-Verbindungen der Pyrrole als geeignet. Außerdem wurden Spektren der farbigen Kondensationsprodukte der Pyrrole und HgCl2-Verbindungen mit p-Dimethyl-aminozimtaldehyd ausgemessen, sowie die Pyrrole und deren Isatinverbindungen papierchromatographisch untersucht.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 50
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 236-240 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Einwirkung von Paraformaldehyd und Chlorwasserstoff auf einige 4-Alkoxyacetophenone wurden 2-Alkoxy-5-acetyl-benzylchloride glatt gewonnen. Aus letzteren konnten durch Umsetzungen die entsprechenden Aldehyde, Cyanide, Acetamide und Karbonsäuren erhalten werden.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 51
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 257-259 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus Diacetyl und Glycerin bildet sich das 2.3-Dimethyl-2.3-dioxy-6-methylol-dioxan-(1.4) (I). UV-Spektrum und Tri-[phenylurethan] von (I) bestätigen die Struktur des cyclischen Bis-halbacetals.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 52
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 278-285 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An ternären flüssigen Systemen, deren eine Komponente als Alkohol polaren Charakter besitzt, wird die Gültigkeit der CAILLETET-MATHIASschen Regel überprüft und versucht, die Dichten der gesättigten Lösungen von Alkohol und Kohlenwasserstoff aus den Dichten der einzelnen Komponenten zu berechnen. Die Additivität der Dichten einiger binärer Systeme bei 20° C ist angegeben. Sämtliche Messungen wurden zwischen 20 und 60° C durchgeführt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 53
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 319-323 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es wird über die Reduktion von seleniger Säure durch Karbonsäuren in Gegenwart von Kaliumpermanganat und Salzsäure berichtet. Die Versuchstemperaturen liegen bei 50 und 70° C. Es wird festgestellt, daß die Reduktion analog der von Goldchlorid verläuft.
    Notes: Reduction of selenous acid by certain carboxylic acids in presence of small quantities of KMnO4 has been studied. The observed enhanced reducing power of the carboxylic acids treated with KMnO4 towards selenous acid has been explained as being due to the formation of intermediate oxidation products of varying degree of stability, which strongly reduce selenous acid. In a few cases the presence of definite oxidation products has been indirectly proved. The results obtained are, in general, similar to those of gold chloride-carboxylic acid reactions studied by MACMAHON and SRIVASTAVA.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 54
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mittels einer 2,0proz. Lösung von β-Oxyäthyliminodiessigsäure als Elutionsmittel werden bei PH-Werten von 7-8 lanthanreiche Ceriterdengemische getrennt. Die zweite Austauschersäule läßt sich hierbei in der H+-Form verwenden. Das gegen Ende der Elution noch ausschließlich am Austauscher befindliche Lanthan kann durch Elutionsmittel höherer Konzentration rasch eluiert werden.Zum Zwecke der Trennung von Didymgemischen kann die zweite Austauscheräule anstatt mit Wasserstoffionen vorteilhaft auch mit Ionen der Yttererden beladen werden, wodurch neben der Trennung der Didym-Komponenten eine bemerkenswerte Fraktionierung des in der zweiten Säle eingesetzten Yttererdengemischs erzielt werden kann.Mit Austauschersäulen von 2,2 cm Durchmesser und 130 cm Länge lassen sich etwa 20 g Seltenerdoxyde in 4 bis 5 Tagen trennen, so daß größere Anteile reiner Oxyde oder doch Fraktionen binärer Gemische anfallen, welche durch Wiederholung des Verfahrens in die reinen Komponenten aufgespalten werden.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 55
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 5 (1957), S. 77-82 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nach einem kurzen Überblick über das Schrifttum wird der Reaktionsablauf bei der Darstellung von Chloranil aus Phenol durch Chlorieren in wäßrig-saurer Phase an Hand analytischer Daten und von Modellversuchen aufgezeigt.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 56
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 5 (1957), S. 97-100 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Um einen vertieften Einblick in die Primärvorgänge der Inkohlungsreaktionen von Braunkohlen in Gegenwart von Wasser zu bekommen, wurden die erhaltenen Sekundärkohlen verschwelt. Die Ergebnisse lassen den Schluß zu, daß bei Inkohlungsreaktionen die Decarboxylierung und Dehydratisierung ab etwa 300° C zugunsten einer Spaltung der Huminsäuren zurückgedrängt wird.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 57
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 241-243 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird im folgenden eine Methode beschrieben, die es gestattet, Zink durch innere Elektrolyse analytisch zu bestimmen. Seines hohen negativen Abscheidungspotentials wegen, wird als Anode Natriumamalgam verwendet. Zinkmengen vor der Größenordnung 100 mg bei 50° C und 50 mg bei Zimmertemperatur werden innerhalb 45 Minuten niedergeschlagen. Die Genauigkeit der Methode wird angegeben.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 58
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 270-277 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The insecticidal activity of some substituted sulphones and sulphonamides and their cyanoethylation products is discussed in relation to the already well-known insecticides. Some of the compounds prepared showed excellent activity. In the experimental part, the preparation of the substances thus tested has been described.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 59
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 306-318 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Wäßrige Magnesiumchloridlösungen können bei Sättigung an diesem Salz geringe Mengen Magnesiumsulfat, Natriumchlorid und Kaliumchlorid enthalten. Derartige Lösungen fallen bei industriellen Verfahren der Carnallitverarbeitung an. Über Ionenausaustauscher auf Wofatit-Basis kann durch Austausch von Natrium- und Kalium-Ionen gegen Magnesium-Ionen der Magnesiumchloridspiegel dieser Lösungen entsprechend erhöht werden. Natrium- und Kalium-Ionen lassen sich über mehrere Stufen auf diese Weise weitgehend entfernen1.Ein Austausch der Sulfat-Ionen in diesen Lösungen gegen Chlor-Ionen kann bei der angewandten Methodik nur in geringem Maße erreicht werden.Die komplizierten Verhältnisse in den untersuchten konzentrierten Elektrolytlösungen benötigen lange Gleichgewichtseinstellungszeiten, führen zu speziellen anomalen Austauscheffekten und erschweren auch die theoretische Behandlung.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 60
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 205-211 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In der vorliegenden Arbeit wird ein neues elektro-analytisches Verfahren zur schnellen und genauen Bestimmung des Thalliums mittels einer durchaus einfachen Apparatur vorgeschlagen. Die quantitative Bestimmung des Thalliums erfolgt in der Form eines Thallium(III)-oxyds, welches sich an der Platinelektrode (der Anode) abscheidet. Die Möglichkeit, eine innere Analyse mit einem auf einer indifferenten Elektrode verlaufenden Oxydationsprozesses durchzuführen, wurde bisher nicht zu analytischen Zwecken benutzt. Es wurde festgestellt, daß die Zusammensetzung des sich an der Anode abscheidenden Niederschlages der Formel Tl2O3 entspricht. Das Vorhandensein von Ag+ n. a. stört nicht die genaue Bestimmung des Thalliums.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 61
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 212-214 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über die Oxydation von o-Xylol in der flüssigen Phase mit Luft in Gegenwart von Kobaltstearat zur o-Toluylsäure berichtet und die Möglichkeit einer autokatalytischen Reaktion in Erwägung gezogen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 62
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 260-269 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die partielle Abspaltung eines Mols Wasser bei in 3-α Stellung substituierter 6 β-Oxycholansäure- und Allocholansäurederivaten führt im 1. Fall zur Darstellung der Δ6 - 3 α-Oxycholensäure und im 2. Fall zur Darstellung der Δ5 - 3 α-Oxycholensäure als Grundkörper. Von beiden Säuren wird die Herstellung einiger Derivate beschrieben. Zur Charakterisierung der Δ6-Sterinverbindungen der Normalreihe und zur Unterscheidung gegenüber den Isomeren Δ5-Verbindungen werden die bei 1650 cm-1 und bei 745 cm-1 auftretenden Banden der Δ6-Doppelbindung zugeordnet.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 63
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 88-89 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction of chloramine with an alkaline solution of benzyl mercaptan yielded benzylsulfinamide.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 64
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 106-113 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The clay mineral montmorillonite was transformed into its phenyl derivative by treatment with thionyl chloride followed by reaction with benzene in the presence of aluminium chloride.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 65
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polarographic half wave potentials and diffusion currents of 1-acetyl-azulene, 1-methyl-3-acetyl-azulene, 2-methyl-1-acetyl-azulene, 3-acetyl-guayazulene, 3-benzoyl-guayazulene, 1,3-diacetyl-azulene and 2-methyl-l,3-diacetyl-azulene have been determined as a function of the apparent pH of the supporting electrolyte.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 66
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 191-192 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 67
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Kulturbrühen von Streptomyces echinatus n. sp. wurde ein neues lipophiles, neutrales Antibioticum - das Echinomycin, C29H37O7N7S - isoliert und durch analytische Daten, UV.- und IR.- Absorptionsspektrum, sowie biologische Wirksamkeit charakterisiert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 68
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 284-299 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Wiederholung der Synthese von Strophanthidin-β-D-glucosid wird beschrieben. Durch Reduktion rnit NaBH4 wurde daraus das bisher unbekannte Strophanthidol-β-D-glucosid (III) in Kristallen erhalten. Es wurde durch sein krist. Penta-O-acetylderivat (IT) charakterisiert.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 69
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Michael addition of methylvinylketone to β-dicarbonyl compounds prepared from d, l-Δ8a-1-oxo-4β-hydroxy-4bβ-methyl-7-ethyl-enedioxy-4aα, 10aβ-dodecahydro-phenanthrene (Ia) and from the corresponding 1,4-diketone I c has been investigated. Thus from the 2-alkoxyoxalyl compounds III, IVa and b the 2α-alkoxyoxalyl-2 β- (γ-oxo-butyl) derivatives Va, Vb and VIa were obtained in excellent yield.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 70
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 350-355 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The amebicidal activity of the phenanthroline quinones published earlier2) and of their derivates described in this paper is discussed. The highest activity was found with 4,7-phenanthrolino-5, 6- quinone 1 and its monosemicarbazone 3, which are also active in man. Further derivatives of 1 are described.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 71
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two new methods for preparing carboxylic acid aryl esters are presented. They consist in reacting the carboxylic acid with (a) aryl sulfites or (b) aryl phosphites in the presence of pyridine. A possible mechanism of the sulfite method is discussed.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 72
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 387-394 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: With a view to investigate the biological degradation of „Doriden“ some glutarimides have been synthesized which are presumptive intermediate products.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 73
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 487-491 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dehydrierung von Bovosidol A und Bovosidol D mit tert. Butylchromat führte zu Bovosid A und Bovosid D. Ca. 50% des Ausgangsmaterials wurden unverändert zurückgewonnen. Nebenprodukte wurden praktisch keine gebildet. Bei derselben Dehydrierungs-Prozedur wurde Scilliglaucosidin-19-ol nicht nur an C-19, sondern auch an C-3 angegriffen. Im Reaktionsprodukt konnten papierchromatographisch Ausgangssubstanz, Scilliglaucosidin, 3-Dehydro-scilliglaucosidin-19-ol und 3-Dehydro-scilliglaucosidin nachgewiesen werden.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 74
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 499-501 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The formation of 2-hydroxy-chinoline-4-carbonic acid from isatine via N-acetyl-isatine and N-acetyl-isatinic acid was investigated. The first two reactions are reversible, the third step is irreversible. The three reactions were carried out simultaneously under pressure.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 75
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957) 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 76
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 193-199 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Natürliches (-)-Colchicin wurde in das bekannte N-Benzylidendesacetyl-colchicein (III) umgewandelt. III konnte alkalisch racemisiert werden. Aus racemischem III gewonnenes DL-Desacetyl-colchicein wurde mit D-Camphersulfonsäure in die Antipoden (II und IV) zerlegt. Letztere führten nach Acetylierung und Einwirkung von Diazomethan u. a. zum natürlichen (-)-Colchicin und zum unnatürlichen (+)-Colchicin. DL-Colchicin wurde sowohl durch Mischung der antipoden (+)- und (-)-Colchicine wie aus racemischem Desacetylcolchicein hergestellt, wobei als Nebenprodukt kristallisiertes DL-Isocolchicin isoliert wurde. Die Konstitution sämtlicher neu hergestellten Verbindungen folgt eindeutig aus ihrer Herstellungsweise und ihren physikalischen Daten.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 77
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 221-228 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Homogeneous ion exchange between cations and complex anions is producing separation-effects in an electric field. If this field is maintained across a stationary gradient of the complex forming anions focusing properties are obtained. It is shown by semiquantitative arguments that a solution of a number of cations Mivi+ is changing into a system of as many narrow zones of the pure species Mi. The para- meters of the method are discussed and several research topics presently under work are mentioned.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 78
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 246-248 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: α, α-Diveratryläthylen kuppelt in Eisessiglösung mit 4-Nitrophenylantidiazotat und 2,4-Dinitrophenyldiazoniumsulfat unter Bildung von Äthylendisazokörpern.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 79
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 265-266 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 80
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 736-740 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die durch Methylierung bzw. Äthylierung aus Tetrahydro-carbazol gebildeten 9,11-Dialkyl-Δ9,10-carbazoleniniumjodide und die aus ihnen durch Lauge gebildeten Basen wurden spektrophotometrisch untersucht.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 81
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 395-401 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of four derivatives of phenylbutazone with one or two hydroxy groups in the phenyl nuclei is described, among them p-hydroxy-phenylbutazone [1-(p-hydroxyphenyl)-2-phenyl-4-n-butylpyrazolidine-3,5-dione] (II) which is one of the metabolites of phenylbutazone in man.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 82
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 428-432 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird eine Apparatur beschrieben, mit der eine schnelle und genaue Bestimmung des Kohlenstoffes und der l4C-Radioaktivität in festen oder flüssigen Substanzen, Lösungen und in biologischem Material ausgeführt werden kann.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 83
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 492-494 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: L'auteur décrit l'hydrogénation du scyllo-ms-inosose et du DL-épi-ms-inosose au moyen du borohydrure de sodium et présente un essai d'explication théorique des résultats obtenus.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 84
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 717-721 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dans la fraction acide du condensat de la fumée de cigarette nous n'avons pas pu déceler de substances définies dont l'activité cancérigène soit reconnue. Une partie importante de cette fraction est constituée par des produits polymérisés qui pourraient être tenus pour responsables du pouvoir cancérigène certain de la fraction acide globale. Dans le condensat de la fumée de cigarette obtenu par un procédé spécial, on a trouvé de l'hydroquinone, ce qui rend probable la présence de p-benzoquinone dans la fumée de cigarette.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 85
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 1056-1059 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1-Hydroxy-2-arylazonaphtaline sind tieferfarbig als die entsprechenden 2-Hydroxy-1-arylazonaphtaline. Übergang in die analogen 9-Hydroxy-10-arylazophenanthrene durch Anellierung eines Benzolrings wirkt bezogen auf die 2-Hydroxy-1-arylazonaphtaline nur sehr schwach bathochrom, bezogen auf die 1-Hydroxy-2-arylazonaphtaline aber beachtlich hypsochrom.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 86
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 1066-1084 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Der thermodynamische Nutzeffekt einer Trennung ist der Quotient aus der mechanischen Energie, welche benötigt wird, die Stofftrennung isotherm und reversibel vorzunehmen, und der mechanischen Energie, welche in einem praktischen Falle für die Trennung aufgewendet wird. Diese Energien werden angegeben für die Herstellung von einer Grammolekel eines Produktes, welches die leichter flüchtige Komponente in einer relativen Konzentration γe enthält, ausgehend von einer grossen Menge eines binären Gemisches, in welchem die leichter flüchtige Komponente in einer relativen Konzentration γ0 vorliegt. Der Nutzeffekt wird angegeben für die Trennung durch Destillation mit Hilfe einer optimal arbeitenden Rektifizierkolonne ohne und mit Verwendung einer Wärmepumpe zur Wiederverwertung der bei der Rücklauferzeugung anfallenden Kondensationswärme.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 87
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The iso-α-irone (2,6)trans (21,22)cis-α-irone) was obtained by fractional distillation of the crude irone prepared by cyclisation of pseudo-irones by means of boron trifluoride. This ketone and its ethylenic stereoisomer, the neo-iso-α-irone (2,6)trans (21, 22)trans-α-irone were reduced to alcohols by means of lithium-aluminium hydride without noticeable stereomutation.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 88
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 1157-1166 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several benzophenone and biphenylmethane derivatives, structural analogues of terramycine, were prepared using the Baeyer, Friedel-Crafts, and Fries reactions.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 89
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 937-949 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Methionylmethionin ist ein relativ saures Dipeptid; pK1′ = 3,20, pK2′ = 7,53, PI′ = 5,36. Dies hat zur Folge, dass das thermodynamische Gleichgewicht zwischen Methionylmethionin und Methionin durch pH-Verschiebungen stärker beeinflusst wird als z. B. das Gleichgewicht, im System Alanylglycin/Alanin + Glycin. In Gegenwart einer Dipeptidase aus Ratten- oder Schweineleber gelingt es, in einer 0,17-m. Lösung von L-Methionin durch blosse Verschiebung des pH zwischen 7 und 8 eine papierchromatographisch nachweisbare Synthese oder Hydrolyse von L-Methionyl-L-methionin zu bewirken. Das Peptid ist auch präparativ gefasst und identifiziert worden. Der Aktivitäts- bereich der Dipeptidase aus Schweineleber liegt zwischen pH 6,5 und 9,5 mit einem Optimum bei pH 7,5. Die Hydrolyse von L-Methionyl-L-methionin erfolgt im untersuchten Konzentrationsbereich nach der nullten Ordnung. D-Methionyl-D-methionin wird durch die Dipeptidase nicht angegriffen.Zur quantitativen Verfolgung der Dipeptidspaltung diente ein genau beschriebenes papierchromatographisches Verfahren, welches gut reproduzierbare Werte liefert.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 90
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 980-1015 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus den Samen von Strophanthus Tholloni Franch. wurden nach Fermentierung 9 krist. Glykoside in freier Form sowie weitere 6 in Form ihrer krist. Acetylderivate isoliert. Ein 16. Stoff (Subst. γ) konnte nur in amorpher, aber praktisch einheitlicher Form isoliert werden. Ausserdem wurden kleine Mengen von 2 weiteren Glykosiden (R, S) papierchromatographisch nachgewiesen.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 91
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Starting from d,l-δ8a-1-oxo-4 β-hydroxy-4b β-methyl-7-ethylene- dioxy-l,2,3,4, 4a α, 4b β, 5,6,7,8,10,10a β-dodecahydro-phenanthrene (I) the preparation of several tricyclic intermediates substituted at carbon atom 2 is described. The structure of these compounds has been established by a series of transformations.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 92
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 1060-1061 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird ermittelt, dass beim 1,2-Chrysenchinon die Arylhydrazonbildung in 2-Stellung erfolgt.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 93
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 1062-1066 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus Knollen von Orchis militaris L., die mit dem Mykorrhizenpilz Rhizoctonia repens Bern. infiziert worden waren, wurden biologisch aktive Fraktionen isoliert, die zum Teil näher untersucht wurden. Neben Cumarin wurden zwei weitere kristalline Substanzen erhalten, von denen eine, der Formel C16H16O3, Orchinol genannt wurde. Orchinol liess sich in frischen Knollen nicht nachweisen; es wird erst während der Inkubation der Knollen und in noch höherem Masse unter der Einwirkung des Pilzes gebildet.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 94
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The ketonic bitter principle limonin and the corresponding secondary alcohol limonol have been shown to undergo a deep-seated hydrolytic cleavage in the presence of alkali. The course of these cleavages which lead to a new series of compounds with 20 and 21 carbon atoms respectively, involves the splitting of a β-substituted furan nucleus. These as well as previous findings are interpreted in terms of the partial formula.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 95
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Unter dem Namen Aminoacyl-Einlagerung wird ein neuer Umlagerungstypus beschrieben, welcher von O-aminoacylierten β-Hydroxysäureamiden zu β-Hydroxyacyl-aminosäureamiden führt. Die β-Hydroxysäure kann aliphatisch oder aromatisch sein. Da der Amidstickstoff substituiert sein darf, gestattet die Reaktion den Aufbau von Peptidketten. Peptide schienen bisher nur durch Aminoacyl-Anlagerungs-Reaktionen zugänglich zu sein. Die Aminoacyl-Einlagerungs-Reaktion weist einen prinzipiell neuen Weg.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 96
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Stereospecific syntheses of cycloserine (D-4-amino-3-isoxazolidinone) are described. The same synthetic methods lead to some 5-substituted 4-amino-3-isoxazolidinones. The stereochemical relationship of these compounds to the parent amino acids is discussed.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 97
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus dem Kulturfiltrat eines Streptomyceten-Stammes, der vorläufig bei Streptomyces olivaceus (Waksman) Waksman & Henrici eingeordnet wurde, liess sich ein kristalliner, antibiotisch wirksamer Farbstoff mit lackmusähnlichen Eigenschaften - das Granaticin - isolieren. Wie aus dem auf röntgenographischem Wege bestimmten Molekulargewicht, den analytischen Daten und Absorptionsspektren des Farbstoffes und seines Tetra-O-acetyl-Derivates folgt, handelt es sich vermutlich um eine tricyclische Tetrahydroxy-chinon-dicarbonsäure C22H20O10.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 98
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 1819-1822 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Abbau von (+)-Catechin mit Ozon und Perameisensäure und Reduktion der veresterten Abbauprodukte mit LiAlH4 führte zu 2-Desoxy-D-adonit, der als kristallisiertes Tetraphenylurethan isoliert und mit einem aus 2-Desoxy-D-ribose hergestellten Vergleichspräparat identifiziert wurde. Dieses Ergebnis beweist die Richtigkeit, der von Freudenberg für (+)-Catechin abgeleiteten absoluten Konfiguration gemäss Formel I.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 99
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 40 (1957), S. 1331-1357 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: From the rhizomes of american Podophyllum peltatum L. it was possible to isolate and characterize four lignan glucosides with anti-mitotic activity: podophyllotoxin-β-D-glucoside (IX), β-peltatin-β-D-glucoside (XI), 4′-demethylpodophyllotoxin-β-D-glucoside (X) and α-peltatin-β-u-glucoside (XII). The constitution of β-peltatin-β-D- glucoside was deduced from the fact that enzymatic cleavage with emulsin yielded D-glucose and the already known β-peltatin. α-Peltatin-β-D-glucoside, the first native glucoside of podophyllum t o be isolated in crystalline form, breaks down to D-glucose and α-peltatin on hydrolysis with emulsin. The position of the sugar component in 4′- demethylpodophyllotoxin-β-D-glucoside and in α-peltatin-β-D-glucoside could be determined by methylation to podophyllotoxin-β-D- glucoside and β-peltatin-β-D-glucoside.Distribution chromatography of the lignan glucosides on columns of silicagel proved a reliable analytical procedure. It could be used both as a test of purity and for assaying enriched fractions and crude plant extracts.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 100
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Starting from the polyhydrophenanthrene derivative I, the preparation of which has been described in the preceding paper, the synthesis of several racemic (18 → 11)-lactones of the pregnene series is presented in detail.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...